KR102104627B1 - Manufacturing method of functional ceramic block and functional ceramic block produced by the same - Google Patents
Manufacturing method of functional ceramic block and functional ceramic block produced by the same Download PDFInfo
- Publication number
- KR102104627B1 KR102104627B1 KR1020190154659A KR20190154659A KR102104627B1 KR 102104627 B1 KR102104627 B1 KR 102104627B1 KR 1020190154659 A KR1020190154659 A KR 1020190154659A KR 20190154659 A KR20190154659 A KR 20190154659A KR 102104627 B1 KR102104627 B1 KR 102104627B1
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- parts
- ceramic block
- antibacterial
- deodorizing
- Prior art date
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/0022—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof obtained by a chemical conversion or reaction other than those relating to the setting or hardening of cement-like material or to the formation of a sol or a gel, e.g. by carbonising or pyrolysing preformed cellular materials based on polymers, organo-metallic or organo-silicon precursors
- C04B38/0025—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof obtained by a chemical conversion or reaction other than those relating to the setting or hardening of cement-like material or to the formation of a sol or a gel, e.g. by carbonising or pyrolysing preformed cellular materials based on polymers, organo-metallic or organo-silicon precursors starting from inorganic materials only, e.g. metal foam; Lanxide type products
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B30/00—Compositions for artificial stone, not containing binders
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3232—Titanium oxides or titanates, e.g. rutile or anatase
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3244—Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3272—Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3284—Zinc oxides, zincates, cadmium oxides, cadmiates, mercury oxides, mercurates or oxide forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
Abstract
Description
본 발명은 항균, 탈취, 음이온 발생 및 원적외선 방사 효과가 있는 기능성 세라믹 블록의 제조방법 및 이에 의해 제조된 기능성 세라믹 블록에 관한 것이다. The present invention relates to a method for manufacturing a functional ceramic block having antibacterial, deodorizing, anion generation and far infrared radiation effects, and a functional ceramic block produced thereby.
세라믹(ceramic)은 무기물질이 주원료인 산화물(oxide), 질화물(nitride), 탄화물(carbide) 등의 재료를 의미한다. 이러한 재료들은 금속재료, 유기재료에 비하여 내식성, 내열성, 내마모성 등이 매우 크며, 광학적 기능, 생체적 기능, 전자기적 기능, 기계적 기능 등의 다양한 기능을 갖는다고 알려져 있다. 따라서, 시멘트, 유리, 법랑, 내화물, 단열재, 건축용 점토제품, 도자기, 유리섬유 등 우리 주변에서 흔히 볼 수 있는 제품은 물론, 컴퓨터의 기억 소자, 반도체, 특수 무기 제품, 초전도 제품 등 첨단 제품의 주재료로 사용되고 있다.Ceramic (ceramic) means a material such as an oxide (oxide), nitride (nitride), carbide (carbide), the main raw material of which is an inorganic material. These materials are known to have very high corrosion resistance, heat resistance, abrasion resistance, and the like, compared to metal materials and organic materials, and have various functions such as optical functions, biological functions, electromagnetic functions, and mechanical functions. Therefore, cement, glass, enamel, refractory materials, insulation materials, clay products for construction, ceramics, glass fibers, etc., as well as products commonly found around us, as well as computer storage devices, semiconductors, special inorganic products, and superconducting products are the main materials Is being used as
특히, 세라믹은 종류에 따라 열을 가하게 되면 전자파의 일종인 원적외선이 방출된다고 알려지고 있어 이를 이용하여 원적외선을 방출하는 세라믹을 함유함으로써 건강이 증진되도록 제조된 의복, 세라믹이 함유되어 원적외선이 방출되는 파스, 세라믹을 함유한 찜질용 매트 등 세라믹의 원적외선 방출을 이용한 제품들이 개발되고 있다. In particular, ceramics are known to emit far-infrared radiation, which is a kind of electromagnetic wave, when heat is applied depending on the type. , Products that use far-infrared emission of ceramics, such as mats for poultice containing ceramics, are being developed.
또한, 세라믹은 항균 제품에도 이용이 되고 있는데, 세라믹을 이용한 항균 제품의 경우, 항균력이 그다지 높지 않다는 단점이 있다. 따라서, 원적외선 방출이나 음이온 방출 효과 및 강력한 항균 효과를 갖고 있을 뿐만 아니라, 보다 다양한 기능을 갖는 세라믹 제품에 대한 요구가 높아지고 있다.In addition, ceramics are also used in antibacterial products. In the case of antibacterial products using ceramics, there is a disadvantage that the antibacterial power is not very high. Therefore, not only has a far infrared ray emission or anion emission effect and a strong antibacterial effect, there is an increasing demand for ceramic products having more various functions.
게다가 환풍 및 환기가 잘 되지 않는 집은 벽면에 곰팡이가 생기게 되는데 홈인테리어나 거실 또는 방 벽체에 적용되어 곰팡이 생성을 방지하고 탈취 기능을 나타내는 제품은 거의 전무한 실정이며, 실내 인테리어에 많이 사용되고 있는 인조 대리석은 화재에 취약한 부분이 있는데, 이를 보완하여 화재 예방에 도움이 되는 인조 대리석의 개발도 요구되고 있다. In addition, the poor ventilation and ventilated houses have mold on the walls. Products applied to home interiors, living rooms, or room walls to prevent mold formation and exhibit deodorizing functions are almost completely unused. Silver is vulnerable to fire, and it is also required to develop artificial marble that supplements this and helps prevent fire.
기능성 세라믹과 관련된 선행기술로는 한국등록특허 제0916739호에 원적외선 방사율을 가지는 천연 광물들을 일정한 비율로 배합 및 소성하여 완료되는 원적외선 방사 세라믹 볼의 제조방법이 개시되어 있고, 한국공개특허 제2004-0089250호에 각섬석과 사문석을 혼합하여 냉장고용 세라믹 탈취제 및 이의 제조방법이 개시되어 있지만, 본 발명의 Na2O, SiO2, MgO, Al2O3, SO3, Cl, K2O, CaO, TiO2, Fe2O3, ZnO 및 ZrO2를 포함하는 액상 세라믹을 가열 발포시켜 고체로 변환시키는 기능성 세라믹 블록의 제조방법 및 이에 의해 제조된 기능성 세라믹 블록에 관해 개시된 바 없다. Prior art related to functional ceramics discloses a method of manufacturing a far-infrared emitting ceramic ball, which is completed by mixing and firing natural minerals having far-infrared emissivity at a constant rate in Korean Patent Registration No. 0916739, and Korean Patent Publication No. 2004-0089250 A mixture of amphibole and serpentine in the arc discloses a ceramic deodorant for a refrigerator and a method for manufacturing the same, but Na 2 O, SiO 2 , MgO, Al 2 O 3 , SO 3 , Cl, K 2 O, CaO, TiO of the present invention is disclosed. No. 2 , Fe 2 O 3 , ZnO and ZrO 2 liquid ceramics are heated and foamed to produce a functional ceramic block for converting to a solid, and the functional ceramic block produced thereby has not been disclosed.
본 발명은 상기와 같은 요구에 의해 도출된 것으로, The present invention is derived by the above-mentioned needs,
1) Na2O, SiO2, MgO, Al2O3, SO3, Cl, K2O, CaO, TiO2, Fe2O3, ZnO 및 ZrO2를 포함하는 액상 바이오 세라믹을 제조하는 단계; 및1) preparing a liquid bioceramic comprising Na 2 O, SiO 2 , MgO, Al 2 O 3 , SO 3 , Cl, K 2 O, CaO, TiO 2 , Fe 2 O 3 , ZnO and ZrO 2 ; And
2) 상기 단계 1)에서 제조한 액상 바이오 세라믹을 가열 발포시켜 고체로 변화시키는 단계;를 포함하는 기능성 세라믹 블록의 제조방법을 제공하고, 상기 제조방법으로 제조된 세라믹 블록의 항균, 탈취, 음이온 발생 및 원적외선 방사 효과를 확인함으로써, 본 발명을 완성하였다.2) providing a method of manufacturing a functional ceramic block comprising a step of heating and foaming the liquid bioceramic prepared in step 1) into a solid, and generating antibacterial, deodorizing, and negative ions of the ceramic block manufactured by the manufacturing method. And by confirming the far-infrared radiation effect, the present invention was completed.
상기 과제를 해결하기 위하여, 본 발명은In order to solve the above problems, the present invention
1) Na2O, SiO2, MgO, Al2O3, SO3, Cl, K2O, CaO, TiO2, Fe2O3, ZnO 및 ZrO2를 포함하는 액상 바이오 세라믹을 제조하는 단계; 및1) preparing a liquid bioceramic comprising Na 2 O, SiO 2 , MgO, Al 2 O 3 , SO 3 , Cl, K 2 O, CaO, TiO 2 , Fe 2 O 3 , ZnO and ZrO 2 ; And
2) 상기 단계 1)에서 제조한 액상 바이오 세라믹을 가열 발포시켜 고체로 변화시키는 단계;를 포함하는 기능성 세라믹 블록의 제조방법을 제공한다. 2) a step of heating and foaming the liquid bioceramic prepared in step 1) into a solid to provide a method of manufacturing a functional ceramic block comprising the same.
또한, 본 발명은 상기 제조방법으로 제조된 세라믹 블록을 제공한다. In addition, the present invention provides a ceramic block manufactured by the above manufacturing method.
또한, 본 발명은 상기 세라믹 블록을 유효성분으로 포함하는 옷장 탈취 및 제습제를 제공한다. In addition, the present invention provides a wardrobe deodorant and dehumidifying agent containing the ceramic block as an active ingredient.
또한, 본 발명은 상기 세라믹 블록을 유효성분으로 포함하는 실내인테리어용 인조 대리석을 제공한다. In addition, the present invention provides an artificial marble for an interior interior comprising the ceramic block as an active ingredient.
본 발명은 기능성 세라믹 블록의 제조방법 및 이에 의해 제조된 기능성 세라믹 블록에 관한 것으로, 본 발명의 Na2O, SiO2, MgO, Al2O3, SO3, Cl, K2O, CaO, TiO2, Fe2O3, ZnO 및 ZrO2를 포함하는 액상 세라믹을 가열 발포시켜 고체로 변환시키는 제조방법으로 제조된 세라믹 블록은 우수한 항균, 탈취, 음이온 발생 및 원적외선 방사 효과가 있고, 항균, 탈취 효과가 반영구적으로 지속되는 효과가 있다. The present invention relates to a method for manufacturing a functional ceramic block and a functional ceramic block produced thereby, Na 2 O, SiO 2 , MgO, Al 2 O 3 , SO 3 , Cl, K 2 O, CaO, TiO of the present invention 2 , Fe 2 O 3 , ZnO and ZrO 2 is a ceramic block manufactured by a method of heating and foaming a liquid ceramic to convert it into a solid, and has excellent antibacterial, deodorizing, anion generating and far infrared radiation effects, and antibacterial and deodorizing effects. Has the effect of lasting semi-permanently.
또한, 본 발명의 기능성 세라믹 블록은 종래의 항균, 탈취제 대비 친환경적 제품으로, 냉장고 및 공기 청정기 필터, 에어컨 필터로 사용가능하고, 신발장, 옷장, 이불장처럼 습기가 많고 밀폐된 공간에 본 발명품을 적용하여 습기를 제거하고, 탈취효과를 가질 수 있으며, 밀폐 공간 및 곰팡이가 서식할 수 있는 공간에 세라믹 블록을 활용한 제품을 적용하여 곰팡이 서식을 억제하고, 항균 및 탈취 효과를 나타내 쾌적한 생활 환경을 형성하는데 도움을 줄 수 있을 뿐만 아니라, 상기 용도 이외에도 다양한 용도로 제작이 가능하다는 장점이 있다.In addition, the functional ceramic block of the present invention is an eco-friendly product compared to a conventional antibacterial and deodorant, and can be used as a refrigerator and air purifier filter and air conditioner filter, and the present invention is applied to a humid and enclosed space such as a shoebox, closet, and futon It removes moisture, has a deodorizing effect, and applies products using ceramic blocks to the enclosed space and the space where mold can inhabit, suppressing mold growth, and showing antibacterial and deodorizing effects to form a comfortable living environment. In addition to being able to help, there is an advantage in that it can be manufactured for a variety of uses other than the above.
도 1은 본 발명의 제조방법으로 제조된 기능성 세라믹 블록 사진이다.
도 2는 본 발명의 제조방법으로 제조된 기능성 세라믹 블록을 포함하는 다양한 용도의 제품의 사진이다.
도 3은 본 발명의 제조방법으로 제조된 기능성 세라믹 블록을 포함하는 인조 대리석 벽체 제품 사진이다.
도 4는 본 발명의 제조방법으로 제조된 기능성 세라믹 블록을 포함하는 인조 대리석 벽체 제품 사시도이다.1 is a photograph of a functional ceramic block produced by the manufacturing method of the present invention.
2 is a photograph of a product of various uses including a functional ceramic block produced by the manufacturing method of the present invention.
3 is a photograph of an artificial marble wall product including a functional ceramic block manufactured by the manufacturing method of the present invention.
4 is a perspective view of an artificial marble wall product including a functional ceramic block manufactured by the manufacturing method of the present invention.
본 발명은The present invention
1) Na2O, SiO2, MgO, Al2O3, SO3, Cl, K2O, CaO, TiO2, Fe2O3, ZnO 및 ZrO2를 포함하는 액상 바이오 세라믹을 제조하는 단계; 및1) preparing a liquid bioceramic comprising Na 2 O, SiO 2 , MgO, Al 2 O 3 , SO 3 , Cl, K 2 O, CaO, TiO 2 , Fe 2 O 3 , ZnO and ZrO 2 ; And
2) 상기 단계 1)에서 제조한 액상 바이오 세라믹을 가열 발포시켜 고체로 변화시키는 단계;를 포함하는 기능성 세라믹 블록의 제조방법에 관한 것이다. 2) a step of heating and foaming the liquid bioceramic prepared in step 1) into a solid; and a method for manufacturing a functional ceramic block comprising the same.
상기 단계 1)의 세라믹 분말의 화학 조성은 Na2O 100 중량부에 대하여, 300~350 중량부의 SiO2, 0.02~0.08 중량부의 MgO, 0.3~0.9 중량부의 Al2O3, 0.1~0.4 중량부의 SO3, 0.3~0.7 중량부의 Cl, 0.07~0.11 중량부의 K2O, 0.01~0.05 중량부의 CaO, 0.05~0.3 중량부의 TiO2, 0.1~0.5 중량부의 Fe2O3, 0.005~0.015 중량부의 ZnO 및 0.005~0.015 중량부의 ZrO2를 포함하는 것일 수 있고, 바람직하게는 Na2O 100 중량부에 대하여, 320~330 중량부의 SiO2, 0.04~0.06 중량부의 MgO, 0.5~0.7 중량부의 Al2O3, 0.2~0.3 중량부의 SO3, 0.4~0.6 중량부의 Cl, 0.08~0.10 중량부의 K2O, 0.02~0.04 중량부의 CaO, 0.1~0.2 중량부의 TiO2, 0.2~0.3 중량부의 Fe2O3, 0.008~0.010 중량부의 ZnO 및 0.009~0.011 중량부의 ZrO2를 포함할 수 있으며, 더 바람직하게는 Na2O 100 중량부에 대하여, 329 중량부의 SiO2, 0.051 중량부의 MgO, 0.647 중량부의 Al2O3, 0.246 중량부의 SO3, 0.534 중량부의 Cl, 0.094 중량부의 K2O, 0.031 중량부의 CaO, 0.136 중량부의 TiO2, 0.245 중량부의 Fe2O3, 0.009 중량부의 ZnO 및 0.010 중량부의 ZrO2를 포함할 수 있지만, 이에 제한되는 것은 아니다.The chemical composition of the ceramic powder of step 1) is 300 to 350 parts by weight of SiO 2 , 0.02 to 0.08 parts by weight of MgO, 0.3 to 0.9 parts by weight of Al 2 O 3 , 0.1 to 0.4 parts by weight based on 100 parts by weight of Na 2 O. SO 3 , 0.3 to 0.7 parts by weight Cl, 0.07 to 0.11 parts by weight K 2 O, 0.01 to 0.05 parts by weight CaO, 0.05 to 0.3 parts by weight TiO 2 , 0.1 to 0.5 parts by weight Fe 2 O 3 , 0.005 to 0.015 parts by weight ZnO And may include 0.005 ~ 0.015 parts by weight of ZrO 2 , preferably Na 2 O 100 parts by weight, 320 ~ 330 parts by weight of SiO 2 , 0.04 ~ 0.06 parts by weight of MgO, 0.5 ~ 0.7 parts by weight of Al 2 O 3 , 0.2 to 0.3 parts by weight SO 3 , 0.4 to 0.6 parts by weight Cl, 0.08 to 0.10 parts by weight K 2 O, 0.02 to 0.04 parts by weight CaO, 0.1 to 0.2 parts by weight TiO 2 , 0.2 to 0.3 parts by weight Fe 2 O 3 , 0.008 to 0.010 parts by weight of ZnO and 0.009 to 0.011 parts by weight of ZrO 2 may be included, more preferably Na 2 O 100 parts by weight of 329 parts by weight of SiO 2 , 0.051 parts by weight of MgO, 0.647 parts by weight of Al 2 O 3 , 0 .246 parts by weight SO 3 , 0.534 parts by weight Cl, 0.094 parts by weight K 2 O, 0.031 parts by weight CaO, 0.136 parts by weight TiO 2 , 0.245 parts by weight Fe 2 O 3 , 0.009 parts by weight ZnO and 0.010 parts by weight ZrO 2 You can, but are not limited to this.
본 발명의 일 구현 예에서, 상기 단계 1)의 액상 바이오 세라믹은 화학물을 혼합한 후, 1~8일 동안 반응시간을 가진 후에 가열 발포하여 세라믹 블록을 제조할 수 있고, 바람직하게는 2~6일 동안 반응시간을 가진 후에 가열 발포하여 세라믹 블록을 제조할 수 있으며, 더 바람직하게는 4일 동안 반응시간을 가진 후에 가열 발포하여 세라믹 블록을 제조할 수 있지만, 이에 한정하는 것은 아니다. In one embodiment of the present invention, the liquid bioceramic of step 1) may be mixed with chemicals, and then heated and foamed after having a reaction time for 1 to 8 days, preferably 2 to The ceramic block may be prepared by heating and foaming after a reaction time for 6 days, and more preferably, a ceramic block may be prepared by heating and foaming after a reaction time for 4 days, but is not limited thereto.
상기 단계 1)의 액상 바이오 세라믹은 반응시간 동안 물이 생성되며, 반응시간 종료 후, 총 화학물 100 중량부에 대하여 100~230 중량부의 물이 생성될 수 있으며, 바람직하게는 총 화학물 100 중량부에 대하여 130~170 중량부의 물이 생성되는 것이며, 더 바람직하게는 총 화학물 100 중량부에 대하여 150 중량부의 물이 생성되는 것이지만, 이에 한정하는 것은 아니다. In the liquid bioceramic of step 1), water is generated during the reaction time, and after completion of the reaction time, 100 to 230 parts by weight of water may be generated relative to 100 parts by weight of the total chemical, preferably 100% of the total chemical 130 to 170 parts by weight of water is generated with respect to parts, and more preferably, 150 parts by weight of water is generated with respect to 100 parts by weight of the total chemical, but is not limited thereto.
상기 단계 2)의 가열 발포는 액상 바이오 세라믹을 내열 코팅된 용기에서 200~400℃의 온도로 3~25분 동안 가열하여 발포시키는 것일 수 있고, 바람직하게는 액상 바이오 세라믹을 밀폐된 내열 코팅된 용기에서 200~400℃의 온도로 10~20분 동안 가열하여, 액상 바이오 세라믹 부피 대비 15~25배의 부피로 완전 발포시켜 고체화하는 것이며, 더 바람직하게는 액상 바이오 세라믹을 밀폐된 내열 코팅된 용기에서 350℃의 온도로 15분 동안 가열하여, 액상 바이오 세라믹 부피 대비 20배의 부피로 완전 발포시켜 고체화하는 것이지만, 이에 한정하는 것은 아니다. The heating and foaming of step 2) may be performed by heating the liquid bioceramic in a heat-resistant coated container at a temperature of 200 to 400 ° C. for 3 to 25 minutes, and preferably, the liquid bioceramic is sealed heat-resistant coated container. Is heated at a temperature of 200 to 400 ° C. for 10 to 20 minutes to solidify by completely foaming to a volume of 15 to 25 times the volume of the liquid bioceramic, more preferably in a sealed heat-resistant coated container It is heated to a temperature of 350 ° C. for 15 minutes, and completely foamed to a volume 20 times the volume of the liquid bioceramic to solidify, but is not limited thereto.
본 발명의 용어 '기능성'은 항균, 탈취, 음이온 발생 및 원적외선 방사 효과를 의미하며, 본 발명의 기능성 세라믹 블록은 항균, 탈취, 음이온 발생 및 원적외선 방사 기능을 갖는다. The term 'functional' of the present invention means antibacterial, deodorizing, anion generating and far infrared radiation effects, and the functional ceramic block of the present invention has antibacterial, deodorizing, anion generating and far infrared radiation functions.
본 발명의 기능성 세라믹 블록은 바람직하게는 The functional ceramic block of the invention is preferably
1) 화학 조성이 Na2O 100 중량부에 대하여, 300~350 중량부의 SiO2, 0.02~0.08 중량부의 MgO, 0.3~0.9 중량부의 Al2O3, 0.1~0.4 중량부의 SO3, 0.3~0.7 중량부의 Cl, 0.07~0.11 중량부의 K2O, 0.01~0.05 중량부의 CaO, 0.05~0.3 중량부의 TiO2, 0.1~0.5 중량부의 Fe2O3, 0.005~0.015 중량부의 ZnO 및 0.005~0.015 중량부의 ZrO2인 액상 바이오 세라믹을 제조하는 단계; 및1) With respect to 100 parts by weight of Na 2 O, 300 to 350 parts by weight of SiO 2 , 0.02 to 0.08 parts by weight of MgO, 0.3 to 0.9 parts by weight of Al 2 O 3 , 0.1 to 0.4 parts by weight of SO 3 , 0.3 to 0.7 Cl by weight, 0.07 to 0.11 part by weight K 2 O, 0.01 to 0.05 part by weight CaO, 0.05 to 0.3 part by weight TiO 2 , 0.1 to 0.5 part by weight Fe 2 O 3 , 0.005 to 0.015 part by weight ZnO and 0.005 to 0.015 part by weight Preparing a liquid bioceramic of ZrO 2 ; And
2) 상기 단계 1)에서 제조한 액상 바이오 세라믹을 내열 코팅된 용기에서 200~400℃의 온도로 3~25분 동안 가열하여 발포시켜 고체로 변화시키는 단계;를 포함하여 제조할 수 있고, 2) heating the liquid bio-ceramic prepared in step 1) in a heat-resistant coated container at a temperature of 200 to 400 ° C. for 3 to 25 minutes to foam to change it into a solid;
더 바람직하게는More preferably
1) 화학 조성이 Na2O 100 중량부에 대하여, 320~330 중량부의 SiO2, 0.04~0.06 중량부의 MgO, 0.5~0.7 중량부의 Al2O3, 0.2~0.3 중량부의 SO3, 0.4~0.6 중량부의 Cl, 0.08~0.10 중량부의 K2O, 0.02~0.04 중량부의 CaO, 0.1~0.2 중량부의 TiO2, 0.2~0.3 중량부의 Fe2O3, 0.008~0.010 중량부의 ZnO 및 0.009~0.011 중량부의 ZrO2인 액상 바이오 세라믹을 제조하는 단계; 및1) Chemical composition of Na 2 O 100 parts by weight, 320 to 330 parts by weight of SiO 2 , 0.04 to 0.06 parts by weight of MgO, 0.5 to 0.7 parts by weight of Al 2 O 3 , 0.2 to 0.3 parts by weight of SO 3 , 0.4 to 0.6 Cl by weight, 0.08 to 0.10 parts by weight K 2 O, 0.02 to 0.04 parts by weight CaO, 0.1 to 0.2 parts by weight TiO 2 , 0.2 to 0.3 parts by weight Fe 2 O 3 , 0.008 to 0.010 parts by weight ZnO, and 0.009 to 0.011 parts by weight Preparing a liquid bioceramic of ZrO 2 ; And
2) 상기 단계 1)에서 제조한 액상 바이오 세라믹을 밀폐된 내열 코팅된 용기에서 200~400℃의 온도로 10~20분 동안 가열하여, 액상 바이오 세라믹 부피 대비 15~25배의 부피로 완전 발포시켜 고체로 변화시키는 단계;를 포함하여 제조할 수 있으며, 2) The liquid bio-ceramic prepared in step 1) is heated in a sealed heat-resistant coated container at a temperature of 200 to 400 ° C. for 10 to 20 minutes, and completely foamed to a volume of 15 to 25 times the volume of the liquid bio-ceramic. Converting to a solid; can be prepared, including
더욱더 바람직하게는Even more preferably
1) 화학 조성이 Na2O 100 중량부에 대하여, 329 중량부의 SiO2, 0.051 중량부의 MgO, 0.647 중량부의 Al2O3, 0.246 중량부의 SO3, 0.534 중량부의 Cl, 0.094 중량부의 K2O, 0.031 중량부의 CaO, 0.136 중량부의 TiO2, 0.245 중량부의 Fe2O3, 0.009 중량부의 ZnO 및 0.010 중량부의 ZrO2인 액상 바이오 세라믹을 제조하는 단계; 및1) With respect to 100 parts by weight of Na 2 O, 329 parts by weight of SiO 2 , 0.051 parts by weight of MgO, 0.647 parts by weight of Al 2 O 3 , 0.246 parts by weight of SO 3 , 0.534 parts by weight of Cl, 0.094 parts by weight of K 2 O , 0.031 parts by weight of CaO, 0.136 parts by weight of TiO 2 , 0.245 parts by weight of Fe 2 O 3 , 0.009 parts by weight of ZnO and 0.010 parts by weight of ZrO 2 to prepare a liquid bioceramic; And
2) 상기 단계 1)에서 제조한 액상 바이오 세라믹을 밀폐된 내열 코팅된 용기에서 350℃의 온도로 15분 동안 가열하여, 액상 바이오 세라믹 부피 대비 20배의 부피로 완전 발포시켜 고체로 변화시키는 단계;를 포함하여 제조하는 것이지만, 이에 제한되는 것은 아니다.2) heating the liquid bio-ceramic prepared in step 1) in a sealed heat-resistant coated container at a temperature of 350 ° C. for 15 minutes, and completely foaming it to a volume of 20 times the volume of the liquid bio-ceramic to change it to a solid; It includes, but is not limited to.
또한, 본 발명은 상기 제조방법으로 제조된 세라믹 블록에 관한 것이다.In addition, the present invention relates to a ceramic block manufactured by the above manufacturing method.
상기 세라믹 블록은 항균, 탈취, 음이온 발생 및 원적외선 방사 효과가 있고, 항균, 탈취 효과가 반영구적으로 지속된다. The ceramic block has antibacterial, deodorizing, anion-generating and far-infrared radiation effects, and the antibacterial and deodorizing effect persists permanently.
본 발명의 세라믹 블록은 원하는 용도로 가공이 용이하다. The ceramic block of the present invention is easy to process for a desired purpose.
또한, 본 발명은 상기 세라믹 블록을 유효성분으로 포함하는 옷장 탈취 및 제습제에 관한 것이다. In addition, the present invention relates to a wardrobe deodorant and dehumidifying agent containing the ceramic block as an active ingredient.
또한, 본 발명은 상기 세라믹 블록을 유효성분으로 포함하는 실내인테리어용 인조 대리석에 관한 것이다. In addition, the present invention relates to artificial marble for indoor interiors comprising the ceramic block as an active ingredient.
상기 인조 대리석은 스타일로폼, 질석, 페라이트석으로부터 선택된 하나 이상의 물질에 본 발명의 세라믹 블록을 혼합하여 제조할 수 있지만, 이에 한정하는 것은 아니다. The artificial marble may be prepared by mixing the ceramic block of the present invention with one or more materials selected from stylofoam, vermiculite, and ferrite stone, but is not limited thereto.
상기 인조 대리석은 후면에 변형방지, 후변형 및 작업성 개선을 위하여 플라스틱, 철판 또는 철망을 추가하여 장착할 수 있고 바람직하게는 플라스틱을 추가 장착하는 것이지만, 이에 한정하는 것은 아니다. The artificial marble may be mounted by adding plastic, a steel plate, or a wire mesh to prevent deformation, post-deformation, and workability on the rear surface, but is preferably limited to plastic addition, but is not limited thereto.
상기 인조 대리석은 후면에 후면판을 보강함으로써, 작업 효율을 상승시키고, 후변형을 방지할 수 있다. The artificial marble reinforces the back plate on the rear surface, thereby increasing work efficiency and preventing post-deformation.
또한, 본 발명은 세라믹 블록을 유효성분으로 포함하는 냉장고 탈취제에 관한 것이다.In addition, the present invention relates to a refrigerator deodorant comprising a ceramic block as an active ingredient.
이하, 제조예 및 실시예를 이용하여 본 발명을 더욱 상세하게 설명하고자 한다. 이들 제조예 및 실시예는 오로지 본 발명을 보다 구체적으로 설명하기 위한 것으로, 본 발명의 범위가 이들에 의해 제한되지 않는다는 것은 당해 기술분야에서 통상의 지식을 가진 자에게 있어 자명한 것이다. Hereinafter, the present invention will be described in more detail by using manufacturing examples and examples. These preparation examples and examples are only intended to illustrate the present invention more specifically, it is apparent to those skilled in the art that the scope of the present invention is not limited by them.
제조예 1. 세라믹 블록의 제조Production Example 1. Preparation of ceramic blocks
Na2O 100 중량부에 대하여, 329 중량부의 SiO2, 0.051 중량부의 MgO, 0.647 중량부의 Al2O3, 0.246 중량부의 SO3, 0.534 중량부의 Cl, 0.094 중량부의 K2O, 0.031 중량부의 CaO, 0.136 중량부의 TiO2, 0.245 중량부의 Fe2O3, 0.009 중량부의 ZnO 및 0.010 중량부의 ZrO2를 포함하는 화학 조성물을 4일 동안 상온(20±5℃)에서 저온숙성 반응시켜 액상 바이오 세라믹을 제조하였다. 이 후 상기 액상 바이오 세라믹을 밀폐된 내열 코팅된 스텐레스 용기에서 350℃의 온도로 15분 동안 가열하여, 액상 바이오 세라믹 부피 대비 20배의 부피로 완전 발포시켜 세라믹 블록을 제조하였다. With respect to 100 parts by weight of Na 2 O, 329 parts by weight of SiO 2 , 0.051 parts by weight of MgO, 0.647 parts by weight of Al 2 O 3 , 0.246 parts by weight of SO 3 , 0.534 parts by weight of Cl, 0.094 parts by weight of K 2 O, 0.031 parts by weight of CaO , 0.136 parts by weight of TiO 2 , 0.245 parts by weight of Fe 2 O 3 , 0.009 parts by weight of ZnO and 0.010 parts by weight of ZrO 2 are reacted at low temperature for 4 days at room temperature (20 ± 5 ° C) to perform liquid bioceramic. It was prepared. Thereafter, the liquid bio-ceramic was heated in a sealed heat-resistant coated stainless steel container at a temperature of 350 ° C. for 15 minutes to completely foam the liquid bio-ceramic to 20 times the volume, thereby preparing a ceramic block.
상기 세라믹 블록은 도 1에 개시된 바와 같이 고체 상태이며, 원하는 크기로 제조가 가능하다. 또한, 상기 세라믹 블록은 도 2 내지 도 4에 개시된 바와 같이 다양한 용도의 제품으로 제조될 수 있다. The ceramic block is in a solid state as disclosed in FIG. 1 and can be manufactured in a desired size. In addition, the ceramic block may be manufactured as a product for various purposes as disclosed in FIGS. 2 to 4.
실시예 1. 항균 시험Example 1. Antibacterial test
상기 제조예 1의 세라믹 블록의 항균 효과를 확인하기 위해, KCL-FIR-1003의 시험방법을 사용하여 대장균, 녹농균 및 황색포도상구균에 대한 항균력을 시험하였다.To confirm the antibacterial effect of the ceramic block of Preparation Example 1, antibacterial activity against E. coli, Pseudomonas aeruginosa and Staphylococcus aureus was tested using the test method of KCL-FIR-1003.
그 결과, 하기 표 1에 개시된 바와 같이 본 발명의 세라믹 블록(5cm×5cm)은 99.9%의 항균력을 나타내어, 매우 우수한 항균력을 가진다는 것을 확인하였다.As a result, as disclosed in Table 1 below, the ceramic block (5 cm × 5 cm) of the present invention exhibited an antibacterial activity of 99.9%, confirming that it has an excellent antibacterial activity.
(CFU/mL)Initial concentration
(CFU / mL)
*CFU: colony forming unit* CFU: colony forming unit
실시예 2. 탈취 시험Example 2. Deodorization test
제조예 1의 세라믹 블록의 탈취 효과를 확인하기 위해, 시간의 변화에 따른 암모니아, 톨루엔, 포름알데하이드의 제거율을 측정하였다. In order to confirm the deodorizing effect of the ceramic block of Preparation Example 1, the removal rate of ammonia, toluene, and formaldehyde according to changes in time was measured.
세라믹 블록(4cm×4cm×1.5cm) 시험편을 5L 크기의 반응기에 넣고 밀봉한 후, 시험가스를 주입하고(암모니아, 톨루엔 초기 농도-50μmol/mol, 포름알데하이드 초기 농도 20μmol/mol), 0~120분 동안 30분 간격으로 시험가스의 농도를 측정하였다. After placing the ceramic block (4 cm × 4 cm × 1.5 cm) test specimen in a 5 L reactor and sealing it, inject the test gas (ammonia, toluene initial concentration -50 μmol / mol, formaldehyde initial concentration: 20 μmol / mol), 0 to 120 The concentration of the test gas was measured at 30 minute intervals for a minute.
시험가스의 제거율은 하기 식 1에 의해 계산하였다. The removal rate of the test gas was calculated by Equation 1 below.
[식 1][Equation 1]
시험가스의 제거율(%)=[{(시험편이 없는 상태의 농도)-(시험편이 있는 상태의 농도)}/(시험편이 없는 상태의 농도)]×100Removal rate of test gas (%) = [{(Concentration without test specimen)-(Concentration without test specimen)} / (Concentration without test specimen)] × 100
그 결과, 표 2에 개시된 바와 같이 본 발명의 세라믹 블록 시험편에 의해 암모니아, 톨루엔, 포름알데하이드가 제거되는 것을 확인하였다. As a result, as shown in Table 2, it was confirmed that ammonia, toluene, and formaldehyde were removed by the ceramic block test piece of the present invention.
Test result
(μmol/mol)blank group concentration
(μmol / mol)
(μmol/mol)Ceramic block group concentration
(μmol / mol)
(%)Deodorization rate
(%)
습도: 49.6±0.3%R.H.Temperature: 25.0 ± 0.4 ℃
Humidity: 49.6 ± 0.3% RH
습도: 49.6±0.3%R.HTemperature: 25.0 ± 0.4 ℃
Humidity: 49.6 ± 0.3% RH
습도: 49.6±0.3%R.HTemperature: 25.0 ± 0.4 ℃
Humidity: 49.6 ± 0.3% RH
실시예 3. 음이온 방출 시험Example 3. Anion release test
제조예 1의 세라믹 블록에서 음이온이 방출되는지 확인하기 위해, KCL-FIR-1042의 방법으로 세라믹 블록의 음이온 방출양을 측정하였다. To confirm that anions are released from the ceramic block of Preparation Example 1, the amount of anion emission of the ceramic block was measured by the method of KCL-FIR-1042.
그 결과, 표 3에 개시된 바와 같이 본 발명의 세라믹 블록은 1㎤ 당 87개의 음이온이 방출되는 것을 확인하였다. As a result, as shown in Table 3, the ceramic block of the present invention was confirmed that 87 anions are released per 1 cm 3.
습도: 47.2±0.4%R.HTemperature: 21.5 ± 0.1 ℃
Humidity: 47.2 ± 0.4% RH
실시예 4. 원적외선 방사율 시험Example 4. Far-infrared emissivity test
제조예 1의 세라믹 블록의 원적외선 방사율을 확인하기 위해, KCL-FIR-1005의 방법으로 세라믹 블록의 원적외선 방사율을 측정하였다. To confirm the far-infrared emissivity of the ceramic block of Preparation Example 1, the far-infrared emissivity of the ceramic block was measured by the method of KCL-FIR-1005.
그 결과, 표 4에 개시된 바와 같이 본 발명의 세라믹 블록은 5~20㎛ 파장의 원적외선 방사율이 0.892이고, 3.60×102(W/㎡, 40℃)의 방사 에너지를 가지는 것을 확인하였다. As a result, as shown in Table 4, it was confirmed that the ceramic block of the present invention has a far-infrared emissivity of 5 to 20 μm and a wavelength of 0.892, and a radiation energy of 3.60 × 10 2 (W / m 2, 40 ° C.).
(측정온도: 40℃, 측정파장: 5㎛~20㎛)Far infrared emissivity
(Measurement temperature: 40 ℃, measurement wavelength: 5㎛ ~ 20㎛)
습도: 24.3±0.3%R.HTemperature: 22.1 ± 0.1 ℃
Humidity: 24.3 ± 0.3% RH
(측정온도: 40℃, 측정파장: 5㎛~20㎛)Far infrared radiation energy
(Measurement temperature: 40 ℃, measurement wavelength: 5㎛ ~ 20㎛)
Claims (8)
2) 상기 단계 1)에서 제조한 액상 바이오 세라믹을 내열 코팅된 용기에서 200~400℃의 온도로 3~25분 동안 가열하여 발포시켜 고체로 변화시키는 단계;를 포함하는 항균, 탈취, 음이온 발생 및 원적외선 방사 기능을 갖는 세라믹 블록의 제조방법.1) With respect to 100 parts by weight of Na 2 O, 300 to 350 parts by weight of SiO 2 , 0.02 to 0.08 parts by weight of MgO, 0.3 to 0.9 parts by weight of Al 2 O 3 , 0.1 to 0.4 parts by weight of SO 3 , 0.3 to 0.7 Cl by weight, 0.07 to 0.11 part by weight K 2 O, 0.01 to 0.05 part by weight CaO, 0.05 to 0.3 part by weight TiO 2 , 0.1 to 0.5 part by weight Fe 2 O 3 , 0.005 to 0.015 part by weight ZnO and 0.005 to 0.015 part by weight Preparing a liquid bioceramic of ZrO 2 ; And
2) heating the liquid bio-ceramic prepared in step 1) in a heat-resistant coated container at a temperature of 200 to 400 ° C. for 3 to 25 minutes to foam to change it into a solid; including antibacterial, deodorizing, and generating negative ions, and Method of manufacturing a ceramic block having a far-infrared radiation function.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020190154659A KR102104627B1 (en) | 2019-11-27 | 2019-11-27 | Manufacturing method of functional ceramic block and functional ceramic block produced by the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020190154659A KR102104627B1 (en) | 2019-11-27 | 2019-11-27 | Manufacturing method of functional ceramic block and functional ceramic block produced by the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR102104627B1 true KR102104627B1 (en) | 2020-04-27 |
Family
ID=70467706
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020190154659A KR102104627B1 (en) | 2019-11-27 | 2019-11-27 | Manufacturing method of functional ceramic block and functional ceramic block produced by the same |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR102104627B1 (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20060068929A (en) * | 2004-12-17 | 2006-06-21 | 신현창 | The foamed ceramics shape of high strength and the making method thereof |
| KR20100105188A (en) * | 2009-03-20 | 2010-09-29 | 조행래 | Material for blocking water vein wave and electromagnetic wave and device including the same |
| KR20150030401A (en) * | 2013-09-12 | 2015-03-20 | 임기태 | Multi-functional artificial marble composition, its production method and multi-functional artificial marble using it |
| KR101600457B1 (en) * | 2015-06-26 | 2016-03-09 | 지투소재기술 주식회사 | Manufacturing method of porous molded ceramic having excellent mechanical property |
-
2019
- 2019-11-27 KR KR1020190154659A patent/KR102104627B1/en active IP Right Grant
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20060068929A (en) * | 2004-12-17 | 2006-06-21 | 신현창 | The foamed ceramics shape of high strength and the making method thereof |
| KR20100105188A (en) * | 2009-03-20 | 2010-09-29 | 조행래 | Material for blocking water vein wave and electromagnetic wave and device including the same |
| KR20150030401A (en) * | 2013-09-12 | 2015-03-20 | 임기태 | Multi-functional artificial marble composition, its production method and multi-functional artificial marble using it |
| KR101600457B1 (en) * | 2015-06-26 | 2016-03-09 | 지투소재기술 주식회사 | Manufacturing method of porous molded ceramic having excellent mechanical property |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101440943B1 (en) | Incombustible panel for interior decoration and facing of architectures and method thereof | |
| KR101266478B1 (en) | The charcoal board and the manufacturing method of using natural materials | |
| KR101649052B1 (en) | Mortar composition comprising rice hull and preparation method thereof | |
| KR100837850B1 (en) | Soil ceramics and process for the preparation thereof | |
| KR100926180B1 (en) | Construction functional board and method formanufacturing thereof | |
| KR101490195B1 (en) | Eco friendly architecture interior for Reducing Sick House Syndrome | |
| KR102104627B1 (en) | Manufacturing method of functional ceramic block and functional ceramic block produced by the same | |
| KR20080018291A (en) | Paint composition using terra alba and the manufacturing method thereof | |
| KR100640042B1 (en) | Composition for construction structure finish member containing a ceramic and a kaolin that radiating an anion and a far infrared rays | |
| US7879252B1 (en) | Functional cotton spray composition, method for producing the same, and building material using the same | |
| KR101796823B1 (en) | Manufacture method of a functional building finishing material | |
| KR100850037B1 (en) | A functional dry cement mortar and manufacturing method thereof | |
| KR20090114497A (en) | Bamboo activated carbon paint | |
| KR101021107B1 (en) | Environmental friendly volcanic stone mortar composition | |
| KR102062047B1 (en) | Eco-friendly composition for manufacturing interior and exterior building material and frame | |
| KR20050015754A (en) | Far infrared rays paint of functional the using loess and manufacture method thereof | |
| KR101098235B1 (en) | antimicrobial ceramic board for plant growth and manufacturing method of the same | |
| JP3085182B2 (en) | Far infrared radiator | |
| KR100631335B1 (en) | Artificial marble | |
| KR101140797B1 (en) | Composition of functional collar cotton spray its manufacturing method and building material using it | |
| KR20160014264A (en) | Environmental friendly ceramic ball and manufacturing method thereof | |
| KR102641751B1 (en) | Antibacterial and deodorizing sintered body having a surface coating layer containing functional metal powder and manufacturing method thereof | |
| KR101110322B1 (en) | Composition of functional cotton spray its manufacturing method and building material using it | |
| KR20150127316A (en) | Mortar comprising natural materials and preparation method thereof | |
| KR20100055730A (en) | Antifungal inorganic paint and its manufacturing method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A302 | Request for accelerated examination | ||
| E902 | Notification of reason for refusal | ||
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant |