KR102376478B1 - Fabric Having Graphene Pattern and Ceramic Chip - Google Patents

Fabric Having Graphene Pattern and Ceramic Chip Download PDF

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KR102376478B1
KR102376478B1 KR1020210173073A KR20210173073A KR102376478B1 KR 102376478 B1 KR102376478 B1 KR 102376478B1 KR 1020210173073 A KR1020210173073 A KR 1020210173073A KR 20210173073 A KR20210173073 A KR 20210173073A KR 102376478 B1 KR102376478 B1 KR 102376478B1
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weight
parts
graphene
ceramic chip
fabric
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나세윤
조다연
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나세윤
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/74Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C23/00Making patterns or designs on fabrics
    • D06C23/04Making patterns or designs on fabrics by shrinking, embossing, moiréing, or crêping
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/17Natural resins, resinous alcohols, resinous acids, or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/08Processes in which the treating agent is applied in powder or granular form
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/13Physical properties anti-allergenic or anti-bacterial
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/16Physical properties antistatic; conductive
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2509/00Medical; Hygiene

Abstract

The present invention relates to a fabric having a graphene pattern and a ceramic chip. More specifically, the present invention relates to a fabric having a graphene pattern and a ceramic chip comprising: a graphene pattern formed on one side of the fabric; and a ceramic chip that is located on the graphene patter and includes loess, natural material powder, graphene powder, a filler, and an adhesive, wherein with respect to 100 parts by weight of loess, the proportions of natural material powder, graphene powder, a filler, and an adhesive are 30-50 parts by weight, 5-10 parts by weight, 1-5 parts by weight, and 15-20 parts by weight, respectively.

Description

그래핀 패턴과 세라믹 칩이 구비된 원단 {Fabric Having Graphene Pattern and Ceramic Chip}Fabric Having Graphene Pattern and Ceramic Chip {Fabric Having Graphene Pattern and Ceramic Chip}

본 발명은 그래핀 패턴과 세라믹 칩이 구비된 원단에 관한 것으로서, 더욱 자세하게는 원단의 일측에 형성된 그래핀 패턴, 및 상기 그래핀 패턴 상에 위치하며, 황토 100 중량부를 기준으로 천연물 분말 30~50 중량부, 그래핀 분말 5~10 중량부, 충진제 1~5 중량부 및 접착제 15~20 중량부를 포함하는 세라믹 칩 을 포함하는 그래핀 패턴과 세라믹 칩이 구비된 원단에 대한 것이다.The present invention relates to a fabric provided with a graphene pattern and a ceramic chip, and more particularly, a graphene pattern formed on one side of the fabric, and positioned on the graphene pattern, based on 100 parts by weight of ocher, 30-50 natural powder It relates to a fabric provided with a graphene pattern and a ceramic chip including a ceramic chip comprising parts by weight, 5 to 10 parts by weight of graphene powder, 1 to 5 parts by weight of a filler, and 15 to 20 parts by weight of an adhesive.

매트리스, 시트, 소파 등에 사용되는 침구나 가구에 사용되는 원단은 일상생활에서 가장 오랫동안 피부와 접촉하는 생활용품으로서, 최근에는 이렇게 생활용품에 사용되는 원단에 원적외선 방사나 음이온 발생, 항균효과와 같은 기능성을 추가하기 위하여 세라믹 및 옥돌 등과 같은 건강물질들을 부착한 제품들이 많이 선보이고 있다. Fabrics used for bedding and furniture used in mattresses, sheets, sofas, etc. are household items that come into contact with the skin for the longest period of time in daily life. In order to add health benefits, many products with health materials such as ceramics and jadeite are being introduced.

그러나 이러한 제품들로부터도 전자파 또는 기타 다양한 유해물질들이 생성되어 인체에 영향을 미친다는 사실이 보고되고 있다. 이러한 유해 환경에 장기간 노출되는 경우, 피부 건조, 소양증 및 아토피 등과 같은 피부 질환부터 시작하여 두통, 시력 저하, 백혈병, 뇌종양, 순환계 이상, 남자 생식기능의 파괴 등 심각한 질병까지 유발할 수 있다. However, it is reported that electromagnetic waves or various other harmful substances are generated from these products and affect the human body. When exposed to these harmful environments for a long time, it can cause serious diseases such as skin diseases such as dry skin, pruritus, and atopic dermatitis, headache, decreased vision, leukemia, brain tumor, circulatory system abnormality, and destruction of male reproductive function.

따라서, 원적외선 방사나 음이온 발생, 항균효과와 같은 기능성 효과를 가지면서도 정전기 등과 같은 미세전류를 흡수 및 소멸시킴으로써 전자파를 차단하고 피부 건조, 소양증 및 아토피 등과 같은 피부 질환을 완화시킬 수 있는 새로운 기능성 원단의 개발이 필요하였다. Therefore, while having functional effects such as far-infrared radiation, generation of negative ions, and antibacterial effect, it absorbs and dissipates microcurrent such as static electricity to block electromagnetic waves and relieve skin diseases such as dry skin, pruritus and atopy. development was necessary.

대한민국 공개특허 제10-2013-0107605Republic of Korea Patent Publication No. 10-2013-0107605 대한민국 등록특허 제10-0620248Republic of Korea Patent Registration No. 10-0620248

본 발명에서는 원적외선 방사, 항균효과와 같은 기능성 효과를 가짐과 동시에 인체에 흐르는 정전기 등과 같은 미세전류를 흡수 및 소멸시킴으로써 피부 건조, 소양증 및 아토피 등과 같은 피부 질환까지 완화시킬 수 있는 기능성 원단을 제공하고자 한다.In the present invention, it has functional effects such as far-infrared radiation and antibacterial effect, and at the same time absorbs and dissipates microcurrent such as static electricity flowing through the human body, thereby alleviating skin diseases such as dry skin, pruritus and atopic dermatitis. .

상기 목적을 달성하기 위하여, 본 발명은 직물지 원단의 일측에 형성된 그래핀 패턴, 및 상기 그래핀 패턴 상에 위치하며, 황토 100 중량부를 기준으로 천연물 분말 30~50 중량부, 그래핀 분말 5~10 중량부, 충진제 1~5 중량부 및 접착제 15~20 중량부를 포함하는 세라믹 칩을 포함하는 그래핀 패턴과 세라믹 칩이 구비된 원단을 제공한다. In order to achieve the above object, the present invention provides a graphene pattern formed on one side of a fabric fabric, and positioned on the graphene pattern, based on 100 parts by weight of loess, 30-50 parts by weight of natural product powder, 5-10 parts by weight of graphene powder Provided is a fabric provided with a graphene pattern and a ceramic chip including a ceramic chip including parts by weight, 1-5 parts by weight of a filler, and 15-20 parts by weight of an adhesive.

상기 천연물 분말이 쑥 분말 30~40 중량%, 상엽 분말 30~40 중량% 및 송엽 분말 30~40 중량%를 포함하는 것이 바람직하며, 상기 접착제는 실리콘 아크릴 중합체 60~80 중량% 및 폴리비닐 아세테이트 20~40중량%를 포함하는 것이 바람직하다. Preferably, the natural product powder contains 30-40% by weight of mugwort powder, 30-40% by weight of upper leaf powder, and 30-40% by weight of pine leaf powder, and the adhesive is 60-80% by weight of silicone acrylic polymer and 20% by weight of polyvinyl acetate It is preferred to include ~40% by weight.

본 발명의 기능성 원단은 원적외선 방사, 항균효과와 같은 기능성 효과를 가짐과 동시에 인체에 흐르는 정전기 등과 같은 미세전류를 흡수 및 소멸시킴으로써 피부 건조, 소양증 및 아토피 등과 같은 피부 질환까지 완화시킬 수 있다. The functional fabric of the present invention has functional effects such as far-infrared radiation and antibacterial effect, and at the same time absorbs and dissipates microcurrent such as static electricity flowing through the human body, thereby alleviating skin diseases such as dry skin, pruritus and atopic dermatitis.

도 1은 본 발명의 일 실시예에 따른 그래핀 패턴과 세라믹 칩이 구비된 원단을 위에서 내려다 본 사진이다.
도 2는 본 발명의 일 실시예에 따른 그래핀 패턴과 세라믹 칩이 구비된 원단의 단면을 보여주는 본 사진이다.
1 is a photo of a fabric provided with a graphene pattern and a ceramic chip as viewed from above according to an embodiment of the present invention.
2 is a view showing a cross-section of a fabric provided with a graphene pattern and a ceramic chip according to an embodiment of the present invention.

이하, 본 발명의 실시예를 참조하여 본 발명을 상세히 설명한다. 이들 실시예는 오로지 본 발명을 보다 구체적으로 설명하기 위해 예시적으로 제시한 것일 뿐, 본 발명의 범위가 이들 실시예에 의해 제한되지 않는다는 것은 당업계에서 통상의 지식을 가지는 자에 있어서 자명할 것이다.Hereinafter, the present invention will be described in detail with reference to examples of the present invention. It will be apparent to those of ordinary skill in the art that these examples are merely presented by way of example to explain the present invention in more detail, and that the scope of the present invention is not limited by these examples. .

또한, 달리 정의하지 않는 한, 본 명세서에서 사용되는 모든 기술적 및 과학적 용어는 본 발명이 속하는 기술 분야의 숙련자에 의해 통상적으로 이해되는 바와 동일한 의미를 가지며, 상충되는 경우에는, 정의를 포함하는 본 명세서의 기재가 우선할 것이다. Further, unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs, and in case of conflict, this specification, including definitions will take precedence.

본 발명은 원단의 일측에 형성된 그래핀 패턴; 및 상기 그래핀 패턴 상에 위치하며, 황토 100 중량부를 기준으로 천연물 분말 30~50 중량부, 그래핀 분말 5~10 중량부, 충진제 1~5 중량부 및 접착제 15~20 중량부를 포함하는 세라믹 칩;을 포함하는 그래핀 패턴과 세라믹 칩이 구비된 원단에 관한 것이다. 이하 각 성분을 자세히 살펴본다. The present invention is a graphene pattern formed on one side of the fabric; And located on the graphene pattern, based on 100 parts by weight of ocher, 30-50 parts by weight of natural product powder, 5-10 parts by weight of graphene powder, 1-5 parts by weight of a filler, and 15-20 parts by weight of an adhesive. It relates to a fabric provided with a graphene pattern and a ceramic chip comprising; Let's look at each component in detail below.

상기 직물지 원단은 어떠한 처리도 되지 않은 원단일 수 있고, 또는 나염 등과 같은 방식을 통해 염색되거나 무늬가 형성된 원단일 수도 있으며, 단일층 원단 혹은 다중직 원단일 수 있다.The textile fabric may be a fabric that has not been treated with any kind, or may be a fabric dyed or patterned through a method such as printing, or may be a single-layer fabric or a multi-woven fabric.

상기 그래핀 패턴은 그래핀 함유 잉크로 인쇄한 패턴으로서 서로 이어져 있는 반복적인 형태이면 어떠한 형태이든 가능하다. 바람직하게는 도 1에 도시된 것과 같이 육각형 형태가 면이 맞닿도록 반복되어 형성될 수 있다. The graphene pattern is a pattern printed with graphene-containing ink and may have any shape as long as it has a repetitive shape connected to each other. Preferably, as shown in FIG. 1 , the hexagonal shape may be repeatedly formed so that the faces are in contact.

상기 그래핀 패턴은 원단 표면에 그래핀 함유 잉크를 인쇄한 후, 원단을 50~100℃로 가열된 압축식 롤러에 통과시킨 후 건조하여 형성시킬 수 있다. 상기 유성잉크는, 유기용제 100 중량부에 대하여, 탄소 70~90 중량부 및 산화아연 1~10 중량부를 포함할 수 있다. The graphene pattern may be formed by printing graphene-containing ink on the surface of the fabric, passing the fabric through a compression roller heated to 50 to 100° C., and drying the fabric. The oil-based ink may contain 70 to 90 parts by weight of carbon and 1 to 10 parts by weight of zinc oxide based on 100 parts by weight of the organic solvent.

상기 유기용제는 탄소를 용해하여 직물지에 용이하게 도포되어 부착되도록 하며, 일 실시예로 폴리아크릴에스터 공중합체를 톨루엔 용제로 용해시켜 고형분 15~45 중량%, 점도 5,000~15,000 cps(20℃)로 제조한 유성 아크릴수지가 사용될 수 있다. The organic solvent dissolves carbon so that it is easily applied and attached to the fabric, and in one embodiment, the polyacrylic ester copolymer is dissolved in a toluene solvent to have a solid content of 15 to 45% by weight and a viscosity of 5,000 to 15,000 cps (20°C). The prepared oil-based acrylic resin may be used.

상기 그래핀은 도전성 물질로, 전자파를 차단하고 미세전류를 흡수하고 전자파를 차단하는 역할을 하며, 유기용제 100 중량부에 대하여 70~90 중량부로 포함될 수 있으며, 탄소의 함량이 70 중량부 미만인 경우에는 전자파 차단 효과가 미미하고, 90 중량부를 초과하는 경우에는 전자파 차단 효과는 뛰어나나 견뢰도가 저하되어 유성잉크가 탈리되는 문제가 발생할 수 있다. The graphene is a conductive material, and serves to block electromagnetic waves, absorb microcurrent, and block electromagnetic waves, and may be included in an amount of 70 to 90 parts by weight based on 100 parts by weight of the organic solvent, and when the carbon content is less than 70 parts by weight The electromagnetic shielding effect is insignificant, and when it exceeds 90 parts by weight, the electromagnetic wave shielding effect is excellent, but the fastness is lowered, so that a problem in which the oil-based ink is detached may occur.

상기 산화아연은 섬유에 항균성을 부가하기 위하여 첨가되며, 유기용제 100 중량부에 대하여 1~10 중량부로 포함될 수 있으며, 1 중량부 미만인 경우에는 항균 효과가 미미하고, 10 중량부를 초과하도록 포함되는 경우에는 다른 성분들과의 혼화성 및 직물지의 전체적인 물성이 저하될 수 있다The zinc oxide is added to add antibacterial properties to the fiber, and may be included in an amount of 1 to 10 parts by weight based on 100 parts by weight of the organic solvent. Miscibility with other ingredients and overall physical properties of fabric may be deteriorated.

상기 그래핀 함유 잉크는 원단 표면에 공지의 다양한 인쇄 방식을 통해 인쇄될 수 있다. The graphene-containing ink may be printed on the surface of the fabric through various known printing methods.

이와 같이 원단에 그래핀 패턴이 형성되고 나면, 상기 그래핀 패턴 상에 그래핀 분말을 함유하는 세라믹 칩이 위치하게 된다. After the graphene pattern is formed on the fabric as described above, the ceramic chip containing the graphene powder is positioned on the graphene pattern.

본 발명은 그래핀 패턴 위에 그래핀 분말을 함유하는 세라믹 칩을 위치시켜 인체에 흐르는 정전기 등과 같은 미세전류가 세라믹 칩으로부터 그래핀 패턴으로 흘러들어가 분산되어 소멸되도록 하는 것을 특징으로 한다. The present invention is characterized in that the ceramic chip containing the graphene powder is placed on the graphene pattern so that a microcurrent such as static electricity flowing through the human body flows from the ceramic chip to the graphene pattern and disperses and disappears.

따라서, 세라믹 칩과 그래핀 패턴 사이에 접촉 부분이 존재하여야 하며, 바람직하게는 도면에 도시된 것과 같이 세라믹 칩의 테두리를 따라 그래핀 패턴이 형성되도록 하는 것이 바람직하다. Therefore, a contact portion should exist between the ceramic chip and the graphene pattern, and preferably, the graphene pattern is formed along the edge of the ceramic chip as shown in the drawings.

상기 세라믹 칩은 시중의 다양한 기능성 세라믹이 사용될 수 있으나, 바람직하게는 황토 100 중량부를 기준으로 천연물 분말 30~50 중량부, 그래핀 분말 5~10 중량부, 충진제 1~5 중량부 및 접착제 15~20 중량부를 포함하는 세라믹 칩을 사용하는 것이 바람직하다. As the ceramic chip, various commercially available functional ceramics may be used, but preferably, based on 100 parts by weight of ocher, 30-50 parts by weight of natural powder, 5-10 parts by weight of graphene powder, 1-5 parts by weight of a filler and 15 parts by weight of an adhesive It is preferable to use a ceramic chip containing 20 parts by weight.

상기 황토는 인체에 유익한 원적외선을 방출하여 세포의 생리 작용을 활발하게 하고 열에너지를 발생시키며 신진대사 및 혈액순환을 활성화시켜 인체의 노화 방지에 효과가 있는 것으로 알려져 있다. 또한, 우수한 항균성으로 곰팡이 등 세균의 번식을 억제하고 높은 흡착성으로 노폐물을 제거하는 유익한 효과가 널리 알려져 있다. 황토에는 다량의 탄산칼슘(CaCO3)이 존재하는데, 이에 의해 황토는 쉽게 부서지지 않는 점력을 지니고 있어 물을 가하면 찰흙으로 변하는 성질이 있다. 이밖에도 황토는 실리카(SiO2), 알루미나(Al2O3), 철분, 마그네슘, 나트륨 등을 함유하고 있다.The loess is known to be effective in preventing aging of the human body by emitting far-infrared rays beneficial to the human body, activating the physiological action of cells, generating thermal energy, and activating metabolism and blood circulation. In addition, the beneficial effect of suppressing the growth of bacteria such as mold with excellent antibacterial properties and removing wastes with high adsorption properties is widely known. A large amount of calcium carbonate (CaCO3) exists in loess, and as a result, loess has a viscous force that does not break easily, so it has a property of turning into clay when water is added. In addition, loess contains silica (SiO2), alumina (Al2O3), iron, magnesium, sodium, and the like.

상기 천연물 분말은 세라믹 칩에 기능성을 부여하기 위한 것으로서, 황토 100 중량부를 기준으로 30~50 중량부가 사용되는 것이 바람직하다. 이보다 적은 경우 기능적 효과를 충분히 발휘하기 어려우며, 이보다 많은 경우 전체적인 성형성이 떨어질 수 있다. The natural product powder is for imparting functionality to the ceramic chip, and is preferably used in an amount of 30-50 parts by weight based on 100 parts by weight of loess. If it is less than this, it is difficult to sufficiently exhibit the functional effect, and if it is more than this, the overall moldability may be deteriorated.

상기 천연물 분말은 다양한 천연물이 사용될 수 있으며, 일 실시예로 쑥 분말 30~40 중량%, 상엽 분말 30~40 중량% 및 송엽 분말 30~40 중량%를 포함할 수 있다. 상기 쑥은 노화를 예방하고 피부재생을 촉진하는데 탁월하며, 항균, 소독 효과도 탁월하다. 상기 상엽은 뽕나무과의 뽕나무 또는 동속 근연식물의 잎을 말린 약재이고, 송엽은 소나무과 식물인 소나무의 잎으로서, 상기 상엽과 송엽은 모두 피부를 진정하는 효과가 있다. Various natural products may be used as the natural product powder, and in one embodiment, it may include 30-40% by weight of mugwort powder, 30-40% by weight of upper leaf powder, and 30-40% by weight of pine leaf powder. The mugwort is excellent for preventing aging and promoting skin regeneration, and has excellent antibacterial and disinfecting effects. The upper leaf is a medicinal herb dried leaves of a mulberry tree in the Morus family or a closely related plant, and the pine needle is a leaf of a pine plant of the Pine family, and both the upper leaf and the pine needle have an effect of soothing the skin.

상기 그래핀 분말은 전자파를 차단하고 미세전류를 흡수하여 원단의 그래핀 패턴으로 전파하는 역할을 하며, 황토 100 중량부를 기준으로 5~10 중량부가 사용되는 것이 바람직하다. 탄소의 함량이 5 중량부 미만인 경우에는 전자파 차단 효과가 미미하고, 10 중량부를 초과하는 경우에는 분산성 및 성형성이 떨어질 수 있다. The graphene powder serves to block electromagnetic waves and absorb microcurrents to propagate to the graphene pattern of the fabric, and 5 to 10 parts by weight is preferably used based on 100 parts by weight of loess. When the carbon content is less than 5 parts by weight, the electromagnetic wave blocking effect is insignificant, and when it exceeds 10 parts by weight, dispersibility and moldability may be deteriorated.

상기 그래핀 분말과 다른 성분들과의 혼화성 및 안정성을 더욱 높이기 위하여, 상기 세라믹 칩은 황토 100 중량부를 기준으로 사이클로덱스트린 0.1~3 중량부를 추가로 포함할 수 있다. 상기 사이클로덱스트린은 글루코오스 그룹을 반복단위로 하여 구성된 환상 화합물로 그래핀과 복합체를 형성하여 그래핀이 서로 뭉치는 현상을 방지할 수 있다. 상기 사이클로덱스트린은 상업적으로 사용가능한 다양한 사이클로덱스트린이 사용될 수 있으며, 일 실시예로 2,3,6-트라이-O-나프토일-베타-사이클로덱스트린이 사용될 수 있다. In order to further improve the compatibility and stability of the graphene powder with other components, the ceramic chip may further include 0.1 to 3 parts by weight of cyclodextrin based on 100 parts by weight of loess. The cyclodextrin is a cyclic compound composed of a glucose group as a repeating unit and forms a complex with graphene to prevent the graphene from aggregating with each other. As the cyclodextrin, various commercially available cyclodextrins may be used, and in one embodiment, 2,3,6-tri-O-naphthoyl-beta-cyclodextrin may be used.

상기 그래핀 분말과 사이클로덱스트린은 각각 별도로 첨가될 수도 있으나, 사이클로덱스트린에 그래핀이 포접된 상태에서 함께 첨가하는 것이 바람직하다. 상기 사이클로덱스트린으로 포접된 그래핀 분말은 상업적으로 가능한 다양한 방법에 의하여 제조될 수 있으나, 일 예로 그래핀 분말, 사이클로덱스트린 및 NaBH4을 혼합하여 혼합물을 제조하는 단계; 상기 혼합물을 초음파 처리하는 단계; 및 상기 초음파 처리물을 증류수와 혼합하여 필터링하는 단계;를 통하여 제조할 수 있으며, 상기 필터링된 사이클로덱스트린에 포접된 그래핀이 혼합되게 된다. The graphene powder and the cyclodextrin may be added separately, respectively, but it is preferable to add them together in a state in which the graphene is included in the cyclodextrin. The graphene powder encapsulated with the cyclodextrin may be prepared by various commercially available methods, for example, preparing a mixture by mixing graphene powder, cyclodextrin, and NaBH 4 ; sonicating the mixture; and mixing the sonicated product with distilled water and filtering.

상기 충진재는 세라믹 칩의 물성을 향상시키기 위한 것으로서, 바람직하게는 석분(stone powder)이 사용될 수 있다. 석분은 입자의 치밀함으로 인하여 첨가제를 사용하지 않아도 높은 강도를 구현할 수 있고, 주변 환경에 따른 부피 변형률이 낮아 장기간 사용시에도 갈라짐 현상이 거의 발생하지 않는다. 상기 석분은 황토석, 대리석, 맥반석, 화강석, 옥석 등 다양한 암석의 분말 형태가 사용될 수 있다. The filler is for improving the physical properties of the ceramic chip, and preferably, stone powder may be used. Due to the compactness of the particles, high strength can be realized without the use of additives, and the volume deformation according to the surrounding environment is low, so cracking hardly occurs even when used for a long period of time. The stone powder may be in powder form of various rocks such as ocher stone, marble, elvan stone, granite, and jadeite.

이때, 상기 석분의 함량은 황토 100 중량부를 기준으로 1~5 중량부가 사용되는 것이 바람직하며, 이보다 미만인 경우에는 강도 향상의 효과가 미미하고, 초과하는 경우에는 성형성이 떨어질 수 있다. At this time, the content of the stone powder is preferably 1 to 5 parts by weight based on 100 parts by weight of loess. If it is less than this, the effect of improving strength is insignificant, and if it exceeds this, the formability may be deteriorated.

상기 접착제는 황토의 각 성분들이 융합되어 성형되도록 하는 역할을 하며, 황토 100 중량부를 기준으로 15~20 중량부를 포함되는 것이 바람직하다. 이보다 미만인 경우에는 성형이 잘 안 이루어지고, 초과하는 경우에는 전체적인 물성이 떨어질 수 있다. The adhesive serves to fuse and mold each component of loess, and is preferably included in an amount of 15 to 20 parts by weight based on 100 parts by weight of loess. If it is less than this, molding is not performed well, and if it exceeds this, overall physical properties may be deteriorated.

상기 접착제는 다양한 친환경 접착제가 사용될 수 있으며, 일 실시예로 일반적으로 접착제 성분으로 사용되는 성분인, 실리콘 아크릴 중합체 60~80 중량% 및 폴리비닐 아세테이트 20~40 중량%를 포함할 수 있다. Various eco-friendly adhesives may be used as the adhesive, and in one embodiment, it may include 60 to 80% by weight of a silicone acrylic polymer and 20 to 40% by weight of polyvinyl acetate, which are components generally used as an adhesive component.

한편, 상기 접착제는 접착 성분으로 젤라틴 성분을 추가로 포함할 수 있다. 상기 젤라틴 성분은 구성성분들 간의 응집력을 높임과 동시에 외부충격을 흡수하는 역할을 한다. 상기 젤라틴 성분은 다양한 재료로부터 유래한 것이 사용될 수 있으나, 바람직하게는 천연재료인 아교가 사용되는 것이 바람직하다. Meanwhile, the adhesive may further include a gelatin component as an adhesive component. The gelatin component serves to absorb external shocks while increasing cohesion between the components. As the gelatin component, those derived from various materials may be used, but it is preferable that glue, which is a natural material, is preferably used.

상기 아교는 동물의 가죽, 힘줄, 창자, 뼈 등을 고아 그 액체를 고형화한 물질로서 화재시 바로 탄화되어 유독가스 발생량이 적고 화재의 진행속도를 낮출 수 있다. 또한, 아교는 적은 함량으로도 높은 접착효과를 얻을 수 있으며, 소재 특유의 탄성으로 인하여 외부충격에 대한 흡수력이 높아, 외부 충격에 의한 깨짐 현상을 방지할 수 있다. The glue is a material obtained by solidifying the liquid by orphaning animal hides, tendons, intestines, bones, etc., and is immediately carbonized in case of fire, thereby reducing the amount of toxic gas generated and reducing the speed of the fire. In addition, a high adhesive effect can be obtained with a small amount of glue, and due to the elasticity of the material, it has high absorption against external shocks, thereby preventing cracking caused by external shocks.

상기 젤라틴 성분은 황토 100 중량부를 기준으로 1~5 중량부 포함되는 것이 바람직하며, 이보다 미만인 경우에는 기능적 효과를 내기 어렵고, 초과하는 경우에는 성형성이 떨어질 수 있다. The gelatin component is preferably included in an amount of 1 to 5 parts by weight based on 100 parts by weight of loess, and if it is less than this, it is difficult to give a functional effect, and if it exceeds this, the moldability may be deteriorated.

또한, 젤라틴 성분의 유동학적 특성을 향상시키고 다른 성분들과의 혼화성을 높이기 위하여, 젤라틴 성분 전체 중량 대비 1~10 중량부의 글리세린이 추가로 첨가되어 사용될 수 있다. In addition, in order to improve the rheological properties of the gelatin component and increase miscibility with other components, 1 to 10 parts by weight of glycerin may be additionally added based on the total weight of the gelatin component.

한편, 상기 세라믹 칩의 제조과정을 살펴보면, 상기 세라믹 칩은, 먼저 앞서 살펴본 황토, 천연물 분말, 그래핀 분말, 충진제 및 접착제를 혼합기에 넣고 반죽을 만드는 혼합 단계, 상기 반죽을 성형기에 넣고 성형하는 성형 단계, 성형된 세라믹 칩을을 280 ~ 330℃온도에서 15 ~ 30분 동안 건조하여 고형화하는 고형화 단계를 통하여 제조할 수 있다. On the other hand, looking at the manufacturing process of the ceramic chip, the ceramic chip is a mixing step of putting yellow clay, natural product powder, graphene powder, a filler and an adhesive into a mixer to make a dough, and molding the dough into a molding machine Step, it can be manufactured through a solidification step of drying the molded ceramic chip at a temperature of 280 ~ 330 ℃ for 15 ~ 30 minutes to solidify.

이와 같이 제조된 세라믹 칩은 바로 사용될 수도 있으나, 세라믹 칩 표면에 천연물 추출액을 분사처리한 후 건조하는 단계를 추가로 거칠 수도 있다. 상기 한방 추출액은 정제수에 쑥, 편백나무 및 솔잎을 24~48시간 동안 담지시키는 단계, 천연물이 담지된 담지액을 100~130℃로 2~3시간 동안 가열하여 유효성분을 추출하는 단계 및 유효성분이 추출된 추출액을 증류기에서 가열하여 증류액을 얻는 단계를 통하여 제조될 수 있다. The ceramic chip prepared in this way may be used directly, but a step of drying after spraying a natural product extract on the surface of the ceramic chip may be additionally performed. The oriental herbal extract includes the steps of supporting mugwort, cypress, and pine needles in purified water for 24 to 48 hours, heating the supporting solution carrying natural products at 100 to 130° C. for 2 to 3 hours to extract active ingredients and active ingredients It can be prepared through the step of heating the extracted extract in a distillate to obtain a distillate.

쑥의 쑥향은 머리를 맑게 하고, 두통을 해소하는 역할을 하며, 편백나무의 향은 코르티졸 호르몬을 줄여주어 스트레스 해소와 함께 스트레스로 인한 정신질환을 막아주고, 심리적인 안정을 주어 숙면을 유도한다. 솔잎은 항생, 항암, 혈압강하, 호르몬 분비촉진, 항산화 등과 같은 독특한 약리작용 효과가 있는 휘발성 물질을 발산하여 아로마테라피(aromatheraphy)에 사용되기도 한다. 상기 쑥, 편백나무 및 솔잎은 정제수 1L당 각각 5~10g, 10~20g 및 10~20g 첨가되는 것이 바람직하다. 이들의 함량이 이보다 적은 경우 각각의 기능적 효과를 충분히 발휘하기 어려우며, 이보다 많은 경우 비용 증가 대비 기능적 상승 효과가 미비하다. The mugwort scent of mugwort clears the head and relieves headaches, and the scent of cypress reduces cortisol hormone to relieve stress and prevent mental illness caused by stress, and provides psychological stability to induce a good night's sleep. Pine needles emit volatile substances that have unique pharmacological effects such as antibiotic, anticancer, blood pressure lowering, hormone secretion promotion, and antioxidant, and are also used in aromatherapy. The mugwort, cypress and pine needles are preferably added in an amount of 5 to 10 g, 10 to 20 g, and 10 to 20 g, respectively, per 1 L of purified water. When the content thereof is less than this, it is difficult to sufficiently exhibit each functional effect, and when the content thereof is more than this, the functional synergistic effect is insufficient compared to the cost increase.

상기 천연물들은 본격적인 추출과정을 시작하기 전에 정제수에 24~48시간 동안 담지 과정을 거쳐 재료들 내부에 충분히 수분이 침투하면서 이후 열추출 과정에서 유효 성분들이 더욱 효율적으로 용출되도록 한다. 상기 담지과정을 거친 담지액은 100~130℃로 2~3시간 동안 가열하여 유효성분을 추출하며, 이후 유효성분이 추출된 추출액은 그대로 사용되는 것이 아니라 세라믹 칩의 공극에 흡수되기 용이한 작은 분자크기의 성분들을 포집하기 위하여 별도의 증류과정을 거치게 된다. The natural products undergo a soaking process in purified water for 24 to 48 hours before starting the full-scale extraction process to allow sufficient moisture to penetrate into the materials, so that the active ingredients are more efficiently eluted in the subsequent thermal extraction process. The supporting solution that has undergone the above supporting process is heated at 100 to 130° C. for 2 to 3 hours to extract the active ingredient. After that, the extract from which the active ingredient is extracted is not used as it is, but has a small molecular size that is easily absorbed into the pores of the ceramic chip. A separate distillation process is performed to collect the components of

자세하게는, 유효성분이 추출된 추출액 1L당 정제수 2~4L를 가하여 희석한 후, 증류기에서 가열하여 증류액을 얻는 단계를 통하여 제조되는 것이 바람직하다. 자세하게는, 증류기를 먼저 350~450℃로 가열한 후, 가열된 증류기에서 증류액이 한방울씩 떨어지기 시작하면 온도를 250도로 낮추어 증류 과정을 8~12시간 동안 계속하여 최종적으로 2~4L의 증류액을 얻을 수 있다. Specifically, it is preferable to prepare through a step of diluting by adding 2-4 L of purified water per 1 L of the extract from which the active ingredient is extracted, and then heating in a distiller to obtain a distillate. In detail, after heating the distiller to 350~450℃ first, when the distillate starts to fall drop by drop from the heated distiller, lower the temperature to 250℃ and continue the distillation process for 8~12 hours, finally distilling 2~4L liquid can be obtained.

이와 같이 준비된 증류액을 세라믹 칩 표면에 분사 후 건조하여 최종적으로 사용할 수 있다. 분사량은 세라믹 칩 표면에 유효성분이 골고루 입혀질 수 있을 만큼 분사한다. 이와 같이 제조된 세라믹칩은 칩의 테두리를 따라 그래핀 패턴이 형성되도록 원단 상에 접착제 등 다양한 방식으로 고정되게 된다. The distillate prepared in this way can be finally used by spraying it on the surface of the ceramic chip and drying it. The amount of spraying is enough to evenly coat the active ingredient on the surface of the ceramic chip. The ceramic chip manufactured in this way is fixed on the fabric in various ways, such as with an adhesive, so that a graphene pattern is formed along the edge of the chip.

이하, 본 발명의 일 실시예를 통해 본 발명의 구체적인 작용과 효과를 설명하고자 한다. 다만, 이는 본 발명의 바람직한 예시로서 제시된 것으로, 실시예에 따라 본 발명의 권리범위가 한정되는 것은 아니다. Hereinafter, specific actions and effects of the present invention will be described through an embodiment of the present invention. However, this is presented as a preferred example of the present invention, and the scope of the present invention is not limited according to the embodiments.

[실시예][Example]

원단 상에 유기용제 100 중량부에 대하여 그래핀 80 중량부 및 산화아연 3 중량부가 포함된 유성잉크로 코팅하고, 150℃에서 120초 동안 열처리 하여 원단 상에 육각 패턴을 형성하였다.An oil-based ink containing 80 parts by weight of graphene and 3 parts by weight of zinc oxide based on 100 parts by weight of the organic solvent was coated on the fabric, and heat-treated at 150° C. for 120 seconds to form a hexagonal pattern on the fabric.

황토 100 중량부에 쑥 분말, 상엽 분말 및 송엽 분말이 동일 중량비로 혼합된 천연물 분말 40 중량부, 그래핀 분말 7 중량부, 석분 3 중량부 및 실리콘 아크릴 중합체 70 중량% 및 폴리비닐 아세테이트 30 중량%를 포함하는 접착제 20 중량부를 혼합하여 반죽을 제조하였다. 제조된 반죽을 성형기에 넣고 육각 칩 형태로 성형한 후, 성형된 세라믹 칩을을 300℃ 에서 30분 동안 건조하여 고형화하였다. 40 parts by weight of natural product powder, 7 parts by weight of graphene powder, 3 parts by weight of stone powder, 70% by weight of silicone acrylic polymer and 30% by weight of polyvinyl acetate A dough was prepared by mixing 20 parts by weight of an adhesive containing The prepared dough was put in a molding machine and molded into hexagonal chips, and then the molded ceramic chips were dried at 300° C. for 30 minutes to solidify.

상기 제조된 세라믹 칩의 테두리가 원단 상의 육각형 패턴 상에 오도록 위치시킨 후 접착제로 제조하여 세라믹 칩이 구비된 원단을 제조하여 도 1,2에 도시하였다. After positioning the edges of the manufactured ceramic chips to come on a hexagonal pattern on the fabric, the fabric was prepared with an adhesive to prepare a fabric equipped with the ceramic chips, as shown in FIGS. 1 and 2 .

상기 제조된 원단의 수맥인체장해 방지시험 및 전자파인체장해 방지시험을 수행한 결과, 인체에 유해한 수맥에너지 및 유해 전자파를 차폐 방지하는 것으로 확인되었다.As a result of performing the test for preventing human body disturbance and electromagnetic wave of the fabric prepared above, it was confirmed that the shielding prevention of water vein energy and harmful electromagnetic waves harmful to the human body was performed.

본 발명은 상술한 특정의 실시예 및 설명에 한정되지 아니하며, 청구범위에서 청구하는 본 발명의 요지를 벗어남이 없이 당해 발명이 속하는 기술 분야에서 통상의 지식을 가진 자라면 누구든지 다양한 변형 실시가 가능하며, 그와 같은 변형은 본 발명의 보호 범위 내에 있게 된다.The present invention is not limited to the specific embodiments and descriptions described above, and without departing from the gist of the present invention claimed in the claims, any person skilled in the art to which the invention pertains can implement various modifications and such modifications shall fall within the protection scope of the present invention.

Claims (4)

원단의 일측에 형성된 그래핀 패턴; 및 상기 그래핀 패턴 상에 위치하며, 황토 100 중량부를 기준으로 천연물 분말 30~50 중량부, 그래핀 분말 5~10 중량부, 충진제 1~5 중량부 및 접착제 15~20 중량부를 포함하는 세라믹 칩;을 포함하며, 상기 세라믹 칩의 테두리를 따라 그래핀 패턴이 형성되고,
상기 천연물 분말은 쑥 분말 30~40 중량%, 상엽 분말 30~40 중량% 및 송엽 분말 30~40 중량%를 포함하며, 상기 접착제는 실리콘 아크릴 중합체 60~80 중량% 및 폴리비닐 아세테이트 20~40중량%를 포함하고,
상기 세라믹 칩에 포한되는 그래핀 분말은 사이클로덱스트린에 포접된 그래핀이며,
상기 접착제는 아교 및 글리세린을 추가로 포함하고, 상기 아교의 함량은 황토 100 중량부를 기준으로 1~5 중량부이며, 상기 글리세린의 함량은 아교 100 중량부를 기준으로 1~10 중량부이고,
상기 세라믹 칩은 쑥, 편백나무 및 솔입의 천연물 추출액을 표면에 분사처리한 후 건조된 것임을 특징으로 하는 그래핀 패턴과 세라믹 칩이 구비된 원단.
a graphene pattern formed on one side of the fabric; and a ceramic chip positioned on the graphene pattern and comprising 30-50 parts by weight of natural product powder, 5-10 parts by weight of graphene powder, 1-5 parts by weight of a filler, and 15-20 parts by weight of an adhesive based on 100 parts by weight of loess including; a graphene pattern is formed along the edge of the ceramic chip,
The natural product powder includes 30-40 wt% of mugwort powder, 30-40 wt% of upper leaf powder, and 30-40 wt% of pine leaf powder, and the adhesive is 60-80 wt% of silicone acrylic polymer and 20-40 wt% of polyvinyl acetate including %,
The graphene powder contained in the ceramic chip is graphene encapsulated in cyclodextrin,
The adhesive further comprises glue and glycerin, the content of the glue is 1 to 5 parts by weight based on 100 parts by weight of loess, the content of the glycerin is 1 to 10 parts by weight based on 100 parts by weight of the glue,
The ceramic chip is a fabric provided with a graphene pattern and ceramic chip, characterized in that it is dried after spraying the natural extracts of mugwort, cypress and cypress on the surface.
삭제delete 삭제delete 삭제delete
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