KR102530848B1 - Aluminum non slip sheet - Google Patents

Abstract

According to the present invention, the aluminum thin plate layer having a shape corresponding to the adhered surface is deformed to provide a heat shielding function; A TPO layer configured on the upper surface of the aluminum thin plate layer to suppress rupture or breakage of the aluminum thin plate layer; A binder layer configured on the upper surface of the TPO layer and enabling printing or printing to provide a corresponding cover function; An anti-slip layer configured on the binder layer to provide an anti-slip function; A heat insulating adhesive layer configured on the lower surface of the aluminum thin plate layer to allow the aluminum thin plate layer to be adhered to the adhered surface and to insulate heat transmitted from the adhered surface; A liner layer formed on the lower surface of the heat insulating adhesive layer to protect the heat insulating adhesive layer and selectively peeled off, and a phosphorescent layer formed in the blank space of the binder layer to accumulate and emit light absorbed from the outside to improve visibility; And it is composed of the upper surface of the binder layer including the photoluminescent layer to provide a high-hardness and high-density glass film to the photoluminescent layer and the binder layer to suppress stains and discoloration of the photoluminescent layer and the binder layer, maintain the color and texture of the printed content for a long time, and There is provided an aluminum non-slip luminous and cover sheet for evacuation guidance including an anti-adhesion layer composed of a ceramic layer or an acrylic layer to suppress the attachment of illegal advertisements by suppressing the attachment of illegal advertisements.

Description

Aluminum non-slip luminescent and cover sheet for evacuation guidance {Aluminum non slip sheet}

The present invention relates to a cover sheet, and more particularly, an aluminum thin plate layer is formed on a TPO layer or a fabric layer to improve durability, and a heat shielding function is provided by the aluminum thin plate layer to prevent easy peeling from the road surface. At the same time, A binder layer and a phosphorescent layer are formed on the upper part of the aluminum thin plate layer to provide the corresponding display function while suppressing the attachment of advertisements such as illegal advertisement stickers to the display layer. will be.

In general, road surface signs for displaying various types of road traffic indication information, prohibited areas, school zones, silver zones, red zones, and the like are installed on road surfaces.

Most of these road signs are marked by operating a construction machine in the field using room temperature paint or fusion-type road sign paint, or a method of installing using an adhesive sheet is mainly used.

However, as described above, in the case of normal temperature type paint or fusion type paint, the thickness of the coating film is thin and durability is low, and it takes a predetermined drying time and hinders traffic depending on the use of the corresponding equipment. Even if the penetration is suppressed, there is a problem in that it is easily peeled off from the road surface by geothermal heat.

In response, information-providing sheets that indicate road traffic display information or evacuation guidance information have been recently disclosed on the road surface, etc., but advertisements or printed materials are illegally attached to the information display portion of the information-providing sheets, so that the information is not provided. Not only is this not done properly, but many social problems are being caused due to waste of manpower and budget for removing illegal advertisements or printed materials.

(Patent Document 0001) Republic of Korea Patent Publication No. 10-2007-01218876

(Patent Document 0002) Republic of Korea Patent No. 1881585

Therefore, an object of the present invention is to improve the durability by forming an aluminum thin plate layer on the TPO layer or the fabric layer, and to provide a heat shield function by the aluminum thin plate layer so that it is not easily peeled off from the road surface, and at the same time, a binder on top of the aluminum thin plate layer. It is to provide an aluminum non-slip phosphorescent cover sheet and an evacuation guide cover sheet capable of suppressing the attachment of advertisements such as illegal advertisement stickers to the display layer while providing a corresponding display function by configuring a layer and a phosphorescent layer.

On the other hand, the object of the present invention is not limited to the purpose mentioned above, and other objects not mentioned will be clearly understood by those skilled in the art from the description below.

According to the present invention, the aluminum thin plate layer having a shape corresponding to the adhered surface is deformed to provide a heat shielding function; A TPO layer configured on the upper surface of the aluminum thin plate layer to suppress rupture or breakage of the aluminum thin plate layer; A binder layer configured on the upper surface of the TPO layer and enabling printing or printing to provide a corresponding cover function; An anti-slip layer configured on the binder layer to provide an anti-slip function; A heat insulating adhesive layer configured on the lower surface of the aluminum thin plate layer to allow the aluminum thin plate layer to be adhered to the adhered surface and to insulate heat transmitted from the adhered surface; A liner layer formed on the lower surface of the heat insulating adhesive layer to protect the heat insulating adhesive layer and selectively peeled off, and a phosphorescent layer formed in the blank space of the binder layer to accumulate and emit light absorbed from the outside to improve visibility; And it is composed of the upper surface of the binder layer including the photoluminescent layer to provide a high-hardness and high-density glass film to the photoluminescent layer and the binder layer to suppress stains and discoloration of the photoluminescent layer and the binder layer, maintain the color and texture of the printed content for a long time, and There is provided an aluminum non-slip luminous and cover sheet for evacuation guidance including an anti-adhesion layer composed of a ceramic layer or an acrylic layer to suppress the attachment of illegal advertisements by suppressing the attachment of illegal advertisements.

Here, the ceramic layer is preferably a one-component anti-adhesion coating agent in which isopropyl alcohol, methyltrimethyloxysilane, trimethoxysilane, 1-butanol titanium salt, and dimethylpolysiloxane are added and mixed.

In addition, the one-component advertisement anti-adhesion coating agent contains 47% by weight of isopropyl alcohol, 45% by weight of methyltrimethyloxysilane, 5% by weight of trimethoxysilane, 2% by weight of 1-butanol titanium salt and 1% by weight of dimethylpolysiloxane It is preferred that weight percent is added and mixed.

In addition, the acrylic layer is a mixed ester compound of butyl acrylic acid-butyl methacrylic acid-methacrylic acid-methyl methacrylic acid-styrene polymer, zinc oxide, 2-ethylhexoic acid-benzoic acid-triethylene glycol, diethylene glycol It is preferably a one-component anti-adhesion coating agent in which monoedyl adder, PE wax, and water are added and mixed.

In addition, the one-component anti-adhesive coating agent is butyl acrylic acid-butyl methacrylic acid-methacrylic acid-methyl methacrylic acid-styrene polymer 100 parts by weight, zinc oxide 1 to 3 parts by weight, 2-ethylhexoic acid- 10 to 20 parts by weight of a mixed ester compound of benzoic acid-triethylene glycol, 10 to 20 parts by weight of diethylene glycol monoedyl ether, 15 to 50 parts by weight of PE Wax, and 200 to 250 parts by weight of water are preferably added and mixed. .

According to the present invention, an aluminum thin plate layer is formed on the TPO layer or the fabric layer to improve durability, and a heat shielding function is provided by the aluminum thin plate layer to prevent easy peeling from the road surface, and at the same time, a binder layer on top of the aluminum thin plate layer. and a phosphorescent layer are configured to provide a corresponding display function, while preventing advertisements such as illegal advertisement stickers from being attached to the display layer.

On the other hand, the effects of the present invention are not limited to the effects mentioned above, and other effects not mentioned will be clearly understood by those skilled in the art from the description of the claims.

1 is a cross-sectional view showing the configuration of an aluminum non-slip luminescent and cover sheet for evacuation guidance according to a preferred embodiment of the present invention;
2 is a cross-sectional view showing the configuration of a cover sheet for luminescence and evacuation guidance according to a modified example of the present invention.

Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.

As shown in FIGS. 1 and 2, the aluminum non-slip luminous and cover sheet for evacuation guidance according to a preferred embodiment of the present invention is deformed while having a shape corresponding to the road surface or adherends of various materials to provide a heat shielding function. An aluminum thin plate layer 10 configured on the upper surface of the aluminum thin plate layer 10 to suppress rupture or fracture of the aluminum thin plate layer 10, a TPO layer 20 configured on the upper surface of the TPO layer 20, and letters or The binder layer 30, which enables printing or printing of designs and provides a corresponding cover function, the anti-slip layer 40, which is composed of the binder layer 30 and provides an anti-slip function, and the aluminum thin plate layer 10 A heat insulating adhesive layer 50 configured on the lower surface to allow the aluminum thin plate layer 10 to be attached to a road surface or an adherend and to insulate heat transmitted from the road surface or adherend, and a heat insulating adhesive layer 50 configured on the lower surface of the heat insulating adhesive layer 50 to insulate heat transmitted from the road surface or adherend ) and a liner layer 60 that is selectively peeled off, a phosphorescent layer 70 and a phosphorescent layer 70 configured in the blank space of the binder layer 30 to accumulate and emit light absorbed from the outside to improve visibility It is configured on the upper surface of the binder layer 30 including the photoluminescent layer 70 and the binder layer 30 to provide a glassy film of high hardness and high density to suppress stains and discoloration of the photoluminescent layer 70 and the binder layer 30. and an anti-adhesion layer 80 composed of a ceramic layer or an acrylic layer that maintains the color and texture of the printed contents for a long time and suppresses the adhesion of the adhesive to suppress the attachment of illegal advertisements.

The aluminum thin plate layer 10 provides a heat-shielding function to suppress peeling of the heat insulating adhesive layer 50 or the like by the geothermal heat of the road surface by providing a property of changing its shape to variably correspond to the shape of the road surface or adherend of various materials. As an aluminum thin plate, it can be easily attached to the road surface or adherend of various materials such as stone, wood, steel, concrete, asphalt, etc. through aluminum material.

Here, the aluminum thin plate layer 10 has a thickness of 0.05 mm to 0.1 mm. If the thickness is less than the above thickness, the ability to absorb heat transmitted from the binder layer 30 in summer is reduced, and the thickness If it exceeds, there is a problem in that the heat transfer function of receiving heat from the heat insulating adhesive layer 50 and transferring it to the binder layer 30 in winter is deteriorated, so it is good to have a critical significance through the above numerical limitation, more preferably Preferably, it is recommended to provide optimal heat shielding and heat transfer functions through having a thickness of 0.07 mm.

Therefore, according to the aluminum thin plate layer 10, it can be easily attached regardless of the material or shape of the road surface or adherend, and at this time, through a predetermined thickness, the heat of the road surface is blocked from being transferred to the binder layer 30 as it is, It is possible to improve the durability of the binder layer 30 by dissipating heat radiated to the binder layer 30 and to improve adhesion by maximally suppressing shape change or expansion and contraction according to temperature.

The TPO layer 20 is formed on the upper surface of the aluminum thin plate layer 10 and is a means for suppressing rupture or breakage of the aluminum thin plate layer 10, and is made of at least one of known PP, PE and PET, and has a waterproof function. to provide.

Here, the TPO layer 20 is preferably made of a high-strength polyolefin material and has a thickness of 0.012 mm to 0.05 mm. When the shape is changed for attachment to a complex, the function of protecting the aluminum thin plate layer 10 is lowered, and when the thickness exceeds the above, the shape variability of the aluminum thin plate layer 10 is suppressed, so that the aluminum thin plate layer 10 is applied to the road surface or Since there is a problem of not being able to change to correspond to the shape of the adherend, it is good to have a critical significance through the above numerical limitation, and more preferably through having a thickness of 0.018mm, providing optimal protection and attachment function It is good to do.

Therefore, according to the TPO layer 20, it is possible to improve the adhesion function of the heat insulating adhesive layer 50 by suppressing the fracture and rupture of the aluminum thin plate layer 10 whose shape is variable to be attached to the road surface or adherend and providing a waterproof function. can

The binder layer 30 is configured on the upper surface of the TPO layer 20 to enable printing or printing of characters or designs, and is a means for providing a corresponding cover function. Primer for printing or printing the corresponding characters or designs function.

Here, the binder layer 30 is a primer made of polyurethane, and is applied with a thickness of 0.04 mm to 0.1 mm. If the thickness is less than the thickness, the adhesion of the anti-slip layer 40 described below is reduced, and the thickness If it exceeds, the gelation layer becomes thick and the shape variability of the aluminum thin plate layer 10 is greatly reduced and usability is reduced, so it is good to have the above critical significance, and more preferably to have a thickness of 0.07 mm Through this, it is good to provide optimal usability and attachment function.

Therefore, according to the binder layer 30, it is possible to print or print to provide a corresponding label function to provide a label function, and also to enable the construction of the non-slip layer 40 and the photoluminescent layer 70 described below. there is.

The anti-slip layer 40 is applied and coated together with the composition of the binder layer 30 during application or coating of the binder layer 30 to provide an anti-slip function, and is preferably a ceramic bead having a predetermined size. .

Here, the anti-slip layer 40 has a thickness of 0.2 mm to 0.6 mm, when the thickness is less than the anti-slip function is reduced, and when the thickness is exceeded, the gelation layer of the binder layer 30 Since it becomes thicker, the shape variability of the aluminum thin plate layer 10 is greatly reduced and usability is lowered, so it is good to have the critical significance as described above, more preferably through having a thickness of 0.3mm, the optimal anti-slip function It is good to provide

Therefore, according to the anti-slip layer 40, when attaching to a road surface or an adherend using the aluminum thin plate layer 10, a non-slip function is provided through an embossed structure, and the corresponding character is printed on the binder layer 30 such as a design or printing can be made possible.

The heat insulating adhesive layer 50 is formed on the lower surface of the aluminum thin plate layer 10 so that the aluminum thin plate layer 10 is attached to the road surface or adherend and is an adhesive means for insulating heat transmitted from the road surface or adherend, for heat insulation Contains adhesive.

Here, the adhesive for heat insulation has an average particle diameter of 350 to 450 mesh, 3 to 5 parts by weight of a heat curing agent, 2 to 3 parts by weight of a room temperature curing agent, and an average particle diameter of 350 to 450 mesh based on 100 parts by weight of the rubber-type adhesive. , 5 to 10 parts by weight of porous inorganic fine particles made of any one selected from the group consisting of diatomaceous earth and mixtures thereof, and 5 to 7 parts by weight of fiberglass.

The rubber-type pressure-sensitive adhesive has a predetermined elasticity and provides adsorption and adhesion functions, and is stably attached to the adherend surface when mixed with the heat curing agent and room temperature curing agent, and the aluminum thin plate layer ( 10) to be attached to the lower surface with stronger adhesion.

Here, since the rubber-type adhesive preferably contains 38% solid content and may have a known composition, a detailed description thereof will be omitted.

The heat curing agent is a curing member that reacts with the rubber-type adhesive or room temperature curing agent when mixed with them to improve various physical properties such as improved impact strength and heat resistance, moisture resistance and mechanical properties, and 100 parts by weight of the rubber-type adhesive 3 to 5 parts by weight are added as a standard. If the amount exceeds 5 parts by weight, the curing time is too fast, making it inconvenient to apply to the aluminum thin plate layer 10, and if the amount is less than 3 parts by weight, the curing time is too slow. Since there is a problem that the adhesive foot becomes long after a long time, it is good to have the above critical significance, and more preferably, it is good to have 4 parts by weight.

Here, since the heat curing agent may have a known composition, a detailed description thereof will be omitted.

The room temperature curing agent, when mixed with the rubber-type adhesive or heat curing agent, reacts with them to cure the mixture at room temperature to prevent the rubber-type adhesive and heat curing agent from spreading to the outside of the adhered surface As a transfer prevention member, 2 to 3 parts by weight is added based on 100 parts by weight of the rubber-type pressure-sensitive adhesive. When the amount exceeds 3 parts by weight, the curing time at room temperature proceeds rapidly, so the usable time of the product is greatly shortened, and when the amount is less than 2 parts by weight Since there is a problem that the rubber-type adhesive and the heat curing agent spread to the outside of the adhered surface, it is good to have the above critical significance, and more preferably, it is good to have 0.5 parts by weight.

Here, since the room temperature curing agent may have a known composition, a detailed description thereof will be omitted.

The porous inorganic fine particles are a heat insulating member that provides an air layer between the aluminum thin plate layer 10 and the road surface, and provides high heat insulating properties through a plurality of pores, and more preferably, the heat insulating effect is achieved through the pores being closed. Better to improve further.

Here, the porous inorganic fine particles are added in an amount of 5 to 10 parts by weight based on 100 parts by weight of the rubber-type adhesive. When the amount exceeds 10 parts by weight, the adhesive function of the rubber-type adhesive, room temperature curing agent and heat curing agent is reduced, and the In the case of less than 5 parts by weight, there is a problem in that the heat insulating property is lowered, so it is good to have the above critical significance, and more preferably, it is good to have 7 parts by weight.

The fiberglass provides fire resistance to suppress volatile adhesive compositions from being ignited by the temperature of the adhered surface when a heat insulating layer is provided between the aluminum thin plate layer 10 and the adhered surface.

Here, the fiberglass is added in an amount of 5 to 7 parts by weight based on 100 parts by weight of the rubber-type adhesive. When the amount exceeds 7 parts by weight, the elasticity is lowered and the shape variability of the aluminum thin plate layer 20 is suppressed, thereby reducing the adhesiveness. This is greatly reduced, and if it is less than 5 parts by weight, there is a problem that fire resistance is lowered, so it is good to have the critical significance as described above, and more preferably, it is good to have 6 parts by weight.

Therefore, according to the heat insulating adhesive layer 50, it bonds between the aluminum thin plate layer 10 and the road surface and at the same time suppresses the transfer of heat from the road surface to the aluminum thin plate layer 10 as much as possible, such as in summer, so that the binder layer 30 etc. Stretching of the back can be suppressed as much as possible.

In addition, according to the heat insulating adhesive layer 50, the heat of the ground or the adherend is transferred to the aluminum thin plate layer 10 in winter, etc., so that the binder layer 30 having a relatively low temperature shrinks at a low temperature. there is.

On the other hand, the heat insulating adhesive layer 50 preferably has a thickness of 0.04 mm to 0.15 mm, and when the thickness is less than the above thickness, the thickness is too thin and the heat reflectance through the aluminum thin plate layer 10 is reduced, and the thickness If it exceeds, the thickness is too thick, so that the temperature of the ground is suppressed from being transferred to the aluminum thin plate layer 10 in winter, etc., and there is a problem that the binder layer 30 shrinks. Preferably through having a thickness of 0.1mm, it is good to provide an optimal heat insulation or heat transfer function.

The liner layer 60 is preferably a release film that is formed on the lower surface of the heat insulating adhesive layer 50 to protect the heat insulating adhesive layer 50 and is selectively peeled off.

The photoluminescence layer 70 is a means for improving visibility by accumulating and emitting light absorbed from the outside in the blank space of the binder layer 30, and may have a known configuration, so a detailed description thereof will be omitted.

Here, the photoluminescent layer 70 preferably has a thickness of 0.05 mm to 0.15 mm. If the thickness is less than the above thickness, the thickness is too thin and visibility and protection properties are reduced. If the thickness exceeds the above thickness, the thickness Since it is too thick, the embossed height of the anti-slip layer 40 is lowered, the non-slip function is lowered, and the shape variability of the aluminum thin plate layer 10 is lowered, so it is good to have the above critical significance, more preferably It is good to provide optimal visibility and usability through having a thickness of 0.1 mm.

The advertisement anti-adhesion layer 80 is formed on the upper surface of the binder layer 30 including the photoluminescent layer 70 and provides a high hardness and high density glassy film to the photoluminescent layer 70 and the binder layer 30 to provide a photoluminescent layer ( 70) and the binder layer 30, as a means for suppressing stains and discoloration, maintaining color and texture of printed contents for a long time, and inhibiting adhesion of illegal advertisements by suppressing adhesion of adhesive, which may be composed of a ceramic layer or an acrylic layer. can

Here, in the ceramic layer, isopropyl alcohol, methyltrimethyloxysilane, trimethoxysilane, 1-butanol titanate, and dimethylpolysiloxane are added and mixed, and the one-component advertisement anti-adhesion coating agent is applied to the photoluminescent layer 70. It may be configured to be coated or coated on the upper surface of the binder layer 30 including.

More preferably, the one-component anti-adhesion coating agent is 47% by weight of isopropyl alcohol, 45% by weight of methyltrimethyloxysilane, 5% by weight of trimethoxysilane, 2% by weight of 1-butanol titanium salt and dimethyl poly It has a configuration in which 1% by weight of siloxane is added and mixed.

Isopropyl alcohol has a CAS number of 67-63-0, and the anti-adhesion coating agent provides adhesion and water-repellent functions when forming the anti-adhesion layer 80, and the methyltrimethyloxysilane and trimethoxysilane , 47% by weight is added with respect to 1-butanol titanium salt and dimethylpolysiloxane, and when the weight% is exceeded, the coating layer formation function is improved by improving the adhesive function, but the corrosion resistance is lowered, and the weight% If it is less than a certain thickness, there is a problem that the coating function is deteriorated because the coating layer of a predetermined thickness is not secured, so it is preferable to have a limited weight% as described above.

Methyltrimethyloxysilane, CAS number 1185-55-3, provides adhesion when the anti-adhesion coating agent forms the anti-adhesion layer 80, and the isopropyl alcohol, trimethoxysilane, 1 - 45% by weight is added relative to the butanol titanate and dimethylpolysiloxane, but when the weight% is exceeded, the increase in adhesion to the binder layer 30 is rather slowed, resulting in additional unnecessary costs. If it is less than the weight %, since the adhesive force with the binder layer 30 is weakened and there is a problem in that it is easily peeled off, it is preferable to have a limited weight % as described above.

Trimethoxysilane, CAS number 2530-83-8, is a regulator for controlling the curing time upon application of a one-component anti-adhesive coating, and isopropyl alcohol, methyltrimethyloxysilane, 1-butanol titanium salt And 5% by weight is added relative to dimethylpolysiloxane. When the weight% is exceeded, the anti-adhesive coating agent has a gel state, and storage stability is reduced. Since there is a problem that the curing time is delayed when applied in a molten state, it is preferable to have a limited weight % as described above.

1-butanol titanate has a CAS number of 5593-70-4, and when the anti-adhesion coating agent forms the anti-adhesion layer 80, it provides UV protection, etc., and the isopropyl alcohol, methyltrimethyloxysilane , 2% by weight is added relative to trimethoxysilane and dimethylpolysiloxane. If the weight% is exceeded, the thickness of the anti-adhesion layer 80 becomes too thick, resulting in poor adhesion of methyltrimethyloxysilane. When it is lowered and is less than the above weight %, the thickness of the anti-adhesion layer 80 is not sufficiently secured, so that the UV blocking property is lowered and the deterioration preventing function of the binder layer 30 is lowered. It is desirable to have the same limited weight percentage.

Dimethylpolysiloxane, CAS number 70131-67-8, makes the anti-adhesion layer 80 have a predetermined elasticity and provides a coating function so that the adhesive composed of illegal advertisements As a configuration that suppresses adhesion to the upper surface of the isopropyl alcohol, methyltrimethyloxysilane, trimethoxysilane and 1-butanol titanium salt is added 1% by weight, if the weight% exceeds the advertisement The elasticity and coating degree of the anti-adhesion layer 80 become too large, so that the adhesive of illegal advertisements cannot be firmly attached, but the curing time is long, reducing manufacturability and strength, and when less than the above weight %, the anti-adhesion layer ( 80) is too small, so that the adhesive of illegal advertisements is firmly attached and the peeling effect of the adhesive of illegal advertisements is reduced.

On the other hand, the acrylic layer is a mixed ester compound of butyl acrylic acid-butyl methacrylic acid-methacrylic acid-methyl methacrylic acid-styrene polymer, zinc oxide, 2-ethylhexoic acid-benzoic acid-triethylene glycol, diethylene glycol A one-component anti-adhesion coating agent in which monoedyl adder, PE wax, and water are added and mixed may be coated or coated on the upper surface of the binder layer 30 including the photoluminescent layer 70.

More preferably, the one-component anti-adhesive coating agent is butyl acrylic acid-butyl methacrylic acid-methacrylic acid-methyl methacrylic acid-styrene polymer 100 parts by weight, zinc oxide 1 to 3 parts by weight, 2-ethyl 10 to 20 parts by weight of a mixed ester compound of hexoic acid-benzoic acid-triethylene glycol, 10 to 20 parts by weight of diethylene glycol monoedyl ether, 15 to 50 parts by weight of PE Wax, and 200 to 250 parts by weight of water are added and mixed have a configuration

The butyl acrylic acid-butyl methacrylic acid-methacrylic acid-methyl methacrylic acid-styrene polymer has CAS number 25950-40-7, and the anti-adhesion coating agent forms the anti-adhesion layer 80 for adhesion and order protection. 100 parts by weight is added to zinc oxide, a mixed ester compound of 2-ethylhexoic acid-benzoic acid-triethylene glycol, diethylene glycol monoedyl ether, PE Wax and water, which provides If it exceeds, the coating layer formation function through improved adhesion function is improved, but corrosion resistance is lowered, and if it is less than the above weight part, a coating layer of a predetermined thickness cannot be secured, so there is a problem in that the coating function is lowered. It is preferable to have a weight part.

Zinc oxide has a CAS number of 7732-18-5 and provides an anti-oxidation function when the anti-adhesion coating agent forms the anti-adhesion layer 80, butyl acrylic acid-butyl methacrylic acid-methacrylic acid- 1 to 3 parts by weight is added based on 100 parts by weight of the methyl methacrylic acid-styrene polymer. If the weight exceeds the above parts, manufacturability such as elongation of the thermoplastic resin is lowered during manufacture of the sheet, and less than the above parts by weight In the case of doing so, it is preferable to have a limited weight part as described above because there is a problem in that the antioxidant function is reduced and easily discolored by ultraviolet rays or the like.

The mixed ester compound of 2-ethylhexoic acid-benzoic acid-triethylene glycol has a CAS number of 852227-26-0, and when the anti-adhesion coating agent forms the anti-adhesion layer 80, it provides a coating function to prevent illegal advertisements. 10 to 20 parts by weight based on 100 parts by weight of butyl acrylic acid-butyl methacrylic acid-methacrylic acid-methyl methacrylic acid-styrene polymer to suppress the adhesion of the adhesive composed of to the upper surface of the anti-adhesion layer 80. In addition, when the weight is exceeded, the elasticity and coating of the anti-adhesion layer 80 become too large, so that the adhesive of illegal advertisements cannot be firmly attached, but the curing time is long, resulting in reduced manufacturability and strength, If it is less than the weight part, the elasticity and coating degree of the anti-adhesive layer 80 become too small, so that the adhesive of illegal advertisements is firmly attached and the peeling effect of the adhesive of illegal advertisements is reduced. It is desirable to have the same limited weight part.

2-Ethylhexoic acid-benzoic acid-triethylene glycol has a CAS number of 111-90-0, and together with a mixed ester compound of 2-ethylhexoic acid-benzoic acid-triethylene glycol, the anti-adhesion coating agent is an anti-adhesion layer ( 80) is formed to provide a coating function to suppress the adhesion of the adhesive composed of illegal advertisements to the upper surface of the advertisement anti-adhesion layer 80, butyl acrylic acid-butyl methacrylic acid-methacrylic acid-methyl methacrylic acid - 10 to 20 parts by weight is added based on 100 parts by weight of the styrene polymer. If the weight exceeds the above, the elasticity and coating degree of the anti-adhesion layer 80 becomes too large, so that the adhesive of illegal advertisements is not firmly attached. However, the curing time is long and the manufacturability and strength are lowered, and if it is less than the weight part, the elasticity and coating degree of the advertisement anti-adhesion layer 80 become too small, so that the adhesive of illegal advertisements is firmly attached and the illegal advertisements Since there is a problem in that the peeling effect of the adhesive is reduced, it is preferable to have a limited weight part as described above.

PE Wax, CAS number 9002-88-4, provides a coating function when the anti-adhesion coating agent forms the anti-adhesion layer 80 so that heat resistance is provided to the binder layer 30, butyl acrylic acid -Butyl methacrylic acid-methacrylic acid-methyl methacrylic acid-styrene polymer is added in an amount of 15 to 50 parts by weight based on 100 parts by weight. It takes a lot of time to cure, and if it is less than the weight part, the heat resistance provided to the binder layer 30 is lowered, and the ink or print particles of the binder layer 30 are easily worn by heat and discolored easily. , It is preferable to have a limited weight part as described above.

Water, CAS number 7732-18-5, which improves the agitation properties and controls the viscosity of the anti-adhesive coating agent, is butyl acrylic acid-butyl methacrylic acid-methacrylic acid-methyl methacrylic acid-styrene polymer 100 200 to 250 parts by weight is added with respect to parts by weight. If it exceeds the above parts by weight, the curing time during application and coating increases, making it impossible to secure a coating layer of a predetermined thickness. Since there is a problem that the control function is lowered and the workability is lowered, it is preferable to have a limited weight part as described above.

Here, the anti-adhesion layer 80 preferably has a thickness of 0.05 mm to 0.15 mm, and if the thickness is less than the thickness, the visibility and protection are reduced because the thickness is too thin, and if the thickness exceeds the thickness Since the thickness is too thick, the embossed height of the anti-slip layer 40 is lowered, the non-slip function is lowered, and the shape variability of the aluminum thin plate layer 10 is lowered. Preferably, it is recommended to provide optimal visibility and usability through having a thickness of 0.1 mm.

Meanwhile, in the present invention, the aluminum thin plate layer 10 and the TPO layer 20 may be laminated with a composition constituting the TPO layer 20 to the aluminum thin plate layer 10, but more preferably, the TPO layer (20) between the sheet and the aluminum thin plate layer 10 made of the composition forming the composition are bonded by a heat dissipation adhesive layer (not shown) using a heat dissipation adhesive, so that solar heat conducted to the binder layer 30 in summer It is preferable to rapidly dissipate heat to the thin plate layer 10 .

Here, 30 to 40 parts by weight of the heat conductive adhesive is added and mixed with 100 parts by weight of the polymer for the heat dissipation adhesive. The polymer is selected from the group consisting of a silicone resin, an epoxy resin, an acrylic resin, a mixture thereof, and a copolymer thereof. The filler for heat conduction includes a first filler having a first average particle diameter, a second filler having a second average particle diameter, and a third filler having a third average particle diameter, and the first average particle diameter is 10 to 30 μm, and the remaining average greater than the particle diameter values, the value obtained by dividing the second average particle diameter by the first average particle diameter is 0.17 to 0.26, the value obtained by dividing the third average particle diameter by the first average particle diameter is 0.09 to 0.11, and the first filler , The volume resistivity of the second filler and the third filler is 104 Ωcm or more, the first filler, the second filler, and the third filler have an average value of the minor axis / major axis of 0.6 to 0.8, and the sum of the masses of the second filler / the first filler The percentage of the sum of the filler masses is 11 to 16, or the percentage of the sum of the masses of the third filler/sum of the mass of the first filler is 4.2 to 5.2, and the first filler, the second filler, and the third filler are alumina (Al2O3), boron nitride (BN), aluminum nitride (AlN), silicon nitride (Si3N4), magnesia (MgO), beryllia (BeO), zinc oxide (ZnO), silicon carbide (SiC), zirconia (ZrO2), and mixtures thereof. do.

On the other hand, the heat dissipation adhesive contains 100 parts by mass of at least one polymer, 1.5 parts by mass or less of expanded graphite powder, and a viscosity of 3000 mPa/s or more at 25°C and a temperature of 15°C or more and 100°C or less under atmospheric pressure. 10 parts by mass or more and 15 parts by mass or less of a liquid phosphate ester in the area, 50 parts by mass or more and 90 parts by mass or less of alumina having a BET specific surface area of 1 m 2 / g or more, expanded graphite powder, and a flame retardant heat conductive inorganic compound excluding the alumina 100 It may also contain 150 parts by mass or more by mass.

Therefore, according to the heat dissipation bonding layer (not shown), while bonding between the TPO layer 20 and the aluminum thin plate layer 10, the heat radiated from the binder layer 30 to the TPO layer 20 in summer is transferred to the aluminum thin plate layer ( 10), it is possible to minimize the expansion of the binder layer 30 by solar heat.

In addition, according to the heat dissipating adhesive layer (not shown), the heat transmitted to the aluminum thin plate layer 10 from the road surface or adherend in winter is quickly transferred to the TPO layer 20 or the binder layer 30, thereby forming the binder layer 30 Shrinkage at this low temperature can be suppressed as much as possible.

On the other hand, the heat dissipating adhesive layer (not shown) preferably has a thickness of 0.06 mm to 0.08 mm, and when the thickness is less than the thickness, the absorption rate of absorbing heat of the binder layer 30 is reduced because the thickness is too thin. If the thickness is exceeded, the thickness is too thick, so there is a problem that the thermal diffusivity to the aluminum thin plate layer 10 is lowered. , it is good to provide optimal heat dissipation.

On the other hand, according to a preferred embodiment of the present invention, the TPO layer 20 is formed on the upper surface of the aluminum thin plate layer 10 to improve the durability of the aluminum thin plate layer 10, but according to a modified example of the present invention, As shown in FIG. 2, a fabric layer 90 such as a nonwoven fabric is further formed on the lower surface of the aluminum thin plate layer 10, and at this time, the fabric layer 90 is impregnated with the heat insulating adhesive layer 50. The fabric layer 90 may serve the same function as a double-sided tape.

Here, the fabric layer 90 preferably has a thickness equal to that of the heat insulating adhesive layer 50 .

Therefore, according to the fabric layer 90, when the aluminum thin plate layer 10 is attached to a road surface or an adherend, a buffering function is provided through a predetermined thickness, thereby improving durability of the aluminum thin plate layer 10.

Hereinafter, the action and effect of the aluminum non-slip luminescent and cover sheet for evacuation guidance according to an embodiment of the present invention will be described through specific examples.

The aluminum thin plate layer 10, which has a shape corresponding to the road surface or adherends of various materials and is deformed to provide a heat shield function, is composed of the upper surface of the aluminum thin plate layer 10 to prevent rupture or breakage of the aluminum thin plate layer 10. It consists of a TPO layer 20 that suppresses, a binder layer 30 that is formed on the upper surface of the TPO layer 20 and provides a corresponding cover function by enabling printing or printing of characters or designs, and a binder layer 30 The non-slip layer 40, which provides an anti-slip function, is composed of the lower surface of the aluminum thin plate layer 10 so that the aluminum thin plate layer 10 is attached to the road surface or adherend and insulates heat transmitted from the road surface or adherend The heat insulating adhesive layer 50 is formed on the lower surface of the heat insulating adhesive layer 50 to protect the heat insulating adhesive layer 50 and is formed in the blank space of the liner layer 60 selectively peeled off and the binder layer 30 to absorb light from the outside. It is formed on the upper surface of the phosphorescent layer 70 that accumulates and emits light to improve visibility and the binder layer 30 including the phosphorescent layer 70, so that the phosphorescent layer 70 and the binder layer 30 have high hardness and high density glass. Advertising composed of a ceramic layer that provides a film to suppress stains and discoloration of the phosphorescent layer 70 and the binder layer 30, maintains the color and texture of the printed content for a long time, and suppresses the adhesion of illegal advertisements by suppressing the adhesion of adhesives An aluminum non-slip luminescent and cover sheet for evacuation guidance including an anti-water adhesion layer 80 is manufactured.

Here, it is preferable that an ink layer or a print layer is formed between the binder layer 30 and the non-slip layer 40 so as to provide a corresponding cover function.

In addition, the ceramic layer is formed by applying and coating an anti-adhesion coating agent, and the anti-adherence coating agent contains 45% by weight of isopropyl alcohol, 40% by weight of methyltrimethyloxysilane, and 2% by weight of trimethoxysilane. %, 1% by weight of 1-butanol titanium salt and 1% by weight of dimethylpolysiloxane are added and mixed.

The aluminum thin plate layer 10, which has a shape corresponding to the road surface or adherends of various materials and is deformed to provide a heat shield function, is composed of the upper surface of the aluminum thin plate layer 10 to prevent rupture or breakage of the aluminum thin plate layer 10. It consists of a TPO layer 20 that suppresses, a binder layer 30 that is formed on the upper surface of the TPO layer 20 and provides a corresponding cover function by enabling printing or printing of characters or designs, and a binder layer 30 The non-slip layer 40, which provides an anti-slip function, is composed of the lower surface of the aluminum thin plate layer 10 so that the aluminum thin plate layer 10 is attached to the road surface or adherend and insulates heat transmitted from the road surface or adherend The heat insulating adhesive layer 50 is formed on the lower surface of the heat insulating adhesive layer 50 to protect the heat insulating adhesive layer 50 and is formed in the blank space of the liner layer 60 selectively peeled off and the binder layer 30 to absorb light from the outside. It is formed on the upper surface of the phosphorescent layer 70 that accumulates and emits light to improve visibility and the binder layer 30 including the phosphorescent layer 70, so that the phosphorescent layer 70 and the binder layer 30 have high hardness and high density glass. Advertising composed of a ceramic layer that provides a film to suppress stains and discoloration of the phosphorescent layer 70 and the binder layer 30, maintains the color and texture of the printed content for a long time, and suppresses the adhesion of illegal advertisements by suppressing the adhesion of adhesives An aluminum non-slip luminescent and cover sheet for evacuation guidance including an anti-water adhesion layer 80 is manufactured.

Here, it is preferable that an ink layer or a print layer is formed between the binder layer 30 and the non-slip layer 40 so as to provide a corresponding cover function.

In addition, the ceramic layer is formed by applying and coating an anti-adhesion coating agent, and the anti-adherence coating agent contains 47% by weight of isopropyl alcohol, 45% by weight of methyltrimethyloxysilane, and 5% by weight of trimethoxysilane. %, 2% by weight of 1-butanol titanium salt and 1% by weight of dimethylpolysiloxane are added and mixed.

The aluminum thin plate layer 10, which has a shape corresponding to the road surface or adherends of various materials and is deformed to provide a heat shield function, is composed of the upper surface of the aluminum thin plate layer 10 to prevent rupture or breakage of the aluminum thin plate layer 10. It consists of a TPO layer 20 that suppresses, a binder layer 30 that is formed on the upper surface of the TPO layer 20 and provides a corresponding cover function by enabling printing or printing of characters or designs, and a binder layer 30 The non-slip layer 40, which provides an anti-slip function, is composed of the lower surface of the aluminum thin plate layer 10 so that the aluminum thin plate layer 10 is attached to the road surface or adherend and insulates heat transmitted from the road surface or adherend The heat insulating adhesive layer 50 is formed on the lower surface of the heat insulating adhesive layer 50 to protect the heat insulating adhesive layer 50 and is formed in the blank space of the liner layer 60 selectively peeled off and the binder layer 30 to absorb light from the outside. It is formed on the upper surface of the phosphorescent layer 70 that accumulates and emits light to improve visibility and the binder layer 30 including the phosphorescent layer 70, so that the phosphorescent layer 70 and the binder layer 30 have high hardness and high density glass. Advertising composed of a ceramic layer that provides a film to suppress stains and discoloration of the phosphorescent layer 70 and the binder layer 30, maintains the color and texture of the printed content for a long time, and suppresses the adhesion of illegal advertisements by suppressing the adhesion of adhesives An aluminum non-slip luminescent and cover sheet for evacuation guidance including an anti-water adhesion layer 80 is manufactured.

Here, it is preferable that an ink layer or a print layer is formed between the binder layer 30 and the non-slip layer 40 so as to provide a corresponding cover function.

In addition, the ceramic layer is formed by applying and coating an anti-adhesion coating agent, and the anti-adherence coating agent contains 50% by weight of isopropyl alcohol, 50% by weight of methyltrimethyloxysilane, and 10% by weight of trimethoxysilane. %, 5% by weight of 1-butanol titanium salt and 5% by weight of dimethylpolysiloxane are added and mixed.

The aluminum thin plate layer 10, which has a shape corresponding to the road surface or adherends of various materials and is deformed to provide a heat shield function, is composed of the upper surface of the aluminum thin plate layer 10 to prevent rupture or breakage of the aluminum thin plate layer 10. It consists of a TPO layer 20 that suppresses, a binder layer 30 that is formed on the upper surface of the TPO layer 20 and provides a corresponding cover function by enabling printing or printing of characters or designs, and a binder layer 30 The non-slip layer 40, which provides an anti-slip function, is composed of the lower surface of the aluminum thin plate layer 10 so that the aluminum thin plate layer 10 is attached to the road surface or adherend and insulates heat transmitted from the road surface or adherend The heat insulating adhesive layer 50 is formed on the lower surface of the heat insulating adhesive layer 50 to protect the heat insulating adhesive layer 50 and is formed in the blank space of the liner layer 60 selectively peeled off and the binder layer 30 to absorb light from the outside. It is formed on the upper surface of the phosphorescent layer 70 that accumulates and emits light to improve visibility and the binder layer 30 including the phosphorescent layer 70, so that the phosphorescent layer 70 and the binder layer 30 have high hardness and high density glass. Advertising composed of an acrylic layer that provides a film to suppress stains and discoloration of the phosphorescent layer 70 and the binder layer 30, maintains the color and texture of the printed content for a long time, and suppresses the adhesion of illegal advertisements by suppressing the adhesion of adhesives An aluminum non-slip luminescent and cover sheet for evacuation guidance including an anti-water adhesion layer 80 is manufactured.

Here, it is preferable that an ink layer or a print layer is formed between the binder layer 30 and the non-slip layer 40 so as to provide a corresponding cover function.

In addition, the acrylic layer is formed by applying and coating an anti-adhesion coating agent, and the anti-adhesion coating agent is butyl acrylic acid-butyl methacrylic acid-methacrylic acid-methyl methacrylic acid-styrene polymer 100 parts by weight, 0.5 parts by weight of zinc oxide, 8 parts by weight of a mixed ester compound of 2-ethylhexoic acid-benzoic acid-triethylene glycol, 8 parts by weight of diethylene glycol monoedyl ether, 10 parts by weight of PE Wax and 100 parts by weight of water It has a configuration that is added and mixed.

The aluminum thin plate layer 10, which has a shape corresponding to the road surface or adherends of various materials and is deformed to provide a heat shield function, is composed of the upper surface of the aluminum thin plate layer 10 to prevent rupture or breakage of the aluminum thin plate layer 10. It consists of a TPO layer 20 that suppresses, a binder layer 30 that is formed on the upper surface of the TPO layer 20 and provides a corresponding cover function by enabling printing or printing of characters or designs, and a binder layer 30 The non-slip layer 40, which provides an anti-slip function, is composed of the lower surface of the aluminum thin plate layer 10 so that the aluminum thin plate layer 10 is attached to the road surface or adherend and insulates heat transmitted from the road surface or adherend The heat insulating adhesive layer 50 is formed on the lower surface of the heat insulating adhesive layer 50 to protect the heat insulating adhesive layer 50 and is formed in the blank space of the liner layer 60 selectively peeled off and the binder layer 30 to absorb light from the outside. It is formed on the upper surface of the phosphorescent layer 70 that accumulates and emits light to improve visibility and the binder layer 30 including the phosphorescent layer 70, so that the phosphorescent layer 70 and the binder layer 30 have high hardness and high density glass. Advertising composed of an acrylic layer that provides a film to suppress stains and discoloration of the phosphorescent layer 70 and the binder layer 30, maintains the color and texture of the printed content for a long time, and suppresses the adhesion of illegal advertisements by suppressing the adhesion of adhesives An aluminum non-slip luminescent and cover sheet for evacuation guidance including an anti-water adhesion layer 80 is manufactured.

Here, it is preferable that an ink layer or a print layer is formed between the binder layer 30 and the non-slip layer 40 so as to provide a corresponding cover function.

In addition, the acrylic layer is formed by applying and coating an anti-adhesion coating agent, and the anti-adhesion coating agent is butyl acrylic acid-butyl methacrylic acid-methacrylic acid-methyl methacrylic acid-styrene polymer 100 parts by weight, 3 parts by weight of zinc oxide, 15 parts by weight of a mixed ester compound of 2-ethylhexoic acid-benzoic acid-triethylene glycol, 15 parts by weight of diethylene glycol monoedyl ether, 30 parts by weight of PE Wax and 200 parts by weight of water It has a configuration that is added and mixed.

The aluminum thin plate layer 10, which has a shape corresponding to the road surface or adherends of various materials and is deformed to provide a heat shield function, is composed of the upper surface of the aluminum thin plate layer 10 to prevent rupture or breakage of the aluminum thin plate layer 10. It consists of a TPO layer 20 that suppresses, a binder layer 30 that is formed on the upper surface of the TPO layer 20 and provides a corresponding cover function by enabling printing or printing of characters or designs, and a binder layer 30 The non-slip layer 40, which provides an anti-slip function, is composed of the lower surface of the aluminum thin plate layer 10 so that the aluminum thin plate layer 10 is attached to the road surface or adherend and insulates heat transmitted from the road surface or adherend The heat insulating adhesive layer 50 is formed on the lower surface of the heat insulating adhesive layer 50 to protect the heat insulating adhesive layer 50 and is formed in the blank space of the liner layer 60 selectively peeled off and the binder layer 30 to absorb light from the outside. It is formed on the upper surface of the phosphorescent layer 70 that accumulates and emits light to improve visibility and the binder layer 30 including the phosphorescent layer 70, so that the phosphorescent layer 70 and the binder layer 30 have high hardness and high density glass. Advertising composed of an acrylic layer that provides a film to suppress stains and discoloration of the phosphorescent layer 70 and the binder layer 30, maintains the color and texture of the printed content for a long time, and suppresses the adhesion of illegal advertisements by suppressing the adhesion of adhesives An aluminum non-slip luminescent and cover sheet for evacuation guidance including an anti-water adhesion layer 80 is manufactured.

Here, it is preferable that an ink layer or a print layer is formed between the binder layer 30 and the non-slip layer 40 so as to provide a corresponding cover function.

In addition, the acrylic layer is formed by applying and coating an anti-adhesion coating agent, and the anti-adhesion coating agent is butyl acrylic acid-butyl methacrylic acid-methacrylic acid-methyl methacrylic acid-styrene polymer 100 parts by weight, 10 parts by weight of zinc oxide, 25 parts by weight of a mixed ester compound of 2-ethylhexoic acid-benzoic acid-triethylene glycol, 25 parts by weight of diethylene glycol monoedyl ether, 60 parts by weight of PE Wax and 260 parts by weight of water It has a configuration that is added and mixed.

As a reference or evaluation example of the aluminum non-slip luminescent and evacuation guidance cover sheet manufactured according to Examples 1 to 6, it is a conventional luminescence and evacuation guidance cover sheet sold by company A.

Subsequently, physical properties such as adhesive strength, tensile strength, insulation resistance, and acid resistance of the cover sheet according to the above embodiments were measured, and after being attached to the same road surface or adherend of the same material, the effect of preventing the attachment of illegal advertisements was evaluated. and shown in Table 1.

Therefore, according to the cover sheet for aluminum non-slip photoluminescence and evacuation guidance according to a preferred embodiment of the present invention, as shown in Table 1 above, compared to the prototype flex sheet, adhesive strength, tensile strength, insulation resistance, acid resistance, etc. It can be seen that the properties and the effect of preventing attachment of illegal advertisements are excellent.

On the other hand, after attaching the aluminum non-slip luminescent and evacuation guidance cover sheets of Examples 1 to 7 on an asphalt crosswalk in summer when the air temperature is 30 ° C and the asphalt temperature is 90 ° C from 9:00 am to 4:00 pm, Z- The peel force (based on ASTM D 952-93), the surface temperature of the cover sheet, the surface temperature of the aluminum thin layer, the elongation length of the cover sheet and the contraction length of the cover sheet were measured, and also the cover sheet of Examples 1 to 7 was attached to an asphalt crosswalk in winter when the air temperature was -10℃ and the asphalt temperature was -25℃ from 9:00 am to 4:00 pm, and then Z-peeling force (based on ASTM D 952-93), surface temperature of the cover sheet , As a result of measuring the surface temperature of the aluminum thin plate layer, the elongation length of the cover sheet and the shrinkage length of the cover sheet, compared to the product of Example 7, which is an evaluation example, in the case of Examples 2 and 5, the elongation and It can be seen that the shrinkage properties are very good. That is, even if it is attached to a road surface such as asphalt having a high temperature change in summer and winter, it is possible to maintain a high adhesion rate without having a significant effect on the temperature of the adhered surface, so that durability can be improved.

Therefore, according to the above, as the TPO layer 20 is formed on the aluminum thin plate layer 10, the possibility of breakage during attachment or breakage during use of the aluminum thin plate layer 10 is suppressed, and usability can be greatly improved.

In addition, since the heat insulating adhesive layer 50 is formed on the lower surface of the aluminum thin plate layer 20, heat from the binder layer 30 is radiated to the aluminum thin plate layer 10 having a relatively low temperature in summer, and heat from the road surface It suppresses transfer to the binder layer 30, and in winter, the heat of the aluminum thin plate layer 10 having a predetermined temperature conducted from the road surface is transferred to the binder layer 30 having a relatively low temperature, etc., and the cover sheet It is possible to minimize thermal deformation of and improve durability.

In addition, the upper surface of the binder layer 30 is coated with an anti-adhesion layer 80 providing a high-hardness and high-density glass film to prevent attachment of illegal advertisements.

Although the preferred embodiments of the present invention have been described with reference to the accompanying drawings, those skilled in the art can make various substitutions and modifications within the scope of not departing from the technical spirit or essential characteristics of the present invention. And it will be appreciated that variations are possible and thus may be embodied in other specific forms. Therefore, the embodiments described above should be understood as illustrative in all respects and not limiting.

Claims (5)

An aluminum thin plate layer 10 having a shape corresponding to the adhered surface and providing a heat shielding function by being deformed; A TPO layer 20 configured on the upper surface of the aluminum thin plate layer 10 to suppress rupture or breakage of the aluminum thin plate layer 10; A binder layer 30 configured on the upper surface of the TPO layer 20 and enabling printing or printing to provide a corresponding cover function; An anti-slip layer 40 configured on the binder layer 30 to provide an anti-slip function; A heat insulating adhesive layer 50 configured on the lower surface of the aluminum thin plate layer 10 so that the aluminum thin plate layer 10 is attached to the adhered surface and insulates heat transmitted from the adhered surface; It is formed on the lower surface of the heat insulating adhesive layer 50 to protect the heat insulating adhesive layer 50 and is formed in the blank space of the selectively peeled liner layer 60 and the binder layer 30 to accumulate and emit light absorbed from the outside to improve visibility. a photoluminescent layer 70 that enhances; And it is configured on the upper surface of the binder layer 30 including the photoluminescent layer 70 to provide a glassy film of high hardness and high density to the photoluminescent layer 70 and the binder layer 30, thereby forming the photoluminescent layer 70 and the binder layer 30. An anti-advertising layer 80 composed of a ceramic layer that suppresses staining and discoloration, maintains the color and texture of the printed contents for a long time, and inhibits the adhesion of adhesive to suppress the attachment of illegal advertisements,
The ceramic layer,
Aluminum non-slip luminous and evacuation guidance sign characterized by being a one-component anti-adhesion coating agent in which isopropyl alcohol, methyltrimethyloxysilane, trimethoxysilane, 1-butanol titanium salt and dimethylpolysiloxane are added and mixed Sheet. delete The method of claim 1, wherein the one-component anti-adhesion coating agent,
Aluminum characterized in that 47% by weight of isopropyl alcohol, 45% by weight of methyltrimethyloxysilane, 5% by weight of trimethoxysilane, 2% by weight of 1-butanol titanate and 1% by weight of dimethylpolysiloxane are added and mixed Cover sheet for non-slip phosphorescent light and evacuation guidance. An aluminum thin plate layer 10 having a shape corresponding to the adhered surface and providing a heat shielding function by being deformed; A TPO layer 20 configured on the upper surface of the aluminum thin plate layer 10 to suppress rupture or breakage of the aluminum thin plate layer 10; A binder layer 30 configured on the upper surface of the TPO layer 20 and enabling printing or printing to provide a corresponding cover function; An anti-slip layer 40 configured on the binder layer 30 to provide an anti-slip function; A heat insulating adhesive layer 50 configured on the lower surface of the aluminum thin plate layer 10 so that the aluminum thin plate layer 10 is attached to the adhered surface and insulates heat transmitted from the adhered surface; It is formed on the lower surface of the heat insulating adhesive layer 50 to protect the heat insulating adhesive layer 50 and is formed in the blank space of the selectively peeled liner layer 60 and the binder layer 30 to accumulate and emit light absorbed from the outside to improve visibility. a photoluminescent layer 70 that enhances; And it is configured on the upper surface of the binder layer 30 including the photoluminescent layer 70 to provide a glassy film of high hardness and high density to the photoluminescent layer 70 and the binder layer 30, thereby forming the photoluminescent layer 70 and the binder layer 30. An anti-adhesion layer 80 composed of an acrylic layer that suppresses staining and discoloration, maintains the color and texture of printed contents for a long time, and suppresses the adhesion of adhesive to suppress the attachment of illegal advertisements,
The acrylic layer,
Butyl acrylic acid-butyl methacrylic acid-methacrylic acid-methyl methacrylic acid-styrene polymer, zinc oxide, mixed ester compound of 2-ethylhexoic acid-benzoic acid-triethylene glycol, diethylene glycol monoedyl ether, PE An aluminum non-slip luminous and cover sheet for evacuation guidance, characterized in that it is a one-component anti-adhesive coating agent in which wax and water are added and mixed. The method of claim 4, wherein the one-component anti-adhesion coating agent,
Butyl acrylic acid-butyl methacrylic acid-methacrylic acid-methyl methacrylic acid-styrene polymer 100 parts by weight, zinc oxide 1 to 3 parts by weight, 2-ethylhexoic acid-benzoic acid-triethylene glycol mixed ester compound 10 to 20 10 to 20 parts by weight of diethylene glycol monoedyl adder, 15 to 50 parts by weight of PE Wax, and 200 to 250 parts by weight of water are added and mixed.

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