KR102206765B1 - Fragrance composition recreating natural Tricholoma matsutake fragrance - Google Patents

Abstract

The present invention is an active ingredient of octenol (1-octen-3-ol), 3-octanol (3-Octanol), 3-octanone (3-Octanone), methyl cinnamate (Methyl cinnamate), aldehyde C9 (( Aldehyde C9), pine needle oil, cinnamon oil, and a fragrance composition that reproduces the natural matsutake scent comprising a pine needle extract, and the fragrance composition according to the present invention is a natural matsutake by newly blending specific artificial synthetic substances and natural substances. It is possible to similarly reproduce the unique flavor of mushrooms, and to provide a fragrance composition having a richer flavor.

Description

Fragrance composition recreating natural Tricholoma matsutake fragrance}

The present invention relates to a perfume composition that reproduces the natural pine mushroom flavor, and more particularly, octenol (1-octen-3-ol), 3-octanol (3-Octanol), 3-octanone (3-Octanone) ), methyl cinnamate, aldehyde C9 ((Aldehyde C9), pine needle oil, cinnamon oil, and a fragrance composition that reproduces the fragrance of natural matsutake mushrooms containing as active ingredients.

There are about 1,000 kinds of edible mushrooms around the world, and about 20 kinds of mushrooms are subject to cultivation. Mushrooms grown the most in the world are mushrooms, followed by oyster mushrooms, wood ear mushrooms, and shiitake mushrooms. Demand for mushrooms is increasing every year, and among them, natural matsutake is drawing attention because it is good for health along with preference for its unique aroma, taste, and chewing texture.

Matsutake mushrooms are a type of fungus that grows naturally in damp places due to the accumulation of fallen leaves under pine trees in autumn. There are cultivated mushrooms and wild mushrooms. It is most often produced from September to October. When the mushrooms are medium-sized, the inside is white, the stem is elastic, and the scent is strong. The life of pine mushrooms lies in the scent and texture. In particular, the scent of matsutake mushrooms is characterized by having a unique scent that further includes methyl cinnamate, which is distinguished from other mushrooms, starting with octenol (1-octen-3-ol), the main component.

In general, solvent extraction and steam distillation were frequently used as analysis methods capable of reproducing the scent of natural matsutake mushrooms having such a unique scent. In addition, there are head space, aqua space, solid phase micro extraction method, and supercritical fluid extraction method. However, since high heat is applied to extract the conventional natural fragrance, there is a problem in that accurate component analysis is difficult due to the high loss of fragrance.

Meanwhile, Korean Patent No. 10-0465972 includes 3-octanol, 3-octanone, and methyl cinnamate, and cis-3- Perfume compositions containing hexenol (cis-3-hexenol) in a specific ratio are known. In addition, Korean Patent Registration No. 10-1455204 discloses a novel lipoxygenase-coding gene derived from domestic matsutake mushrooms involved in the biosynthesis of octenol (1-octen-3-ol), the main component of matsutake mushroom flavor. Enzymes, hydroperoxide lyase coding genes, and hydroperoxide lyases are known. However, as in the preceding literature, there was no example containing a pine mushroom extract directly in order to more excellently reproduce the aroma of pine mushrooms.

Accordingly, in the present invention, a fragrance composition that reproduces the scent of natural matsutake mushrooms that can be used as a fragrance for cosmetics or food additives and other household products is confirmed, and the present invention is completed. I did.

Domestic registration patent No. 10-0465972 (2005.01.03) Domestic Registration Patent No. 10-1455204 (2014.10.21)

The main object of the present invention is to provide a fragrance composition that reproduces the unique aroma of natural matsutake mushrooms through an appropriate and effective combination of a specific artificial synthetic substance and natural matsutake mushroom extract.

Another object of the present invention is to provide a cosmetic, food or food additive and other household products containing the perfume composition.

In order to achieve the above object, the present invention in one embodiment, octenol (1-octen-3-ol) 46-70% by weight, 3-octanol (3-Octanol) 1-2% by weight, 3- Octanone (3-Octanone) 0.1-1% by weight, methyl cinnamate (Methyl cinnamate) 20-30% by weight, aldehyde C9 (Aldehyde C9) 0.1-0.3% by weight, pine needle oil 6-8% by weight, cinnamon oil 0.1- It provides a fragrance composition comprising 0.6% by weight, and 1-25% by weight of the mushroom extract.

In addition, the present invention in another embodiment octenol (1-octen-3-ol) 46-61% by weight, 3-octanol (3-Octanol) 1-2% by weight, 3-octanone (3-Octanone) 0.1-1% by weight, 20-30% by weight of methyl cinnamate, 0.1-0.3% by weight of Aldehyde C9, 6-8% by weight of pine needle oil, 0.1-0.6% by weight of cinnamon oil, and chrysanthemum It provides a flavor composition comprising 10 to 25% by weight of mushroom extract.

In addition, the present invention provides cosmetics, foods or food additives and other household products containing the perfume composition.

The fragrance composition according to the present invention is reproducible similar to the unique fragrance of natural matsutake mushrooms by newly combining and blending specific artificial synthetic materials and natural materials, and it is possible to provide a fragrance composition having a richer fragrance.

In addition, the imitation scent of the natural matsutake can be used not only in the preparation of fragrances by itself, but also excellent in similarity and palatability of the scent when applied to various cosmetics, foods or food additives and household products including fragrances. Do.

The present invention is intended to illustrate and describe specific embodiments as various changes may be made and various embodiments may be provided.

However, this is not intended to limit the present invention to a specific embodiment, it is to be understood to include all changes, equivalents, and substitutes included in the spirit and scope of the present invention.

Hereinafter, the present invention will be described in detail.

The present invention relates to a perfume composition that reproduces the natural matsutake scent. More specifically, the present invention relates to a perfume composition that reproduces the unique fragrance of natural matsutake mushrooms through an appropriate and effective combination of a specific artificial synthetic substance and a natural substance.

In particular, the fragrance composition according to the present invention is reproducible similar to the unique fragrance of natural matsutake mushrooms, and by including a specific artificial synthetic material, it is possible to provide a fragrance composition having a richer fragrance. In addition, the natural matsutake scent can be used directly in the preparation of fragrances as such, as well as various cosmetics including fragrances (fragrance cosmetics, basic cosmetics, hair cosmetics, bath products, etc.), food or food additives ( When applied to flavor, sauce, juice, ice cream, candy, seasoning, spices, etc., the similarity and palatability of the scent are excellent.

The perfume composition according to the present invention is characterized in that it comprises octenol, 3-octanol, 3-octanone, methyl cinnamate, aldehyde C9, pine needle oil, cinnamon oil, and a mushroom extract.

Each of the constituents contained in the composition are components that make up the aroma of natural matsutake mushrooms, and may be obtained by artificially synthesizing each of them, but may also be obtained by extracting from natural matsutake mushrooms. Specifically, the methyl cinnamate is a main component material that accounts for 80 to 90% by weight of the fragrance component when extracting the fragrance of natural matsutake mushrooms, and each of 3-octanol, 3-octanone and octenol contains 0.2 to 2.5% by weight. These are the constituent substances that occupy. However, the present invention is not a fragrance composition reproduced by equally blending the substances extracted from the natural matsutake mushrooms with the component substances constituting the scent of the natural matsutake mushrooms, but combining a novel component substances and adjusting the contents thereof. By newly blending, a novel fragrance composition that reproduces the natural matsutake scent is provided.

Specifically, the composition in one embodiment octenol 46-70% by weight, 3-octanol 1-2% by weight, 3-octanone 0.1-1% by weight, methyl cinnamate 20-30% by weight, aldehyde C9 0.1 -0.3% by weight, pine needle oil 6-8% by weight, cinnamon oil 0.1-0.6% by weight, and a mushroom extract 1-25% by weight.

In addition, the composition in another embodiment is octenol 46-61% by weight, 3-octanol 1-2% by weight, 3-octanone 0.1-1% by weight, methyl cinnamate 20-30% by weight, aldehyde C9 0.1 -0.3% by weight, pine needle oil 6-8% by weight, cinnamon oil 0.1-0.6% by weight and consisting of 10-25% by weight of the mushroom extract.

In the composition, octenol, 3-octanol, 3-octanone, methyl cinnamate, aldehyde C9, pine needle oil, cinnamon oil, and champignon mushroom extract, which are the main ingredients for reproducing the natural matsutake flavor, are outside the above content range. When included, it is not preferable because the inherent odor and similarity of the natural matsutake mushroom and the palatability of the odor are lowered.

In particular, when the composition contains less than 1% by weight of the extract of matsutake mushrooms, the inherent smell, similarity and palatability of natural matsutake mushrooms may be inferior, and when the composition contains more than 25% by weight of the extract of matsutake mushrooms, natural matsutake The similarity and palatability of the mushrooms do not have a significant effect, so there is a problem in that economic efficiency is lowered due to the increase in the use of expensive mushrooms. Accordingly, the composition may preferably contain 1-25% by weight of the mushroom extract, but more preferably 10-25% by weight.

In addition, the composition further includes additional ingredients in addition to the main components constituting the natural matsutake scent, so that it is possible to provide a fragrance composition similar to the actual natural matsutake scent and having a richer scent. Although it may further contain certain additional ingredients, it can be used within a range that does not significantly affect the odor of natural matsutake mushrooms. As an additional component, a colorant, water, an organic solvent, and the like may be included therein.

On the other hand, champignon mushroom is a new variety of mushrooms breeding newly improved shiitake mushrooms, and the shape, meat quality, taste and scent are very similar to those of natural matsutake.

The champignon mushroom extract may be extracted by any one method selected from the group consisting of a solvent extraction method, a steam distillation method, a head space, aqua space, a solid phase micro extraction method, and a supercritical fluid extraction method, and preferably, aqua space ( It may be extracted by the Aqua Space method, but is not limited thereto.

In addition, in the present invention, the analysis method for the aroma component of natural pine mushrooms is not particularly limited, but a space (SPACE, Solid Phase Aroma Concentrate Extraction) method may be preferably used. The space method is a headspace scent component collection method in which fragrance components are adsorbed and analyzed by graphite carbon-based adsorbents, and is the latest analysis method used to capture, analyze, and reproduce scents similar to those when we directly sniff.

The composition reproduced according to the above can be used not only directly as a perfume, but also used in combination with cosmetics, food or food additives, household products and other industrial products base, and the blending amount is appropriately used by conventional techniques in the art. You can choose and mix. Specific examples include skin, lotion, essence, cream, shampoo, cleansing, shampoo, conditioner, hair cosmetics, fragrance, flavor, sauce, tea, beverage, candy, ice cream, sweets, jelly, seasoning, soap, dishwashing agent, laundry detergent , Detergent, softener, disinfectant, disinfectant, insect repellent, bleach, toothpaste, mouthwash, toilet paper and other additives to improve the use of medicines.

Hereinafter, the present invention will be described in more detail through examples and experimental examples, but the present invention is not limited thereto, and other applications and modifications of the present invention by those skilled in the art are possible.

Preparation Example 1. Preparation of pine mushroom extract

After cutting 300 g of champignon mushroom thickly and putting it into a round bottom flask container with a branch, the heated air from the top of the container flows at a flow rate of 2000 ml/min, and the fragrance is extracted from the bottom of the container at a rate of 1800 ml/mim. , Liquefied with dry ice to obtain a liquid containing a fragrance. In order to completely capture the fragrance of the natural pine mushrooms, this process was continued for a total of 15 hours, and after solvent extraction with ether in the aqueous fragrance solution, 0.020 g of a fragrance concentrate obtained by concentration was obtained.

Examples 1 to 4. Preparation of natural pine mushroom flavoring composition

1-octen-3-ol, 3-octanol, 3-octanone, methyl cinnamate, aldehyde C9 ((Aldehyde) C9), pine needle oil, cinnamon oil, and pine mushroom extract were combined to prepare natural matsutake mushroom flavor compositions of Examples 1 to 4.

The content of each component included in the composition is summarized in Table 1 below.

Perfume ingredient (% by weight) Comparative example Example 1 Example 2 Example 3 Example 4 1-octen-3-ol - 70 61 51 46 3-Octanol - One One One One 3-Octanone - One One One One Methyl cinnamate - 20 20 20 20 Aldehyde C9 - 0.1 0.1 0.1 0.1 Pine Needle oil - 6.8 6.8 6.8 6.8 Cinnamon Bark oil - 0.1 0.1 0.1 0.1 Pineapple Mushroom Extract - One 10 20 25 Wild pine mushroom 100 Total amount 100.0 100.0 100.0 100.0 100.0

Comparative example.

Fresh wild pine mushrooms collected from Yangyang and Bonghwa were prepared as comparative examples.

Experimental Example 1. Comparative sensory evaluation of natural pine mushroom flavoring composition

Sensory evaluation was performed on the similarity, palatability, and strength of natural pine mushrooms and the flavor composition prepared in the above example.

The sensory evaluation was performed on five fragrance experts composed of perfumers, and the similarity of fragrance to the evaluation items was scored in the range of 1 (low similarity) to 5 (high similarity). In other words, the closer the evaluation score is to 5, the better the natural matsutake flavor is reproduced. In addition, palatability was scored in the range of 1 (dissatisfied) to 5 (satisfied). Intensity refers to the intensity of fragrance, and is used as a basic sensory evaluation item of fragrance compositions. Intensity was scored in the range of 1 (low intensity) to 5 (high intensity).

The sensory evaluation results were calculated as an average value and are shown in Table 2 below.

division Example 1 Example 2 Example 3 Example 4 Similarity 3.5 4.5 4.6 4.5 Palatability 4.1 4.3 4.3 4.2 burglar 3.4 3.5 3.6 3.6

As can be seen in Table 2, it was confirmed that among the perfume compositions prepared in the Example, in particular, the perfume composition prepared in Example 3 had an overall high similarity and palatability to the natural matsutake scent.

So far, the present invention has been looked at around its preferred embodiments. Those of ordinary skill in the art to which the present invention pertains will be able to understand that the present invention may be implemented in a modified form without departing from the essential characteristics of the present invention.

Claims (5)

Octenol (1-octen-3-ol) 51% by weight, 3-Octanol (3-Octanol) 1% by weight, 3-Octanone (3-Octanone) 1% by weight, methyl cinnamate (Methyl cinnamate) 20% by weight %, aldehyde C9 (Aldehyde C9) 0.1% by weight, pine needle oil 6.8% by weight, cinnamon oil 0.1% by weight, and a fragrance composition that reproduces the natural matsutake flavor consisting of 20% by weight of a mushroom extract. delete delete Cosmetics containing the perfume composition of claim 1. Household products containing the perfume composition of claim 1.