KR102136201B1 - Neutralizing apparatus and pyrolysis system using thereof - Google Patents

Abstract

According to the present invention, a thermal decomposition device for thermally decomposing a polymer compound; In the thermal decomposition system comprising an extraction device for distilling the gas moving from the pyrolysis device to separate the extract from the gas and a gas combustion device configured to burn the gas and exhaust it to the outside after burning the gas, after the extraction device It is connected to the end of the gas supply pipe for neutralization is supplied with the gas in the extracted state; A neutralization tank having a vertical cylindrical structure and filling the hollow with cooling water at a certain level, and the gas supply pipe for neutralization penetrates to the lower portion of the hollow so that the gas is discharged and dissolved as cooling water; It is located on one side of the neutralization tank, has a cylindrical structure, and a certain amount of iron is filled in the hollow. When the cooling water in which the gas is dissolved from the neutralization tank is circulated, hydrochloric acid and iron are contacted with the gas and react with iron chloride to neutralize the hydrochloric acid component. Tank; A cooling water circulation supply pipe surrounding the gas supply pipe for neutralization from the upper end of the neutralization tank and penetrating from the neutralization tank to the lower side of the neutralization tank and moving from the neutralization tank to the chloride reaction tank to circulate the cooling water in which the hydrochloric acid component is neutralized inside the neutralization tank; And a neutralizing gas discharge pipe configured to wrap the cooling water circulation supply pipe at the upper end of the neutralizing tank and discharged to the cooling water of the neutralizing tank so that the gas whose neutralized hydrochloric acid component is neutralized is moved to a process means in the rear stage. A neutralizing device is provided.

Description

Neutralizing apparatus and pyrolysis system using the same

The present invention relates to a neutralization device and a thermal decomposition system using the same, and more specifically, a gas generated when a polymer compound such as waste vinyl, waste plastic, or highly pathogenic waste is introduced into a thermal decomposition device and decomposed into low molecules through heat in a vacuum. It relates to a neutralization device that can neutralize the acidic component of the dioxin and suppress the generation of dioxins and a thermal decomposition system using the same.

As modern life is modernized, livestock rearing in factory systems and polymer plastics that are used and discarded are increasing environmental pollution. Particularly, when a highly pathogenic livestock disease occurs, all of them are buried, and there is a serious problem of soil and water pollution and a high risk of disease recurrence.

Accordingly, recently, a method of thermally decomposing polymer compounds such as waste plastics or waste plastics or waste plastics such as highly pathogenic livestock has been disclosed.

In the conventional pyrolysis system, after the polymer compound is introduced into the pyrolysis device, the polymer compound is heated to 250°C to 480°C to activate the molecule by increasing the degree of disorder (entropy) than the internal energy (enthalpy) due to the endothermic reaction. When it is thermally decomposed, weak bonds are broken to generate new low-molecular (C3-C38) materials, and the distillation and separation process in which the gas generated during the thermal decomposition process is cooled and condensed by a plurality of extraction devices configured at the rear end of the thermal decomposition device It is implemented so that high-quality oil is separated from the gas, and the gas delivered from the extraction device is burned and exhausted to the outside by a gas combustion device configured at the rear end of the extraction device.

However, since the conventional pyrolysis system separates the oil from the gas through the extraction device, it is burned by the gas combustion device and exhausted to the outside, thus, when a large amount of hydrochloric acid component contained in the gas reacts with oxygen during combustion, dioxin There is a problem in that the atmosphere is polluted and components such as gas combustion devices are easily corroded by hydrochloric acid components.

In addition, since the conventional pyrolysis system has a process in which a certain amount of a polymer compound is introduced into the pyrolysis apparatus through a bogie means and thermally decomposed and then discharged to the outside of the pyrolysis apparatus in order to secure a vacuum state in the pyrolysis apparatus, the polymer compound There is a problem in that the thermal decomposition process is not continuous because it is not continuously input to the thermal decomposition apparatus, and thereby, the thermal decomposition efficiency is lowered.

In addition, the conventional pyrolysis system has a structure in which a plurality of heating pipes are arranged along the longitudinal direction while the heating means for providing heat to the pyrolysis apparatus penetrates the other side from one side in the width direction of the pyrolysis housing having a cylindrical structure, The heating pipe penetrates the pyrolytic housing is very complicated, and according to the structural complexity, maintenance is also inconvenient.

(Patent Document 0001) Registered Patent No. 10-1515287

(Patent Document 0002) Registered Patent No. 10-0551939

Therefore, an object of the present invention is to provide a neutralizing device that can suppress the generation of dioxins during combustion by a gas combustion device, and a thermal decomposition system using the neutralizing device configured to neutralize the hydrochloric acid component in the gas at the rear end of the extraction device.

In addition, an object of the present invention is a heating means is configured such that a plurality of heating pipes are arranged radially along the longitudinal direction of the pyrolysis housing on the inner circumferential surface of the pyrolysis housing having a cylindrical structure, so that the heating means is easy to configure and easy to maintain. It is to provide a neutralization device capable of enabling and a pyrolysis system using the same.

On the other hand, the object of the present invention is not limited to the object mentioned above, other objects not mentioned will be clearly understood by those skilled in the art from the following description.

To this end, according to the present invention, a thermal decomposition device for thermally decomposing a polymer compound; In the thermal decomposition system comprising an extraction device for distilling the gas moving from the pyrolysis device to separate the extract from the gas and a gas combustion device configured to burn the gas and exhaust it to the outside after burning the gas, after the extraction device It is connected to the end of the gas supply pipe for neutralization is supplied with the gas in the extracted state; A neutralization tank having a vertical cylindrical structure and filling the hollow with cooling water at a certain level, and the gas supply pipe for neutralization penetrates to the lower portion of the hollow so that the gas is discharged and dissolved as cooling water; It is located on one side of the neutralization tank, has a cylindrical structure, and a certain amount of iron is filled in the hollow. When the cooling water in which the gas is dissolved from the neutralization tank is circulated, hydrochloric acid and iron are contacted with the gas and react with iron chloride to neutralize the hydrochloric acid component. Tank; A cooling water circulation supply pipe surrounding the gas supply pipe for neutralization from the upper end of the neutralization tank and penetrating from the neutralization tank to the hollow lower portion and moving from the neutralization tank to the chlorination reaction tank to circulate the cooling water in which the hydrochloric acid component is neutralized inside the neutralization tank; And a neutralizing gas discharge pipe configured to wrap the cooling water circulation supply pipe at the upper end of the neutralizing tank and discharged to the cooling water of the neutralizing tank so that the gas whose neutralized hydrochloric acid component is neutralized is moved to a process means in the rear stage. A neutralizing device is provided.

Here, the neutralization apparatus, the cooling water circulating supply pipe is a neutralizing gas supply pipe is configured to supply gas to the inside of the cooling water circulation supply pipe, the cooling water circulation supply pipe, the cooling water by a partition wall made of zigzag in the region where the neutralizing gas supply pipe is installed When the neutralizing gas discharge pipe is configured to communicate with the upper end of the neutralizing tank, the cooling water circulation supply pipe and the neutralizing gas supply pipe have a structure supported on the upper end of the neutralizing tank. It is preferable that the cooling trap is connected to maintain the cooling state of the cooling water.

In addition, it is preferable that the iron charged in the chlorination reaction tank is configured to be replaceable in the chlorination reaction tank while the iron block having the pores is filled in the frame of the cylinder.

On the other hand, according to the present invention, the neutralizing device as described above; A pyrolysis device for thermally decomposing polymer compounds by heating; It comprises an extraction device for separating the extract from the gas by distilling the gas moved from the pyrolysis device, and a gas combustion device configured to burn the gas and exhaust it to the outside, and the thermal decomposition device continuously inputs to one side. A thermal decomposition housing in which a device is communicated to provide a space in which a polymer compound is continuously introduced therein; A heating means configured inside the thermal decomposition housing and providing heat inside the thermal decomposition housing to thermally decompose the polymer compound; And a gas moving means configured to be communicable inside the pyrolysis housing and allowing gas generated upon pyrolysis to move toward the extraction device.

Here, the thermal decomposition housing, the housing body; A cover panel covering both ends of the housing body; A through hole formed in the center of the cover panel on one side of the housing body, and a continuous injecting device communicating with a polymer compound therein; An outlet through which holes in the center of the other cover panel of the housing body are formed and thermally decomposed polymer compounds are discharged to the outside; A pyrolysis tube configured to communicate with the inlet and the outlet inside the housing body to provide a pyrolysis space in which pyrolysis is performed; A heating means inserting hole formed at a regular interval at the edge of the cover panel and allowing heating means to be inserted and supported to provide heat to the pyrolysis tube; And a cleaning door configured on the other side of the housing body to allow opening and closing of the outlet.

In addition, the heating means is arranged in a space between the housing body and the pyrolysis tube through the heating means insertion hole of the cover panel at regular intervals along the longitudinal direction of the housing body and provides heat to the pyrolysis space of the pyrolysis tube It is preferable to include an explosion-proof heater.

Therefore, according to the present invention, a neutralizing device for neutralizing the hydrochloric acid component in the gas at the rear end of the extraction device is configured to suppress the generation of dioxin during combustion by the gas combustion device.

In addition, the heating means is configured such that a plurality of heating pipes are radially arranged along the longitudinal direction of the thermal decomposition housing on the inner circumferential surface of the thermal decomposition housing of the pyrolysis apparatus having a cylindrical body structure, thereby enabling easy configuration and easy maintenance of the heating means. have.

Meanwhile, the effects of the present invention are not limited to the above-mentioned effects, and other effects not mentioned will be clearly understood by those skilled in the art from the description of the claims.

1 and 2 are plan and side views, respectively, showing the overall configuration of a pyrolysis system according to a preferred embodiment of the present invention;
3 is a view showing the configuration of a continuous injection device in the thermal decomposition system of the present invention;
4 to 8 are views showing the configuration of a pyrolysis apparatus in the pyrolysis system of the present invention, respectively; And
9 and 10 are views showing the configuration of a neutralization device in the pyrolysis system of the present invention, respectively.

Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.

1 to 10, the thermal decomposition system according to a preferred embodiment of the present invention, the thermal decomposition device 100 to thermally decompose the polymer compound, and continuously input the polymer compound to one side of the thermal decomposition device 100 The continuous injection device 200, the distillation of the gas moving from the thermal decomposition device 100 to extract the extract, such as high-quality oil, the extraction device 300, neutralizing the acidic component of the gas moved from the extraction device 300 It is composed between the neutralization device 400, the gas combustion device 500 for burning the gas whose acidic component is neutralized by the neutralization device 400, and exhausting it to the outside, and is thermally decomposed between the extraction device 300 and the neutralization device 400. And a vacuum pump 600 that allows the gas of the device 100 to move from the extraction device 300 to the neutralization device 400.

Continuous injection device 200, as shown in FIG. 3, is a device that continuously injects a polymer compound into the thermal decomposition device 100 to improve the thermal decomposition efficiency, compressed in block form, waste plastic or waste plastic or high pathogenicity Conveyor 210 where polymer compounds such as waste are moved, and grinding means 220 and crushing means 220 that allow polymer compounds moved along the conveyor 210 to have a predetermined height from the ground to be input and crushed. It is located in communication with the crushing means 220 and the macromolecular compound is crushed from the crushing means 220 so as to be freely dropped and collected so that it can communicate between the collecting means 230 and the collecting means 230 and the thermal decomposition device 100. It is configured to compress the polymer compound collected in the collection means 230, and includes compression means 240 and the like to be input to the thermal decomposition device 100.

Here, since the conveyor 210, the crushing means 220, and the collecting means 230 may have a known configuration, detailed description will be omitted.

The compressing means 240 is such that when the polymer compound is freely dropped in the collection container 231 of the collection means 230 and collected in a certain amount, the polymer compound is pressed and injected into the pyrolysis apparatus 100 from one side of the collection container 231. As a means to do this, the collection bin during stretching operation in the state configured on one side of the inside of the input path 241, the input path 241, which is configured to communicate with the pyrolysis apparatus 100 from the lower portion of the collection bin 231 of the collection means 230 (231) between the end of the injector 242 and the input path 241 and the thermal decomposition apparatus 100 to press the polymer compound collected in the lower portion to be introduced into the interior of the pyrolysis apparatus 100 through the input path 241 It includes a compression stage 243 and the like is configured to extend while having a diameter gradually smaller than the input path 241 to compress the polymer compound pressed by the input unit 242.

Here, the continuous injection device 200, between the grinding means 220 and the collecting means 230 or at least one of the collecting means 230, the inside of the thermal decomposition device 100 to maintain a vacuum A means (not shown) is configured, so that even if a polymer compound is continuously input from the outside into the pyrolysis apparatus 100, the inside of the pyrolysis apparatus 100 can be maintained in a vacuum state, more preferably, by the door means. In a state in which the path of movement of the polymer compound is shielded, it is preferable that the polymer compound is compressed into the thermal decomposition apparatus 100 after the vacuum process is performed inside the input path 241 by a vacuum means or the like.

Therefore, according to the continuous injection device 200, by continuously introducing a polymer compound into the interior of the thermal decomposition device 100, the thermal decomposition process can be continuously performed to improve the thermal decomposition efficiency.

Pyrolysis apparatus 100, as shown in Figures 4 to 8, as a device for thermally decomposing a polymer compound continuously injected from the continuous injection device 200 in a vacuum state, a continuous injection device 200 on one side The thermal decomposition housing 110 to provide a space in which a polymer compound is continuously injected therein in communication therewith, and is configured inside the thermal decomposition housing 110 and provides heat inside the thermal decomposition housing 110 so that the polymer compound is thermally decomposed. The means 120 and the pyrolytic housing 110 are configured to be communicatively inside and include gas moving means 130 for allowing the gas generated during pyrolysis to move toward the extraction device 300.

Here, the thermal decomposition device 100, a vacuum means for performing a vacuum process so that the interior of the thermal decomposition housing 110 has a vacuum state, and is rotatably installed inside the lower portion of the thermal decomposition housing 110, and the continuous injection device 200 ), it is preferable that the residue of the thermally decomposed polymer compound further includes a screw conveyor that moves from one side of the thermal decomposition housing 110 toward the other side.

The thermal decomposition housing 110 has a cylindrical body-shaped housing body 111, a cover panel 112 covering both ends of the housing body 111, and a through hole formed in the center of the cover panel 112 on one side of the housing body 111. And the continuous injection device 200 is in communication with the polymer compound is introduced into the inlet 113, the other side of the cover body 112 of the housing body 111 is formed through-hole and the residue of the thermally decomposed polymer compound to the outside The outlet 114 to be discharged, the inlet 112 and the outlet 114 inside the housing body 111 is configured to communicate with the pyrolysis tube 115 and the cover panel 112 to provide a thermal decomposition space for thermal decomposition. It is formed on the other side of the heating means insertion hole 116 and the housing body 111 so that heat is provided to the thermal decomposition pipe 115 by forming and forming a hole through the edge at a regular interval and allowing the heating means 120 to be inserted and supported. And a cleaning door 117 that enables opening and closing of the outlet 114.

Here, the components of the thermal decomposition housing 110, it is preferable to have a material having a strong corrosion resistance and heat resistance.

In addition, between the cleaning door 117 for opening and closing the outlet 114 and the housing body 111, it is preferable to maintain a vacuum state through a known packing member and a sealing structure.

The heating means 120 is spaced at regular intervals along the longitudinal direction of the housing body 111 in the space between the housing body 111 and the pyrolysis tube 115 through the heating means insertion hole 116 of the cover panel 112. It includes a plurality of explosion-proof heaters 121 that are arranged radially and provide heat to the pyrolysis space of the pyrolysis tube 115.

Explosion-proof heater 121, the housing body 111 in a state corresponding to the length of the inner peripheral surface of the housing body 111, that is, a method of being inserted from one side of the heating means insertion hole 116 of the cover panel 112 To be arranged continuously, or in the state having a length 1/2 of the length of the housing body 111, the inner circumferential surface of the housing body 111, that is, from both sides to the middle of the heating means insertion hole 116 of the cover panel 112 It may have a structure that is continuously arranged in an inserted manner.

Here, the explosion-proof heater 121, for example, has a temperature range of about 1100 ℃ APM tube can provide a temperature up to 1350 ℃, the heating element 123 in the center of the protective metal pipe 122 It is assembled and has a structure in which the heating element 123 is protected by supporting the insulator 124 having good thermal conductivity and good electrical insulation at a high temperature, and the heating element inserted into the inner space between the housing body 111 and the thermal decomposition tube 115 Part, a non-heating part having one end extended to the heating part and exposed to the outside of the housing body 111, a fixed part connected to the other end of the non-heating part, and a fixed part connected to the fixed part and transferred to the non-heating part by the heating part And a packing flange for reducing the pressure.

On the other hand, according to the present invention, when the explosion-proof heater 121 is inserted and supported between the housing body 111 and the pyrolysis tube 115, the space between the explosion-proof heater 121 is filled with a heat insulating member is explosion-proof heater ( It is preferable that the heat generated from 121) is not radiated to the outside of the housing body 111.

The gas moving means 130 is configured to be able to communicate inside the pyrolysis tube 115 and allows gas generated in the pyrolysis space to move to the rear end of the pyrolysis apparatus 100, from the outside of the housing body 111. A plurality of gas inlet pipes 131 and a plurality of gas inlet pipes 131 that allow gas to flow in through a plurality of pipes to the inside of the pyrolysis pipe 115, so that gas is collected toward the dust collection and extraction device 300. It includes a gas moving pipe 132 and the opening and closing valve 133 to open and close the gas inlet pipe 132 to be moved.

Here, each of the components of the gas moving means 130, it is preferable to have a stainless steel or titanium material that can withstand high temperatures without corrosion when contacting the gas.

On the other hand, the screw conveyor is more preferably installed in the section from the middle of the thermal decomposition tube 115 to the outlet 114, more preferably the lower inner portion of the thermal decomposition housing 110, and the thermal decomposition pipe by the continuous injection device 200 The residue (carbon, etc.) of the polymer compound to be thermally decomposed while moving (115) can be moved from the middle to the other side of the thermal decomposition pipe 115, and when the residue collection bin is separately constructed near the cleaning door 117 It is possible to reduce the cleaning time by allowing the container to be collected.

On the other hand, according to the present invention, it is preferable that the oil trap and the water trap for removing oil and water in the gas are additionally configured at the rear end of the neutralization device 400.

In addition, according to the present invention, in the early stage of the thermal decomposition process, the polymer compound is incinerated without being thermally decomposed, and thus carbon or wax is generated a lot, so the extraction device 300 except the neutralization device 400 is a combustion gas device 500 The configuration directly connected to may be simply configured so that the gas at the beginning of the process is treated separately.

Hereinafter, the thermal decomposition process of the thermal decomposition apparatus 100 according to a preferred embodiment of the present invention will be described.

First, the polymer compound, which is the object to be subjected to the thermal decomposition process, is continuously input by the continuous injection device 200 inside the thermal decomposition housing 110 of the thermal decomposition apparatus 100 and the thermal decomposition pipe 115.

Here, the continuous injection device 200 crushes the compressed polymer compound in the form of a block and continuously injects the crushed polymer compound into the thermal decomposition space of the pyrolysis tube 115 through the compression means 240.

Thereafter, the vacuum state is maintained in the thermal decomposition device 100 by a vacuum pump 600 or a vacuum means, which will be described later.

Thereafter, high heat is provided by the heating means 120 to the thermal decomposition pipe 115 of the thermal decomposition apparatus 100 to thermally decompose the polymer compound introduced into the thermal decomposition space.

Thereafter, the gas inside the thermal decomposition space generated during the thermal decomposition of the polymer compound is moved to the extraction device 300 to separate the extract, that is, oil, from the gas.

On the other hand, the residue of the polymer compound is moved to the other side of the pyrolysis tube 115 by a screw conveyor configured in the inner lower portion of the pyrolysis tube 115 and is automatically collected in the residue collection container when constructing the residue collection container.

Therefore, according to the thermal decomposition device 100, by continuously introducing a polymer compound into the interior of the thermal decomposition tube 115 from the continuous injection device 200, the thermal decomposition process can be continuously performed to improve the thermal decomposition efficiency.

In addition, the explosion-proof heater 121 in the interior of the thermal decomposition housing 110 is thermally decomposed is disposed radially at regular intervals in the longitudinal direction of the thermal decomposition housing 110, so that the housing body in the lower inner portion of the housing body 111 Compared to the conventional configuration in which the heating means 120 is installed while being penetrated in the width direction of (111), the installation configuration of the heating means 120 can be simplified and maintenance can be facilitated.

In addition, a screw conveyor configured to allow the residue of the polymer compound to be discharged to the opposite side of the input direction of the polymer compound is formed inside the housing body 111 so that the collection efficiency of the residue can be improved.

The extraction device 300 is a device for separating high-quality oil by distilling the gas moving from the gas moving means 130 of the thermal decomposition device 100, and extracting gas from the gas moving tube 132 of the gas moving means 130. The carbon removal filter means 310 for removing the residues of the carbon and polymer compounds in the gas supplied, and the gas from which the residues of the carbon and polymer compounds are removed are supplied from the carbon removal filter means 310 to extract banca oil from the gas The banca oil extracting means 320, the gas from which the banca oil is extracted from the banca oil extracting means 320 is supplied, and the gas from which the diesel is extracted from the gas extracting means 330 and the gas extracting means 330 for extracting gas oil from the gas It includes a gasoline extraction means 340 for extracting gasoline from the gas receiving the supply.

Here, the extraction device 300, the gas supply pipe through which the gas is supplied from the configuration means of the front end, the gas supplied through the gas supply pipe is cooled by an air cooling method and cooled again by a water cooling method to extract the corresponding extract in the process of gas condensation. It may be composed of a reaction tank to be extracted and a gas outflow pipe to supply the gas from which the extract is extracted from the reaction tank to a configuration means in the rear stage, and may have a known configuration, and thus detailed description will be omitted.

Therefore, according to the extraction device 300, it can be recycled as an alternative fuel through the extraction of banca oil, light oil and gasoline, etc. from the gas of the thermally decomposed polymer compound in a distillation method.

On the other hand, the neutralization apparatus 400 according to a preferred embodiment of the present invention, as shown in FIGS. 8 and 9, neutralizes the acidic component of the gas moved from the extraction apparatus 300 to the gas combustion apparatus 500 As a device for suppressing the generation of dioxin during combustion by, it is connected to the rear end of the extraction device 300, the gas supply pipe 410 for supplying the gas in the state in which the extract is extracted, has a vertical cylindrical structure and is constant in the hollow. Cooling water (not shown) at the water level is filled, and the neutralization gas supply pipe 410 penetrates to the lower side of the hollow, so that the gas is discharged and dissolved in cooling water (not shown) to neutralize the tank 420 and the neutralizing tank 420. It has a cylindrical structure and is filled with a certain amount of iron (not shown) in the hollow, and when the cooling water (not shown) in which the gas is dissolved from the neutralization tank 420 is circulated, hydrochloric acid and iron (not shown) are in contact with the gas. It is penetrated to the hollow lower part of the neutralizing tank 420 while surrounding the gas supply pipe 410 for neutralization from the upper end of the chloride reaction tank 430 and the neutralizing tank 420 to be neutralized by reacting with iron chloride. The cooling water circulation supply pipe 440 and the upper side of the neutralization tank 420 that are moved from the tank 420 to the chloride reaction tank 430 such that coolant (not shown) in which the hydrochloric acid component is neutralized is circulated inside the neutralization tank 420. It is configured to wrap the cooling water circulation supply pipe 440 at the end, and is discharged to the cooling water (not shown) of the neutralization tank 420 to neutralize the gas discharge pipe 450 to allow the hydrochloric acid component neutralized gas to be moved to the subsequent process means. Includes.

Here, the neutralization apparatus 400 may be configured in a plurality of consecutively arranged to allow the neutralization process to proceed multiple times to improve the neutralization efficiency.

In addition, since the gas supply pipe 410 for supplying gas is configured inside the cooling water circulation supply pipe 440 through which cooling water (not shown) is circulated, the gas is supplied to the neutralization tank 420 along the gas supply pipe 410 for neutralization. The gas to be cooled is cooled by cooling water (not shown) so that the amount of gas discharged and dissolved in the cooling water (not shown) is increased and neutralization efficiency can be improved.

Here, the cooling water circulation supply pipe 440 allows the cooling water (not shown) to be moved to the zigzag by a partition wall formed of zigzag at a portion where the neutralizing gas supply pipe 410 is installed, thereby cooling water (not shown) and neutralizing gas supply pipe It is preferable to increase the contact area or time of the 410 to improve the cooling efficiency of the gas.

In addition, when the neutralizing gas discharge pipe 450 is configured to communicate with the upper end of the neutralizing tank 420, the cooling water circulation supply pipe 440 and the neutralizing gas supply pipe 410 are supported through the structure supported at the upper end of the neutralizing tank 420. , It is possible to facilitate the assembly configuration and maintenance of the neutralizing device 400.

Here, the neutralization tank 420 or the chloride reaction tank 430 is preferably connected to a known cooling cycle or cooling trap to maintain the cooling state of the cooling water (not shown), through which, to improve the neutralization efficiency It is good.

In addition, the cooling water (not shown) charged in the neutralization tank 420 may have a configuration in which the filling amount is adjusted or exchanged depending on the acidity.

In addition, the iron (not shown) filled in the chloride reaction tank 430 is, for example, an iron block having a porosity, such as iron scrubber or a demister filter made of iron, in a state in which the frame of the cylinder is filled with a chloride reaction tank ( 430) is configured to be replaceable to facilitate maintenance such as replacement depending on the degree of chloride of iron (not shown).

Hereinafter, a neutralization process of the neutralization apparatus 400 according to a preferred embodiment of the present invention will be described.

First, the gas generated in the thermal decomposition device 100 is discharged to the cooling water (not shown) of the neutralization tank 420 through the gas supply pipe 410 for neutralization in a state in which extracts such as oil are separated by the extraction device 300. And dissolved.

Then, while the cooling water (not shown) is circulated to the chloride reaction tank 430 on one side of the neutralization tank 420, the iron (not shown) charged in the chloride reaction tank 430 and the hydrochloric acid component of the cooling water (not shown) contact and It reacts to neutralize the hydrochloric acid component.

Thereafter, cooling water (not shown) in which the hydrochloric acid component is neutralized is supplied to the interior of the neutralization tank 420 through the cooling water circulation supply pipe 440.

Thereafter, the gas generated in the neutralization tank 420 is moved to the gas combustion apparatus 500 through the neutralization gas discharge pipe 450.

Therefore, according to the neutralizing device 400, after the extract is extracted and supplied to the gas combustion device 500, the hydrochloric acid component in the gas is dissolved in cooling water (not shown) and reacted with iron (not shown) to neutralize it. Through the process, the hydrochloric acid component of the gas to be burned in the gas combustion apparatus 500 is reduced through the neutralization process so that the generation of dioxin during combustion of the gas combustion apparatus 500 can be suppressed.

The gas combustion apparatus 500 is a device for receiving acid-neutralized gas from the neutralizing gas discharge pipe 450 of the neutralizing apparatus 400 and combusting it, and then exhausting it to the outside. Gas is introduced from the neutralizing gas discharge pipe 450 , A combustion furnace 510 providing space for combustion and exhaust, and combustion means 520 configured inside the combustion furnace 510 to combust gas.

The combustion furnace 510 is a combustion chamber that provides a space in which gas introduced from the neutralizing gas discharge pipe 450 is burned, and may have a cylindrical structure having a predetermined height, and the gas inflow pipe through which the gas flows in and outside air from outside It is preferable that the inflow outside air inlet pipe is configured at the lower end, and a helical guide is formed on the inner wall of the hollow so that the outside air and the gas are moved in a spiral to maximize combustion efficiency.

Combustion means 520 is a means for generating a flame in the interior of the combustion furnace 510, so that the gas is burned, a communication pipe in which the gas inlet pipe and the outside air inlet pipe communicate with the lower end of the combustion furnace 510, A combustion circle connected to the end of the communication pipe and installed in an annular shape, a plurality of injection nozzles configured to protrude to be inclined at a predetermined angle from the upper surface of the combustion circle toward the inner periphery, and to inject gas and outside air, It is configured on one side of the combustion circle and consists of an ignition plug or the like, which generates a flame to ignite the gas injected from the injection nozzle and the outside air.

Therefore, according to the gas combustion apparatus 500, the aromatic element contained in the gas of the polymer compound moving to the combustion furnace 510 can be discharged to the outside after being burned by the combustion means 520.

The vacuum pump 600 is a device that is configured between the extraction device 300 and the neutralization device 400 and allows the gas of the pyrolysis device 100 to be moved from the extraction device 300 to the neutralization device 400. Since it may have a configuration, a detailed description will be omitted.

Therefore, according to the vacuum pump 600, by being located between the extraction device 300 and the neutralization device 400, the vacuum pump 600 is located between the neutralization device 400 and the gas combustion device 500 when the neutralization device ( In addition to the gas of 400), the cooling water (not shown) is moved to the gas combustion apparatus 500 to prevent a conventional problem in which gas combustion efficiency is lowered.

Hereinafter, the pyrolysis process of the pyrolysis system according to a preferred embodiment of the present invention will be described.

First, the polymer compound, which is the object to be subjected to the thermal decomposition process, is continuously input by the continuous injection device 200 inside the thermal decomposition housing 110 of the thermal decomposition apparatus 100 and the thermal decomposition pipe 115.

Here, the continuous injection device 200 crushes the compressed polymer compound in the form of a block and continuously injects the crushed polymer compound into the thermal decomposition space of the pyrolysis tube 115 through the compression means 240.

Thereafter, a vacuum state is maintained in the pyrolysis apparatus 100, the extraction apparatus 300, and the neutralization apparatus 400 by a vacuum pump 600 or a vacuum means.

Thereafter, high heat is provided by the heating means 120 to the thermal decomposition pipe 115 of the thermal decomposition apparatus 100 to thermally decompose the polymer compound introduced into the thermal decomposition space.

Thereafter, the gas inside the thermal decomposition space generated during the thermal decomposition of the polymer compound is moved to the extraction device 300 to separate the extract, that is, oil, from the gas.

Subsequently, the gas from which the extract is separated and extracted is transferred to the neutralization device 400 and neutralized while the hydrochloric acid component in the gas is reacted with iron (not shown) in a state dissolved in cooling water (not shown).

Subsequently, the gas with reduced hydrochloric acid component is transferred to the gas combustion apparatus 500 and oxidized while being discharged to the outside while the aromatic element having a bad smell is removed.

Therefore, according to the present invention, by treating the wastes such as highly pathogenic livestock or polymer compounds such as waste vinyl or waste plastic within a short period of time, it prevents contagious outbreaks caused by high pathogenic livestock and extracts alternative fuels from waste plastics or waste plastics for recycling. Improve it.

In addition, it is lighter than an incinerator that incinerates waste at high temperature and pressure when manufactured in a size that can be mounted on a truck, so that the polymer compound can be processed regardless of where the polymer compound is generated.

In the above-described present invention, specific embodiments have been described, but various modifications can be carried out without departing from the scope of the present invention. Therefore, the scope of the invention should not be determined by the described embodiments, but should be defined by the equivalents of the claims and claims.

Claims (6)

The gas generated in the thermal decomposition device 100 for thermally decomposing the polymer compound is distilled to receive the gas in the state in which the extract is extracted from the extraction device 300 for extracting the extract to supply the gas to the gas combustion device 500 In the neutralizing device,
It is connected to the rear end of the extraction device 300, the gas supply pipe 410 for neutralization is supplied with gas in the extracted state;
With a vertical cylindrical structure, a cooling water (not shown) of a certain level is filled in the hollow, and the neutralizing gas supply pipe 410 penetrates to the lower portion of the hollow to allow gas to be discharged and dissolved into cooling water (not shown). );
It is located on one side of the neutralization tank 420 and has a cylindrical structure and is filled with a predetermined amount of iron (not shown) in the hollow and hydrochloric acid and iron in the gas during circulation of cooling water (not shown) in which gas is dissolved from the neutralization tank 420 (Not shown) is in contact with the chloride reaction tank 430 to react with iron chloride to neutralize the hydrochloric acid component;
While encapsulating the gas supply pipe 410 for neutralization from the upper end of the neutralization tank 420, it penetrates to the hollow lower portion of the neutralization tank 420 and moves from the neutralization tank 420 to the chloride reaction tank 430 to neutralize the hydrochloric acid component. A cooling water circulation supply pipe 440 to allow the cooled water (not shown) to circulate inside the neutralization tank 420; And
It is configured to wrap the cooling water circulation supply pipe 440 at the upper end of the neutralization tank 420 and is discharged to the cooling water (not shown) of the neutralization tank 420 to neutralize the gas in which the hydrochloric acid component is neutralized to be moved to the process means in the rear stage. Neutralization device comprising a gas discharge pipe (450). According to claim 1,
A gas supply pipe 410 for neutralization in which gas is supplied to the inside of the cooling water circulation supply pipe 440 through which cooling water (not shown) is circulated is formed,
Cooling water circulation supply pipe 440,
Cooling water (not shown) is moved to the zigzag by a partition wall formed of zigzag at the site where the neutralizing gas supply pipe 410 is installed,
When the neutralizing gas discharge pipe 450 is in communication with the upper end of the neutralizing tank 420, the cooling water circulation supply pipe 440 and the neutralizing gas supply pipe 410 have a structure supported on the upper end of the neutralizing tank 420,
A neutralization device characterized in that a cooling cycle or a cooling trap is connected to the neutralization tank 420 or the chloride reaction tank 430 to maintain the cooling state of the cooling water (not shown). The method of claim 2, wherein the iron (not shown) is charged in the chloride reaction tank 430,
Neutralization device characterized in that the iron block having a porous structure is configured to be replaceable in the chloride reaction tank 430 while being filled in the frame of the cylinder. The neutralizing apparatus 400 according to any one of claims 1 to 3;
A thermal decomposition device 100 for heating and decomposing a polymer compound;
Extraction device 300 for distilling the gas moving from the pyrolysis device 100 to separate the extract in the gas; And
It is configured at the rear end of the extraction device 300 and includes a gas combustion device 500 that exhausts the gas and then exhausts it to the outside.
Pyrolysis device 100,
A continuous decomposition device 200 in communication with one side, a thermal decomposition housing 110 that provides a space for continuously introducing a polymer compound therein;
A heating means 120 configured inside the thermal decomposition housing 110 and providing heat inside the thermal decomposition housing 110 to thermally decompose the polymer compound; And
Pyrolysis system, characterized in that it comprises a gas transfer means (130) configured to be communicatively inside the pyrolysis housing (110) and to move the gas generated during pyrolysis toward the extraction device (300). The method of claim 4, wherein the thermal decomposition housing 110,
Housing body 111;
A cover panel 112 covering both ends of the housing body 111;
A through hole 113 formed through a central portion of the cover panel 112 of one side of the housing body 111 and a continuous injection device 200 communicating therewith to input a polymer compound therein;
An outlet 114 through which holes in the center of the other cover panel 112 of the housing body 111 are formed and the residues of the thermally decomposed polymer compound are discharged to the outside;
A pyrolysis tube 115 configured to communicate with the inlet 112 and the outlet 114 inside the housing body 111 to provide a pyrolysis space where pyrolysis is performed;
A heating means insertion hole 116 which is formed through a radially spaced hole at the edge of the cover panel 112 and allows the heating means 120 to be inserted and supported to provide heat to the pyrolysis tube 115; And
Pyrolysis system, characterized in that it comprises a cleaning door (117) that is configured on the other side of the housing body 111 to enable the opening and closing of the outlet (114). According to claim 5, The heating means 120,
The space between the housing body 111 and the pyrolysis tube 115 through the heating means insertion hole 116 of the cover panel 112 is arranged radially at regular intervals along the longitudinal direction of the housing body 111 and the pyrolysis tube ( Pyrolysis system, characterized in that it comprises a plurality of explosion-proof heaters 121 to provide heat to the pyrolysis space of 115).

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