KR102143690B1 - A semi-inflammable insulation material and manufacturing method for it - Google Patents

A semi-inflammable insulation material and manufacturing method for it Download PDF

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KR102143690B1
KR102143690B1 KR1020180080283A KR20180080283A KR102143690B1 KR 102143690 B1 KR102143690 B1 KR 102143690B1 KR 1020180080283 A KR1020180080283 A KR 1020180080283A KR 20180080283 A KR20180080283 A KR 20180080283A KR 102143690 B1 KR102143690 B1 KR 102143690B1
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parts
weight
semi
silane compound
layer
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KR20190139116A (en
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류우상
박재남
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대한폴리텍(주)
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02—Physical, chemical or physicochemical properties
    • B32B7/027—Thermal properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022—Non-woven fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
    • C09D1/04—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates with organic additives
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
    • C09J183/04—Polysiloxanes
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62—Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
    • E04B1/78—Heat insulating elements
    • E04B1/80—Heat insulating elements slab-shaped
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62—Insulation or other protection; Elements or use of specified material therefor
    • E04B1/92—Protection against other undesired influences or dangers
    • E04B1/94—Protection against other undesired influences or dangers against fire
    • E04B1/941—Building elements specially adapted therefor
    • E04B1/942—Building elements specially adapted therefor slab-shaped
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B32B2260/021—Fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04—Impregnation, embedding, or binder material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/304—Insulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B32B2307/3065—Flame resistant or retardant, fire resistant or retardant

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  • Organic Chemistry (AREA)
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Abstract

본 발명은 준불연 단열재 및 이의 제조방법에 관한 것으로, 특히 난연성이 우수하며, 화재발생시 유해가스의 발생을 현저히 줄일 수 있으며, 단열성이 우수하며, 경량으로 단열재의 설치가 용이하며, 방수성이 우수하며, 강도가 우수하며, 동시에 내구성이 우수한 준불연 단열재 및 이를 생산성이 높게 제조할 수 있는 준불연 단열재의 제조방법에 관한 것이다.The present invention relates to a semi-non-combustible insulation material and a method of manufacturing the same, particularly excellent in flame retardancy, can significantly reduce the generation of harmful gases in the event of a fire, has excellent heat insulation properties, and is lightweight, easy to install the insulation material, excellent waterproofness, and , It has excellent strength, and at the same time, it relates to a method of manufacturing a semi-non-combustible insulation material that is excellent in durability and a semi-non-combustible insulation material that can be manufactured with high productivity.

Description

준불연 단열재 및 이의 제조방법{A semi-inflammable insulation material and manufacturing method for it}A semi-inflammable insulation material and manufacturing method for it}

본 발명은 준불연 단열재 및 이의 제조방법에 관한 것으로, 특히 난연성이 우수하며, 화재발생시 유해가스의 발생을 현저히 줄일 수 있으며, 단열성이 우수하며, 경량으로 단열재의 설치가 용이하며, 방수성이 우수하며, 강도가 우수하며, 동시에 내구성이 우수한 준불연 단열재 및 이를 생산성이 높게 제조할 수 있는 준불연 단열재의 제조방법에 관한 것이다.The present invention relates to a semi-non-combustible insulation material and a method of manufacturing the same, particularly excellent in flame retardancy, can significantly reduce the generation of harmful gases in the event of a fire, has excellent heat insulation properties, and is lightweight, easy to install the insulation material, excellent waterproofness, and , It has excellent strength, and at the same time, it relates to a method of manufacturing a semi-non-combustible insulation material that is excellent in durability and a semi-non-combustible insulation material that can be manufactured with high productivity.

이하에 기술되는 내용은 단순히 본 발명과 관련되는 배경 정보만을 제공할 뿐 종래기술을 구성하는 것이 아니다.The content described below merely provides background information related to the present invention and does not constitute a prior art.

실내 공간은 겨울철 난방이 이루어지고, 에어컨을 이용한 여름철 냉방이 수행되고 있으며, 이러한 실내 공간의 냉난방 효율의 증대는 단열을 통하여 얻을 수 있기 때문에, 다양한 단열재를 이용한 단열 시공이 이루어지고 있다.The indoor space is heated in winter, and cooling is performed in summer using an air conditioner, and since the increase in cooling and heating efficiency of the indoor space can be obtained through heat insulation, heat insulation construction using various insulating materials is being performed.

특히 최근 대형 화재사고로 많은 인명피해와 재산피해가 발생하였는데, 이 화재사고의 경우 건물의 외벽을 난연성능 및 불연성능이 없는 단열재, 접착몰탈, 마감재로 시공을 하는 일명 '드라이비트 공법'으로 시공을 하여 화재 확산 속도가 빨랐고 이로 인해 피해가 더욱 커진 것이 원인으로 지목되고 있다.In particular, a lot of personal and property damage has occurred due to a recent large-scale fire accident.In this case, the outer wall of the building is constructed by the so-called'dry bit method', in which the outer wall of the building is constructed with insulation, adhesive mortar, and finishing materials that do not have flame retardant and non-flammable performance. It was pointed out that the fire spread quickly, and the damage increased further.

이에 정부에서는 '건축물의 피난/방화구조 등의 기준에 관한 규칙'을 개정하여 건축물 마감재료의 화재안전성 기준을 대폭 강화하였으며, 2016년 4월부터 시행되고 있다.Accordingly, the government revised the'Rules on the Standards for Evacuation/Fire Protection of Buildings, etc.' to reinforce the fire safety standards for building finishing materials, which have been implemented since April 2016.

종래 단열 시공에 사용되는 단열재의 대표적인 예로는, 스티로폼, 발포 폴리우레탄, 발포 폴리에틸렌이 주종을 있다. 그 중에서도 폴리우레탄 계열이 가장 우수한 열전도 특성을 갖고 있어 많이 사용된다. 그러나, 단열재로 많이 사용되고 있는 발포 폴리우레탄의 경우, 화재시 인화성이 높고, 화재 초기에 다량의 유독가스가 발생되는 문제로 인해 사용상의 많은 문제점을 갖고 있다.Typical examples of heat insulating materials used in conventional heat insulation construction include styrofoam, foamed polyurethane, and foamed polyethylene. Among them, the polyurethane series is widely used because it has the most excellent heat conduction properties. However, in the case of foamed polyurethane, which is widely used as an insulating material, there are many problems in use due to the high flammability in case of fire and a large amount of toxic gas generated at the beginning of the fire.

종래 우수한 단열재를 제공하기 위하여 페놀 폼 단열재가 개발되기도 하였으나, 페놀 폼 단열재의 경우 강도가 비교적 약하고, 가공이 용이하지 않아 현장에서 단독으로 사용하기에는 한계가 있다.Conventionally, phenolic foam insulation has been developed in order to provide excellent insulation, but in the case of phenolic foam insulation, strength is relatively weak and processing is not easy, so there is a limit to use alone in the field.

또한 대한민국 특허 제1177383호에서는 단열재의 전면에 불연재를 형성하는 단계와, 상기 불연재의 전면과, 상기 단열재의 이면에 알루미늄박지를 형성하는 내화성 복합 소재 제조방법을 개시하였다. 그러나 상기 방법은 내화성 복합소재의 제조가 공정이 지나치게 복잡한 문제가 있으며, 알루미늄 박지가 쉽게 찢어지고 손상되어 단열재의 설치 및 유지에 어려움이 있어 이에 대한 개선이 절실히 요청되고 있다. In addition, Korean Patent No. 11737383 discloses a method of manufacturing a fire-resistant composite material in which a non-combustible material is formed on the front surface of an insulation material, and an aluminum foil is formed on the front surface of the non-combustible material and the rear surface of the insulation material. However, the above method has a problem that the manufacturing process of the fire-resistant composite material is too complex, and the aluminum foil is easily torn and damaged, making it difficult to install and maintain the insulation material, and thus improvement is urgently required.

대한민국특허 제1177383호Korean Patent No. 11173833

본 발명은 상기와 같은 종래기술의 문제점을 해결하기 위하여 안출된 것으로서 난연성이 우수하며, 화재발생시 유해가스의 발생을 현저히 줄일 수 있으며, 단열성이 우수하며, 경량으로 단열재의 설치가 용이하며, 방수성이 우수하며, 강도가 우수하며, 동시에 내구성이 우수한 준불연 단열재 및 이의 제조방법을 제공하는 것을 목적으로 한다.The present invention has been devised to solve the problems of the prior art as described above, has excellent flame retardancy, can significantly reduce the occurrence of harmful gases in the event of a fire, has excellent thermal insulation properties, and is lightweight and easy to install an insulation material, and has waterproof properties. An object of the present invention is to provide a semi-non-combustible heat insulator that is excellent, has excellent strength, and has excellent durability, and a method of manufacturing the same.

이러한 과제를 해결하기 위하여 본 발명은 In order to solve these problems, the present invention

단열재층과 피착체층을 포함하는 준불연 단열재로서,As a semi-non-combustible insulation material comprising an insulation layer and an adherend layer,

(a) 단열재층;(a) an insulation layer;

(b) 상기 단열재층 표면에 형성된 접착제층;(b) an adhesive layer formed on the surface of the heat insulating material layer;

(c) 상기 접착제층 표면에 형성된 피착체층을 포함하며,(c) comprising an adherend layer formed on the surface of the adhesive layer,

상기 피착체층은 부직포를 물유리 코팅액에 침지시켜 건조한 것인 준불연 단열재를 제공한다.The adherend layer provides a semi-non-combustible heat insulating material that is dried by immersing the nonwoven fabric in a water glass coating solution.

상기 (b) 물유리 코팅액은 상기 물유리 100 중량부에 대하여 (1) 알루미늄 분말 0.1 내지 20 중량부, (2) 아민기를 함유하는 실란화합물 0.01 내지 10 중량부; (3) 글리시딜기를 포함하는 실란 화합물 0.01 내지 10 중량부; 및 (4) 테트라알콕시 실란화합물 0.01 내지 10 중량부를 포함하는 것이 좋다.The (b) water glass coating solution includes (1) 0.1 to 20 parts by weight of aluminum powder, (2) 0.01 to 10 parts by weight of a silane compound containing an amine group based on 100 parts by weight of the water glass; (3) 0.01 to 10 parts by weight of a silane compound containing a glycidyl group; And (4) 0.01 to 10 parts by weight of a tetraalkoxy silane compound.

상기 (1) 아민기를 함유하는 실란화합물: (2) 글리시딜기를 포함하는 실란 화합물: (3) 테트라알콕시 실란화합물은 1-5: 1-5: 1-5의 몰비율로 결합되어 있는 것이 좋다.The (1) silane compound containing an amine group: (2) a silane compound containing a glycidyl group: (3) the tetraalkoxy silane compound is bonded in a molar ratio of 1-5: 1-5: 1-5 good.

상기 (b) 접착제층은 폴리실세스퀴옥산 수지를 포함하는 것이 좋다.It is preferable that the (b) adhesive layer contains a polysilsesquioxane resin.

또한 본 발명은 준불연 단열재의 제조방법에 있어서,In addition, the present invention in the method of manufacturing a semi-non-combustible heat insulating material,

S1) 단열재층을 준비하는 단계;S1) preparing a heat insulating material layer;

S2) 상기 단열재층 표면에 접착제층을 형성하는 단계;S2) forming an adhesive layer on the surface of the insulating material layer;

S3) 부직포를 단열재의 크기에 맞게 재단한 후 물유리 코팅액에 침지시킨 후 꺼내어 건조하여 피착체층을 준비하는 단계; 및S3) preparing an adherend layer by cutting the nonwoven fabric according to the size of the insulating material, immersing it in a water glass coating solution, taking it out and drying it; And

S4) 상기 접착제층의 표면에 피착체층을 결합하는 단계;S4) bonding an adherend layer to the surface of the adhesive layer;

를 포함하는 것을 특징으로 하는 준불연 단열재의 제조방법을 제공한다.It provides a method of manufacturing a semi-non-combustible heat insulating material comprising a.

상기 물유리 코팅액은 상기 물유리 100 중량부에 대하여 (1) 알루미늄 분말 0.1 내지 20 중량부, (2) 아민기를 함유하는 실란화합물 0.01 내지 10 중량부; (3) 글리시딜기를 포함하는 실란 화합물 0.01 내지 10 중량부; 및 (4) 테트라알콕시 실란화합물 0.01 내지 10 중량부를 포함하는 것이 좋다.The water glass coating solution includes (1) 0.1 to 20 parts by weight of aluminum powder, (2) 0.01 to 10 parts by weight of a silane compound containing an amine group based on 100 parts by weight of the water glass; (3) 0.01 to 10 parts by weight of a silane compound containing a glycidyl group; And (4) 0.01 to 10 parts by weight of a tetraalkoxy silane compound.

상기 접착제층은 폴리실세스퀴옥산 수지를 포함하는 것이 좋다.It is preferable that the adhesive layer contains a polysilsesquioxane resin.

본 발명에 따르면 난연성이 우수하며, 화재발생시 유해가스의 발생을 현저히 줄일 수 있으며, 단열성이 우수하며, 경량으로 단열재의 설치가 용이하며, 방수성이 우수하며, 강도가 우수하며, 동시에 내구성이 우수한 준불연 단열재를 제공할 수 있다.According to the present invention, it has excellent flame retardancy, can significantly reduce the occurrence of harmful gases in case of fire, has excellent insulation, and is lightweight, making it easy to install an insulation material, has excellent waterproofness, excellent strength, and at the same time excellent durability. Non-flammable insulation can be provided.

도 1은 본 발명의 일실시예에 따른 준불연 단열재의 단면모식도를 나타낸 것이다.
도 2는 본 발명의 다른 실시예에 따른 준불연 단열재의 단면모식도를 나타낸 것이다.
도 3은 본 발명의 일실시예에 따른 준불연 단열재 제조방법의 모식도를 나타낸 것이다.
도 4는 본 발명의 다른 실시예에 따른 준불연 단열재 제조방법의 모식도를 나타낸 것이다.1 is a schematic cross-sectional view of a semi-non-combustible insulating material according to an embodiment of the present invention.
Figure 2 is a schematic cross-sectional view of a semi-non-combustible insulation according to another embodiment of the present invention.
3 is a schematic diagram of a method for manufacturing a semi-non-combustible insulation material according to an embodiment of the present invention.
Figure 4 shows a schematic diagram of a method of manufacturing a semi-non-combustible insulation material according to another embodiment of the present invention.

아래에서는 첨부한 도면을 참고로 하여 본 발명의 실시예에 대하여 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자가 용이하게 실시할 수 있도록 상세히 설명한다. 그러나 본 발명은 여러 가지 상이한 형태로 구현될 수 있으며 여기에서 설명하는 실시예에 한정되지 않는다. 그리고 도면에서 본 발명을 명확하게 설명하기 위해서 설명과 관계없는 부분은 생략하였으며, 명세서 전체를 통하여 유사한 부분에 대해서는 유사한 도면 부호를 붙였다.Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings so that those skilled in the art to which the present invention pertains may easily practice. However, the present invention can be implemented in many different forms and is not limited to the embodiments described herein. In addition, in order to clearly describe the present invention in the drawings, parts irrelevant to the description are omitted, and like reference numerals are assigned to similar parts throughout the specification.

명세서 전체에서, 어떤 부분이 어떤 구성요소를 "포함"한다고 할 때, 이는 특별히 반대되는 기재가 없는 한 다른 구성요소를 제외하는 것이 아니라 다른 구성요소를 더 포함할 수 있는 것을 의미한다.Throughout the specification, when a part “includes” a certain component, it means that the component may further include other components, not to exclude other components, unless otherwise stated.

도 1은 본 발명의 일실시예에 따른 준불연 단열재의 단면모식도를 나타낸 것이고, 도 2는 본 발명의 다른 실시예에 따른 준불연 단열재의 단면모식도를 나타낸 것이고, 도 3은 본 발명의 일실시예에 따른 준불연 단열재 제조방법의 모식도를 나타낸 것이고, 도 4는 본 발명의 다른 실시예에 따른 준불연 단열재 제조방법의 모식도를 나타낸 것이다.1 is a cross-sectional schematic diagram of a semi-non-combustible insulation material according to an embodiment of the present invention, Figure 2 is a cross-sectional schematic diagram of a semi-non-combustible insulation material according to another embodiment of the present invention, Figure 3 is an embodiment of the present invention A schematic diagram of a method of manufacturing a semi-non-combustible insulation material according to an example is shown, and FIG. 4 is a schematic diagram of a method of manufacturing a semi-non-combustible insulation material according to another embodiment of the present invention.

본 발명의 준불연 단열재(100)는 단열재층(10)과 피착체층(30)을 포함하는 준불연 단열재(100)로서,The semi-non-combustible insulation material 100 of the present invention is a semi-non-combustible insulation material 100 comprising an insulation material layer 10 and an adherend layer 30,

(a) 단열재층(10); (b) 상기 단열재층(10) 표면에 형성된 접착제층(20); (c) 상기 접착제층(20) 표면에 형성된 피착체층(30)을 포함하며,(a) a heat insulating material layer 10; (b) an adhesive layer 20 formed on the surface of the heat insulating material layer 10; (c) including an adherend layer 30 formed on the surface of the adhesive layer 20,

상기 피착체층(30)은 부직포를 물유리 코팅액에 침지시켜 건조한 것을 특징으로 한다.The adherend layer 30 is characterized in that the nonwoven fabric is immersed in a water glass coating solution and dried.

본 발명의 준불연 단열재(100)는 The semi-non-combustible heat insulator 100 of the present invention

S1) 단열재층(10)을 준비하는 단계;S1) preparing a heat insulating material layer 10;

S2) 상기 단열재층(10) 표면에 접착제층(20)을 형성하는 단계;S2) forming an adhesive layer 20 on the surface of the insulating material layer 10;

S3) 부직포를 단열재의 크기에 맞게 재단한 후 물유리 코팅액에 침지시킨 후 꺼내어 건조하여 피착체층(30)을 준비하는 단계; 및S3) preparing the adherend layer 30 by cutting the nonwoven fabric according to the size of the insulating material, immersing it in a water glass coating solution, taking it out, and drying it; And

S4) 상기 접착제층(20)의 표면에 피착체층(30)을 결합하는 단계;S4) bonding the adherend layer 30 to the surface of the adhesive layer 20;

를 포함하여 제조될 수 있다.It can be prepared, including.

본 발명에서 상기 S1) 단계의 단열재층(10)으로 사용되는 단열재는 공지의 단열재가 사용될 수 있으며, 구체적인 예로 발포우레탄, 발포폴리우레아, 우레탄폼, 발포폴리이소시안누레이트(polyisocyanurate), 발포폴리스틸렌, 비드법 발포스틸렌, 압출법 발포스틸렌, 발포스티로폼, 발포에틸렌, 발포프로필렌 중 선택되는 1종 또는 2종 이상이 혼합된 것일 수 있다.In the present invention, the heat insulating material used as the heat insulating material layer 10 of the step S1) may be a known heat insulating material, and specific examples thereof are urethane foam, polyurea foam, urethane foam, polyisocyanurate foam, polystyrene foam , Bead method foamed styrene, extrusion method foamed styrene, foamed styrofoam, foamed ethylene, foamed propylene may be one or a mixture of two or more.

본 발명에서 상기 S2) 단계의 접착체층(20)에 사용되는 접착체는 단열재에 사용되는 공지의 접착제가 사용될 수 있으며, 구체적인 예로 아크릴수지접착제, 아크릴수지 접착제, 우레탄아크릴레이트와 에폭시아크릴레이트의 혼합 접착제, 우레아 수지 접착제, 폴리실세스퀴옥산 수지 중 1종 또는 2종 이상 혼합하여 사용할 수 있다.In the present invention, the adhesive used for the adhesive layer 20 of the step S2) may be a known adhesive used for an insulating material, and specific examples include acrylic resin adhesive, acrylic resin adhesive, urethane acrylate and epoxy acrylate mixture One or two or more of adhesives, urea resin adhesives, and polysilsesquioxane resins may be used in combination.

바람직하기로는 상기 접착제층(21)은 폴리실세스퀴옥산 수지를 적어도 접착제의 50 중량%를 포함하는 것이 좋으며, 더욱 바람직하기로는 60 내지 90 중량%를 포함하는 것이 좋다. 특히 상기 폴리실세스퀴옥산 수지는 (1) 아민기를 함유하는 실란화합물: (2) 글리시딜기를 포함하는 실란 화합물: (3) 테트라알콕시 실란화합물은 1-5: 1-5: 1-5의 몰비율로 결합되어 있는 폴리실세스퀴옥산 수지인 것이 좋다. 이 경우 단열재층(10)과 피착체층(30)과의 접착력이 동시에 우수하며, 난연성이 우수하며, 화재발생시 유해가스의 발생을 현저히 줄일 수 있으며, 단열성이 우수하며, 내구성이 우수하며, 강도가 우수하며, 동시에 방수성이 우수한 장점을 가질 수 있다.Preferably, the adhesive layer 21 is preferably a polysilsesquioxane resin containing at least 50% by weight of the adhesive, more preferably 60 to 90% by weight. In particular, the polysilsesquioxane resin is (1) a silane compound containing an amine group: (2) a silane compound containing a glycidyl group: (3) a tetraalkoxy silane compound is 1-5: 1-5: 1-5 It is preferable that it is a polysilsesquioxane resin bonded in a molar ratio of. In this case, the adhesion between the insulating material layer 10 and the adherend layer 30 is excellent at the same time, has excellent flame retardancy, can significantly reduce the occurrence of harmful gases in the event of a fire, is excellent in insulation, has excellent durability, and has excellent strength. It is excellent, and at the same time, it can have an advantage of excellent waterproofness.

상기 접착제의 사용량은 단열재와 피착체를 견고하게 접착시킬 수 있는 정도이면 특별히 한정되지 않으며, 구체적인 예로 단열재층(10) 100 중량부에 대하여 접착제층(20, 21) 0.1 내지 10 중량부로 형성할 수 있다.The amount of the adhesive used is not particularly limited as long as it can firmly bond the insulating material and the adherend, and a specific example may be formed in 0.1 to 10 parts by weight of the adhesive layers 20 and 21 based on 100 parts by weight of the insulating material layer 10. have.

또한 상기 접착제층(21)에는 흑연, 그라핀, 탄소나노튜브, 플러렌, 팽창성 흑연, 산화알루미늄 수화물, 삼산화안티몬, 산화비소, 암모늄 폴리포스페이트 및 황산칼슘로 이루어지는 군으로 선택되는 1종 이상의 물질을 더욱 포함할 수 있다. 상기 물질들은 각각 독립적으로 접착제 100 중량부에 대하여 0.1 내지 10 중량부의 양으로 포함될 수 있으며, 이 경우 접착제층의 난연성을 강화할 수 있다.In addition, the adhesive layer 21 further contains at least one material selected from the group consisting of graphite, graphene, carbon nanotubes, fullerene, expandable graphite, aluminum oxide hydrate, antimony trioxide, arsenic oxide, ammonium polyphosphate, and calcium sulfate. Can include. Each of the above substances may be independently included in an amount of 0.1 to 10 parts by weight based on 100 parts by weight of the adhesive, and in this case, the flame retardancy of the adhesive layer may be enhanced.

본 발명의 피착체층(30)의 준비는 부직포를 단열재의 크기에 맞게 재단한 후 물유리 코팅액에 침지시킨 후 꺼내어 건조하여 준비한다.The preparation of the adherend layer 30 of the present invention is prepared by cutting the nonwoven fabric according to the size of the insulating material, immersing it in a water glass coating solution, taking it out, and drying it.

상기 부직포는 단열재에 사용되는 공지의 부직포가 사용될 수 있으며, 구체적인 예로 종이, 폴리프로필렌, 폴리이미드, PET 재질의 부직포가 사용될 수 있으며, 내화성 섬유가 사용될 수도 있으며, 이에 한정되는 것은 아니다.The non-woven fabric may be a known non-woven fabric used for a heat insulating material, specific examples may be paper, polypropylene, polyimide, PET material non-woven fabric may be used, and fire-resistant fibers may be used, but is not limited thereto.

상기 부직포의 두께는 임의로 조절될 수 있으며, 구체적인 예로 1 내지 7 mm의 두께인 것을 사용할 수 있다.The thickness of the nonwoven fabric may be arbitrarily adjusted, and as a specific example, a thickness of 1 to 7 mm may be used.

본 발명에서 상기 물유리 코팅액은 물유리 100 중량부에 대하여 (1) 알루미늄 분말 0.1 내지 20 중량부, (2) 아민기를 함유하는 실란화합물 0.01 내지 10 중량부; (3) 글리시딜기를 포함하는 실란 화합물 0.01 내지 10 중량부; 및 (4) 테트라알콕시 실란화합물 0.01 내지 10 중량부를 포함하는 것이 좋다. 바람직하기로 상기 물유리는 내수성 물유리를 사용하는 것이 좋다.In the present invention, the water glass coating solution includes (1) 0.1 to 20 parts by weight of aluminum powder, (2) 0.01 to 10 parts by weight of a silane compound containing an amine group based on 100 parts by weight of water glass; (3) 0.01 to 10 parts by weight of a silane compound containing a glycidyl group; And (4) 0.01 to 10 parts by weight of a tetraalkoxy silane compound. Preferably, the water glass is preferably a water-resistant glass.

상기 (1) 알루미늄 분말은 장축의 길이가 1 내지 30 um인 알루미늄 분말을 사용할 수 있다. 상기 알루미늄 분말의 함량은 물유리 100 중량부에 대하여 0.1 내지 20 중량부로 포함시키는 것이 좋으며, 상기 범위 내인 경우 피착체층(30)의 기계적 강도를 향상시키며, 내수성을 동시에 만족시킬 수 있다.As the (1) aluminum powder, aluminum powder having a long axis length of 1 to 30 um may be used. The content of the aluminum powder is preferably included in an amount of 0.1 to 20 parts by weight based on 100 parts by weight of water glass. If it is within the above range, the mechanical strength of the adherend layer 30 may be improved, and water resistance may be satisfied at the same time.

상기 (2) 아민기를 함유하는 실란화합물은 구체적으로 N-2-아미노메틸-3-아미노프로필트리에톡시실란, 아미노프로필트리알콕시실란, N-2-아미노에틸-3-아미노프로필트리메톡시실란 및 N-2-아미노메틸-3-아미노프로필트리메톡시실란으로 이루어지는 군으로부터 1종 이상 선택되는 것일 수 있다. 상기 아민기를 함유하는 실란화합물의 함량은 상기 물유리 100 중량부에 대하여 0.01 내지 10 중량부로 포함시키는 것이 좋으며, 상기 범위 내인 경우 알루미늄 분말이 피착체층(30)에서 이탈되는 것을 막으면서, 피착체층(30)이 우수한 접착성과 내수성을 동시에 가지도록 할 수 있다.Specifically, the silane compound containing the (2) amine group is N-2-aminomethyl-3-aminopropyltriethoxysilane, aminopropyltrialkoxysilane, and N-2-aminoethyl-3-aminopropyltrimethoxysilane. And it may be one or more selected from the group consisting of N-2-aminomethyl-3-aminopropyltrimethoxysilane. The content of the silane compound containing the amine group is preferably included in an amount of 0.01 to 10 parts by weight based on 100 parts by weight of the water glass, and if it is within the above range, while preventing the aluminum powder from being separated from the adherend layer 30, the adherend layer 30 ) Can have excellent adhesion and water resistance at the same time.

상기 (3) 글리시딜기를 포함하는 실란 화합물은 구체적으로 3-글리시독시프로필트리메톡시실란 또는 3-글리시독시프로필트리에톡시실란을 단독 또는 혼합하여 사용하는 것일 수 있다. 상기 글리시딜기를 포함하는 실란 화합물의 함량은 상기 물유리 100 중량부에 대하여 0.01 내지 10 중량부로 포함시키는 것이 좋으며, 상기 범위 내인 경우 알루미늄 분말이 피착체층(30)에서 이탈되는 것을 막으면서, 피착체층(30)이 우수한 접착성과 내수성을 동시에 가지도록 할 수 있다.The (3) silane compound containing a glycidyl group may be specifically 3-glycidoxypropyltrimethoxysilane or 3-glycidoxypropyltriethoxysilane alone or in combination. The content of the silane compound containing the glycidyl group is preferably included in an amount of 0.01 to 10 parts by weight based on 100 parts by weight of the water glass, and if it is within the above range, while preventing the aluminum powder from being separated from the adherend layer 30, the adherend layer (30) It can be made to have excellent adhesion and water resistance at the same time.

상기 (4) 테트라알콕시 실란화합물은 구체적으로 각각의 알콕시기가 독립적으로 탄소수 1 내지 5를 가지는 테트라알콕시 실란화합물을 사용할 수 있으며, 구체적인 예로 테트라에톡시실란(TEOS)가 사용될 수 있다. 상기 테트라알콕시 실란 화합물의 함량은 상기 물유리 100 중량부에 대하여 0.01 내지 10 중량부로 포함시키는 것이 좋으며, 상기 범위 내인 경우 알루미늄 분말이 피착체층(30)에서 이탈되는 것을 막으면서, 피착체층(30)이 우수한 접착성과 내수성을 동시에 가지도록 할 수 있다.The (4) tetraalkoxy silane compound may specifically be a tetraalkoxy silane compound having 1 to 5 carbon atoms for each alkoxy group independently, and a specific example may be tetraethoxysilane (TEOS). The content of the tetraalkoxy silane compound is preferably included in an amount of 0.01 to 10 parts by weight based on 100 parts by weight of the water glass. If it is within the above range, while preventing the aluminum powder from being separated from the adherend layer 30, the adherend layer 30 It can be made to have excellent adhesion and water resistance at the same time.

바람직하기로 상기 (2) 아민기를 함유하는 실란화합물: (3) 글리시딜기를 포함하는 실란 화합물: (4) 테트라알콕시 실란화합물(TEOS)은 1-5: 1-5: 1-5의 몰비율로 혼합되는 것이 좋다. 이 경우 (2) 아민기를 함유하는 실란화합물: (3) 글리시딜기를 포함하는 실란 화합물: (4) 테트라알콕시 실란화합물(TEOS)의 결합을 통하여 형성되는 폴리실세스퀴옥산 수지 공중합체로 인하여 알루미늄 분말이 피착체층(30)에 강력하게 결합하고, 피착체층(30)의 난연성이 우수하며, 화재발생시 유해가스의 발생을 현저히 줄일 수 있으며, 단열성이 우수하며, 내구성이 우수하며, 강도가 우수하며, 동시에 방수성이 우수한 준불연 단열재를 제조할 수 있다.Preferably, the (2) silane compound containing an amine group: (3) a silane compound containing a glycidyl group: (4) tetraalkoxy silane compound (TEOS) is 1-5: 1-5: 1-5 moles It is good to mix in proportions. In this case, (2) a silane compound containing an amine group: (3) a silane compound containing a glycidyl group: (4) a polysilsesquioxane resin copolymer formed through the bonding of a tetraalkoxy silane compound (TEOS) Aluminum powder is strongly bonded to the adherend layer 30, the adherend layer 30 has excellent flame retardancy, can significantly reduce the occurrence of harmful gases in the event of a fire, has excellent insulation, excellent durability, and excellent strength. And, at the same time, it is possible to manufacture a semi-non-combustible insulating material excellent in waterproofness.

또한 상기 물유리 코팅액은 흑연, 그라핀, 탄소나노튜브, 플러렌, 팽창성 흑연, 산화알루미늄 수화물, 삼산화안티몬, 산화비소, 암모늄 폴리포스페이트 및 황산칼슘로 이루어지는 군으로 선택되는 1종 이상의 물질을 더욱 포함할 수 있다. 상기 물질들은 각각 독립적으로 물유리 100 중량부에 대하여 0.1 내지 10 중량부의 양으로 포함될 수 있으며, 이 경우 피착체층(30)의 난연성을 강화할 수 있다. In addition, the water glass coating liquid may further include at least one material selected from the group consisting of graphite, graphene, carbon nanotubes, fullerene, expandable graphite, aluminum oxide hydrate, antimony trioxide, arsenic oxide, ammonium polyphosphate, and calcium sulfate. have. Each of the above materials may be independently included in an amount of 0.1 to 10 parts by weight based on 100 parts by weight of water glass, and in this case, the flame retardancy of the adherend layer 30 may be enhanced.

본 발명에서 상기 건조의 방법은 특별히 한정되지 않으며, 50 내지 250 ℃, 0.5 내지 4.5 kgf/㎠의 압력조건에서 압착 건조할 수 있다.In the present invention, the method of drying is not particularly limited, and pressure drying may be performed under pressure conditions of 50 to 250° C. and 0.5 to 4.5 kgf/cm 2.

본 발명에서 상기 피착체층(30)은 상기 부직포를 물유리 코팅액에 침지시킨 후 꺼내어 건조함으로써 부직포 전체에 물유리 코팅액이 골고루 스며들어 건조하게 되며, 피착체층(30) 전체가 고르고 우수한 난연성을 가지며, 화재발생시 유해가스의 발생을 현저히 줄일 수 있으며, 단열성이 우수하며, 내구성이 우수하며, 강도가 우수하며, 동시에 방수성이 우수한 장점을 가지게 된다.In the present invention, the adherend layer 30 is dried by immersing the nonwoven fabric in a water glass coating solution, taking it out, and drying it, so that the water glass coating solution is evenly permeated and dried over the entire nonwoven fabric, and the entire adherend layer 30 has an even and excellent flame retardancy, and when a fire occurs. It can significantly reduce the generation of harmful gases, has excellent thermal insulation properties, excellent durability, excellent strength, and at the same time has excellent waterproof properties.

본 발명에서는 S4) 상기 접착제층(20, 21)의 표면에 피착체층(30)을 결합하여 최종 준불연 단열재(100)가 완성된다.In the present invention, S4) by bonding the adherend layer 30 to the surfaces of the adhesive layers 20 and 21, the final semi-non-combustible heat insulating material 100 is completed.

본 발명에 따른 준불연 단열재(100)는 불연성 재료인 물유리 코팅액을 사용한 피착체층(30)을 포함하여 난연성이 우수하며, 화재발생시 유해가스의 발생을 현저히 줄일 수 있으며, 단열성이 우수하며, 경량으로 단열재의 설치가 용이하며, 내구성이 우수하며, 강도가 우수하며, 동시에 방수성이 우수한 준불연 단열재를 제공할 수 있다. 바람직하기로 접착제층(21)에 폴리실세스퀴옥산 수지가 포함될 경우 피착제층(30)에 포함되어 있는 공중합체와 상호간의 접착력을 더욱 향상시켜 더욱 우수한 피착체층(30)과의 접착력을 가지게 할 수 있다.The semi-non-combustible insulation material 100 according to the present invention has excellent flame retardancy, including the adherend layer 30 using a water glass coating solution, which is a non-combustible material, can significantly reduce the occurrence of harmful gases in the event of a fire, has excellent insulation properties, and is lightweight. It is easy to install a heat insulator, has excellent durability, has excellent strength, and can provide a semi-non-combustible heat insulator having excellent waterproof properties. Preferably, when a polysilsesquioxane resin is included in the adhesive layer 21, the adhesive strength between the copolymer contained in the adhesive layer 30 and the mutually improved is further improved so that the adhesive strength with the adherend layer 30 can be improved. I can.

특히 도 3의 모식도에 따라 제조된 도 1의 준불연 단열재(실시예 1), 도 4의 모식도에 따라 제조된 도 2의 준불연 단열재(실시예 2), 상기 실시예 1에 물유리 코팅액에 흑연 1 중량%를 더욱 포함시켜 제조한 준불연 단열재(실시예 3), 및 상기 실시예 2에 접착제층 및 물유리 코팅액에 각각 흑연 1 중량%를 더욱 포함시켜 제조한 준불연 단열재(실시예 4)에 대하여 난연 특성을 측정하여 하기 표 1에 나타내었다. 준불연 2급을 만족시키는 경우 ‘○’로 표시하고, 만족시키지 못하는 경우를 ‘×’로 표시하였다.In particular, the semi-non-combustible insulation of FIG. 1 (Example 1) manufactured according to the schematic diagram of FIG. 3, the semi-non-combustible insulation of FIG. 2 manufactured according to the schematic diagram of FIG. 4 (Example 2), and graphite in the water glass coating solution in Example 1 In the semi-non-combustible insulation prepared by further including 1% by weight (Example 3), and the semi-non-combustible insulation prepared by further including 1 wt% of graphite in the adhesive layer and the water glass coating solution in Example 2, respectively (Example 4) The flame retardant properties were measured and shown in Table 1 below. If the semi-non-flammable level 2 is satisfied, it is indicated as'○', and if it is not satisfied, it is indicated as'x'.

- 가스 유해성 시험: 시험방법 KS F 2271-Gas hazard test: Test method KS F 2271

- 열방출율 시험: 시험방법 KS F ISO 5660-1-Heat release rate test: Test method KS F ISO 5660-1

구분division 실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 실시예 4Example 4 가스 유해성 시험Gas hazard test ○○ ○○ ○○ ○○ 열방출율 시험Heat release rate test ○○ ○○ ○○ ○○

상기 표 1에 나타나는 바와 같이 본 발명의 실시예들의 경우 모두 준불연 2급의 난연 특성을 나타내었다.As shown in Table 1, all of the examples of the present invention exhibited the flame retardant properties of semi-non-flammable class 2.

또한 상기 표 1에는 표시되지 않았으나 실시예 2 및 4의 경우 실시예 1에 비하여 발생된 가스의 양이 실시예 1보다 적어 더욱 우수한 난연특성을 가짐을 확인할 수 있었으며, 피착체층의 접착강도가 더욱 우수하였다.In addition, although not shown in Table 1, in the case of Examples 2 and 4, it was confirmed that the amount of gas generated compared to Example 1 was less than that of Example 1, so that it had more excellent flame retardant properties, and the adhesion strength of the adherend layer was more excellent. I did.

이상에서 본 발명의 실시예에 대하여 상세하게 설명하였지만 본 발명의 권리범위는 이에 한정되는 것은 아니고 다음의 청구범위에서 정의하고 있는 본 발명의 기본 개념을 이용한 당업자의 여러 변형 및 개량 형태 또한 본 발명의 권리범위에 속하는 것이다.Although the embodiments of the present invention have been described in detail above, the scope of the present invention is not limited thereto, and various modifications and improvements of those skilled in the art using the basic concept of the present invention defined in the following claims are also provided. It belongs to the scope of rights.

Claims (11)

단열재층과 피착체층을 포함하는 준불연 단열재로서,
(a) 단열재층;
(b) 상기 단열재층 표면에 형성된 접착제층;
(c) 상기 접착제층 표면에 형성된 피착체층을 포함하며,
상기 피착체층은 부직포를 물유리 코팅액에 침지시켜 건조한 것이며,
상기 물유리 코팅액은 상기 물유리 100 중량부에 대하여 (1) 장축의 길이가 1 내지 30 um인 알루미늄 분말 0.1 내지 20 중량부, (2) 아민기를 함유하는 실란화합물 0.01 내지 10 중량부; (3) 글리시딜기를 포함하는 실란 화합물 0.01 내지 10 중량부; 및 (4) 테트라알콕시 실란화합물 0.01 내지 10 중량부를 포함하며,
상기 (2) 아민기를 함유하는 실란화합물: (3) 글리시딜기를 포함하는 실란 화합물: (4) 테트라알콕시 실란화합물은 1-5: 1-5: 1-5의 몰비율로 포함되어 있는 것인 준불연 단열재.As a semi-non-combustible insulation material comprising an insulation layer and an adherend layer,
(a) an insulation layer;
(b) an adhesive layer formed on the surface of the heat insulating material layer;
(c) comprising an adherend layer formed on the surface of the adhesive layer,
The adherend layer is dried by immersing a nonwoven fabric in a water glass coating solution ,
The water glass coating solution includes (1) 0.1 to 20 parts by weight of aluminum powder having a length of 1 to 30 um, and (2) 0.01 to 10 parts by weight of a silane compound containing an amine group based on 100 parts by weight of the water glass; (3) 0.01 to 10 parts by weight of a silane compound containing a glycidyl group; And (4) 0.01 to 10 parts by weight of a tetraalkoxy silane compound,
The (2) silane compound containing an amine group: (3) a silane compound containing a glycidyl group: (4) the tetraalkoxy silane compound is contained in a molar ratio of 1-5: 1-5: 1-5 Phosphorus semi-noncombustible insulation. 삭제delete 삭제delete 제1항에 있어서,
상기 (b) 접착제층은 폴리실세스퀴옥산 수지를 포함하는 것을 특징으로 하는 준불연 단열재.The method of claim 1,
The (b) adhesive layer is a semi-non-combustible heat insulating material comprising a polysilsesquioxane resin. 제1항에 있어서,
상기 접착제층은 흑연, 그라핀, 탄소나노튜브, 플러렌, 팽창성 흑연, 산화알루미늄 수화물, 삼산화안티몬, 산화비소, 암모늄 폴리포스페이트 및 황산칼슘로 이루어지는 군으로 선택되는 1종 이상의 물질을 각각 독립적으로 접착제 100 중량부에 대하여 0.1 내지 10 중량부의 양으로 더욱 포함하는 것을 특징으로 하는 준불연 단열재.The method of claim 1,
The adhesive layer includes at least one material selected from the group consisting of graphite, graphene, carbon nanotubes, fullerene, expandable graphite, aluminum oxide hydrate, antimony trioxide, arsenic oxide, ammonium polyphosphate, and calcium sulfate, each independently adhesive 100 Semi-non-combustible insulating material, characterized in that it further comprises 0.1 to 10 parts by weight based on parts by weight. 제1항에 있어서,
상기 물유리 코팅액은 흑연, 그라핀, 탄소나노튜브, 플러렌, 팽창성 흑연, 산화알루미늄 수화물, 삼산화안티몬, 산화비소, 암모늄 폴리포스페이트 및 황산칼슘로 이루어지는 군으로 선택되는 1종 이상의 물질을 각각 독립적으로 물유리 100 중량부에 대하여 0.1 내지 10 중량부의 양으로 더욱 포함하는 것을 특징으로 하는 준불연 단열재.The method of claim 1,
The water glass coating solution is one or more materials selected from the group consisting of graphite, graphene, carbon nanotubes, fullerene, expandable graphite, aluminum oxide hydrate, antimony trioxide, arsenic oxide, ammonium polyphosphate, and calcium sulfate, each independently water glass 100 Semi-non-combustible insulating material, characterized in that it further comprises 0.1 to 10 parts by weight based on parts by weight. 준불연 단열재의 제조방법에 있어서,
S1) 단열재층을 준비하는 단계;
S2) 상기 단열재층 표면에 접착제층을 형성하는 단계;
S3) 부직포를 단열재의 크기에 맞게 재단한 후 물유리 코팅액에 침지시한 후 꺼내어 건조하여 피착체층을 준비하는 단계; 및
S4) 상기 접착제층의 표면에 피착체층을 결합하는 단계;
를 포함하며,
상기 물유리 코팅액은 상기 물유리 100 중량부에 대하여 (1) 장축의 길이가 1 내지 30 um인 알루미늄 분말 0.1 내지 20 중량부, (2) 아민기를 함유하는 실란화합물 0.01 내지 10 중량부; (3) 글리시딜기를 포함하는 실란 화합물 0.01 내지 10 중량부; 및 (4) 테트라알콕시 실란화합물 0.01 내지 10 중량부를 포함하며,
상기 (2) 아민기를 함유하는 실란화합물: (3) 글리시딜기를 포함하는 실란 화합물: (4) 테트라알콕시 실란화합물은 1-5: 1-5: 1-5의 몰비율로 포함되어 있는 것을 특징으로 하는 준불연 단열재의 제조방법.In the method of manufacturing a semi-non-combustible insulation material,
S1) preparing a heat insulating material layer;
S2) forming an adhesive layer on the surface of the insulating material layer;
S3) preparing an adherend layer by cutting the nonwoven fabric according to the size of the insulating material, immersing it in a water glass coating solution, taking it out and drying it; And
S4) bonding an adherend layer to the surface of the adhesive layer;
Including,
The water glass coating solution includes (1) 0.1 to 20 parts by weight of aluminum powder having a length of 1 to 30 um, and (2) 0.01 to 10 parts by weight of a silane compound containing an amine group based on 100 parts by weight of the water glass; (3) 0.01 to 10 parts by weight of a silane compound containing a glycidyl group; And (4) 0.01 to 10 parts by weight of a tetraalkoxy silane compound,
The (2) silane compound containing an amine group: (3) a silane compound containing a glycidyl group: (4) the tetraalkoxy silane compound is contained in a molar ratio of 1-5: 1-5: 1-5 Method for producing a semi-non-combustible insulation material characterized by. 삭제delete 제7항에 있어서,
상기 접착제층은 폴리실세스퀴옥산 수지를 포함하는 것을 특징으로 하는 준불연 단열재의 제조방법.The method of claim 7,
The adhesive layer is a method of manufacturing a semi-non-combustible heat insulating material, characterized in that comprising a polysilsesquioxane resin. 제7항에 있어서,
상기 접착제층은 흑연, 그라핀, 탄소나노튜브, 플러렌, 팽창성 흑연, 산화알루미늄 수화물, 삼산화안티몬, 산화비소, 암모늄 폴리포스페이트 및 황산칼슘로 이루어지는 군으로 선택되는 1종 이상의 물질을 각각 독립적으로 접착제 100 중량부에 대하여 0.1 내지 10 중량부의 양으로 더욱 포함하는 것을 특징으로 하는 준불연 단열재의 제조방법.The method of claim 7,
The adhesive layer includes at least one material selected from the group consisting of graphite, graphene, carbon nanotubes, fullerene, expandable graphite, aluminum oxide hydrate, antimony trioxide, arsenic oxide, ammonium polyphosphate, and calcium sulfate, each independently adhesive 100 Method for producing a semi-non-combustible heat insulating material, characterized in that it further comprises 0.1 to 10 parts by weight based on parts by weight. 제7항에 있어서,
상기 물유리 코팅액은 흑연, 그라핀, 탄소나노튜브, 플러렌, 팽창성 흑연, 산화알루미늄 수화물, 삼산화안티몬, 산화비소, 암모늄 폴리포스페이트 및 황산칼슘로 이루어지는 군으로 선택되는 1종 이상의 물질을 각각 독립적으로 물유리 100 중량부에 대하여 0.1 내지 10 중량부의 양으로 더욱 포함하는 것을 특징으로 하는 준불연 단열재의 제조방법.The method of claim 7,
The water glass coating solution is one or more materials selected from the group consisting of graphite, graphene, carbon nanotubes, fullerene, expandable graphite, aluminum oxide hydrate, antimony trioxide, arsenic oxide, ammonium polyphosphate, and calcium sulfate, each independently water glass 100 Method for producing a semi-non-combustible insulation, characterized in that it further comprises 0.1 to 10 parts by weight based on parts by weight.
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