KR101986945B1

KR101986945B1 - Integrated 3-layered Sheet Film for Printed Circuit Board and the method for Manufacturing thereof

Info

Publication number: KR101986945B1
Application number: KR1020180071336A
Authority: KR
Inventors: 이숙자
Original assignee: 이숙자
Priority date: 2018-06-21
Filing date: 2018-06-21
Publication date: 2019-06-07

Abstract

The present invention relates to a multi-layer film for a printed circuit board and a production method thereof. The multi-layer film for a printed circuit board has excellent heat resistance, followability and releasability and also reduces contamination because of not containing environmentally harmful substances. In addition, since the cushion degree thereof is excellent, a slip phenomenon of a substrate convex portion (reinforcing plate) can be prevented and a problem that contamination possibly occurs on the substrate can be solved. The multi-layer film is produced by a single step in a production process so that the cost can be reduced.

Description

TECHNICAL FIELD [0001] The present invention relates to an integrated multi-layer sheet film having a three-layer structure for a printed circuit board and a method for manufacturing the same.

The present invention relates to a multilayer sheet film for use in a printed circuit board. The multilayer sheet film is excellent in heat resistance, followability and releasability, and is excellent in heat resistance, Characterized in that a manufacturing method of forming a multilayer sheet structure by using an environmentally friendly resin and forming the multilayer sheet structure by a single process is applied.

Generally, printed circuit boards (PCBs) are widely used in various electronic products such as computers, mobile phones, displays, communication networks, and semiconductor modules as well as TVs. As a kind of such a PCB, a flexible printed circuit board (FPCB) having particularly excellent flexibility has recently been extensively used.

During the manufacturing process of the FPCB, there is a hot press process in which an insulating film (Cover-Layer) of a polyimide material is thermally bonded to a base film. The hot press process is a process of stacking the cover layer on the base film by placing a cover layer on the upper part of the body of the FPCB, that is, the base film on which the conductive layer is formed, pressing the cover layer with the press part, The environmentally harmful substances contained in the cushion film (mainly polyvinyl chloride, PVC) are vaporized by the high temperature and the high pressure during the hot pressing process, so that the substrate is contaminated while the release film is permeated, and the air is also contaminated. In addition, in addition to using polyvinyl chloride as a cushion film in the process of manufacturing the printed circuit board, lead, cadmium, mercury, and chromium are used for improving thermal stability and cushioning property. It is regulated.

As a result, the plating process and the environmentally harmful substances remain on the surface of the substrate at the time of the post-process (gold plating, etc.).

In order to solve the above problems, many companies have tried to replace the cushion film (polyvinyl chloride, PVC) by using an environmentally friendly resin such as polypropylene (PP) resin. However, The resin is twisted together with the substrate after most of the thermocompression, or a polypropylene resin or the like which forms the cushion layer (core layer) flows down. As a result, errors are generated in the PCB.

Precedent literature

- Patent literature

(Patent Document 1) Korean Patent Publication No. KR-10-0806763

(Patent Document 2) Korean Patent Publication No. KR-10-0713988

The above-referenced references referred to in this application are not permissible to be related prior art to this application.

It is an object of the present invention to provide an integral multi-layer sheet film for a printed circuit board capable of minimizing environmental pollutants generated during the manufacturing process, which is a problem of a multilayer sheet film for a conventional printed circuit board.

The integral multi-layer sheet film provided in the present invention is superior in heat resistance, followability, releasability, and the like, compared with the conventional multilayer sheet film, while using an eco-friendly resin such as polypropylene resin or the like without using a polyvinyl chloride resin in the cushion layer Have the same or better physical properties.

It is still another object of the present invention to provide a method for producing an integral multi-layer sheet film for a printed circuit board.

In order to achieve the object of the present invention in order to minimize the environmental pollutants generated in the conventional multilayer sheet film, the inventor of the present invention has found that the cushion layer of the conventional film can be made environmentally friendly By using a resin, the object of the present invention can be achieved.

The integral multi-layer sheet film for a printed circuit board provided in the present invention is formed into a structure similar to the various embodiments described below.

One embodiment of the present invention is a semiconductor device comprising: a core layer; A first resin layer on the core layer; And a second resin layer under the core layer, wherein the first resin layer and the second resin layer are a resin in which a polypropylene (PP) resin and a polydimethylsiloxane (PDMS) resin are mixed, Is a eco-friendly resin for a printed circuit board.

In the multilayer sheet film for a printed circuit board of the present invention, paper may be attached to the lower part of the second resin layer using an adhesive. In this case, it is used to remove the paper when it is attached to the printed circuit board, and the paper can be made of kraft paper or canvas paper.

The multilayer sheet film for a printed circuit board of the present invention can prevent contamination of the substrate by the cover film adhesive component during molding by using a resin having a low softening temperature on both the inner and outer sides of the multilayered sheet film for the first resin layer and the second resin layer, The eco-friendly resin used for the core layer may be a polypropylene terpolymer (TER-PP), a high density polyethylene (HDPE), a low density polyethylene (LDPE), a polyethylene terephthalate (PET) Polybutylene terephthalate (PBT), polyethylene, and ethylene propylene diene monomer (EPDM). The terpolymer polypropylene (TER-PP) of the polypropylene is prepared by mixing propylene monomer and two monomers selected from ethylene, butene, hexene and octene.

By using the eco-friendly resin as described above without using the conventional polyvinyl chloride resin as described above, the multilayer sheet film provided by the present invention is excellent in the production process of high temperature, high pressure, etc. and the chlorine It is possible to minimize the generation of environmental pollutants such as gas and prevent the phenomenon that the resin layer, which may occur during the thermocompression bonding, melts down, thereby preventing contamination of the secondary substrate.

Further, the first and second resin layers of the present invention are characterized in that heat resistance and releasability are improved by using a resin made of a polypropylene resin and a polydimethylsiloxane (PDMS) resin.

The polydimethylsiloxane (PDMS) resin may contain more than 0 to 30 parts by weight, preferably 0.2 to 20 parts by weight, more preferably 0.2 to 5 parts by weight, based on 100 parts by weight of the polypropylene resin do. When the content of the polydimethylsilic acid resin exceeds 30 parts by weight, the following property and releasability of the multilayer sheet film may be significantly deteriorated.

In addition, only the polypropylene resin can be used without using the polydimethylsiloxane resin, and the film produced in this case also exhibits the same properties as the above-mentioned film.

In one example of the present invention, the thicknesses of the first resin layer and the second resin layer may be 10 to 70 mu m, preferably 20 to 60 mu m, or 30 to 50 mu m, more preferably 35 to 45 mu m . By adjusting the thicknesses of the first resin layer and the second resin layer in the above range, the heat resistance and releasability can be improved. For example, when the thicknesses of the first resin layer and the second resin layer are less than 10 m, the resin layer is melted by heat and is fused to the substrate to cause a tearing phenomenon, so that the heat resistance and releasability of the multi- . If the thickness of the first resin layer and the second resin layer exceeds 70 m, the cushioning property may be deteriorated as the hardness of the resin layer increases. In addition, when the thickness of the first resin layer and the second resin layer exceeds 70 m, The followability may deteriorate, and the leakage of the adhesive may occur, which may cause contamination of the printed circuit board.

In one example of the present invention, the thickness of the core layer may be 50 to 400 占 퐉, preferably 120 to 300 占 퐉 or 130 to 280 占 퐉, more preferably 150 to 250 占 퐉. By controlling the thickness of the core layer in the above-described range, it is possible to improve the followability of the bent portion of the multilayer release film to the substrate.

For example, when the thickness of the core layer is less than 50 탆, the strength of the film may be lowered and the substrate swelling phenomenon and heat resistance may be lowered. If the thickness of the core layer exceeds 400 탆, the printed circuit board may be contaminated due to a large amount of adhesive in the substrate due to a decrease in elasticity and followability of the cushion.

The multilayer sheet film for a printed substrate provided in the present invention has a multilayer structure, but may be integrally formed through a single process by applying a T-die method or a co-extrusion method.

In one embodiment of the present invention, in the method of producing an integral multi-layer sheet film for use in a printed circuit board of the present invention,

Extrusion coating the first resin layer, the core layer and the second resin layer at once using a T-die method;

And simultaneously cooling and coiling the coated film.

In another embodiment of the present invention, the method of manufacturing an integral multi-layer sheet film for use in a printed circuit board of the present invention can employ a co-extrusion method instead of the above-mentioned T-die method.

The line speed of the step of winding and coiling the coated film may be 10 to 200 m / min, preferably 50 to 150 m / min, more preferably 120 to 130 m / min. When the winding speed is less than 10 m / min, the heat resistance and releasability of the multilayered sheet film deteriorate because the speed is too slow. If the winding speed is more than 200 m / min, the speed may become too fast and the followability may be deteriorated.

Also, the cooling step may use cooling water, and the temperature of the cooling water may be 4 to 50 캜. The gloss of the multilayer sheet film can be improved by keeping the cooling water within the above range.

Wherein the first resin layer and the second resin layer are a resin made by mixing a polypropylene (PP) resin and a polydimethylsiloxane (PDMS) resin, wherein the core layer is an eco-friendly resin, Same as.

The T-die method used in the present invention is a method in which a resin such as polypropylene resin or TER-PP, which is applied to the first resin layer, the core layer and the second resin layer, is vacuum-dried and melted by an extruder, Means a method of extruding and coating into a sheet by a single process.

The co-extrusion method used in the present invention is a method in which the resin is melted and then extruded simultaneously using two or more extruders to laminate a plurality of layers by a single process, A multilayer sheet film can be produced.

In one example, according to the method for producing an integral multi-layer sheet for use in the printed circuit board of the present invention, the first resin layer, the core layer, and the second resin layer are formed by a conventional three layer T- Can be prepared.

The integral multi-layer sheet film for a printed circuit board is excellent in heat resistance, followability and releasability. Particularly, since the core layer is not stretched, It is possible to solve the problem that the abrasion of the part (reinforcing plate) and the contamination of the copper part of the substrate can be solved, and it is not necessary to use multiple release films over the film during the operation, The multilayer film for a printed circuit board can be economically provided.

In addition, since the integral multi-layer sheet film is produced by using an eco-friendly material, there is no problem of environmental pollution and there is an advantage that it can be recycled.

1 is a cross-sectional view of an integral multi-layer film produced according to one embodiment of the present invention.
2 is a cross-sectional view of a film produced by attaching a paper to the bottom of a multilayer film produced according to one embodiment of the present invention.

Hereinafter, the present invention will be described in more detail with reference to the following examples. However, the scope of the present invention is not limited by the following examples. The embodiments of the present invention are provided to enable those skilled in the art to more fully understand the present invention.

Example 1

First resin layer and second resin layer: Prepared by mixing polypropylene resin (PP) and polydimethylsiloxane (PDMS) resin and having a thickness of 40 占 퐉.

Core layer: Prepared by mixing 50% homopolypropylene (HPP) and 50% TER-PP on a weight basis and having a thickness of 180 탆.

5 g of a polydimethylsiloxane resin was mixed with 100 g of a polypropylene resin (PP), and the resulting mixture was put into an extruder and subjected to melt reaction at a reaction temperature of 240 캜 to obtain a polypropylene-polydimethylsiloxane copolymer (PP-PDMS) pellet.

Homopolypropylene (HPP) and TER-PP were mixed as a core layer at a weight ratio of 50:50 to prepare a core layer having a thickness of 180 탆.

The resulting PP-PDMS was used as a skin resin, HPP as an intermediate layer resin, raw materials for each layer were put in separate hoppers, and a film having a thickness of 40 탆 was produced by extrusion processing. The obtained film was used as a release film for the first resin layer and the second resin layer.

The first resin layer, the core layer, and the second resin layer were integrally formed into a three-layered multilayer sheet by a T-die method.

At this time, the temperature of each extruder was set at 180 ° C to 280 ° C, the temperature of the feed block was set at 270 ° C, and the Ti die temperature was set at 255 ° C at the edge and 275 ° C at the center for thickness adjustment.

Example 2

Core layer: It is made by mixing 30% by weight of polybutylene terephthalate (PBT), 50% of polypropylene and 20% of low density polyethylene (LDPE) and having a thickness of 200 μm.

In the same manner as in Example 1 except that the core layer in Example 1 was changed to 30% of polybutylene terephthalate, 50% of polypropylene, 20% of low density polyethylene, and a thickness of 200 탆, the integral multi- . Table 1 shows the results of evaluating resin flow, followability, occurrence of copper foil (occurrence of separation of cover film and copper foil during chip mounting operation) and releasability of the monolithic multilayer film produced by the above manufacturing method.

Example 3

First resin layer and second resin layer: A polypropylene resin (PP) and a polydimethylsiloxane (PDMS) resin were mixed and made into a thickness of 40 占 퐉.

Core layer: Prepared by mixing 40% by weight of homopolyethylene, 30% by weight of ethylene propylene diene monomer (EPDM) and 20% by weight of low density polyethylene, and having a thickness of 180 占 퐉.

An integral multi-layer film was prepared in the same manner as in Example 1, except that the core layer was changed to 40% by weight of homopolyethylene, 30% of ethylene propylene diene monomer (EPDM) and 20% of low density polyethylene . Table 1 shows the results of evaluating resin flow, followability, occurrence of copper foil (occurrence of separation of cover film and copper foil during chip mounting operation) and releasability of the monolithic multilayer film produced by the above manufacturing method.

Example 4

Core layer: manufactured by mixing 40% by weight of homopolypropylene, 50% of polypropylene terpolymer (TER-PP) and 10% of low density polyethylene and having a thickness of 180 占 퐉.

An integral multi-layer film was prepared in the same manner as in Example 1, except that the core layer was changed to homopolypropylene 40, 50% polypropylene terpolymer (TER-PP) and 10% low density polyethylene on a weight basis. Table 1 shows the results of evaluating resin flow, followability, occurrence of copper foil (occurrence of separation of cover film and copper foil during chip mounting operation) and releasability of the monolithic multilayer film produced by the above manufacturing method.

Example 5

Core layer: Prepared by mixing 30% homopolypropylene, 50% TER-PP and 20% low density polyethylene on a weight basis and having a thickness of 180 탆.

An integral multi-layer film was prepared in the same manner as in Example 1, except that the core layer was changed to 30% homopolypropylene, 50% TER-PP and 20% low-density polyethylene on a weight basis. Table 1 shows the results of evaluating resin flow, followability, occurrence of copper foil (occurrence of separation of cover film and copper foil during chip mounting operation) and releasability of the monolithic multilayer film produced by the above manufacturing method.

Example 6

Core layer: made of 100% TER-PP and having a thickness of 180 탆.

An integral multi-layer film was prepared in the same manner as in Example 1 except that the core layer was changed to TER-PP. Table 1 shows the results of evaluating resin flow, followability, occurrence of copper foil (occurrence of separation of cover film and copper foil during chip mounting operation) and releasability of the monolithic multilayer film produced by the above manufacturing method.

Example 7

First resin layer and second resin layer: made of polypropylene resin (PP) and having a thickness of 40 占 퐉.

Core layer: Prepared by mixing 60% of TER-PP and 40% of low density polyethylene on a weight basis and having a thickness of 180 탆.

An integral multi-layer film was prepared in the same manner as in Example 1, except that the core layer was changed to 60% TER-PP and 40% low-density polyethylene on the basis of weight. Table 1 shows the results of evaluating resin flow, followability, occurrence of copper foil (occurrence of separation of cover film and copper foil during chip mounting operation) and releasability of the monolithic multilayer film produced by the above manufacturing method.

Example 8

First resin layer and second resin layer: made of polybutylene terephthalate resin and having a thickness of 40 占 퐉.

Core layer: manufactured by mixing 50% by weight of polybutylene terephthalate, 25% by weight of low-density polyethylene and 25% by weight of linear low-density polyethylene (LLDPE) and having a thickness of 200 탆.

The first resin layer and the second resin layer were made of polybutylene terephthalate and the core layer was composed of 50% by weight of polybutylene terephthalate, 25% of low density polyethylene and linear low-density polyethylene (LLDPE) 25%, and a thickness of 200 [micro] m, the same procedure as in Example 1 was carried out to produce an integral multi-layer film. Table 1 shows the results of evaluating resin flow, followability, occurrence of copper foil (occurrence of separation of cover film and copper foil during chip mounting operation) and releasability of the monolithic multilayer film produced by the above manufacturing method.

The followability of the multi-layer film produced according to the above examples, the occurrence of the occurrence of the copper foil contamination and the releasability thereof are shown in Table 1, and the physical properties of the films in Examples and Comparative Examples were measured in the following manner.

One. Resin flow

Hot press process conditions were measured at 150 to 160 캜 at 30 to 50 kgf / cm 2 for 1 hour. The initial area of the specimen was calculated as the ratio of the area of the raw material of the core layer flowing after the hot pressing operation. The higher the flowability value, the lower the heat resistance of the core layer raw material and the adhesion between the release films in the FPCB process is increased, thereby increasing the defect rate. The flowability of the integral multi-layer sheet film was evaluated in four steps.

◯ 0 (excellent), ◯ 1 to 2 (good), △ 3 to 5 (normal), X 6 or more (poor)

2. Follow-up

The FPCB substrate was manufactured and hot-pressed for 1 hour at 150 to 160 ° C at 30 to 50 kgf / cm 2 to measure the flow rate of the epoxy adhesive in the substrate outer layer cover film. The thickness of the epoxy adhesive in the outer layer cover film Observation and followability of the substrate were evaluated in four steps.

80 占 퐉 or less (good), 80 to 120 占 퐉 (good), 120 to 150 占 퐉 (normal), 150 占 퐉 or more (poor)

3. Copper contamination Occurrence

After the release work, the release film was removed, and the frequency (number / m ² ) of occurrence of contamination occurred due to the transfer of the polyimide cover layer film adhesive from the release film was visually observed to evaluate the stain resistance of the transfer in four stages.

◯ 0 (excellent), ◯ 1 to 2 (good), △ 3 to 5 (normal), X 6 or more (poor)

4. Dissimilarity

When the release film was removed after the press work, the degree of breakage of the release film was observed, and compared with the standard sample, it was evaluated as 4 grade.

◎ Excellent compared to standard sample, ○ Similar to standard sample, △ Slightly insufficient compared to standard sample, Bad relative to X standard sample

division Film Composition / Thickness (占 퐉) Property evaluation The first resin layer The second resin layer Core layer Resin flow Follow-up Copper pollution Dysplasia Example 1 (PP + pdms) / 40 (PP + pdms) / 40 (HPP 50% + ERPP 50%) / 180 ◎ ○ ○? ○? Example 2 (PP + pdms) / 40 (PP + pdms) / 40 (PBT 30% + PP50% + LD20%) / 200 ○ ○? ○? △ Example 3 (PP + pdms) / 40 (PP + pdms) / 40 (HPP 40% + EPDM 30% + LDPE 20%) / 180 ○ △ △ △ Example 4 (PP + pdms) / 40 (PP + pdms) / 40 (HPP 40% + TER PP 50% + LDPE 10%) / 180 ○ △ ○ ○? Example 5 (PP + pdms) / 40 (PP + pdms) / 40 (HPP 30% + TER PP 50% + LDPE 20%) / 180 △ ○ ○? △ Example 6 (PP + pdms) / 40 (PP + pdms) / 40 Ter pp / 180 ○ ○? ○? ○? Example 7 (PP) / 40 (PP) / 40 (TER PP 60% + LDPE 40%) / 180 ○ ◎ ○ △ Example 8 PBT / 40 PBT / 40 (PBT 50% + DPE 25% + LDPE 25%) / 200 ○ △ ○ △

From the above results, it can be concluded that the embodiment of the present invention, in which a multilayer sheet film for a printed circuit board was produced using only eco-friendly water without using polyvinyl chloride resin, heavy metal element or the like used in a multilayer sheet film for a conventional printed circuit board, It is understood that the multilayer sheet film produced by the prior art exhibits similar or superior followability, releasability and copper foil contamination.

In particular, the multilayer sheet film provided in the present invention can be manufactured in a single step by melting the environmentally-friendly resin constituting each layer and applying a Ti die or a co-extrusion method, thereby reducing the manufacturing cost and reducing the manufacturing costs of harmful gases such as chlorine, Lead, mercury, and other heavy metals, it is possible to remarkably reduce environmental pollution as compared with the prior art.

Accordingly, when the multilayered film for a printed circuit board is manufactured according to the manufacturing method of the present invention, it is possible to manufacture an integral multi-layered film for a printed circuit board having excellent physical properties such as trackability and releasability while reducing environmental pollution.

10: The multilayer sheet film provided by the present invention
11: First resin layer
12: core layer
13: second resin layer
14: Paper layer

Claims

1. A film made of an integral multi-layer sheet for use in a printed circuit board (PCB), said multi-layer sheet comprising: a core layer;
A first resin layer on the core layer; And
And a second resin layer under the core layer,
Wherein the first resin layer and the second resin layer are formed by mixing 0.2 to 5 parts by weight of a polydimethylsiloxane (PDMS) resin with respect to 100 parts by weight of a polypropylene (PP) resin,
Wherein the core layer is manufactured by selecting at least one member selected from the group consisting of a polypropylene terpolymer (TER-PP, terpolymer polypropylene), polybutylene terephthalate (PBT), ethylene propylene diene monomer (EPDM)
Wherein the thickness of the first resin layer and the second resin layer is 35 to 45 占 퐉 and the thickness of the core layer is 150 to 250 占 퐉.

delete

A method of manufacturing an integral multi-layer sheet film for use in a printed circuit board,
Extrusion coating the first resin layer, the core layer and the second resin layer at once using a T-die method;
And simultaneously cooling and coiling the coated film,
Wherein the first resin layer and the second resin layer are formed by mixing 0.2 to 5 parts by weight of a polydimethylsiloxane (PDMS) resin with respect to 100 parts by weight of a polypropylene (PP) resin,
Wherein the core layer is made of at least one selected from the group consisting of a polypropylene terpolymer (TER-PP, Terpolymer Polypropylene), polybutylene terephthalate (PBT) and ethylene propylene diene monomer (EPDM)
Wherein the line speed of the step of winding and simultaneously cooling the coated film is 10 to 200 m / min and the cooling temperature is 4 to 50 ° C.

delete

A method of manufacturing an integral multi-layer sheet film for use in a printed circuit board,
Extrusion coating the first resin layer, the core layer and the second resin layer at once using a co-extrusion method;
And simultaneously cooling and coiling the coated film,
Wherein the first resin layer and the second resin layer are formed by mixing 0.2 to 5 parts by weight of a polydimethylsiloxane (PDMS) resin with respect to 100 parts by weight of a polypropylene (PP) resin,
Wherein the core layer is made of at least one selected from the group consisting of a polypropylene terpolymer (TER-PP, Terpolymer Polypropylene), polybutylene terephthalate (PBT) and ethylene propylene diene monomer (EPDM)
Wherein the line speed of the step of winding and simultaneously cooling the coated film is 10 to 200 m / min and the cooling temperature is 4 to 50 ° C.

delete

1. A film made of an integral multi-layer sheet for use in a printed circuit board (PCB), said multi-layer sheet comprising: a core layer;
A first resin layer on the core layer; And
A second resin layer under the core layer; And
And a paper sheet attached to the lower portion of the second resin layer using an adhesive,
Wherein the first resin layer and the second resin layer are formed by mixing 0.2 to 5 parts by weight of a polydimethylsiloxane (PDMS) resin with respect to 100 parts by weight of a polypropylene (PP) resin,
Wherein the core layer is made of at least one selected from the group consisting of a polypropylene terpolymer (TER-PP, Terpolymer Polypropylene), polybutylene terephthalate (PBT) and ethylene propylene diene monomer (EPDM)
The thickness of the first resin layer and the second resin layer is 35 to 45 mu m, and the thickness of the core layer is 150 to 250 mu m,
Characterized in that said paper is selected from canvas paper or kraft paper.