KR101950065B1 - Plasma generating film manufacturing method - Google Patents
Plasma generating film manufacturing method Download PDFInfo
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- KR101950065B1 KR101950065B1 KR1020160001521A KR20160001521A KR101950065B1 KR 101950065 B1 KR101950065 B1 KR 101950065B1 KR 1020160001521 A KR1020160001521 A KR 1020160001521A KR 20160001521 A KR20160001521 A KR 20160001521A KR 101950065 B1 KR101950065 B1 KR 101950065B1
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/2406—Generating plasma using dielectric barrier discharges, i.e. with a dielectric interposed between the electrodes
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/46—Generating plasma using applied electromagnetic fields, e.g. high frequency or microwave energy
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- H05H2001/466—
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- Spectroscopy & Molecular Physics (AREA)
- Electromagnetism (AREA)
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Abstract
A plasma generating apparatus is disclosed. The plasma generator comprises a power supply; And a plasma generating film on which a first electrode grounded on one surface of the insulating film is formed and a second electrode connected to the power source is formed on the other surface, wherein the insulating film is provided as a polyimide material.
Description
BACKGROUND OF THE
Plasma has been widely used for the surface treatment of semiconductors, display devices, and various parts, and has expanded its applicability to become a fusion technology field used in biotechnology research, medical care, air cleaning, and incinerator. Particularly, the field of medicine is expanding such as tooth whitening, cancer cell death, blood coagulation speed promotion, skin whitening, wound healing, etc. In the case of a laser which has been used mainly in the past, an image due to heat damage and a wide There is a fundamental disadvantage in that it is impossible to uniformly treat the area. However, in the case of plasma, there is no heat damage, and according to the plasma generating apparatus, it is possible to uniformly and efficiently treat a large area of treatment area.
Oxygen radicals such as ultraviolet rays (UV) and ozone generated in the plasma, nitrogen oxides such as nitrogen monoxide, currents and charge carriers are caused to increase in cell immunity, sterilization, cancer cell necrosis and blood circulation .
Conventional plasma generators mainly generate ozone and nitrogen oxides. However, a device for generating a high concentration of carbon dioxide is not known. High concentrations of carbon dioxide inhalation cause respiratory problems, but when absorbed into skin tissue, blood vessels, muscles, etc., the partial pressure of oxygen in the blood vessels increases, resulting in lipolysis and metabolic increase. In particular, in cases of wound, the main cause of the wound not recovering is the decrease of oxygen concentration in the wound tissue. Therefore, methods of treating the wound by inducing the increase of oxygen concentration by injecting carbon dioxide from the outside have been introduced. Therefore, there is a demand for a medical atmospheric-pressure plasma generator capable of generating carbon dioxide at a concentration of at least carbon dioxide contained in air at atmospheric pressure.
In the conventional plasma generating apparatus, when plasma is generated without supplying nitrogen gas from the outside, nitrogen oxide is generated due to the content of nitrogen contained in the air, so that it is difficult to expect a high concentration of nitrogen oxide.
Further, when the conductive layer such as copper is adhered to the dielectric body through the adhesive layer made of the adhesive, there is a risk that the conductive layer detaches from the dielectric due to a decrease in the chemical performance of the adhesive when the temperature of the plasma generating device is increased. In contrast, in the prior art in which a conductive layer is formed only by sputtering, atomic layer deposition, or ion plating on a dielectric, the height of the conductive layer (several tens of nm) is much smaller than the diameter of the filament in the generated plasma (several tens of μm) In this case, the physicochemical etching of the conductive layer and the dielectric is very accelerated by the filament, and the disadvantage is that it generates a large number of particles.
The present invention provides a plasma generating apparatus capable of generating carbon dioxide at a high concentration using plasma generation.
Further, the present invention provides a plasma generator capable of controlling the concentration of generated ozone, nitrogen oxide, and carbon dioxide by controlling the temperature of the plasma generator.
A plasma generator according to the present invention includes a power source; And a plasma generating film on which a first electrode grounded on one surface of the insulating film is formed and a second electrode connected to the power source is formed on the other surface, wherein the insulating film is provided as a polyimide material.
The insulating film may have a thickness of 25 to 38 mu m.
Also, the concentration of carbon dioxide produced in the plasma generating film may be greater than the concentration of carbon dioxide in the atmosphere.
The step of forming the first electrode and the second electrode on the insulating film may include: a step of performing nitrogen ion plating on one surface of the insulating film; Oxygen plasma processing the other surface of the insulating film; Forming a conductive thin film on both surfaces of the insulating film through a sputtering process; A step of increasing the thickness of the conductive thin film through an electrolytic plating process; And forming a pattern on at least one thin film of the conductive thin film.
In addition, protrusions are formed on the surface of one of the first electrode and the second electrode, and the protrusions may have any one of triangular, rectangular, and semicircular shapes.
In addition, the electrode having the above shape may have a size of 0.1 to 1 mm.
At least one of the first electrode and the second electrode may be provided in a predetermined pattern, and the electrode pattern may be provided in a smooth curve in a region where the direction is switched.
The width of the electrode pattern may be 0.2 to 2 mm.
In addition, the distance between the electrode patterns of the electrode may be larger than twice the electric field area generated in the electrode pattern.
According to the present invention , gases such as ozone, nitrogen oxides, carbon monoxide, and carbon dioxide, ultraviolet rays and the like are generated from plasma to remove harmful bacteria and viruses, promote skin regeneration, promote lipolysis, increase blood vessels , It can give a high therapeutic effect to human skin through induction .
1 is a view showing a plasma generator according to an embodiment of the present invention.
2 is a view illustrating a process of forming electrodes on both surfaces of an insulating film according to an embodiment of the present invention.
3 is a view showing various shapes of electrodes formed according to an embodiment of the present invention.
FIG. 4 is a graph of radicals generated in a film-type plasma generator according to an embodiment of the present invention, measured by Fourier transform infrared spectroscopy (FT-IR).
5 is a view showing one surface of a plasma generating film according to another embodiment of the present invention.
6 is a photograph showing a plasma generating film according to another embodiment of the present invention.
7 is an SEM photograph showing a state in which dielectric breakdown occurs on the surface of the insulating film and the electrode.
8 is a flowchart showing a plasma generation control method according to an embodiment of the present invention.
FIG. 9 is a graph illustrating changes in Vpp value according to an exemplary embodiment of the present invention.
10 is a SEM photograph showing a significant amount of etching on the surface of the electrode and the dielectric after the generation of the plasma for 30 seconds in the plasma generator having the electrode height of 100 nm according to the conventional method (when the height of the copper electrode is 100 nm, Electrode and dielectric surface after formation)
11 is a SEM photograph showing electrodes and a dielectric surface after a 30 second plasma is generated in a plasma generator having an electrode height of 8.6 μm according to the present invention. (When the height of a copper electrode is 8.6 .mu.m, And dielectric surfaces)
Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. However, the technical spirit of the present invention is not limited to the embodiments described herein but may be embodied in other forms. Rather, the embodiments disclosed herein are provided so that the disclosure can be thorough and complete, and will fully convey the scope of the invention to those skilled in the art.
In this specification, when an element is referred to as being on another element, it may be directly formed on another element, or a third element may be interposed therebetween. Further, in the drawings, the thicknesses of the films and regions are exaggerated for an effective explanation of the technical content.
Also, while the terms first, second, third, etc. in the various embodiments of the present disclosure are used to describe various components, these components should not be limited by these terms. These terms have only been used to distinguish one component from another. Thus, what is referred to as a first component in any one embodiment may be referred to as a second component in another embodiment. Each embodiment described and exemplified herein also includes its complementary embodiment. Also, in this specification, 'and / or' are used to include at least one of the front and rear components.
The singular forms "a", "an", and "the" include plural referents unless the context clearly dictates otherwise. It is also to be understood that the terms such as " comprises "or" having "are intended to specify the presence of stated features, integers, Should not be understood to exclude the presence or addition of one or more other elements, elements, or combinations thereof. Also, in this specification, the term "connection " is used to include both indirectly connecting and directly connecting a plurality of components.
In the following description of the present invention, a detailed description of known functions and configurations incorporated herein will be omitted when it may make the subject matter of the present invention rather unclear.
1 is a view showing a plasma generator according to an embodiment of the present invention.
Referring to Figure 1, the
The
The plasma generating
First and
2 is a view illustrating a process of forming electrodes on both surfaces of an insulating film according to an embodiment of the present invention.
2, the step of forming electrodes on both surfaces of the insulating film includes a step of performing heat treatment in a vacuum environment, a step of performing nitrogen ion beam treatment on one surface of the insulating film, a step of performing oxygen plasma treatment on the other surface of the insulating film, A step of forming a conductive thin film on both surfaces of the insulating film through a sputtering process, a step of increasing the thickness of the conductive thin film through an electrolytic plating process, and a step of forming a pattern on at least one of the conductive thin films formed on both surfaces of the insulating film do. The above-described processes can be sequentially performed. According to the embodiment, the heat treatment process may be performed in an atmosphere at 100 ° C., and the conductive thin film may include nickel, chromium, and copper thin films, and may be sequentially formed on both sides of the insulating film. And the pattern formation process includes a dry or wet etching process.
The manufacturing process of the
3 is a view showing various shapes of electrodes formed according to an embodiment of the present invention.
Referring to FIG. 3, at least one of the
The
FIG. 4 is a graph of oxide gas generated in a plasma generating film according to an embodiment of the present invention, measured by Fourier transform infrared spectroscopy (FT-IR).
The red graph is a graph in which carbon dioxide and moisture contained in the atmosphere are measured. The black graph is a graph showing oxide gasses occurring in a plasma generating film according to an embodiment of the present invention.
As shown in the graph of FIG. 4, in the plasma generating film according to the present invention, it can be seen that the concentration of carbon dioxide is higher than the concentration of carbon dioxide contained in air, and the generation of carbon monoxide (CO) can also be confirmed.
5 is a view showing one surface of a plasma generating film according to another embodiment of the present invention.
Referring to FIG. 5, the
In addition, the
In addition, the
The distance d between the
In addition, the
6 is a photograph showing a plasma generating film according to another embodiment of the present invention. As shown in Fig. 6, the electrode pattern formed on the plasma generating film can be variously changed.
1, the
The
A
The
The
Here, the reference Vpp value is an average value of the Vpp values measured at the
According to the embodiment, the
The
According to an embodiment, the predetermined percentage range may be from 99.5% to 97%. The
The interruption of the
8 is a flowchart showing a plasma generation control method according to an embodiment of the present invention.
8, the plasma generation control method includes a step of applying a voltage to the plasma generating film 110 (S10), a step S20 of measuring a voltage Vpp of a voltage applied to the
The step of cutting off the voltage application (S50) is performed when the measured Vpp value falls within a predetermined percentage range of the reference Vpp value. According to the embodiment, step S50 of interrupting the voltage application cuts off the voltage application when the measured Vpp value corresponds to 99.5% to 97% of the reference Vpp value.
FIG. 9 is a graph illustrating changes in Vpp value according to an exemplary embodiment of the present invention.
Referring to FIG. 9, the reference time is set to 30 seconds, and the average Vpp value is calculated in units of 30 seconds and displayed on the graph. The Vpp value displayed in the first 30 seconds was set as the reference Vpp value, and in the experiment, it was 3.40 kV. When the percentage range was set to 97%, the power supply was cut off at 6 minutes in which 3.30 kV corresponding to 97% of the reference Vpp value appeared as the Vpp value.
Table 1 below shows the characteristics of the plasma generating film and the plasma generating process according to an embodiment of the present invention.
Surface temperature: 20 ~ 45 ℃
- Semicircle of edge of electrode.
- The shape of the electrode should be C, S, O type.
- The electrode width is 0.2 to 2.0 mm
The characteristics of Table 1 have the following advantages.
(1) Since the insulation film and the electrode thickness are micro-sized and thin, a flexible plasma generating film can be realized.
(2) Since it is possible to reduce the operating frequency flexibly, the electrode impedance can be increased and the electrode design capable of large-area processing is possible.
(3) Since the thickness of the insulating film is very thin, it is possible to generate plasma at a low applied voltage.
(4) Since the thickness of the plasma-generating film is low, the plasma generation density is low, and the radicals generated in the plasma are diffused into the human body by natural diffusion and a temperature reduction effect is caused by the diffusion with molecules in the air during the diffusion process That is, the skin temperature is low. This prevents DNA damage by unnecessarily high density radicals while preventing the skin from burning due to heat generation in the plasma generating film.
(5) According to the film production method described above, since the surface roughness of the insulating film is small and the interface between the insulating film and the conductive layer is uniform, high reliability can be secured in the power cutoff function through the Vpp monitor.
(6) The shape of the above-described electrode pattern generates a uniform plasma density on the surface of the electrode, and a uniform treatment effect on the surface to be treated and an increase in the life of the plasma generating apparatus can be expected.
(7) The concentration of carbon dioxide produced in the above-mentioned plasma generating film is larger than the concentration of carbon dioxide in the atmosphere. The resulting carbon dioxide promotes skin fat breakdown, increased blood circulation, and decreased melanocytes.
While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the scope of the present invention is not limited to the disclosed exemplary embodiments. It will also be appreciated that many modifications and variations will be apparent to those skilled in the art without departing from the scope of the present invention.
100: Plasma generator
110: Plasma generating film
111: insulating film
112: first electrode
113: second electrode
120: Power supply
130: Trance
140: Vpp measuring sensor
150: controller
Claims (9)
Wherein the step of forming the first electrode and the second electrode on the insulating film
A step of subjecting one surface of the insulating film to a nitrogen ion plating treatment;
Oxygen plasma processing the other surface of the insulating film;
Forming a conductive thin film on both surfaces of the insulating film through a sputtering process in an argon gas atmosphere;
A step of increasing the thickness of the conductive thin film through an electrolytic plating process;
And forming a pattern on at least one thin film of the conductive thin film.
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KR102327261B1 (en) * | 2019-10-22 | 2021-11-17 | 한양대학교 산학협력단 | Insecticide apparatus |
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JP2010033914A (en) * | 2008-07-29 | 2010-02-12 | Kyocera Corp | Dielectric structure, and discharge device and fluid reformer using the same |
JP2013078573A (en) * | 2011-09-21 | 2013-05-02 | Nbc Meshtec Inc | Floating virus removal unit |
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JP2010033914A (en) * | 2008-07-29 | 2010-02-12 | Kyocera Corp | Dielectric structure, and discharge device and fluid reformer using the same |
JP2013078573A (en) * | 2011-09-21 | 2013-05-02 | Nbc Meshtec Inc | Floating virus removal unit |
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