KR102480819B1 - Hair styling wax composition and manufacturing method for the same - Google Patents

Abstract

The present invention is polyvinylpyrrolidone 4% to 7% by weight; 20% to 40% by weight of an aqueous solvent; 33% to 60% by weight of a solid wax including microcrystalline wax, ozokerite, beeswax and candelilla wax; 7% to 11% by weight of a solid formulation aid; 5% to 10% by weight of oil; and 1% to 20% by weight of additives; It relates to a hair styling wax composition comprising a and a method for preparing the same. Accordingly, the present invention provides a hair styling wax composition having excellent setting power, spreadability and washability, preventing white cast, and having excellent fixing power for curly hair, and a method for preparing the same.

Description

Hair styling wax composition and manufacturing method thereof {HAIR STYLING WAX COMPOSITION AND MANUFACTURING METHOD FOR THE SAME}

The present invention relates to hair styling wax compositions and methods of making the same.

In general, hair styling means giving outward characteristics to the shape of hair in order to enhance aesthetic effect. As such, as one of the methods for styling hair, a method using a hair styling agent is widely used.

A hair styling agent is a physical setting method that is applied to the hair surface to fix the hair in a desired shape. Representative examples of such hair styling agents include hair foam, hair mousse, hair spray, hair oil, hair gel, and hair wax.

Among these hair styling agents, hair wax is a styling agent having a creamy or solid formulation that requires high fixing power, and has a high effect of fixing a desired shape while giving appropriate shine to hair. Hair styling waxes are used in a variety of textures and formulations depending on the length and quality of hair. In general, heavy texture products are used for short and weak hair, creamy texture products with excellent spreadability for medium or long hair, and high adhesive texture products for stiff hair.

In the prior art, hair styling waxes use a lot of oily components to have high fixing power and excellent hair styling function. However, in the case of hair wax containing a high content of oily components, spreadability is very low due to its high viscosity when applied to hair. In this case, there is a disadvantage in that uniform coating on the hair is difficult, and the hair looks greasy and does not wash well during washing, so it may look unclean.

In addition, when excessively using raw materials of wax components to increase hair set hold, the hardness is excessively increased, and the solidified oily component is broken to generate white powder, which may cause white cast. Since this can make the hair look worse, it is very important to prevent white cast in hair styling wax products.

Therefore, there is a growing need to develop a hair styling wax composition that has excellent setting power, spreadability, and washability, and can prevent white cast while also having excellent fixing power for characteristic hair such as curly hair.

One object of the present invention is to provide a hair styling wax composition having excellent setting power, spreadability and washability, preventing cloudiness, and having excellent fixing power to curly hair, and a method for producing the same.

One embodiment of the present invention is 4% to 7% by weight of polyvinylpyrrolidone; 20% to 40% by weight of an aqueous solvent; 33% to 60% by weight of a solid wax including microcrystalline wax, ozokerite, beeswax and candelilla wax; 7% to 11% by weight of a solid formulation aid; 5% to 10% by weight of oil; and 1% to 20% by weight of additives; It relates to a hair styling wax composition comprising a.

Of the solid wax, 30% to 50% by weight of microcrystalline wax, 20% to 30% by weight of ozokerite, 10% to 20% by weight of beeswax, and 10% to 20% by weight of candelilla wax can be included as

The solid formulation auxiliary may include at least one of a saturated fatty acid compound having 10 to 50 carbon atoms, a fatty acid alcohol compound having 10 to 50 carbon atoms, and a fatty acid ester compound having 10 to 50 carbon atoms.

The oil may include at least one of vegetable oil, mineral oil, petrolatum, synthetic oil, unsaturated fatty acids having 1 to 30 carbon atoms, and liquid fatty acid derivatives.

The additive may include one or more of hair nutrients, surfactants, emulsifiers, preservatives, and fragrances.

Another embodiment of the present invention is to add a second solution obtained by melting and mixing solid wax, solid formulation auxiliary and additives to a first solution in which polyvinylpyrrolidone is dissolved in an aqueous solvent, and It relates to the above-described hair styling wax composition manufacturing method comprising the step of preparing wax composition particles by pulverizing the mixture at a high speed at a solidifying temperature.

The solidification temperature may be 50 °C to 60 °C.

After preparing the wax composition particles, a step of homogenizing by dissolving the wax composition particles at a melting temperature and then performing cooling may be further performed.

The present invention provides a hair styling wax composition having excellent setting power, spreadability, and washability, preventing cloudiness, and having excellent fixing power for curly hair, and a method for preparing the same.

One embodiment of the present invention is 4% to 7% by weight of polyvinylpyrrolidone; 20% to 40% by weight of an aqueous solvent; 33% to 60% by weight of a solid wax including microcrystalline wax, ozokerite, beeswax and candelilla wax; 7% to 11% by weight of a solid formulation aid; 5% to 10% by weight of oil; and 1% to 20% by weight of additives; It relates to a hair styling wax composition comprising a.

Accordingly, the present invention provides a hair styling wax composition that is excellent in setting power, spreadability and washability, can prevent white cast, and has excellent fixation power for curly hair.

In particular, the hair styling wax composition of the present invention is dried and solidified in a short time by controlling the contents of solid components including solid wax and solid formulation auxiliary, oil and moisture within the above ranges, thereby providing excellent setting and fixing power for curly hair ( Curly relief) and at the same time, the effect of preventing white cast is excellent.

The polyvinylpyrrolidone is a polymer resin usable for hair, and is applied to the hair surface with excellent spreadability during hair styling, and then forms a film film with moisture drying to fix the hair in a desired shape. In this case, the hair styling wax composition implements excellent setting power that changes the hair shape to a desired shape by the user during hair styling, and at the same time implements excellent fixing power that can be quickly dried and fixed in a set state.

When the content of polyvinylpyrrolidone in the hair styling wax composition exceeds 7% by weight, it is difficult to prevent the whitening phenomenon of the hair styling wax, the styling ability to realize the desired hair shape is reduced, and the hair styling during styling after application Restyling that changes the shape of the is difficult. In addition, when the content of polyvinylpyrrolidone is less than 4% by weight, it is difficult to maintain the shape of the hair for a long time or to increase the fixation force.

The aqueous solvent is not particularly limited as long as it can be used in the hair styling wax composition. For example, when water such as purified water is used as an aqueous solvent, the moisture content of the wax composition is increased, and the spreadability to hair can be improved by preventing the formulation from being excessively solidified.

When the content of the aqueous solvent in the hair styling wax composition is less than 20% by weight, fluidity suitable for hair styling wax products cannot be realized. On the contrary, if it exceeds 40% by weight, the drying time after styling is excessively increased, and the setting power and fixing power to the hair are lowered.

In one embodiment, the polyvinylpyrrolidone may be used in an aqueous solution dissolved in the aqueous solvent. In addition, the polyvinylpyrrolidone aqueous solution may further include a water-soluble additive within the content range of the additives described later. In this case, miscibility with the solid wax, solid formulation auxiliary and oil described later can be further improved.

After the solid wax is applied to the hair surface during hair styling, it serves to fix the hair in a desired shape by forming a film film along with drying of moisture. In addition, the solid wax includes a mixture of microcrystalline wax, ozokerite, beeswax, and candelilla wax, thereby improving miscibility with solid formulation aids, oil, and moisture while preventing formulation separation, Fixing power to hair can be further improved.

If the content of the solid wax in the hair styling wax composition is less than 33% by weight, the setting and fixing power for hair is lowered, and in particular, it is difficult to implement the setting and fixing power for hair having strong restoring properties such as curly. On the contrary, if it exceeds 60% by weight, it is difficult to prevent the whitening phenomenon of the hair styling wax, the styling ability to realize the desired hair shape and the setting power are lowered, and it is difficult to re-styling to change the shape of the hair during styling after application.

The microcrystalline wax is an amorphous wax that can be used for hair, and is attached to the surface of the hair during hair styling to give the hair flexibility to realize a natural shape according to the user's movement, and to achieve excellent fluidity, spreadability and fixation.

In one embodiment, the microcrystalline wax may be included in 30% to 50% by weight of the solid wax. Within the above range, the hair styling wax composition can implement excellent setting power, fixing power, and spreadability in a more balanced way.

In another embodiment, the microcrystalline wax may be included in 15% to 25% by weight of the total hair styling wax composition. Within the above range, the hair styling wax composition can implement excellent setting power, fixing power, and spreadability in a more balanced way.

The ozokerite is a mineral wax usable for hair, and improves the miscibility of components included in the hair styling wax composition, and has excellent bonding, emulsifying, and thickening properties, thereby realizing high fluidity, spreadability, and fixation.

In one embodiment, the ozokerite may be included in 20% to 30% by weight of the solid wax. Within the above range, the hair styling wax composition can implement excellent setting power, fixing power, and spreadability in a more balanced way.

In another embodiment, the ozokerite may be included in 9% to 15% by weight of the total hair styling wax composition. Within the above range, the hair styling wax composition can implement excellent setting power, fixing power, and spreadability in a more balanced way.

The beads wax is an amorphous wax that can be used for hair, and is attached to the surface of the hair during hair styling to give the hair flexibility to realize a natural shape according to the user's movement, and implements excellent fluidity, spreadability and fixation.

In one embodiment, the beeswax may be included in 10% to 20% by weight of the solid wax. Within the above range, the hair styling wax composition can implement excellent setting power, fixing power, and spreadability in a more balanced way.

In another embodiment, the beeswax may be included in 5% to 10% by weight of the total hair styling wax composition. Within the above range, the hair styling wax composition can implement excellent setting power, fixing power, and spreadability in a well-balanced manner.

The candelilla wax is an amorphous wax that can be used for hair, and is attached to the surface of the hair during hair styling to give the hair flexibility to realize a natural shape according to the user's movement, and to realize excellent fluidity, spreadability and fixing power.

In one embodiment, the candelilla wax may be included in 10% to 20% by weight of the solid wax. Within the above range, the hair styling wax composition can implement excellent setting power, fixing power, and spreadability in a more balanced way.

In another embodiment, the candelilla wax may be included in an amount of 4% to 10% by weight of the total hair styling wax composition. Within the above range, the hair styling wax composition can implement excellent setting power, fixing power, and spreadability in a well-balanced manner.

The solid formulation adjuvant acts in combination with the solid wax to further increase the setting power of the hair styling wax composition, while further improving quick-drying and fixing power. In addition, the solid formulation adjuvant allows the solid wax to achieve excellent miscibility with liquid oil and aqueous solvents, while achieving both styling properties and fixing power of the entire hair styling wax composition, and preventing cloudiness.

Specifically, the solid formulation auxiliary may include at least one solid material selected from among a saturated fatty acid compound having 10 to 50 carbon atoms, a fatty acid alcohol compound having 10 to 50 carbon atoms, and a fatty acid ester compound having 10 to 50 carbon atoms. In addition, solid formulation adjuvants are used except for liquid formulation adjuvants in the above examples. In this case, the hair styling wax composition can implement excellent setting power, fixing power, and spreadability in a more balanced manner.

The saturated fatty acid compound having 10 to 50 carbon atoms is more specifically a saturated fatty acid having 10 to 30 carbon atoms, for example, capric acid, undecylic acid, lauric acid, tridecylic acid, myristic acid, pentadecylic acid, palmitic acid acid, margaric acid, stearic acid, nonadecylic acid, arachidic acid, heneicosylic acid, behenic acid, trichosylic acid, lignoceric acid, pentacosylic acid, cerotic acid, heptacosylic acid, montanic acid, nonaco Silic acid, melissic acid, and solid-state isomers thereof may be used, but are not limited thereto. 1 type of these components can be used individually or in mixture of 2 or more types.

The fatty alcohol compound having 10 to 50 carbon atoms is more specifically a fatty alcohol having 10 to 30 carbon atoms, for example, lauryl alcohol, myristyl alcohol, cetyl alcohol, hexadecyl alcohol, stearyl alcohol, nonadecyl alcohol, arachidyl alcohol, heneicosyl alcohol, behil alcohol, tricosyl alcohol, lignoceryl alcohol, pentacosyl alcohol, ceretyl alcohol, heptacosyl alcohol, montyl alcohol, nonacosyl alcohol, melissyl alcohol and These solid-state isomers and the like can be used, but are not limited thereto. 1 type of these components can be used individually or in mixture of 2 or more types.

The fatty acid ester having 10 to 50 carbon atoms is more specifically a fatty acid alkyl ester having 10 to 40 carbon atoms; fatty acid glyceryl esters having 10 to 40 carbon atoms; and esters of alcohols having 10 to 20 carbon atoms and fatty acids having 10 to 30 carbon atoms.

The fatty acid alkyl ester having 10 to 40 carbon atoms is, for example, caprate, undecylate, laurate, tridecylate, myristate, pentadecylate, palmitate, margarate substituted with an alkyl group having 1 to 10 carbon atoms. , Stearate, Nonadesylate, Arachidate, Heneicosylate, Behenate, Tricosylate, Lignocerate, Pentacosylate, Serotate, Heptacosylate, Montanate, Nonacosylate, Melisylate and solid-state isomers thereof, etc. may be used, but are not limited thereto. 1 type of these components can be used individually or in mixture of 2 or more types.

The fatty acid glyceryl ester having 10 to 40 carbon atoms is, for example, glyceryl caprate, glyceryl undecylate, glyceryl laurate, glyceryl tridecylate, glyceryl myristate, glyceryl pentadecylate, glyceryl Palmitate, Glyceryl Margarate, Glyceryl Stearate, Glyceryl Nonadesylate, Glyceryl Arachidate, Glyceryl Heneicosylate, Behenate, Tricosylate, Lignocerate, Pentacosylate, Serotate, Heptacosylates, montanates, nonacosylates, melisylates, and solid-state isomers thereof may be used, but are not limited thereto. 1 type of these components can be used individually or in mixture of 2 or more types.

Esters of the alcohol having 10 to 20 carbon atoms and saturated fatty acids having 10 to 30 carbon atoms are, for example, PEG-100 stearate, PEG-150 distearate, PEG-150 pentaerythrityl tetrastearate, steareth -21, Ceteareth-3, Ceteareth-15, Ceteareth-20, Ceteareth-25, Ceteth-12, Stearic Acid, Ceteth-3, Ceteth-12, Ceteth-20, Ceteth-30 , Ceteth-50 and mixtures thereof, and the like can be used. In this case, the hair styling wax composition can implement excellent setting power, fixing power, and spreadability in a more balanced manner.

When the content of the solid formulation adjuvant in the hair styling wax composition is less than 7% by weight, it is difficult to improve miscibility with aqueous solvents and oils, and styling properties are deteriorated. When the content of the solid formulation adjuvant in the hair styling wax composition is more than 11% by weight, it is difficult to prevent cloudiness, and the formulation is excessively solidified, so that fluidity suitable for a wax product for hair styling cannot be realized.

In addition, the sum of the contents of the solid wax and the solid formulation adjuvant in the hair styling wax composition may be 40% to 71% by weight, specifically 45% to 60% by weight, and more specifically 45% to 50% by weight. there is. When the total content of the solid wax and the solid formulation adjuvant is less than 40% by weight, setting and fixing power to hair is reduced, and it is difficult to implement setting and fixing power to curly hair in particular. On the contrary, if it exceeds 61% by weight, it is difficult to prevent clouding, and the formulation is excessively solidified, so that fluidity suitable for a wax product for hair styling cannot be implemented.

The oil may include at least one of vegetable oil, mineral oil, petrolatum, synthetic oil, unsaturated fatty acids having 1 to 30 carbon atoms, and liquid fatty acid derivatives. In the above examples, oil includes only liquid materials, excluding solid materials. In this case, the hair styling wax composition can implement excellent setting power, fixing power, and spreadability in a more balanced manner. In this case, it is possible to prevent cloudiness and to prevent the formulation from being excessively solidified, thereby implementing excellent flowability, setting power and fixing power to the hair.

The vegetable oil may be, for example, essential oils of various plants, castor oil, safflower oil, cottonseed oil, corn oil, olive oil, almond oil, and liquid oil such as avocado oil, but is not limited thereto. In addition, the type of the plant is not limited and suitable types may be used depending on the purpose. These vegetable oils can be used individually by 1 type or in mixture of 2 or more types.

The mineral oil may be, for example, a mixture of alkanes having 15 to 40 carbon atoms derived from non-vegetable raw materials (minerals).

The synthetic oil may be, for example, hydrocarbon oil and halo-substituted hydrocarbon oil, derivatives, analogues and homologs thereof, etc., but is not limited thereto.

The unsaturated fatty acids having 10 to 30 carbon atoms are, for example, alpha-linolenic acid, eicosapentaenoic acid, docosahexaenoic acid, linolenic acid, gamma-linolenic acid, and dihomo-gamma-linolenic acid substituted with an alkyl group having 1 to 10 carbon atoms. , arachidonic acid, foulic acid, oleic acid, elaidic acid, eicosenoic acid, erucic acid, nervonic acid, and liquid isomers thereof, etc. may be used, but are not limited thereto. 1 type of these components can be used individually or in mixture of 2 or more types.

The liquid fatty acid derivative may include a liquid material other than a solid phase among the aforementioned fatty acid alcohol compounds having 10 to 50 carbon atoms and fatty acid ester compounds having 10 to 50 carbon atoms.

When the oil content in the hair styling wax composition is less than 5% by weight, it is difficult to prevent cloudiness, and the formulation is excessively solidified so that fluidity suitable for a hair styling wax product cannot be realized. On the contrary, if it exceeds 10% by weight, the setting and fixing power for hair is lowered, and it is difficult to implement the setting and fixing force for curly hair.

The additive may include one or more of hair nutrients, surfactants, emulsifiers, preservatives, and fragrances.

The hair nutrients may be, for example, honey extract, royal jelly extract, propolis, and the like.

The surfactant is, for example, POE sorbitan fatty acid esters such as polyoxyethylene (hereinafter referred to as POE) sorbitan monooleate, POE sorbitan monostearate, POE sorbitan trioleate, POE sorbitan mono POE sorbitol fatty acid esters such as oleate, POE sorbitol pentaoleate, and POE sorbitol monostearate, POE glycerin fatty acid esters such as POE glycerin monostearate, POE glycerin monoisostearate, and POE glycerin isostearate , POE fatty acid esters such as POE monooleate, POE distearate, POE dioleate, POE oleyl ether, POE stearyl ether, POE behenyl ether, POE 2-octyldodecyl ether, POE 2-hexyldecyl ether , POE alkyl ethers such as POE 2-heptylundecyl ether, POE 2-decyltetradecyl ether, POE 2-decylpentadecyl ether, and POE cholestanol ether, POE alkyl phenyl ethers such as POE nonylphenyl ether, POE POP block copolymers, POE/POP alkyl ethers such as POE/POP cetyl ether, POE/POP 2-decyltetradecyl ether, POE/POP hydrogenated lanolin, POE castor oil or hydrogenated castor oil derivatives such as POE castor oil , POE beeswax/lanolin derivatives such as POE sorbit beeswax, POE phytosterol ether, POE polyether modified silicone surfactants, PEG-150 pentaerythrityl tetrastearate, polyethylene glycol ether of oleyl alcohol, polyethylene glycol of cetyl alcohol glycol ethers such as ether; and the like. Among these, a hydrophilic nonionic interface selected from HLB13 or higher polyoxyalkylene addition type alkyl ether, polyoxyalkylene addition type alkyl ester, polyoxyalkylene addition type sorbitan, polyoxyalkylene addition type hydrogenated castor oil, and polyoxyalkylene addition type phytosterol. An active agent, or a hydrophilic anionic surfactant selected from N-acylglutamates and acylalkyltaurine salts may be used, but is not limited thereto. 1 type of these components can be used individually or in mixture of 2 or more types.

The emulsifier is, for example, propylene glycol, dipropylene glycol, polypropylene glycol, polyoxyethylene polyoxypropylene glycol, polyoxypropylene polyoxyethylene glycol, glycerol, ethoxylated glycerol, propoxylated glycerol, sorbitol, ethoxylated sorbitol , hydroxypropyl sorbitol, polyethylene glycol, methoxy polyethylene glycol, etc. may be used, but is not limited thereto. 1 type of these components can be used individually or in mixture of 2 or more types.

For example, Gausseria oil, lavender oil, vanilla spice, bergamot oil, ambergris, ionone spice, jasmine oil, rose oil, clove oil, geraniol oil, blended spice, mint for spice, musk for spice, etc. may, but is not limited thereto. 1 type of these components can be used individually or in mixture of 2 or more types.

Additives in the hair styling wax composition may be included in an amount of 1% to 20% by weight. In this case, it is possible to realize more excellent fluidity, setting power and fixing power to the hair without impairing the formulation of the hair styling wax composition.

Another embodiment of the present invention is to add a second solution obtained by melting and mixing solid wax, solid formulation auxiliary and additives to a first solution in which polyvinylpyrrolidone is dissolved in an aqueous solvent, and It relates to a method for producing the above-described hair styling wax composition comprising the step of preparing wax composition particles by pulverizing the mixture at a high speed at a solidifying temperature.

Accordingly, the present invention provides a hair styling wax composition having excellent setting power, spreadability, and washability, preventing cloudiness, and having excellent fixing power for curly hair, and a method for preparing the same.

In addition, the method for preparing the hair styling wax composition of the present invention improves the fluidity of the hair styling wax composition compared to the conventional method of simple emulsification of an aqueous solvent and oil and fat components, while containing a high content of solid oil and solid formulation adjuvants. Curing phenomenon can be prevented.

In the method for preparing the hair styling wax composition of the present invention, specific components and compositions are as described above.

In the method for preparing the hair styling wax composition of the present invention, the first solution may be a solution containing a water-soluble component in the hair styling wax composition of the present invention described above. In addition, the second solution may be a solution containing an oily component in the hair styling wax composition of the present invention described above.

Specifically, the first solution may be a solution of polyvinylpyrrolidone in an aqueous solvent. In addition, the first solution may further include a water-soluble component among additive components. The method for preparing the first solution is not particularly limited, and may be, for example, mixing the respective components thoroughly by adding an aqueous solvent and water-soluble components to a reactor, followed by stirring, heating, and hot water bath.

In one embodiment, the first solution may be to stir after adding polyvinylpyrrolidone and a water-soluble emulsifier to an aqueous solvent.

Specifically, the second solution may be a mixture of solid wax, solid formulation auxiliary and oil at a temperature equal to or higher than the melting temperature, for example, 70°C to 80°C. In addition, the second solution may further include an oil component among additive components. The method for preparing the second solution is not particularly limited. For example, solid wax, solid formulation aids, oil and oily additives are added to the reactor, and then stirred, heated, hot water, etc. are performed to completely melt and mix each component. it may be

The first solution and the second solution are mixed and then pulverized at a solidification temperature at a high speed to obtain wax composition particles.

A mixing method of the first solution and the second solution is not particularly limited, but may be cooled to a solidification temperature after stirring at a melting temperature or higher to increase miscibility, for example. At this time, stirring may be performed simultaneously with the process of cooling to the solidification temperature, and the cooling temperature may be gradually or stepwise lowered.

The solidification refers to a point at which the mixture of the first solution and the second solution in a molten state starts to be solidified. The solidification temperature may vary depending on the composition of the entire hair styling wax composition, but may be, for example, 50 °C to 60 °C. Within the above range, high-speed grinding efficiency may be excellent.

The mixture of the first solution and the second solution may be cooled to a solidification temperature and then pulverized at high speed to obtain fine particles of the wax composition. The high-speed pulverization method is not particularly limited, and specifically, the wax composition particles may be pulverized using a pulverizer while maintaining the solidification temperature. The grinding device may be a homomixer, a paddle mixer, etc., and grinding may be performed at a speed of, for example, 3000 rpm or more in the case of a homomixer and 500 rpm or more in the case of a paddle mixer, for a time of, for example, 10 minutes to 50 minutes. . Within the above range, the size of the wax composition particles may be more uniform and the high-speed grinding efficiency may be more excellent.

After preparing the wax composition particles, a step of homogenizing by dissolving the wax composition particles at a melting temperature and then performing cooling may be further performed. In this case, the homogeneity of the wax composition, which is difficult to improve, can be greatly improved.

Specifically, the homogenizing step is to raise the temperature of the wax composition particles to a melting temperature or higher, for example, 60 to 80 ° C, re-dissolve the pulverized wax composition particles, and then solidify again to a temperature or lower including cooling to a temperature of This homogenization step may be repeatedly performed, for example, 1 or more times, 2 to 5 times, 2 to 3 times, and the like. In this case, the degree of homogenization can be further improved.

In addition, after the homogenization step, the above-described high-speed grinding or high-speed grinding and homogenization may be additionally performed. In this case, miscibility and homogeneity of the wax composition, which is difficult to improve homogeneity, can be further improved.

The homogenized hair styling wax composition as described above may be mixed with additives, for example, hair nutrients, etc. after homogenization, and filled in a product container.

Example

Hereinafter, the configuration and operation of the present invention will be described in more detail through preferred embodiments of the present invention. However, this is presented as a preferred example of the present invention and cannot be construed as limiting the present invention by this in any sense.

Example 1

34.6% by weight of purified water, 6% by weight of polyvinylpyrrolidone, and 5% by weight of propylene glycol were added to the main tank and stirred to prepare a first solution in a completely dissolved state. Then, the temperature of the first solution was heated to 75 °C.

In a separate oil phase tank, 15 wt% of microcrystalline wax, 10 wt% of ozokerite, 5 wt% of beeswax, and 6 parts by weight of candelilla wax were put as solid wax in a separate oil phase tank, and while heating at 75° C. or higher, stearic acid as a solid formulation aid, A total of 9% by weight of glycylstearate SE and Ceteth-20 were added at 3% by weight each, oleyl alcohol 3% by weight, vegetable oil (olive oil) 2.5%, surfactant 2.4% by weight, fragrance 0.7% by weight, A second solution was prepared by adding 0.5% by weight of phenoxyethanol to completely dissolve the mixture.

After preparing a mixture by adding the second solution to the first solution, the mixture was stirred for 10 minutes while maintaining 75 ° C., and the mixture was slowly cooled to 65 ° C. while sufficiently stirring, and then cooled again to the solidification temperature of 55 ° C.

The mixture was pulverized at a high speed of 3000 rpm in a homomixer for 30 minutes while maintaining a solidification temperature of 55° C. to prepare finely pulverized wax composition particles.

After raising the temperature of the wax composition particles to 65 ° C., dissolving the non-uniform particles for 10 minutes, cooling them to 55 ° C., maintaining the temperature and pulverizing at a high speed of 3000 rpm in a homomixer for 30 minutes.

Then, to the hair styling wax composition homogenized at 55 ° C., a total of 0.3% by weight of honey extract, royal jelly extract, and propolis extract, which are hair nutrients among additive components, was added at 0.1% by weight each, stirred for 10 minutes, and then heated to 60 ° C. After raising and maintaining the temperature, the preparation of the hair styling wax composition was completed. The hair styling wax composition prepared as described above was filled into a product container through a filling facility maintaining 60° C., cooled naturally at room temperature, and then hardened into a product.

Examples 2 to 3

A hairstyling wax composition was prepared in the same manner as in Example 1, except that the contents of the components used were changed as shown in Table 1 below .

Comparative Example 1

A hairstyling wax composition was prepared in the same manner as in Example 1, except that the contents of the components used were changed as shown in Table 1 below and the high-speed grinding process was not performed .

Comparative Example 2

A hairstyling wax composition was prepared in the same manner as in Example 1, except that the contents of the components used were changed as shown in Table 1 below .

Comparative Examples 3 to 4

A hairstyling wax composition was prepared in the same manner as in Example 1, except that the contents of the components used were changed as shown in Table 1 below and the high-speed grinding process was not performed .

ingredient name Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 1st solution Purified water 35.6 33.0 26.0 38.5 17.5 35.6 32.5 polyvinylpyrrolidone 5.0 6.0 7.0 10.0 2.0 5.0 5.0 sub Total 40.6 39.0 33.0 48.5 19.5 40.6 37.5 solid wax microcrystalline wax 15.0 15.0 15.0 8.0 15.0 15.0 15.0 ozokerite 10.0 13.0 13.0 8.0 12.0 10.0 9.0 beeswax 5.0 5.0 8.0 4.0 12.0 5.0 5.0 candelilla wax 6.0 4.0 6.0 5.0 12.0 6.0 4.0 sub Total 36.0 37.0 42.0 25.0 51.0 36.0 33.0 Solid Formulation Supplements stearic acid 3.0 3.0 3.0 3.0 3.0 3.0 3.0 Glyceryl Stearate SE 3.0 3.0 3.0 3.0 3.0 3.0 3.0 Ceteth-20 3.0 3.0 3.0 3.0 3.0 3.0 3.0 sub Total 9.0 9.0 9.0 9.0 9.0 9.0 9.0 oil oleyl alcohol 3.0 3.0 3.0 4.0 5.0 3.0 5.0 vegetable oil 2.5 2.5 2.5 4.0 5.0 2.5 5.0 sub Total 5.5 5.5 5.5 8.0 10.0 5.5 10.0 additive aqueous dispersant
(added in the first solution) 5.0 5.0 5.0 5.0 5.0 5.0 5.0 Surfactants
(added in the second solution) 2.4 3.0 4.0 3.0 4.0 2.4 4.0 Spices
(added in the second solution) 0.7 0.7 0.7 0.7 0.7 0.7 0.7 antiseptic
(added in the second solution) 0.5 0.5 0.5 0.5 0.5 0.5 0.5 hair nutrients 0.3 0.3 0.3 0.3 0.3 0.3 0.3 sub Total 8.9 9.5 10.5 9.5 10.5 8.9 10.5 Sum 100.0 100.0 100.0 100.0 100.0 100.0 100.0

<Physical property evaluation method>

For the hair styling compositions prepared in Examples and Comparative Examples, 20 evaluators (male: 12, female: 8) evaluated setting power, spreadability, washability, anti-cloudiness, and fixation power for curly hair in the following ways, respectively. (curly relaxation ability) was evaluated.

1) Setting power: After taking 8g of the hair composition prepared in the above Examples and Comparative Examples in the hands of each evaluator and evenly applying it to the hair, the degree of hair clumping and hardening was recorded on a 5-point scale according to the following setting power evaluation criteria , the average value was calculated by summing the scores of all evaluators. The results are shown in Table 2.

<Setting Power Evaluation Criteria>

1 point: very bad, 2 points: bad, 3 points: average, 4 points: good, 5 points: very good

2) Spreadability: Each evaluator scored the same amount of samples of Examples and Comparative Examples filled in the product container with their fingers and spread well to the hair according to the following spreadability evaluation criteria. After recording the total score, The average value was calculated by adding the scores of the evaluators. The results are shown in Table 2.

<Spreadability Evaluation Criteria>

1 point: very bad, 2 points: bad, 3 points: average, 4 points: good, 5 points: very good

3) Washability: Each evaluator took 8g of the hair composition prepared in the above Examples and Comparative Examples, applied it to the hair, rinsed it with the same shampoo, and then the degree of washing was recorded on a 5-point scale according to the following setting evaluation criteria. Then, the average value was calculated by summing the scores of all evaluators. The results are shown in Table 2.

<Evaluation Criteria for Washability>

1 point: very bad, 2 points: bad, 3 points: average, 4 points: good, 5 points: very good

4) Anti-cloudy property: The evaluator took 1 g of the hair composition prepared in the above Examples and Comparative Examples and evenly applied it to the hair bundle (thickness 5 mm, length 100 mm), and the degree of cloudiness that appeared on the hair after 30 minutes was evaluated as the following anti-cloudy property evaluation criteria After recording according to the 5-point scale, the average value was calculated by summing the scores of all evaluators. The results are shown in Table 2.

<Criteria for anti-cloudy properties>

1 point: very much white turbidity

2 points: There is a little white turbidity, and there is no gloss

3 points: No white cast, but no gloss

4 points: No cloudiness, but normal gloss

5 points: no white cast, excellent gloss

5) Curly relief: Each evaluator placed a hair bundle (30 strands, 130mm) on a cylindrical rod (diameter 12mm, length 100mm) with a permanent agent (Voxanical Wave Lotion from Iljin Cosmetics Co., Ltd., agent 1 20 minutes, agent 2) 10 minutes), apply 1 g of the hair composition prepared in Examples and Comparative Examples to the hair wavy through the treatment, straighten it with a brush, and measure the length after 30 minutes.

When the ability of curls to be stretched and fixed by wax is referred to as curl relaxation ability, the curl relaxation ability was calculated according to Equation 1 below.

[Equation 1]

Curly relief (%) = {(L _t -L ₀ )/(LL ₀ )} X 100

Here, L is the hair length before perm treatment, L ₀ is the length after perm treatment, and L _t is the length after 1 hour after applying wax.

The higher the number, the better the curly hair straightens. The average value was calculated by testing each of the three samples of Examples and Comparative Examples, and the results are shown in Table 2.

parts by weight Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 setting force 4.0 4.5 4.7 4.0 3.1 4.0 3.1 spreadability 4.8 4.7 4.0 3.9 1.3 1.3 4.8 washability 4.8 4.7 4.0 3.9 1.8 3.9 3.3 Anti-cloudy property 4.8 4.8 4.1 2.9 2.2 3.1 4.1 holding power
(curly strength, %) 75 80 82.8 67.7 80 75.8 58.6

As can be seen from the results of Table 2, within the composition range of the present invention, the hair styling wax compositions of Examples 1 to 3 prepared through high-speed grinding (emulsion-grinding-re-grinding) at a solidification temperature have excellent setting power. , spreadability and washability, can prevent cloudiness, and has excellent fixation power for curly hair.

On the other hand, Comparative Example 1 containing less than 33% by weight of solid wax and prepared by a general emulsification method rather than high-speed milling cannot prevent white cast, and easily breaks after fixing the hair, realizing a sufficient level of curly relaxation. It was hard to do.

In addition, Comparative Example 2, which contained more than 50% by weight of solid wax and was prepared by the same high-speed grinding method as Example, showed very poor usability and spreadability, resulting in unsatisfactory results in all sensory evaluations.

In addition, Comparative Example 3, in which the same composition as Example 1 was prepared by a general emulsification method rather than high-speed grinding, was difficult to use due to excessively high hardness, and Comparative Example 4 showed unsatisfactory results in sensory evaluation.

Claims (10)

4% to 7% by weight of polyvinylpyrrolidone;
20% to 40% by weight of an aqueous solvent;
33% to 60% by weight of a solid wax including microcrystalline wax, ozokerite, beeswax and candelilla wax;
7% to 11% by weight of a solid formulation aid;
5% to 10% by weight of oil; and
1% to 20% by weight of additives;
Hair styling wax composition comprising a.
According to claim 1,
Of the solid wax, 30% to 50% by weight of microcrystalline wax, 20% to 30% by weight of ozokerite, 10% to 20% by weight of beeswax, and 10% to 20% by weight of candelilla wax A hair styling wax composition comprising the.
According to claim 1,
The solid formulation adjuvant is a hair styling wax composition comprising at least one of a saturated fatty acid compound having 10 to 50 carbon atoms, a fatty acid alcohol compound having 10 to 50 carbon atoms, and a fatty acid ester compound having 10 to 50 carbon atoms.
According to claim 1,
The oil is a hair styling wax composition comprising at least one of vegetable oil, mineral oil, petrolatum, synthetic oil, unsaturated fatty acids having 1 to 30 carbon atoms, and liquid fatty acid derivatives.
According to claim 1,
The additive is a hair styling wax composition comprising at least one of hair nutrients, surfactants, emulsifiers, preservatives and fragrances.
Adding a second solution obtained by melting and mixing solid wax, solid formulation auxiliary, oil, and additives to a first solution in which polyvinylpyrrolidone is dissolved in an aqueous solvent,
A method for preparing a hair styling wax composition comprising the step of preparing wax composition particles by high-speed pulverization of a mixture of the first solution and the second solution at a solidifying temperature,
The hair styling wax composition
4% to 7% by weight of the polyvinylpyrrolidone;
20% to 40% by weight of the aqueous solvent;
33% to 60% by weight of the solid wax;
7% to 11% by weight of the solid formulation auxiliary;
5% to 10% by weight of the oil; and
1% to 20% by weight of the additive;
A method for producing a hair styling wax composition comprising a.
delete According to claim 6,
The solid wax comprises 30% to 50% by weight of microcrystalline wax, 20% to 30% by weight of ozokerite, 10% to 20% by weight of beeswax, and 10% to 20% by weight of candelilla wax. A method for preparing a hair styling wax composition.
According to claim 6,
The method of producing a hair styling wax composition wherein the solidification temperature is 50 ° C to 60 ° C.
According to claim 6,
A method for producing a hair styling wax composition comprising, after the step of preparing the wax composition particles, a step of dissolving the wax composition particles at a melting temperature and then homogenizing by performing cooling.