KR101903956B1 - 질소-함유 헤테로시클릭 에폭시 경화제, 조성물 및 방법 - Google Patents

질소-함유 헤테로시클릭 에폭시 경화제, 조성물 및 방법 Download PDF

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KR101903956B1
KR101903956B1 KR1020160152184A KR20160152184A KR101903956B1 KR 101903956 B1 KR101903956 B1 KR 101903956B1 KR 1020160152184 A KR1020160152184 A KR 1020160152184A KR 20160152184 A KR20160152184 A KR 20160152184A KR 101903956 B1 KR101903956 B1 KR 101903956B1
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amine
epoxy
curing agent
group
amines
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KR20170066220A (ko
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쉬잉 젱
수디르 아난타차르
샤피크 니사라리 파젤
미첼 이안 쿠크
로버트 마르조 데오도르 라이징
웨이 차오
에지 잔 티즈마
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에보니크 데구사 게엠베하
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
    • C08K5/3445—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/5046—Amines heterocyclic
    • C08G59/5053—Amines heterocyclic containing only nitrogen as a heteroatom
    • C08G59/5073—Amines heterocyclic containing only nitrogen as a heteroatom having two nitrogen atoms in the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/08—Bridged systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/5006—Amines aliphatic
    • C08G59/502—Polyalkylene polyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/5046—Amines heterocyclic
    • C08G59/5053—Amines heterocyclic containing only nitrogen as a heteroatom
    • C08G59/508—Amines heterocyclic containing only nitrogen as a heteroatom having three nitrogen atoms in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/5046—Amines heterocyclic
    • C08G59/5053—Amines heterocyclic containing only nitrogen as a heteroatom
    • C08G59/508—Amines heterocyclic containing only nitrogen as a heteroatom having three nitrogen atoms in the ring
    • C08G59/5086—Triazines; Melamines; Guanamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/56—Amines together with other curing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/56—Amines together with other curing agents
    • C08G59/60—Amines together with other curing agents with amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3472—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Epoxy Resins (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
KR1020160152184A 2015-11-17 2016-11-15 질소-함유 헤테로시클릭 에폭시 경화제, 조성물 및 방법 Active KR101903956B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201562256262P 2015-11-17 2015-11-17
US62/256,262 2015-11-17
US15/343,632 2016-11-04
US15/343,632 US10556985B2 (en) 2015-11-17 2016-11-04 Nitrogen-containing heterocyclic epoxy curing agents, compositions and methods

Publications (2)

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KR20170066220A KR20170066220A (ko) 2017-06-14
KR101903956B1 true KR101903956B1 (ko) 2018-10-02

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US (1) US10556985B2 (https=)
EP (1) EP3170849B1 (https=)
JP (1) JP6401226B2 (https=)
KR (1) KR101903956B1 (https=)
CN (1) CN107099021B (https=)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10465039B2 (en) 2015-11-17 2019-11-05 Evonik Degussa Gmbh Epoxy curing agents, compositions and uses thereof
US10253225B2 (en) * 2016-12-23 2019-04-09 Evonik Degussa Gmbh APCHA as a building block in curing agent formulations for structural adhesives
US10450406B2 (en) * 2017-08-30 2019-10-22 Saudi Arabian Oil Company Fluorinated polyimide-based epoxy materials
JP7242694B2 (ja) 2018-03-05 2023-03-20 エボニック オペレーションズ ゲーエムベーハー エポキシ配合物のための脂環式アミン：エポキシ系のための新規な硬化剤
US11352541B2 (en) 2018-08-30 2022-06-07 Saudi Arabian Oil Company Sealing compositions and methods of sealing an annulus of a wellbore
US11168243B2 (en) 2018-08-30 2021-11-09 Saudi Arabian Oil Company Cement compositions including epoxy resin systems for preventing fluid migration
US10696888B2 (en) 2018-08-30 2020-06-30 Saudi Arabian Oil Company Lost circulation material compositions and methods of isolating a lost circulation zone of a wellbore
EP3798246B1 (en) * 2019-09-27 2024-01-31 Henkel AG & Co. KGaA One component (1k) composition based on modified epoxy resin
US11891476B2 (en) * 2019-11-08 2024-02-06 Evonik Operations Gmbh Phenalkamine epoxy curing agents from methylene bridged poly(cyclohexyl-aromatic) amines and epoxy resin compositions containing the same
US11332656B2 (en) 2019-12-18 2022-05-17 Saudi Arabian Oil Company LCM composition with controlled viscosity and cure time and methods of treating a lost circulation zone of a wellbore
US11370956B2 (en) 2019-12-18 2022-06-28 Saudi Arabian Oil Company Epoxy-based LCM compositions with controlled viscosity and methods of treating a lost circulation zone of a wellbore
US11193052B2 (en) 2020-02-25 2021-12-07 Saudi Arabian Oil Company Sealing compositions and methods of plugging and abandoning of a wellbore
US11236263B2 (en) 2020-02-26 2022-02-01 Saudi Arabian Oil Company Method of sand consolidation in petroleum reservoirs
EP4179000A4 (en) * 2020-07-10 2024-03-27 Evonik Operations GmbH Epoxy-amine adduct
US12173113B2 (en) 2021-03-17 2024-12-24 Evonik Operations Gmbh Waterborne epoxy curing agent
WO2023010442A1 (en) 2021-08-05 2023-02-09 Evonik Operations Gmbh Amine composition, epoxy system prepared from the amine composition and an epoxy resin, and use of the epoxy system
US11827841B2 (en) 2021-12-23 2023-11-28 Saudi Arabian Oil Company Methods of treating lost circulation zones
CN117327433B (zh) * 2023-09-28 2025-05-06 江苏进华重防腐涂料有限公司 建筑物排水用铸铁管和铸铁配件的环氧漆及其制备和应用

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014095027A (ja) 2012-11-08 2014-05-22 Tosoh Corp エポキシ硬化剤用アミン組成物

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2643977A (en) 1951-01-29 1953-06-30 Cities Service Res & Dev Co Method of inhibiting corrosion of metals
GB1424702A (en) 1972-04-27 1976-02-11 Kanebo Ltd Method of decolourizing waste coloured aqueous liquid
CA1101448A (en) 1977-06-21 1981-05-19 Edward L. Manigault Self bonding refractory composition of alumina and chrome oxide
EP0003479B1 (de) 1978-02-11 1981-09-16 Schering Aktiengesellschaft Härtungsmittel und Verfahren zur Herstellung von Epoxid-Polyaddukten
DE2922176C3 (de) 1979-05-31 1995-11-09 Akzo Gmbh Wasserhärtbare Polyisocyanat- oder Polyepoxid-Gemische
US4533682A (en) 1983-04-29 1985-08-06 Desoto, Inc. Imidazolidine-blocked amine polymers
US4877578A (en) 1985-03-29 1989-10-31 Petrolite Corporation Corrosion inhibitors
ATE243227T1 (de) * 1990-05-21 2003-07-15 Dow Global Technologies Inc Latente katalysatoren, härtungsinhibierte epoxyharzzusammensetzungen und daraus hergestellte laminate
US5280091A (en) 1992-02-07 1994-01-18 Air Products And Chemicals, Inc. Epoxy resins cured with mixed methylene bridged poly(cyclohexyl-aromatic)amine curing agents
US5618905A (en) * 1995-04-11 1997-04-08 Air Products And Chemicals, Inc. Partially methylated polyamines as epoxy curing agents
DK1114076T3 (da) 1998-09-14 2003-07-07 Vantico Ag Acceleratorer til hærdbare systemer
BRPI0510093B8 (pt) * 2004-04-20 2022-12-27 Dendritic Nanotechnologies Inc polímeros dendríticos
US8147964B2 (en) 2007-02-07 2012-04-03 Air Products And Chemicals, Inc. Benzylated polyalkylene polyamines and uses thereof
US8143331B2 (en) 2007-02-07 2012-03-27 Air Products And Chemicals, Inc. Alkylated polyalkyleneamines and uses thereof
US8518547B2 (en) * 2007-02-07 2013-08-27 Air Products And Chemicals, Inc. Alkylated polyalkylene polyamines and uses thereof
US8168296B2 (en) 2007-02-07 2012-05-01 Air Products And Chemicals, Inc. Benzylated polyalkylene polyamines and uses thereof
JP5408612B2 (ja) 2009-04-13 2014-02-05 奥野製薬工業株式会社 アルミニウム合金の陽極酸化皮膜用封孔処理方法
WO2013003202A1 (en) 2011-06-30 2013-01-03 Dow Global Technologies Llc Curable epoxy resin systems containing mixtures of amine hardeners and an excess of epoxide groups
CN103333136B (zh) 2013-07-05 2015-07-22 河北工业大学 一种多胺基酰胺阳离子沥青乳化剂的制备方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014095027A (ja) 2012-11-08 2014-05-22 Tosoh Corp エポキシ硬化剤用アミン組成物

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Publication number Publication date
EP3170849A1 (en) 2017-05-24
JP2017095703A (ja) 2017-06-01
US20170137562A1 (en) 2017-05-18
JP6401226B2 (ja) 2018-10-10
KR20170066220A (ko) 2017-06-14
US10556985B2 (en) 2020-02-11
EP3170849B1 (en) 2019-08-28
CN107099021B (zh) 2019-09-13
CN107099021A (zh) 2017-08-29

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