KR102158093B1 - Eco-friendly composition for pipe making - Google Patents

Eco-friendly composition for pipe making Download PDF

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KR102158093B1
KR102158093B1 KR1020190018968A KR20190018968A KR102158093B1 KR 102158093 B1 KR102158093 B1 KR 102158093B1 KR 1020190018968 A KR1020190018968 A KR 1020190018968A KR 20190018968 A KR20190018968 A KR 20190018968A KR 102158093 B1 KR102158093 B1 KR 102158093B1
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eco
weight
parts
friendly composition
pipe
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KR20200100952A (en
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김화익
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주식회사 대건케미칼
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)

Abstract

본 발명은 PP(폴리프로필렌:polypropylene), PE(폴리에틸렌:Polyethylene) 및 PVC(폴리염화비닐:Poly Vinyl Chloride) 중 어느 하나의 수지로 이루어진 파이프를 제조시에 포함되어 수질개선 및 항균 효과를 향상시킬 수 있는 친환경 조성물에 관한 것으로, 더욱 상세하게는 PP(폴리프로필렌:polypropylene), PE(폴리에틸렌:Polyethylene) 및 PVC(폴리염화비닐:Poly Vinyl Chloride) 중 어느 하나의 수지로 이루어진 파이프에 포함되는 친환경 조성물에 있어서, 상기 친환경 조성물은 분말형태의 황토, 백운모, 현무암, 제올라이트, 맥반석, 전기석 및 šœ가이트를 포함하여 이루어지는 것을 특징으로 한다.The present invention is included in the manufacture of a pipe made of any one of PP (polypropylene), PE (polyethylene: Polyethylene) and PVC (polyvinyl chloride: Poly Vinyl Chloride) to improve water quality and improve antibacterial effects. It relates to an eco-friendly composition that can be, more specifically, an eco-friendly composition contained in a pipe made of any one of PP (polypropylene), PE (polyethylene: polyethylene), and PVC (polyvinyl chloride: polyvinyl chloride). In, the eco-friendly composition is characterized in that it comprises a powdered loess, muscovite mica, basalt, zeolite, elvan, tourmaline, and š-gite.

Description

파이프 제조용 친환경 조성물{Eco-friendly composition for pipe making}Eco-friendly composition for pipe making}

본 발명은 PP(폴리프로필렌:polypropylene), PE(폴리에틸렌:Polyethylene) 및 PVC(폴리염화비닐:Poly Vinyl Chloride) 중 어느 하나의 수지로 이루어진 파이프를 제조시에 포함되어 수질개선 및 항균 효과를 향상시킬 수 있는 친환경 조성물에 관한 것이다.The present invention is included in the manufacture of a pipe made of any one of PP (polypropylene), PE (polyethylene: Polyethylene) and PVC (polyvinyl chloride: Poly Vinyl Chloride) to improve water quality and improve antibacterial effects. It relates to an environmentally friendly composition that can be.

일반적으로 폴리염화비닐 수지는 저렴한 가격에 비해 물리, 화학적 성질이 우수하여 다양한 분야에서 폭넓게 사용되고 있으나 내열성, 인장강도 및 내충격성에 취약하고 열변형이나 시간이 경과하면 변색되는 등의 단점이 있어 이를 보완하기 위하여 열안정제, 가공조제, 자외선방지제, 충격보강제, 충진제 등의 첨가제를 사용하고 있다.In general, polyvinyl chloride resin is widely used in various fields due to its excellent physical and chemical properties compared to its low price, but it has disadvantages such as heat resistance, tensile strength, and impact resistance, and it has disadvantages such as thermal deformation or discoloration over time. To do this, additives such as heat stabilizers, processing aids, UV inhibitors, impact modifiers, and fillers are used.

일 예로 대한민국 특허등록 제601004호에는 안정제와 폴리염화비닐 레진으로 이루어진 혼합분말을 사용하여 피브이시(PVC) 관을 제조하는 방법이 개시되어 있다. For example, Korean Patent Registration No. 601004 discloses a method of manufacturing a PVC tube by using a mixed powder consisting of a stabilizer and a polyvinyl chloride resin.

상기 기술에 있어서는 충격보강제 등의 작용에 기해 내충격성은 향상되고 있지만, 합성 수지관의 강도가 증가함에 따라 도리어 크랙이 발생하여 관의 찢김현상 및 취성적 파괴가 발생하는 문제가 있었다.In the above technology, impact resistance is improved due to the action of an impact modifier or the like, but as the strength of the synthetic resin tube increases, there is a problem that cracks are generated, resulting in tearing and brittle fracture of the tube.

한편 대한민국 특허공개 2010-0012480호에서는 상수도관이나 하수도관으로 주로 사용되는 폴리염화비닐 파이프 및 파이프 이음관에 관한 것으로, 폴리염화비닐 레진 100 중량부에 대하여 황토 5~45 중량부, 경탄(CaCo3) 8~25 중량부, 복합안정제 2~3중량부, 충격보강제 6~8 중량부를 함유하는 폴리염화비닐 수지 조성물을 제시하고 있는 바, 황토의 성질에 기해 친환경적이면서도 항균성이 있는 폴리염화비닐 수지 조성물을 제공할 수 있으나, 본 기술에서는 황토가 첨가됨에 의해 이질의 재질로서 폴리염화비닐 레진과 황토간에 부착력이 저하되어 강도가 저하되는 문제가 있으며, 황토는 다공성에 기해 친수성 성질이 있는 바, 황토는 소수성의 성질을 발현하는 폴리염화비닐 등 합성수지와 혼합성이 높지 않아 결국 균일한 분산이 어려우며, 이러한 비균일한 황토의 분산은 항균작용의 비균일, 기계적 물성의 저하 등의 문제가 있다.Meanwhile, Korean Patent Publication No. 2010-0012480 relates to polyvinyl chloride pipes and pipe joints mainly used as water supply pipes or sewer pipes, and 5 to 45 parts by weight of loess and hard coal (CaCo3) per 100 parts by weight of polyvinyl chloride resin. We propose a polyvinyl chloride resin composition containing 8 to 25 parts by weight, 2 to 3 parts by weight of a complex stabilizer, and 6 to 8 parts by weight of an impact modifier. Based on the nature of loess, an eco-friendly and antibacterial polyvinyl chloride resin composition However, in the present technology, as a heterogeneous material due to the addition of loess, there is a problem that the adhesion between polyvinyl chloride resin and loess is lowered, resulting in a decrease in strength, and loess has a hydrophilic property due to its porosity, and loess is hydrophobic. It is difficult to uniformly disperse because it does not have high miscibility with synthetic resins such as polyvinyl chloride that expresses the properties of, and this non-uniform dispersion of loess has problems such as non-uniformity of antibacterial action and deterioration of mechanical properties.

한편 종래에 수도관으로 사용되는 주철관 또는 아연관 등의 금속제 관은 장기간 사용 시 용존산소에 의해 관내벽이 쉽게 부식되는 현상이 발생하며 부식된 녹이 물과 섞여 적수 혹은 백색의 오염물을 발생시키는 문제가 있었다.Meanwhile, metal pipes such as cast iron pipes or zinc pipes used as water pipes in the past have a problem that the inner wall of the pipe is easily corroded by dissolved oxygen when used for a long period of time, and there is a problem that the corroded rust mixes with water to generate red water or white pollutants. .

이러한 문제에 기해 내구성 및 내약품성 측면에서 우수한 특성을 나타내는 고밀도 폴리에틸렌을 이용한 수도관이 제시되나, 내부로 물을 저속으로 흘리거나 장기 체류시킬 경우 대장균과 같은 유해 미생물이 번식되며 미생물 번식으로 암모니아성 및 수소성 악취가 심한 문제가 있었다.Due to this problem, a water pipe made of high-density polyethylene, which exhibits excellent characteristics in terms of durability and chemical resistance, is proposed, but when water is flowed into the interior at a low speed or stayed for a long time, harmful microorganisms such as E. coli are propagated, and ammonia and water There was a problem with a severe odor of firing.

국내공개특허 제2010-0012480호(공개일:2010.02.08.)Korean Patent Publication No. 2010-0012480 (Publication date: 2010.02.08.) 국내등록특허 제10-1186928호(공고일:2012.09.28.)Domestic registration patent No. 10-1186928 (announcement date: 2012.09.28.) 국내등록특허 제10-0974995호(공고일:2010.08.09.)Domestic registration patent No. 10-0974995 (announcement date: 2010.08.09.)

상술한 종래의 문제점을 해결하기 위해 본 발명은 친환경적인 황토의 첨가에 대한 다른 조성물과의 부착력을 증대시켜 파이프의 물성을 증대시키되 오염물의 발생이나 곰팡이 등과 같은 유해균의 발생을 방지시킬 수 있는 파이프 제조용 친환경 조성물을 제공하고자 하는데 그 목적이 있다.In order to solve the above-described conventional problems, the present invention increases the physical properties of the pipe by increasing the adhesion with other compositions to the addition of environmentally friendly loess, but for manufacturing pipes that can prevent the occurrence of harmful bacteria such as pollutants or mold. There is an objective to provide an eco-friendly composition.

상술한 기술적 과제를 해결하기 위해 본 발명에 따른 파이프 제조용 친환경 조성물은 PP(폴리프로필렌:polypropylene), PE(폴리에틸렌:Polyethylene) 및 PVC(폴리염화비닐:Poly Vinyl Chloride) 중 어느 하나의 수지로 이루어진 파이프에 포함되는 친환경 조성물에 있어서, 상기 친환경 조성물은 분말형태의 황토, 백운모, 현무암, 제올라이트, 맥반석, 전기석 및 šœ가이트를 포함하여 이루어지는 것을 특징으로 한다.In order to solve the above-described technical problem, the eco-friendly composition for pipe manufacturing according to the present invention is a pipe made of any one of PP (polypropylene), PE (polyethylene: Polyethylene), and PVC (polyvinyl chloride: polyvinyl chloride). In the eco-friendly composition contained in, the eco-friendly composition is characterized in that it comprises a powder form of loess, muscovite, basalt, zeolite, elvan, tourmaline, and š-gite.

또한 상기 친환경 조성물은 황토 100중량부에 대하여, 백운모 90 내지 100중량부, 현무암 5 내지 8중량부, 제올라이트 5 내지 10중량부, 맥반석 5 내지 7중량부, 전기석 3 내지 5중량부 및 šœ가이트 2 내지 3중량부 포함하여 혼합되는 것이 바람직하다.In addition, the eco-friendly composition is based on 100 parts by weight of loess, 90 to 100 parts by weight of muscovite mica, 5 to 8 parts by weight of basalt, 5 to 10 parts by weight of zeolite, 5 to 7 parts by weight of elvan, 3 to 5 parts by weight of tourmaline, and šœgite It is preferably mixed, including 2 to 3 parts by weight.

또한 상기 친환경 조성물은 800 내지 1,000℃의 온도로 3 내지 5시간 동안 소성(燒成)하여 수분이 없는 상태이고, 700 내지 900 메쉬의 분말형태를 갖는 것이 바람직하다.In addition, the eco-friendly composition is fired for 3 to 5 hours at a temperature of 800 to 1,000° C. so as to have no moisture, and preferably has a powder form of 700 to 900 mesh.

본 발명에 따르면, 종래와는 차별적으로 파이프를 제조시에 혼합되는 수지조성물과 그 입자크기와 제올라이트의 사용으로 인해 부착력이 증대되어 제조된 파이프의 물성을 향상시키되 전기석, 현무암, 맥반석 및 백운모에 의해 항균이나 항곰팡이 효과를 극대화 하는 효과를 갖는다.According to the present invention, differently from the prior art, the resin composition mixed during the manufacture of the pipe, its particle size, and the use of zeolite increase the adhesion, thereby improving the properties of the manufactured pipe, but by using tourmaline, basalt, elvan, and muscovite It has the effect of maximizing antibacterial or antifungal effect.

또한 종래와는 차별적으로 본 발명인 친환경 조성물을 이루는 광물에 소성을 실시하여 미세기공이 많은 광물군에 유해물질의 흡착 분해 효과와 물이끼(물때)가 고착되지 않는 효과를 높이되 특히, 전기석의 미세전류에 의한 영구적인 물 클러스트를 분해하여 상수관으로 파이프를 제조하여 식용가능한 물을 공급시에 인체에 유익한 수질이 개선된 물을 제공하는 효과를 갖는다.In addition, by performing firing on the minerals that make up the eco-friendly composition of the present invention differently from the prior art, the adsorption and decomposition effect of harmful substances and the effect of not adhering peat moss (water stain) to the mineral group with many micropores are enhanced. It has the effect of providing water with improved water quality, which is beneficial to the human body when supplying edible water by decomposing a permanent water cluster by making a pipe into a water supply pipe.

이하, 상기 목적 외에 본 발명의 다른 목적 및 특징들은 첨부 도면을 참조한 실시 예에 대한 설명을 통하여 명백히 드러나게 될 것이며, 다르게 정의되지 않는 한, 기술적이거나 과학적인 용어를 포함해서 여기서 사용되는 모든 용어들은 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자에 의해 일반적으로 이해되는 것과 동일한 의미를 가지고 있다. 일반적으로 사용되는 사전에 정의되어 있는 것과 같은 용어들은 관련 기술의 문맥상 가지는 의미와 일치하는 의미를 가진 것으로 해석되어야 하며, 본 출원에서 명백하게 정의하지 않는 한, 이상적이거나 과도하게 형식적인 의미로 해석되지 않는다.Hereinafter, other objects and features of the present invention in addition to the above objects will be clearly revealed through the description of the embodiments with reference to the accompanying drawings, and unless otherwise defined, all terms used herein including technical or scientific terms are It has the same meaning as commonly understood by one of ordinary skill in the art to which the invention belongs. Terms such as those defined in a commonly used dictionary should be interpreted as having a meaning consistent with the meaning in the context of the related technology, and should not be interpreted as an ideal or excessively formal meaning unless explicitly defined in this application. Does not.

이하, 본 발명에 따른 파이프 제조용 친환경 조성물에 대하여 상세히 설명한다. 설명에 앞서, 본 발명은 PP(폴리프로필렌:polypropylene), PE(폴리에틸렌:Polyethylene) 및 PVC(폴리염화비닐:Poly Vinyl Chloride) 중 어느 하나의 수지조성물로 이루어진 상/하수도 파이프를 예시적으로 설명하고 있으나 이는 하나의 실시예에 불과하며, 이러한 수지조성물을 사용하고 있는 사용처가 다른 종류의 파이프 (예를 들어, 농수용관, 난방용관이나 해수용관 등)에도 활용가능하다는 점에 유의한다.Hereinafter, an eco-friendly composition for manufacturing a pipe according to the present invention will be described in detail. Prior to the description, the present invention exemplarily describes a water supply/sewer pipe made of a resin composition of any one of PP (polypropylene), PE (polyethylene: Polyethylene) and PVC (polyvinyl chloride: Polyvinyl Chloride), and However, it should be noted that this is only an example, and the use place using such a resin composition can be used for other types of pipes (eg, pipes for agricultural water, pipes for heating, pipes for seawater, etc.).

먼저, 본 발명에서의 친환경 조성물은 황토(黃土), 백운모(白雲母), 현무암(玄武岩), 제올라이트(zeolite), 맥반석(麥飯石), 전기석(tourmaline) 및 šœ가이트(shungite)가 혼합된 것을 포함하여 이루어지며, 이러한 상기 친환경 조성물은 파이프를 제조시에 사용하는 수지조성물 및 비납계 열안정제 등과 함께 혼합되어 상/하수도에 사용되는 파이프를 성형할 수 있게 된다.First, the eco-friendly composition in the present invention is a mixture of loess, white mica, basalt, zeolite, elvan stone, tourmaline, and šœgite. The eco-friendly composition is mixed with a resin composition and a non-lead heat stabilizer, etc. used in manufacturing pipes, so that pipes used for water supply and sewage can be molded.

본 발명에서의 친환경 조성물을 이루는 광물군은 모두 분말형태를 형성하여 파이프를 제조시에 다른 수지조성물과 혼합 및 융해가 용이할 수 있도록 한다.All of the mineral groups constituting the eco-friendly composition in the present invention form a powder form so that it can be easily mixed and melted with other resin compositions when manufacturing a pipe.

본 발명인 친환경 조성물을 이루는 광물 중 하나인 제올라이트는 파이프를 제조시에 사용하는 수지조성물과 상기 친환경 조성물 간의 촉매 역할을 하는 광물군으로 사용하는데 그 이유는 해당 제올라이트는 다양한 이온을 수용할 수 있는 구조로 이루어져 있어 해당 수지조성물과 친환경 조성물이 서로 혼합시에 다른 양이온으로 쉽게 전이될 수 있기 때문이다.Zeolite, one of the minerals constituting the eco-friendly composition of the present invention, is used as a group of minerals that act as a catalyst between the resin composition used in manufacturing pipes and the eco-friendly composition. The reason is that the zeolite has a structure that can accommodate various ions. This is because the resin composition and the eco-friendly composition can be easily transferred to other cations when mixed with each other.

토르마린이라고도 불리는 전기석은 영구적인 전기 특성을 갖는 극성결정체이며, 알루미늄은 물론, 철, 마그네슘, 나트륨 및 리튬 등의 원소가 혼합된 광물로 파이프를 제조시에 그 함유량에 따라 해당 파이프의 색상을 달리할 수 있는 재료로 사용될 수 있다.Tourmaline, also called tourmaline, is a polar crystal with permanent electrical properties.It is a mineral mixed with elements such as iron, magnesium, sodium and lithium, as well as aluminum. When manufacturing a pipe, the color of the pipe can be changed according to its content. It can be used as a possible material.

아울러 본 발명인 친환경 조성물에 함유되는 전기석은 약 0.03 내지 0.06A(암페어)의 미세전류를 발생시키며, 해당 미세전류의 생성을 통해 파이프를 제조시에 음이온의 생성과 원적외선을 방출하여 해당 파이프 면에 물에 의한 이물질이 고착되는 것을 방지하는 기능을 수행한다.In addition, the tourmaline contained in the eco-friendly composition of the present invention generates a microcurrent of about 0.03 to 0.06A (ampere), and through the generation of the microcurrent, the generation of negative ions and far-infrared rays are emitted during pipe manufacturing. It performs the function of preventing foreign matter from sticking to.

즉, 전기석에 강한 열과 압력을 가하여 강알카리성을 갖는 해당 전기석을 약산성알카리성으로 변화시켜 이물질이 파이프 면에 고착되는 것을 방지하여 물때가 생성되는 것을 방지하는 것이다.That is, by applying strong heat and pressure to the tourmaline, the tourmaline having strong alkalinity is changed to weakly acidic alkalinity to prevent foreign substances from sticking to the pipe surface, thereby preventing the formation of scale.

현무암은 상술한 제올라이트와 동일하게 원적외선 방출의 효과가 있으며, 이를 통해 항균의 효과를 갖는 광물로 이러한 항균 효과를 갖는 현무암은 파이프 내에서 흐르는 물을 정화하는 기능을 수행한다.Basalt has the same effect of emitting far-infrared rays as in the above-described zeolite, and through this, it is a mineral having an antibacterial effect, and basalt having such an antibacterial effect performs a function of purifying water flowing in a pipe.

맥반석은 약리작용(藥理作用) 효과가 강한 대표적인 광물로 본 발명인 친환경 조성물을 이용하여 파이프를 제조하되 해당 파이프를 하수관이 아닌, 상수관으로 사용시에 그 효과를 극대화할 수 있으며, 하수관으로 사용시에도 다른 광물이 갖는 효과를 극대화할 수 있는 기능을 갖는다.Elvanstone is a representative mineral with strong pharmacological effect. A pipe is manufactured using the eco-friendly composition of the present invention, but the effect can be maximized when the pipe is used as a water pipe instead of a sewer pipe. It has the function of maximizing the effect of minerals.

백운모는 단사정계 광물의 하나로 판상, 편상, 인상 결정의 육각형 외곽을 형상하고 있으며, 자연상에서 알루미늄이나 철 성분이 치환되어 포함되어 있는 광물로 전기석과 함께 사용시에 해당 전기석의 효과를 극대화할 수 있는 광물로 본 발명에서는 사용한다.Muscovite is a monoclinic mineral that has a hexagonal outer shape of plate, flake, and raised crystals, and is a mineral that contains aluminum or iron substituted in nature. When used with tourmaline, it is a mineral that can maximize the effect of the tourmaline. As used in the present invention.

한편, 상술한 광물은 황토 100중량부에 대하여, 백운모 90 내지 100중량부, 현무암 5 내지 8중량부, 제올라이트 5 내지 10중량부, 맥반석 5 내지 7중량부, 전기석 3 내지 5중량부 및 šœ가이트 2 내지 3중량부 포함하여 혼합으로 본 발명인 친환경 조성물을 이루며, 각각의 광물은 혼합 효과를 위해 700 내지 900 메쉬의 입자크기를 갖도록 한다.On the other hand, the above-described minerals are based on 100 parts by weight of loess, 90 to 100 parts by weight of muscovite, 5 to 8 parts by weight of basalt, 5 to 10 parts by weight of zeolite, 5 to 7 parts by weight of elvan, 3 to 5 parts by weight of tourmaline, and šœ By mixing, including 2 to 3 parts by weight of gite, the eco-friendly composition of the present invention is formed, and each mineral has a particle size of 700 to 900 mesh for a mixing effect.

해당 입자의 범위는 파이프를 제조시에 다른 수지조성물과의 부착력이 증대되어 파이프 제품의 물성이 크게 향상될 수 있는 장점을 갖는다.The range of the particles has the advantage that the physical properties of the pipe product can be greatly improved by increasing the adhesion with other resin compositions when manufacturing the pipe.

이때, 분말형태를 갖는 각각의 광물은 3 내지 5시간 동안 800 내지 1,000℃ 이내인 고온의 온도로 소성(燒成)하여 수분 함유량이 없는 상태를 갖도록 하는 것이 바람직하다.At this time, each mineral having a powder form is preferably calcined at a high temperature within 800 to 1,000°C for 3 to 5 hours to have a state without moisture content.

아울러 본 발명인 친환경 조성물을 소성하는 이유는 각각의 광물에 잔여하는 유기물과 층간수, 복합수 및 결정수를 소멸시키기 위한 것이며, 철분과 미네랄이 산화되면서 파이프를 성형하는 안료의 색상이 진해짐과 동시에 명도가 좋아지는 효과를 갖도록 하기 위함이다.In addition, the reason for firing the eco-friendly composition of the present invention is to dissipate organic matter, interlayer water, complex water, and crystal water remaining in each mineral, and as iron and minerals are oxidized, the color of the pigment forming the pipe becomes darker. This is to have the effect of improving the brightness.

아울러 소성을 통해 광물이 갖는 고유의 특성인 원적외선, 음이온발산, 항균 및 항곰팡이 기능을 향상시키기 위한 목적으로도 활용된다.In addition, it is also used for the purpose of improving the functions of far-infrared rays, anion emission, antibacterial and anti-fungal functions, which are inherent properties of minerals through firing.

이와 같은 구성으로 이루어진 본 발명에 따른 친환경 조성물은 종래와는 차별적으로 파이프를 제조시에 혼합되는 수지조성물과 그 입자크기와 제올라이트의 사용으로 인해 부착력이 증대되어 제조된 파이프의 물성을 향상시키되 전기석, 현무암, 맥반석 및 백운모에 의해 항균이나 항곰팡이 효과를 극대화 하는 효과를 갖는다.The eco-friendly composition according to the present invention having such a configuration increases the adhesive force due to the use of the resin composition and the particle size and zeolite that are mixed when manufacturing the pipe differently from the conventional one, thereby improving the physical properties of the manufactured pipe. It has the effect of maximizing antibacterial and antifungal effects by basalt, elvan and muscovite.

또한 종래와는 차별적으로 본 발명인 친환경 조성물을 이루는 광물에 소성을 실시하여 미세기공이 많은 광물군에 유해물질의 흡착 분해 효과와 물이끼(물때)가 고착되지 않는 효과를 높이되 특히, 전기석의 미세전류에 의한 영구적인 물 클러스트를 분해하여 상수관으로 파이프를 제조하여 식용가능한 물을 공급시에 인체에 유익한 수질이 개선된 물을 제공하는 효과를 갖는다.In addition, by performing firing on the minerals that make up the eco-friendly composition of the present invention differently from the prior art, the adsorption and decomposition effect of harmful substances and the effect of not adhering peat moss (water stain) to the mineral group with many micropores are enhanced. It has the effect of providing water with improved water quality, which is beneficial to the human body when supplying edible water by decomposing a permanent water cluster by making a pipe into a water supply pipe.

이상과 같이 본 발명에서는 구체적인 구성 요소 등과 같은 특정 사항들과 한정된 실시예 및 도면에 의해 설명되었으나 이는 본 발명의 보다 전반적인 이해를 돕기 위해서 제공된 것일 뿐, 본 발명은 상기의 실시예에 한정되는 것은 아니며, 본 발명이 속하는 분야에서 통상적인 지식을 가진 자라면 이러한 기재로부터 다양한 수정 및 변형이 가능하다.As described above, in the present invention, specific matters such as specific components, etc., and limited embodiments and drawings have been described, but this is provided only to help a more general understanding of the present invention, and the present invention is not limited to the above embodiments. , If a person of ordinary skill in the field to which the present invention belongs, various modifications and variations are possible from these descriptions.

따라서, 본 발명의 사상은 설명된 실시예에 국한되어 정해져서는 아니 되며, 후술하는 특허청구범위뿐 아니라 이 특허청구범위와 균등하거나 등가적인 변형이 있는 모든 것들은 본 발명 사상의 범주에 속한다고 할 것이다.Therefore, the spirit of the present invention is limited to the described embodiments and should not be defined, and all those having variations equivalent or equivalent to the claims, as well as the claims to be described later, will belong to the scope of the inventive concept. .

Claims (3)

PP(폴리프로필렌:polypropylene), PE(폴리에틸렌:Polyethylene) 및 PVC(폴리염화비닐:Poly Vinyl Chloride) 중 어느 하나의 수지로 이루어진 파이프에 포함되는 친환경 조성물에 있어서,
상기 친환경 조성물은 분말형태의 황토, 백운모, 현무암, 제올라이트, 맥반석, 전기석 및 šœ가이트를 포함하되,
황토 100중량부에 대하여, 백운모 90 내지 100중량부, 현무암 5 내지 8중량부, 제올라이트 5 내지 10중량부, 맥반석 5 내지 7중량부, 전기석 3 내지 5중량부 및 šœ가이트 2 내지 3중량부 포함하여 혼합되며,
상기 친환경 조성물은 800 내지 1,000℃의 온도로 3 내지 5시간 동안 소성(燒成)하여 수분이 없는 상태이되 철분과 미네랄이 산화되면서 파이프를 성형하는 안료의 색상이 진해짐과 동시에 명도가 향상될 수 있게 하며, 700 내지 900 메쉬의 분말형태를 갖는 것을 특징으로 하는 파이프 제조용 친환경 조성물.
In an eco-friendly composition contained in a pipe made of any one of PP (polypropylene), PE (polyethylene: Polyethylene) and PVC (polyvinyl chloride: Poly Vinyl Chloride),
The eco-friendly composition includes powdery loess, muscovite, basalt, zeolite, elvan, tourmaline, and gite,
Based on 100 parts by weight of loess, including 90 to 100 parts by weight of muscovite mica, 5 to 8 parts by weight of basalt, 5 to 10 parts by weight of zeolite, 5 to 7 parts by weight of elvan, 3 to 5 parts by weight of tourmaline, and 2 to 3 parts by weight of gite And mixed,
The eco-friendly composition is calcined at a temperature of 800 to 1,000°C for 3 to 5 hours, so that there is no moisture, but iron and minerals are oxidized, so that the color of the pigment forming the pipe becomes dark and the brightness can be improved And, an eco-friendly composition for manufacturing a pipe, characterized in that it has a powder form of 700 to 900 mesh.
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