KR102093614B1 - A waterproof and anti corrosion method by using ceramics - Google Patents
A waterproof and anti corrosion method by using ceramics Download PDFInfo
- Publication number
- KR102093614B1 KR102093614B1 KR1020170180214A KR20170180214A KR102093614B1 KR 102093614 B1 KR102093614 B1 KR 102093614B1 KR 1020170180214 A KR1020170180214 A KR 1020170180214A KR 20170180214 A KR20170180214 A KR 20170180214A KR 102093614 B1 KR102093614 B1 KR 102093614B1
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- South Korea
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- methacrylate
- ceramic
- primer
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- 238000005260 corrosion Methods 0.000 title description 6
- 230000007797 corrosion Effects 0.000 title description 2
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
- C04B41/522—Multiple coatings, for one of the coatings of which at least one alternative is described
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
- C04B41/483—Polyacrylates
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
- C04B41/488—Other macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
- C04B41/488—Other macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
- C04B41/4892—Polyamides
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
- C04B41/4994—Organo-phosphorus compounds
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/002—Priming paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/64—Insulation or other protection; Elements or use of specified material therefor for making damp-proof; Protection against corrosion
- E04B1/644—Damp-proof courses
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
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- Wood Science & Technology (AREA)
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Abstract
본 발명은 습윤면에 구애됨이 없이 시공 가능한 세라믹 방수방식공법에 관한 것으로서, 프라이머가 도포되는 프라이머층과, 바탕조정제가 도포되는 바탕조정층 및 세라믹방식재가 도포되는 세라메탈층을 포함하는 세라믹 방수방식공법에 있어서, 상기 프라이머층은 20 ~ 40 중량부의 메칠메타크릴레이트(methyl-methacrylate)와; 15 ~ 20 중량부의 하이드록시에틸메타크릴레이트(hydroxy-ethyl-methacrylate)와; 10 ~ 12.5 중량부의 폴리메칠메타크릴레이트(polymethyl-methacrylate)와; 1 ~ 2 중량부의 에틸렌글리콜디메타크릴레이트(ethylene-glycol-dimethacrylate)와; 0.5 ~ 1중량부의 부틸디글리콜메타크릴레이트(butyl-diglycol-methacrylate)와; 0.5 ~ 1중량부의 2-에틸헥실아크릴레이트(2-ethyl-hexyl-acrylate)와; 0.5 ~ 1중량부의 파라톨루이딘에톡실레이티드(para-toluidine ethoxylated)와; 0.5 ~ 1 중량부의 파라핀(paraffine)과; 0.5 ~ 1 중량부의 안트라퀴논다이(anthraquinone dye)와; 0.5 ~ 1 중량부의 메타크릴로일옥시에틸 포스페이트(methacryloyloxyethyl-phosphate)와; 10 ~ 12.5 중량부의 디벤조일 퍼옥사이드(dibenzoyl-peroxide)와; 10 ~ 12.5 중량부의 디시클로 헥실 프탈레이트(dicyclohexyl-phthalate)와; 10 ~ 12.5 중량부의 불활성 충전제의 혼합물(mixture of inert fillers)과; 0.5 ~ 1 중량부의 우레탄 메탈크릴레이크(urethane-methacrylate); 및 0.5 ~ 1 중량부의 선형 프탈레이트 에스테르(linear phthalate ester);로 조성되는 것을 특징으로 한다.The present invention relates to a ceramic waterproofing method that can be applied without regard to the wet surface, a ceramic waterproofing layer including a primer layer to which a primer is applied, a base adjustment layer to which a background adjustment agent is applied, and a cerametal layer to which a ceramic anticorrosive material is applied. In the anticorrosion method, the primer layer is 20 to 40 parts by weight of methyl methacrylate (methyl-methacrylate); 15 to 20 parts by weight of hydroxyethyl methacrylate (hydroxy-ethyl-methacrylate); 10 to 12.5 parts by weight of polymethyl methacrylate (polymethyl-methacrylate); 1 to 2 parts by weight of ethylene glycol dimethacrylate (ethylene-glycol-dimethacrylate); 0.5 to 1 part by weight of butyl diglycol methacrylate (butyl-diglycol-methacrylate); 0.5 to 1 part by weight of 2-ethylhexyl acrylate (2-ethyl-hexyl-acrylate); 0.5 to 1 part by weight of para-toluidine ethoxylated; 0.5 to 1 part by weight of paraffin (paraffine); 0.5 to 1 part by weight of anthraquinone dye; 0.5 to 1 part by weight of methacryloyloxyethyl phosphate (methacryloyloxyethyl-phosphate) and; 10 to 12.5 parts by weight of dibenzoyl-peroxide; 10 to 12.5 parts by weight of dicyclohexyl-phthalate; 10 to 12.5 parts by weight of a mixture of inert fillers (mixture of inert fillers); 0.5 to 1 part by weight of urethane metal acrylate (urethane-methacrylate); And 0.5 to 1 part by weight of a linear phthalate ester.
Description
본 발명은 습윤면에 구애됨이 없이 시공 가능한 세라믹 방수방식공법에 관한 것으로서, 더욱 상세하게는, 습윤상태를 유지하는 바탕면에 직접적으로 시공 가능하고, 프라이머 상에 도포되는 세라믹 방식재인 세라메탈을 도포함으로써, 바탕면에 대한 내부적 요인 또는 외부적 요인 등에 구애됨이 없이 방수방식공법을 수행할 수 있고, 이로 인해 시공의 공기를 단축하여 방식시공의 경쟁력을 강화하는 습윤면에 구애됨이 없이 시공 가능한 세라믹 방수방식공법에 관한 것이다.The present invention relates to a ceramic waterproofing method that can be applied without regard to the wet surface, and more particularly, to the ceramic surface, which can be applied directly to a base surface that maintains a wet state and is applied on a primer. By applying, it is possible to carry out the waterproofing method without being affected by internal factors or external factors, etc., thereby reducing the air of the construction, thereby strengthening the competitiveness of the method of construction, regardless of the wet surface. It relates to a possible ceramic waterproof method.
일반적으로, 공동주택, 공공건물, 오피스텔 또는 백화점, 할인마트와 같은 상업시설이나, 건축물 지하 주차장이나, 창고, 각종 공장 및 수처리시설의 대형수조, 저장조 등에는 방식층이 형성되고, 상기 방식층은 하도(프라이머), 중도 및 상도로 분류된다. 여기서, 상기 하도는 모체의 소지면과 후속 도장인 중도와의 접착력을 향상시키기 위한 공정이고, 중도는 모체의 소지면의 요철과 크랙보수 또는 소지면이 평활해지도록 도막을 두껍게 도포하면서 콘크리트의 기공을 통한 습기의 침투를 차단하기 위한 공정이며, 상도는 내수성, 내약품성, 내마모성, 내오염성 및 원하는 색상을 표현하기 위한 최종 마감공정이다.In general, anticorrosion layers are formed in commercial facilities such as apartments, public buildings, officetels or department stores, discount marts, underground parking lots in buildings, warehouses, large water tanks and storage tanks of water treatment facilities, etc. It is classified as primer (primer), middle and top. Here, the base coat is a process for improving the adhesion between the base surface of the matrix and the intermediate degree, which is the subsequent painting, and the midway is the moisture through the pores of the concrete while thickly coating the unevenness and crack repair of the base surface of the matrix or the base surface to be smooth. It is a process to block the penetration of water, and the top coat is the final finishing process for expressing water resistance, chemical resistance, abrasion resistance, contamination resistance, and a desired color.
상기와 같은 방식층 시공방법은, 콘크리트 바탕면에 대략 8% 이하가 되도록 습기를 제거하기 위해 건조작업을 수행한다.The anticorrosive layer construction method as described above performs a drying operation to remove moisture so that it is about 8% or less on the concrete surface.
바탕면의 건조작업이 완료되면, 휘발성유기화합물 등이 함유된 용제용 프라이머를 도포하여 프라이머층을 형성한다.When the drying operation of the ground surface is completed, a primer layer is formed by applying a primer for a solvent containing a volatile organic compound or the like.
프라이머층이 형성되면, 바탕면의 기공을 제거하기 위해 무기질 타입의 바탕조정재 등과 같은 조성물로 중도층을 형성한다.When the primer layer is formed, a middle layer is formed with a composition such as an inorganic type base adjuster to remove pores on the base surface.
중도층이 형성되면, 방식기능을 수행하기 위해 에폭시 또는 폴리 우레아 등과 같은 조성물로 상도층을 형성한다.When the middle layer is formed, a top layer is formed of a composition such as epoxy or polyurea to perform anticorrosive functions.
그러나, 하도 공정에서 프라이머에 함유되는 휘발성유기화합물은 주위 습기와 반응하여, 물과 기름처럼 침투하지 못하고 콘크리트 바탕 표면에 겉도는 문제점이 있다.However, in the primer process, the volatile organic compound contained in the primer reacts with the surrounding moisture, so that it does not penetrate like water and oil, and there is a problem in appearance on the concrete surface.
또한, 수분으로 인해 콘크리트 바탕면에 형성된 기공이 다수 형성되고, 시공 후 바탕면의 기공을 통해 방식층으로 상승하여 들뜸 현상이 발생하면서 바탕면과의 부착력을 감소시킴으로써, 박리, 박락현상이 발생하는 문제점이 있다.In addition, a number of pores formed on the concrete base surface are formed due to moisture, and after construction, it rises to the anti-corrosion layer through the pores of the base surface, thereby causing exfoliation and reducing adhesion to the base surface, resulting in peeling and peeling. There is a problem.
또한, 습한날씨나 건조한 날씨 등과 같은 외부조건에 따라 바탕면의 수분함량에 큰차이가 발생하고, 이로 인해 건조작업에 소요되는 기간이 일정하지 않음으로써, 방수시공에 대한 신뢰성을 확보하기 어려운 문제점이 있다.In addition, due to external conditions such as wet weather or dry weather, a large difference occurs in the moisture content of the ground surface, and as a result, the time required for drying is not constant, making it difficult to secure reliability in waterproof construction. have.
결국, 종래의 프라이머는 습기에 약하기 때문에 날씨에 의한 외부적환경조건 및 콘크리트 바탕면의 습윤상태 등에 의한 내부적환경조건 등에 따라 방식시공의 불량이 발생하는 문제점이 있다.As a result, the conventional primer is weak to moisture, and thus, there is a problem in that the anti-corrosion occurs due to external environmental conditions due to weather and internal environmental conditions due to the wet state of the concrete base surface.
상기와 같은 문제점을 해결하기 위해 제안하는 것으로서, 본 발명의 목적은, 습윤상태를 유지하는 바탕면에 직접적으로 시공 가능하고, 프라이머 상에 도포되는 세라믹 방식재인 세라메탈을 도포함으로써, 바탕면에 대한 내부적 요인 또는 외부적 요인 등에 구애됨이 없이 방수방식공법을 수행할 수 있고, 이로 인해 시공의 공기를 단축하여 방식시공의 경쟁력을 강화하는 습윤면에 구애됨이 없이 시공 가능한 세라믹 방수방식공법을 제공하는 데 있다.As proposed to solve the above problems, the object of the present invention is to be applied directly to the base surface to maintain the wet state, by applying a ceramic anti-corrosive ceramic material applied on the primer, to the base surface It is possible to perform the waterproofing method without regard to internal factors or external factors, thereby providing a ceramic waterproofing method that can be applied without regard to the wet surface, which shortens the air of construction and enhances the competitiveness of the method. To have.
상기와 같은 목적을 달성하기 위한 본 발명은, 프라이머가 도포되는 프라이머층과, 일정두께의 바탕조정제가 도포되는 바탕조정층및 일정두께의 세라믹방식재가 도포되는 세라메탈층을 포함하는 세라믹 방수방식공법에 있어서, 상기 프라이머층은 30 ~ 60%의 습윤상태에서도 시공할 수 있는 프라이머 조성물로 이루어지고; 상기 프라이머조성물은 20 ~ 40 중량부의 메칠메타크릴레이트(methyl-methacrylate)와; 15 ~ 20 중량부의 하이드록시에틸메타크릴레이트(hydroxy-ethyl-methacrylate)와; 10 ~ 12.5 중량부의 폴리메칠메타크릴레이트(polymethyl-methacrylate)와; 1 ~ 2 중량부의 에틸렌글리콜디메타크릴레이트(ethylene-glycol-dimethacrylate)와; 0.5 ~ 1중량부의 부틸디글리콜메타크릴레이트(butyl-diglycol-methacrylate)와; 0.5 ~ 1중량부의 2-에틸헥실아크릴레이트(2-ethyl-hexyl-acrylate)와; 0.5 ~ 1중량부의 파라톨루이딘에톡실레이티드(para-toluidine ethoxylated)와; 0.5 ~ 1 중량부의 파라핀(paraffine)과; 0.5 ~ 1 중량부의 안트라퀴논다이(anthraquinone dye)와; 0.5 ~ 1 중량부의 메타크릴로일옥시에틸 포스페이트(methacryloyloxyethyl-phosphate)와; 10 ~ 12.5 중량부의 디벤조일 퍼옥사이드(dibenzoyl-peroxide)와; 10 ~ 12.5 중량부의 디시클로 헥실 프탈레이트(dicyclohexyl-phthalate)와; 10 ~ 12.5 중량부의 불활성 충전제의 혼합물(mixture of inert fillers)과; 0.5 ~ 1 중량부의 우레탄 메탈크릴레이크(urethane-methacrylate); 및 0.5 ~ 1 중량부의 선형 프탈레이트 에스테르(linear phthalate ester);로 조성되는 것을 특징으로 한다.The present invention for achieving the above object is a ceramic waterproofing method comprising a primer layer to which a primer is applied, a base adjustment layer to which a background thickness adjusting agent is applied, and a ceramic metal layer to which a ceramic anticorrosive material is applied. In, the primer layer is made of a primer composition that can be applied even in a wet state of 30 to 60%; The primer composition is 20 to 40 parts by weight of methyl methacrylate (methyl-methacrylate) and; 15 to 20 parts by weight of hydroxyethyl methacrylate (hydroxy-ethyl-methacrylate); 10 to 12.5 parts by weight of polymethyl methacrylate (polymethyl-methacrylate); 1 to 2 parts by weight of ethylene glycol dimethacrylate (ethylene-glycol-dimethacrylate); 0.5 to 1 part by weight of butyl diglycol methacrylate (butyl-diglycol-methacrylate); 0.5 to 1 part by weight of 2-ethylhexyl acrylate (2-ethyl-hexyl-acrylate); 0.5 to 1 part by weight of para-toluidine ethoxylated; 0.5 to 1 part by weight of paraffin (paraffine); 0.5 to 1 part by weight of anthraquinone dye; 0.5 to 1 part by weight of methacryloyloxyethyl phosphate (methacryloyloxyethyl-phosphate) and; 10 to 12.5 parts by weight of dibenzoyl-peroxide; 10 to 12.5 parts by weight of dicyclohexyl-phthalate; 10 to 12.5 parts by weight of a mixture of inert fillers (mixture of inert fillers); 0.5 to 1 part by weight of urethane metal acrylate (urethane-methacrylate); And 0.5 to 1 part by weight of a linear phthalate ester.
본 발명에 있어서, 불활성 충전제 혼합물은, 실리카, 산화지르코늄, 규산 알루미네이트 및 탄산칼슘이 0.2 : 0.3 : 0.5 : 1 중량비율로 혼합;되는 것이 바람직하다.In the present invention, it is preferable that the inert filler mixture is mixed with silica, zirconium oxide, aluminate silicate, and calcium carbonate in a weight ratio of 0.2: 0.3: 0.5: 1.
본 발명에 있어서, 세라메탈층은, 주제와 경화제가 1 : 1 중량비율로 이루어지는 세라믹 방식재이고; 상기 주제는 12 ~ 15 중량부의 산화규소(SiO2)와, 4 ~ 5 중량부 이산화타이타늄과, 0.5 ~ 1 중량부의 흄과, 4 ~ 6 중량부의 운모와, 7 ~ 10 중량부의 산화 지르코늄과, 4 ~ 6 중량부의 규산 알루미네이트와, 7 ~ 15 중량부의 방해석과, 0.1 ~ 0.5 중량부의 페로시안화 제2철과, 16 ~ 20 중량부의 에폭시수지와, 0.3 ~ 1 중량부의 친유기성 점토와, 20 ~ 45 중량부의 비스페놀-F 에폭시수지, 및 0.1 ~ 0.5 중량부의 12-하이드록시옥타데칸아마이드로 조성되며; 상기 경화제는 35 ~ 45 중량부의 아이소포론 디아민(5-AMINO-1,3,3-TRIMETHYLCYCLOHEXANEMETH AMINE)과, 35 ~ 45 중량부의 폴리아미도아민(POLYAMIDOAMINE) 및 15 ~ 25 중량부의 반응 생성물;로 조성되는 것이 바람직하다.In the present invention, the ceramic layer is a ceramic anticorrosive material composed of a main agent and a curing agent in a 1: 1 weight ratio; The above topics include 12 to 15 parts by weight of silicon oxide (SiO2), 4 to 5 parts by weight of titanium dioxide, 0.5 to 1 part by weight of fume, 4 to 6 parts by weight of mica, 7 to 10 parts by weight of zirconium oxide, 4 ~ 6 parts by weight of silicate aluminate, 7 ~ 15 parts by weight of calcite, 0.1 ~ 0.5 parts by weight of ferric cyanide, 16 ~ 20 parts by weight of epoxy resin, 0.3 ~ 1 parts by weight of lipophilic clay, 20 ~ 45 parts by weight of bisphenol-F epoxy resin, and 0.1 to 0.5 parts by weight of 12-hydroxyoctadecanamide; The curing agent is composed of 35 to 45 parts by weight of isophorone diamine (5-AMINO-1,3,3-TRIMETHYLCYCLOHEXANEMETH AMINE), 35 to 45 parts by weight of polyamidoamine (POLYAMIDOAMINE) and 15 to 25 parts by weight of reaction products; It is preferred.
본 발명에 의하면, 습윤상태를 유지하는 바탕면에 직접적으로 시공이 가능하고, 프라이머 상에 도포되는 세라믹 방식재인 세라메탈을 도포함으로써, 바탕면에 대한 내부적 요인 또는 외부적 요인 등에 구애됨이 없이 방수방식공법을 수행할 수 있고, 이로 인해 시공의 공기를 단축하여 방식시공의 경쟁력을 강화하는 효과가 있다.According to the present invention, it is possible to apply directly to the base surface to maintain the wet state, and by applying ceramic metal, a ceramic anticorrosive material applied on the primer, waterproof without regard to internal factors or external factors to the base surface. It is possible to carry out the anti-corrosion method, thereby reducing the air of the construction to enhance the competitiveness of the anti-corrosion construction.
이하, 본 발명의 바람직한 실시 예를 상세히 설명하면 다음과 같다.Hereinafter, a preferred embodiment of the present invention will be described in detail.
본 발명의 세라믹 방수방식공법은 습윤상태의 바탕면에 도포가 가능하도록 도포되는 프라이머층과, 상기 프라이머 상에 일정두께의 바탕조정제가 도포되는 바탕조정층 및 상기 바탕조정제 상에 세라믹 방수제가 일정두께 도포되는 세라메탈층을 포함한다.The ceramic waterproofing method of the present invention includes a primer layer applied to be able to be applied to a wet base surface, a base adjustment layer coated with a predetermined thickness of the background adjuster on the primer, and a predetermined thickness of the ceramic waterproofing agent on the background adjuster. It includes a ceramic layer to be applied.
상기 프라이머층은 30 ~ 60%의 습윤상태를 유지하는 바탕면에 시공이 가능하도록 조성된 프라이머를 일정두께 도포된다.The primer layer is coated with a primer having a thickness of 30 to 60% so that the primer can be applied to a base surface that maintains a wet state.
상기 프라이머 조성물은, 20 ~ 40 중량부의 메칠메타크릴레이트(methyl-methacrylate, CAS-no: 80-62-6)와, 15 ~ 20 중량부의 하이드록시에틸메타크릴레이트(hydroxy-ethyl-methacrylate, CAS-no: 868-77-9)와, 10 ~ 12.5 중량부의 폴리메칠메타크릴레이트(polymethyl-methacrylate, CAS-no: 25852-37-3)와, 1 ~ 2 중량부의 에틸렌글리콜디메타크릴레이트(ethylene-glycol-dimethacrylate, CAS-no: 97-90-5)와, 0.5 ~ 1 중량부의 부틸디글리콜메타크릴레이트(butyl-diglycol-methacrylate, CAS-no: 7328-22-5)와, 0.5 ~ 1 중량부의 2-에틸헥실아크릴레이트(2-ethyl-hexyl-acrylate, CAS-no: 103-11-7)와, 0.5 ~ 1 중량부의 파라톨루이딘에톡실레이티드(para-toluidine ethoxylated, CAS-no: 3077-12-1)와, 0.5 ~ 1 중량부의 파라핀(paraffine, CAS-no: 64742-51-4)과, 0.5 ~ 1 중량부의 안트라퀴논다이(anthraquinone dye, CAS-no: C.I.Solvent violet 13)와, 0.5 ~ 1 중량부의 메타크릴로일옥시에틸 포스페이트(methacryloyloxyethyl-phosphate, CAS-no: 52628-03-2)와, 10 ~ 12.5 중량부의 디벤조일 퍼옥사이드(dibenzoyl-peroxide, CAS-no: 94-36-0)와, 10 ~ 12.5 중량부의 디시클로 헥실 프탈레이트(dicyclohexyl-phthalate, CAS-no: 84-61-7)와, 10 ~ 12.5 중량부의 불활성 충전제의 혼합물(mixture of inert fillers, mixture of: 1318-59-8, 12001-26-2, 14808-60-7, each 33,3..%)과, 0.5 ~ 1 중량부의 우레탄 메탈크릴레이트(urethane-methacrylate, CAS-no: 607-134-00-4), 및 0.5 ~ 1 중량부의 선형 프탈레이트 에스테르(linear phthalate ester, CAS-no: 68515-42-4)로 조성된다.The primer composition, 20 to 40 parts by weight of methyl methacrylate (methyl-methacrylate, CAS-no: 80-62-6), 15 to 20 parts by weight of hydroxyethyl methacrylate (hydroxy-ethyl-methacrylate, CAS -no: 868-77-9), 10 to 12.5 parts by weight of polymethyl-methacrylate (CAS-no: 25852-37-3), and 1 to 2 parts by weight of ethylene glycol dimethacrylate ( ethylene-glycol-dimethacrylate, CAS-no: 97-90-5), 0.5 to 1 part by weight of butyl-diglycol-methacrylate, CAS-no: 7328-22-5, 0.5 to 1 part 1 part by weight of 2-ethylhexyl acrylate (2-ethyl-hexyl-acrylate, CAS-no: 103-11-7), and 0.5 to 1 part by weight of para-toluidine ethoxylated, CAS-no : 3077-12-1), 0.5 to 1 part by weight of paraffine (CAS-no: 64742-51-4), 0.5 to 1 part by weight of anthraquinone dye (anthraquinone dye, CAS-no: CISolvent violet 13 ) And 0.5 to 1 part by weight of methacryloyloxyethyl Phosphate (methacryloyloxyethyl-phosphate, CAS-no: 52628-03-2), 10 to 12.5 parts by weight of dibenzoyl-peroxide (CAS-no: 94-36-0), and 10 to 12.5 parts by weight of dish Mixture of inert fillers, mixture of: 1318-59-8, 12001-26-2, and 10 to 12.5 parts by weight of cyclohexyl phthalate (CAS-no: 84-61-7) 14808-60-7, each 33,3 ..%), 0.5 to 1 part by weight of urethane metal acrylate (CA-no: 607-134-00-4), and 0.5 to 1 part by weight of linear It consists of a phthalate ester (linear phthalate ester, CAS-no: 68515-42-4).
상기 메칠메타크릴레이트(methyl-methacrylate)는 글라이콜디메타크릴레이트로 가교되며, 피막형성제, 점증제의 기능을 수행한다. 이 경우, 20 중량부를 미만이면 피막형성 또는 점증기능이 원활하게 이루어지지 않고, 40 중량부를 초과하면 물성변화는 없으면서 재료 추가에 따른 단가의 상승으로 경제적이지 못하다.The methyl methacrylate (methyl-methacrylate) is crosslinked with glycol dimethacrylate, and functions as a film-forming agent and a thickener. In this case, if the amount is less than 20 parts by weight, the film formation or the thickening function is not smoothly performed, and if it exceeds 40 parts by weight, there is no change in physical properties and it is not economical due to the increase in unit cost due to the addition of the material.
상기 하이드록시에틸메타크릴레이트(hydroxy-ethyl-methacrylate)는 콘테츠렌즈의 주재료로 사용될 만큼 환경친화적인 재료로서, 접착기능을 포함한다. 이 경우, 15 중량부 미만이면 조성물간의 접착기능을 수행하지 못하고, 20 중량부 초과하면 물성변화는 없으면서 재료 추가에 따른 단가의 상승으로 경제적이지 못하다.The hydroxyethyl methacrylate (hydroxy-ethyl-methacrylate) is an environmentally friendly material that can be used as a main material of a contact lens, and includes an adhesive function. In this case, if it is less than 15 parts by weight, the adhesive function between the compositions cannot be performed, and if it exceeds 20 parts by weight, there is no change in physical properties and it is not economical due to an increase in unit price due to the addition of the material.
상기 폴리메칠메타크릴레이트(polymethyl-methacrylate)는 메칠메타크릴레이트의 폴리머로서, 피막형성제의 기능을 수행하는 것이다. 이 경우, 10 중량부 미만이면 피막형성이 원활하게 수행되지 못하고, 12.5 중량부 초과하면 물성변화는 없으면서 재료 추가에 따른 단가의 상승으로 경제적이지 못하다.The polymethyl methacrylate (polymethyl-methacrylate) is a polymer of methyl methacrylate, which functions as a film-forming agent. In this case, if the amount is less than 10 parts by weight, film formation is not smoothly performed, and if it exceeds 12.5 parts by weight, there is no change in physical properties and it is not economical due to an increase in unit price due to the addition of material.
상기 에틸렌글리콜디메타크릴레이트(ethylene-glycol-dimethacrylate)는 접착성능을 향상시키는 기능을 수행한다. 이 경우, 1 중량부 미만이면 접착성능 즉, 속경화성능을 발휘하지 못하고, 2 중량부 초과하면 과도한 접착성능을 발휘하여 너무 단단해져 신축성이 떨어지는 문제점이 있다.The ethylene glycol dimethacrylate (ethylene-glycol-dimethacrylate) serves to improve the adhesion performance. In this case, if it is less than 1 part by weight, the adhesion performance, that is, the fast curing performance cannot be exhibited, and if it exceeds 2 parts by weight, excessive adhesion performance is exhibited, which makes it too hard to degrade elasticity.
상기 부틸디글리콜메타크릴레이트는 피막형성 및 점증제 기능을 수행한다. 이 경우, 0.5 중량부 미만이면 피막형성 또는 점증제의 기능을 발휘하지 못하고, 1 중량부 초과하면 물성변화는 없으면서 재료 추가에 따른 단가의 상승으로 경제적이지 못하다.The butyl diglycol methacrylate performs film forming and thickener functions. In this case, if it is less than 0.5 part by weight, the function of forming or thickening agent is not exerted, and if it is more than 1 part by weight, there is no change in physical properties and it is not economical due to an increase in unit price due to the addition of material.
상기 2-에틸헥실아크릴레이트(2-ethyl-hexyl-acrylate)는 중합반응을 종결시키는 기능을 수행한다. 0.5 중량부 미만이면 신장률이 감소하고, 1 중량부 초과하면 경도가 증가하는 문제점이 있다.The 2-ethylhexyl acrylate (2-ethyl-hexyl-acrylate) serves to terminate the polymerization reaction. If it is less than 0.5 part by weight, the elongation decreases, and if it exceeds 1 part by weight, the hardness increases.
상기 파라톨루이딘에톡실레이티드는 유기합성을 통한 계면활성제 기능을 수행한다. 이 경우, 0.5 중량부 미만이면 계면활성제 기능을 수행하지 못하고, 1 중량부 초과하면 물성변화는 없으면서 재료 추가에 따른 단가의 상승으로 경제적이지 못하다.The paratoluidine ethoxylated functions as a surfactant through organic synthesis. In this case, if it is less than 0.5 part by weight, the surfactant function cannot be performed, and if it exceeds 1 part by weight, there is no change in physical properties and it is not economical due to an increase in unit cost due to the addition of the material.
상기 파라핀(paraffine)은 윤활성이 있는 석유원료를 탈랍해서 얻는 것으로서, 석탄가스를 탄화수소로 바꾸는 반응에서 얻어진 생성물 중의 하나이다. 이는 나무의 방수용 도장제, 녹방지제 및 콘크리트의 처리제로 사용된다. 이 경우, 0.5 중량부 미만이면 처리기능이 미미하고, 1 중량부 초과하면 물성변화는 없으면서 재료 추가에 따른 단가의 상승으로 경제적이지 못하다.The paraffin (paraffine) is obtained by dewaxing a lubricating petroleum raw material, and is one of products obtained in a reaction of converting coal gas to hydrocarbon. It is used as a waterproofing agent for wood, a rust inhibitor, and a treatment agent for concrete. In this case, if it is less than 0.5 part by weight, the treatment function is insignificant, and if it exceeds 1 part by weight, there is no change in physical properties and it is not economical due to an increase in unit cost due to the addition of material.
상기 안트라퀴논 다이(anthraquinone dye)는 여러 종류의 염료와 색소의 근원이 되는 물질로서, 안트라센을 산화시키거나 벤젠과 프탈산 무수물을 축합하여 만든다. 알리자린과 그 외의 많은 식물색소의 화학적 구조는 안트라귀논과 비슷하다. 안트라귀논은 알리자린 및 건염염료군을 포함한 수많은 합성염료로 전환될 수 있다. 안트라귀논이 산화에는 매우 안정하지만 쉽게 환원되어 다양한 생성물을 만든다. 알칼리 용액에서 이티온산나트륨에 의해 환원되어 안트라히드로퀴논이 되는데, 이것은 물에 녹는 알칼리 금속염이다. 이 경우, 0.5 중량부 미만이면 알칼리기능을 발휘하지 못하고, 1 중량부 초과하면 물성변화는 없으면서 재료 추가에 따른 단가의 상승으로 경제적이지 못하다.The anthraquinone dye is a material that is a source of various kinds of dyes and pigments, and is made by oxidizing anthracene or condensing benzene and phthalic anhydride. The chemical structure of alizarin and many other plant pigments is similar to that of anthraquinone. Anthraquinone can be converted into a number of synthetic dyes, including the alizarin and tendon dye groups. Anthraquinone is very stable to oxidation, but is easily reduced to produce various products. It is reduced by sodium itionate in an alkali solution to become an anhydrohydroquinone, which is an alkali metal salt soluble in water. In this case, if it is less than 0.5 part by weight, the alkali function cannot be exhibited, and if it exceeds 1 part by weight, there is no change in physical properties and it is not economical due to an increase in the unit price due to the addition of the material.
상기 메타크릴로일록시에틸 포스페이트는 바탕면에 조성물을 침투시키는 침투성능을 발휘하는 기능을 수행한다. 이 경우, 0.5 중량부 미만이면 침투성능이 저하되어 원활한 시공면을 유지할 수 없고, 1 중량부 초과하면 물성변화는 없으면서 재료 추가에 따른 단가의 상승으로 경제적이지 못하다.The methacryloyl oxyethyl phosphate performs a function of exerting the penetrating performance of penetrating the composition on the ground surface. In this case, if it is less than 0.5 part by weight, the permeation performance decreases, and thus a smooth construction surface cannot be maintained, and if it exceeds 1 part by weight, there is no change in physical properties and it is not economical due to an increase in unit cost due to material addition.
상기 디벤조일 퍼옥사이드는 발수성능을 발휘하는 기능을 수행한다. 이 경우, 10 중량부 미만이면 발수성능이 저하되고, 12.5 중량부 초과하면 물성변화는 없으면서 재료 추가에 따른 단가의 상승으로 경제적이지 못하다.The dibenzoyl peroxide performs a function of exerting water repellency. In this case, if it is less than 10 parts by weight, the water-repellent performance decreases, and if it exceeds 12.5 parts by weight, there is no change in physical properties and it is not economical due to the increase in unit cost due to the addition of materials.
상기 디시클로 헥실 프탈레이트(dicyclohexyl-phthalate)는 가소제의 기능을 수행하는 것으로서, 10 중량부 미만이면 가소제 기능을 발휘하지 못하고, 12.5 중량부 초과하면 물성변화는 없으면서 재료 추가에 따른 단가의 상승으로 경제적이지 못하다.The dicyclohexyl phthalate performs a function of a plasticizer. If it is less than 10 parts by weight, the plasticizer function is not exhibited. If it exceeds 12.5 parts by weight, there is no change in physical properties, and it is economical due to an increase in unit cost due to material addition. Can not do it.
상기 불활성 충전제의 혼합물(mixture of inert fillers)은 물리적성질 예컨대, 인장강도, 모듈러스, 마모, 노화, 내광성, 균열, 전기적 저항 등의 성질을 개선하여 소수성에 의한 발수성능을 발휘하여 바탕면의 습윤상태에서도 도포가 가능하도록 한다.The mixture of inert fillers (mixture of inert fillers) improves physical properties such as tensile strength, modulus, abrasion, aging, light resistance, cracking, electrical resistance, etc., and exhibits water repellent performance by hydrophobicity, thereby moistening the ground surface. It is also possible to apply.
상기 불활성 충전제 혼합물은 실리카, 산화지르코늄, 규산 알루미네이트 및 탄산칼슘이 0.2 : 0.3 : 0.5 : 1 중량비율로 혼합된다. 물론, 이에 한정하는 것은 아니며, 습윤상태에 도포가 가능하면서 물리적 성질을 개선시킬 수 있는 혼합물이면 어느 것이든 사용 가능하다.In the inert filler mixture, silica, zirconium oxide, aluminate silicate and calcium carbonate are mixed in a weight ratio of 0.2: 0.3: 0.5: 1. Of course, the present invention is not limited thereto, and any mixture that can be applied in a wet state and improve physical properties can be used.
상기 불활성 충전제의 경우, 10 중량부 미만이면 물리적 성질 개선효과가 미비하고, 12.5 중량부 초과하면 재료 추가에 따른 단가의 상승으로 경제적이지 못하다.In the case of the inert filler, if it is less than 10 parts by weight, the effect of improving physical properties is insufficient, and if it is more than 12.5 parts by weight, it is not economical due to an increase in unit cost due to material addition.
상기 우레탄 메탈크릴레이트는 우레탄의 공중합체로서, 인장강도와, 접착력 및 코팅안정성 등의 물리적 특성을 향상시키도록 하는 기능을 수행한다. 이 경우, 0.5 중량부 미만이면 요구되는 물리적 특성을 발휘할 수 없고, 1 중량부 초과하면 재료 추가에 따른 단가의 상승으로 경제적이지 못하다.The urethane metal acrylate is a copolymer of urethane, and performs a function to improve physical properties such as tensile strength, adhesion, and coating stability. In this case, if it is less than 0.5 part by weight, the required physical properties cannot be exhibited, and if it is more than 1 part by weight, it is not economical due to an increase in unit cost due to the addition of the material.
상기 선형 프탈레이트 에스테르(linear phthalate ester)는 성형을 쉽게 해주고 부드러운 유연성을 가지도록 하는 가소제 기능을 수행한다. 이 경우, 0.5 중량부 미만이면 가소제 기능이 미비하고, 1 중량부 초과하면 재료 추가에 따른 단가의 상승으로 경제적이지 못하다.The linear phthalate ester performs a plasticizer function that facilitates molding and has soft flexibility. In this case, if it is less than 0.5 part by weight, the plasticizer function is insufficient, and if it is more than 1 part by weight, it is not economical due to an increase in unit cost due to the addition of the material.
상기 바탕조정층은 일정두께의 바탕조정제를 도포하여 형성한다. 이 경우, 상기 바탕조정제는 종래에 사용되는 것을 사용함으로써, 여기에서 상세한 설명은 생략한다.The base adjustment layer is formed by applying a base adjustment agent having a predetermined thickness. In this case, the above-described background adjustment agent is used by conventionally used, and thus detailed description is omitted here.
상기 세라메탈층은 세라믹 방수제를 일정두께로 도포하여 형성하는 것이다.The ceramic layer is formed by applying a ceramic waterproof agent to a certain thickness.
상기 세라메탈층은 주제와 경화제가 1 : 1 중량비율로 혼합하여 이루어진다.The ceramic layer is formed by mixing a main material and a curing agent in a 1: 1 weight ratio.
상기 세라메탈의 주제는 12 ~ 15 중량부의 산화규소(SiO2)와, 4 ~ 5 중량부 이산화타이타늄과, 0.5 ~ 1 중량부의 흄과, 4 ~ 6 중량부의 운모와, 7 ~ 10 중량부의 산화 지르코늄과, 4 ~ 6 중량부의 규산 알루미네이트와, 7 ~ 15 중량부의 방해석과, 0.1 ~ 0.5 중량부의 페로시안화 제2철과, 16 ~ 20 중량부의 에폭시수지와, 0.3 ~ 1 중량부의 친유기성 점토와, 20 ~ 45 중량부의 비스페놀-F 에폭시수지, 및 0.1 ~ 0.5 중량부의 12-하이드록시옥타데칸아마이드로 조성된다.The subject of the cerametal is 12 to 15 parts by weight of silicon oxide (SiO2), 4 to 5 parts by weight of titanium dioxide, 0.5 to 1 part by weight of fume, 4 to 6 parts by weight of mica, and 7 to 10 parts by weight of zirconium oxide And 4 to 6 parts by weight of silicate aluminate, 7 to 15 parts by weight of calcite, 0.1 to 0.5 parts by weight of ferric cyanide, 16 to 20 parts by weight of epoxy resin, and 0.3 to 1 parts by weight of an organic-organic clay. , 20 to 45 parts by weight of bisphenol-F epoxy resin, and 0.1 to 0.5 parts by weight of 12-hydroxyoctadecaneamide.
상기 산화규소(SiO2)는 결정체 석영으로서, 플루오르화수소산을 제외한 산 및 알칼리에 침해되지 않는 성질을 가진다.The silicon oxide (SiO2) is a crystalline quartz, and has a property not to be invaded by acids and alkalis except hydrofluoric acid.
상기 이산화타이타늄은 빛을 쬐면 광촉매 작용 및 초친수성 작용이 일어나고, 이러한 작용에 의해 발수성능이 발휘되도록 한다.When the titanium dioxide is exposed to light, a photocatalytic action and a superhydrophilic action occur, and water repellency is exhibited by this action.
상기 흄(fume)은 증기 또는 가스상의 연소생성물이 응축하여 생성된 고체입자이다.The fume is a solid particle produced by condensation of a vapor or gaseous combustion product.
상기 운모는 2차원적인 층상구조를 갖는 층상규산염에 속하며, 이는 충전제윤활제, 및 흡착제 기능을 가진다.The mica belongs to a layered silicate having a two-dimensional layered structure, which has a filler lubricant, and an adsorbent function.
상기 산화 지르코늄(ZIRCONIUM OXIDE)은 누르스름하거나 또는 갈색을 띠는 지르코늄의 산화물로서, 화학식은 ZrO2이며, 부식에 대한 저항이 강하다.The zirconium oxide (ZIRCONIUM OXIDE) is a yellow or brownish oxide of zirconium, the chemical formula is ZrO2, and has a strong resistance to corrosion.
상기 규산 알루미네이트(ALUMINATE SILICATE)는 CAS NO 1327-36-2로서, 시멘트와 만나면 포졸란반응에 의해 조직을 치말하게 하는 기능을 수행한다.The silicate aluminate (ALUMINATE SILICATE) is CAS NO 1327-36-2, and when it meets cement, it performs a function of letting the tissue to be lethal by a pozzolanic reaction.
상기 방해석은 탄산칼슘(CACO3)의 안정한 형태로서, 유기산이나 용해된 이산화탄소(CO2)를 함유하는 지하수에 매우 잘 용해된다.The calcite is a stable form of calcium carbonate (CACO3) and is very soluble in ground water containing organic acid or dissolved carbon dioxide (CO2).
상기 페로시안화 제2철은 감청의 착색안료이다.The ferrocyanide ferric cyanide is a blue pigment.
상기 에폭시수지는 C-C-O가 삼각형으로 결합되어 있는 에폭시기를 가진 수지 상태의 화합물이나 그 화합물과 경화제를 중합하여 얻는 열경화성 합성수지이다.The epoxy resin is a thermosetting synthetic resin obtained by polymerizing a compound in a resin state having an epoxy group in which C-C-O is bonded in a triangle or a curing agent with the compound.
상기 친유기성 점토(ORGANOPHILIC CLAY)는 표면의 수산화기를 통해 친수성을 소수성으로 또는 친유기성으로 개질하는 것으로서, 4차 암모늄 화합물, 비스(수소산 수지 알킬) 다이메탈, 벤토나이트 등이 있다.The organophilic clay (ORGANOPHILIC CLAY) is a hydrophilic or hydrophilic modified by a surface hydroxyl group, quaternary ammonium compounds, bis (hydrogen resin alkyl) dimetal, bentonite and the like.
상기 비스페놀-F 에폭시수지는 에폭시기와 수지 내에 있는 수산화기가 반응에 참여하게 된다.The bisphenol-F epoxy resin participates in the reaction between the epoxy group and the hydroxyl group in the resin.
상기 12-하이드록시옥타데칸아마이드는 유화안정제, 결합제 등의 기능을 수행한다.The 12-hydroxyoctadecane amide functions as an emulsifying stabilizer and a binder.
상기 세라메탈의 경화제는 35 ~ 45 중량부의 아이소포론 디아민(5-AMINO-1,3,3-TRIMETHYLCYCLOHEXANEMETH AMINE)과, 35 ~ 45 중량부의 폴리아미도아민(POLYAMIDOAMINE) 및 15 ~ 25 중량부의 반응 생성물로 조성된다.The curing agent of the cerametal is 35 to 45 parts by weight of isophorone diamine (5-AMINO-1,3,3-TRIMETHYLCYCLOHEXANEMETH AMINE), 35 to 45 parts by weight of polyamidoamine (POLYAMIDOAMINE) and 15 to 25 parts by weight of reaction products Is created.
상기 폴리아미도아민은 반응성이 높은 폴리아마이드 수지(REACTIVE POLYAMIDE RESIN)이다.The polyamidoamine is a highly reactive polyamide resin (REACTIVE POLYAMIDE RESIN).
상기 반응 생성물은 지방산, 톨-기름, 테트라에틸렌펜타민과의 반응 생성물이다.The reaction product is a reaction product with fatty acids, tall oil, and tetraethylenepentamine.
한편, 상기 세라메탈은 주제와 경화제를 혼합하여 정형화된 제품을 미세분말화시켜 충전제로 사용하거나, 또는 주제만을 혼합한 것을 충전제로 사용할 수 있다.On the other hand, the cera metal can be used as a filler by mixing the main subject and a curing agent to form a fine powder into a molded product, or a mixture of only the main subject as a filler.
상기와 같이 구조로 구성되는 세라믹 방수방식공법은 습윤면 예컨대, 30 ~ 60%의 습윤상태를 유지하는 바탕면에 직접적으로 시공이 가능함으로써, 프라이머 상에 도포되는 세라믹 방수재인 세라메탈층에 대한 접착상태를 유지하도록 한다.The ceramic waterproof method comprising the structure as described above can be applied directly to a wet surface, for example, a base surface that maintains a wet state of 30 to 60%, thereby adhering to a ceramic waterproof material, a ceramic metal layer applied on a primer. Try to keep it.
이로 인해, 바탕면이 내부적 요인 또는 외부적 요인 등에 구애됨이 없이 세라믹 방수방식 공법에 따른 세라믹 방식재인 세라메탈의 시공이 원활하게 이루어져 방식시공의 공기를 단축함으로써, 방식공법에 대한 경쟁력을 강화한다.For this reason, the construction of ceramic metal, a ceramic anticorrosive material according to the ceramic waterproofing method, is smoothly constructed without being concerned with internal factors or external factors, thereby shortening the air for anticorrosive construction, thereby strengthening the competitiveness of the anticorrosive construction method. .
이상에서 설명한 것은 습윤면에 구애됨이 없이 시공 가능한 세라믹 방수방식공법을 실시하기 위한 하나의 실시 예에 불과한 것으로서, 본 발명은 상기한 실시 예에 한정되지 아니한다. 본 발명에 속하는 분야에서 통상의 지식을 가진 자라면, 본 발명의 요지를 벗어남이 없이 다양한 변경실시가 가능하다는 것을 이해할 수 있을 것이다.What has been described above is only one embodiment for implementing a ceramic waterproof method that can be constructed without being concerned with the wet surface, and the present invention is not limited to the above-described embodiment. Those skilled in the art to which the present invention pertains will appreciate that various modifications can be made without departing from the gist of the present invention.
Claims (3)
상기 프라이머층은 습윤상태의 바탕면에서도 시공할 수 있는 프라이머 조성물로 이루어지고;
상기 프라이머조성물은 20 ~ 40 중량부의 메칠메타크릴레이트(methyl-methacrylate)와, 15 ~ 20 중량부의 하이드록시에틸메타크릴레이트(hydroxy-ethyl-methacrylate)와, 10 ~ 12.5 중량부의 폴리메칠메타크릴레이트(polymethyl-methacrylate)와, 1 ~ 2 중량부의 에틸렌글리콜디메타크릴레이트(ethylene-glycol-dimethacrylate)와, 0.5 ~ 1중량부의 부틸디글리콜메타크릴레이트(butyl-diglycol-methacrylate)와, 0.5 ~ 1중량부의 2-에틸헥실아크릴레이트(2-ethyl-hexyl-acrylate)와, 0.5 ~ 1중량부의 파라톨루이딘에톡실레이티드(para-toluidine ethoxylated)와, 0.5 ~ 1 중량부의 파라핀(paraffine)과, 0.5 ~ 1 중량부의 안트라퀴논다이(anthraquinone dye)와, 0.5 ~ 1 중량부의 메타크릴로일옥시에틸 포스페이트(methacryloyloxyethyl-phosphate)와, 10 ~ 12.5 중량부의 디벤조일 퍼옥사이드(dibenzoyl-peroxide)와, 10 ~ 12.5 중량부의 디시클로 헥실 프탈레이트(dicyclohexyl-phthalate)와, 실리카, 산화지르코늄, 규산 알루미네이트 및 탄산칼슘이 0.2 : 0.3 : 0.5 : 1 중량비율로 혼합되는 10 ~ 12.5 중량부의 불활성 충전제의 혼합물(mixture of inert fillers)과, 0.5 ~ 1 중량부의 우레탄 메타크릴레이트(urethane-methacrylate), 및 0.5 ~ 1 중량부의 선형 프탈레이트 에스테르(linear phthalate ester)로 조성되고;
상기 세라메탈층은, 주제와 경화제가 1 : 1 중량비율로 이루어지는 세라믹 방식재이며;
상기 주제는 12 ~ 15 중량부의 산화규소(SiO2)와, 4 ~ 5 중량부 이산화타이타늄과, 0.5 ~ 1 중량부의 흄과, 4 ~ 6 중량부의 운모와, 7 ~ 10 중량부의 산화 지르코늄과, 4 ~ 6 중량부의 규산 알루미네이트와, 7 ~ 15 중량부의 방해석과, 0.1 ~ 0.5 중량부의 페로시안화 제2철과, 16 ~ 20 중량부의 에폭시수지와, 0.3 ~ 1 중량부의 친유기성 점토와, 20 ~ 45 중량부의 비스페놀-F 에폭시수지, 및 0.1 ~ 0.5 중량부의 12-하이드록시옥타데칸아마이드로 조성되고;
상기 경화제는 35 ~ 45 중량부의 아이소포론 디아민(5-AMINO-1,3,3-TRIMETHYLCYCLOHEXANEMETH AMINE)과, 35 ~ 45 중량부의 폴리아미도아민(POLYAMIDOAMINE) 및 15 ~ 25 중량부의 반응 생성물;
로 조성되는 것을 특징으로 하는 습윤면에 구애됨이 없이 시공 가능한 세라믹 방수방식공법.In the ceramic waterproof method comprising a primer layer to which a primer is applied, a base adjustment layer to which a background regulator is applied, and a ceramic metal layer to which a ceramic anticorrosive material is applied,
The primer layer is made of a primer composition that can be applied even on a wet surface;
The primer composition is 20 to 40 parts by weight of methyl methacrylate (methyl-methacrylate), 15 to 20 parts by weight of hydroxyethyl methacrylate (hydroxy-ethyl-methacrylate), and 10 to 12.5 parts by weight of polymethyl methacrylate (polymethyl-methacrylate), 1 to 2 parts by weight of ethylene-glycol-dimethacrylate, 0.5 to 1 part by weight of butyl-diglycol-methacrylate, and 0.5 to 1 part by weight 2 parts by weight of 2-ethyl-hexyl-acrylate, 0.5 to 1 part by weight of para-toluidine ethoxylated, 0.5 to 1 part by weight of paraffine, 0.5 ~ 1 part by weight of anthraquinone dye, 0.5 ~ 1 part by weight of methacryloyloxyethyl phosphate, 10 ~ 12.5 parts by weight of dibenzoyl-peroxide, 10 ~ 12.5 parts by weight of dicyclo hexyl phthaley (dicyclohexyl-phthalate), a mixture of 10 to 12.5 parts by weight of inert fillers in which silica, zirconium oxide, aluminate silicate and calcium carbonate are mixed at a weight ratio of 0.2: 0.3: 0.5: 1 and 0.5 ~ 1 part by weight of urethane methacrylate (urethane-methacrylate), and 0.5 to 1 part by weight of a linear phthalate ester (linear phthalate ester);
The ceramic layer is a ceramic anticorrosive material composed of a main agent and a curing agent in a 1: 1 weight ratio;
The above topics include 12 to 15 parts by weight of silicon oxide (SiO2), 4 to 5 parts by weight of titanium dioxide, 0.5 to 1 part by weight of fume, 4 to 6 parts by weight of mica, 7 to 10 parts by weight of zirconium oxide, 4 ~ 6 parts by weight of silicate aluminate, 7 ~ 15 parts by weight of calcite, 0.1 ~ 0.5 parts by weight of ferric cyanide, 16 ~ 20 parts by weight of epoxy resin, 0.3 ~ 1 parts by weight of lipophilic clay, 20 ~ 45 parts by weight of bisphenol-F epoxy resin, and 0.1 to 0.5 parts by weight of 12-hydroxyoctadecanamide;
The curing agent is 35 to 45 parts by weight of isophorone diamine (5-AMINO-1,3,3-TRIMETHYLCYCLOHEXANEMETH AMINE), 35 to 45 parts by weight of polyamidoamine (POLYAMIDOAMINE) and 15 to 25 parts by weight of reaction products;
Ceramic waterproof method that can be constructed without being concerned with the wet surface, characterized in that it is composed of.
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