KR102146195B1 - The recycling asphalt mixture for reforming - Google Patents

The recycling asphalt mixture for reforming Download PDF

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KR102146195B1
KR102146195B1 KR1020190082359A KR20190082359A KR102146195B1 KR 102146195 B1 KR102146195 B1 KR 102146195B1 KR 1020190082359 A KR1020190082359 A KR 1020190082359A KR 20190082359 A KR20190082359 A KR 20190082359A KR 102146195 B1 KR102146195 B1 KR 102146195B1
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cement
weight
parts
waste
aggregate
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KR1020190082359A
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Korean (ko)
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권기재
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권기재
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02Agglomerated materials, e.g. artificial aggregates
    • C04B18/021Agglomerated materials, e.g. artificial aggregates agglomerated by a mineral binder, e.g. cement
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/04Macromolecular compounds
    • C04B16/06Macromolecular compounds fibrous
    • C04B16/0616Macromolecular compounds fibrous from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B16/0625Polyalkenes, e.g. polyethylene
    • C04B16/0633Polypropylene
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/06Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
    • C04B18/08Flue dust, i.e. fly ash
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • C04B20/026Comminuting, e.g. by grinding or breaking; Defibrillating fibres other than asbestos
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/36Bituminous materials, e.g. tar, pitch
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/26Bituminous materials, e.g. tar, pitch
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Road Paving Structures (AREA)

Abstract

Provided is a modified recycled asphalt composition using waste extraction-molded cement to prevent cost increase due to use of a large amount of additives and modifiers. According to the present invention, the recycled asphalt composition comprises cyclic aggregate with large, middle, and small diameters, a filler, a binder, emulsified asphalt, a recycling agent, and a mixed solution. Waste extraction-molded cement aggregate, which is formed by pulverizing waste extraction-molded cement made through first curing and second curing at a particle size of 8 mm or less, is applied as the cyclic aggregate of the small particle size of the cyclic aggregate, wherein the waste extraction-molded cement comprises 5-20 parts by weight of cement and 75-93 parts by weight of fly ash, and 3-5 parts by weight of the waste extraction-molded cement aggregate are included in the cyclic aggregate with respect to the total weight of the cyclic aggregate. The filler and the binder are applied to waste extraction-molded cement powder which is made by pulverizing waste extraction-molded cement made through first curing and second curing, wherein the waste extraction-molded cement comprises 5-20 parts by weight of cement, 75-93 parts by weight of fly ash, and 2 parts by weight of artificial fiber applying polypropylene fiber and 6-8 parts by weight of the waste extraction-molded cement powder are included in the cyclic aggregate with respect to the total weight of the cyclic aggregate.

Description

폐압출성형시멘트를 이용한 개질 재생아스팔트 조성물{The recycling asphalt mixture for reforming} The recycling asphalt mixture for reforming using waste extrusion cement

본 발명은 재생아스팔트 조성물에 관한 것으로, 더욱 상세하게는 폐압출성형시멘트를 이용한 개질 재생아스팔트 조성물에 관한 것이다.The present invention relates to a regenerated asphalt composition, and more particularly, to a modified regenerated asphalt composition using waste extrusion cement.

주지하다시피, 노후된 도로의 개보수 및 오래된 주택단지 등의 철거가 지속적으로 이루어지고 있다. 또한, 자연환경을 보호하는 목적에 따라 쇄석골재를 채취하는 석산의 허가가 시간이 경과할수록 곤란해지고 있는 등 폐아스팔트 콘크리트 또는/및 폐 시멘트 콘크리트를 분쇄한 순환골재의 재활용 방법이 더 많이 개발되는 것이 필요한 사회적 환경이 조성되고 있다.As is well known, the renovation of old roads and the demolition of old housing complexes are continuing. In addition, it is more difficult to develop recycling methods for recycled aggregates obtained by pulverizing waste asphalt concrete or/and cement concrete, as it is becoming more difficult as time passes for the permission of seoksan to collect crushed stone aggregate for the purpose of protecting the natural environment. The necessary social environment is being created.

일반적으로 상온순환아스콘은 신제품의 쇄석골재, 폐아스팔트 콘크리트 및 폐 시멘트 콘크리트를 분쇄한 순환골재, 채움재, 유화아스팔트 및 재생첨가제로 이루어진다.In general, room temperature circulating ascon is composed of new crushed stone aggregate, waste asphalt concrete and recycled aggregate obtained by crushing waste cement concrete, filling material, emulsified asphalt, and recycled additives.

대한민국 특허등록 제10-0599492호에서는 유화아스팔트를 사용하지 않고, 부피팽창제, 지수제, 경화촉진제 및 유동성 혼화제를 함유하는 폐아스콘을 활용한 반강성 포장용 조성물이 개시되어 있으나, 상기의 발명은 지수제 등의 사용에 따라 충분한 초기경화가 일어나지 않아 동절기의 시공에 문제가 있으며 아스팔트의 내구성이나 탄성이 저하되는 문제점이 발생할 우려가 제기될 수 있다.Republic of Korea Patent Registration No. 10-0599492 discloses a composition for semi-rigid packaging that does not use emulsified asphalt and uses waste ascon containing a volume expander, an indexing agent, a curing accelerator and a fluid admixture. Since sufficient initial hardening does not occur according to the use of the lamp, there may be a problem in construction in winter, and there may be a concern that the durability or elasticity of the asphalt may be deteriorated.

또한, 대한민국 공개특허공보 제10-2011-26038호에서는 재생개질제로 유연제, 탄성체, 점증제, 박리방지제, 무기 분말 및 단섬유 중에서 하나 이상과 중온 첨가제로 수화제, 왁스 및 발포제 중 하나 이상을 함유하는 온도조정 개질 재생아스콘의 조성물이 개시되어 있으나, 제조공정이 복잡하며, 내구성이나 수분 민감성에 대한 문제점을 고려하고 있지 못하였다.In addition, Korean Patent Laid-Open Publication No. 10-2011-26038 contains at least one of a softener, an elastic body, a thickener, a peeling inhibitor, an inorganic powder and a short fiber as a regeneration modifier, and at least one of a hydrating agent, a wax and a foaming agent as a medium temperature additive. Although a composition of temperature-controlled modified regenerated ascon is disclosed, the manufacturing process is complicated, and the problems of durability and moisture sensitivity have not been considered.

대한민국 특허등록 제10-0867097호에서는 음이온계 유화아스팔트와 골재와 골재 사이에서 망상구조를 형성하여 공극을 채우고 접착력과 인장강도를 증가시키기 위하여 아크릴폴리머를 함유하는 포장용 아스팔트 콘크리트가 개시되고, 대한민국 특허등록 제10-0946588호에서 폐아스콘, 신골재, 채움재, 유화아스팔트 및 재생첨가재를 포함하는 재생아스팔트 콘크리트 혼합물이 개시되어 있으나, 상기의 재생첨가제는 중 파라핀 증류액, 비투멘(Bitumen) 및 미네랄 피치(Mineral Pitch) 등을 사용하고 있어 비가열에 따른 순환골재와 시멘트의 결합력이 저하될 우려가 있다.Korean Patent Registration No. 10-0867097 discloses anionic emulsified asphalt and asphalt concrete for pavement containing acrylic polymer in order to fill the voids by forming a network structure between aggregate and aggregate, and to increase adhesion and tensile strength. No. 10-0946588 discloses a mixture of recycled asphalt concrete containing waste ascon, new aggregate, filling material, emulsified asphalt and recycled additives, but the recycled additives include heavy paraffin distillate, bitumen and mineral pitch ( Mineral pitch), etc., are used, so there is a concern that the bonding strength between recycled aggregate and cement may decrease due to non-heating.

한편, KSF3501 아스팔트 포장용 채움재 규격에 의하면 채움재는 석회석분, 포틀랜드 시멘트, 소석회, 플라이 애시, 회수더스트, 전기로 제강더스트, 주물더스트, 각종 소각회 및 기타 적당한 광물성 물질의 분말이라고 규정하고 있다. 그러기 때문에 일반적으로 산업현장에서는 관련 KS규격도 만족하면서 기존에 제시된 기술의 문제점인 강성과 내구성의 부족을 만회 할 목적으로 상온순환 아스팔트 포장용 채움재로서 1종 포틀랜트 시멘트를 사용하고 있는 실정이다.On the other hand, according to the KSF3501 asphalt pavement filler standard, the filler is stipulated as limestone powder, Portland cement, slaked lime, fly ash, recovered dust, electric furnace steelmaking dust, casting dust, various incineration ash, and other suitable mineral powders. Therefore, in general, industrial sites are using Type 1 Portland Cement as a filling material for normal temperature circulation asphalt pavement in order to make up for the lack of rigidity and durability, which is a problem of the existing technology while satisfying the related KS standard.

또한, 대한민국 등록특허 10-1242097호, 10-1847179호, 10-1487180호 등에서는 포틀랜드 시멘트를 대체하는 채움재 및 결합재 기술을 개시하였는데, 이는 TDF소각재 및 중유혼소 소각재 등 아스팔트와 유사한 검정색을 발색하는 것을 하나의 기술적 특성으로 제시하고 있다. 이와 같이 지금까지 제시된 상온순환아스콘의 선행기술들은 기존의 검은색 아스팔트조성물의 물리적 성능을 보완하기 위한 기술들이며, 기존의 상온 순환아스콘의 경우는 시멘트를 결합재 및 채움재로 활용하기때문에 겨울철 추운날씨에 시공되는 경우 시멘트의 수화반응이 지연되어 초기 동해를 입게 될 수 있으며, 평상시의 경우도 수분이 많은 현장에서 시공될 경우 혼합물에 포함된 수분이 너무 많게 되어 소정의 목적을 달성하지 못하는 경우가 있다.In addition, Republic of Korea Patent Registration Nos. 10-1242097, 10-1847179, 10-1487180, etc. disclose the filling material and binder technology to replace Portland cement, which is similar to the color of asphalt, such as TDF incineration material and heavy oil mixed incineration material. It is presented as a technical characteristic. As such, the prior technologies of room temperature circulation ascon presented so far are technologies to supplement the physical performance of the existing black asphalt composition, and in the case of the existing room temperature circulation ascon, since cement is used as a binder and filler, it is installed in cold weather in winter. If it is, the hydration reaction of the cement may be delayed, resulting in initial freezing. Even in normal cases, if the construction is carried out at a site with a lot of moisture, the moisture contained in the mixture may become too much and the predetermined purpose may not be achieved.

또한, 대한민국 공개특허 제2000-0030064호에서는 폐아스콘 사용량을 제한한 가운데 물성향상을 도모하기 위하여 시멘트를 사용하지 않고 산업부산물인 플라이애시 및 유기계섬유를 이용한 도로포장용 고성능 개질 재생아스팔트 혼합물의 제조방법에 대해 개시하고 있다. 그러나 사용된 폐아스콘의 함량이 적거나, 역학적인 물성이 열악하거나 여러 다른 재료를 혼입하기 위한 추가적인 장비와 공정을 필요로 하는 문제이 있다.In addition, Korean Patent Laid-Open Publication No. 2000-0030064 discloses a method of manufacturing a high-performance modified recycled asphalt mixture for road pavement using fly ash and organic fibers, which are industrial by-products, without using cement to improve physical properties while limiting the amount of waste ascon. Are disclosed. However, there is a problem that the content of used waste ascon is low, mechanical properties are poor, or additional equipment and processes are required to mix different materials.

이에, 본 발명은 종래 재생아스팔트 조성물이 갖는 제반적인 문제점을 해결하기 위해 창안된 것으로, Thus, the present invention is invented to solve the general problems of the conventional recycled asphalt composition,

본 발명이 해결하고자 하는 과제는 다량의 첨가제 및 개질제의 사용으로 인한 비용증가를 방지하고, 폐압출성형멘트를 재생골재 또는 채움재 및 결합제로 사용하여 천연골재자원의 보호와 환경보호적 측면을 강화함과 동시에 기존 아스팔트 콘크리트가 갖고 있는 강도, 경도, 점성도, 안정도, 유연성을 고루 갖춘 폐압출성형시멘트를 이용한 개질 재생아스팔트 조성물을 제공하는데 있다.The problem to be solved by the present invention is to prevent an increase in cost due to the use of a large amount of additives and modifiers, and to reinforce the protection of natural aggregate resources and environmental protection by using the waste extrusion molding as recycled aggregate or filler and binder. At the same time, it is to provide a modified regenerated asphalt composition using waste extruded cement that has the strength, hardness, viscosity, stability, and flexibility of existing asphalt concrete.

본 발명이 해결하고자 하는 다른 과제는 시멘트와 함께 별도로 플라이애쉬를 채움재로 추가사용하지 않고 플라이애쉬를 주성분으로 하는 폐압출성형멘트를 재생골재 또는 채움재로 적용할 수 있어 여러 다른 재료를 혼입하기 위한 추가적인 장비와 공정이 필요하지 않은 폐압출성형시멘트를 이용한 개질 재생아스팔트 조성물을 제공하는데 있다.Another problem to be solved by the present invention is that, without additionally using fly ash as a filling material separately with cement, waste extrusion moldings containing fly ash as a main component can be applied as recycled aggregate or filling material. It is to provide a modified recycled asphalt composition using waste extrusion cement that does not require equipment and processes.

본 발명이 해결하고자 하는 또 다른 과제는 인조섬유제 또는 탄소섬유를 결합재로 포함한 폐압출성형멘트를 채움재 및 결합제로 적용함으로써 별도로 합성섬유 또는 천연섬유를 추가하는 과정, 즉 여러 다른 재료를 혼입하기 위한 추가적인 장비와 공정이 필요하지 않은 폐압출성형시멘트를 이용한 개질 재생아스팔트 조성물을 제공하는데 있다.Another problem to be solved by the present invention is the process of adding synthetic fibers or natural fibers separately by applying the waste extrusion mold including artificial fibers or carbon fibers as a binder as a filler and a binder, that is, an additional process for incorporating various other materials. It is to provide a modified recycled asphalt composition using waste extrusion cement that does not require equipment and processes.

상기한 과제를 해결하기 위한 본 발명의 구체적인 수단으로는;As a specific means of the present invention for solving the above problems;

상,중,하의 입경을 갖는 순환골재, 채움재 및 결합제, 유화아스팔트, 재생첨가제 및 혼합액을 포함하는 재생아스팔트 조성물에 있어서,In a recycled asphalt composition comprising a recycled aggregate having a particle size of upper, middle, and lower, a filler and a binder, an emulsified asphalt, a regeneration additive, and a mixed solution,

상기 순환골재에는 시멘트 5~20중량부와 플라이애쉬 75~93중량부를 주원료로 하여 1,2차 양생제조되어 건축자재로 사용된 폐압출성형시멘트를 입경 8mm 이하로 파쇄한 폐압출성형시멘트골재를 하입경 순환골재로 적용하되, 상기 폐압출성형시멘트골재는 상기 순환골재 전체 중량부에 대하여 3~5중량부로 포함되고,The recycled aggregate contains waste extrusion-molded cement aggregate of 5 to 20 parts by weight of cement and 75 to 93 parts by weight of fly ash as the main raw materials, and crushed waste extrusion cement used as a construction material to a particle diameter of 8 mm or less. It is applied as a lower particle diameter recycled aggregate, and the waste extrusion-molded cement aggregate is included in 3 to 5 parts by weight based on the total weight of the recycled aggregate,

상기 채움재 및 결합제는 시멘트 5~20중량부와 플라이애쉬 75~93중량부와 폴리프로필렌섬유가 적용되는 인조섬유제 2중량부를 포함하며 1,2차 양생제조되어 건축자재로 사용된 폐압출성형시멘트를 미쇄분으로 파쇄한 폐압출성형시멘트미쇄분을 적용하되, 상기 폐압출성형시멘트미쇄분은 상기 순환골재 전체 중량부에 대하여 6~8중량부로 포함되는 것을 특징으로 하는 폐압출성형시멘트를 이용한 개질 재생아스팔트 조성물을 구비한다.The filler and binder include 5 to 20 parts by weight of cement, 75 to 93 parts by weight of fly ash, and 2 parts by weight of man-made fiber to which polypropylene fiber is applied, and the first and second curing materials are used as construction materials. Reformed and regenerated using waste extrusion cement, characterized in that the pulverized waste extrusion cement crushed into pulverized powder is applied, wherein the pulverized waste extrusion cement is included in 6 to 8 parts by weight based on the total weight of the recycled aggregate. It has an asphalt composition.

바람직한 실시예로써, 상기 채움재 및 결합제는 시멘트 5~20중량부와 플라이애쉬 75~93중량부와 탄소섬유 2~20중량부를 포함하며 1,2차 양생제조되어 접지부재로 사용된 폐압출성형시멘트를 미쇄분으로 파쇄한 폐압출성형시멘트미쇄분을 적용할 수 있다.In a preferred embodiment, the filler and the binder contain 5 to 20 parts by weight of cement, 75 to 93 parts by weight of fly ash, and 2 to 20 parts by weight of carbon fiber, and are manufactured for primary and secondary curing and used as a grounding member. The waste extrusion cement fine pulverized powder crushed into fine pulverized powder can be applied.

바람직한 실시예로써, 상기 채움재 및 결합제는 건축자재로 사용된 폐압출성형시멘트 미쇄분과 접지부재로 사용된 폐압출성형시멘트 미쇄분을 50: 50 비율로 혼합한 것을 적용할 수 있다.In a preferred embodiment, the filler and the binder may be a mixture of the pulverized waste extrusion cement used as a building material and the pulverized waste extrusion cement used as a grounding member in a ratio of 50:50.

본 발명에 따른 폐압출성형시멘트를 이용한 개질 재생아스팔트 조성물은 하입경 순환골재와 채움재 및 결합제에 폐압출성형시멘트를 적용함에 따라 다량의 첨가제 및 개질제의 사용으로 인한 비용증가를 방지할 수 있다. The modified recycled asphalt composition using the waste extrusion cement according to the present invention can prevent an increase in cost due to the use of a large amount of additives and modifiers as the waste extrusion cement is applied to the lower particle diameter recycled aggregate, the filling material, and the binder.

또한, 폐압출성형멘트를 재생골재 또는 채움재 및 결합제로 사용하여 천연골재자원의 보호와 환경보호적 측면을 강화함과 동시에 기존 아스팔트 콘크리트가 갖고 있는 강도, 경도, 점성도, 안정도, 유연성을 고루 갖춘 개질 재생아스팔트 조성물을 제공할 수 있다.In addition, by using the waste extrusion molding as recycled aggregate or filling material and binder, the protection of natural aggregate resources and environmental protection are reinforced, and at the same time, the modified and regenerated with the strength, hardness, viscosity, stability, and flexibility of existing asphalt concrete. Asphalt compositions can be provided.

특히, 본 발명은 시멘트와 함께 별도로 플라이애쉬를 채움재로 추가사용하지 않고 플라이애쉬를 주성분으로 하며 인조섬유제를 포함하는 폐압출성형멘트를 재생골재 또는 채움재로 적용할 수 있어, 여러 다른 재료를 혼입하기 위한 추가적인 장비와 공정이 필요하지 않아 제조비용을 절감할 수 있는 효과가 있다.In particular, the present invention does not additionally use fly ash as a filling material separately with cement, and can be applied as a recycled aggregate or filling material, which is a waste extrusion mold containing fly ash as a main component and containing artificial fibers. There is an effect of reducing manufacturing cost because additional equipment and processes are not required.

이하, 본 발명의 바람직한 실시예를 상세하게 설명하기로 한다.Hereinafter, a preferred embodiment of the present invention will be described in detail.

<제1 실시예><First Example>

본 발명의 제1 실시예에 따른 폐압출성형시멘트를 이용한 개질 재생아스팔트 조성물은 폐압출성형시멘트골재를 포함하는 순환골재와, 채움재 및 결합제로 적용되는 폐압출성형시멘트미쇄분과, 유화아스팔트, 재생첨가제 및 혼합액을 포함하여 구성된다.The modified regenerated asphalt composition using the waste extrusion cement according to the first embodiment of the present invention includes a recycled aggregate including waste extrusion cement aggregate, a pulverized waste extrusion cement applied as a filler and a binder, emulsified asphalt, and a recycled additive. And a mixed solution.

여기서, 본 발명의 제1 실시예에서는 폐압출성형시멘트에 있어, 건축자재로 사용된 압출성형시멘트, 예컨대 건물의 내, 외장재(인방, 몰딩 및 이중바닥재를 포함한다.)와 방음벽의 방음패널 및 조립식 데크구조물의 데크보드에 사용된 폐압출성형시멘트를 적용한다. 이때, 폐압출성형시멘트는 시멘트, 천연섬유제, 인조섬유제, 증점제를 포함하되, 플라이애쉬를 주원료로 포함하여 제조된 것이다. Here, in the first embodiment of the present invention, in the waste extrusion cement, the extruded cement used as a building material, for example, the interior and exterior materials of the building (including linings, moldings, and double floor materials) and soundproof panels and soundproof walls of the soundproof walls, and The waste extrusion cement used for the deck board of the prefabricated deck structure is applied. At this time, the waste extrusion cement is manufactured by including cement, natural fiber, artificial fiber, and thickener, and includes fly ash as the main raw material.

그 제조과정을 살펴보면, 시멘트, 천연섬유제, 인조섬유제, 증점제 및 물로 이루어지는 조성물의 계량 및 혼합단계를 수행한다. 이때, 본 발명에서는 상기 조성물의 계량 및 혼합단계에서 플라이애쉬를 주원료로 첨가한다. 이후, 혼합물의 압출성형 및 절단단계를 수행하고, 이러한 압출물의 1차양생단계를 거치는데, 1차 양생단계에서 는 60℃ ~ 75℃의 온도에서 10 ~ 18시간 동안 상기 압출물을 1차 양생한다. 이후, 1차 양생된 압출물의 오토클레이브에서 2차 양생단계를 수행하는데, 이때에는 150℃ ~ 180℃의 온도와 80kg/cm2 ~ 10kg/cm2의 압력환경에서 10 ~ 18시간 동안 상기 1차 양생된 압출물을 세라믹화 되도록 2차 양생하여 제조된다. Looking at the manufacturing process, a step of measuring and mixing a composition consisting of cement, natural fiber, artificial fiber, thickener and water is performed. At this time, in the present invention, fly ash is added as a main material in the step of measuring and mixing the composition. Thereafter, the extrusion molding and cutting steps of the mixture are performed, and the first curing step of the extrudate is performed. In the first curing step, the extrudate is first cured at a temperature of 60°C to 75°C for 10 to 18 hours. do. Thereafter, a second curing step is performed in the autoclave of the first cured extrudate, in which case the first curing step is performed for 10 to 18 hours in a temperature of 150° C. to 180° C. and a pressure environment of 80 kg/cm 2 to 10 kg/cm 2 . It is prepared by secondary curing the cured extrudate to be ceramic.

이와 같은 압출성형시멘트는 흡수율 20(g/cm3)이하, 흡수에 대한 길이변화율 18%이하, 휨강도 12(N/mm2)이상, 허용변위량(탄성변위량) 50(mm)이하, 허용변위량(영구잔류변위량) LA/500이하의 물성값을 갖는다. Such extrusion-molded cement has an absorption rate of 20 (g/cm3) or less, a length change rate of 18% or less for absorption, a flexural strength of 12 (N/mm 2 ) or more, an allowable displacement (elastic displacement) of 50 (mm) or less, and an allowable displacement (permanent). Residual displacement) It has a property value of less than LA/500.

상기 순환골재는 KSF2572 규격인 008, 015, 03, 06 및 12, 25, 5, 10, 13, 15, 20, 25, 30, 40, 50, 60, 80, 100mm의 체에 통과시켜 체거름한 폐아스콘 또는 폐콘크리트를 입경에 따라 분류하여 수득한 폐아스콘/폐콘크리트 순환골재를 채용한다. 이와 같은 폐아스콘/폐콘크리트로 된 순환골재는 순환골재의 입경분포가 상,중,하입경으로 분포되는데, 상입경은 25~13mm의 입경이 부여됨과 아울러 순환골재 전체 중량부에 대하여 20~70중량부가 적용되고, 중입경은 13~8mm의 입경이 부여됨과 아울러 순환골재 전체 중량부에 대하여 20~50중량부가 적용된다. 아울러, 상기 상입경, 중입경에 적용되는 폐아스콘/폐콘크리트로 된 순환골재는 폐아스콘 또는 폐콘크리트를 단독으로 사용하거나 서로 혼합하여 사용할 수 있다.The recycled aggregate is sieved by passing through a sieve of KSF2572 standard 008, 015, 03, 06 and 12, 25, 5, 10, 13, 15, 20, 25, 30, 40, 50, 60, 80, 100mm. Waste ascon/waste concrete recycled aggregate obtained by classifying waste ascon or waste concrete according to particle size is employed. In such recycled aggregate made of waste ascon/waste concrete, the particle diameter distribution of the recycled aggregate is distributed in the upper, middle, and lower particle diameters, and the upper particle diameter is given a particle diameter of 25 to 13 mm and 20 to 70 parts by weight of the total weight of the recycled aggregate. A weight part is applied, and a particle diameter of 13 to 8 mm is given for the median particle diameter, and 20 to 50 parts by weight is applied to the total weight part of the recycled aggregate. In addition, the recycled aggregate made of waste ascon/waste concrete applied to the upper and medium particle diameters may be used alone or in combination with waste ascon or waste concrete.

이때, 순환골재에 있어, 하입경 순환골재는 시멘트 5~20중량부와 플라이애쉬 75~93중량부를 주원료로 하는 폐압출성형시멘트를 입경 8mm 이하로 파쇄한 폐압출성형시멘트골재를 적용한다. 이와 같은 상기 폐압출성형시멘트골재는 전술한 바와 같이 건축자재에 적용된 폐압출성형시멘트를 입경 8mm이하로 파쇄하여 얻을 수 있으며, 상기 순환골재 전체 중량부에 대하여 3~5중량부로 포함된다. 따라서, 상기와 같이 하입경 순환골재로 적용되는 폐압출성형시멘트골재는 폐아스콘/폐콘크리트로 된 순환골재(상입경, 중입경)에 대하여 낮은 강성의 성질을 갖기 때문에 상층의 하중을 하부로 전달하는 기능을 수행한다.At this time, in the recycled aggregate, the lower particle diameter recycled aggregate is a waste extrusion-molded cement aggregate made of 5 to 20 parts by weight of cement and 75 to 93 parts by weight of fly ash as the main raw materials to a particle diameter of 8 mm or less. The waste extrusion-molded cement aggregate can be obtained by crushing the waste extrusion-molded cement applied to the building material to a particle diameter of 8 mm or less as described above, and is included in 3 to 5 parts by weight based on the total weight of the recycled aggregate. Therefore, the waste extrusion molded cement aggregate applied as a lower particle diameter recycled aggregate as described above has a property of low rigidity against the recycled aggregate (upper particle diameter, medium particle diameter) made of waste ascon/waste concrete, so the load of the upper layer is transmitted to the lower side. Performs the function of

상기 채움재 및 결합제는 시멘트 5~20중량부와 플라이애쉬 75~93중량부와 폴리플로필렌섬유(PP) 또는 탄소섬유가 적용되는 인조섬유제 2중량부를 포함하는 폐압출성형시멘트를 미쇄분으로 파쇄한 폐압출성형시멘트미쇄분을 적용한다. 이와 같은 폐압출성형시멘트미쇄분은 상기 순환골재 전체 중량부에 대하여 6~8중량부로 포함된다. The filler and the binder are crushed waste extrusion cement containing 5 to 20 parts by weight of cement, 75 to 93 parts by weight of fly ash, and 2 parts by weight of man-made fiber to which polypropylene fiber (PP) or carbon fiber is applied. The waste extrusion molding cement fine powder is applied. Such waste extrusion-molded cement fine powder is included in 6 to 8 parts by weight based on the total weight of the recycled aggregate.

이때, 상기와 같이 채움재 및 결합제로 적용된 폐압출성형시멘트미쇄분은 시멘트 5~20중량부와 플라이애쉬 75~93중량부와 폴리프로필렌섬유(PP)가 적용되는 인조섬유제 2중량부를 포함하는 폐압출성형시멘트(건축자재로 사용된 폐압출성형시멘트)를 미쇄분으로 파쇄하여 얻을 수 있는 것이어서, 플라이애쉬가 갖는 특성, 즉 시멘트의 수화에 의해 생성되는 수산화칼슘이 플라이애쉬의 포졸란 반응으로 소비되고, 불용성염으로 변화하기 때문에 내산성이 향상되고, 재생 아스팔트의 조직을 치밀하게 하여 침식저항에 대하여도 우수한 장점을 갖는다. At this time, the waste extrusion molded cement pulverized powder applied as a filler and a binder as described above includes 5 to 20 parts by weight of cement, 75 to 93 parts by weight of fly ash, and 2 parts by weight of an artificial fiber to which polypropylene fiber (PP) is applied. It can be obtained by crushing molded cement (waste extrusion molded cement used as a building material) into pulverized powder, so the properties of fly ash, that is, calcium hydroxide produced by hydration of cement, are consumed by the pozzolanic reaction of fly ash and are insoluble. As it changes into salt, acid resistance is improved, and the structure of recycled asphalt is made dense, and it has excellent advantages in terms of erosion resistance.

또한, 상기 시멘트는 골재 사이의 결합력을 증가시킬 수 있으며, 아스팔트 콘크리트의 소성변형이 일어나는 것을 방지할 수 있다. In addition, the cement may increase the bonding force between the aggregates and prevent plastic deformation of asphalt concrete from occurring.

아울러, 폴리프로필렌섬유(PP)가 적용되는 인조섬유제는 재생 아스팔트의 크랙을 방지하며, 내충격성을 향상시키고, 내마모성을 향상시키는 다양한 보강기능을 하게 된다. 다시 말하면, 폴리프로필렌섬유(PP)가 적용되는 인조섬유제는 재생 아스팔트의 유동저항성, 마모저항성, 동적안정도, 균열저항성 등의 역학적 성능 및 내구성을 개선하여 소성변형(Rutting), 패임(Pothole), 밀림(Shoving, Corrugation), 블리딩, 바퀴 눌림자국 등과 장기적으로는 피로균열, 저온균열, 접속부 균열, 마모, 라벨링 및 격자균열 등의 발생을 최소화하는 것이다.In addition, the artificial fiber agent to which the polypropylene fiber (PP) is applied has various reinforcing functions to prevent cracking of recycled asphalt, improve impact resistance, and improve abrasion resistance. In other words, the artificial fiber to which polypropylene fiber (PP) is applied improves the mechanical performance and durability of recycled asphalt such as flow resistance, abrasion resistance, dynamic stability, crack resistance, etc. to improve plastic deformation (Rutting), pothole, and push. (Shoving, Corrugation), bleeding, wheel press marks, etc. In the long term, it minimizes the occurrence of fatigue cracks, low temperature cracks, joint cracks, abrasion, labeling and grid cracks.

또 다르게, 본 발명의 제1 실시예에서는 천연섬유제가 포함된 폐압출성형시멘트를 미쇄분으로 파쇄하여 채움재 및 결합제로 적용할 수 있다. 다시 말하면, 채움재 및 결합제로 적용되는 폐압출성형시멘트는 상기한 인조섬유제와 함께 천연섬유제가 포함된 것을 적용할 수 있는 것이다. 이때, 천연섬유제는 펄프가 적용되는데, 펄프는 온도편차에 따른 길이변화가 적고 내수성, 내화성, 차음성이 우수한 소재로서, 폐압출성형시멘트 전체 중량부에 대하여 2중량부로 포함된다.Alternatively, in the first embodiment of the present invention, the waste extruded cement containing natural fiber may be crushed into fine pulverized powder and applied as a filler and a binder. In other words, the waste extruded cement applied as a filler and a binder can be applied to those containing natural fibers together with the aforementioned artificial fibers. At this time, the natural fiber is pulp, which is a material having little change in length according to temperature variation and excellent in water resistance, fire resistance, and sound insulation, and is included in 2 parts by weight based on the total weight of the waste extrusion cement.

여기서, 본 발명에서와 같이 채움재 및 결합제로 폐압출성형시멘트미쇄분을 적용하면, 기존과 같은 시멘트와, 플라이애쉬 및 인조섬유제를 각, 각 순환골재에 혼합하는 과정을 생략할 수 있는 장점이 있다. 다시 말하면, 상기 폐압출성형시멘트미쇄분은 시멘트와, 플라이애쉬 및 인조섬유제를 포함하고 있기 때문에 폐압출성형시멘트미쇄분을 순환골재에 첨가하는 작업만으로 이들 성분들을 별도로 각,각 순환골재에 첨가하는 작업들을 생략할 수 있어 여러 다른 재료를 혼입하기 위한 추가적인 장비와 공정이 필요하지 않은 것이다. 아울러, 산업상 폐기물로 분류되어 주로 매립으로 처분하는 폐압출성형시멘트를 재활용할 수 있어 매립비용의 절감효과와 재활용에 따른 비용절감의 장점이 있다.Here, when the waste extrusion-molded cement pulverized powder is applied as a filler and a binder as in the present invention, there is an advantage that the process of mixing cement, fly ash, and artificial fiber as in the prior art into each and each recycled aggregate can be omitted. . In other words, since the pulverized waste extruded cement contains cement, fly ash and artificial fibers, these components are separately added to each of the recycled aggregates only by adding the crushed waste extruded cement to the recycled aggregate. Since operations can be omitted, additional equipment and processes are not required to mix different materials. In addition, since it is possible to recycle waste extrusion cement that is classified as industrial waste and is mainly disposed of by landfill, there is an advantage of reducing landfill cost and cost by recycling.

상기 유화아스팔트는 아스팔트 유제라고도 하는데 물속에서 아스팔트가 상분리 현상을 일으키지 않고 분산(分散) 상태를 유지하도록 유화제(乳化劑)를 넣은 아스팔트를 말한다. 이때, 유화제는 보통 계면활성제가 많이 쓰이는데, 양전하(+)를 띠고 있으면 양이온(cation)계 유화 아스팔트, 음전하(-)를 띠고 있으면 음이온(anion)계 유화아스팔트라고 한다. 이와 같은 유화아스팔트는 순환골재 표면과 접촉하면서 아스팔트와 물이 분리되고 아스팔트만 순환골재 표면에 달라붙는데, 이와 같이 물과 아스팔트가 분리되는 현상을 유화아스팔트의 분해라고 하며, 유화아스팔트는 가열하지 않아도 순환골재 표면에 막을 이루어 잘 달라붙는 것이 특징이다. 또한, 유화아스팔트를 사용하면 공사기간이 단축되어 경제적이며, 시공 장비가 간단해서 좁은 도로를 포장하는데 유리하며 공사 도중 화재나 화상, 공해 등의 위험이 적다는 장점이 있다.The emulsified asphalt, also known as an asphalt emulsion, refers to asphalt in which an emulsifier is added to maintain a dispersed state without causing a phase separation phenomenon in water. At this time, the emulsifier is usually a surfactant. If it has a positive charge (+), it is called a cation-based emulsified asphalt, and if it has a negative charge (-), it is called an anion-based emulsified asphalt. As such emulsified asphalt is in contact with the surface of the recycled aggregate, the asphalt and water are separated and only the asphalt adheres to the surface of the recycled aggregate. It forms a film on the surface of the aggregate and adheres well. In addition, the use of emulsified asphalt is economical because the construction period is shortened, and the construction equipment is simple, so it is advantageous for paving narrow roads, and there are advantages in that there is little risk of fire, burns, pollution, etc.

따라서, 유화아스팔트는 폐아스콘으로 된 순환골재에 부착되어 있는 기존의 아스팔트를 유화시킨 후 혼합 포설시 다시 부착가능하게 하는 기능을 수행한다. 이 유화아스팔트는 순환골재 100중량부에 대하여 01 ~ 7중량부로 포함되는 것이 바람직하다. 01중량부 미만 포함되면 순환골재에 부착되어 있는 구 아스팔트를 유화시키는 능력이 부족하게 되며, 7중량부 이상 포함하면 순환골재에 대비한 아스팔트의 양이 많아져 혼합물의 유동성과 시공성은 좋아지나 혼합물이 너무 유동하기 쉬운 상태가 되어 포장체의 강성 및 내구성이 저하된다.Therefore, the emulsified asphalt performs a function of emulsifying the existing asphalt attached to the recycled aggregate made of waste ascon and making it possible to attach again when mixing and laying. It is preferable that the emulsified asphalt is contained in an amount of 01 to 7 parts by weight based on 100 parts by weight of the recycled aggregate. If it is contained less than 01 parts by weight, the ability to emulsify the old asphalt attached to the recycled aggregate will be insufficient, and if it contains more than 7 parts by weight, the amount of asphalt compared to the recycled aggregate will increase, improving the fluidity and workability of the mixture, but It becomes too easy to flow and the rigidity and durability of the package decrease.

상기 재생첨가제 및 혼합액은 첨가제의 역할, 즉 유화아스팔트가 순환골재와 잘 융화되게 하여 제반 물성을 향상시키는 기능을 한다. 재생첨가제 및 혼합액은 순환골재 100중량부에 대하여 1~7중량부 포함되는 것이 바람직하다. 재생첨가제(일반적으로 말레산, 나트륨카르복실셀룰로오스, 물유리 등) 및 혼합액(아크릴계 수지 중합체 또는 SBR 수지 중합체와 혼합된 물)은 1중량부 미만 포함되면 너무 소량이어서 유화아스팔트의 역할을 충분히 보조하지 못하며, 7중량부 이상 포함되면 혼합액으로 사용한 물의 양이 너무 많이 혼합물내에 포함되는 결과가 되기 때문에 초기강도가 하락할 수 있다.The regenerative additive and the mixed solution function as an additive, that is, to improve general physical properties by making the emulsified asphalt well compatible with the recycled aggregate. It is preferable that the regeneration additive and the mixed solution contain 1 to 7 parts by weight based on 100 parts by weight of the recycled aggregate. Regeneration additives (generally maleic acid, sodium carboxylcellulose, water glass, etc.) and mixed liquids (water mixed with acrylic resin polymer or SBR resin polymer) are too small to support the role of emulsified asphalt if it is contained in less than 1 part by weight. If more than 7 parts by weight is included, the initial strength may decrease because too much of the amount of water used as the mixture is contained in the mixture.

이에, 본 발명의 제1 실시예에 따른 개질 재생아스팔트 조성물의 제조과정을 설명한다.Thus, the manufacturing process of the modified regenerated asphalt composition according to the first embodiment of the present invention will be described.

수집된 폐아스콘/폐콘크리트를 파쇄하여 상입경 13~25mm 순환골재 20 ~ 70중량부, 중입경 8~13mm 순환골재 20 ~ 50중량부를 선별하고, 폐압출성형시멘트를 파쇄하여 하입경 8mm 이하 순환골재 3 ~ 5중량부를 선별한다. 제조한 폐아스콘/폐콘크리트와 폐압출성형시멘트 순환골재 100중량부에 대하여 채움재 및 결합재로 적용된 폐압출성형시멘트미쇄분 6 내지 7중량부, 아스팔트 유제 1 내지 3중량부, 첨가제 1 내지 3중량부, 라텍스계 SBR 중합체 또는 아크릴계 수지 중합체와 물로 이루어진 혼합액 1 내지 6중량부의 조성물을 제조한 후 균일한 농도와 입도분포를 위하여 옴니믹서에 투입한후 혼합하여 재생아스팔트를 제조하였다. 상세한 조성은 표 1에 기재되어 있다.Collected waste ascon/waste concrete is crushed to select 20 to 70 parts by weight of recycled aggregate with a top particle diameter of 13 to 25 mm, and 20 to 50 parts by weight of recycled aggregate with a medium particle diameter of 8 to 13 mm, and crush the waste extrusion cement to circulate less than 8 mm Select 3 to 5 parts by weight of aggregate. 6 to 7 parts by weight of pulverized waste extrusion cement applied as a filler and binder, 1 to 3 parts by weight of asphalt emulsion, 1 to 3 parts by weight of additives per 100 parts by weight of manufactured waste ascon/waste concrete and waste extrusion cement recycled aggregate , After preparing a composition of 1 to 6 parts by weight of a mixture consisting of a latex-based SBR polymer or an acrylic resin polymer and water, added to an omnimixer for a uniform concentration and particle size distribution, and mixed to prepare a recycled asphalt. The detailed composition is shown in Table 1.


구분

division

중량부

Parts by weight

순환골재
(폐압출성형시멘트골재 포함)

Recycled aggregate
(Including waste extrusion cement aggregate)

상입경 20~70
중입경 20~50
하입경 3~5

Upper mouth diameter 20~70
Medium particle diameter 20~50
Lower mouth diameter 3~5

채움재 및 결합제
(폐압출성형시멘트미쇄분)

Filling material and binder
(Waste extrusion cement fine powder)


6~7


6~7

아스팔트유제

Asphalt emulsion

1~3

1~3

첨가제

additive

1~3

1~3

혼합액

Mixed liquid

1~6

1-6

다음으로 KS F 2327에 따라 폐압출성형시멘트를 하입경 순환골재와 채움재 및 결합제로 적용한 본 발명의 재생 아스팔트의 마샬안정도와 흐름값을 측정하였다. 이때, 비교예는 상기 실시예의 바람직한 배합과 다르게 하며, 채움재 및 결합재로서 시중에서 유통되는 1종 보통 포틀랜트 시멘트를 적용하여 비교시료로 삼고, KS F 2327에 따라 마샬안정도와 흐름값을 측정하였다. 상세한 측정값은 표 2에 기재되어 있다.Next, in accordance with KS F 2327, the marshall stability and flow value of the recycled asphalt of the present invention, in which the waste extruded cement was applied as a lower particle diameter recycled aggregate, a filler, and a binder were measured. At this time, the comparative example was different from the preferred formulation of the above example, and used as a comparative sample by applying a commercially available one type of ordinary portland cement as a filler and a binder, and the marshall stability and flow value were measured according to KS F 2327. Detailed measurements are listed in Table 2.

구분 division 무게(Kg)Weight(Kg) 두께(cm)Thickness(cm) 마샬안정도(Kn)Marshall stability (Kn) 흐름값(1/100cm)Flow value (1/100cm) 실시예Example 11.56911.569 6.466.46 7.9337.933 30.1630.16 비교예Comparative example 1155411554 6.386.38 5.2395.239 33.2533.25

구체적인 측정방법을 설명하면, 공시체의 제작 및 수량 및 혼합물의 시료 채취는 KS F 2350에 따랐으며, 공시체는 마샬다짐(Marshall Compactor)으로 제작하였으며, 60 ±5 ℃ 오븐에서 48시간 양생을 실시한 후, 오븐 양생이 끝난 공시체는 상온의 실내에서 2~3시간 방치 후 탈형하였다. 몰드에서 탈형된 공시체는 시험을 위해 25±1 ℃의 공기욕조에 넣고 2시간 동안 유지시켰다.Explaining the specific measurement method, the preparation and quantity of the specimen and the sample collection of the mixture were in accordance with KS F 2350, and the specimen was manufactured with Marshall Compactor, and after curing for 48 hours in an oven at 60 ±5 ℃, After oven curing, the specimens were left in the room at room temperature for 2-3 hours and then demolded. The specimen demolded from the mold was placed in an air bath at 25±1° C. for testing and maintained for 2 hours.

상기 표 2에서 알 수 있듯이, 본 발명의 실시예가 비교예와 비해 높은 마샬안정도를 나타냈으며, 흐름값 역시 낮게 나타났다.As can be seen from Table 2, the examples of the present invention exhibited higher marshall stability compared to the comparative examples, and the flow value was also lower.

아울러, 본 발명의 제1 실시예에 따른 개질 재생아스팔트 조성물에 대하여 품질시험과 검사성적을 한 결과가 표 3에 기재되어 있다.In addition, the results of quality tests and inspection results for the modified regenerated asphalt composition according to the first embodiment of the present invention are shown in Table 3.

시험검사종목Test and inspection items 단위 unit 결과 result 포화도Saturation % % 6969 공극률 Porosity % % 5.35.3 3골재피막비율3 Aggregate film ratio % % 95이상 More than 95

표 3에서 확인되는 바와 같이 포화도, 공극률, 골재피막비율이 일반 아스팔트 콘크리트보다 높은 수준으로 결과가 도출되었다. 특히, 공극률에서 매우 우수한 결과치를 보여 이는 일반 도로포장재로 사용하기에 적합한 것임을 알 수 있는데, 이는 하입경 순환골재로 적용되는 폐압출성형시멘트와, 채움재 및 결합제로 적용되는 폐압출성형시멘트미쇄분이 입자가 큰 폐아스콘 순환골재와, 폐콘크리트 순환골재의 간극을 충진하는 역할을 하며, 상기의 조성으로 이루어졌을 때 혼합물의 안정성, 감온성, 내구성 등을 개선시키고 공극률을 감소시키는 효과를 얻을 수 있는 것임을 알 수 있다. 아울러, 공극률의 감소효과는 폐아스콘 순환골재와, 폐콘크리트 순환골재의 배합을 위해 다량의 유화아스팔트와 시멘트를 소비해야하는 문제점을 해결할 수 있는 것이다.As shown in Table 3, the results were derived with higher levels of saturation, porosity, and aggregate film ratio than that of general asphalt concrete. In particular, it can be seen that it is suitable for use as a general road pavement material, showing a very good result in porosity, which is a particle of waste extrusion cement applied as a lower particle diameter recycled aggregate and waste extrusion cement applied as a filler and a binder. It is known that it serves to fill the gaps between the waste ascon recycled aggregate and the recycled concrete recycled aggregate, and when it is made of the above composition, it is possible to obtain the effect of improving the stability, temperature sensitivity, durability, etc. of the mixture and reducing the porosity. I can. In addition, the effect of reducing the porosity can solve the problem of consuming a large amount of emulsified asphalt and cement to mix the waste ascon recycled aggregate and the waste concrete recycled aggregate.

따라서, 본 발명은 천연골재를 사용함이 없이 순수히 폐아스콘, 폐콘크리트, 시멘트, 폐압출성형시멘트만을 사용하여 고갈되어가는 천연골재를 보호하고, 재생골재, 특히 폐압출성형시멘트를 사용하여 친환경적이라는 특징을 갖는 것이다. Therefore, the present invention protects the depleted natural aggregate by using only waste ascon, waste concrete, cement, and waste extrusion cement without using natural aggregate, and is eco-friendly by using recycled aggregate, especially waste extrusion cement. To have.

<제2 실시예><Second Example>

본 발명의 제2 실시예에 따른 재생 아스팔트 조성물은 채움재 또는 결합제에 접지부재로 사용된 폐압출성형시멘트를 적용한다. 다시 말하면, 본 발명의 제2 실시예에서는 폐압출성형시멘트에 있어, 전주로부터 지중으로 인출되는 접지선 또는 건물의 접지설비에서 인출되는 접지선에 연결되도록 지중에 설치되어 사용되는 접지부재로 사용된 폐압출성형시멘트를 적용한다. 이와 같이, 접지부재로 사용된 폐압출성형시멘트는 시멘트, 도전성재료, 플라이애쉬, 증점제를 포함하되, 플라이애쉬를 주원료로 포함하여 제조된 것이다. In the recycled asphalt composition according to the second embodiment of the present invention, waste extrusion cement used as a ground member is applied to a filler or a binder. In other words, in the second embodiment of the present invention, in the waste extrusion molded cement, the waste extrusion used as a grounding member installed and used in the ground so as to be connected to the ground wire drawn out from the electric pole to the ground or the ground wire drawn out from the grounding facility of the building. Apply forming cement. In this way, the waste extrusion-molded cement used as the grounding member includes cement, conductive material, fly ash, and thickener, but is manufactured by including fly ash as the main raw material.

이때, 접지부재용도의 폐압출성형시멘트는 시멘트 5~20중량부와 플라이애쉬 75~93중량부와 탄소섬유 2~20중량부를 포함하며 1,2차 양생제조된 것이다. 이에 따라, 플라이애쉬와 시멘트는 전술한 제1 실시예에서와 동일한 작용, 효과를 나타내는 것이다.At this time, the waste extrusion molded cement for the grounding member includes 5 to 20 parts by weight of cement, 75 to 93 parts by weight of fly ash, and 2 to 20 parts by weight of carbon fiber, and is manufactured by first and second curing. Accordingly, fly ash and cement exhibit the same actions and effects as in the first embodiment described above.

여기서, 탄소섬유는 길이가 5~10mm로 된 탄소섬유를 사용함이 바람직한데, 이와 같은 탄소섬유는 유기섬유를 불활성 기체 속에서 가열, 탄화하여 만든 섬유로서, 금속보다 가벼우면서도 금속에 비해 강도와 탄성이 뛰어나며 내열성, 내충격성이 좋고 부식에 강한 특징으로 가지고 있는 것으로 알려진 바, 압축 강도의 향상과 재료 간의 혼합성을 향상시켜주는 바인더(binder)역할을 하게 된다.Here, it is preferable to use carbon fibers having a length of 5 to 10 mm, and such carbon fibers are fibers made by heating and carbonizing organic fibers in an inert gas, and are lighter than metal but have strength and elasticity compared to metal. It is known to have excellent heat resistance, impact resistance, and corrosion resistance, and serves as a binder that improves the compressive strength and improves the blendability between materials.

따라서, 본 발명의 제2 실시예에 따른 재생 아스팔트 조성물은 접지부재로 사용된 폐압출성형시멘트를 미쇄분으로 파쇄하여 채움재 또는 결합제로 적용함에 따라서 입자가 큰 폐아스콘 순환골재와, 폐콘크리트 순환골재의 간극을 충진하는 역할을 하며, 혼합물의 안정성, 감온성, 내구성 등을 개선시키고 공극률을 감소시키는 효과를 얻을 수 있다. 또한, 접지부재로 사용된 폐압출성형시멘트를 사용하여 친환경적이라는 특징을 갖는 것이다. Therefore, in the recycled asphalt composition according to the second embodiment of the present invention, waste extrusion cement used as a grounding member is crushed into pulverized powder and applied as a filler or a binder, so that waste ascon recycled aggregate with large particles and recycled concrete recycled aggregate It serves to fill the gap of the mixture, and improves the stability, temperature sensitivity, durability, etc. of the mixture, and can obtain the effect of reducing the porosity. In addition, it is eco-friendly by using the waste extrusion cement used as a grounding member.

또한, 본 발명의 제2실시예에서와 같이 채움재 및 결합제로 접지부재로 사용된 폐압출성형시멘트미쇄분을 적용하면, 기존과 같은 시멘트와, 플라이애쉬 및 탄소섬유를 각, 각 순환골재에 혼합하는 과정을 생략할 수 있는 장점이 있다. 다시 말하면, 상기 폐압출성형시멘트미쇄분은 시멘트와, 플라이애쉬 및 탄소섬유를 포함하고 있기 때문에 폐압출성형시멘트미쇄분을 순환골재에 첨가하는 작업만으로 이들 성분들을 별도로 각,각 순환골재에 첨가하는 작업들을 생략할 수 있어 여러 다른 재료를 혼입하기 위한 추가적인 장비와 공정이 필요하지 않은 것이다. 아울러, 산업상 폐기물로 분류되어 주로 매립으로 처분하는 폐압출성형시멘트를 재활용할 수 있어 매립비용의 절감효과와 재활용에 따른 비용절감의 장점이 있다.In addition, as in the second embodiment of the present invention, when the pulverized waste extruded cement used as a grounding member as a filler and a binder is applied, cement, fly ash, and carbon fibers are mixed with each of the recycled aggregates. There is an advantage in that the process of doing so can be omitted. In other words, since the pulverized waste extruded cement contains cement, fly ash and carbon fiber, these components are separately added to each and each recycled aggregate only by adding the pulverized waste extruded cement to the recycled aggregate. Since operations can be omitted, additional equipment and processes are not required to mix different materials. In addition, since it is possible to recycle waste extrusion cement that is classified as industrial waste and is mainly disposed of by landfill, there is an advantage of reducing landfill cost and cost by recycling.

한편, 상기와 같은 플라이애쉬를 주원료로 하는 건축부재로 사용된 폐압출성형시멘트와 접지부재로 사용된 폐압출성형시멘트는 하입경 순환골재 또는 채움재 및 결합제로 사용할 때 50 : 50의 비율로 혼합해서 사용할 수 있다. 다시 말하면, 플라이애쉬, 시멘트, 인조섬유제를 포함하는 폐압출성형시멘트와, 플라이애쉬, 시멘트, 탄소섬유를 포함하는 폐압출성형시멘트를 50 : 50의 비율로 혼합하여 사용할 수 있는 것이다. 이에 따르면, 인조섬유제와 탄소섬유를 동시에 포함함에 따른 다양한 보강기능 및 재료 간의 혼합성을 향상시켜주는 바인더(binder)기능을 동시에 얻을 수 있는 것이다.On the other hand, the waste extrusion cement used as the main material of the above fly ash and the waste extrusion cement used as the grounding member are mixed in a ratio of 50:50 when used as a lower particle diameter recycled aggregate or as a filler and a binder. Can be used. In other words, waste extrusion cement containing fly ash, cement, and man-made fibers and waste extrusion cement containing fly ash, cement, and carbon fiber can be mixed in a ratio of 50:50. According to this, various reinforcing functions and a binder function that improves blendability between materials can be obtained at the same time by including the artificial fibers and carbon fibers at the same time.

<제3 실시예><Third Example>

본 발명의 제3 실시예에 따른 재생 아스팔트 조성물은 상기 하입경 순환골재인 폐압출성형시멘트골재 및 상기 채움재 및 결합제로 폐칼라압출시멘트를 적용한다. 이와 같은 폐칼라압출성형시멘트는 시멘트, 무기질 원료, 광물 및 인조섬유제, 증점제 및 무기질 색소를 포함하는데, 상기 무기질 원료는 상기 무기질 원료는 규사, 규회석, 모래 6호사이고, 상기 광물 및 인조섬유제는 해포석, 펄프와 인조섬유 중 어느 하나를 포함한 것이다.In the recycled asphalt composition according to the third embodiment of the present invention, waste extrusion-molded cement aggregate, which is the lower particle diameter recycled aggregate, and waste color extruded cement as the filler and binder are applied. Such waste color extrusion cement includes cement, inorganic raw materials, minerals and artificial fibers, thickeners and inorganic pigments, and the inorganic raw materials include silica sand, wollastonite, sand 6, and the mineral and artificial fibers , It contains either pulp or artificial fibers.

이때, 무기질 색소는 산화철, 합성 안료산화철, 운모, 펄라이트 중 어느 하나로 이루어지는데, 폐칼라압출성형시멘트 조성물 전체 중량부에 대하여 15 ~ 30 중량부로 첨가된다.At this time, the inorganic pigment is made of any one of iron oxide, synthetic pigment iron oxide, mica, and pearlite, and is added in an amount of 15 to 30 parts by weight based on the total weight of the waste color extrusion cement composition.

이에, 본 발명의 제3 실시예에 따른 재생 아스팔트 조성물은 상기 하입경 순환골재인 폐압출성형시멘트골재 및 상기 채움재 및 결합제로 폐칼라압출시멘트를 적용하기 위해 폐칼라압출시멘트를 입경 8mm이하로 파쇄하거나 미쇄분으로 파쇄한다.Accordingly, the recycled asphalt composition according to the third embodiment of the present invention crushes the waste color extruded cement to a particle diameter of 8 mm or less in order to apply the waste extruded cement aggregate as the lower particle diameter circulating aggregate and the filler and the binder. Or crushed with fine crushed powder.

따라서, 본 발명의 제3 실시예에 따른 재생 아스팔트 조성물은 다양한 발색효과를 줄 수 있어 기존의 검정색으로 기층용 포장에 한정되던 용도를 각종 경관포장용도로 활용할 수 있는 것이다.Therefore, the recycled asphalt composition according to the third embodiment of the present invention can provide various color development effects, and thus the use limited to the existing black pavement for the base layer can be used for various landscape pavement purposes.

한편, 전술한 실시예들은 당업자가 본 발명을 용이하게 이해하고 실시할 수 있도록 구체적인 예를 든 것일 뿐, 본 발명의 권리범위를 한정하려는 것은 아니다. 따라서, 전술한 실시예들에 대해 다양한 변형이나 변경이 가능함을 주목하여야 한다. 본 발명의 권리범위는 원칙적으로 후술되는 특허청구범위에 의해 정하여진다.Meanwhile, the above-described embodiments are merely specific examples so that those skilled in the art can easily understand and implement the present invention, and are not intended to limit the scope of the present invention. Therefore, it should be noted that various modifications or changes can be made to the above-described embodiments. In principle, the scope of the present invention is determined by the claims to be described later.

Claims (3)

상,중,하의 입경을 갖는 순환골재, 채움재 및 결합제, 유화아스팔트, 재생첨가제 및 혼합액을 포함하며, 상기 순환골재에는 시멘트 5~20중량부와 플라이애쉬 75~93중량부를 주원료로 하여 1,2차 양생제조된 폐압출성형시멘트를 입경 8mm 이하로 파쇄한 폐압출성형시멘트골재를 하입경 순환골재로 적용하되, 상기 폐압출성형시멘트골재는 상기 순환골재 전체 중량부에 대하여 3~5중량부로 포함되고, 상기 채움재 및 결합제는 시멘트 5~20중량부와 플라이애쉬 75~93중량부와 폴리프로필렌섬유가 적용되는 인조섬유제 2중량부를 포함하며 1,2차 양생제조되어 건축자재로 사용된 폐압출성형시멘트를 미쇄분으로 파쇄한 폐압출성형시멘트미쇄분을 적용하되, 상기 폐압출성형시멘트미쇄분은 상기 순환골재 전체 중량부에 대하여 6~8중량부로 포함되는 폐압출성형시멘트를 이용한 개질 재생아스팔트 조성물에 있어서,
상기 채움재 및 결합제는 시멘트 5~20중량부와 플라이애쉬 75~93중량부와 탄소섬유 2~20중량부를 포함하며 1,2차 양생제조되어 접지부재로 사용된 폐압출성형시멘트를 미쇄분으로 파쇄한 폐압출성형시멘트미쇄분이 적용됨을 특징으로 하는 폐압출성형시멘트를 이용한 개질 재생아스팔트 조성물.
Containing recycled aggregate having particle diameters of upper, middle, and lower, fillers and binders, emulsified asphalt, recycled additives, and mixed solutions, the recycled aggregate contains 5 to 20 parts by weight of cement and 75 to 93 parts by weight of fly ash as main raw materials. Apply the waste extrusion-molded cement aggregate obtained by crushing the primary curing-produced waste extrusion cement to a particle diameter of 8 mm or less as a lower particle diameter recycled aggregate, and the waste extrusion-molded cement aggregate is included in an amount of 3 to 5 parts by weight based on the total weight of the recycled aggregate. The filling material and the binder include 5 to 20 parts by weight of cement, 75 to 93 parts by weight of fly ash, and 2 parts by weight of man-made fiber to which polypropylene fiber is applied, and the first and second curing materials are used as construction materials. Reformed regenerated asphalt composition using waste extrusion-molded cement containing 6 to 8 parts by weight based on the total weight of the recycled aggregate by applying the waste extrusion-molded cement crushed cement into pulverized powder In,
The filler and binder contain 5 to 20 parts by weight of cement, 75 to 93 parts by weight of fly ash, and 2 to 20 parts by weight of carbon fiber, and are manufactured for the first and second curing, and the waste extrusion cement used as a grounding member is crushed into pulverized powder. A modified recycled asphalt composition using waste extrusion cement, characterized in that one waste extrusion cement fine powder is applied.
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100284707B1 (en) * 1999-05-14 2001-03-15 실뱅가르노 Cement board composition for the extrusion molding and method of preparing the same
KR100765675B1 (en) * 2006-08-28 2007-10-12 주식회사 벽산 Non-asbestos extrusion cement pannel and manufacturing method thereof
KR101296159B1 (en) * 2013-03-13 2013-08-28 국보환경(주) Method for manufacturing and composite of base asphalt using aged asphalt concrete and cementless binder
KR101438650B1 (en) * 2013-06-03 2014-09-12 (주)미코인더스트리 Imitation lime stone and method for fabricating the same
KR101759616B1 (en) * 2015-12-24 2017-07-20 주식회사 금송 Ascon composition

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100284707B1 (en) * 1999-05-14 2001-03-15 실뱅가르노 Cement board composition for the extrusion molding and method of preparing the same
KR100765675B1 (en) * 2006-08-28 2007-10-12 주식회사 벽산 Non-asbestos extrusion cement pannel and manufacturing method thereof
KR101296159B1 (en) * 2013-03-13 2013-08-28 국보환경(주) Method for manufacturing and composite of base asphalt using aged asphalt concrete and cementless binder
KR101438650B1 (en) * 2013-06-03 2014-09-12 (주)미코인더스트리 Imitation lime stone and method for fabricating the same
KR101759616B1 (en) * 2015-12-24 2017-07-20 주식회사 금송 Ascon composition

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