KR101962249B1 - Eco-friendly sulfate-resisting mortar composition for repairing the surface of concrete structures and construction method using the same - Google Patents

Eco-friendly sulfate-resisting mortar composition for repairing the surface of concrete structures and construction method using the same Download PDF

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KR101962249B1
KR101962249B1 KR1020180130496A KR20180130496A KR101962249B1 KR 101962249 B1 KR101962249 B1 KR 101962249B1 KR 1020180130496 A KR1020180130496 A KR 1020180130496A KR 20180130496 A KR20180130496 A KR 20180130496A KR 101962249 B1 KR101962249 B1 KR 101962249B1
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vermiculite
powder
weight
nickel slag
fiber sheet
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KR1020180130496A
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Korean (ko)
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이재화
김경래
곽은구
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주식회사 한강이앤씨
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02Agglomerated materials, e.g. artificial aggregates
    • C04B18/027Lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/14Waste materials; Refuse from metallurgical processes
    • C04B18/141Slags
    • C04B18/144Slags from the production of specific metals other than iron or of specific alloys, e.g. ferrochrome slags
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/16Waste materials; Refuse from building or ceramic industry
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/16Waste materials; Refuse from building or ceramic industry
    • C04B18/165Ceramic waste
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/0076Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials characterised by the grain distribution
    • C04B20/008Micro- or nanosized fillers, e.g. micronised fillers with particle size smaller than that of the hydraulic binder
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04GSCAFFOLDING; FORMS; SHUTTERING; BUILDING IMPLEMENTS OR AIDS, OR THEIR USE; HANDLING BUILDING MATERIALS ON THE SITE; REPAIRING, BREAKING-UP OR OTHER WORK ON EXISTING BUILDINGS
    • E04G23/00Working measures on existing buildings
    • E04G23/02Repairing, e.g. filling cracks; Restoring; Altering; Enlarging
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2015Sulfate resistance
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/72Repairing or restoring existing buildings or building materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The present invention relates to an eco-friendly sulfate-resisting mortar composition using industrial byproducts and a construction method of restoring a concrete cross section using the same. More specifically, the composition comprises: vermiculite and silicate soda waste powder made by grinding vermiculite board scraps generated during processes of cutting and processing a vermiculite board manufactured by mixing and pressing vermiculite, which is light aggregate, and liquified sodium silicate (Na_2O· SiO_2·H_2O) which is a mineral material; nickel slag powder made by grinding nickel slag generated during a nickel smelting process; and waste glass powder made by grinding a glass fiber sheet generated during a cutting process among processes for manufacturing the glass fiber sheet.

Description

산업부산물을 활용한 친환경 내황산염 모르타르 조성물 및 이를 이용한 콘크리트 단면복구시공공법{Eco-friendly sulfate-resisting mortar composition for repairing the surface of concrete structures and construction method using the same}BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an eco-friendly sulphate mortar composition utilizing an industrial by-product, and a method for recovering a concrete using the eutectic sulphate mortar composition.

본 발명은 산업부산물을 활용한 친환경 내황산염 모르타르 조성물 및 이를 이용한 콘크리트 단면복구시공공법에 관한 것으로, 보다 상세하게는 경량골재인 질석과 무기질 재료인 액상규산나트륨(Na2O·nSiO2·xH2O)를 혼합, 가압하여 제조된 질석보드를 절단 및 가공하는 공정에서 발생되는 질석보드스크랩을 분쇄한 질석 및 규산소다 함유 폐분말과, 니켈 제련과정에서 발생하는 니켈슬래그를 분쇄한 니켈슬래그분말과, 유리섬유시트 제조공정중 절단공정에서 발생하는 유리섬유시트를 분쇄한 폐유리분말을 포함하여 조성되는 산업부산물을 활용한 친환경 내황산염 모르타르 조성물 및 이를 이용한 콘크리트 단면복구시공공법에 관한 것이다.The present invention relates to a concrete section Recovery construction method by Eco sulfate mortar composition and using the same advantage of the industrial by-products, more particularly to a lightweight aggregate in the liquid sodium silicate is vermiculite and the inorganic material (Na 2 O · nSiO 2 · xH 2 O), a powder of vermiculite and sodium silicate containing pulverized vermiculite board scrap generated in the process of cutting and processing the vermiculite board produced by pressurization, nickel slag powder obtained by crushing nickel slag generated in the nickel smelting process, And a waste glass powder obtained by pulverizing a glass fiber sheet produced in a cutting process during a glass fiber sheet manufacturing process, and to a method of recovering and rehabilitating a concrete section using the waste by-product.

철근 콘크리트 구조물은 화학적 부식환경, 염해 및 중성화, 수분침투 등에 의해 내부의 철근이 부식하게 되고, 철근의 부식은 철근의 팽창으로 이어져 결국 콘크리트구조물이 열화되면서 장기적으로 내구성 및 사용성 저하를 초래한다.Reinforced concrete structures are subject to chemical corrosion, corrosion and neutralization, water penetration, and corrosion of reinforcing bars leads to expansion of reinforcing bars, resulting in deterioration of concrete structures, resulting in long-term durability and poor usability.

이러한 구조물의 열화는 계속 진행되면 결국 구조물의 붕괴를 초래할 위험성이 있기 때문에 콘크리트 구조물의 내구성 증진을 위해 지속적으로 단면복구나 표면보호와 같은 보수공법들이 사용되고 있다.As the deterioration of these structures continues, there is a danger of causing the collapse of the structure. Therefore, maintenance methods such as section repair and surface protection are continuously used to improve the durability of the concrete structure.

즉, 콘크리트 구조물 표면의 박리 또는 초기 결함이 있거나 균열의 발생은 열화요인의 이동을 용이하게 하여 열화의 진행을 촉진시키므로 철근 콘크리트 구조물의 안정성 및 성능의 확보를 위해서는 열화 초기에 보수를 실시하여 더 이상의 열화의 진행을 억제하고 내구성능을 회복하고 향상시킬 필요가 있다.In other words, peeling of the surface of the concrete structure or occurrence of cracks or cracks facilitates the movement of deterioration factors and promotes the progress of deterioration. Therefore, in order to secure the stability and performance of the reinforced concrete structure, It is necessary to suppress the progress of deterioration and restore and improve durability performance.

따라서, 콘크리트의 열화, 강재의 부식, 기타의 원인에 의해 구조물 단면의 박리나 탈락 등의 열화인자를 포함하는 콘크리트 부분을 제거한 후 단면을 그 원래의 성능 및 형태로 복원하기 위해 단면복구재료를 충진하거나 뿜칠 시공을 하여 보수를 실시한다.Therefore, in order to restore the section to its original performance and form after removing the concrete part including the deterioration factor such as detachment or detachment of the section of the structure due to deterioration of concrete, corrosion of steel, Or repairs by spraying.

종래의 단면복구 및 표면보수 시공에는 시멘트계 모르타르나, 폴리머 시멘트 모르타르를 사용하고 있는데, 한국등록특허 10-0654152(2006년11월29일)에는 시멘트 15~35중량부, 다기능성 슬래그골재6호(입자 03~06) 17~37중량부, 다기능성 슬래그골재5호(입자 06~085) 17~27중량부, 고강도용 혼화제 1~20중량부, 슬래그분말 1~10중량부, 소석회 01~5중량부, 유동화제 001~025중량부, 증점제 001~05중량부, 보수제 001~025중량부, 지연제 05~5중량부, 촉진제 001~025중량부를 혼합한 뿜칠용보수보강재에 수용폴리머를 혼합하여 사용하는 것을 특징으로 하는 다기능성 슬래그골재를 이용한 노출콘크리트 구조물보수보강재가 공지되어 있다.Conventionally, cement mortar or polymer cement mortar is used for repairing the surface and repairing the surface. In Korean Patent No. 10-0654152 (November 29, 2006), 15 to 35 parts by weight of cement, 6 parts by weight of multifunctional slag aggregate No. 6 17 to 27 parts by weight of a multifunctional slag aggregate No. 5 (particles 06 to 085), 1 to 20 parts by weight of a high-strength admixture, 1 to 10 parts by weight of a slag powder, 001 to 025 parts by weight of a fluidizing agent, 001 to 05 parts by weight of a thickener, 001 to 025 parts by weight of a filler, 05 to 5 parts by weight of a retarder and 001 to 025 parts by weight of an accelerator, The present invention relates to an exposed concrete reinforcing material for reinforced concrete, and more particularly, to a reinforced concrete structure for reinforcing exposed concrete using the multifunctional slag aggregate.

또한, 한국등록특허 10-1084040(2011년11월10일)에는 시멘트 40 ~ 85 중량%, 고로 [0013] 급냉 슬래그 및 고로 서냉 슬래그가 7~9:1~3의 중량비율로 혼합된 것으로서 평균입경이 2~10 μm인 합성 슬래그 미분말 5 ~ 45중량%, 수축 저감재 5% ~ 20중량%, 고분자 수지 05 ~ 15 중량% 및 섬유 02 ~ 2중량%를 포함하는 단면 복구 모르타르용 결합재 조성물이 공지되어 있다.In addition, in Korean Patent No. 10-1084040 (November 10, 2011), 40 to 85% by weight of cement, blast furnace slag and blast furnace slag were mixed at a weight ratio of 7 to 9: 1 to 3, A binder composition for a single-sided recovery mortar comprising 5 to 45 wt% of a synthetic slag fine powder having a particle diameter of 2 to 10 μm, a shrinkage reducing material of 5 to 20 wt%, a polymer resin of 5 to 15 wt%, and a fiber of 2 to 2 wt% Lt; / RTI >

또한, 한국등록특허 10-1141347(2012년04월23일)에는 고로 슬래그 25~80 중량부, 알파형 반수석고 03~25 중량부, 폴리비닐알콜단섬유 01~5 중량부, 고분자분말 2~8 중량부, 실리카퓸 5~15 중량부, 플라이애쉬 10~40 중량부, 메타카올린 3~40 중량부, 유동화제 01~3중량부, 소포제 005~5 중량부를 포함하는 지오폴리머모르타르; 및 규산소다(물유리) 40~60 중량부 및 실록산 35~60 중량부를 포함하는 모르타르 혼화액; 을 포함하고, 상기 고분자분말은, EVA계, NR(Natural Rubber)계, NBR(Natural Rubber-Butadien Rubber), SBR(Styrene-ButadienRubber), 폴리비닐아세테이트계 수지에서 선택되는 어느 하나 이상의 수지 분말을 포함하는 것을 특징으로 하는 환경 친화적인 지오폴리머 단면복구용 모르타르 조성물이 공지되어 있다.In Korean Patent No. 10-1141347 (Apr. 23, 2012), 25 to 80 parts by weight of blast furnace slag, 03 to 25 parts by weight of alpha-type hemihydrate gypsum, 01 to 5 parts by weight of polyvinyl alcohol short fibers, 8 to 8 parts by weight of silica fume, 5 to 15 parts by weight of silica fume, 10 to 40 parts by weight of fly ash, 3 to 40 parts by weight of meta kaolin, 01 to 3 parts by weight of fluidizing agent and 005 to 5 parts by weight of defoaming agent; 40 to 60 parts by weight of sodium silicate (water glass) and 35 to 60 parts by weight of siloxane; Wherein the polymer powder includes one or more resin powders selected from the group consisting of EVA, NR (natural rubber), NBR (natural rubber-butadiene rubber), SBR (styrene-butadiene rubber) A mortar composition for restoring an environmentally friendly geopolymer section is known.

또한, 한국등록특허 10-1164623(2012년07월04일)에는 콘크리트 구조물의 열화방지 및 단면보수용 폴리머 몰탈 조성물을 구성함에 있어서, 시멘트 100중량부, 실리카샌드 80~110중량부, 슬래그 15~40중량부, 가넷 5~12중량부 및 혼화제 06~40중량부를 포함하여 이루어지는 것을 특징으로 하는 콘크리트 구조물의 열화방지 및 단면보수용 폴리머 몰탈 조성물이 공지되어 있다.In addition, Korean Patent No. 10-1164623 (Jul. 04, 2012) discloses a method for constructing a polymer mortar composition for preventing deterioration of a concrete structure and for maintenance of a section, which comprises 100 parts by weight of cement, 80 to 110 parts by weight of a silica sand, 40 to 40 parts by weight of garnet, 5 to 12 parts by weight of garnet, and 06 to 40 parts by weight of an admixture are known as a polymer mortar composition for preventing deterioration and maintenance of a concrete structure.

또한, 한국등록특허 10-1566965(2015년11월02일)에는 포틀랜드 시멘트 10~50 중량부; 제강 슬래그 1~20 중량부; 무수석고 1~5 중량부; 골재 40~60 중량부; 혼화제 03~2 중량부;를 포함하는 것을 특징으로 하는 콘크리트 구조물의 보수용 모르타르 조성물이 공지되어 있다.Korean Patent No. 10-1566965 (November 02, 2015) discloses that 10 to 50 parts by weight of Portland cement; 1 to 20 parts by weight of steelmaking slag; 1 to 5 parts by weight of anhydrous gypsum; 40 to 60 parts by weight of aggregate; And 03 to 2 parts by weight of an admixture.

그러나, 콘크리트는 건조수축, 온도 변화 등에 의해서도 균열이 발생되며, 이러한 구조물의 균열부위 및 표면에서 콘크리트의 중성화가 촉진됨과 동시에 구조물의 콘크리트 부분에서 열화현상이 복합적으로 발생되어 구조물의 표면이 박리, 박락의 현상을 보이는 문제가 있으므로 따라서 철근 콘크리트 구조물의 결함을 보수하거나 보강하여야 하고, 이에 사용되는 몰타르는 기존의 구조물 표면이나 단면 등에 보충하여 타설하였을 때 기존의 콘크리트 구조물과 실질적으로 결합할 수 있어야 하는데, 상기 종래의 선행문헌들의 보수모르타르들은 초기 복구 및 보수시공시에는 부착강도가 발현되나, 콘크리트 구조물 강력한 접착이 이루어지지 않아 시간이 경과할 수록 열화되어 다시 보수공사를 해야 하는 문제점이 있었다However, concrete is cracked due to drying shrinkage and temperature change, and the neutralization of concrete is promoted at cracks and surfaces of such a structure, and at the same time, deterioration phenomenon occurs in a concrete portion of the structure, Therefore, it is necessary to repair or reinforce the defects of the reinforced concrete structure, and the mortar to be used should be able to be substantially combined with the existing concrete structure when it is installed by supplementing the surface or cross section of the existing structure. However, The repair mortars of the above prior art documents exhibit adhesive strength at the time of initial restoration and maintenance, but are not strongly bonded to concrete structures, and deteriorate as time elapses, which requires repair work

한국등록특허 10-0654152(2006년11월29일)Korean Patent No. 10-0654152 (November 29, 2006) 한국등록특허 10-1084040(2011년11월10일)Korean Patent No. 10-1084040 (November 10, 2011) 한국등록특허 10-1141347(2012년04월23일)Korean Patent No. 10-1141347 (April 23, 2012) 한국등록특허 10-1164623(2012년07월04일)Korean Registered Patent No. 10-1164623 (July 04, 2012) 한국등록특허 10-1566965(2015년11월02일)Korean Patent No. 10-1566965 (November 02, 2015)

본 발명은 상기한 종래의 문제점들을 해결하기 위한 것으로, 경량골재인 질석과 무기질 재료인 액상규산나트륨(Na2O·nSiO2·xH2O)를 혼합, 가압하여 제조된 질석보드를 절단 및 가공하는 공정에서 발생되는 질석보드스크랩을 분쇄한 질석 및 규산나트륨 함유 폐분말과, 니켈 제련과정에서 발생하는 니켈슬래그를 분쇄한 니켈슬래그분말과, 유리섬유시트 제조공정중 절단공정에서 발생하는 유리섬유시트를 분쇄한 폐유리분말을 포함하여 조성되는 산업부산물을 활용한 친환경 내황산염 모르타르 조성물 및 이를 이용한 콘크리트 단면복구시공공법을 제공하는 것을 해결하고자 하는 과제로 한다.Disclosure of the Invention The present invention has been made to solve the above-mentioned problems, and it is an object of the present invention to provide a method for cutting and processing a vermiculite board produced by mixing and pressing vermiculite, which is lightweight aggregate, and liquid sodium silicate (Na 2 O.nSiO 2 .xH 2 O) And a nickel slag powder obtained by crushing the nickel slag generated in the nickel smelting process and a glass fiber sheet produced in the cutting process during the production process of the glass fiber sheet, The present invention also provides an eco-friendly resulfuric acid mortar composition using industrial by-products comprising waste glass powder obtained by pulverizing waste glass powder, and a method of recovering and rehabilitating concrete section using the same.

본 발명은 상기 과제를 해결하기 위하여, 시멘트와; 경량골재인 질석과 무기질 재료인 액상규산나트륨(Na2O·nSiO2·xH2O)를 혼합, 가압하여 제조된 질석보드를 절단 및 가공하는 공정에서 발생되는 질석보드스크랩을 분쇄한 질석 및 규산나트륨 함유 폐분말과; 니켈 제련과정에서 발생하는 니켈슬래그를 분쇄한 니켈슬래그분말과; 유리섬유시트 제조공정중 절단공정에서 발생하는 유리섬유시트를 분쇄한 폐유리분말;을 포함하여 조성되는 산업부산물을 활용한 친환경 내황산염 모르타르 조성물을 해결수단으로 한다.In order to solve the above problems, the present invention provides a cement composition comprising: cement; The vermiculite board scrap generated in the process of cutting and processing the vermiculite board produced by mixing and pressing the vermiculite, which is lightweight aggregate, and the liquid sodium silicate (Na 2 O.nSiO 2 .xH 2 O), which is an inorganic material, A sodium-containing waste powder; A nickel slag powder obtained by crushing nickel slag generated in a nickel smelting process; A waste glass powder obtained by pulverizing a glass fiber sheet generated in a cutting process during a glass fiber sheet production process; and an eco-friendly resorcinol mortar composition utilizing industrial by-products.

상기 질석 및 규산소다 함유 폐분말, 니켈슬래그분말, 폐유리분말은 입도가 0.1-18um인 것을 과제의 해결수단으로 한다.The vermiculite and sodium silicate-containing waste powder, the nickel slag powder and the waste glass powder have a particle size of 0.1 to 18 um.

상기 니켈 슬래그 분말은 MgO 성분이 25-30중량% 함유되는 것을 과제의 해결수단으로 한다.The nickel slag powder has a MgO content of 25-30% by weight.

또한, 본 발명은, 콘크리트면의 보수대상부위를 브레이커로 파쇄 및 치핑하고, 레이턴스 및 이물질을 그라인더, 샌드블라스터, 고압수세척기, 워터젯으로부터 선택되는 방법으로 제거하여 전처리하는 단계와; 상기 산업부산물을 활용한 친환경 내황산염 모르타르 조성물을 적량의 물과 혼합하여 상기 전처리된 보수대상부위에 미장 또는 숏크리트방식으로 충전 시공하는 단계;를 포함하여 구성되는 콘크리트 단면복구 시공공법을 과제의 해결수단으로 한다.The present invention also provides a method of manufacturing a concrete structure, comprising the steps of: crushing and chipping a concrete part to be repaired on a concrete surface with a breaker, removing the laitance and a foreign substance by a method selected from a grinder, a sand blaster, a high pressure water washing machine and a water jet; The present invention relates to a method for recovering a concrete slab, comprising the steps of: mixing a mortar composition of an environmentally friendly persulfate mortar with an appropriate amount of water using the above-mentioned industrial byproducts and filling and filling the pretreated repair target site with a mortar or a shotcrete method; .

본 발명의 산업부산물을 활용한 친환경 내황산염 모르타르 조성물 이를 이용한 콘크리트 단면복구시공공법은 콘크리트면의 중성화 억제 뿐만 아니라 염화물 이온의 차폐 및 방수효과를 향상시키고, 콘크리트와의 부착강도를 향상시키며, 수축, 팽창에 대한 안정성을 높이고, 균열로 인한 누수와 들뜸을 방지하도록 복구 및 보수할 수 있는 후수한 효과가 있다.Eco-friendly resulfuric acid mortar composition utilizing the industrial by-product of the present invention is useful for not only inhibiting the neutralization of the concrete surface but also improving the shielding and waterproofing effect of chloride ion, improving the adhesion strength to concrete, There is a posterior effect that can be restored and repaired in order to enhance stability against expansion and to prevent leakage and lifting due to cracks.

본 발명은, 시멘트와; 경량골재인 질석과 무기질 재료인 액상규산나트륨(Na2O·nSiO2·xH2O)를 혼합, 가압하여 제조된 질석보드를 절단 및 가공하는 공정에서 발생되는 질석보드스크랩을 분쇄한 질석 및 규산나트륨 함유 폐분말과; 니켈 제련과정에서 발생하는 니켈슬래그를 분쇄한 니켈슬래그분말과; 유리섬유시트 제조공정중 절단공정에서 발생하는 유리섬유시트를 분쇄한 폐유리분말;을 포함하여 조성되는 산업부산물을 활용한 친환경 내황산염 모르타르 조성물을 기술구성의 특징으로 한다.The present invention relates to a cement composition comprising: cement; The vermiculite board scrap generated in the process of cutting and processing the vermiculite board produced by mixing and pressing the vermiculite, which is lightweight aggregate, and the liquid sodium silicate (Na 2 O.nSiO 2 .xH 2 O), which is an inorganic material, A sodium-containing waste powder; A nickel slag powder obtained by crushing nickel slag generated in a nickel smelting process; A waste glass powder obtained by pulverizing a glass fiber sheet produced in a cutting process during a glass fiber sheet manufacturing process; and an eco-friendly resorcinol mortar composition utilizing an industrial by-product.

상기 질석 및 규산소다 함유 폐분말, 니켈슬래그분말, 폐유리분말은 입도가 0.1-18um인 것을 기술구성의 특징으로 한다.The vermiculite and sodium silicate-containing waste powder, nickel slag powder, and waste glass powder have a particle size of 0.1-18 μm.

상기 니켈 슬래그 분말은 MgO 성분이 25-30중량% 함유되는 것을 기술구성의 특징으로 한다.The nickel slag powder is characterized in that the MgO component is contained in an amount of 25-30% by weight.

또한, 본 발명은, 콘크리트면의 보수대상부위를 브레이커로 파쇄 및 치핑하고, 레이턴스 및 이물질을 그라인더, 샌드블라스터, 고압수세척기, 워터젯으로부터 선택되는 방법으로 제거하여 전처리하는 단계와; 상기 산업부산물을 활용한 친환경 내황산염 모르타르 조성물을 적량의 물과 혼합하여 상기 전처리된 보수대상부위에 미장 또는 숏크리트방식으로 충전 시공하는 단계;를 포함하여 구성되는 콘크리트 단면복구 시공공법을 기술구성의 특징으로 한다.The present invention also provides a method of manufacturing a concrete structure, comprising the steps of: crushing and chipping a concrete part to be repaired on a concrete surface with a breaker, removing the laitance and a foreign substance by a method selected from a grinder, a sand blaster, a high pressure water washing machine and a water jet; The present invention relates to a method for repairing a concrete cross-sectional area, comprising the steps of: mixing an environment-friendly manganese sulfate mortar composition using an industrial by-product with an appropriate amount of water and filling the pre-treated repair target site with a mortar or a shotcrete method; .

이하에서는 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 용이하게 실시할 수 있도록 본 발명의 바람직한 실시예를 통하여 상세히 설명한다. 그러나 본 발명은 여러 가지 상이한 형태로 구현될 수 있으며, 여기에서 설명하는 실시예에 한정되지 않는다.Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. The present invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein.

우선, 본 발명의 산업부산물을 활용한 친환경 내황산염 모르타르 조성물은, 시멘트와; 경량골재인 질석과 무기질 재료인 액상규산나트륨(Na2O·nSiO2·xH2O)를 혼합, 가압하여 제조된 질석보드를 절단 및 가공하는 공정에서 발생되는 질석보드스크랩을 분쇄한 질석 및 규산나트륨 함유 폐분말과; 니켈 제련과정에서 발생하는 니켈슬래그를 분쇄한 니켈슬래그분말과; 유리섬유시트 제조공정중 절단공정에서 발생하는 유리섬유시트를 분쇄한 폐유리분말;을 포함하여 조성된다.First, the eco-friendly sodium sulfate mortar composition utilizing the industrial by-products of the present invention comprises cement; The vermiculite board scrap generated in the process of cutting and processing the vermiculite board produced by mixing and pressing the vermiculite, which is lightweight aggregate, and the liquid sodium silicate (Na 2 O.nSiO 2 .xH 2 O), which is an inorganic material, A sodium-containing waste powder; A nickel slag powder obtained by crushing nickel slag generated in a nickel smelting process; And a waste glass powder obtained by pulverizing a glass fiber sheet produced in the cutting process during the production process of the glass fiber sheet.

여기서, 상기 질석 및 규산나트륨 함유 폐분말은 경량골재인 질석과 무기질 재료인 액상규산나트륨(Na2O·nSiO2·xH2O)를 혼합, 가압하여 제조된 질석보드를 절단 및 가공하는 공정에서 발생되는 산업부산물인 질석보드스크랩을 분쇄한 것으로 상기 질석 및 규산나트륨 함유 폐분말은 경량성(기존 질석 0.4g/cm3에 비해 1g/cm3)으로 이루어져 있으며 액상규산나트륨(Na2O·nSiO2·xH2O)은 모르타르에 혼합될 경우 강도 증진 효과를 갖는 것이 특징이므로 본 발명에서는 이를 사용하여 모르타르의 중량 감소와 강도증진효과를 발휘하게 된다.The vermiculite and the sodium silicate-containing waste powder are prepared by mixing and pressing vermiculite, which is a lightweight aggregate, with liquid sodium silicate (Na 2 O.nSiO 2 .xH 2 O) as an inorganic material, and cutting and processing the vermiculite board the vermiculite-containing sodium silicate, and that the milling industry by-product of vermiculite board scrap generated waste powder is made up of light weight (1g / cm 3, compared to traditional vermiculite 0.4g / cm 3) and the liquid sodium silicate (Na 2 O · nSiO 2 · xH 2 O) is mixed with mortar and has a strength improving effect. Therefore, in the present invention, weight reduction and strength enhancement effect of the mortar are exhibited.

또한, 상기 니켈슬래그분말은 니켈 제련과정에서 발생하는 산업부산물인 니켈슬래그를 분쇄한 것으로 상기 니켈 슬래그 분말은 MgO 성분이 약 25-30중량%정도 함유되어 있어 이 성분은 열과 산에 대한 안정성을 갖는 것으로 상기 니켈슬래그분말을 포함하는 모르타르는 하수관거 또는 터널에 적용될 경우 황산염에 대한 저항성을 가지며 열에 대한 안정성을 가지게 된다.In addition, the nickel slag powder is obtained by crushing nickel slag, which is an industrial by-product generated in the nickel smelting process, and the nickel slag powder contains about 25-30% by weight of MgO component, and this component has stability against heat and acid The mortar containing the nickel slag powder is resistant to sulfate and has heat stability when applied to sewer pipes or tunnels.

또한, 상기 폐유리분말은 유리섬유시트 제조공정중 절단공정에서 발생하는 유리섬유시트를 분쇄한 것으로 일자(-)구조를 가지는 유리섬유는 모르타르를 보강하는 효과가 있으나 격자구조를 가지는 폐유리분말 보다 1.2-1.4% 정도 인장 강도 저하가 발생되는 것으로 나타나므로 본 발명에서는 유리섬유시트 제조공정중 절단공정에서 발생하는 유리섬유시트를 분쇄한 격자구조를 가지는 폐유리분말로 사용하는 것이 특징이다.In addition, the waste glass powder is obtained by crushing a glass fiber sheet produced in a cutting process during a glass fiber sheet manufacturing process. The glass fiber having a (-) structure has an effect of reinforcing mortar, The present invention is characterized by using a waste glass powder having a lattice structure obtained by crushing a glass fiber sheet produced in the cutting process during the production process of the glass fiber sheet.

상기 질석 및 규산나트륨 함유 폐분말, 니켈슬래그분말, 폐유리분말은 입도가 0.1-18um인 것이 바람직한데, 상기 입도로 사용될 경우 시멘트 입자에 비해 미세하기 때문에 시멘트 입자들 사이의 충전효과로 인하여 강도 증진이 나타타나게 된다.Preferably, the vermiculite and sodium silicate-containing waste powder, the nickel slag powder, and the waste glass powder have a particle size of 0.1 to 18 μm. When the particle size is smaller than that of the cement particles, Will appear.

아울러, 본 발명의 산업부산물을 활용한 친환경 내황산염 모르타르 조성물 이를 이용한 콘크리트 단면복구시공공법은 콘크리트면의 보수대상부위를 브레이커로 파쇄 및 치핑하고, 레이턴스 및 이물질을 그라인더, 샌드블라스터, 고압수세척기, 워터젯으로부터 선택되는 방법으로 제거하여 전처리하는 단계와; 상기 산업부산물을 활용한 친환경 내황산염 모르타르 조성물을 절량의 물과 혼합하여 상기 전처리된 보수대상부위에 미장 또는 숏크리트방식으로 충전 시공하는 단계;를 포함하여 구성되는 것이 특징이다.In addition, the present invention provides a method for recovering concrete from a concrete surface using an industrial sludge mortar composition using the industrial by-product of the present invention, which comprises crushing and chipping a repair target portion of a concrete surface with a breaker, , Water jet, and preprocessing; And mixing the eco-friendly sodium sulfate mortar composition using the industrial by-product with water in a volume to fill the pre-treated portion to be repaired with a mortar or a shotcrete method.

[본 발명의 산업부산물을 활용한 친환경 내황산염 모르타르 조성물의 제조][Preparation of eco-friendly sulfonate mortar composition utilizing industrial by-products of the present invention]

보통포틀랜드 시멘트 300중량부와; 경량골재인 질석과 무기질 재료인 액상규산나트륨(Na2O·nSiO2·xH2O)를 혼합, 가압하여 제조된 질석보드를 절단 및 가공하는 공정에서 발생되는 질석보드스크랩을 입도 10㎛로 분쇄한 질석 및 규산나트륨 함유 폐분말 200중량부와; 니켈 제련과정에서 발생하는 니켈슬래그를 입도 10㎛로 분쇄한 니켈슬래그분말 80중량부와; 유리섬유시트 제조공정중 절단공정에서 발생하는 유리섬유시트를 입도 10㎛로 분쇄한 폐유리분말 50중량부에 적량의 물을 혼합하여 본 발명의 산업부산물을 활용한 친환경 내황산염 모르타르 조성물을 제조하였다.300 parts by weight of ordinary Portland cement; The vermiculite board scrap generated in the process of cutting and processing the vermiculite board produced by mixing and pressing the vermiculite as the lightweight aggregate and the liquid sodium silicate (Na 2 O.nSiO 2 .xH 2 O) as the inorganic material is crushed to a particle size of 10 μm 200 parts by weight of a vermiculite and sodium silicate-containing waste powder; 80 parts by weight of a nickel slag powder obtained by pulverizing nickel slag produced in a nickel smelting process to a particle size of 10 mu m; A glass fiber sheet produced in a cutting process in a glass fiber sheet production process was mixed with an appropriate amount of water in 50 parts by weight of waste glass powder ground to a particle size of 10 탆 to prepare an environmentally resistant sulfonate mortar composition utilizing the industrial by-product of the present invention .

[모르타르 조성물의 성능평가][Performance evaluation of mortar composition]

상기 [실시예 1]에서 제조된 산업부산물을 활용한 친환경 내황산염 모르타르 조성물을 이용하여 KS F 4042 콘크리트 구조물 보수용 시멘트 모르타르 시험방법에 준하여 시험을 실시하였으며, 그 결과를 하기 [표 1]에 나타내었다.The test was carried out in accordance with the test method for cement mortar for repairing concrete structures of KS F 4042 by using an environmentally friendly persulfate mortar composition using the industrial by-products prepared in [Example 1]. The results are shown in Table 1 below .

시험항목Test Items 품질기준Quality standards 실시예 1Example 1 휨 강도(N/㎟)Flexural strength (N / mm2) 6.0 이상6.0 or higher 10.510.5 압축강도(N/㎟)Compressive strength (N / mm2) 20.1 이상20.1 or more 54.054.0 부착강도(N/㎟)Bond strength (N / mm2) 1.0 이상1.0 or higher 1.71.7

상기 [표 1]에 나타난 바와 같이, 본 발명의 산업부산물을 활용한 친환경 내황산염 모르타르 조성물은 모든 시험항목에서 품질기준을 만족하는 값을 나타내고 있으므로 콘크리트 구조물 보수용 시멘트 모르타르 조성물로 사용될 수 있음을 알 수 있다.As shown in Table 1, the eco-friendly manganese sulfate mortar composition utilizing the industrial by-products of the present invention shows a value satisfying the quality standards in all the test items, so that it can be used as a cement mortar composition for repairing concrete structures .

이상의 설명은 본 발명의 기술사상을 예시적으로 설명한 것에 불과한 것으로서, 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자라면 본 발명의 본질적인 특성에서 벗어나지 않는 범위에서 다양한 수정 및 변형이 가능할 것이다. 따라서, 본 발명에 개시된 실시예들은 본 발명의 기술 사상을 한정하기 위한 것이 아니라 설명하기 위한 것이고, 이러한 실시예에 의하여 본 발명의 기술 사상의 범위가 한정되는 것은 아니다. 본 발명의 보호 범위는 아래의 청구범위에 의하여 해석되어야 하며, 그와 동등한 범위 내에 있는 모든 기술 사상은 본 발명의 권리범위에 포함되는 것으로 해석되어야 할 것이다.The foregoing description is merely illustrative of the technical idea of the present invention, and various changes and modifications may be made by those skilled in the art without departing from the essential characteristics of the present invention. Therefore, the embodiments disclosed in the present invention are intended to illustrate rather than limit the scope of the present invention, and the scope of the technical idea of the present invention is not limited by these embodiments. The scope of protection of the present invention should be construed according to the following claims, and all technical ideas within the scope of equivalents should be construed as falling within the scope of the present invention.

Claims (4)

시멘트와; 경량골재인 질석과 무기질 재료인 액상규산나트륨(Na2O·nSiO2·xH2O)를 혼합, 가압하여 제조된 질석보드를 절단 및 가공하는 공정에서 발생되는 질석보드스크랩을 분쇄한 질석 및 규산나트륨 함유 폐분말과; 니켈 제련과정에서 발생하는 니켈슬래그를 분쇄한 니켈슬래그분말과; 유리섬유시트 제조공정중 절단공정에서 발생하는 유리섬유시트를 분쇄한 격자구조를 가지는 폐유리분말;을 포함하여 조성되되,
상기 질석 및 규산소다 함유 폐분말, 니켈슬래그분말, 격자구조를 가지는 폐유리분말은 입도가 0.1-18um이고,
상기 니켈 슬래그 분말은 MgO 성분이 25-30중량% 함유되는 것을 특징으로 하는 산업부산물을 활용한 친환경 내황산염 모르타르 조성물
Cement and; The vermiculite board scrap generated in the process of cutting and processing the vermiculite board produced by mixing and pressing the vermiculite, which is lightweight aggregate, and the liquid sodium silicate (Na 2 O.nSiO 2 .xH 2 O), which is an inorganic material, A sodium-containing waste powder; A nickel slag powder obtained by crushing nickel slag generated in a nickel smelting process; And a waste glass powder having a lattice structure obtained by pulverizing a glass fiber sheet generated in a cutting process during a glass fiber sheet production process,
The above vermiculite and sodium silicate-containing waste powder, nickel slag powder and waste glass powder having a lattice structure have a particle size of 0.1 to 18 um,
Wherein the nickel slag powder contains an MgO component in an amount of 25-30% by weight.
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