KR102304499B1 - Method for preparing functional fabric material containing germanium - Google Patents
Method for preparing functional fabric material containing germanium Download PDFInfo
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- KR102304499B1 KR102304499B1 KR1020200031844A KR20200031844A KR102304499B1 KR 102304499 B1 KR102304499 B1 KR 102304499B1 KR 1020200031844 A KR1020200031844 A KR 1020200031844A KR 20200031844 A KR20200031844 A KR 20200031844A KR 102304499 B1 KR102304499 B1 KR 102304499B1
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic System; Titanates; Zirconates; Stannates; Plumbates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/59—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with ammonia; with complexes of organic amines with inorganic substances
- D06M11/61—Liquid ammonia
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
Abstract
Description
본 발명은 게르마늄을 분말이 아닌 완전한 용액으로 용융하는 방법과 이를 이용하여 제조된 게르마늄 용액이 함유된 섬유원단의 제조방법에 관한 것으로서, 보다 상세하게는 섬유원단에 게르마늄 분말 또는 게르마늄 분말이 함유된 수용액을 단순히 코팅하는 것이 아닌, 게르마늄을 완전히 용융시켜 그 원자 하나하나를 섬유에 침지시켜 항균성 및 내취성의 기능이 향상된 기능성 섬유원단의 제조방법에 관한 것이다.The present invention relates to a method of melting germanium into a complete solution, not a powder, and a method for manufacturing a textile fabric containing a germanium solution prepared using the same, and more particularly, to an aqueous solution containing germanium powder or germanium powder in the textile fabric. It relates to a method for manufacturing a functional textile fabric with improved antibacterial and brittle properties by immersing each atom in the fiber by completely melting germanium, rather than simply coating it.
일반적으로 게르마늄은 회백색의 금속원소로서 일반적으로 게르마늄은 회백색의 금속 원소로서, 부스러지기 쉬우며, 황화 광물을 제련하거나 석탄을 태울 때 부산물로 얻을 수 있고, 특수한 조건에서만 금속으로서의 물리·화학적 성질을 나타내는 반도체이며, 반도체 소자, 트랜지스터,광학 유리, 각종 합금 따위의 주요 재료로 쓰인다.In general, germanium is a grayish-white metallic element. In general, germanium is a grayish-white metallic element that is easily brittle, can be obtained as a by-product when smelting sulfide minerals or burning coal, and exhibits physical and chemical properties as a metal only under special conditions. It is a semiconductor and is used as a major material for semiconductor devices, transistors, optical glass, and various alloys.
게르마늄은 원적외선과 음이온을 방출하기 때문에 항균 및 방취 효과가 뛰어남에 따라 인체에 유해한 세균을 없애 무좀이나 땀띠 등을 예방하는데 탁월하다. 그리고 신체와 근접하게 되면 그 외곽전자가 침투압으로 인해 신체의 피하조직 속의 모세혈관까지 침투됨에 따라 혈관 속에 있는 전자를 이동시켜 혈액을 정화하여 정상화시키며 통증도 완화시키는 효과가 있다.Since germanium emits far-infrared rays and negative ions, it has excellent antibacterial and deodorizing effects, so it is excellent for preventing athlete's foot and sweat bands by eliminating harmful bacteria to the human body. And when it comes close to the body, the outer electrons penetrate to the capillaries in the subcutaneous tissue of the body due to the penetrating pressure.
이에 따라 종래에 게르마늄 등의 광물질을 직물에 혼합하여 항균성 및 항취성 등의 섬유를 제조하는 방법이 다양하게 시도되어 왔다. 그러나 상기와 같은 게르마늄 및 광물질 등을 이용하여 직물을 제조할 때에 피부가 민감한 사람들한테는 피부염, 알레르기 등과 같은 피부트러불 같은 부작용이 발생할 가능성이 높아, 이를 방지하려는 기술도 다양하게 시도되고 있다.Accordingly, in the prior art, various methods have been tried to prepare fibers having antibacterial and anti-brittle properties by mixing a mineral material such as germanium with a fabric. However, when manufacturing a fabric using germanium and minerals as described above, side effects such as skin troubles such as dermatitis and allergies are highly likely to occur to people with sensitive skin, and various techniques for preventing this are being attempted.
게다가 게르마늄을 섬유에 혼합시키는 종래의 기술에서는 게르마늄 분말을 섬유와 혼합하는 방법에 있어서, 게르마늄 분말을 코팅제와 섞어 섬유에 코팅하는 방식으로 혼합하기 때문에 게르마늄 성분과 섬유가 강한 결합력을 통하여 고정되어 있는 것이 아니라, 물리적인 압력 등으로 단순히 함유되어 있기 때문에 게르마늄이 함유된 섬유를 몇 번만 세탁하여도 게르마늄 성분이 섬유에서 이탈되어 상기와 같은 항균성 등의 효과가 오랫동안 지속되지 않는다는 문제점이 있다.In addition, in the conventional technique of mixing germanium into fibers, in the method of mixing germanium powder with fibers, germanium powder is mixed with a coating agent and mixed by coating the fibers, so that the germanium component and the fibers are fixed through a strong bonding force. Rather, since it is simply contained under physical pressure, etc., there is a problem that the germanium component is separated from the fiber even if the fiber containing germanium is washed only a few times, so that the effect such as antibacterial property as described above does not last for a long time.
상기와 같은 문제점을 해결하기 위하여 본 발명자들은 게르마늄을 분말화하여 단순히 물리적으로 섬유에 고정시키는 것이 아닌, 게르마늄을 완전히 용융시킨 게르마늄 용액을 섬유에 침지하는 방법을 통하여 게르마늄과 섬유를 강한 결합력을 이용하여 고정시킴으로써 게르마늄이 섬유에서 이탈되는 것을 방지한 것으로서, 본 발명에서 제공하는 게르마늄 성분이 함유된 섬유원단은 다수에 걸쳐 세탁을 하더라도 게르마늄에 섬유에 단단하게 고정되어 있어서 섬유의 항균성, 항취성 등의 효과가 반영구적으로 지속될 수 있다.In order to solve the above problems, the present inventors did not simply physically fix germanium to the fiber by pulverizing germanium, but by immersing the germanium solution in which germanium was completely melted into the fiber by using strong bonding force between germanium and the fiber. By fixing, germanium is prevented from being separated from the fiber, and the fiber fabric containing germanium component provided in the present invention is firmly fixed to the germanium fiber even after washing many times, so the effect of antibacterial and anti-brittle properties of the fiber can be semi-permanent.
본 발명은 상기와 같은 문제점을 해결하기 위한 것으로서, 본 발명에서는 게르마늄 성분과 섬유를 강한 결합력으로 고정하기 위하여 게르마늄 분말이 아닌 게르마늄을 완전히 용융한 게르마늄 수용액을 이용하여 섬유에 고정시키고, 또한 게르마늄 등 광물이 함유된 섬유의 부작용을 최소화하기 위해서 특정한 첨가제를 더 첨가함으로써 본 발명을 완성하게 되었다.The present invention is to solve the above problems, and in the present invention, in order to fix the germanium component and the fiber with a strong bonding force, it is fixed to the fiber using an aqueous solution of germanium in which germanium is completely melted, not germanium powder, and also minerals such as germanium The present invention was completed by further adding specific additives in order to minimize the side effects of the fibers contained therein.
상기한 과제를 달성하기 위하여 본 발명에서 제공하는 게르마늄이 함유된 섬유직물의 제조방법은 종래의 대부분의 기술에서 주로 사용되었었던 게르마늄 분말을 이용하여 섬유에 단순히 코팅하는 방법에 아닌 게르마늄을 완전히 용융시킨 게르마늄 용액을 바인더를 이용하여 섬유에 침지시키는 방법을 이용함으로써 본 기술을 완성하게 되었다.In order to achieve the above object, the method for manufacturing a textile fabric containing germanium provided by the present invention is a method of completely melting germanium rather than simply coating the fibers using germanium powder, which has been mainly used in most conventional techniques. This technique was completed by using a method of immersing a germanium solution in a fiber using a binder.
또한, 게르마늄 성분이 유발할 수 있는 부작용을 최소화하기 위해서 본 발명에서 제공하는 게르마늄 성분이 함유된 섬유원단은 사포닌 성분을 더 첨가함으로써 게르마늄 섬유가 피부에 미치는 부작용을 최소화할 수 있었다.In addition, in order to minimize the side effects that may be caused by the germanium component, the fiber fabric containing the germanium component provided in the present invention was able to minimize the side effect of the germanium fiber on the skin by further adding a saponin component.
본 발명에서 제공하는 게르마늄 성분이 함유된 섬유원단은 게르마늄과 섬유가 강한 결합력으로 고정되어 있어서, 본 발명에서 제공하는 섬유원단을 이용하여 제조한 제품을 다수회에 걸쳐서 세탁을 하더라도 게르마늄 성분이 섬유에 그대로 고착되어 있어서 항균성, 항취성 등의 우수한 기능이 반 영구적으로 유지될 수 있다. 또한, 사포닌을 더 첨가함으로써 피부가 민감한 사람들에게 발생할 수 있는 알레르기, 피부염 등의 피부트러불이 발생하는 것을 방지할 수 있다.In the textile fabric containing the germanium component provided in the present invention, germanium and the fiber are fixed by a strong bonding force, so even if the product manufactured using the textile fabric provided in the present invention is washed a number of times, the germanium component is not attached to the fiber. As it is fixed as it is, excellent functions such as antibacterial and anti-brittle properties can be semi-permanently maintained. In addition, by adding more saponin, it is possible to prevent skin troubles such as allergies and dermatitis that may occur in people with sensitive skin.
이하에서는 본 발명에서 제공하고자 하는 게르마늄이 함유된 섬유원단의 제조방법에 대해서 자세히 설명한다.Hereinafter, a method for manufacturing a textile fabric containing germanium to be provided by the present invention will be described in detail.
본 발명에서 제공하는 게르마늄 성분이 함유된 섬유원단을 제조하는 방법은 다음의 단계로 이루어진다.The method for manufacturing a textile fabric containing germanium component provided by the present invention consists of the following steps.
게르마늄을 졸-겔 방법을 적용하여 게르마늄 수용액을 제조하는 단계;preparing an aqueous solution of germanium by applying a sol-gel method to germanium;
상기 게르마늄 수용액에 섬유원단 및 바인더 화합물을 첨가하여 반응시키는 단계 및 상기 단계의 반응물을 가열하여 게르마늄을 섬유에 고착한 후에 세척하고 섬유원단을 수득하는 단계 및 상기 섬유원단을 냉각시키는 단계로 이루어진다.It consists of a step of reacting by adding a fiber fabric and a binder compound to the germanium aqueous solution, and a step of heating the reactant in the step to fix germanium to the fiber, washing and obtaining a fiber fabric, and cooling the fiber fabric.
본 발명에서 제공하는 게르마늄 성분이 함유된 섬유원단을 제조하기 위해서는 상기 단계에서 게르마늄을 단순히 분말화하는 것이 아닌 완전히 용융시켜 게르마늄 수용액으로 제조하는 것이 중요하다.In order to manufacture the fabric containing the germanium component provided in the present invention, it is important to completely melt the germanium in the above step, rather than simply powdering it, to prepare a germanium aqueous solution.
상기 바인더 화합물로서는 수계 폴리에스터, 아크릴에멀젼 또는 폴리우레탄고분자 등이 사용될 수 있고, 상기 게르마늄 수용액과 바인더 화합물을 첨가한 후에 25 내지 30℃에서 2 내지 3시간 동안 교반하여 반응시킨다. 상기 단계에서 게르마늄 수용액과 바인더 화합물의 중량비는 게르마늄 수용액 100 중량부당 바인더 화합물 200 내지 300 중량부를 혼합하는 것이 바람직하다.As the binder compound, water-based polyester, acrylic emulsion or polyurethane polymer may be used, and after the germanium aqueous solution and the binder compound are added, the mixture is reacted by stirring at 25 to 30° C. for 2 to 3 hours. In the above step, the weight ratio of the germanium aqueous solution and the binder compound is preferably 200 to 300 parts by weight of the binder compound per 100 parts by weight of the germanium aqueous solution.
상기 게르마늄 수용액과 바인더 화합물을 반응시킨 후에 가열하고 급냉각하는 단계는 180 내지 200℃ 에서 10 내지 20분간 가열한 후에 20 내지 25℃의 수조에서 급냉각시키는 단계이다.The step of heating and rapid cooling after reacting the germanium aqueous solution with the binder compound is a step of heating at 180 to 200 °C for 10 to 20 minutes and then rapidly cooling in a water bath of 20 to 25 °C.
본 발명의 또 다른 실시예로서는 상기 게르마늄 수용액과 바인더 화합물을 혼합하는 단계에서 게르마늄 수용액 100중량부 대비 10 내지 50 중량부의 사포닌을 더 추가하여 반응시킬 수 있다.In another embodiment of the present invention, in the step of mixing the germanium aqueous solution and the binder compound, 10 to 50 parts by weight of saponin may be further added to react with 100 parts by weight of the germanium aqueous solution.
상기 사포닌은 종래의 게르마늄, 제올라이트 등의 분말이 첨가된 기능성 섬유에서 발생할 수 있는 알레르기, 피부염 등을 방지하기 위한 것으로서, 사포닌을 더 추가함으로써 민감성 피부를 가진 사람들에게 발생하는 피부 트러블을 현저하게 감소시킬 수 있다.The saponin is to prevent allergies, dermatitis, etc. that may occur in functional fibers to which powders such as germanium and zeolite are added. can
본 발명에서 제공하는 게르마늄을 완전히 용융시켜 게르마늄 수용액을 제조하는 방법은 졸-겔 방법을 적용하여 완전한 수용액으로 제조하는 것이고 그 방법은 다음의 단계를 통하여 이루어진다.The method for preparing a germanium aqueous solution by completely melting germanium provided in the present invention is to prepare a complete aqueous solution by applying the sol-gel method, and the method is made through the following steps.
고체인 게르마늄과 염산을 반응시켜 염화게르마늄을 제조하는 단계 및 상기 염화 게르마늄 용액에 수산화암모니아 용액을 첨가하여 반응시켜 수산화 게르마늄 수용액을 제조하는 단계로 이루어진다.It consists of a step of preparing germanium chloride by reacting solid germanium with hydrochloric acid, and preparing an aqueous solution of germanium hydroxide by adding an ammonia hydroxide solution to the germanium chloride solution and reacting it.
상기의 게르마늄 용융 과정 수산화암모니아 용액을 첨가하는 단계는 그 전 단계에서 생성된 염화게르마늄 용액이 산성이므로, 알카리성인 수산화 암모니아를 반응시켜 반응액을 중성으로 유지하기 위함이다.In the step of adding the ammonia hydroxide solution in the germanium melting process, since the germanium chloride solution generated in the previous step is acidic, alkaline ammonia hydroxide is reacted to maintain the reaction solution neutral.
상기의 과정을 거쳐서 수산화 게르마늄이 생성되고, 암모니아 기체와 이산화탄소가 발생해 증발되며, 용액에는 게르마늄과 염소이온이 존재하게 된다. 이러한 과정을 통해서 본 발명에서 제공하는 완전히 용융된 게르마늄 용액을 준비할 수 있다.Through the above process, germanium hydroxide is generated, ammonia gas and carbon dioxide are generated and evaporated, and germanium and chlorine ions are present in the solution. Through this process, the completely molten germanium solution provided in the present invention can be prepared.
보다 구체적으로는 상기 염화 게르마늄을 제조하는 단계는 게르마늄 100 중량부당 10% 염산 수용액 200 내지 300 중량부를 혼합하여 게르마늄을 가수분해하는 공정이고, 다음 단계로서 상기 반응물에 200 내지 300중량부의 수산화 암모니아용액을 첨가하여 반응시킴으로써 수산화 게르마늄을 수득할 수 있다.More specifically, the step of preparing germanium chloride is a process of hydrolyzing germanium by mixing 200 to 300 parts by weight of a 10% aqueous hydrochloric acid solution per 100 parts by weight of germanium, and as the next step, 200 to 300 parts by weight of ammonia hydroxide solution in the reactant. By adding and reacting, germanium hydroxide can be obtained.
본 발명에서 제공하는 게르마늄이 함유된 섬유원단의 제조방법은 위에서 수득된 수산화 게르마늄을 유효 성분으로 사용한다.The method for manufacturing a textile fabric containing germanium provided in the present invention uses germanium hydroxide obtained above as an active ingredient.
상기의 과정을 통해서 본 발명에서 제공하는 게르마늄은 분말상태가 아닌 완전한 용액상태로 전환시킬 수 있고, 용액상태로 전환된 게르마늄을 바인더 화합물을 이용하여 섬유와 반응시킴으로써 상기 게르마늄은 섬유에 강력하게 고정될 수 있다.Through the above process, germanium provided in the present invention can be converted into a complete solution state rather than a powder state, and by reacting the germanium converted into a solution state with the fiber using a binder compound, the germanium can be strongly fixed to the fiber. can
이하 본 발명에서 제공하는 게르마늄이 함유된 섬유원단의 제조방법을 구체적인 실시예를 이용하여 설명하나, 본 발명의 범주가 하기의 실시예에 한정되지 않는다는 것은 통상의 기술자에게는 당연한 것이다.Hereinafter, the manufacturing method of the germanium-containing textile fabric provided by the present invention will be described using specific examples, but it is natural for those skilled in the art that the scope of the present invention is not limited to the following examples.
<실시예><Example>
게르마늄 10g을 10% 염산 수용액 25g과 혼합하여 반응시켜 염화 게르마늄 수용액 35g을 얻었다. 상기 수용액을 액적상태로 가하면서 동시에 수산화 암모니아용액 20g을 액적상태로 첨가하면서 교반하여 반응시켜 최종적으로 수산화 게르마늄을 포함하는 수용액 55g을 수득하였다.10 g of germanium was mixed with 25 g of a 10% aqueous hydrochloric acid solution and reacted to obtain 35 g of an aqueous solution of germanium chloride. While adding the aqueous solution in a droplet state, at the same time 20 g of an ammonia hydroxide solution was added in a droplet state and stirred to react, finally 55 g of an aqueous solution containing germanium hydroxide was obtained.
섬유원단을 물에 담지하고, 상기 과정을 통해서 수득된 수산화 게르마늄을 포함하는 수용액과 바인더 화합물로서 아크릴 에멀젼 200g을 혼합한 후에 25℃에서 3시간 동안 반응시킨 후, 상기 혼합물을 180℃에서 20분간 가열한 후에 섬유원단만을 남기고 용액을 버린 후에 상기 섬유원단을 20℃수조에서 급냉각시켰다. The fiber fabric is supported in water, and 200 g of an acrylic emulsion as a binder compound is mixed with an aqueous solution containing germanium hydroxide obtained through the above process, and then reacted at 25° C. for 3 hours, and then the mixture is heated at 180° C. for 20 minutes. After discarding the solution leaving only the fabric, the fabric was rapidly cooled in a water bath at 20°C.
상기의 과정을 통해서 수득된 섬유원단에는 게르마늄 이온이 섬유의 사이사이에 견고하게 고정되고, 이러한 과정을 통하여 게르마늄이 함유된 섬유원단을 수득하였다.In the fabric obtained through the above process, germanium ions were firmly fixed between the fibers, and through this process, a fabric containing germanium was obtained.
상기의 과정을 통하여 수득된 본 발명에서 제공하는 게르마늄이 함유된 섬유원단은 각종 스포츠의류, 모자, 안대, 스카프 등으로 제조될 수 있고, 또한 다양한 종류의 내의로도 제조될 수 있다.The textile fabric containing germanium provided in the present invention obtained through the above process may be manufactured into various sports clothing, hats, eye patches, scarves, etc., and may also be manufactured into various types of underwear.
본 발명에서 제공하는 게르마늄이 함유된 섬유원단을 이용하여 제조된 의류를 착용한 상태에서 혈장 젖산 및 산화질소의 방출량을 시험하였다.Plasma lactic acid and nitric oxide emissions were tested while wearing clothes manufactured using the germanium-containing fabric provided by the present invention.
본 발명에서 제공하는 섬유원단을 이용하여 제조된 의류를 착용한 상태(실험군)와 일반의류를 착용한 상태(대조군)에서 1시간 동안 운동한 후에 발생하는 혈장 젖산의 변화(표 1) 및 혈장 산화질소의 변화(표 2)를 대비하였다.Changes in plasma lactic acid (Table 1) and plasma oxidation occurring after exercise for 1 hour in the state wearing clothes manufactured using the textile fabric provided in the present invention (experimental group) and wearing general clothes (control group) Changes in nitrogen (Table 2) were compared.
(혈장 젖산의 변화)(changes in plasma lactate)
(혈장 산화질소의 변화)(changes in plasma nitric oxide)
상기 표 1로부터 본 발명에서 제공하는 섬유원단을 이용하여 제조한 의복을 착용하고 운동한 후에는 일반 의복을 착용한 후보다 젖산 수치가 현저히 낮은 것으로 나타나 몸의 피로도를 현저히 감소시킬 수 있고, 상표 표 2로부터 본 발명에서 제공하는 섬유원단을 이용하여 제조한 의복을 착용한 후에는 혈액량의 증가로 혈류가 현저하게 증가된다는 것을 알 수 있다.From Table 1 above, after wearing clothes manufactured using the textile fabric provided in the present invention and exercising, the lactic acid level was significantly lower than after wearing general clothes, so that fatigue of the body can be significantly reduced. From 2, it can be seen that the blood flow is significantly increased due to an increase in blood volume after wearing the clothes manufactured using the textile fabric provided by the present invention.
또한 본 발명에서 제공하는 방법을 통하여 제된 게르마늄이 함유된 섬유원단(실시예)이 다수의 세척과정을 거친 후에서 상기 게르마늄이 섬유에 강력하게 고정되어 있는 지를 확인하기 위하여 종래의 게르마늄을 코팅하는 방식을 이용하여 제조된 섬유원단(비교예)과 세척 후의 게르마늄에서 방사되는 평균 방사율을 측정하였다(표 3).In addition, the conventional method of coating germanium in order to check whether the germanium-containing fiber fabric (Example) prepared through the method provided in the present invention is strongly fixed to the fiber after going through a number of washing processes. The average emissivity spun from the fabric (Comparative Example) and germanium after washing was measured (Table 3).
(본 발명의 섬유원단과 일반 게르마늄 원단의 평균 방사율 측정)(Measurement of average emissivity of textile fabric of the present invention and general germanium fabric)
상기의 결과에 나타난 바와 같이, 본 발명에서 제공하는 게르마늄 함유 섬유원단을 종래의 게르마늄 원단과 달리 다수의 세척과정을 거친 후에서 섬유 내에 포함되어 있는 게르마늄이 거의 일정하게 유지되고 있다는 것을 알 수 있다. 이는 본 발명에서 제공하는 게르마늄 성분을 섬유에 침지시키는 과정이 종래의 기술보다 우수하다는 것을 나타낸다.As shown in the above results, it can be seen that after the germanium-containing fiber fabric provided in the present invention undergoes a number of washing processes, unlike the conventional germanium fabric, the germanium contained in the fiber is maintained almost constantly. This indicates that the process of immersing the germanium component provided in the present invention into the fiber is superior to the prior art.
본 발명은 산업상 이용가능하다.The present invention is industrially applicable.
Claims (3)
a) 게르마늄과 염산을 반응시켜 게르마늄을 가수분해하여 염화 게르마늄을 제조하는 단계; 상기 단계에서 수득된 용액에 수산화암모니아 용액 첨가하여 반응시켜 수산화 게르마늄 수용액을 제조하는 단계;
b) 섬유원단과 상기 단계에서 수득된 수산화 게르마늄 수용액 100 중량부당 바인더 화합물을 200 내지 300 중량부를 혼합하여 반응시키는 단계; 상기 단계의 반응물을 180 내지 200℃에서 10 내지 20분 동안 가열하여 게르마늄을 섬유원단에 고착한 후 반응액을 제거하는 단계; 상기 단계에서 수득된 섬유원단을 20 내지 25℃의 수조에서 냉각하여 세척하는 단계;로 이루어지며,
상기 a)단계의 게르마늄 수용액을 제조하는 방법은 게르마늄 100 중량부당 10% 염산 수용액 200 내지 300 중량부를 혼합하여 게르마늄을 가수분해한 후에 게르마늄 100 중량부당 200 내지 300 중량부의 수산화 암모니아 용액을 첨가하여 반응시키는 것으로 이루어지고,
상기 b)단계에서의 바인더 화합물은 수계 폴리에스터 및 폴리우레탄고분자로 이루어지는 군에서 선택되는 어느 하나인 것을 특징으로 하는 게르마늄 성분이 함유된 섬유원단을 제조하는 방법
It relates to a method for manufacturing a fabric containing germanium component, the manufacturing method comprising;
a) reacting germanium with hydrochloric acid to hydrolyze germanium to prepare germanium chloride; preparing an aqueous solution of germanium hydroxide by adding an ammonia hydroxide solution to the solution obtained in the above step and reacting;
b) reacting the fiber fabric with 200 to 300 parts by weight of a binder compound per 100 parts by weight of the germanium hydroxide aqueous solution obtained in the above step; removing the reaction solution after fixing the germanium to the fiber fabric by heating the reactant of the above step at 180 to 200° C. for 10 to 20 minutes; The step of washing and cooling the fiber fabric obtained in the above step in a water bath of 20 to 25 ℃; consists of,
The method for preparing the germanium aqueous solution of step a) involves hydrolyzing germanium by mixing 200 to 300 parts by weight of a 10% aqueous hydrochloric acid solution per 100 parts by weight of germanium, and then adding 200 to 300 parts by weight of ammonia hydroxide solution per 100 parts by weight of germanium to react made up of
The binder compound in step b) is a method for producing a textile fabric containing a germanium component, characterized in that any one selected from the group consisting of water-based polyester and polyurethane polymer
According to claim 1, wherein in the step of mixing and reacting the fiber fabric, the germanium hydroxide aqueous solution and the binder compound, 10 to 50 parts by weight of saponin is further added per 100 parts by weight of the germanium aqueous solution. how to manufacture
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| KR20020072253A (en) | 2002-03-30 | 2002-09-14 | (주)성호바이오텍 | Multi-Functional Coating Compositions and Textiles Coated with the Same |
| KR101081856B1 (en) | 2008-12-30 | 2011-11-09 | 김순옥 | Mineral material is included manufacture method of material |
| CN108360254A (en) * | 2018-04-25 | 2018-08-03 | 宁波大千纺织品有限公司 | A kind of functionality anti-fatigue health-caring knitting fabric and preparation method thereof |
| KR101932894B1 (en) * | 2018-10-15 | 2018-12-26 | 김은봉 | Method for mamufacturing water-soluble germanium-containing functional plastic raw material and product using the functional plastic produced thereby |
| KR20190110296A (en) * | 2018-03-20 | 2019-09-30 | 지용태 | Whole fabric radiating far-infrared ray and manufacturing process thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR20020072253A (en) | 2002-03-30 | 2002-09-14 | (주)성호바이오텍 | Multi-Functional Coating Compositions and Textiles Coated with the Same |
| KR101081856B1 (en) | 2008-12-30 | 2011-11-09 | 김순옥 | Mineral material is included manufacture method of material |
| KR20190110296A (en) * | 2018-03-20 | 2019-09-30 | 지용태 | Whole fabric radiating far-infrared ray and manufacturing process thereof |
| CN108360254A (en) * | 2018-04-25 | 2018-08-03 | 宁波大千纺织品有限公司 | A kind of functionality anti-fatigue health-caring knitting fabric and preparation method thereof |
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