KR101895384B1 - Polysiloxane-polycarbonate copolymer with improved flame retardancy and method for preparing the same - Google Patents

Abstract

The present invention relates to a polysiloxane-polycarbonate copolymer with improved flame retardancy and to a manufacturing method thereof, and more particularly, to a polysiloxane-polycarbonate copolymer with excellent transparency and excellent flame retardancy by including a polysiloxane and polycarbonate block having a specific structure with three terminal-hydroxyl groups as repeating units.

Description

Polysiloxane-polycarbonate copolymers with excellent flame retardancy and methods for preparing the same

The present invention relates to a polysiloxane-polycarbonate copolymer having excellent flame retardancy and a method for producing the polysiloxane-polycarbonate copolymer, and more particularly to a polysiloxane-polycarbonate copolymer having a specific structure having three terminal- And at the same time exhibiting excellent flame retardancy, and a process for producing the same.

Polycarbonate resins are widely used as electrical parts, machine parts and industrial resins because of their excellent heat resistance, mechanical properties (particularly impact strength) and transparency. Particularly, when a polycarbonate resin is used as a case material for a TV housing, a computer monitor housing, a copying machine, a printer, a notebook battery, and a lithium battery in which a lot of heat is radiated in the electric and electronic fields, heat resistance and mechanical properties as well as excellent flame retardancy are required .

The most common method used to impart flame retardancy to a polycarbonate resin is to mix a bromine-based or chlorine-based compound, which is a halogen flame retardant, with the polycarbonate resin. However, when a halogen flame retardant is used, the function of flame retardancy is sufficiently exhibited in the event of a fire, but hydrogen halide gas is generated during resin processing, which causes mold corrosion and environmental pollution problems. In addition, dioxins, which are harmful to human bodies, This is why the regulation on use of these products is expanding. In order to cope with this, a flame retardant polycarbonate resin composition using an alkali metal salt as a non-halogen flame retardant and a fluorinated polyolefin resin as an anti-dripping agent has been developed. However, in this case, there arises a problem that the transparency, which is one of the merits of the polycarbonate resin, is deteriorated due to the fluorinated polyolefin-based resin (particularly the fluorinated ethylene-based resin) and the metal salt-based flame retardant used for ensuring the flame retardancy of the polycarbonate resin.

In order to overcome such deterioration in transparency, an alloy of a silicon-based additive and a silicone-based copolymer has been proposed. However, although the technology using a silicone additive has an advantage of being environmentally friendly as a non-halogen flame retardant, its transparency is still low and relatively high, and it has disadvantages that various colors are limited when used as an exterior material. In addition, there is a problem that application to large-sized products is limited because the liquidity is insufficient for injection into large-sized articles.

Accordingly, development of a polycarbonate resin composition capable of realizing harmonious physical properties such as excellent transparency, fluidity and low temperature impact strength while sufficiently exhibiting flame retardancy is required.

United States Patent Application Publication No. 2003/0105226

Disclosure of Invention Technical Problem [8] The present invention has been made to overcome the problems of the prior art as described above, and it is an object of the present invention to provide a polysiloxane-polycarbonate copolymer excellent in transparency and low temperature impact strength while remarkably improving flame retardancy.

In order to solve the above-mentioned technical problems, the present invention provides a hydroxyl-terminated polysiloxane having an ester bond represented by the following formula:

[Chemical Formula 1]

In Formula 1,

R ₁ independently represents a hydrogen atom, a halogen atom, a hydroxy group, an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, or an aryl group having 6 to 12 carbon atoms,

R ₂ independently represents a hydrocarbon group or a hydroxy group having 1 to 13 carbon atoms,

R ₃ independently represents an alkylene group having 2 to 8 carbon atoms,

Y represents a linear or branched aliphatic group having 1 to 20 carbon atoms or a mononuclear or polynuclear aromatic group having 6 to 30 carbon atoms,

m is independently an integer of 0 to 4,

n independently represents an integer of 2 to 1,000.

In one embodiment of the present invention, the hydroxy-terminated polysiloxane having an ester bond may be the reaction product of a hydroxy-terminated siloxane of the following formula 2 with an acyl compound of the formula 3:

(2)

In Formula 2,

R ₁ independently represents a hydrogen atom, a halogen atom, a hydroxy group, an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, or an aryl group having 6 to 12 carbon atoms,

R ₂ independently represents a hydrocarbon group or a hydroxy group having 1 to 13 carbon atoms,

R ₃ independently represents an alkylene group having 2 to 8 carbon atoms,

m represents an integer of 0 to 4,

n represents an integer of 2 to 1,000;

(3)

In Formula 3,

X represents a hydroxy group or a halogen group,

Y represents a linear or branched aliphatic group having 1 to 20 carbon atoms or a monocyclic or polycyclic aromatic group having 6 to 30 carbon atoms.

According to another aspect of the present invention there is provided a polysiloxane-polycarbonate copolymer comprising a hydroxy-terminated polysiloxane having an ester bond of Formula 1 and a polycarbonate block of Formula 6 as repeating units:

[Chemical Formula 6]

In Formula 6,

R ₄ represents a bivalent aromatic hydrocarbon group having 6 to 30 carbon atoms, wherein the bivalent aromatic hydrocarbon group is unsubstituted or substituted with an alkyl group, a cycloalkyl group, an alkenyl group, an alkoxy group, a halogen atom, or nitro.

According to one embodiment of the present invention, in the polysiloxane-polycarbonate copolymer, the content of the hydroxyl-terminated polysiloxane having an ester bond may be 0.5 to 20% by weight based on the total amount of the copolymer.

In one embodiment of the invention, the polysiloxane-polycarbonate copolymer may have a viscosity average molecular weight of from 15,000 to 200,000.

According to another aspect of the present invention, there is provided a process for preparing a polysiloxane-polycarbonate intermediate, comprising: reacting a hydroxyl-terminated polysiloxane having an ester bond of Formula 1 with an oligomeric polycarbonate under an interface reaction condition to form a polysiloxane-polycarbonate intermediate; And polymerizing the polysiloxane-polycarbonate intermediate using a first polymerization catalyst. The polysiloxane-polycarbonate copolymer is produced by a process comprising the steps of:

In one embodiment of the present invention, the step of forming the polysiloxane-polycarbonate intermediate comprises mixing the oligomeric polycarbonate with the hydroxy-terminated polysiloxane having the ester bond in a weight ratio of 0.5: 99.5 to 20:80 . ≪ / RTI >

In one embodiment of the present invention, the step of forming the polysiloxane-polycarbonate intermediate may comprise forming a mixture comprising the oligomeric polycarbonate and the hydroxy-terminated polysiloxane having the ester bond, wherein The mixture may further include a phase transfer catalyst, a molecular weight modifier, and a second polymerization catalyst.

In one embodiment of the present invention, the step of forming the polysiloxane-polycarbonate intermediate comprises: forming a mixture comprising the oligomeric polycarbonate and the hydroxy-terminated polysiloxane having the ester bond; And extracting the organic phase from the mixture after completion of the reaction of the oligomeric polycarbonate with the hydroxyl-terminated polysiloxane having the ester bond, and the step of polymerizing the polysiloxane-polycarbonate intermediate may include: 1 polymerization catalyst to the extracted organic phase.

In one embodiment of the invention, the oligomeric polycarbonate may have a viscosity average molecular weight of from 1,000 to 27,000.

The polysiloxane-polycarbonate copolymer according to the present invention contains a polysiloxane having a specific structure represented by the above-mentioned formula (1) as a repeating unit, so that excellent physical properties inherent to polycarbonate such as impact resistance and transparency can be satisfactorily maintained, It can be applied to various applications such as construction, automobile parts, and electric / electronic parts.

Hereinafter, the present invention will be described in more detail.

As used herein, the term "reaction product" means a material in which two or more reactants are formed by reaction.

In addition, although the terms "first", "second" and the like are used herein to describe a polymerization catalyst, the polymerization catalyst is not limited by these terms. These terms are merely used to distinguish polymerization catalysts from each other. For example, the first polymerization catalyst and the second polymerization catalyst may be the same kind of catalyst or different kinds of catalysts.

The letter "R" used to represent hydrogen, a halogen atom and / or a hydrocarbon group in the formulas described in the present specification has a subscript indicated by a numeral, but the letter "R" But is not limited thereto. The "R" represents, independently of each other, hydrogen, a halogen atom and / or a hydrocarbon group. For example, the "R" s may represent the same hydrocarbon group or may represent other hydrocarbon groups, irrespective of whether two or more "R" have the same or different numbers of subscripts.

ester Having a bond  Hydroxy-terminated Poly Siloxane

The hydroxyl-terminated polysiloxane having an ester bond according to the present invention is represented by the following formula (1).

[Chemical Formula 1]

In Formula 1,

R ₁ independently represents a hydrogen atom, a halogen atom, a hydroxy group, an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, or an aryl group having 6 to 12 carbon atoms,

R ₂ independently represents a hydrocarbon group or a hydroxy group having 1 to 13 carbon atoms,

R ₃ independently represents an alkylene group having 2 to 8 carbon atoms,

Y represents a linear or branched aliphatic group having 1 to 20 carbon atoms or a mononuclear or polynuclear aromatic group having 6 to 30 carbon atoms,

m is independently an integer of 0 to 4,

n independently represents an integer of 2 to 1,000.

More specifically, in Formula 1,

R ₁ is, independently, a hydrogen atom, a halogen atom (such as F, Cl, or Br), a hydroxyl group, an alkyl group having 1 to 10 carbon atoms (e.g., methyl, An alkoxy group having 1 to 10 carbon atoms (e.g., methoxy, ethoxy, propoxy or butoxy) or an aryl group having 6 to 12 carbon atoms (e.g., a phenyl group, a chloro group, A phenyl group, a benzyl or a tolyl group)

R ₂ is independently a hydrocarbon group having 1 to 13 carbon atoms or a hydroxyl group, wherein the hydrocarbon group having 1 to 13 carbon atoms is an alkyl group or an alkoxy group having 1 to 13 carbon atoms, an alkenyl group or alkenyloxy group having 2 to 13 carbon atoms, An aryloxy group having 6 to 10 carbon atoms, an aralkyl group or an aralkoxy group having 7 to 13 carbon atoms, or an alkaryl group or an alkaryloxy group having 7 to 13 carbon atoms,

R ₃ independently represents an alkylene group having 2 to 8 carbon atoms,

m is independently an integer of 0 to 4,

n independently represents an integer of 2 to 1,000, preferably an integer of 2 to 500, more preferably an integer of 5 to 100,

Y represents a linear or branched aliphatic group having 1 to 20 carbon atoms, or a monocyclic or polycyclic aromatic group having 6 to 30 carbon atoms, more specifically, Y is an aliphatic group substituted or unsubstituted with a halogen atom; An aliphatic group containing an oxygen, nitrogen or sulfur atom in the main chain; Or 1,3,5-benzenetriol, 1,3,5-benzenetricarbonyl trichloride, 4-hydroxymethylbenzene- 1,3-diol (4- (Hydroxymethyl) benzene-1,3-diol), 1,3,5-tris (4-carboxyphenyl) benzene, Benzene-1,3,5-triacetic acid, 1,3-benzenediol 5- [1 (E) -2- (2-hydroxyphenyl) ethenyl] 1,3-benzenediol, 5- [1 (E) -2- (2-hydroxyphenyl) ethenyl], 4-benzylbenzene-1,2,3- triol, benzenetriol, or biphenyl-3,4 ', 5-tricarboxylic acid. The term " aromatic "

In one embodiment, Y may be represented by any one of formulas (4a) to (4i) below.

[Chemical Formula 4a]

(4b)

[Chemical Formula 4c]

[Chemical formula 4d]

[Chemical Formula 4e]

[Formula 4f]

[Chemical Formula 4g]

[Chemical Formula 4h]

[Formula 4i]

In one embodiment, the hydroxy-terminated polysiloxane having an ester bond may be the reaction product of a hydroxy-terminated siloxane of formula 2 with an acyl compound.

(2)

In Formula 2,

R ₁ is, independently, a hydrogen atom, a halogen atom (such as F, Cl, or Br), a hydroxyl group, an alkyl group having 1 to 10 carbon atoms (e.g., methyl, An alkoxy group having 1 to 10 carbon atoms (e.g., methoxy, ethoxy, propoxy or butoxy) or an aryl group having 6 to 12 carbon atoms (e.g., a phenyl group, a chloro group, A phenyl group, a benzyl or a tolyl group)

R ₂ is independently a hydrocarbon group having 1 to 13 carbon atoms or a hydroxyl group, wherein the hydrocarbon group having 1 to 13 carbon atoms is an alkyl group or an alkoxy group having 1 to 13 carbon atoms, an alkenyl group or alkenyloxy group having 2 to 13 carbon atoms, An aryloxy group having 6 to 10 carbon atoms, an aralkyl group or an aralkoxy group having 7 to 13 carbon atoms, or an alkaryl group or an alkaryloxy group having 7 to 13 carbon atoms,

R ₃ independently represents an alkylene group having 2 to 8 carbon atoms,

m is independently an integer of 0 to 4,

n independently represents an integer of 2 to 1,000, preferably an integer of 2 to 500, more preferably an integer of 5 to 100.

The acyl compound may have a mixed structure including, for example, an aromatic, aliphatic, or both aromatic and aliphatic groups. When the acyl compound is aromatic or mixed, it may have 6 to 30 carbon atoms. When the acyl compound is aliphatic, it may have 1 to 20 carbon atoms. The acyl compound may further contain a halogen, oxygen, nitrogen, or sulfur atom.

For example, the acyl compound may have the following formula (3).

(3)

In Formula 3,

X may represent a hydroxy group or a halogen group,

Y represents a linear or branched aliphatic group having 1 to 20 carbon atoms or a monocyclic or polycyclic aromatic group having 6 to 30 carbon atoms.

For example, Y is a substituted or unsubstituted aliphatic group with a halogen atom; An aliphatic group containing an oxygen, nitrogen or sulfur atom in the main chain; Or 1,3,5-benzenetriol, 1,3,5-benzenetricarbonyl trichloride, 4-hydroxymethylbenzene- 1,3-diol (4- (Hydroxymethyl) benzene-1,3-diol), 1,3,5-tris (4-carboxyphenyl) benzene, Benzene-1,3,5-triacetic acid, 1,3-benzenediol 5- [1 (E) -2- (2-hydroxyphenyl) ethenyl] 1,3-benzenediol, 5- [1 (E) -2- (2-hydroxyphenyl) ethenyl, 4-benzylbenzene-1,2,3-triol ), Benzenetriol, or biphenyl-3,4 ', 5-tricarboxylic acid. The term " aromatic "

In one embodiment, Y in formula (3) may be represented by the following formulas (4a) to (4i).

[Chemical Formula 4a]

(4b)

[Chemical Formula 4c]

[Chemical formula 4d]

[Chemical Formula 4e]

[Formula 4f]

[Chemical Formula 4g]

[Chemical Formula 4h]

[Formula 4i]

The hydroxy-terminated polysiloxane of Formula 2 may be synthesized, for example, at a molar ratio of 2: 1 using a platinum catalyst, with a compound of Formula 5a having a double bond with a hydroxyl group and a compound of Formula 5b containing silicon .

[Chemical Formula 5a]

In the above formula (5a)

R ₁ represents a hydrogen atom, a halogen atom (for example, F, Cl, or Br), a hydroxyl group, an alkyl group having 1 to 10 carbon atoms (e.g., a methyl group, ethyl group, propyl group, butyl group, pentyl group, An alkoxy group having 1 to 10 carbon atoms (e.g., methoxy, ethoxy, propoxy or butoxy) or an aryl group having 6 to 12 carbon atoms (e.g., a phenyl group, a chlorophenyl group, Or a tolyl group)

m represents an integer of 0 to 4,

k represents an integer of 1 to 7;

[Chemical Formula 5b]

In Formula 5b,

R ₂ are, each independently, represents a hydrocarbon group or hydroxy group of a carbon number of 1 to 13, wherein the carbon number of 1 to 13. The hydrocarbon group having 1 to 13 alkyl group or an alkoxy group, an alkenyl group or alkenyloxy group having 2 to 13 carbon atoms, 3 An aryloxy group having 6 to 10 carbon atoms, an aralkyl group or an aralkoxy group having 7 to 13 carbon atoms, or an alkaryl group or an alkaryloxy group having 7 to 13 carbon atoms,

n represents an integer of 2 to 1,000, preferably an integer of 2 to 500, more preferably an integer of 5 to 100.

Reference may be made to U.S. Patent No. 6,072,011 for the preparation of the hydroxy-terminated siloxane of Formula 2 above.

Polysiloxane - Polycarbonate Copolymer

The polysiloxane-polycarbonate copolymer according to the present invention may contain, as a repeating unit, a polycarbonate block represented by the following formula (6) together with a hydroxyl-terminated polysiloxane having an ester bond of the above formula (1).

[Chemical Formula 6]

In Formula 6,

R ₄ may represent a bivalent aromatic hydrocarbon group having 6 to 30 carbon atoms, wherein the bivalent aromatic hydrocarbon group is unsubstituted or substituted with an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms , An alkoxy group having 1 to 20 carbon atoms, a halogen atom or nitro.

The aromatic hydrocarbon group may be derived from a compound of the following formula (7).

(7)

In Formula 7,

X is an alkylene group; Linear, branched or cyclic alkylene groups having no functional groups; Or a straight, branched or cyclic alkylene group having a functional group selected from the group consisting of sulfides, ethers, sulfoxides, sulfones, ketones, naphthyls and isobutylphenyls, Linear, branched or cyclic alkylene group,

R ₅ and R ₆ each independently represent a hydrogen atom, a halogen atom, or a straight, branched or cyclic alkyl group having 1 to 20 carbon atoms,

m and n independently represent an integer of 0 to 4;

The compound of formula (7) is, for example, bis (4-hydroxyphenyl) methane, bis (4-hydroxyphenyl) phenylmethane, bis Ethyl-1,1-bis (4-hydroxyphenyl) propane, 1-phenyl-1, Bis (4-hydroxyphenyl) ethane, 1-naphthyl-1,1-bis (4-hydroxyphenyl) (4-hydroxyphenyl) decane, 2-methyl-1,1-bis (4-hydroxyphenyl) propane, 2,2- Bis (4-hydroxyphenyl) butane, 2,2-bis (4-hydroxyphenyl) pentane, 2,2- Bis (3-fluoro-4-hydroxyphenyl) propane, 4-methyl-2,2-bis (4-hydroxyphenyl) Pentane, 4,4-bis (4-hydroxyphenyl) heptane, diphenyl-bis (4-hydroxyphenyl) Resorcinol, Hydroquinone, 4,4'-dihydroxyphenyl ether [bis (4-hydroxyphenyl) ether], 4,4'-dihydroxy- Dihydroxy-3,3'-dichlorodiphenyl ether, bis (3,5-dimethyl-4-hydroxyphenyl) ether, bis (3,5- Hydroxyphenyl) ether, 1,4-dihydroxy-2,5-dichlorobenzene, 1,4-dihydroxy-3-methylbenzene, 4,4'-dihydroxydiphenol [p, p Dihydroxyphenyl], 3,3'-dichloro-4,4'-dihydroxyphenyl, 1,1-bis (4-hydroxyphenyl) cyclohexane, 1,1- (3,5-dimethyl-4-hydroxyphenyl) cyclohexane, 1,1-bis (3,5-dichloro-4-hydroxyphenyl) cyclohexane, (4-hydroxyphenyl) decane, 1,1-bis (4-hydroxyphenyl) cyclododecane, 4-bis (4-hydroxyphenyl) propane, 1,4-bis (4-hydroxyphenyl) butane, 1,4-bis (4-hydroxyphenyl) isobutane, 2,2- (3,5-dimethyl-4-hydroxyphenyl) methane, bis (3,5-dichloro-4-hydroxyphenyl) methane, 2,2- 4-hydroxyphenyl) propane, 2,2-bis (3,5-dibromo-4-hydroxyphenyl) propane, Bis (4-hydroxyphenyl) sulfone], bis (3,5-dimethyl-4-hydroxyphenyl) Hydroxyphenyl) sulfone, bis (3-chloro-4-hydroxyphenyl) sulfone, bis (4-hydroxyphenyl) sulfone, bis Bis (3,5-dibromo-4-hydroxyphenyl) sulfoxide, 4,4'-dihydroxybenzophenone, 3,3 ', 5,5'-tetramethyl-4,4'-dihydroxybenz Benzophenone, 4,4'-dihydroxy-diphenyl, methyl hydroquinone, 1,5-dihydroxy naphthalene, and may be selected from 2,6-dihydroxy naphthalene, is not limited thereto. Representative examples include 2,2-bis (4-hydroxyphenyl) propane (bisphenol A). Other functional dihydric phenols can be found in US Pat. Nos. US 2,999,835, US 3,028,365, US 3,153,008 and US 3,334,154, and the dihydric phenols may be used singly or in combination of two or more. Can be used.

The carbonate precursor may be, for example, carbonyl chloride (phosgene), carbonyl bromide, bishaloformate, diphenyl carbonate or dimethyl carbonate as the other monomer of the polycarbonate resin.

In a preferred embodiment, the content of the hydroxyl-terminated polysiloxane having an ester bond is 0.5 to 20% by weight, preferably 2 to 15% by weight, more preferably 3 To 10% by weight, and the content of the polycarbonate may be 80 to 99.5% by weight, preferably 85 to 98% by weight, more preferably 90 to 97% by weight, based on the total weight of the polysiloxane-polycarbonate copolymer have.

If the content of the hydroxyl-terminated polysiloxane having an ester bond is less than 0.5% by weight, the flame retardancy may be deteriorated. If the content is more than 20% by weight, flame retardancy may be improved but transparency may be deteriorated.

In one preferred embodiment, the polysiloxane-polycarbonate copolymer according to the present invention may have a viscosity average molecular weight ( _Mv ) of from 15,000 to 200,000, more preferably from 15,000 to 100,000.

If the viscosity average molecular weight of the polysiloxane-polycarbonate copolymer is less than 15,000, mechanical properties may be significantly deteriorated. If the viscosity average molecular weight is more than 200,000, a problem may arise in processing the resin due to an increase in melt viscosity.

The polysiloxane-polycarbonate copolymer according to the present invention comprises a step (1) of reacting a hydroxyl-terminated polysiloxane having an ester bond with an oligomeric polycarbonate under an interfacial reaction condition comprising an aqueous alkali solution and an organic phase to form a polysiloxane-polycarbonate intermediate ); And (2) polymerizing the polysiloxane-polycarbonate intermediate using a first polymerization catalyst.

In one preferred embodiment, step (1) of forming the polysiloxane-polycarbonate intermediate comprises reacting the hydroxyl-terminated polysiloxane having an ester bond with an oligomeric polycarbonate in a ratio of from 0.5: 99.5 to 20: 80, preferably from 2: To 15:85, and more preferably from 3:97 to 10:90.

If the weight ratio of the hydroxyl-terminated polysiloxane having an ester bond is less than 0.5 parts by weight based on the total 100 parts by weight of the hydroxyl-terminated polysiloxane having an ester bond and the oligomeric polycarbonate, the flame retardancy may be lowered, If it exceeds the above range, the flame retardancy is improved but the transparency may be lowered.

In one embodiment, The oligomeric polycarbonate used in the preparation of the polysiloxane-polycarbonate copolymer is prepared by adding the above-mentioned divalent phenol compound to an alkaline aqueous solution to obtain a phenol salt state, then adding salt phenols into dichloromethane injected with phosgene gas ≪ / RTI > For oligomer preparation, it is desirable to maintain the molar ratio of phosgene to bisphenol in the range of about 1: 1 to 1.5: 1, more preferably about 1: 1 to 1.2: 1.

If the molar ratio of phosgene to 1 mole of bisphenol is less than 1, the reactivity may be lowered. If the molar ratio of phosgene to 1 mole of bisphenol is more than 1.5, there may be a problem in workability due to an excessive increase in molecular weight.

The oligomerization reaction may be generally carried out at a temperature in the range of about 15 to 60 DEG C, and an alkali metal hydroxide (e.g., sodium hydroxide, etc.) may be used to adjust the pH of the reaction mixture.

In one embodiment, the oligomeric polycarbonate may have a viscosity average molecular weight of from 1,000 to 27,000, preferably from 1,000 to 15,000.

If the viscosity average molecular weight of the oligomeric polycarbonate is less than 1,000, the molecular weight distribution may be widened and the physical properties may be deteriorated. When the oligomeric polycarbonate exceeds 27,000, the reactivity may be lowered.

In one embodiment, the step (1) of forming the polysiloxane-polycarbonate intermediate comprises forming a mixture comprising the oligomeric polycarbonate and the hydroxyl-terminated polysiloxane having the ester bond, wherein the mixture May further comprise a phase transfer catalyst, a molecular weight modifier and a second polymerization catalyst.

In one embodiment, the step (1) of forming the polysiloxane-polycarbonate intermediate comprises: forming a mixture comprising a hydroxyl-terminated polysiloxane having the ester bond and the oligomeric polycarbonate; And extracting the organic phase from the resultant mixture after completion of the reaction of the oligomeric polycarbonate with the hydroxyl-terminated polysiloxane having the ester bond, wherein the step (2) of polymerizing the intermediate is carried out in the presence of the first polymerization catalyst To the extracted organic phase.

Specifically, the polysiloxane-polycarbonate copolymer according to the present invention can be prepared by adding a hydroxyl-terminated polysiloxane having an ester bond to an organic phase-water mixture containing an oligomeric polycarbonate, and adding a molecular weight regulator and a catalyst stepwise .

As the molecular weight modifier, a monofunctional compound similar to the monomer used in the production of the polycarbonate may be used. Monofunctional materials include, for example, p-isopropylphenol, p-tert-butylphenol (PTBP), p-cumylphenol, p-isooctylphenol, and p- Phenol-based derivatives such as phenol, or aliphatic alcohols. Preferably, p-tert-butylphenol (PTBP) can be used.

As the catalyst, a polymerization catalyst and / or a phase transfer catalyst may be used. As the polymerization catalyst, for example, triethylamine (TEA) can be used. As the phase transfer catalyst, for example, a compound of the following formula (8) can be used.

[Chemical Formula 8]

(R ₇ ) ₄ Q ⁺ X ^-

In Formula 8,

R ₇ represents an alkyl group having 1 to 10 carbon atoms,

Q represents nitrogen or phosphorus,

X may represent a halogen atom or -OR ₈ , wherein R ₈ may represent a hydrogen atom, an alkyl group having 1 to 18 carbon atoms or an aryl group having 6 to 18 carbon atoms.

Specifically, the phase-transfer catalyst, for _{example, [CH 3 (CH 2)} 3] 4 NX, [CH 3 (CH 2) 3] 4 PX, [CH 3 (CH 2) 5] 4 NX, [CH 3 _{(CH 2) 6] 4 NX} , [CH 3 (CH 2) 4] 4 NX, CH 3 [CH 3 (CH 2) 3] 3 NX, CH 3 [CH 3 (CH 2) 2] can be a ₃ NX have.

In the above formulas, X represents Cl, Br or -OR ₈ , wherein R ₈ may represent a hydrogen atom, an alkyl group having 1 to 18 carbon atoms or an aryl group having 6 to 18 carbon atoms.

The content of the phase transfer catalyst is not particularly limited, but is preferably about 0.01 to 10% by weight based on the total weight of the mixture of the hydroxyl-terminated polysiloxane having an ester bond and the oligomeric polycarbonate.

If the content of the phase-transition catalyst is less than 0.01% by weight, the reactivity may be deteriorated. If the content of the phase-transition catalyst is more than 10% by weight, precipitates may be precipitated or the transparency may be deteriorated.

In one embodiment, the polysiloxane-polycarbonate copolymer according to the present invention may be prepared, and then the organic phase dispersed in methylene chloride may be alkaline cleaned and then separated. Subsequently, the organic phase is washed with 0.1N hydrochloric acid solution and then washed repeatedly with distilled water two to three times. When the cleaning is completed, the concentration of the organic phase dispersed in methylene chloride can be adjusted to a constant level, and granulation can be performed using a predetermined amount of pure water at 70 to 80 ° C.

If the temperature of the pure water is less than 70 ° C, the assembling speed is decreased and the assembly time may be very long. If the pure water temperature exceeds 80 ° C, it may become difficult to obtain the polysiloxane-polycarbonate copolymer in a uniform size.

When the assembly is completed, it is preferable to firstly dry at 100 to 110 ° C for 5 to 10 hours and secondly at 110 to 120 ° C for 5 to 10 hours.

Hereinafter, the present invention will be described in more detail by way of examples, but the present invention is not limited thereto.

[ Example ]

<Ester Having a bond  Hydroxy-terminated Polysiloxane  Manufacturing>

Example  A-1

A condenser was attached to a 500 ml three-necked flask and 600 g of hydroxy terminated siloxane monomer (BY16-799) of Dow corning was dissolved in 300 ml of chloroform under a nitrogen atmosphere. Then, triethylamine (TEA) 67 ml of catalyst were added.

After the solution was refluxed, 40.6 g of 1,3,5-benzene tricarbonyl trichloride was dissolved in 1,000 ml of chloroform, and the mixture was slowly added for 1 hour. The mixture was refluxed for 12 hours . After the solvent of the reaction solution was removed, the solution was dissolved in acetone and washed with hot distilled water. And then dried in a vacuum oven for 24 hours to prepare a hydroxy-terminated polysiloxane having an ester bond represented by the following formula (9).

[Chemical Formula 9]

< Polysiloxane - Preparation of Polycarbonate Copolymer &gt;

Example  B-1

Bisphenol A in aqueous solution and phosgene gas were interfacially reacted in the presence of methylene chloride to prepare an oligomeric polycarbonate mixture having a viscosity average molecular weight of about 1,000.

The organic phase of the obtained oligomeric polycarbonate mixture was sampled, and 2 wt% of a hydroxyl-terminated polysiloxane having an ester bond of the above formula (9) dissolved in an aqueous solution of sodium hydroxide, tetrabutyl ammonium chloride (TBACl) , 186 메틸 of methylene chloride and 1.5 g of p-tert-butylphenol (PTBP) were mixed and reacted for 2 hours.

Only the organic phase of the oligomeric polycarbonate mixture was collected in the reacted organic phase, and the remaining aqueous phase and triethylamine were added thereto, followed by reaction for 3 hours. After the layer separation, only the organic phase was sampled, and an aqueous solution of sodium hydroxide, methylene chloride and triethylamine were mixed and reacted for 4 hours.

After separation of the layers, the organic phase having an increased viscosity was washed with alkali and then separated. Subsequently, the organic phase was washed with 0.1 N hydrochloric acid solution and then washed repeatedly with distilled water two to three times. The cleaning was completed and the concentration of the organic phase was fixed at a constant level of 76 DEG C using a predetermined amount of pure water. After the assembly was completed, the polysiloxane-polycarbonate copolymer was first dried at 110 DEG C for 8 hours and then at 120 DEG C for 10 hours.

The physical properties of the prepared polysiloxane-polycarbonate copolymer were measured and reported in Table 1 below.

Example  B-2

Polysiloxane-polycarbonate copolymer was prepared in the same manner as in Example B-1 except that the content of the hydroxyl-terminated polysiloxane having an ester bond of the above formula (9) was changed from 2 wt% to 5 wt% .

The physical properties of the prepared polysiloxane-polycarbonate copolymer were measured and reported in Table 1 below.

Example  B-3

Polysiloxane-polycarbonate copolymer was prepared in the same manner as in Example B-1 except that the content of the hydroxyl-terminated polysiloxane having an ester bond of the above formula (9) was changed from 2 wt% to 7 wt% .

The physical properties of the prepared polysiloxane-polycarbonate copolymer were measured and reported in Table 1 below.

Example  B-4

Polysiloxane-polycarbonate copolymer was prepared in the same manner as in Example B-1 except that the content of the hydroxyl-terminated polysiloxane having an ester bond of the above formula (9) was changed from 2 wt% to 10 wt%.

The physical properties of the prepared polysiloxane-polycarbonate copolymer were measured and reported in Table 1 below.

Example  B-5

Polysiloxane-polycarbonate copolymer was prepared in the same manner as in Example B-1 except that the content of the hydroxyl-terminated polysiloxane having the ester bond of the formula (9) was changed from 2 wt% to 15 wt%.

The physical properties of the prepared polysiloxane-polycarbonate copolymer were measured and reported in Table 1 below.

Example  B-6

The content of the hydroxyl-terminated polysiloxane having the ester bond in the above formula (9) was changed from 2 wt% to 5 wt% and the content of p-tert-butylphenol (PTBP) as a molecular weight modifier was changed from 1.5 g to 0.198 g , A polysiloxane-polycarbonate copolymer was prepared in the same manner as in Example B-1.

The physical properties of the prepared polysiloxane-polycarbonate copolymer were measured and reported in Table 1 below.

Comparative Example  B-1

The physical properties of a linear polycarbonate having a viscosity average molecular weight of 31,200 (Samyang, 3030IR) were measured and described in Table 1 below.

Comparative Example  B-2

A linear polycarbonate having a viscosity average molecular weight of 70,900 was prepared in the same manner as in Example B-1, except that the hydroxyl-terminated polysiloxane having an ester bond of the formula (9) was not used.

The physical properties of the linear polycarbonate resin thus prepared were measured and reported in Table 1 below.

Comparative Example  B-3

Except that 5% by weight of the hydroxy-terminated polysiloxane of the following formula (10) was used instead of 2% by weight of the hydroxyl-terminated polysiloxane having the ester bond of the above formula (9), and the polysiloxane-polycarbonate Lt; / RTI &gt;

The physical properties of the prepared polysiloxane-polycarbonate copolymer were measured and reported in Table 1 below.

[Chemical formula 10]

As shown in Table 1 above, the polysiloxane-polycarbonate copolymers prepared according to Examples B-1 to B-6 had a linear polycarbonate resin prepared according to Comparative Examples B-1 and B-2 and Comparative Examples B- Polycarbonate copolymer prepared according to the above-mentioned Polysiloxane-Polycarbonate Copolymer, while maintaining transparency equal to or higher than that of Polysiloxane-Polycarbonate Copolymer prepared according to &quot; 3 &quot;

The performance evaluation methods used in the above Examples and Comparative Examples are as follows.

(a) H-NMR (nuclear magnetic resonance spectroscope): Measured using Avance DRX 300 from Bruker. The peak of the methyl group of the dimethylsiloxane observed at 0.2 ppm by H-NMR and the peak of the methylene group of the polysiloxane-polycarbonate bonded portion observed at 2.6 ppm and the peak of the methoxy group of the polysiloxane-polycarbonate bonded portion observed at 3.9 ppm Respectively.

(b) a viscosity average molecular weight (M _V): for measuring the viscosity of a methylene chloride solution at 20 ℃ using Ube load viscometer (Ubbelohde Viscometer) and an intrinsic viscosity from which the [η] was calculated from the equation below.

^{[η] = 1.23x10 -5 Mv 0} .83

(c) Transmittance: The transmittance was measured using a haze meter (Haze-Gard Plus manufactured by BYK GARDNER).

(d) Flammability: The flame retardancy was measured by the UL-94 flame retardancy test method prescribed by Underwriter's Laboratories (UL) of the United States. This method is a method of evaluating the flame retardancy from the burning time and dripping property after attaching the flame of the burner to the vertically fixed specimen of constant size for 10 seconds. The burning time is the length of time the specimen continues to burn with flame after the flame has been removed and the burning of the cotton by the drip is carried out by a drop of cotton from the label sample about 300 mm below the bottom of the specimen And the flammability rating is divided according to Table 2 below.

Claims (10)

A hydroxyl-terminated polysiloxane having an ester bond represented by the following formula (1):

[Chemical Formula 1]

In Formula 1,
R ₁ independently represents a hydrogen atom, a halogen atom, a hydroxy group, or an alkyl group having 1 to 10 carbon atoms,
R ₂ independently represents an alkyl group having 1 to 13 carbon atoms,
R ₃ independently represents an alkylene group having 2 to 8 carbon atoms,
Y represents a monocyclic or polycyclic aromatic group having 6 to 30 carbon atoms,
m is independently an integer of 0 to 4,
n independently represents an integer of 2 to 1,000. The hydroxy-terminated polysiloxane according to claim 1, which is a reaction product of a hydroxy-terminated siloxane of the following formula (2) and an acyl compound of the following formula (3)

(2)

In Formula 2,
R ₁ independently represents a hydrogen atom, a halogen atom, a hydroxy group, or an alkyl group having 1 to 10 carbon atoms,
R ₂ independently represents an alkyl group having 1 to 13 carbon atoms,
R ₃ independently represents an alkylene group having 2 to 8 carbon atoms,
m represents an integer of 0 to 4,
n represents an integer of 2 to 1,000;

(3)

In Formula 3,
X represents a hydroxy group or a halogen group,
Y represents a monocyclic or polycyclic aromatic group having 6 to 30 carbon atoms. A polysiloxane-polycarbonate copolymer comprising a hydroxy-terminated polysiloxane having an ester linkage of claim 1 or 2 and a polycarbonate block of formula (6) as recurring units:

[Chemical Formula 6]

In Formula 6,
R ₄ represents a divalent aromatic hydrocarbon group having 6 to 30 carbon atoms,
Wherein the bivalent aromatic hydrocarbon group is unsubstituted or substituted with an alkyl group, a cycloalkyl group, an alkenyl group, an alkoxy group, a halogen atom, or nitro. The polysiloxane-polycarbonate copolymer according to claim 3, wherein the content of the hydroxyl-terminated polysiloxane having an ester bond is 0.5 to 20% by weight based on the total weight of the polysiloxane-polycarbonate copolymer. The polysiloxane-polycarbonate copolymer of claim 3, wherein the polysiloxane-polycarbonate copolymer has a viscosity average molecular weight of from 15,000 to 200,000. Reacting a hydroxy-terminated polysiloxane having an ester linkage of claim 1 or 2 with an oligomeric polycarbonate under an interfacial reaction condition to form a polysiloxane-polycarbonate intermediate; And
Polymerizing said polysiloxane-polycarbonate intermediate using a first polymerization catalyst.
A process for producing a polysiloxane-polycarbonate copolymer. 7. The process of claim 6, wherein the step of forming the polysiloxane-polycarbonate intermediate comprises mixing the oligomeric polycarbonate with a hydroxy-terminated polysiloxane having an ester linkage in a weight ratio of from 0.5: 99.5 to 20: 80, -Polycarbonate Copolymer - Patent application 7. The method of claim 6, wherein forming the polysiloxane-polycarbonate intermediate comprises forming a mixture comprising a hydroxy-terminated polysiloxane having an ester bond and an oligomeric polycarbonate, wherein the mixture comprises a phase transfer catalyst, A modifier, and a second polymerization catalyst. &Lt; RTI ID = 0.0 &gt; 8. &lt; / RTI &gt; The method according to claim 6,
The step of forming the polysiloxane-polycarbonate intermediate comprises the steps of: forming a mixture comprising a hydroxyl-terminated polysiloxane having an ester bond and an oligomeric polycarbonate; And extracting the organic phase from the mixture after the reaction of the oligomeric polycarbonate with the hydroxy-terminated polysiloxane having the ester bond is completed,
Wherein the step of polymerizing the polysiloxane-polycarbonate intermediate comprises the step of providing a first polymerization catalyst to the extracted organic phase.
A process for producing a polysiloxane-polycarbonate copolymer. The process for preparing a polysiloxane-polycarbonate copolymer according to claim 6, wherein the oligomeric polycarbonate has a viscosity average molecular weight of 1,000 to 27,000.