KR102053703B1 - Composition for Light Diffused Anti-Glare Film and Light Diffused Anti-Glare Film Using the Same - Google Patents
Composition for Light Diffused Anti-Glare Film and Light Diffused Anti-Glare Film Using the Same Download PDFInfo
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- KR102053703B1 KR102053703B1 KR1020140037179A KR20140037179A KR102053703B1 KR 102053703 B1 KR102053703 B1 KR 102053703B1 KR 1020140037179 A KR1020140037179 A KR 1020140037179A KR 20140037179 A KR20140037179 A KR 20140037179A KR 102053703 B1 KR102053703 B1 KR 102053703B1
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/02—Diffusing elements; Afocal elements
- G02B5/0205—Diffusing elements; Afocal elements characterised by the diffusing properties
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/1336—Illuminating devices
- G02F1/13362—Illuminating devices providing polarized light, e.g. by converting a polarisation component into another one
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- Optics & Photonics (AREA)
- Nonlinear Science (AREA)
- Mathematical Physics (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Optical Elements Other Than Lenses (AREA)
- Polarising Elements (AREA)
Abstract
The present invention provides a light diffusing antiglare film composition having a front transmissivity of 100% or more and a slope diffusivity of 200% or more, a light diffusing antiglare film formed using the same, a polarizing plate and a liquid crystal display device having the light diffusing antiglare film. to provide. The light-diffusion anti-glare film according to the present invention has high haze and excellent front transparence and slope diffusivity.
Description
The present invention relates to a light diffusing anti-glare film composition and a light-diffusion anti-glare film using the same, and more particularly, a composition for light-diffusion anti-glare film that can be used in the manufacture of a light-diffusion anti-glare film excellent in front transmittance and slope diffusion sharpness, A light diffusion antiglare film formed using the same, a polarizing plate and a liquid crystal display device provided with the light diffusion antiglare film.
In recent years, the liquid crystal display device is rapidly expanding the application range of mobile phones, personal computer monitors, televisions, liquid crystal projectors, and the like. In general, a liquid crystal display device operates a liquid crystal in display modes such as twisted nematic (TN) mode, vertical alignment (VA) mode, and in-plane switching (IPS) mode, and electrically controls light passing through the liquid crystal. A character or an image is displayed by showing the difference of contrast on a screen.
Conventionally, in the liquid crystal display device, there is a problem that high contrast cannot be obtained when the display screen is viewed from an oblique direction, and that good display characteristics cannot be obtained due to a gray level inversion phenomenon in which the contrast of an image is reversed, that is, a narrow viewing angle. It has been pointed out.
As a method for solving the above problems, a technique for providing a light diffusing anti-glare film on the visual side of the liquid crystal display device is known. For example, the light-diffusion anti-glare film (light-diffusion sheet) which has a high haze light-diffusion layer formed by apply | coating the coating liquid containing microparticles | fine-particles on a base material is well known. By arranging such a light-diffusion antiglare film on the viewing side surface of the liquid crystal display device, when viewing the display screen of the liquid crystal display device at an angle, it is possible to extend the viewing angle by reducing the contrast of the image or improving the gray level inversion phenomenon.
However, in the conventional light-diffusion antiglare film, when sufficient light diffusivity is provided to obtain a wide viewing angle, the transmission sharpness of the display image is lowered, and thus the front contrast of the display image is lowered, and the surface of the light diffusion layer is reduced. There was a problem that the so-called whitening that caused the entire screen to appear white due to diffuse reflection occurred. On the contrary, if it was intended to provide sufficient transmission sharpness, the light diffusivity was insufficient and a wide viewing angle could not be obtained (see Japanese Patent Laid-Open No. 2012-48223).
The present invention is to solve the above problems, one object of the present invention is to provide a composition for light-diffusion anti-glare film that can be used in the production of a light-diffusion anti-glare film excellent in front transmission sharpness and slope diffusion sharpness.
Another object of the present invention is to provide a light diffusing antiglare film formed using the composition for light diffusing antiglare film.
Still another object of the present invention is to provide a polarizing plate provided with the light diffusion antiglare film.
Still another object of the present invention is to provide a liquid crystal display device having the light diffusing antiglare film.
On the other hand, the present invention provides a light diffusing anti-glare film composition having a front transmissive vividness of 100% or more, the slope diffusion sharpness of 200% or more.
In one embodiment of the present invention, the light diffusing anti-glare film is characterized in that the haze is 80 to 90%.
The composition for light-diffusion anti-glare film which concerns on one Embodiment of this invention is characterized by including a silicone particle, a translucent resin, an initiator, and a solvent.
On the other hand, the present invention provides a light-diffusion anti-glare film is formed on one side or both sides of the transparent substrate, the light-diffusion layer comprising a cured product of the composition for light-diffusion anti-glare film is formed.
On the other hand, the present invention provides a polarizing plate characterized in that the light-diffusion anti-glare film is provided.
On the other hand, the present invention provides a liquid crystal display device characterized in that the light diffusion anti-glare film is provided.
The light-diffusion anti-glare film according to the present invention has high haze and excellent front transparence and slope diffusivity. In addition, the liquid crystal display device including the light diffusing anti-glare film according to the present invention can remove the backlight diffusion film to prevent scratches generated on the surface of the backlight side polarizer due to the backlight diffusion film.
Hereinafter, the present invention will be described in more detail.
One embodiment of the present invention relates to a light diffusing antiglare film composition having a front transmissivity of at least 100% and a slope diffusivity of at least 200%.
In one embodiment of the present invention, the light diffusing anti-glare film is characterized in that the haze is 80 to 90%.
Said haze and transmission sharpness are prescribed | regulated to JISK 7105-1981 "the optical characteristic test method of plastics", and the method of obtaining the haze itself is also prescribed | regulated to JIS K 7136: 2000 "the method of obtaining the haze of a plastic-transparent material". It is. Haze is a value defined by following formula (1).
[Equation 1]
Haze = (diffusion transmittance / total light transmittance) * 100 (%)
On the other hand, the transmission sharpness means the image sharpness measured by the transmission method. As defined in the above specification, the image clarity is a value obtained according to Equation 2 below from the highest crest and the lowest crest recorded on the recording paper when any optical light is used. In addition, in this specification, the average value of the measurement result of the vertical direction and the horizontal direction of the test piece was employ | adopted.
[Equation 2]
Image Clarity = [(Highest Digging-Lowest Digging) / (Highest Digging + Lowest Digging)] × 100 (%)
In the above standard, as optical light used for measuring image sharpness, four types of ratios of the width of the dark portion and the ridge are 1: 1, and the widths are 0.125 mm, 0.5 mm, 1.0 mm, and 2.0 mm are defined. In the above, the four types of optical light are used to determine the transmission clarity with the total value of the image clarity measured by the transmission method. Thus, since the total value of the value measured using four types of optical light is made into transmission sharpness, the maximum value, ie, the value (total value of) measured without a sample, becomes 400%.
In the present specification, the front transmissive sharpness means the transmissive sharpness measured at the position of 0 degrees in the normal direction of the front face, and the diffuse sharpness means the transparency sharpness measured at the position of 30 degrees in the normal direction of the front face.
The composition for light-diffusion antiglare film which concerns on one Embodiment of this invention contains a silicon particle, a translucent resin, an initiator, and a solvent.
The composition for light-diffusion antiglare film which concerns on one Embodiment of this invention is characterized by including the silicon particle which has translucent as a diffused particle. The silicon particles may be applied without limitation as long as they are generally used in the art as forming concave and convexities on the surface of the antiglare film to impart antiglare properties to the film. The silicon particles preferably have a specific surface area of 20 m 2 / g to 30 m 2 / g and a diameter of 2.0 μm to 5.0 μm. If the diameter of the silicon particles is less than 2.0㎛ the surface of the anti-glare layer is difficult to form irregularities, the anti-glare effect does not appear, if the diameter exceeds 5.0㎛ the surface of the anti-glare layer roughness causes a problem of poor visibility.
It is preferable that the usage-amount of the said silicon particle contains 20-100 weight part with respect to 100 weight part of translucent resins. If the content of the silicon particles in less than 20 parts by weight based on 100 parts by weight of the translucent resin, the light scattering is lowered, the light diffusivity of the slope is lowered, if the content of the particles exceeds 100 parts by weight severely decrease the light transmittance problem Have.
In one embodiment of the present invention, the light transmissive resin is a photocurable resin, and the photocurable resin may include a photocurable (meth) acrylate oligomer and / or a monomer.
As said photocurable (meth) acrylate oligomer, epoxy (meth) acrylate, urethane (meth) acrylate, etc. are used normally, and urethane (meth) acrylate is preferable. Urethane (meth) acrylate can manufacture the polyfunctional (meth) acrylate which has a hydroxyl group in a molecule, and the compound which has an isocyanate group in presence of a catalyst. Specific examples of the polyfunctional (meth) acrylate having a hydroxy group in the molecule include 2-hydroxyethyl (meth) acrylate, 2-hydroxyisopropyl (meth) acrylate and 4-hydroxybutyl (meth) acrylic. At least one selected from the group consisting of latex, caprolactone ring-opening hydroxyacrylate, pentaerythritol tri / tetra (meth) acrylate mixture, and dipentaerythritol penta / hexa (meth) acrylate mixture. Specific examples of the compound having an isocyanate group include 1,4-diisocyanatobutane, 1,6-diisocyanatohexane, 1,8-diisocyanatooctane, 1,12-diisocyanatododecane, 1, 5-diisocyanato-2-methylpentane, trimethyl-1,6-diisocyanatohexane, 1,3-bis (isocyanatomethyl) cyclohexane, trans-1,4-cyclohexene diisocyanate, 4,4 '-Methylenebis (cyclohexyl isocyanate), isophorone diisocyanate, toluene-2,4-diisocyanate, toluene-2,6-diisocyanate, xylene-1,4-diisocyanate, tetramethylxylene-1, 3-diisocyanate, 1-chloromethyl-2,4-diisocyanate, 4,4'-methylenebis (2,6-dimethylphenylisocyanate), 4,4'-oxybis (phenylisocyanate), hexamethylene diisocyanate Trifunctional Isocyanates Derived from, and Trimethane Propanol Adduct Toluenediiso O it may be one or more selected from the group consisting of carbonate.
The monomer can be used conventionally without limitation, monomers having unsaturated groups such as (meth) acryloyl groups, vinyl groups, styryl groups, allyl groups, etc. in the photocurable functional groups are preferable, and among them (meth) The monomer which has an acryloyl group is preferable.
Specific examples of the monomer having a (meth) acryloyl group include neopentyl glycol acrylate, 1,6-hexanediol (meth) acrylate, propylene glycol di (meth) acrylate, and triethylene glycol di (meth) acrylate. , Dipropylene glycol di (meth) acrylate, polyethylene glycol di (meth) acrylate, polypropylene glycol di (meth) acrylate, trimethylolpropane tri (meth) acrylate, trimethylol ethane tri (meth) acrylate, 1,2,4-cyclohexanetetra (meth) acrylate, pentaglycerol tri (meth) acrylate, pentaerythritol tetra (meth) acrylate, pentaerythritol tri (meth) acrylate, dipentaerythritol tri (meth) acrylic Rate, dipentaerythritol penta (meth) acrylate, dipentaerythritol tetra (meth) acrylate, dipentaerythritol hexa (meth) acrylic Yit, tripentaerythritol tri (meth) acrylate, tripentaerythritol hexatri (meth) acrylate, bis (2-hydroxyethyl) isocyanurate di (meth) acrylate, hydroxyethyl (meth) acrylate , Hydroxypropyl (meth) acrylate, hydroxybutyl (meth) acrylate, isooctyl (meth) acrylate, isodecyl (meth) acrylate, stearyl (meth) acrylate, tetrahydrofurfuryl (meth) It may be selected from the group consisting of acrylate, phenoxyethyl (meth) acrylate, and isobornol (meth) acrylate.
The photocurable (meth) acrylate oligomer and monomer which are the above-mentioned translucent resins can be used individually or in combination of 2 or more, respectively.
The light-transmissive resin is not particularly limited, but may be included in an amount of 1 to 80 parts by weight based on 100 parts by weight of the total composition for the light diffusion antiglare film. If it is 1 part by weight or less, it is difficult to achieve sufficient hardness, and when it exceeds 80 parts by weight, curling becomes severe.
In one embodiment of the present invention, the photoinitiator can be used without limitation those used in the art. Specifically as the photoinitiator, 2-methyl-1- [4- (methylthio) phenyl] 2-morpholinepropanone-1, diphenyl ketone benzyl dimethyl ketal, 2-hydroxy-2-methyl-1-phenyl -1-one, 4-hydroxycyclophenyl ketone, dimethoxy-2-phenylacetophenone, anthraquinone, fluorene, triphenylamine, carbazole, 3-methylacetophenone, 4-knoloacetophenone, 4, At least one selected from the group consisting of 4-dimethoxyacetophenone, 4,4-diaminobenzophenone, 1-hydroxycyclohexylphenylketone, and benzophenone can be used.
The photoinitiator may be included in an amount of 0.1 to 10 parts by weight based on 100 parts by weight of the total composition for the light diffusion antiglare film. When the content of the photoinitiator is less than 0.1 parts by weight, the curing rate is slow, and when it exceeds 10 parts by weight, cracks may occur in the anti-glare light diffusion layer due to over curing.
In one embodiment of the present invention, the solvent can be used without limitation so long as it is known as a solvent in the art. In one example, the solvent is an alcohol-based (methanol, ethanol, isopropanol, butanol, methylcellulose, ethyl solusorb, 1-methoxy-2-propanol, etc.), ketones (methyl ethyl ketone, methyl butyl ketone, methyl iso Butyl ketone, diethyl ketone, dipropyl ketone, cyclohexanone and the like), hexane type (hexane, heptane, octane and the like), benzene type (benzene, toluene, xylene and the like) and the like can be preferably used. Solvents illustrated above can be used individually or in combination of 2 types or more, respectively.
The solvent may be included in an amount of 10 to 95 parts by weight based on 100 parts by weight of the total composition of the light diffusing antiglare film. If the solvent is less than 10 parts by weight on the basis of the high viscosity, the workability is low, when the solvent exceeds 95 parts by weight, it takes a long time in the curing process and there is a problem of low economic efficiency.
The light diffusing antiglare film composition according to an embodiment of the present invention, in addition to the components described above, components generally used in the art, such as antioxidants, UV absorbers, light stabilizers, thermal polymerization inhibitors, Leveling agents, surfactants, lubricants, antifouling agents and the like may additionally be included.
One embodiment of the present invention relates to a light diffusing antiglare film formed using the composition for light diffusing antiglare film described above. The light-diffusion anti-glare film according to one embodiment of the present invention is characterized in that a light-diffusion layer comprising a cured product of the composition for light-diffusion anti-glare film described above is formed on one or both surfaces of the transparent substrate.
As the transparent substrate, any plastic film having transparency can be used. For example, a cycloolefin derivative having a unit of a monomer containing a cycloolefin such as norbornene or a polycyclic norbornene monomer, cellulose (diacetyl cellulose, triacetyl cellulose, acetyl cellulose butyrate, isobutyl ester cellulose, Propionyl cellulose, butyryl cellulose, acetyl propionyl cellulose), ethylene vinyl acetate copolymer, polyester, polystyrene, polyamide, polyetherimide, polyacryl, polyimide, polyether sulfone, polysulfone, polyethylene, polypropylene, Polymethylpentene, polyvinyl chloride, polyvinylidene chloride, polyvinyl alcohol, polyvinyl acetal, polyether ketone, polyether ether ketone, polyether sulfone, polymethyl methacrylate, polyethylene terephthalate, polybutylene terephthalate, Polyethylene naphthalene , Polycarbonate, polyurethane, and epoxy can be selected and used, and an unoriented, uniaxial or biaxially oriented film can be used.
Specifically, the uniaxial or biaxially stretched polyester film excellent in transparency and heat resistance among the above-described transparent substrates, or a cycloolefin derivative film capable of coping with the enlargement of the film while being excellent in transparency and heat resistance, transparency and optically anisotropy Triacetyl cellulose film free, high transparency and low cost acrylic copolymer film can be suitably used.
The thickness of the transparent substrate is not particularly limited, but may be 8 to 1000 μm, specifically 20 to 150 μm. If the thickness of the transparent substrate is less than 8 μm, the strength of the film is lowered, resulting in poor workability.
The light-diffusion anti-glare film according to one embodiment of the present invention can be produced by coating and curing the light-diffusion anti-glare film composition of the present invention on one or both sides of the transparent substrate to form a light-diffusion layer.
The composition for light-diffusion anti-glare film which concerns on one Embodiment of this invention coats a transparent base material suitably using well-known methods, such as a die coater, an air knife, a reverse roll, a spray, a blade, casting, gravure, microgravure, and a spin coating. (Coating Process) is possible.
After applying the light diffusing antiglare film composition to a transparent substrate, the volatiles are dried by evaporation for 10 seconds to 1 hour, more specifically 30 seconds to 30 minutes at a temperature of 30 to 150 ℃, UV Irradiate and harden light. The irradiation amount of the UV light may be specifically about 0.01 to 10J / ㎠, more specifically 0.1 to 2J / ㎠.
At this time, the thickness of the light diffusion layer formed may be specifically 1 to 30㎛, more specifically 1.5 to 10㎛. When the thickness of the light diffusion layer is included in the above range it can be obtained an excellent hardness effect.
One embodiment of the present invention relates to a polarizing plate provided with the light diffusing antiglare film described above. The polarizing plate according to the embodiment of the present invention may be manufactured by stacking the above-described light diffusing antiglare film on one surface of the polarizing film such that the transparent substrate side of the light diffusing antiglare film faces the polarizing film.
The polarizing film is not particularly limited, and for example, a biaxial material such as iodine or a dichroic dye is adsorbed onto a hydrophilic polymer film such as a polyvinyl alcohol film or an ethylene-vinyl acetate copolymerized partial saponified film. A stretched film, a polyene oriented film such as a dehydrated product of polyvinyl alcohol or a dehydrochloric acid processed product of polyvinyl chloride, or the like can be used. Specifically, those made of a dichroic substance such as a polyvinyl alcohol film and iodine can be used. Although the thickness of these polarizing films is not specifically limited, Generally, it is about 5-80 micrometers.
One embodiment of the present invention relates to a liquid crystal display device provided with the light diffusing anti-glare film described above. When the polarizing plate of the present invention described above is usually attached to a liquid crystal display device, the light-diffusion antiglare film is adhered to a glass substrate of a liquid crystal panel through an adhesive layer or the like so that the light diffusing antiglare film is a visible side (light exit side) and the liquid crystal It is incorporated in the display device.
The liquid crystal display device according to one embodiment of the present invention is preferably configured to include a backlight device, a light deflecting means, a backlight side polarizing plate, a liquid crystal cell, and the polarizing plate of the present invention in this order. Specifically, in the case of the TN type liquid crystal display device of the normally white mode, the liquid crystal cell in which a liquid crystal layer is provided between a backlight device, two prism films as a light deflection means, a backlight side polarizing plate, and a pair of transparent substrates, and The polarizing plate (view side polarizing plate) of this invention is arrange | positioned in this order. The member constituting the liquid crystal display device and its manufacturing method are based on methods known in the art, and detailed description thereof will be omitted.
The light-diffusion anti-glare film according to one embodiment of the present invention can be used in reflective, transmissive, semi-transmissive LCD or LCD of various driving methods such as TN type, STN type, OCB type, HAN type, VA type, and IPS type. .
Hereinafter, the present invention will be described in more detail with reference to Examples, Comparative Examples and Experimental Examples. These examples, comparative examples and experimental examples are only for illustrating the present invention, it is apparent to those skilled in the art that the scope of the present invention is not limited thereto.
Examples 1 to 6 and Comparative Examples 1 to 4: Preparation of the composition for light diffusion antiglare film
Each component was mixed at a ratio (unit; wt%) as shown in Table 1 to prepare a light diffusing anti-glare composition.
M340: pentaerythritol tree / tetraacrylate
Tospearl 120: 2 탆 diameter silicon particles (refractive index 1.43, momentary)
Tospearl 130: 3 micrometer diameter silicon particles (refractive index 1.43, momentary)
XX-04HW: 5 micrometers diameter acrylic particle (Sekisui Corporation)
XX-11HW: 2 micrometers diameter acrylic particle (Sekisui Corporation)
XX-17HW: 7 µm diameter acrylic particles (Sekisui Co., Ltd.)
XX-10HW: 3 micrometers diameter acrylic particle (Sekisui Corporation)
PGME: 1-methoxy-2-propanol
Irgacure 184: 1-hydroxycyclohexylphenyl ketone
BYK-3550: Silicone Modified Oil (BYK)
Experimental Example 1: Preparation and Evaluation of Light Diffusion Anti-glare Film
After stirring the composition for the light-diffusion anti-glare film prepared in the above Examples and Comparative Examples for 2 hours, and applied to the triacetyl cellulose film (40㎛, TAC) with a meyer bar so that the thickness is 1.5 ~ 3㎛, 80 ℃ After drying for 2 minutes at 400mJ / cm 2 was cured to prepare a light-diffusion anti-glare film.
The physical properties of the light-diffusion antiglare film prepared as described above were measured as follows, and the results are shown in Table 2 below.
(1) haze measurement
Haze of each film was measured using the HM-150 Haze Meter of MURAKAMI.
(2) Front (0 degree) transmission sharpness measurement
The transmission sharpness of each film was measured using the sharpness measuring instrument (ICM-1T, Suga Corporation). Transparency clarity was determined by the sum of the clarity values of the slit intervals of 0.125 mm, 0.5 mm, 1.0 mm, and 2.0 mm.
(3) Measurement of slope sharpness (30 degrees)
Diffusion sharpness of each film was measured using the sharpness measuring instrument (ICM-1T, Suga Corporation). The diffusion sharpness of the 30 degree slope was measured at a position of 30 degrees in the normal direction of the front face, and the numerical value was determined by the sum of the diffusion sharpness values of the slit intervals of 0.125 mm, 0.5 mm, 1.0 mm, and 2.0 mm.
As shown in Table 2, the light-diffusion anti-glare film of Examples 1 to 6 according to the present invention using silicon particles as the diffusing particles has a haze of 82.1 to 86.4%, a transmission clarity (front face 0 degree) and a diffused clarity (slope 30). 100) or more and 200% or more, respectively, it was confirmed that the light diffusivity is superior to the antiglare film of Comparative Examples 2 to 4 using the acrylic particles as the diffusion particles.
Having described the specific part of the present invention in detail, it is apparent to those skilled in the art that this specific technology is only a preferred embodiment, which is not intended to limit the scope of the present invention. Do. Those skilled in the art to which the present invention pertains will be able to make various applications and modifications within the scope of the present invention based on the above contents.
Therefore, the substantial scope of the present invention will be defined by the appended claims and equivalents thereof.
Claims (10)
The light diffusion antiglare film has a haze of 80 to 90%,
The light-diffusion antiglare film composition comprises a diffusion particle, a light transmitting resin, an initiator and a solvent consisting of only silicon particles,
The composition for light-diffusion antiglare film, wherein the silicon particles are contained in an amount of 25 to 100 parts by weight based on 100 parts by weight of the translucent resin.
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| WO2012014849A1 (en) | 2010-07-27 | 2012-02-02 | 住友化学株式会社 | Light-scattering film, method of manufacturing same, light-scattering polarizing plate, and liquid-crystal display device |
| KR20120024211A (en) * | 2010-09-06 | 2012-03-14 | 동우 화인켐 주식회사 | Anti-glare film, polarizing plate and display device using the same |
| KR20120129643A (en) * | 2011-05-20 | 2012-11-28 | 동우 화인켐 주식회사 | Coating composition for anti-glare and anti-reflection, film using the same, polarizing plate, and display device |
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| JP2010170122A (en) | 2008-12-23 | 2010-08-05 | Sumitomo Chemical Co Ltd | Optical film and liquid crystal display device comprising the same |
| JP2012078736A (en) | 2010-10-06 | 2012-04-19 | Sumitomo Chemical Co Ltd | Light diffusion film and manufacturing method for the same, light diffusion polarization plate, and liquid crystal display device |
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| KR20150112631A (en) | 2015-10-07 |
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