KR101911824B1 - Initial Reaction Control Type Concrete Pavement Composition and Pavement Method Using the Concrete - Google Patents

Initial Reaction Control Type Concrete Pavement Composition and Pavement Method Using the Concrete Download PDF

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KR101911824B1
KR101911824B1 KR1020170144747A KR20170144747A KR101911824B1 KR 101911824 B1 KR101911824 B1 KR 101911824B1 KR 1020170144747 A KR1020170144747 A KR 1020170144747A KR 20170144747 A KR20170144747 A KR 20170144747A KR 101911824 B1 KR101911824 B1 KR 101911824B1
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weight
parts
concrete
magnesia
road pavement
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KR1020170144747A
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Korean (ko)
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박동철
양완희
이정우
황무연
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주식회사 위드엠텍
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/10Lime cements or magnesium oxide cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/06Oxides, Hydroxides
    • C04B22/066Magnesia; Magnesium hydroxide
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/08Acids or salts thereof
    • C04B22/16Acids or salts thereof containing phosphorus in the anion, e.g. phosphates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/12Nitrogen containing compounds organic derivatives of hydrazine
    • C04B24/126Urea
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068Ingredients with a function or property not provided for elsewhere in C04B2103/00
    • C04B2103/0088Compounds chosen for their latent hydraulic characteristics, e.g. pozzuolanes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/60Agents for protection against chemical, physical or biological attack
    • C04B2103/65Water proofers or repellants
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00034Physico-chemical characteristics of the mixtures
    • C04B2111/00068Mortar or concrete mixtures with an unusual water/cement ratio
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00732Uses not provided for elsewhere in C04B2111/00 for soil stabilisation

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention relates to technology for concrete road pavement, and more specifically, to a rapid-hardening ceramic binder composition capable of controlling an initial reaction, which effectively inhibits heat of an initial reaction to enable mass-production and mass-construction and have excellent bonding strength and permeation resistance to salts as well as compressive strength and bending strength, thereby being able to be advantageously used as a binder for a concrete road pavement material; a concrete road pavement material preferably including the composition; and a method for concrete road pavement preferably using the road pavement material. According to the present invention, the rapid-hardening ceramic binder composition capable of controlling an initial reaction comprises: 15-45 parts by weight of phosphate; 1-10 parts by weight of sodium metaphosphate (NaPO_3)_6; 1-10 parts by weight of borate; 10-40 parts by weight of an extender; 0.5-7 parts by weight of urea (CO(NH_2)_2; and 0.3-4 parts by weight of alkali salt, based on 100 parts by weight of water-repellent magnesia wherein the water-repellent magnesia is generated by mixing 100 parts by weight of magnesia with 0.5-5 parts by weight of a water-repellent agent and grinding the mixture in a grinder to have 1,500-3,000 g/cm^2cm^2 of fineness in a mixed state.

Description

초기반응 제어형 콘크리트 도로포장재, 그리고 그 도로포장재를 이용한 콘크리트 도로포장공법{Initial Reaction Control Type Concrete Pavement Composition and Pavement Method Using the Concrete}BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a concrete pavement method and a concrete pavement method,

본 발명은 콘크리트 도로포장 기술에 관한 것으로, 더욱 상세하게는 초기 반응열을 효과적으로 억제하여 대량 생산 및 대량 시공을 가능케 하면서도 압축강도와 휨강도는 물론 부착강도와 염분침투저항성에서 우수한 성능을 발현하여 콘크리트 도로포장재용 결합재로 유리하게 활용할 수 있는 초기반응 제어형 초속경 세라믹 결합재 조성물과, 이를 바람직하게 포함한 콘크리트 도로포장재, 그리고 그 도로포장재를 바람직하게 이용한 콘크리트 도로포장공법에 관한 것이다.The present invention relates to a concrete road pavement technology, and more particularly, to a concrete road pavement technology which effectively suppresses the initial reaction heat to enable mass production and mass construction, and exhibits excellent performance in terms of bond strength and salt penetration resistance as well as compressive strength and bending strength, The present invention relates to an initial reaction-controlled ultra-light ceramic binder composition which can be advantageously used as a refractory binder, a concrete road pavement material preferably containing the same, and a concrete road pavement method using the road pavement material.

시멘트는 경제적이고 우수한 물리적 성능을 나타내므로 여러 종류의 건설 및 산업 분야에 사용되고 있으나, 상대적으로 낮은 초기강도, 동절기 공사 제약, 부피 변화(소성 수축, 자기 수축, 건조 수축 등), C3A의 존재에 따른 내화학성 취약 등이 단점으로 지적된다. Cement is used in many kinds of construction and industrial fields due to its economical and excellent physical properties. However, it has relatively low initial strength, wintertime construction restriction, volume change (plastic shrinkage, autogenous shrinkage and drying shrinkage) And weak chemical resistance.

시멘트를 대체할 수 있는 것으로 인산염계 초속경 세라믹 결합재가 있다. 인산염계 초속경 세라믹 결합재 관련 선행 특허로는 공개특허 제10-2009-0093612호, 등록특허 제10-1187409호, 등록특허 제10-1339584호 등이 있다. 인산염계 초속경 세라믹 결합재는 시멘트 대비 초기강도가 매우 우수할 뿐만 아니라 동절기 공사의 제약이 없고 경화과정에서 부피변화를 수반하지 않는다. 또한 황산염에 취약한 C3A가 존재하지 않으므로 내황산염 및 내화학성도 우수하다. 하지만 기존의 인삼염계 초속경 세라믹 결합재는 초기 경화단계에서 내수성이 취약한 단점이 있으며, 또한 1500℃ 이상에서 과소(dead burn)된 형태의 마그네시아 원료와 인산염 등을 사용하기 때문에 매우 고가인 한계가 있다. 마그네이사 원료가 과소되지 않을 경우 물과 교반시 급격하게 반응하기 때문에 적절한 작업시간을 확보하기 어렵고 충분한 반응을 유도할 수 없다. Phosphate based ceramics binders can replace cement. Prior art patents related to phosphate-based ultra-rapid ceramic binders include Published Applications 10-2009-0093612, Registered Patent No. 10-1187409, and Registered Patent No. 10-1339584. Phosphate based ceramics binders have very good initial strength compared to cement and have no limitations for winter construction and do not involve volume change during curing process. It is also excellent in sulfates and chemical resistance because C3A is not vulnerable to sulfate. However, the conventional ginseng base ceramics ceramics binder has a disadvantage in that the water resistance is poor in the initial curing step, and since it uses dead burned magnesia raw materials and phosphates at a temperature of 1500 ° C or higher, there is a limit in price. If the raw material of the magnet is not underconsumed, it reacts rapidly with stirring with water, so it is difficult to ensure appropriate working time and sufficient reaction can not be induced.

종래 인산염계 초속경 세라믹 결합재의 단점을 개선한 기술로 등록특허 제10-1580991호, 등록특허 제10-1580989호가 있다. 이들 특허에서 제안하는 결합재는 마그네시아를 소수성 발수제와 함께 혼합 분쇄함으로써 마그네시아 표면에 발수제가 분산코팅되게 처리한 상태로 사용하고, 인산염, 메타 인산나트륨, 붕산염, 증량제 등을 적절히 조성한다는데 특징이 있다. 이러한 결합재를 이용하면 압축강도 및 부착강도는 물론, 내수성, 동결융해 저항성, 염소이온 침투저항성에서 우수한 성능을 나타내고, 특히 저온에서도 경화시간이 크게 지연되지 않고 우수한 강도특성을 나타낸다. 그러나 1~3㎥ 이상의 제조할 경우 강한 발열반응에 의해 온도 상승이 크며, 이로 인해 반응이 더욱 촉진되어 적절한 작업시간의 확보는 물론 현장에 시공이 가능한 수준의 유동성 확보가 어렵다는 문제가 있다. 이에 따라 대량 생산 및 대량 시공이 곤란하여 콘크리트 도로포장용으로 활용하기에는 한계가 있다.As a technique for improving the disadvantages of the conventional phosphate based ultra rapid ceramic binder, there are the registered patent No. 10-1580991 and the registered patent No. 10-1580989. The binders proposed in these patents are characterized in that the magnesia is mixed and pulverized together with the hydrophobic water repellent agent so that the surface of the magnesia is dispersedly coated with a water repellent agent, and phosphate, sodium metaphosphate, borate, and an extender are appropriately prepared. When such a binder is used, it exhibits excellent performance in terms of water resistance, freeze-thaw resistance and chlorine ion penetration resistance, as well as compressive strength and adhesion strength, and exhibits excellent strength characteristics without a significant delay in curing time, particularly at low temperatures. However, in case of production of 1 to 3 m < 3 > or more, the temperature rise is large due to a strong exothermic reaction, which further promotes the reaction, thereby making it difficult to ensure appropriate working time and securing fluidity at a level that can be applied on site. As a result, it is difficult to mass-produce and mass-install, and thus it is limited to be used for paving concrete roads.

대한민국등록특허 제10-1580991호Korean Patent No. 10-1580991 대한민국등록특허 제10-1580989호Korean Patent No. 10-1580989

본 발명은 종래 초속경 세라믹 결합재의 단점을 개선하고자 개발된 것으로서, 초기 반응열을 효과적으로 억제하여 대량 생산 및 대량 시공을 가능케 하면서도 압축강도와 휨강도는 물론 부착강도와 염분침투저항성에서 우수한 성능을 발현하여 콘크리트 도로포장재용 결합재로 유리하게 활용할 수 있는 초기반응 제어형 초속경 세라믹 결합재 조성물을 제공하는데 기술적 과제가 있다.The present invention has been developed to improve the disadvantages of the conventional rapid ceramic binder and is capable of effectively suppressing the initial reaction heat to enable mass production and large-scale construction, and exhibits excellent performance in terms of the bonding strength and the salt permeation resistance as well as the compressive strength and bending strength, There is a technical problem in providing an initial reaction-controlled ultra-rapid ceramic binder composition which can be advantageously used as a binder for road paving materials.

또한 본 발명은 초기반응 제어형 초속경 세라믹 결합재 조성물을 이용하여 바람직하게 배합설계한 콘크리트 도로포장재와 이 도로포장재를 바람직하게 이용한 콘크리트 도로포장공법 내지 콘크리트 도로포장 보수공법을 제공하고자 한다.Also, the present invention provides a concrete road paving material suitably blended with an initial reaction-controlled ultra-rapid ceramic binder composition, and a concrete road pavement method or a concrete pavement repairing method using the pavement material.

상기한 기술적 과제를 해결하기 위해 본 발명은 발수 마그네시아 100중량부에 대하여, 인산2수소칼륨(KH2PO4), 인산2수소나트륨(NaH2PO4), 인산수소2암모늄((NH4)2HPO4), 인산2수소암모늄(NH4H2PO4) 중에서 하나 이상 선택된 인산염 15~45중량부; 메타인산나트륨(NaPO3)6 1~10중량부; 붕산(H3BO3), 붕사(Na2B4O7·10H2O) 중에서 하나 이상 선택된 붕산염 1~10중량부; 포졸란 분말, 광물성 분말 중에서 하나 이상 선택된 증량제 10~40중량부; 우레아(CO(NH2)2) 0.5~7중량부; 알칼리염 0.3~4중량부;를 포함하여 조성되되, 상기 발수 마그네시아는, 마그네시아 100중량부에 발수제 0.5~5중량부를 분쇄기에서 혼합 분쇄되어 혼합된 상태에서 1500~3000g/㎠의 분말도를 가지도록 처리된 것임을 특징으로 하는 초기반응 제어형 초속경 세라믹 결합재 조성물을 제공한다.(KH 2 PO 4 ), sodium dihydrogenphosphate (NaH 2 PO 4 ), ammonium dihydrogenphosphate ((NH 4 ) 2), and the like are added to 100 parts by weight of water repellent magnesia. 2 HPO 4 ) and ammonium dihydrogen phosphate (NH 4 H 2 PO 4 ); Sodium metaphosphate (NaPO 3 ) 6 1 to 10 parts by weight; 1 to 10 parts by weight of a borate selected from boric acid (H 3 BO 3 ) and borax (Na 2 B 4 O 7 · 10H 2 O); 10 to 40 parts by weight of an extender selected from at least one of a pozzolana powder and a mineral powder; 0.5 to 7 parts by weight of urea (CO (NH 2 ) 2 ); 0.3 to 4 parts by weight of an alkali salt, wherein the water repellent magnesia is prepared by mixing 100 parts by weight of magnesia with 0.5 to 5 parts by weight of a water repellent agent in a pulverizer so as to have a powdery viscosity of 1500 to 3000 g / Wherein the initial reaction-controlled ultra-light ceramic binder composition has an initial reaction-controlled ultra-light ceramic binder composition.

또한 본 발명은 상기 초기반응 제어형 초속경 세라믹 결합재 조성물을 이용한 콘크리트 도로포장재 배합에서, 결합재(B) 380~600kg/㎥; 잔골재율(S/a) 45~55중량%; 물결합재비(W/B) 20~24중량%; 굵은골재 최대치수 10~25mm; 슬럼프 150~220mm;로 배합 설계되는 것을 특징으로 하는 콘크리트 도로포장재를 제공한다.In addition, the present invention relates to a method for preparing a concrete road pavement using the above-mentioned initial reaction-controlled ultra-rapid ceramic binder composition, wherein the binder (B) Fine aggregate ratio (S / a) of 45 to 55% by weight; Water binding ratio (W / B) of 20 to 24% by weight; Largest aggregate size 10 ~ 25mm; And a slump of 150 to 220 mm.

나아가 본 발명은 도로의 기층 위로 상기 콘크리트 도로포장재를 포설하는 것을 특징으로 하는 콘크리트 도로포장공법 또는 콘크리트 포장도로에서 콘크리트 포장면의 열화부분을 제거하여 청소한 후 상기 콘크리트 도로포장재를 포설하여 마무리하는 것을 특징으로 하는 콘크리트 도로포장 보수공법를 제공한다.Further, the present invention is characterized in that the concrete road pavement material is laid on the base layer of the road, or the concrete road pavement method or the concrete pavement road is cleaned by removing the deteriorated portion of the concrete pavement surface, It provides a concrete road pavement maintenance method which is characterized by.

본 발명에 따르면 다음과 같은 효과를 기대할 수 있다.According to the present invention, the following effects can be expected.

첫째, 본 발명에 따른 초속경 세라믹 결합재와 콘크리트 도로포장재는 초기 반응열을 효과적으로 억제할 수 있기 때문에 적절한 작업시간을 확보할 수 있어 대량 생산 및 대량 시공이 가능하여 현장에서 유리하게 적용할 수 있다. 그뿐만 아니라 조기에 초기강도를 확보할 수 있어 양생공정을 생략하면서 긴급공사에 유리하게 적용할 수 있다. 따라서 본 발명은 부분적인 도로포장의 보수공사는 물론 도로 전체에 걸친 포장공사에도 활용할 수 있다.First, since the ultra rapid ceramic binder and the concrete roadway pavement material according to the present invention can effectively suppress the initial reaction heat, it is possible to secure a proper working time, and mass production and mass construction are possible, which can be advantageously applied in the field. In addition to that, the initial strength can be secured early, so that the curing process can be omitted and it can be advantageously applied to emergency work. Therefore, the present invention can be utilized not only for repairing partial road pavement but also for pavement construction over the entire road.

둘째, 본 발명에 따른 초속경 세라믹 결합재와 콘크리트 도로포장재는 압축강도와 휨강도는 물론 부착강도와 염분침투저항성에서 우수한 성능을 발현하기 때문에 우수한 내구성을 확보할 수 있다.Second, the ultra rapid ceramic binder and concrete road pavement according to the present invention exhibit excellent durability because they exhibit excellent performance in terms of compressive strength and bending strength, as well as bond strength and salt penetration resistance.

도 1은 본 발명에 따른 콘크리트 도로포장 보수공법에 대한 시공순서도이다.1 is a view showing a construction procedure of a concrete road pavement repairing method according to the present invention.

본 발명은 결합재로 발수 마그네시아와 인산염을 주요 재료로 하는 초속경 세라믹 결합재에 관한 것으로, 초기 반응열을 효과적으로 억제할 수 있도록 우레아와 알칼리염을 더 포함하여 조성한다는데 특징이 있다. 이로써 본 발명의 초속경 세라믹 결합재 조성물은 적절한 작업시간을 확보하여 대량 생산 및 대량 시공이 가능해진다.The present invention relates to a ultra rapid ceramic binder having a water-repellent magnesia and a phosphate as a binder, and is characterized in that it further comprises urea and an alkali salt so as to effectively suppress the initial reaction heat. As a result, the ultra rapid ceramic binder composition of the present invention can be mass-produced and mass-produced by securing a suitable working time.

구체적으로 본 발명에 따른 초기반응 제어형 초속경 세라믹 결합재 조성물은, 발수 마그네시아 100중량부에 대하여, 인산염 15~45중량부; 메타 인산나트륨(NaPO3)6 1~10중량부; 붕산염 1~10중량부; 증량제 10~40중량부; 우레아(CO(NH2)2) 0.5~7중량부; 알칼리염 0.3~4중량부;를 포함하여 조성되는 것을 특징으로 한다. Specifically, the initial reaction-controlled ultra-rapid ceramic binder composition according to the present invention is characterized in that 15 to 45 parts by weight of a phosphate is added to 100 parts by weight of water repellent magnesia; Sodium metaphosphate (NaPO 3 ) 6 1 to 10 parts by weight; 1 to 10 parts by weight of a borate; 10 to 40 parts by weight of an extender; 0.5 to 7 parts by weight of urea (CO (NH 2 ) 2 ); And 0.3 to 4 parts by weight of an alkali salt.

본 발명에서 발수 마그네시아는, 마그네시아 100중량부에 발수제 0.5~5중량부를 분쇄기에서 혼합 분쇄되어 혼합된 상태에서 1500~3000g/㎠의 분말도를 가지도록 처리된 것이다. 여기서 마그네시아는 MgO, MgO·CaO 중 어느 하나 이상의 형태로 준비하면 되며, 다만 MgO+CaO > 97중량%이고, MgO/CaO(중량비) > 2.5 이상인 것이 바람직하다. 특히 마그네시아는 탄산마그네슘(MgCO3)이나 돌로마이트(CaMg(CO3)2)를 1100~1350℃ 범위에서 소성하여 수급하면 적당한데, 소성온도가 1100℃ 이하이면 물과 혼합시 급격하게 반응하여 충분하게 경화하지 못하고, 1350℃ 이상일 경우 경제성을 상실한다. 다만 1100~1200℃의 소성온도는 다소 낮으므로 소성시간을 최소 3H 이상(바람직하게는 6H 이상) 확보하는 것이 유리하다.In the present invention, the water repellent magnesia is prepared by mixing 0.5 to 5 parts by weight of water repellent with 100 parts by weight of magnesia in a pulverizer to obtain a powder having a particle size of 1500 to 3000 g / cm < 2 > In this case, the magnesia may be prepared in any one or more of MgO, MgO and CaO, but it is preferable that MgO + CaO is more than 97% by weight and MgO / CaO (weight ratio) is more than 2.5. Particularly, magnesia is suitable when firing magnesium carbonate (MgCO 3 ) or dolomite (CaMg (CO 3 ) 2 ) in the range of 1100 to 1350 ° C and supplying it. When the firing temperature is 1100 ° C or less, If it is not cured, and it is over 1350 ℃, economical efficiency is lost. However, since the firing temperature at 1100 to 1200 ° C is somewhat low, it is advantageous to secure the firing time at least 3H or more (preferably 6H or more).

발수 마그네시아에서 발수제는 발수효과 발현을 통해 마그네시아의 급격한 반응을 억제하는 역할을 하며, 왁스에멀젼, 칼슘스테아레이트, 알루미늄스테아레이트 중에서 하나 이상 선택하여 사용한다. 통상 사용하는 발수제 중에서 시멘트 수화물과 반응하여 발수효과를 나타내는 스테아린산, 올레익산 등은 부적합하다.In water repellent magnesia, the water repellent agent suppresses the sudden reaction of magnesia through the manifestation of water repellent effect, and at least one of wax emulsion, calcium stearate, and aluminum stearate is selected and used. Among commonly used water repellent agents, stearic acid and oleic acid, which react with cement hydrate and exhibit a water repellent effect, are unsuitable.

발수 마그네시아는 마그네시아 100중량부에 발수제 0.5~5중량부를 분쇄기(볼밀/진동밀 등)에서 혼합 분쇄하여 준비한다. 발수제가 0.5중량부 미만이면 발수효과가 부족하고 적절한 작업시간 확보가 곤란하며, 발수제가 5중량부 초과하면 과도한 발수로 충부한 반응 유도가 곤란하여 강도발현이 부족해진다. 혼합 분쇄에 따라 발수제가 마그네시아 표면에 적절히 분산 코팅되게 함으로써 발수효과를 극대화시킬 수 있다. 마그네시아는 이미 분쇄된 미분말 형태는 물론 분쇄전 클링커 형태도 가능하며, 다만 마그네시아 클링커는 5mm 통과분의 입도를 갖는 것이 적당한데 입도가 너무 크면 발수제가 마그네시아의 표면에 분산 코팅되는 효율이 저하된다. 혼합 분쇄 조건(분쇄 시간, 방법, 분쇄 메디아 등)은 발수 마그네시아의 분말도가 1500~3000g/㎠의 범위가 되도록 적절히 조정하면 되며, 분말도가 너무 크면 적절한 작업시간 확보가 곤란하고 분말도가 너무 작으면 초기 강도 확보가 곤란하다. Water repellent magnesia is prepared by mixing and pulverizing 100 parts by weight of magnesia with 0.5 to 5 parts by weight of a water repellent agent in a pulverizer (ball mill / vibrating mill or the like). If the water repellent agent is less than 0.5 part by weight, the water repellency effect is insufficient and it is difficult to secure a proper working time. If the water repellent agent is more than 5 parts by weight, it is difficult to induce the reaction with excessive water repellency. The water repellent agent is appropriately dispersed and coated on the surface of the magnesia according to the mixed pulverization, thereby maximizing the water repellent effect. The magnesia may be in the form of a pulverized fine powder as well as a pre-milled clinker. However, it is appropriate that the magnesia clinker has a particle size of 5 mm. If the particle size is too large, the efficiency of dispersing and coating the water repellent agent on the surface of the magnesia is lowered. The powder milling condition (milling time, method, pulverizing media, etc.) can be suitably adjusted so that the water repellency of the water repellent magnesia is in the range of 1500-3000 g / cm 2. If the powdering degree is too large, It is difficult to secure initial strength.

초속경 세라믹 결합재에서 인산염은 마그네시아와 함께 수화반응하여 경화하는 주요한 재료인데, 인산2수소칼륨(KH2PO4), 인산2수소나트륨(NaH2PO4), 인산수소2암모늄((NH4)2HPO4), 인산2수소암모늄(NH4H2PO4) 중에서 하나 이상 선택한다. 이들 인산염은 마그네시아와 함께 아래와 같은 반응식으로 수화반응을 한다.Zinnia light inde major material which is cured by hydration reaction with phosphate magnesia in the ceramic binder, 2 potassium dihydrogenphosphate (KH 2 PO 4), dihydrogen phosphate, sodium (NaH 2 PO 4), dibasic ammonium ((NH 4) 2 HPO 4 ) and ammonium dihydrogen phosphate (NH 4 H 2 PO 4 ). These phosphates react with the magnesia in a hydration reaction as follows.

MgO + 2(NH4)H2PO4 + 3H2O -> Mg(NH4)2(HPO4)2·4H2OMgO + 2 (NH 4 ) H 2 PO 4 + 3H 2 O -> Mg (NH 4 ) 2 (HPO 4 ) 2 .4H 2 O

MgO + (NH4)2HPO4 + 5H2O -> MgNH4PO4·6H2O + NH3 MgO + (NH 4 ) 2 HPO 4 + 5H 2 O -> MgNH 4 PO 4 .6H 2 O + NH 3

MgO + KH2PO4 + 5H2O -> MgKPO4·6H2OMgO + KH 2 PO 4 + 5H 2 O -> MgKPO 4 .6H 2 O

MgO + NaH2PO4 + 5H2O -> MgNaPO4·6H2OMgO + NaH 2 PO 4 + 5H 2 O -> MgNaPO 4 .6H 2 O

초속경 세라믹 결합재에서 인산염은 발수 마그네시아 100중량부에 대하여 15~45중량부를 사용하는 것이 바람직하다. 인산염이 15중량부 미만이면 적절한 반응을 유도하지 못하여 초기에 높은 강도를 확보할 수 없게 되며, 45중량부 초과하면 발열이 심하고 작업시간을 확보할 수 없다. 한편 인산염 중 인산2수소칼륨과 인산2수소나트륨은 반응성이 좋으나 발열이 심한데 반해, 인산수소2암모늄과 인산2수소암모늄은 발열은 다소 낮으나 암모니아 가스의 발생으로 악취가 발생하는 특성이 있다. 이에 따라 인산2수소칼륨과 인산2수소나트륨 중 하나 이상에 의한 제1인산염과 인산수소2암모늄과 인산2수소암모늄 중 하나 이상에 의한 제2인산염을 혼합하여 사용하는 것이 바람직하다. 다만 과도한 발열의 억제와 악취발생 회피를 위하여 바람직하게는 제1인산염 70~90중량%; 제2인산염 10~30중량%;로 조성하는 것이 바람직하다. It is preferable that 15 to 45 parts by weight of phosphate is used in the ultra rapid ceramic binder in 100 parts by weight of water repellent magnesia. When the amount of the phosphate is less than 15 parts by weight, an appropriate reaction can not be induced, so that high strength can not be secured at an early stage. If the amount is more than 45 parts by weight, heat generation is severe and the working time can not be secured. On the other hand, potassium dihydrogenphosphate and sodium dihydrogenphosphate in phosphates are good in reactivity but have a high heat generation. On the other hand, ammonium dihydrogenphosphate and ammonium dihydrogenphosphate have a characteristic that the generation of odor is generated due to the generation of ammonia gas. Accordingly, it is preferable to use a mixture of a first phosphate by at least one of potassium dihydrogenphosphate and sodium dihydrogen phosphate, and a second phosphate by at least one of ammonium dihydrogenphosphate and ammonium dihydrogenphosphate. However, in order to suppress excessive heat generation and to prevent odor generation, 70 to 90% by weight of the primary phosphate is preferably used. 10 to 30% by weight of a second phosphate;

초속경 세라믹 결합재에서 메타 인산나트륨(NaPO3)6은 마그네시아와의 반응에서 발열을 억제하여 적절한 작업시간 확보에 기여하고, 더불어 경화체의 강도 증진에도 기여한다. 메타 인산나트륨은 발수 마그네시아 100중량부에 대하여 1~10중량부 범위에서 인산염의 5중량% 이상으로 사용하는 것이 바람직하다. 메타 인산나트륨의 사용량이 너무 적으면 작업시간의 확보 효과가 미미하며, 너무 많으면 반응지연 효과가 더 이상 개선되지 않아 경제성이 상실된다.Sodium metaphosphate (NaPO 3 ) 6 in ultra rapid ceramic binders suppresses heat generation in the reaction with magnesia, contributes to ensuring proper working time, and also contributes to the strength of the cured product. The sodium metaphosphate is preferably used in an amount of 1 to 10 parts by weight based on 100 parts by weight of the water-repellent magnesia in an amount of 5% by weight or more based on the phosphate. If the amount of sodium metaphosphate used is too small, the effect of securing the working time is insignificant. If the amount is too much, the reaction delay effect is not further improved and the economical efficiency is lost.

초속경 세라믹 결합재에서 붕산염은 반응의 지연으로 적절한 작업시간의 확보에 기여하는 재료가 된다. 붕산염으로는 붕산(Boric acid, H3BO3), 붕사(Borax, Na2B4O7·10H2O) 중에서 하나 이상 선택하면 적당하다. 붕산염은 발수 마그네시아 100중량부에 대하여 1~10중량부 범위에서 인산염의 0.1중량% 이상으로 사용하는 것이 바람직한데, 너무 적으면 반응지연 효과가 없고 너무 많으면 반응지연 효과가 더 이상 개선되지 않아 경제성이 상실된다. Borate is a material that contributes to ensuring proper working time due to the delay of reaction in the ceramics binder. It is appropriate to select one or more of boric acid (Boric acid, H 3 BO 3 ) and borax (Borax, Na 2 B 4 O 7 · 10H 2 O). The borate is preferably used in an amount of 0.1 wt% or more of the phosphate in the range of 1 to 10 parts by weight based on 100 parts by weight of the water-repellent magnesia. If the borate is too small, the reaction delay effect does not exist. Is lost.

초속경 세라믹 결합재에서 증량제는 증량 효과를 위한 필러(Filler)가 되는데, 석탄회나 메타카올린과 같은 포졸란 분말이나, 석회석 미분말 등의 광물성 분말이 적당하다. 특히 포졸란 분말은 반응성 증량제로써 단순히 증량효과뿐만 아니라 재령 1일 이후의 강도증진에도 효과가 있다. 증량제는 발수 마그네시아 100중량부에 대하여 10~40중량부 범위에서 사용하는 것이 바람직하다. In the ceramics binders with a very high initial speed, the expanding agent becomes a filler for the increasing effect, and a pozzolan powder such as fly ash or meta kaolin, or a mineral powder such as a limestone fine powder is suitable. In particular, pozzolan powder is effective as a reactive extender, not only for increasing effect but also for improving strength after 1 day of age. The amount of the extender is preferably in the range of 10 to 40 parts by weight based on 100 parts by weight of the water-repellent magnesia.

초속경 세라믹 결합재에서 우레아(CO(NH2)2)는 반응열의 상승을 억제하여 적절한 작업시간의 확보를 가능하게 하고, 또한 분산 및 유동성 개선에도 역할한다. 우레아는 발수 마그네시아 100중량부에 대하여 0.5~ 7.0중량부가 바람직한데, 너무 소량이면 효과가 미미하고, 7중량부를 초과하면 초기강도가 크게 저하한다.Urea (CO (NH 2 ) 2 ) in the ultra rapid ceramic binder suppresses the rise of the reaction heat, thereby ensuring an appropriate working time, and also serves to improve dispersion and fluidity. The urea is preferably 0.5 to 7.0 parts by weight based on 100 parts by weight of the water-repellent magnesia. If the amount is too small, the effect is insignificant. If the amount is more than 7 parts by weight, the initial strength is greatly reduced.

초속경 세라믹 결합재에서 알칼리염(Alkali salt)은 산성환경을 억제하여 촉박한 경화를 완화함으로써 작업시간의 확보와 유동성 확보에 역할한다. 알칼리염은 황산칼륨(K2SO4), 황산나트륨(Na2SO4)가 경제적이고 효과적이다. 알칼리염은 발수 마그네시아 100중량부에 대하여 0.3~4.0중량부가 바람직하며, 너무 소량이면 효과가 미미하고 4중량부를 초과하면 초기 경화가 지연되고 강도성능이 저하될 뿐만 아니라 경화 후 백화 현상이 심화한다. Alkali salt (Alkali salt) in ultra fast ceramic binders plays a role in securing the working time and securing the fluidity by suppressing the acid environment and alleviating the hardening hardening. Potassium sulphate (K 2 SO 4 ) and sodium sulphate (Na 2 SO 4 ) are economical and effective. The alkali salt is preferably 0.3 to 4.0 parts by weight based on 100 parts by weight of the water repellent magnesia. If the amount is too small, the effect is insignificant. If the amount is more than 4 parts by weight, the initial curing is delayed and the strength performance is deteriorated.

위와 같은 구성의 초속경 세라믹 결합재는 일반 시멘트와 마찬가지로 페이스트(물과 혼합), 모르타르(잔골재, 물과 혼합), 콘크리트(잔골재, 굵은 골재, 물과 혼합)로 이용할 수 있다. 다만 본 발명에서는 대량 생산 및 대량 시공의 콘크리트 도로포장재로 바람직하게 이용하기 위해, 초속경 세라믹 결합재(B) 380~600kg/㎥; 잔골재율(S/a) 45~55중량%; 물결합재비(W/B) 20~24중량%; 굵은골재 최대치수 10~25mm; 슬럼프 150~220mm;로 배합설계할 것을 제안한다. 이와 같은 콘크리트 도로포장재 배합에서 초속경 세라믹 결합재(B)는 단위재료량이 380kg/㎥ 미만이면 적절한 성능의 확보가 곤란하고, 600kg/㎥ 초과하면 경제성을 상실한다. 잔골재율(S/a)은 45중량% 미만이면 굵은 골재가 지나치게 많아 작업성이 불량해지고 표면에 거칠어지며, 55중량% 초과하면 혼합수가 과도하게 소요되어 강도성능 등 물리적 성능이 하락한다. 물결합재비(W/B)는 20중량% 초과하면 경우 작업성 확보가 곤란하고, 24중량% 초과하면 과도한 혼합수량의 투입으로 강도성능이 급격히 저하한다. 굵은골재 최대치수는 통상의 골재 범위이 되나 작업성 향상을 고려하면 가급적 작은 치수가 적절하다. 슬럼프는 150mm 초과하면 신속한 작업성 확보가 곤란하고, 220mm 초과하면 과도한 혼합수량의 투입으로 강도성능이 급격히 저하한다.Ceramic binder with the above-mentioned composition can be used as paste (mixed with water), mortar (mixed with fine aggregate, water), concrete (mixed with fine aggregate, coarse aggregate, water) However, in order to suitably use it as a concrete road pavement material for mass production and large-scale construction, the present invention is characterized in that it comprises 380 to 600 kg / m < 3 > Fine aggregate ratio (S / a) of 45 to 55% by weight; Water binding ratio (W / B) of 20 to 24% by weight; Largest aggregate size 10 ~ 25mm; It is suggested to formulate slump with 150 ~ 220mm; In the case of such a concrete road pavement material, it is difficult to obtain appropriate performance if the unit material amount is less than 380 kg / m 3, and the economic efficiency is lost if the unit material amount exceeds 600 kg / m 3. When the amount of fine aggregate (S / a) is less than 45% by weight, the amount of coarse aggregate is excessively large, resulting in poor workability and roughness on the surface. When the amount exceeds 55% by weight, excessive mixing water is required. When the water-binding ratio (W / B) is more than 20% by weight, it is difficult to secure workability. When the water-binding ratio is more than 24% by weight, The maximum size of coarse aggregate is usually in the range of aggregate, but a smaller size is suitable as far as improvement of workability is considered. When the slump is more than 150 mm, it is difficult to ensure quick workability. When the slump is more than 220 mm, the strength performance sharply drops due to an excessive amount of mixing.

위와 같이 배합설계되는 콘크리트 도로포장재는 아래 [시험예2,3)에서와 같이 압축강도, 휨강도, 부착강도, 염분침투저항성, 길이변화에서 우수한 성능을 발휘하기 때문에 콘크리트 도로포장공법에 유리하게 적용할 수 있다. 특히 상당히 빨리(3hr) 요구강도의 발현이 가능하므로 콘크리트 도로포장을 새로 하거나 기존의 포장도로를 보수하는 경우에는 수시간 내에 공사진행하여 신속하게 도로를 개통할 수 있다. 콘크리트 신설 도로포장은 통상적인 방법과 마찬가지로 도로 기층 위로 콘크리트 도로포장재를 포설하면서 진행하면 된다. 기존 콘크리트 포장도로의 보수는 도 1과 같이 수행하는데, 콘크리트 포장면을 절삭하여 열화부분을 제거하여 청소한 후 도로포장재를 포설하여 마무리(피니셔, 타이닝 등)하면서 진행한다. The concrete road pavement material having the above composition is advantageously applied to the concrete road pavement method because it exhibits excellent performance in compressive strength, bending strength, adhesion strength, salt penetration resistance and length change as in the following [Test Examples 2 and 3] . Especially, it is possible to express the required strength very quickly (3hr), so that when the concrete pavement is re-packed or the existing pavement is repaired, the construction can be started within a few hours and the road can be opened quickly. Concrete new road pavement can be carried out by laying concrete pavement material on the road base like the usual way. The repair of existing concrete pavement is performed as shown in Fig. 1, and the concrete pavement is cut to remove the deteriorated parts, and then the road pavement is laid and finishing (finisher, tinning, etc.) is performed.

이하에서는 시험예에 의거하여 본 발명을 상세히 살펴본다. 다만, 아래의 시험예는 본 발명을 예시하기 위한 것일 뿐이며, 본 발명의 범위가 이로써 한정되는 것은 아니다.Hereinafter, the present invention will be described in detail based on a test example. However, the following test examples are only for illustrating the present invention, and the scope of the present invention is not limited thereto.

[[ 시험예1Test Example 1 ] ] 초속경Fast speed 세라믹  ceramic 결합재Binders

1. 초속경 세라믹 결합재 조성1. Ceramic binder composition

아래 [표 1]과 같은 재료 구성으로 초속경 세라믹 결합재를 준비하였다.The ceramic fasteners were prepared as shown in Table 1 below.

초속경 세라믹 결합재의 재료 구성(중량부)Material composition (parts by weight) 구분division 비교예Comparative Example 실시예Example 비고Remarks 발수 마그네시아Water repellent magnesia 100100 100100 마그네시아(MgO 97.5% 1300℃ 3H 소성) 97중량%와 발수제(칼슘스테아레이트) 3중량%의 조성물을 볼밀에서 30분 혼합 분쇄.
분말도 2,350cm2/g
97% by weight of magnesia (MgO 97.5% 1300 ° C 3H calcination) and 3% by weight of a water repellent agent (calcium stearate) were mixed and milled in a ball mill for 30 minutes.
The powder also has a density of 2,350 cm <
인산염phosphate 3535 3535 인산2수소칼륨:인산2수소암모늄
= 8:2(중량비)
Potassium dihydrogen phosphate: ammonium dihydrogen phosphate
= 8: 2 (weight ratio)
메타 인산나트륨Sodium metaphosphate 77 77 -- 붕산염Borate 1111 1111 -- 반응성 증량제Reactive extender 28 28 2828 석탄회: 비중 2.23, 분말도 3450cm2/g
Fly Ash: specific gravity 2.23, powder 3450 cm2 / g
우레아Urea -- 3.53.5 화학식 CO(NH2)2 , 비중 1.335,
NITROGEN CONTENT > 46중량%, IRON < 1ppm, MOISTURE < 0.5중량%, FREE AMMONIA < 150ppm
Formula CO (NH 2) 2, specific gravity 1.335,
NITROGEN CONTENT> 46 wt%, IRON <1 ppm, MOISTURE <0.5 wt%, FREE AMMONIA <150 ppm
알칼리염Alkaline salt -- 1.51.5 황산나트륨(Na2SO4): 비중 2.69,
함량 > 99중량%, 불용분 < 0.05중량%
Sodium sulfate (Na 2 SO 4 ): specific gravity 2.69,
A content of > 99 wt%, an insoluble content of < 0.05 wt%

2. 모르타르 배합 2. Mortar formulation

위 [표 1]과 같은 조성으로 준비한 결합재를 가지고 아래 [표 2]와 같은 조건으로 모르타르를 배합하였다. The mortar was compounded with the binder prepared in the same composition as the above [Table 1] under the conditions as shown in Table 2 below.

모르타르 배합Mortar combination 구분division 비교예/실시예Comparative Example / Example 골재비Aggregate rain 결합재 : 표준사 = 1:1(중량비)Binder material: standard yarn = 1: 1 (weight ratio) 혼합수Mixed water 혼합수 / 결합재 = 14중량%Mixed water / binder = 14 wt%

3. 모르타르 특성3. Mortar characteristics

위 [표 2]에 따른 모르타르에 대하여 유동성, 경화시간, 재령별 압축강도, 길이변화를 시험하였다. 유동성 시험은 KS L 5105에 의한 플로우 시험으로 실시하여 원지름을 mm로 표시하였고, 압축강도 시험은 KS F 2403에 따라 시험체를 제작하여 KS F 2405에 따라 실시하였다. 길이변화 시험은 40×40×160mm 시험체를 제작하여 부착형 스트레인게이지를 부착하고 20±2℃, 상대습도 60±5%의 항온항습실에서 56일간 연속하여 측정하였다. 시험 결과는 아래 [표 3]과 같다.The flowability, curing time, compressive strength and length variation at different ages were tested for the mortar according to Table 2 above. The fluidity test was carried out by the flow test according to KS L 5105 and the circle diameter was expressed in mm. The compressive strength test was carried out in accordance with KS F 2405 by preparing a specimen according to KS F 2403. A 40 × 40 × 160 mm test specimen was prepared, and attached strain strain gage was attached and measured continuously for 56 days in a temperature and humidity chamber at 20 ± 2 ° C and a relative humidity of 60 ± 5%. The test results are shown in [Table 3] below.

모르타르 성능Mortar performance 구분division 비교예Comparative Example 실시예Example 유동성(Flow)(mm)Flow (mm) 160mm160mm 225mm225mm 경화시간(초결기준)Curing time (based on initials) 8분8 minutes 21분21 minutes 발열온도(1H)Heating temperature (1H) 4545 3434 발열온도(3H)Heating temperature (3H) 6363 5656 강도(MPa)Strength (MPa) 2 시간 2 hours 3838 2828 4 시간4 hours 4343 3737 1일1 day 5656 5757 3일3 days 7878 7676 7일7 days 8686 9191

위의 [표 3]에서와 같이 실시예는 비교예와 비교할 때, 초기 반응열이 억제되고 경화시간도 지연되며 유동성도 향상될 뿐만 아니라 4시간 이후의 강도에서는 다시 회복되는 현상을 나타냈다.As shown in the above [Table 3], the initial reaction heat was suppressed, the curing time was delayed and the fluidity was improved as compared with the comparative example, and the phenomenon was recovered again at the strength after 4 hours.

[[ 시험예2Test Example 2 ] 콘크리트 도로포장재] Concrete road packaging material

1. 콘크리트 도로포장재 배합1. Concrete road packaging material formulation

위의 [표 1]의 초속경 세라믹 결합재를 이용하여 아래 [표 4]와 같은 조성으로 모르타르를 배합하였다. 포틀랜드 시멘트계 초속경 시멘트 중 가장 널리 알려진 CSA(칼슘설포알루미네이트)계 초속경 시멘트를 비교예로 하고 본 발명에 따른 초속경 세라믹 결합재를 실시예1,2로 하여 성능을 비교하였다.The mortar was compounded with the composition as shown in Table 4 below using the ceramics binder of initial speed [Table 1] above. The most rapidly known CSA (calcium sulfoaluminate) based ultra rapid cement among portland cement based fast curing cement was compared and the performance of the ultra rapid ceramic binder according to the present invention was compared with the first and second embodiments.

콘크리트 도로포장재 배합Concrete road packaging material combination 구 분division 굵은골재
최대치수
(mm)
Coarse aggregate
Maximum dimensions
(mm)
물결합재비
(W/C)(%)
Water coupling ratio
(W / C) (%)
잔골재율
S/a(%)
Fine aggregate rate
S / a (%)
단위량(kg/m³)Unit quantity (kg / m³)
물(W)Water (W) CSA계
초속경
시멘트
CSA system
Fast speed
cement
[표 1]의 실시예Examples of [Table 1] 잔골재
(S)
Fine aggregate
(S)
굵은골재
(G)
Coarse aggregate
(G)
라텍스Latex
비교예Comparative Example 1919 3838 5454 7676 360360 -- 906906 783783 115115 실시예1Example 1 1313 2222 5252 119119 -- 540540 844844 794794 -- 실시예2Example 2 1313 2323 5050 110110 -- 480480 864864 880880 --

2. 콘크리트 도로포장재 성능2. Performance of concrete road pavement material

위 [표 4]의 콘크리트 도로포장재에 대하여 유동성, 재령별 압축강도/휨강도/부착강도, 염분침투저항성에 대해 시험하였다. 시험 결과는 아래 [표 5]와 같이 나타냈다.For the concrete road pavement in Table 4, fluidity, compressive strength / bending strength / bond strength, and salt penetration resistance according to ages were tested. The test results are shown in Table 5 below.

콘크리트 도로포장재의 성능Performance of concrete roadway packaging material 구 분division 실시예1Example 1 실시예2Example 2 비교예Comparative Example 도로공사 시방기준Standard of road construction specification 슬럼프(mm)Slump (mm) 200200 210210 190190 160~220160 ~ 220 공기량(%)Air volume (%) 4.94.9 4.14.1 4.34.3 3~6%3 to 6% 압축강도
(MPa)
Compressive strength
(MPa)
3hr3hr 28.228.2 23.623.6 -- 21MPa 이상
(개방시간기준)
21 MPa or more
(Based on opening time)
4hr4hr -- -- 23.123.1 7일7 days 36.936.9 31.231.2 28.328.3 28일28th 49.349.3 40.240.2 35.835.8 휨강도(MPa)Flexural strength (MPa) 3hr3hr 4.74.7 4.14.1 -- 3.15MPa 이상
(개방시간기준)
3.15MPa or more
(Based on opening time)
4hr4hr -- -- 3.73.7 7일7 days 7.27.2 5.85.8 4.64.6 28일28th 9.89.8 8.78.7 7.87.8 부착강도(MPa)Bond strength (MPa) 3hr3hr 2.42.4 1.91.9 -- 1.4Mpa 이상
(개방시간기준)
1.4Mpa or more
(Based on opening time)
4hr4hr -- -- 1.51.5 7일7 days 2.62.6 2.42.4 1.61.6 28일28th 3.23.2 2.92.9 1.61.6 염분침투저항성Salt penetration resistance 7일7 days 322322 387387 14201420 1000 쿨롱 이하Below 1000 Coulombs

위의 [표 5]에서와 같이 유동성과 압축강도/휨강도/부착강도는 비교예와 실시예1,2 모두 도로공사 시방기준을 만족하는 것으로 확인되며, 특히 압축강도/휨강도/부착강도는 실시예1,2가 비교예보다 더욱 빨리(3hr) 개방시간 기준 이상의 강도발현이 이루어지는 것으로 확인된다. 염분침투저항성은 비교예의 경우 도로공사 시방기준을 만족하지 못했으나, 실시예1,2는 도로공사 시방기준을 우수한 수준으로 만족하는 것으로 확인된다.As shown in [Table 5], it was confirmed that the comparative example and examples 1 and 2 satisfied the road construction specifications, and the compressive strength / flexural strength / 1 and 2 exhibited a strength of more than the open time reference (3 hr) faster than the comparative example. In the comparative example, the salt penetration resistance did not satisfy the road construction specification standard, but in Examples 1 and 2, it is confirmed that the road construction specification criterion satisfies the excellent level.

[[ 시험예3Test Example 3 ] 현장적용 특성] Field application characteristics

1. 현장 생산1. Field production

아래 [표 6]과 같은 배합으로 콘크리트 도로포장재를 3㎥ 연속 생산하였다.The concrete road pavement was produced in the same manner as in [Table 6].

현장 생산 배합표Field Production Scheme 구 분division 굵은골재
최대치수
(mm)
Coarse aggregate
Maximum dimensions
(mm)
슬럼프
(cm)
slump
(cm)
물결합재비
(W/B)(%)
Water coupling ratio
(W / B) (%)
잔골재율
S/a(%)
Fine aggregate rate
S / a (%)
단위량(kg/m³)Unit quantity (kg / m³)

(W)
water
(W)
[표 1]의 실시예(B)Example (B) of Table 1 [ 잔골재
(S)
Fine aggregate
(S)
굵은골재
(G)
Coarse aggregate
(G)
배합combination 1313 16~2216 to 22 2222 5454 119119 540540 847847 730730

2. 성능평가2. Performance Evaluation

위 [표 6] 배합의 콘크리트 도로포장재에 대해 성능을 평가하였으며, 그 결과는 아래 [표 7]과 같이 나타냈다. The performance of the concrete road pavement of Table 6 was evaluated, and the results are shown in Table 7 below.

콘크리트 도로포장재의 성능Performance of Concrete Road Packaging Materials 구분division 결과result 평가 방법Assessment Methods 압축강도(MPa)Compressive strength (MPa) 28.6(3시간)28.6 (3 hours) KS F 2405KS F 2405 휨강도(MPa)Flexural strength (MPa) 4.6(3시간)4.6 (3 hours) KS F 2408KS F 2408 7.4(7일)7.4 (7 days) 부착강도(MPa)Bond strength (MPa) 1.82(3시간)1.82 (3 hours) KS F 2762KS F 2762 2.12(7일)2.12 (7 days) 염분침투저항성(Coulombs)Salt penetration resistance (Coulombs) 470(7일)470 (7 days) KS F 2711KS F 2711 건조수축(%)Dry shrinkage (%) 0.0317(7일)0.0317 (7 days) KS F 2424KS F 2424

위의 [표 7]에서와 같이 콘크리트 도로포장재를 연속으로 대량 생산하는 경우에도 압축강도/휨강도/부착강도/건축수축에서 우수한 성능을 나타냈다. 이에 따라 본 발명에 따른 콘크리트 도로포장재는 도로포장공사 내지 도로포장 보수공사에 대량으로 적용할 수 있을 것으로 기대된다.As shown in [Table 7] above, even in the case of continuous mass production of concrete pavement materials, excellent performance was shown in compressive strength / bending strength / bond strength / construction shrinkage. Accordingly, the concrete road pavement material according to the present invention is expected to be applied in a large amount to road paving work or road pavement repair work.

Claims (5)

삭제delete 삭제delete 콘크리트 도로포장재 배합에서,
단위결합재량(B) 380~600kg/㎥; 잔골재율(S/a) 45~55중량%; 물결합재비(W/B) 20~24중량%; 굵은골재 최대치수 25mm; 슬럼프 150~220mm;로 배합 설계되되,
결합재는, 발수 마그네시아 100중량부에 대하여, 인산2수소칼륨(KH2PO4)과 인산2수소나트륨(NaH2PO4) 중 하나 이상에 의한 제1인산염 70~90중량%와 인산수소2암모늄((NH4)2HPO4)과 인산2수소암모늄(NH4H2PO4) 중 하나 이상에 의한 제2인산염 10~30중량%로 조성된 인산염 15~45중량부; 메타인산나트륨(NaPO3)6 1~10중량부; 붕산(H3BO3), 붕사(Na2B4O7·10H2O) 중에서 하나 이상 선택된 붕산염 1~10중량부; 포졸란 분말, 광물성 분말 중에서 하나 이상 선택된 증량제 10~40중량부; 우레아(CO(NH2)2) 0.5~7중량부; 황산칼륨(K2SO4), 황산나트륨(Na2SO4) 중 하나 이상으로 마련된 알칼리염 0.3~4중량부;를 포함하여 조성된 것으로, 상기 발수 마그네시아가, 탄산마그네슘(MgCO3)이나 돌로마이트(CaMg(CO3)2)를 1100~1350℃에서 소성한 마그네시아 100중량부에 왁스에멀젼, 칼슘스테아레이트, 알루미늄스테아레이트 중에서 하나 이상 선택된 발수제 0.5~5중량부를 분쇄기에서 혼합 분쇄되어 혼합된 상태에서 1500~3000g/㎠의 분말도를 가지도록 처리된 것임을 특징으로 하는 초기반응 제어형 콘크리트 도로포장재.
In concrete road pavement formulations,
Unit bonding disposal amount (B) 380 to 600 kg / m 3; Fine aggregate ratio (S / a) of 45 to 55% by weight; Water binding ratio (W / B) of 20 to 24% by weight; Largest aggregate size 25mm; Slump 150 ~ 220mm; designed to be mixed,
The binder is composed of 70 to 90% by weight of a primary phosphate based on at least one of potassium dihydrogen phosphate (KH 2 PO 4 ) and sodium dihydrogen phosphate (NaH 2 PO 4 ), 100 to 2% 15 to 45 parts by weight of a phosphate composed of 10 to 30% by weight of a second phosphate by at least one of (NH 4 ) 2 HPO 4 and ammonium dihydrogen phosphate (NH 4 H 2 PO 4 ); 1 to 10 parts by weight of sodium metaphosphate (NaPO 3 ) 6 ; 1 to 10 parts by weight of a borate selected from boric acid (H 3 BO 3 ) and borax (Na 2 B 4 O 7 · 10H 2 O); 10 to 40 parts by weight of an extender selected from at least one of a pozzolana powder and a mineral powder; 0.5 to 7 parts by weight of urea (CO (NH 2 ) 2 ); 0.3 to 4 parts by weight of an alkali salt prepared from at least one of potassium sulfate (K 2 SO 4 ) and sodium sulfate (Na 2 SO 4 ), wherein the water repellent magnesia is magnesium carbonate (MgCO 3) or dolomite 0.5 to 5 parts by weight of a water repellent selected from wax emulsion, calcium stearate and aluminum stearate are mixed and ground in 100 parts by weight of magnesia calcined at 1100 to 1350 캜 at a temperature of 1500 to 3000 g / Cm &lt; 2 &gt;.
도로의 기층 위로 제3항에 따른 콘크리트 도로포장재를 포설하는 것을 특징으로 하는 콘크리트 도로포장공법.A concrete road paving method according to claim 3, characterized in that a concrete road pavement material according to claim 3 is laid on the base layer of the road. 콘크리트 포장도로에서, 콘크리트 포장면의 열화부분을 제거하여 청소한 후, 제3항에 따른 콘크리트 도로포장재를 포설하여 마무리하는 것을 특징으로 하는 콘크리트 도로포장 보수공법.The concrete road pavement repairing method is characterized in that the concrete pavement is cleaned by removing the deteriorated part of the concrete pavement surface, and then the concrete road pavement material according to claim 3 is laid.
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