KR102133884B1 - 섬유 원료 상에 촉매를 고정화하는 방법, 수득한 섬유 원료 및 이 원료의 용도 - Google Patents

섬유 원료 상에 촉매를 고정화하는 방법, 수득한 섬유 원료 및 이 원료의 용도 Download PDF

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KR102133884B1
KR102133884B1 KR1020147034655A KR20147034655A KR102133884B1 KR 102133884 B1 KR102133884 B1 KR 102133884B1 KR 1020147034655 A KR1020147034655 A KR 1020147034655A KR 20147034655 A KR20147034655 A KR 20147034655A KR 102133884 B1 KR102133884 B1 KR 102133884B1
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catalyst
organic
groups
organic catalyst
polymer support
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KR20150021931A (ko
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지웡 이
벤자민 리스트
클라우스 옵비스
갈 토마스 마이어
요헨 스테판 구트만
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슈투디엔게젤샤프트 콜레 엠베하
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/123—Organometallic polymers, e.g. comprising C-Si bonds in the main chain or in subunits grafted to the main chain
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    • B01J31/0257—Phosphorus acids or phosphorus acid esters
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    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
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    • C07C67/29—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by introduction of oxygen-containing functional groups
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    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
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    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
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    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/44—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing nitrogen and phosphorus
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    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
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    • D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
    • D06M14/20—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin
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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Plasma & Fusion (AREA)
  • Electromagnetism (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
KR1020147034655A 2012-05-31 2013-05-28 섬유 원료 상에 촉매를 고정화하는 방법, 수득한 섬유 원료 및 이 원료의 용도 Expired - Fee Related KR102133884B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12170144.5A EP2669009A1 (en) 2012-05-31 2012-05-31 Process for the immobilization of catalysts on textile materials, the obtained textile materials and the use of said materials
EP12170144.5 2012-05-31
PCT/EP2013/060991 WO2013178640A1 (en) 2012-05-31 2013-05-28 Process for the immobilization of catalysts on textile materials, the obtained textile materials and the use of said materials

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KR20150021931A KR20150021931A (ko) 2015-03-03
KR102133884B1 true KR102133884B1 (ko) 2020-07-15

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US (1) US20150158021A1 (https=)
EP (2) EP2669009A1 (https=)
JP (1) JP6270826B2 (https=)
KR (1) KR102133884B1 (https=)
IL (1) IL235889A0 (https=)
IN (1) IN2014DN09850A (https=)
WO (1) WO2013178640A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
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US10837949B1 (en) * 2012-03-22 2020-11-17 Piers Richard Warburton Peracetic acid sensor with filter to remove hydrogen peroxide
CN107469858B (zh) * 2017-09-13 2019-11-15 石家庄学院 一种季戊四醇固载的手性二胺衍生硫脲催化剂及其制备方法与应用
AU2024346577A1 (en) 2023-09-19 2026-03-19 Studiengesellschaft Kohle Ggmbh Process for preparing a self-supported chiral catalyst polymer and the so-obtained catalyst polymer

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU483290B2 (en) * 1974-01-18 1976-07-15 Unisearch Limited Surface- grafted inert core copolymers for the preparation of water-insoluble enzymes
GB1517662A (en) * 1976-03-12 1978-07-12 California Inst Of Techn Photochemical preparation of catalysts for addition reactions of olefines
JPS577259A (en) * 1980-06-18 1982-01-14 Japan Organo Co Ltd Catalyst used in organic reaction
US4377681A (en) * 1982-03-04 1983-03-22 Monsanto Company Liquid crystal copolyesters
JP2846975B2 (ja) * 1991-07-10 1999-01-13 日本原子力研究所 反応蒸留用固体酸触媒
US5874165A (en) * 1996-06-03 1999-02-23 Gore Enterprise Holdings, Inc. Materials and method for the immobilization of bioactive species onto polymeric subtrates
WO1998050152A1 (en) * 1997-05-07 1998-11-12 Olah George A Nanoscale solid superacid catalysts with pendant fluoroalkylsulfonic acid or fluoro, perfluoroalkylsulfonic acid groups
DE10061981C2 (de) 2000-12-13 2003-03-27 Webasto Vehicle Sys Int Gmbh Fahrzeugdach mit einer Dachöffnung und zumindest einem bewegbaren Deckel
CN100410234C (zh) * 2003-04-25 2008-08-13 东亚合成株式会社 利用手性布朗斯台德酸的不对称合成用催化剂和使用该催化剂的不对称合成方法
DE102005011926B4 (de) * 2004-03-16 2014-08-21 Deutsches Textilforschungszentrum Nord-West E.V. Verfahren zur photochemischen Immobilisierung von Proteinen an polymeren Trägermaterialien
DE102007006874A1 (de) * 2007-02-07 2008-08-14 Deutsches Textilforschungszentrum Nord-West E.V. Textile Materialien mit daran fixierten metallorganischen Katalysatoren
JP2012200702A (ja) * 2011-03-28 2012-10-22 Kurita Water Ind Ltd 固体酸触媒および固体酸触媒反応器
JP2012250160A (ja) * 2011-06-01 2012-12-20 Univ Of Tsukuba 活性酸素種の消去方法及びそのための製剤
EP2615098A1 (en) * 2012-01-10 2013-07-17 Studiengesellschaft Kohle mbH Chiral imidodiphosphates and derivatives thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ENGINEERING TRASACTIONS, Vol.20, pp.19~24 (2010.)

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WO2013178640A1 (en) 2013-12-05
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