KR101989928B1 - coating material compositon for construction and coating material comprising the same - Google Patents
coating material compositon for construction and coating material comprising the same Download PDFInfo
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- KR101989928B1 KR101989928B1 KR1020180136000A KR20180136000A KR101989928B1 KR 101989928 B1 KR101989928 B1 KR 101989928B1 KR 1020180136000 A KR1020180136000 A KR 1020180136000A KR 20180136000 A KR20180136000 A KR 20180136000A KR 101989928 B1 KR101989928 B1 KR 101989928B1
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/4596—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with fibrous materials or whiskers
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
- C04B41/483—Polyacrylates
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5024—Silicates
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5025—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
- C04B41/5035—Silica
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5025—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
- C04B41/5041—Titanium oxide or titanates
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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Abstract
Description
본 발명은 건축마감재용 바름재 조성물 및 이를 포함하는 건축마감재용 바름재에 관한 것으로서, 부착강도, 인장강도가 우수할 뿐만 아니라 열적 성능이 우수한 건축마감재용 바름재 조성물 및 이를 포함하는 건축마감재용 바름재에 관한 것이다.The present invention relates to a coating material composition for building finishing materials and a coating material for building finishing materials comprising the same, as well as excellent adhesion strength, tensile strength, and a thermal finishing material composition for building finishing materials and a building finishing material comprising the same It's about ashes.
일반적으로 건축물의 외장재로 사용되는 제품 중 아크릴 에멀젼을 주로 한 얇은 바름재는 일반 규사 혹은 컬러 코팅 규사, 안료 등을 혼합하여 제조된다.Generally, thin coating material mainly made of acrylic emulsion is manufactured by mixing general silica sand or color coated silica sand and pigment.
얇은 바름재는 대부분 단열재의 상부나 건축물의 가장 외측면에 시공되기 때문에 외기 온도의 변화나 건축물의 수축 팽창 등에 의해 표면에 균열이 발생하는 문제점이 있다. 한편, 가장 표면부에 시공되는 마감재로서 얇은 바름재는 외부 복사열이 투과되는 부위로 일사가 표면에 축적됨으로 인해 건축물의 실내 온도 변화의 주요한 인자가 된다. Since the thin coating material is mostly installed on the upper side of the heat insulating material or the outermost surface of the building, there is a problem that the surface is cracked due to the change in the outside air temperature or the contraction and expansion of the building. On the other hand, as a finishing material to be installed on the most surface portion, the thin coating material is a site through which external radiant heat is transmitted, and as a result, solar radiation accumulates on the surface, and thus becomes a major factor in changing the room temperature of a building.
따라서, 얇은 바름재의 인장강도를 강화하고 차열성과 같은 성능을 부여된 외장 마감재의 개발이 요구되고 있다. Therefore, there is a demand for the development of an exterior finish that has enhanced the tensile strength of the thin coating material and is endowed with performance such as heat shielding properties.
본 발명은 건축물의 외장에 1 ~ 5mm의 얇은 두께로 미장하여도 부착강도, 인장강도가 우수할 뿐만 아니라 차열성이 우수한 건축마감재용 바름재 조성물 및 이를 포함하는 건축마감재용 바름재를 제공하는 것이다.The present invention is to provide a coating material composition for building finishing materials and a building finishing material comprising the same as well as excellent adhesion strength, tensile strength and excellent heat shielding even when plastered with a thin thickness of 1 ~ 5mm on the exterior of the building. .
상술한 과제를 해결하기 위하여, 본 발명의 건축마감재용 바름재 조성물은 아크릴 에멀젼 수지, 실란개질 아크릴 에멀젼 수지, 셀룰로오즈 섬유, 골재, 이산화타이타늄(TiO2) 및 알루미노실리케이트(aluminosilicate)를 포함한다.In order to solve the above problems, the coating material composition for building finishing materials of the present invention comprises an acrylic emulsion resin, a silane-modified acrylic emulsion resin, cellulose fibers, aggregate, titanium dioxide (TiO 2 ) and aluminosilicate (aluminosilicate).
본 발명의 바람직한 일실시예에 있어서, 본 발명의 단열재용 바탕조정재 조성물은 아크릴 에멀젼 수지 100 중량부에 대하여, 실란개질 아크릴 에멀젼 수지 15 ~ 25 중량부, 셀루로오즈 섬유 1.5 ~ 2.5 중량부, 골재 302 ~ 505 중량부, 이산화타이타늄 25 ~ 42 중량부 및 알루미노실리케이트 25 ~ 42 중량부를 포함할 수 있다.In a preferred embodiment of the present invention, the base material for heat insulating material composition of the present invention is based on 100 parts by weight of the acrylic emulsion resin, 15 to 25 parts by weight of silane-modified acrylic emulsion resin, 1.5 to 2.5 parts by weight of cellulose fibers, aggregate 302 to 505 parts by weight, 25 to 42 parts by weight of titanium dioxide and 25 to 42 parts by weight of aluminosilicate.
본 발명의 바람직한 일실시예에 있어서, 본 발명의 단열재용 바탕조정재 조성물은 아크릴 에멀젼 수지 100 중량부에 대하여, 실란개질 아크릴 에멀젼 수지 17 ~ 23 중량부, 셀루로오즈 섬유 1.7 ~ 2.3 중량부, 골재 342 ~ 464 중량부, 이산화타이타늄 28 ~ 39 중량부 및 알루미노실리케이트 28 ~ 39 중량부를 포함할 수 있다.In a preferred embodiment of the present invention, the base material for heat insulating material composition of the present invention is based on 100 parts by weight of the acrylic emulsion resin, 17 to 23 parts by weight of the silane-modified acrylic emulsion resin, 1.7 to 2.3 parts by weight of cellulose fibers, aggregate 342 to 464 parts by weight, titanium dioxide 28 to 39 parts by weight and aluminosilicate may comprise 28 to 39 parts by weight.
본 발명의 바람직한 일실시예에 있어서, 골재는 0.15 ~ 0.6mm인 규사를 포함할 수 있다.In one preferred embodiment of the present invention, the aggregate may comprise silica sand 0.15 ~ 0.6mm.
본 발명의 바람직한 일실시예에 있어서, 실란개질 아크릴 에멀젼 수지는 고형분을 27 ~ 33중량%로 포함하고, pH 6 ~ 11이며, 점도는 200 cps(25℃) 이하이고, 유리전이온도(Tg)가 -20 ~ 20℃일 수 있다.In a preferred embodiment of the present invention, the silane-modified acrylic emulsion resin contains a solid content of 27 to 33% by weight, pH 6 ~ 11, the viscosity is 200 cps (25 ℃) or less, the glass transition temperature (Tg) It may be -20 ~ 20 ℃.
본 발명의 바람직한 일실시예에 있어서, 셀룰로오즈 섬유는 1,500 ~ 2,500㎛의 길이, 30 ~ 40㎛의 두께, 5 ~ 30g/l의 부피 밀도(bulk density)를 가질 수 있다.In a preferred embodiment of the present invention, the cellulose fibers may have a length of 1,500 to 2,500 μm, a thickness of 30 to 40 μm, and a bulk density of 5 to 30 g / l.
본 발명의 바람직한 일실시예에 있어서, 알루미노실리케이트는 원형 중공체(hollw shperes)일 수 있다.In one preferred embodiment of the invention, the aluminosilicate may be circular hollow bodies (hollw shperes).
본 발명의 바람직한 일실시예에 있어서, 알루미노실리카이트는 20 ~ 110㎛의 입자크기, 0.5 ~ 1.0 cm3의 비중, 1500 ~ 2100℃의 융점을 가질 수 있다.In a preferred embodiment of the present invention, the aluminosilicate may have a particle size of 20 ~ 110㎛, specific gravity of 0.5 ~ 1.0 cm 3 , melting point of 1500 ~ 2100 ℃.
한편, 본 발명의 건축마감재용 바름재는 앞서 언급한 건축마감재용 바름재 조성물을 포함한다.On the other hand, the building material for building finishing material of the present invention includes the above-mentioned building material for building finishing material.
본 발명의 바람직한 일실시예에 있어서, 본 발명의 건축마감재용 바름재는 건축물의 외장 바름재일 수 있다.In a preferred embodiment of the present invention, the building material for the finishing material of the present invention may be an exterior coating material of the building.
본 발명의 바람직한 일실시예에 있어서, 본 발명의 건축마감재용 바름재(재령 28일 기준)는 3mm의 두께를 가질 때, KS F 4715 규정에 의해 측정한 부착강도가 1.0 ~ 2.0 N/mm2일 수 있다.In a preferred embodiment of the present invention, when the coating material for building finishing material of the present invention (age 28 days) has a thickness of 3mm, the adhesion strength measured by the KS F 4715 regulation 1.0 ~ 2.0 N / mm 2 Can be.
본 발명의 바람직한 일실시예에 있어서, 본 발명의 건축마감재용 바름재(재령 28일 기준)는 3mm의 두께를 가질 때, KS M ISO 1798 규정에 의해 측정한 인장강도가 0.5 ~ 1.5 N/mm2일 수 있다.In a preferred embodiment of the present invention, when the coating material for building finishing materials (age 28 days) of the present invention has a thickness of 3mm, the tensile strength measured by the KS M ISO 1798 standard 0.5 ~ 1.5 N / mm Can be 2
본 발명의 바람직한 일실시예에 있어서, 본 발명의 건축마감재용 바름재는 하기 실험방법 1에 의해 측정한 융빙율이 50% 이하일 수 있다.In a preferred embodiment of the present invention, the coating material for building finishing material of the present invention may have a melting rate of 50% or less measured by Experimental Method 1 below.
[실험방법 1]Experimental Method 1
스티로폼 구조체(Box) 내부에는 1리터의 얼음을 넣어 놓고, 스티로폼 구조체(Box) 외부 표면에는 건축마감재용 바름재 조성물을 도포한 뒤, 완전 경화시켜 두께 3mm로 건축마감재용 바름재를 형성한 후, 외기에 노출시킨 후부터 16,000초가 지난 후의 얼음의 융빙율을 측정한다.1 liter of ice is placed in the styrofoam structure (Box), and the coating material composition for building finish is applied to the outer surface of the styrofoam structure (Box), and then completely cured to form a coating material for building finish with a thickness of 3 mm. Measure the ice melt rate after 16,000 seconds after exposure to outside air.
본 발명의 건축마감재용 바름재 조성물 및 이를 포함하는 건축마감재용 바름재는 부착강도, 인장강도가 우수할 뿐만 아니라 열적 성능이 우수하다.The coating material composition for building finishing material of the present invention and the building material for building finish including the same have excellent adhesive strength, tensile strength and excellent thermal performance.
또한, 본 발명의 건축마감재용 바름재 조성물 및 이를 포함하는 건축마감재용 바름재는 특히, 건축물의 외장에 1 ~ 5mm의 얇은 두께로 시공하여도 부착강도, 인장강도가 우수할 뿐만 아니라, 온도저감효과가 우수하고, 융빙율 또한 낮다.In addition, the coating material composition for building finishing material of the present invention and the building material for building finish comprising the same, in particular, even if the construction of a thin thickness of 1 ~ 5mm on the exterior of the building excellent adhesion strength, tensile strength, temperature reduction effect Is excellent, and the melting rate is low.
이하, 첨부한 도면을 참고로 하여 본 발명의 실시예에 대하여 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 용이하게 실시할 수 있도록 상세히 설명한다. 본 발명은 여러 가지 상이한 형태로 구현될 수 있으며 여기에서 설명하는 실시예에 한정되지 않는다.Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings so that those skilled in the art may easily implement the present invention. As those skilled in the art would realize, the described embodiments may be modified in various different ways, all without departing from the spirit or scope of the present invention.
본 발명의 건축마감재용 바름재 조성물은 아크릴 에멀젼 수지, 실란개질 아크릴 에멀젼 수지, 셀룰로오즈 섬유, 골재, 이산화타이타늄 및 알루미노실리케이트를 포함한다.The coating material composition for building finishing materials of the present invention includes an acrylic emulsion resin, a silane-modified acrylic emulsion resin, cellulose fibers, aggregates, titanium dioxide and aluminosilicate.
먼저, 본 발명의 아크릴 에멀젼 수지(acryl emulsion resin)은 본 발명의 건축마감재용 바름재 조성물에 포함되어 각종 물리적 성능을 개선하는 혼화용 폴리머의 역할을 한다.First, the acrylic emulsion resin of the present invention is included in the coating material composition for building finishing materials of the present invention serves as a blending polymer for improving various physical performance.
본 발명의 아크릴 에멀젼 수지는 합성 유기 고분자 물질로서, 열에 의하여 유동성이 생기므로 열가소성 수지라고도 할 수 있다. 통상적으로 건축마감재용 바름재 조성물에 사용되는 아크릴 에멀젼은 제한없이 사용될 수 있으며 바람직하게는, 알킬 아크릴레이트 또는 알킬 메타크릴레이트를 포함하는 소수성 아크릴 단량체, 아크릴아미드 화합물, 비닐 피롤리돈 화합물 및 아미노에틸 아크릴레이트 화합물로 이루어진 군에서 선택된 적어도 하나의 단량체, 에틸렌옥사이드 부가 아크릴 단량체, 불포화 카르복시산 단량체 및 히드록시기 또는 글리시딜기를 함유하는 아크릴 단량체를 포함하는 친수성 단량체 및 중합개시제를 반응시켜 제조할 수 있다. 이 때, 분자량은 100 ~ 100만일 수 있다.The acrylic emulsion resin of the present invention is a synthetic organic polymer material, and may be referred to as a thermoplastic resin because fluidity is generated by heat. The acrylic emulsions typically used in building finish compositions for building finishes can be used without limitation, preferably hydrophobic acrylic monomers, acrylamide compounds, vinyl pyrrolidone compounds and aminoethyls, including alkyl acrylates or alkyl methacrylates. It can be prepared by reacting at least one monomer selected from the group consisting of an acrylate compound, an ethylene oxide addition acrylic monomer, an unsaturated carboxylic acid monomer and a hydrophilic monomer including a hydroxy group or an acrylic monomer containing a glycidyl group and a polymerization initiator. At this time, the molecular weight may be 1 million to 1 million.
또한, 바람직하게는, 본 발명의 아크릴 에멀젼 수지는 퓨어 아크릴 에멀젼 수지, EVA-아크릴 혼성 에멀젼 수지 및 스타이렌-아크릴 에멀젼 수지 중 1종 이상을 포함할 수 있다.In addition, preferably, the acrylic emulsion resin of the present invention may include at least one of a pure acrylic emulsion resin, an EVA-acrylic hybrid emulsion resin and a styrene-acrylic emulsion resin.
다음으로, 본 발명의 실란개질 아크릴 에멀젼 수지는 실란으로 표면이 개질된 아크릴 에멀젼 수지로서 본 발명의 건축마감재용 바름재 조성물에 포함되어 인장강도를 상승시키는 역할을 한다.Next, the silane-modified acrylic emulsion resin of the present invention is included in the coating material composition for building finishing materials of the present invention as an acrylic emulsion resin whose surface is modified with silane serves to increase the tensile strength.
구체적으로, 본 발명의 실란개질 아크릴 에멀젼 수지는 유-무기 하이브리드 실란개질 아크릴 에멀젼 수지로서, 음이온성을 가질 수 있다. 또한, 실란개질 아크릴 에멀젼 수지의 아크릴 에멀젼 수지의 소재는 앞서 언급한 아크릴 에멀젼 수지의 소재와 동일 또는 상이할 수 있다.Specifically, the silane-modified acrylic emulsion resin of the present invention is an organic-inorganic hybrid silane-modified acrylic emulsion resin, and may have anionicity. In addition, the material of the acrylic emulsion resin of the silane-modified acrylic emulsion resin may be the same or different from the material of the acrylic emulsion resin mentioned above.
또한, 본 발명의 실란개질 아크릴 에멀젼 수지는 고형분을 27 ~ 33중량%, 바람직하게는 28 ~ 32중량%, 더욱 바람직하게는 29 ~ 31중량%로 포함할 수 있다.In addition, the silane-modified acrylic emulsion resin of the present invention may contain a solid content of 27 to 33% by weight, preferably 28 to 32% by weight, more preferably 29 to 31% by weight.
또한, 본 발명의 실란개질 아크릴 에멀젼 수지는 pH가 6 ~ 11, 바람직하게는 7 ~ 10, 더욱 바람직하게는 8 ~ 9일 수 있다.In addition, the silane-modified acrylic emulsion resin of the present invention may have a pH of 6 to 11, preferably 7 to 10, more preferably 8 to 9.
또한, 본 발명의 실란개질 아크릴 에멀젼 수지는 점도가 200 cps(25) 이하, 바람직하게는 100 cps(25) 이하, 더욱 바람직하게는 10 ~ 100 cps(25)일 수 있다.In addition, the silane-modified acrylic emulsion resin of the present invention may have a viscosity of 200 cps (25) or less, preferably 100 cps (25) or less, more preferably 10 to 100 cps (25).
또한, 본 발명의 실란개질 아크릴 에멀젼 수지는 유리전이온도(Tg)가 -20 ~ 20, 바람직하게는 -10 ~ 10, 더욱 바람직하게는 -5 ~ 5를 가질 수 있다.In addition, the silane-modified acrylic emulsion resin of the present invention may have a glass transition temperature (Tg) of -20 to 20, preferably -10 to 10, more preferably -5 to 5.
또한, 본 발명의 실란개질 아크릴 에멀젼 수지는 아크릴 에멀젼 수지 100 중량부에 대하여 15 ~ 25 중량부, 바람직하게는 17 ~ 23 중량부, 더욱 바람직하게는 19 ~ 21 중량부로 포함할 수 있으며, 만일 실란개질 아크릴 에멀젼이 15 중량부 미만으로 포함하면, 인장강도가 개선효과가 낮아지는 문제가 있을 수 있고, 25 중량부를 초과하여 포함하면 가격이 상승하는 문제가 있을 수 있다.In addition, the silane-modified acrylic emulsion resin of the present invention may comprise 15 to 25 parts by weight, preferably 17 to 23 parts by weight, more preferably 19 to 21 parts by weight with respect to 100 parts by weight of the acrylic emulsion resin, If the modified acrylic emulsion is included in less than 15 parts by weight, there may be a problem that the tensile strength improvement effect is lowered, and if it contains more than 25 parts by weight there may be a problem that the price rises.
다음으로, 본 발명의 골재는 콘크리트, 모르타르, 선회반죽, 역청질 혼합물 등과 같이 결합재에 의하여 뭉쳐서 한 덩어리는 이룰 수 있는 건설용 광물질 재료로서 화학적으로 안정한 것을 사용할 수 있다. 또한, 본 발명의 골재는 하천, 산림, 공유수면, 기타 지상, 지하 등에 부존되어 있는 쇄석용 암석, 모래, 자갈, 슬래그를 포함하며, 골재의 평균입경에 따라 5mm 이상인 조골재(粗骨材), 5mm 이하의 세골재(洗骨材)로 나눌 수 있는데, 본 발명의 골재는 평균입경이 0.15mm ~ 0.6mm, 바람직하게는 0.25mm ~ 0.6mm인 규사를 포함할 수 있다. 만일, 골재의 평균입경이 0.15mm 미만이면 유동성 저하로 인한 작업성의 문제가 있을 수 있고, 0.6mm를 초과하면 건축물의 내외장에 미장시 문제가 있을 수 있다.Next, the aggregate of the present invention may be chemically stable as a construction mineral material that can be agglomerated by a binder such as concrete, mortar, kneading dough, bituminous mixture and the like. In addition, the aggregate of the present invention includes rocks, sand, gravel, slag for crushed stone, which is present in rivers, forests, public waters, other ground, underground, etc., and coarse aggregates (粗 骨材) having an average particle diameter of 5 mm or more, Can be divided into fine aggregate (洗 骨材) of 5mm or less, the aggregate of the present invention may include a silica sand having an average particle diameter of 0.15mm ~ 0.6mm, preferably 0.25mm ~ 0.6mm. If the average particle diameter of the aggregate is less than 0.15mm, there may be a problem of workability due to fluidity deterioration, and if the average particle diameter exceeds 0.6mm, there may be a problem when plastering the interior and exterior of the building.
또한, 본 발명의 골재는 아크릴 에멀젼 수지 100 중량부에 대하여 302 ~ 505 중량부, 바람직하게는 342 ~ 464 중량부, 더욱 바람직하게는 383 ~ 424 중량부를 포함할 수 있으며, 만일 골재가 302 중량부 미만으로 포함하거나 505 중량부를 초과하게 된다면 건축물의 내외장에 미장 성능이 저하되어 두께가 증가하게 되며, 바름성의 저하로 부착강도 저하와 물 흡수계수가 증가하게 되는 문제가 있을 수 있다.In addition, the aggregate of the present invention may comprise 302 ~ 505 parts by weight, preferably 342 ~ 464 parts by weight, more preferably 383 ~ 424 parts by weight, based on 100 parts by weight of the acrylic emulsion resin, if the aggregate is 302 parts by weight If less than or exceeds 505 parts by weight, the plastering performance is reduced in the interior and exterior of the building to increase the thickness, there may be a problem that the adhesion strength is lowered and the water absorption coefficient is increased due to deterioration.
다음으로, 본 발명의 셀룰로오즈(cellulose) 섬유는 셀룰로오즈(cellulose)를 포함하는 섬유로서, 본 발명의 건축마감재용 바름재 조성물에 포함되어 인장강도 및 휨인성 증진 및 취성적 성질을 개선시키는 역할을 한다.Next, the cellulose fiber of the present invention is a fiber containing cellulose, and is included in the coating material composition for building finishing materials of the present invention to improve tensile strength and flexural toughness and improve brittleness. .
구체적으로, 본 발명의 셀룰로오즈(cellulose) 섬유는 목재로부터 추출되어진 천연 셀룰로오즈 섬유일 수 있으며, 1,500 ~ 2,500㎛의 길이, 바람직하게는 1,700 ~ 2,300㎛의 길이, 더욱 바람직하게는 1,900 ~ 2,100㎛의 길이를 가질 수 있다.Specifically, the cellulose fiber of the present invention may be a natural cellulose fiber extracted from wood, the length of 1,500 ~ 2,500㎛, preferably the length of 1,700 ~ 2,300㎛, more preferably the length of 1,900 ~ 2,100㎛ It can have
또한, 본 발명의 셀룰로오즈(cellulose) 섬유는 30 ~ 40㎛의 두께, 바람직하게는 32 ~ 38㎛의 두께, 더욱 바람직하게는 33 ~ 42㎛의 두께를 가질 수 있다.In addition, the cellulose fibers of the present invention may have a thickness of 30 to 40 μm, preferably 32 to 38 μm, more preferably 33 to 42 μm.
또한, 본 발명의 셀룰로오즈(cellulose) 섬유는 5 ~ 30g/l의 부피 밀도(bulk density), 바람직하게는 8 ~ 27g/l의 부피 밀도, 더욱 바람직하게는 10 ~ 25g/l의 부피 밀도를 가질 수 있다.In addition, the cellulose fibers of the present invention may have a bulk density of 5 to 30 g / l, preferably a bulk density of 8 to 27 g / l, more preferably a volume density of 10 to 25 g / l. Can be.
또한, 본 발명의 셀룰로오즈(cellulose) 섬유는 셀룰로오즈 함유량(cellulose content)이 90 중량% 이상, 바람직하게는 65 중량%, 더욱 바람직하게는 99 ~ 99.8 중량%일 수 있다.In addition, the cellulose fibers of the present invention may have a cellulose content of 90% by weight or more, preferably 65% by weight, more preferably 99-99.8% by weight.
또한, 본 발명의 셀룰로오즈(cellulose) 섬유는 pH 가 4.5 ~ 8.5, 바람직하게는 5.5 ~ 6.5일 수 있다.In addition, the cellulose fibers of the present invention may have a pH of 4.5 to 8.5, preferably 5.5 to 6.5.
또한, 본 발명의 셀룰로오즈(cellulose) 섬유는 아크릴 에멀젼 수지 100 중량부에 대하여 1.5 ~ 2.5 중량부, 바람직하게는 1.7 ~ 2.3 중량부, 더욱 바람직하게는 1.9 ~ 2.1 중량부를 포함할 수 있으며, 만일 셀룰로오즈 섬유가 1.5 중량부 미만으로 포함하면, 부착강도와 인장강도의 증진이 낮은 문제가 있을 수 있고, 2.55 중량부를 초과하게 된다면 부착강도와 인장강도 증진 효과가 저하되며, 가격상승의 문제가 있을 수 있다.In addition, the cellulose fibers of the present invention may comprise 1.5 to 2.5 parts by weight, preferably 1.7 to 2.3 parts by weight, more preferably 1.9 to 2.1 parts by weight, based on 100 parts by weight of the acrylic emulsion resin, If the fiber is less than 1.5 parts by weight, there may be a problem of low adhesion strength and enhancement of tensile strength, and if it exceeds 2.55 parts by weight, the effect of improving adhesion strength and tensile strength may be lowered, and there may be a problem of price increase. .
다음으로, 본 발명의 이산화타이타늄(TiO2)은 본 발명의 건축마감재용 바름재 조성물에 포함되어 열적 성능을 개선하는 역할을 한다.Next, titanium dioxide (TiO 2 ) of the present invention is included in the coating material composition for building finishing materials of the present invention serves to improve the thermal performance.
구체적으로, 본 발명의 이산화타이타늄은 아크릴 에멀젼 수지 100 중량부에 대하여 25 ~ 42 중량부, 바람직하게는 28 ~ 39 중량부, 더욱 바람직하게는 31 ~ 35 중량부를 포함할 수 있으며, 만일 이산화타이타늄이 25 중량부 미만으로 포함하면, 표면 온도의 저감효과가 낮아지는 문제가 있을 수 있고, 42 중량부를 초과하게 된다면 부착강도 및 인장강도 저하의 문제가 있을 수 있다.Specifically, the titanium dioxide of the present invention may include 25 to 42 parts by weight, preferably 28 to 39 parts by weight, more preferably 31 to 35 parts by weight, based on 100 parts by weight of the acrylic emulsion resin. If it contains less than 25 parts by weight, there may be a problem that the effect of reducing the surface temperature is lowered, if it exceeds 42 parts by weight may have a problem of lowering the adhesion strength and tensile strength.
마지막으로, 본 발명의 알루미노실리케이트(aluminosilicate)는 본 발명의 건축마감재용 바름재 조성물에 포함되어 열적 성능을 개선하는 역할을 한다.Finally, the aluminosilicate of the present invention is included in the coating material composition for the building finishing material of the present invention serves to improve the thermal performance.
구체적으로, 본 발명의 알루미노실리케이트는 알루미노실리케이트(aluminosilicate)를 주성분으로 포함하는 세라믹의 미세한 원형 중공체 분말(Ceramic Microscopic Hollow Spheres)일 수 있으며, 중공 구조에 의하여 현저히 우수한 열적 성능을 가질 수 있다.Specifically, the aluminosilicate of the present invention may be ceramic microscopic hollow spheres (Ceramic Microscopic Hollow Spheres) containing aluminosilicate (aluminosilicate) as a main component, it may have a remarkably excellent thermal performance by the hollow structure .
또한, 본 발명의 알루미노실리케이트는 20 ~ 110㎛의 입자크기, 바람직하게는 30 ~ 100㎛의 입자크기를 가질 수 있다.In addition, the aluminosilicate of the present invention may have a particle size of 20 ~ 110㎛, preferably a particle size of 30 ~ 100㎛.
또한, 본 발명의 알루미노실리케이트는 0.5 ~ 1.0 cm3의 비중, 바람직하게는 0.7 ~ 0.88cm3의 비중을 가질 수 있다.In addition, the aluminosilicate of the present invention may have a specific gravity of 0.5 to 1.0 cm 3, preferably a specific gravity of 0.7 ~ 0.88cm 3.
또한, 본 발명의 알루미노실리케이트는 1500 ~ 2100℃의 융점, 더욱 바람직하게는 1600 ~ 2000℃의 융점을 가질 수 있다.In addition, the aluminosilicate of the present invention may have a melting point of 1500 ~ 2100 ℃, more preferably 1600 ~ 2000 ℃ melting point.
또한, 본 발명의 알루미노실리케이트는 압축강도가 2500 ~ 3500 N/㎠, 바람직하게는 2800 ~ 3200 N/㎠일 수 있다.In addition, the aluminosilicate of the present invention may have a compressive strength of 2500 to 3500 N / cm 2, preferably 2800 to 3200 N / cm 2.
또한, 본 발명의 알루미노실리케이트는 아크릴 에멀젼 수지 100 중량부에 대하여 25 ~ 42 중량부, 바람직하게는 28 ~ 39 중량부, 더욱 바람직하게는 31 ~ 35 중량부를 포함할 수 있으며, 만일 알루미노실리케이트가 25 중량부 미만으로 포함하면, 열적성능이 저하되는 문제가 있을 수 있고, 42 중량부를 초과하게 된다면 경제성 저하 및 부착강도 저하의 문제가 있을 수 있다.In addition, the aluminosilicate of the present invention may comprise 25 to 42 parts by weight, preferably 28 to 39 parts by weight, more preferably 31 to 35 parts by weight based on 100 parts by weight of the acrylic emulsion resin, and if the aluminosilicate If it contains less than 25 parts by weight, there may be a problem that the thermal performance is lowered, and if it exceeds 42 parts by weight, there may be a problem of economical efficiency and adhesion strength degradation.
한편, 본 발명의 건축마감재용 바름재 조성물은 물을 더 포함할 수 있으며, 물은 아크릴 에멀젼 수지 100 중량부에 대하여 35 ~ 59 중량부, 바람직하게는 39 ~ 54 중량부, 더욱 바람직하게는 44 ~ 49 중량부를 포함할 수 있으며, 만일 물이 35 중량부 미만으로 포함하면, 작업성 저하의 문제가 있을 수 있고, 59 중량부를 초과하게 된다면 본 발명의 건축마감재용 바름재 조성물을 시공할 때, 흘러내림의 문제가 있을 수 있다.On the other hand, the coating material composition for building finishing materials of the present invention may further comprise water, water is 35 to 59 parts by weight, preferably 39 to 54 parts by weight, more preferably 44 to 100 parts by weight of the acrylic emulsion resin It may include ~ 49 parts by weight, if the water is included less than 35 parts by weight, there may be a problem of workability degradation, if it exceeds 59 parts by weight when constructing a coating material composition for building finishing materials of the present invention, There may be a problem of running down.
나아가, 본 발명의 건축마감재용 바름재는 앞서 설명한 건축마감재용 바름재 조성물을 포함한다.Furthermore, the coating material for building finishing materials of the present invention includes the coating material composition for building finishing materials described above.
구체적으로, 본 발명의 건축마감재용 바름재는 앞서 설명한 건축마감재용 바름재 조성물이 경화된 것일 수 있으며, 본 발명의 건축마감재용 바름재는 건축물의 내장 또는 외장 바름재로 사용가능하지만, 바람직하게는 건축물의 외장 바름재로서 사용하여 부착강도, 인장강도뿐만 아니라 우수한 차열성을 가질 수 있다.Specifically, the building material for the building finishing material of the present invention may be a curing material composition for the building material described above, the building material for the building material of the present invention can be used as interior or exterior coating material of the building, preferably building It can be used as exterior coating material of to have excellent heat shielding property as well as adhesion strength and tensile strength.
한편, 본 발명의 건축마감재용 바름재는 경화한 후 1 ~ 5mm의 두께, 바람직하게는 2 ~ 4mm의 두께, 더욱 바람직하게는 2.5 ~ 3.5mm의 두께를 가질 수 있으며, 이와 같이 얇은 두께를 가질 때에도, 부착강도, 인장강도뿐만 아니라 우수한 차열성을 가질 수 있다.On the other hand, the coating material for building finishing material of the present invention may have a thickness of 1 to 5mm, preferably 2 to 4mm, more preferably 2.5 to 3.5mm after curing, even when having a thin thickness It can have excellent heat shielding properties as well as adhesion strength and tensile strength.
구체적으로, 본 발명의 건축마감재용 바름재(재령 28일 기준)는 3mm의 두께를 가질 때, KS F 4715 규정에 의해 측정한 부착강도가 1.0 ~ 2.0 N/mm2, 바람직하게는 1.3 ~ 2.0 N/mm2, 더욱 바람직하게는 1.4 ~ 1.8 N/mm2 일 수 있다.Specifically, when the finishing material for building finishing material of the present invention (age 28 days) has a thickness of 3mm, the adhesive strength measured by the KS F 4715 regulation 1.0 ~ 2.0 N / mm 2 , preferably 1.3 ~ 2.0 N / mm 2 , more preferably 1.4-1.8 N / mm 2 .
또한, 본 발명의 건축마감재용 바름재(재령 28일 기준)는 3mm의 두께를 가질 때, KS M ISO 1798 규정에 의해 측정한 인장강도가 0.5 ~ 1.5 N/mm2, 바람직하게는 0.6 ~ 1.3 N/mm2, 더욱 바람직하게는 0.7 ~ 1.0 N/mm2 일 수 있다.In addition, when the finishing material for building finishing materials of the present invention (age 28 days) has a thickness of 3mm, the tensile strength measured according to the KS M ISO 1798 regulation 0.5 ~ 1.5 N / mm 2 , preferably 0.6 ~ 1.3 N / mm 2 , more preferably 0.7 to 1.0 N / mm 2 .
또한, 본 발명의 건축마감재용 바름재는 하기 실험방법 1에 의해 측정한 융빙율이 50% 이하, 바람직하게는 20 ~ 49%, 더욱 바람직하게는 40 ~ 48.5%일 수 있다.In addition, the coating material for the building finishing material of the present invention may have a melting rate of 50% or less, preferably 20 to 49%, more preferably 40 to 48.5%, measured by Experimental Method 1 below.
[실험방법 1]Experimental Method 1
스티로폼 구조체(Box) 내부에는 1리터의 얼음을 넣어 놓고, 스티로폼 구조체(Box) 외부 표면에는 건축마감재용 바름재 조성물을 도포한 뒤, 완전 경화시켜 두께 3mm로 건축마감재용 바름재를 형성한 후, 외기에 노출시킨 후부터 16,000초가 지난 후의 얼음의 융빙율을 측정한다.1 liter of ice is placed in the styrofoam structure (Box), and the coating material composition for building finish is applied to the outer surface of the styrofoam structure (Box), and then completely cured to form a coating material for building finish with a thickness of 3 mm. Measure the ice melt rate after 16,000 seconds after exposure to outside air.
이하, 실시예를 통하여 본 발명을 더욱 구체적으로 설명하기로 하지만, 하기 실시예가 본 발명의 범위를 제한하는 것은 아니며, 이는 본 발명의 이해를 돕기 위한 것으로 해석되어야 할 것이다.Hereinafter, the present invention will be described in more detail with reference to Examples, but the following Examples are not intended to limit the scope of the present invention, which will be construed as to help the understanding of the present invention.
[실시예] EXAMPLE
실시예 1 : 건축마감재용 바름재 조성물의 제조 Example 1 Preparation of a Coating Material Composition for Building Finishing Materials
(1) 아크릴 에멀젼 수지(칠성고분자 CS-200) 100 중량부에 대하여, 실란개질 아크릴 에멀젼 수지(아펙, AP6243) 20 중량부, 골재인 규사(평균 입경 : 0.4mm) 403.33 중량부, 셀룰로오즈 섬유(나이콘소재, FIF400) 2 중량부, 이산화타이타늄(이영세라켐) 33.33 중량부, 알루미노실리케이트 원형중공체(인슐래드아시아, 인슐래드) 33.33 중량부를 혼합한 후 1분 동안 62rpm으로 믹싱(mixing)하여, 혼합물을 제조하였다. (1) 20 parts by weight of a silane-modified acrylic emulsion resin (Apec, AP6243), aggregate silica sand (average particle diameter: 0.4mm) 403.33 parts by weight, cellulose fiber (100 parts by weight of acrylic emulsion resin (Chilsung polymer CS-200) 2 parts by weight of a Nikon material, FIF400), 33.33 parts by weight of titanium dioxide (Lee Young Cerachem), 33.33 parts by weight of an aluminosilicate circular hollow body (Insulin Asia, Insulin), and then mixed at 62 rpm for 1 minute, A mixture was prepared.
(2) 제조한 혼합물에 아크릴 에멀젼 수지 100 중량부에 대하여, 물 46.66 중량부를 투입한 후, 30초 동안 62rpm으로 저속 믹싱(mixing)한 후, 30초 동안 정지한다. 마지막으로, 다시 1분 동안 125rpm으로 고속 믹싱하여 건축마감재용 바름재 조성물을 제조하였다.(2) After adding 46.66 parts by weight of water to 100 parts by weight of the acrylic emulsion resin, the mixture was mixed at low speed of 62 rpm for 30 seconds and then stopped for 30 seconds. Finally, a high-speed mixing at 125rpm again for 1 minute to prepare a coating material composition for building finishing materials.
실시예 2 ~ 실시예 21Example 2-Example 21
실시예 1과 동일한 방법으로 건축마감재용 바름재 조성물을 제조하였다. 다만, 표 1 및 표 2에 기재된 바와 같이 성분들의 함량을 달리하여 실시예 2 ~ 실시예 21의 건축마감재용 바름재 조성물을 제조하였다.In the same manner as in Example 1 A coating material composition for building finishing materials was prepared. However, by varying the content of the components as described in Table 1 and Table 2 to prepare a coating material composition for building finishing materials of Examples 2 to 21.
비교예 1 Comparative Example 1
실시예 1과 동일한 방법으로 건축마감재용 바름재 조성물을 제조하였다. 다만, 표 2 에 기재된 바와 같이 실란개질 아크릴 에멀젼 수지를 사용하지 않고, 건축마감재용 바름재 조성물을 제조하였다.In the same manner as in Example 1 A coating material composition for building finishing materials was prepared. However, the coating material composition for building finishing materials was produced, without using a silane modified acrylic emulsion resin as described in Table 2.
비교예 2Comparative Example 2
실시예 1과 동일한 방법으로 건축마감재용 바름재 조성물을 제조하였다. 다만, 표 2 에 기재된 바와 같이 셀룰로오즈 섬유를 사용하지 않고, 건축마감재용 바름재 조성물을 제조하였다.In the same manner as in Example 1 A coating material composition for building finishing materials was prepared. However, the coating material composition for building finishing materials was manufactured, without using a cellulose fiber as shown in Table 2.
비교예 3 Comparative Example 3
실시예 1과 동일한 방법으로 건축마감재용 바름재 조성물을 제조하였다. 다만, 표 2 에 기재된 바와 같이 이산화타이타늄을 사용하지 않고, 건축마감재용 바름재 조성물을 제조하였다.In the same manner as in Example 1 A coating material composition for building finishing materials was prepared. However, the coating material composition for building finishing materials was manufactured, without using titanium dioxide as shown in Table 2.
비교예 4Comparative Example 4
실시예 1과 동일한 방법으로 건축마감재용 바름재 조성물을 제조하였다. 다만, 표 2 에 기재된 바와 같이 알루미노실리케이트 원형중공체를 사용하지 않고, 건축마감재용 바름재 조성물을 제조하였다.In the same manner as in Example 1 A coating material composition for building finishing materials was prepared. However, as shown in Table 2, without using an aluminosilicate circular hollow body, a coating material composition for building finishing materials was prepared.
실시예 22Example 22
실시예 1과 동일한 방법으로 건축마감재용 바름재 조성물을 제조하였다. 다만, 실시예 1과 달리 알루미노실리케이트 원형중공체가 아닌 알루미노실리케이트를 사용하여 건축마감재용 바름재 조성물을 제조하였다.In the same manner as in Example 1 A coating material composition for building finishing materials was prepared. However, unlike Example 1, aluminosilicate was used instead of the aluminosilicate circular hollow body to prepare a coating material composition for building finishing materials.
실험예 1 : 부착강도 측정(N/mmExperimental Example 1 Measurement of Bond Strength (N / mm 22 ))
가로 7cm X 세로 7cm X 높이 3cm의 콘크리트 판 표면에 실시예 1 ~ 22 및 비교예 1 ~ 4에서 제조한 건축마감재용 바름재 조성물을 각각 도포한 뒤 20℃의 온도에서 14일동안 완전 경화시켜 두께 3mm로 건축마감재용 바름재를 형성하였다.7 cm x 7 cm x 3 cm high concrete plate surface was applied to the coating material composition for building finishes prepared in Examples 1 to 22 and Comparative Examples 1 to 4, respectively, and completely cured for 14 days at a temperature of 20 ℃ thickness 3mm was used to form the finishing material for the building finish.
형성된 건축마감재용 바름제에 대해 KS F 4715 규정에 의해 부착강도를 측정하여 하기 표 3 및 표 4에 나타내었다.Bond strength was measured according to KS F 4715 for the formed finishes for the building finishes and is shown in Table 3 and Table 4 below.
실험예 2 : 인장강도 측정(N/mmExperimental Example 2 Tensile Strength Measurement (N / mm 22 ))
표면에 이형제가 도포된 인장강도 시험체에 실시예 1 ~ 22 및 비교예 1 ~ 4에서 제조한 건축마감재용 바름재 조성물을 각각 도포한 뒤 20℃의 온도에서 14일동안 완전 경화시켜 두께 3mm로 건축마감재용 바름재를 형성하였다. 형성된 건축마감재용 바름제에 대해 KS M ISO 1798 연질 발포 고분자재료- 인장강도 및 파단 신장률 측정 방법 규정에 의해 인장강도를 측정하여 하기 표 3 및 표 4에 나타내었다.After applying the coating material composition for building finishing materials prepared in Examples 1 to 22 and Comparative Examples 1 to 4 on the tensile strength test body coated with the release agent on the surface, and completely cured for 14 days at a temperature of 20 ℃ to build a thickness of 3mm A finish material for the finish was formed. Tensile strength was measured according to the KS M ISO 1798 soft foamed polymer material-tensile strength and elongation at break rate measurement method regulation for the formed building finishing agent is shown in Table 3 and Table 4.
실험예 3 : 열적 성능평가Experimental Example 3: Thermal Performance Evaluation
30cm(가로) X 30cm(세로) X 30cm(높이)를 가지는 스티로폼 구조체(Box)를 준비하였다. 준비한 스티로폼 구조체(Box) 내부에는 냉매로서 1리터의 얼음을 넣어 놓고, 스티로폼 구조체(Box) 외부 표면에는 실시예 1 ~ 22 및 비교예 1 ~ 4에서 제조한 건축마감재용 바름재 조성물을 각각 도포한 뒤 20±2℃의 온도에서 24시간동안 완전 경화시켜 두께 3mm로 건축마감재용 바름재를 형성하였다.A styrofoam structure (Box) having a width of 30 cm x 30 cm (height) x 30 cm (height) was prepared. 1 liter of ice was put as a refrigerant in the prepared styrofoam structure (Box), and the coating material composition for building finishing materials prepared in Examples 1 to 22 and Comparative Examples 1 to 4 was applied to the outer surface of the styrofoam structure (Box), respectively. After curing completely for 24 hours at a temperature of 20 ± 2 ℃ to form a coating material for building finishing material with a thickness of 3mm.
그 후, 외기에 노출시킨 후부터 16,000초 동안 스티로폼 구조체(Box) 내부의 최고 온도, 최저 온도, 스티로폼 구조체(Box) 외부의 최고 온도, 최저 온도를 측정하였으며, 외기에 노출시킨 후부터 16,000초가 지난 후의 얼음의 융빙율을 측정하여 하기 표 3 및 표 4에 나타내었다. After that, the highest temperature, the lowest temperature, the highest temperature and the lowest temperature outside the Styrofoam structure (Box) were measured for 16,000 seconds after exposure to the outside air, and the ice after 16,000 seconds after exposure to the outside air was measured. Melting rate of the was measured and shown in Table 3 and Table 4.
상기 표 3 및 표 4에 기재된 바와 같이, 실시예 1 ~ 3에서 제조된 건축마감재용 바름재 조성물은 부착강도 및 인장강도가 우수할 뿐만 아니라, 차열성이 우수하고 융빙율이 낮음을 확인할 수 있었다.As described in Tables 3 and 4, the coating material composition for building finishes prepared in Examples 1 to 3 was found to have excellent adhesion strength and tensile strength, as well as excellent heat shielding properties and low melting rate. .
또한, 실시예 4에서 제조된 건축마감재용 바름재 조성물은 실시예 1 ~ 3에서 제조된 건축마감재용 바름재 조성물과 비교하여, 차열성 및 융빙율은 유사하지만, 부착강도 및 인장강도가 저하됨을 확인할 수 있었다.In addition, the coating material composition for building finishing materials prepared in Example 4 Compared with the coating material composition for building finishes prepared in Examples 1 to 3, the heat shielding and melting rate is similar, but it was confirmed that the adhesion strength and tensile strength is reduced.
또한, 실시예 5에서 제조된 건축마감재용 바름재 조성물은 실시예 1 ~ 3에서 제조된 건축마감재용 바름재 조성물과 비교하여, 부착강도, 인장강도, 차열성 및 융빙율이 유사함을 확인할 수 있어, 실란개질 아크릴 에멀젼 수지를 실시예 1 ~ 3에서 제조된 건축마감재용 바름재 조성물보다 많이 포함하여도 물성 개선이 없음을 확인할 수 있었다.In addition, the coating material composition for building finishing materials prepared in Example 5 Compared with the coating material composition for building finishes prepared in Examples 1 to 3, it can be confirmed that the adhesion strength, tensile strength, heat shielding and melting rate are similar, silane-modified acrylic emulsion resin prepared in Examples 1 to 3 It could be confirmed that there is no improvement in physical properties even if it contains more than the coating material composition for the finished building material.
또한, 실시예 6에서 제조된 건축마감재용 바름재 조성물은 실시예 1에서 제조된 건축마감재용 바름재 조성물과 비교하여, 부착강도 및 인장강도가 저하됨을 확인할 수 있었으며, 실시예 8에서 제조된 건축마감재용 바름재 조성물은 실시예 1에서 제조된 건축마감재용 바름재 조성물과 비교하여, 부착강도 및 인장강도가 현저히 저하될 뿐만 아니라, 융빙율 또한 증가됨을 확인할 수 있었다.In addition, the coating material composition for building finishing materials prepared in Example 6 Compared with the coating material composition for building finish material prepared in Example 1, it was confirmed that the adhesion strength and tensile strength is reduced, the building material for building finish material prepared in Example 8 Compared with the coating material composition for building finishes prepared in Example 1, it was confirmed that not only the adhesion strength and tensile strength significantly decreased, but also the melting rate increased.
또한, 실시예 7에서 제조된 건축마감재용 바름재 조성물은 실시예 1에서 제조된 건축마감재용 바름재 조성물과 비교하여, 부착강도 및 인장강도가 저하되고, 융빙율이 상승함을 확인할 수 있었으며, 실시예 9에서 제조된 건축마감재용 바름재 조성물은 실시예 1에서 제조된 건축마감재용 바름재 조성물과 비교하여, 부착강도 및 인장강도가 현저히 저하될 뿐만 아니라, 융빙율 또한 현저히 증가됨을 확인할 수 있었다.In addition, the coating material composition for building finishing materials prepared in Example 7 Compared with the coating material composition for building finishing materials prepared in Example 1, it was confirmed that the adhesion strength and tensile strength is lowered, the melting rate is increased, the building material for building finishing materials prepared in Example 9 Compared with the coating material composition for building finishing materials prepared in Example 1, not only the adhesion strength and tensile strength was significantly lowered, but also the melting rate was significantly increased.
또한, 실시예 10에서 제조된 건축마감재용 바름재 조성물은 실시예 1에서 제조된 건축마감재용 바름재 조성물과 비교하여, 부착강도 및 인장강도가 저하됨을 확인할 수 있었으며, 실시예 12에서 제조된 건축마감재용 바름재 조성물은 실시예 1에서 제조된 건축마감재용 바름재 조성물과 비교하여, 부착강도 및 인장강도가 현저히 저하됨을 확인할 수 있었다.In addition, the coating material composition for building finishing materials prepared in Example 10 Compared with the coating material composition for building finishing materials prepared in Example 1, it was confirmed that the adhesion strength and tensile strength is reduced, the building material for building finishing materials prepared in Example 12 Compared with the coating material composition for building finishes prepared in Example 1, it was confirmed that the adhesive strength and tensile strength is significantly reduced.
또한, 실시예 11 및 13에서 제조된 건축마감재용 바름재 조성물은 실시예 1 에서 제조된 건축마감재용 바름재 조성물과 비교하여, 부착강도, 인장강도, 차열성 및 융빙율이 유사함을 확인할 수 있어, 셀룰로오즈 섬유를 실시예 1에서 제조된 건축마감재용 바름재 조성물보다 많이 포함하여도 물성 개선이 없음을 확인할 수 있었다.In addition, the coating material composition for building finishing materials prepared in Examples 11 and 13 Compared to the coating material composition for building finishing materials prepared in Example 1, it can be confirmed that the adhesion strength, tensile strength, heat shielding and melting rate is similar, the cellulose fiber is applied to the building material coating material for building finishing materials prepared in Example 1 Including more, it was confirmed that there is no improvement in physical properties.
또한, 실시예 14에서 제조된 건축마감재용 바름재 조성물은 실시예 1에서 제조된 건축마감재용 바름재 조성물과 비교하여, 차열성이 저하되고, 융빙율이 상승함을 확인할 수 있었으며, 실시예 16에서 제조된 건축마감재용 바름재 조성물은 실시예 1에서 제조된 건축마감재용 바름재 조성물과 비교하여, 차열성이 현저히 저하되고, 융빙율이 현저히 증가됨을 확인할 수 있었다.In addition, the coating material composition for building finishing materials prepared in Example 14 Compared with the coating material composition for building finishing materials prepared in Example 1, it was confirmed that the heat shielding property is lowered, the melting rate is increased, the building material for building finishing materials prepared in Example 16 Compared with the coating material composition for building finishes prepared in Example 1, it was confirmed that the heat shielding properties are significantly lowered, the melting rate is significantly increased.
또한, 실시예 15에서 제조된 건축마감재용 바름재 조성물은 실시예 1에서 제조된 건축마감재용 바름재 조성물과 비교하여, 부착강도 및 인장강도가 저하되고, 실시예 17에서 제조된 건축마감재용 바름재 조성물은 실시예 1에서 제조된 건축마감재용 바름재 조성물과 비교하여, 부착강도 및 인장강도가 현저히 저하됨을 확인할 수 있었다.In addition, the coating material composition for building finishing materials prepared in Example 15 Compared with the coating material composition for building finishing materials prepared in Example 1, the adhesive strength and tensile strength is lowered, and the coating material composition for building finishing materials prepared in Example 17 Compared with the coating material composition for building finishes prepared in Example 1, it was confirmed that the adhesive strength and tensile strength is significantly reduced.
또한, 실시예 18에서 제조된 건축마감재용 바름재 조성물은 실시예 1에서 제조된 건축마감재용 바름재 조성물과 비교하여, 부착강도, 인장강도 및 차열성이 저하되고, 융빙율이 상승함을 확인할 수 있었으며, 실시예 20에서 제조된 건축마감재용 바름재 조성물은 실시예 1에서 제조된 건축마감재용 바름재 조성물과 비교하여, 부착강도 및 인장강도가 저하되고, 차열성이 현저히 저하되며, 융빙율이 현저히 증가됨을 확인할 수 있었다.In addition, the coating material composition for building finishing materials prepared in Example 18 Compared with the coating material composition for building finishing materials prepared in Example 1, it was confirmed that the adhesion strength, tensile strength and heat shielding properties are lowered, the melting rate is increased, the building material for building finishing materials prepared in Example 20 silver Compared with the coating material composition for building finishes prepared in Example 1, it was confirmed that the adhesion strength and tensile strength is lowered, the heat shielding properties are significantly lowered, and the melting rate is significantly increased.
또한, 실시예 19에서 제조된 건축마감재용 바름재 조성물은 실시예 1에서 제조된 건축마감재용 바름재 조성물과 비교하여, 부착강도 및 인장강도가 저하되고, 실시예 21에서 제조된 건축마감재용 바름재 조성물은 실시예 1에서 제조된 건축마감재용 바름재 조성물과 비교하여, 부착강도 및 인장강도가 현저히 저하됨을 확인할 수 있었다.In addition, the coating material composition for building finishing materials prepared in Example 19 Compared with the coating material composition for building finishing materials prepared in Example 1, the adhesive strength and tensile strength is lowered, and the coating material composition for building finishing materials prepared in Example 21 Compared with the coating material composition for building finishes prepared in Example 1, it was confirmed that the adhesive strength and tensile strength is significantly reduced.
또한, 실시예 22에서 제조된 건축마감재용 바름재 조성물은 실시예 1에서 제조된 건축마감재용 바름재 조성물과 비교하여, 차열성이 현저히 저하되며, 융빙율이 현저히 증가됨을 확인할 수 있었다.In addition, the coating material composition for building finishing materials prepared in Example 22 Compared with the coating material composition for building finishes prepared in Example 1, it was confirmed that the thermal insulation is significantly lowered, the melting rate is significantly increased.
또한, 비교예 1 및 2에서 제조된 건축마감재용 바름재 조성물은 실시예 1에서 제조된 건축마감재용 바름재 조성물과 비교하여, 부착강도 및 인장강도가 현저히 저하됨을 확인할 수 있었다.In addition, the coating material composition for building finishing materials prepared in Comparative Examples 1 and 2 Compared with the coating material composition for building finishes prepared in Example 1, it was confirmed that the adhesive strength and tensile strength is significantly reduced.
또한, 비교예 3 및 4에서 제조된 건축마감재용 바름재 조성물은 실시예 1에서 제조된 건축마감재용 바름재 조성물과 비교하여, 부착강도 및 인장강도가 저하되고, 차열성이 현저히 저하되며, 융빙율이 현저히 증가됨을 확인할 수 있었다.In addition, the coating material composition for building finishing materials prepared in Comparative Examples 3 and 4 Compared with the coating material composition for building finishes prepared in Example 1, it was confirmed that the adhesion strength and tensile strength is lowered, the heat shielding properties are significantly lowered, and the melting rate is significantly increased.
본 발명의 단순한 변형이나 변경은 이 분야의 통상의 지식을 가진 자에 의해서 용이하게 실시될 수 있으며, 이러한 변형이나 변경은 모두 본 발명의 영역에 포함되는 것으로 볼 수 있다.Simple modifications or changes of the present invention can be easily carried out by those skilled in the art, and all such modifications or changes can be seen to be included in the scope of the present invention.
Claims (13)
With respect to 100 parts by weight of the acrylic emulsion resin, 17 to 23 parts by weight of silane-modified acrylic emulsion resin, 1.7 to 2.3 parts by weight of cellulose fiber, 342 to 464 parts by weight of aggregate, 28 to 39 parts by weight of titanium dioxide, and aluminosilicate circular hollow body 28 A coating material composition for building finishing materials comprising ~ 39 parts by weight.
상기 골재는 0.15 ~ 0.6mm인 규사를 포함하는 것을 특징으로 하는 건축마감재용 바름재 조성물.
The method of claim 1,
The aggregate is a finish material composition for building finishing materials, characterized in that it comprises a silica sand 0.15 ~ 0.6mm.
상기 실란개질 아크릴 에멀젼 수지는 고형분을 27 ~ 33중량%로 포함하고, pH 6 ~ 11이며, 점도는 200 cps(25℃) 이하이고, 유리전이온도(Tg)가 -20 ~ 20℃인 것을 특징으로 하는 건축마감재용 바름재 조성물.
The method of claim 1,
The silane-modified acrylic emulsion resin contains a solid content of 27 to 33% by weight, pH 6 ~ 11, the viscosity is 200 cps (25 ℃) or less, the glass transition temperature (Tg) is characterized in that -20 ~ 20 ℃ Coating material composition for building finishing materials.
상기 셀룰로오즈 섬유는 1,500 ~ 2,500㎛의 길이, 30 ~ 40㎛의 두께, 5 ~ 30g/l의 부피 밀도(bulk density)를 가지는 것을 특징으로 하는 건축마감재용 바름재 조성물.
The method of claim 1,
The cellulose fiber has a length of 1,500 ~ 2,500㎛, 30 ~ 40㎛ thickness, 5 ~ 30g / l coating material composition for a building finish, characterized in that having a bulk density (bulk density).
상기 알루미노실리케이트 원형 중공체는 20 ~ 110㎛의 입자크기, 0.5 ~ 1.0의 비중, 1500 ~ 2100℃의 융점을 가지는 것을 특징으로 하는 건축마감재용 바름재 조성물.
The method of claim 1,
The aluminosilicate circular hollow body has a particle size of 20 ~ 110㎛, specific gravity of 0.5 ~ 1.0, the melting point of the construction finish material, characterized in that it has a melting point of 1500 ~ 2100 ℃.
Claim 1, 4, 5, 6 and 8 of claim 1, comprising a coating material composition for building finishing materials according to any one of claims.
상기 건축마감재용 바름재는 건축물의 외장 바름재인 것을 특징으로 하는 건축마감재용 바름재.
The method of claim 9,
The building finish material for the building finish material, characterized in that the exterior finish material for the building.
상기 건축마감재용 바름재(재령 28일 기준)는 3mm의 두께를 가질 때, KS F 4715 규정에 의해 측정한 부착강도가 1.0 ~ 2.0 N/mm2인 것을 특징으로 하는 건축마감재용 바름재.
The method of claim 9,
The building material for finishing materials (based on age 28) has a thickness of 3mm, the coating material, characterized in that the adhesion strength measured by the KS F 4715 regulation 1.0 ~ 2.0 N / mm 2 , the building material.
상기 건축마감재용 바름재(재령 28일 기준)는 3mm의 두께를 가질 때, KS M ISO 1798 규정에 의해 측정한 인장강도가 0.5 ~ 1.5 N/mm2인 것을 특징으로 하는 건축마감재용 바름재.
The method of claim 9,
The building material for finishing materials (based on age 28) has a thickness of 3mm, the building material finishing material, characterized in that the tensile strength of 0.5 ~ 1.5 N / mm 2 measured by KS M ISO 1798.
상기 건축마감재용 바름재는 하기 실험방법 1에 의해 측정한 융빙율이 50% 이하인 것을 특징으로 하는 건축마감재용 바름재.
[실험방법 1]
스티로폼 구조체(Box) 내부에는 1리터의 얼음을 넣어 놓고, 스티로폼 구조체(Box) 외부 표면에는 건축마감재용 바름재 조성물을 도포한 뒤, 완전 경화시켜 두께 3mm로 건축마감재용 바름재를 형성한 후, 외기에 노출시킨 후부터 16,000초가 지난 후의 얼음의 융빙율을 측정한다.
The method of claim 9,
The building finish material for the building finish material, characterized in that the melting rate measured by the test method 1 below 50% or less.
Experimental Method 1
1 liter of ice is placed in the styrofoam structure (Box), and the coating material composition for building finish is applied to the outer surface of the styrofoam structure (Box), and then completely cured to form a coating material for building finish with a thickness of 3 mm. Measure the ice melt rate after 16,000 seconds after exposure to outside air.
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