KR101893657B1 - Apparatus and application method of generating plasma reactive species for non-thermal sterilization in water - Google Patents

Abstract

It is an object of the present invention to provide a device for sterilizing a non-heated food material by increasing the efficiency of generation of reactive oxygen species and active nitrogen species generated by plasma and ultimately increasing the efficiency of water transfer to water, , Thermal stability, and the like.
The present invention relates to a dielectric tube enclosing and enclosing an outer side of an electrode and a gas pipe for allowing the gas to pass through only a plasma generation section to increase the efficiency of generating active oxygen species and active nitrogen species, And the active oxygen species and the active nitrogen species were transferred to the water in the form of fine bubbles to improve the treatment efficiency. In addition, the present invention is an improved type plasma apparatus in which an auxiliary electrode is provided outside an outer dielectric tube to increase the generation efficiency of active oxygen species and active nitrogen species. The present invention applies plasma-treated water to sterilization of ingredients

Description

TECHNICAL FIELD [0001] The present invention relates to an apparatus and a method for generating a plasma active species for water treatment for non-thermal sterilization,

The present invention relates to an apparatus for generating a discharge gas including active oxygen species and active nitrogen species in a water using plasma and a method of using the same, and more particularly, to an apparatus and a method for producing a discharge gas including an active oxygen species and an active nitrogen species generated from a dielectric barrier discharge plasma To an electrode and a gas pipe structure which can be smoothly injected into water, and a method of utilizing the same.

Plasma is applied to bio- and environmental fields, and reactive oxygen species and active nitrogen species generated by plasma are generated by sterilization of microorganisms. Thus, plasma application researches are actively conducted. Accordingly, sterilized water is produced using plasma, and low-temperature plasma is discharged at atmospheric pressure to use for disinfecting food ingredients. Korean Patent No. 10-1461085 discloses a technique for treating atmospheric pressure low-temperature plasma on the surface of a food material. Such a method should be accompanied with a conventional food material cleaning method in which a foreign object or the like is washed with water. However, in the case of using treated water using a discharge gas, since it is a food material processing method in which plasma processing and sterilization are simultaneously performed, see.

In order to increase the production efficiency of the active species by the plasma discharge, the gas containing oxygen for the plasma discharge section should be confined to a certain extent and be effectively transferred into the water without loss of the active species generated by the plasma.

In addition, since it is desirable to use the atmosphere by eliminating the gas feeder since the utilization of the apparatus is increased by providing portability of the apparatus, a plasma generating apparatus compatible with the confinement of the space in which the gas exists is required.

In addition, a plasma sterilization device for foodstuffs that can be applied variously in real life should have electrical safety and thermal stability.

Meanwhile, in order to exhibit cleaning and germicidal effects on various food materials, it is necessary not only that the active radicals generated by the plasma discharge are abundant, but also the facts discovered by the present inventors through practical experiments are that the ozone generated by the plasma discharge, (OH ^- ) or nitric oxide species (NO _x ^- ). The ozone treatment effect of the ozone is insignificant, but it has a problem that the worker's respiratory health can be deteriorated. Therefore, the kind and amount of the radical generated by the plasma discharge device need to be controlled to perform the desired treatment substantially.

An object of the present invention is to provide a device for disinfection of a food material by improving the efficiency of generation of reactive oxygen species and active nitrogen species generated by plasma and ultimately increasing the efficiency of water transfer into the water, Safety, thermal stability, and the like of the plasma material. That is, the main object of the present invention is to sterilize a subject by injecting active gas of plasma generated in the air into the water for cleaning the foodstuffs contained in the water, the processing equipment, the environment, the dishes and the like.

According to the above object, the present invention provides a dielectric tube which surrounds and surrounds the electrode closely, and a gas pipe is installed so that only a portion of the gas to be injected can pass through the plasma, thereby increasing the efficiency of generating active oxygen species and active nitrogen species, And the length to the injection port into the water was minimized, and active oxygen species and active nitrogen species were transferred to the water in the form of fine bubbles, thereby improving the treatment efficiency.

That is,

A first electrode and a second electrode placed in respective inner dielectric tubes;

An outer dielectric tube in which the first electrode and the second electrode are arranged side by side in a state that they are inserted into the respective inner dielectric tubes and to which a discharge gas is supplied;

A bubble diffuser connected to the outer dielectric tube end and immersed in water; And

And a power source connected to the electrode, wherein the plasma generating device is constituted,

A food material, a food material processing tool or a tableware, which is the object to be treated,

The plasma is discharged through the gas injected into the outer dielectric tube due to the voltage applied to the electrode to generate active species including at least one of hydroxyl group, reactive oxygen species, and active nitrogen species, and is injected into the water in the form of fine bubbles, Respectively,

The plasma is generated by the plasma generator at an energy of 100 to 150 mJ / sec, and active species including at least one of the hydroxyl group, the reactive oxygen species, and the active nitrogen species generated from the plasma are injected into the water, The cleaning method comprising the steps of:

In the above, the object to be treated includes at least one of a food material, a food material processing tool, a food material processing environment, a medical instrument, a medical instrument, or a cover.

In the above, a cleaning method is characterized in that active species including at least one of a hydroxyl group, an active oxygen species or an active nitrogen species generated from a plasma is injected into water for at least 30 seconds for sterilization and cleaning.

In the above, a plasma is generated at an energy of 120 to 150 mJ / sec to lower the concentration of ozone in the generated active species and increase the concentration of hydroxyl groups or active nitrogen species to sterilize and clean.

Further, according to the present invention,

A first electrode and a second electrode placed in respective inner dielectric tubes;

An outer dielectric tube in which the first electrode and the second electrode are arranged side by side in a state that they are inserted into the respective inner dielectric tubes and to which a discharge gas is supplied;

A bubble diffuser connected to the outer dielectric tube end and immersed in water; And

And a power source connected to the electrode, wherein the plasma generating device is constituted,

The water tank is filled with water, the bubble diffuser is put into water,

The plasma is discharged through the gas injected into the outer dielectric tube due to the voltage applied to the electrode to generate active species including at least one of hydroxyl group, reactive oxygen species, and active nitrogen species, and is injected into the water in the form of fine bubbles, Lt; / RTI >

And the object to be treated is washed with the plasma-treated water.

Further, according to the present invention,

A first electrode and a second electrode placed in respective inner dielectric tubes;

An outer dielectric tube in which the first electrode and the second electrode are arranged side by side in a state that they are inserted into the respective inner dielectric tubes and to which a discharge gas is supplied;

A bubble diffuser connected to the outer dielectric tube end and

A plasma generating device including a power source connected to the electrode,

Including a water tank,

Food ingredients, food processing tools or tableware, which are the object to be treated, are put into water in a water tank,

The bubble diffuser of the plasma generating device is immersed in water,

The plasma is discharged through the gas injected into the outer dielectric tube due to the voltage applied to the electrode to generate active species including at least one of hydroxyl group, reactive oxygen species, and active nitrogen species, and is injected into the water in the form of fine bubbles, Respectively,

Characterized in that a plasma having an energy of 100 to 150 mJ / sec is generated with respect to the object to be treated, and active species containing one or more hydroxyl groups, reactive oxygen species or active nitrogen species generated therefrom are supplied to water for sterilization and cleaning Device.

In the above, an auxiliary electrode is formed outside the outer dielectric tube to improve the generation of active species including at least one of the hydroxyl groups of the plasma, the active oxygen species, and the active nitrogen species, And a cleaning device for cleaning the surface of the substrate.

In the present invention, it is not necessary to use a separate gas supply cylinder by using air in the atmosphere as a discharge gas, so that the portability is very good. The plasma gas discharged due to the gas pipe structure is not lost and uniform and rich active oxygen species and active nitrogen species can be obtained according to the treatment time.

According to the present invention, the bacteria can be sterilized for about 30 seconds to about 1 minute by the plasma-treated bubble water, which is very useful for sterilizing and cleaning food materials.

Further, according to the present invention, it is possible to increase production rates of hydroxyl groups, nitrogen active species, and the like, which are useful for germicidal cleaning treatment of food ingredients, and to control the production rate of ozone which is relatively low in usability and can prevent operator's safety, Can be performed.

In addition, the plasma treated water according to the present invention is industrially useful because it can be treated like ordinary water without a separate wastewater treatment step since the half-lives of active species are not so short as compared with the treated water such as foodstuffs by chemical treatment .

In addition, the plasma-treated water according to the present invention can improve the microbiological safety by treating food materials and the like, immersing tools such as processing equipment, cutting boards, and washing water for the food processing chamber.

1 is a configuration diagram showing a plasma generating apparatus according to the present invention.
FIG. 2 is a photograph showing the entire construction of the plasma generating apparatus according to the present invention.
FIG. 3 shows a device configuration and an experimental condition table for an experiment to sterilize crops such as leaf leaves using the plasma generating apparatus according to the present invention.
FIG. 4 shows a voltage-current graph applied to the plasma generating apparatus of FIG. 3 and an optical spectrum graph for analyzing active species generated from the plasma generating apparatus.
FIG. 5 shows an apparatus for measuring the concentration of active species NO ₂ generated from a plasma generator in a discharge gas, conditions and measurement results thereof.
FIG. 6 is a graph showing the changes in the concentration of the active species as a function of the voltage application time for the plasma generating apparatus, and the change in the state such as temperature and pH.
7 is photographs showing sterilization of bacteria in water using the plasma generating apparatus of the present invention.
FIG. 8 is a photograph and a graph of an experiment in which bacterial-infected sesame leaves were treated with plasma to confirm the sterilizing power as in the experiment of FIG.
9 is a front view and a cross-sectional view illustrating the improved plasma electrode structure in detail according to the present invention. An auxiliary electrode is formed outside the outer dielectric tube of Fig.
FIG. 10 is a photograph showing that plasma is discharged by applying power to the plasma electrode of FIG.

Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.

Fig. 1 shows a configuration of a plasma generating apparatus used for performing heat pretreatment and sterilization of food ingredients using the plasma of the present invention.

The plasma generator is constructed by closely surrounding the linear electrode 100 with the dielectric tube 200 and enclosing the linear electrode 100 in the gas pipe 300. Generally, the covered wires are covered with a dielectric, so they can be put in a gas pipe. In this embodiment, two electrodes 100 coated with a dielectric material are bundled with a fixing member 400 made of an insulator ring and placed in a gas pipe 300 made of an insulator. A gas pipe 300 is fixed to the end of the gas pipe 300 with a fixing member 500) were fixed. The front surface of the gas connection pipe 500 has an opening to allow gas to flow in and out. The pair of electrodes are arranged side by side so that a plasma discharge occurs between both electrodes. For convenience, the first electrode and the second electrode may be referred to as a dielectric tube 200 and an inner dielectric tube, and the gas tube 300 may be referred to as an outer dielectric tube.

An AC power source was applied to one end of each electrode 100 and the other end was left as a floating DBD plasma generator. That is, the ground electrode is left without being constructed separately, and the plasma is discharged with the water surface as the ground surface. The output voltage is adjusted from 2.75 kV to 10 kV as an alternating current of 100 kHz or less depending on the situation. That is, it will selectively control the plasma energy to be applied depending on the application, such as the capacity of the object to be treated and the species of bacteria to be treated.

The discharge gas uses air without a separate gas supply pipe, and preferably a fan (not shown) for blowing air into the gas pipe 300 can be provided. That is, a tube having a fan is connected to the gas pipe 300, and a plasma discharge occurs due to the electrode 100 to which air is introduced and a high voltage is applied. Plasma discharges generate active species including a large amount of reactive oxygen species and active nitrogen species, and air including active oxygen species and / or active nitrogen species is sent to the water due to the blowing action of the fan to form microbubbles (See FIG. 3). These microbubbles become a medium for transporting active oxygen species and / or active nitrogen species and spread in the supplied water to impart a sterilizing power. Microbubbles are a means of high concentration of radicals in the bubbles themselves, and water containing active species gas containing them provides a highly effective sterilization effect. That is, each bubble forms a kind of isolated system, and active oxygen species and / or active nitrogen species contained therein are highly concentrated in the isolated system, and are transported in this state to provide high concentration radicals to the object to be treated.

In this embodiment, the gas to be injected increases the efficiency of generating active oxygen species by providing a gas pipe so that only the portion where the plasma is generated, and minimizes the length from the discharge section to the inlet to the water, Oxygen species were transferred to the water to increase the treatment efficiency.

FIG. 2 is a photograph showing a configuration of the plasma generating apparatus according to the present embodiment as a whole. A plasma source section, a chamber structure for sample processing, a slicer power supply, and a voltage transformer section. 1, a bubble diffuser may be connected to one end of the electrode to be used for water treatment. In the present embodiment, the bubble diffuser is made of porous ceramics, which is commercially available and can be easily purchased from an aquarium supply store.

In this case, the electrode may be made of a conductor other than copper, and the inner quartz tube and the outer quartz tube may be made of other dielectric materials such as glass, ceramics and the like.

Next, the plasma-treated bubble water generated by using the plasma generating apparatus of the present invention was applied to a sesame leaf sterilization treatment.

FIG. 3 shows a device configuration and an experimental condition table for an experiment to sterilize crops such as leaf leaves using the plasma generating apparatus according to the present invention. In this case, the voltage applied to the electrode of the plasma generator is controlled by the slider duck, the AC power is applied to the electrode through the neon transfer, and air is supplied through the air compressor to generate micro bubbles. 3, a bubble diffuser was connected to the end of the plasma generator, and the bubble diffuser was inserted into the water tank to enable the active gas generated in the plasma to enter into the water in the form of micro bubbles. In the water tank, And sesame leaves. Bacterial infected sesame leaves may be placed with deionized water (DI water). Although specific experimental conditions are shown in the table, these values are exemplary and can be adjusted. The energy supplied by the plasma was 120 mJ / sec, but the same results can be obtained even at 100 to 150 mJ / sec, which is somewhat deviated from this. The treatment time is preferably at least 30 seconds, and a sufficient effect can be obtained within about 1 minute, which can be maintained for a maximum of 300 seconds.

FIG. 4 shows a voltage-current graph applied to the plasma generating apparatus of FIG. 3 and an optical spectrum graph for analyzing active species generated from the plasma generating apparatus.

NO, NO ₂ , NO ₂ ^- , NO ₃ ^- _{, and} active species were detected by the combination of N ₂ * (N ₂ second positive system: 200 to 310 nm band) and O (777, 852 nm band) And, as is known, ozone is produced by the following reaction.

O ₂ + O? O ₃ (254 nm) _,

Also, OH · (OH radical: 309 nm band) + OH · H ₂ O ₂ (254 nm) is generated.

5 shows an apparatus, conditions and measurement results for measuring the concentration of NO ₂ generated from the plasma generating apparatus. The measured NO ₂ concentration was about 115 ppm.

FIG. 6 is a graph showing changes in the concentration of the active species with respect to the voltage application time for the plasma generating device, and the change in the state such as temperature and pH. Data were collected with a treatment time of up to 300 seconds at 2.75 kV and 3.75 kV applied voltage and the concentrations of hydrogen peroxide, nitrogen monoxide and hydroxyl were shown. The applied voltage is one experimental value, and about 2.75 to 10 kV can be applied to impart the sterilizing power to the treatment water of about 50 ml. The ozone concentration was measured in the gaseous state with the applied voltage as a factor. The voltage shown in the graph of Fig. 6 is a sliced duck applied voltage.

The concentration of hydrogen peroxide, nitrogen monoxide, and hydroxyl groups generated by the plasma was found to be higher in the case of application of 3.75 kV than in the case of 2.75 kV in most cases, and the concentration thereof tended to increase with increasing treatment time. The pH gradually decreased when the treatment time was 30 seconds, and the ozone concentration was decreased as the applied voltage increased.

As described above, in order to increase the concentrations of hydroxyl radicals and nitric oxide species, which are more effective in the treatment of foodstuffs, it is preferable to treat them for 30 seconds to 3 minutes at an applied voltage higher than 2.75 kV on the basis of 50 ml treated water in order to lower the concentration of ozone see. When the amount of treated water is increased, a plurality of plasma sources of the same structure may be constructed or the applied voltage may be increased.

In the treatment of food ingredients, hydroxyl groups and nitric oxide species exhibit microbicidal effect, but relatively little ozone has a bactericidal effect. In particular, since the active species exhibit a scavenging reaction with respect to antioxidants, the method of the present invention is preferably applied to an initial stage treatment in which the food material is not cut off, in view of sterilizing effect and nutrition.

It is preferable to clean and / or sterilize the foodstuff using the plasma-treated water as described above at the initial stage, and then clean it with pure water to remove the residual material remaining on the surface of the foodstuff. There may be a problem of browning the ingredients.

7 are photographs showing the sterilization of suspension of liquid cultured bacteria ( Escherichia coli and Staphylococcus aureus ) using the plasma generating apparatus of the present invention. It can be seen that the concentration of the plasma-treated bacteria was drastically lowered for 60 seconds.

FIG. 8 is a photograph and a graph of bactericidal activity inoculated on a sesame leaf through the experiment of FIG. 3; FIG. It was confirmed that the concentrations of bacteria ( E. coli and S. aureus ) in plasma treated sesame leaf for 1 minute were significantly lowered.

It can be concluded that bacteria and the like are sufficiently killed by the plasma treatment bubble water treatment for 2 minutes. Therefore, it is possible to apply processed water using plasma generating equipment to foodstuffs such as vegetables, fruit, fish, meat, fish and shellfish, process equipment, and production site.

FIGS. 9 and 10 illustrate an alternative embodiment in which the configuration of the plasma electrode is modified and improved to cause a more active discharge. A plasma source portion, a slicing power supply, and a voltage changing portion are proposed. The electrode configuration of the plasma source portion is shown in detail in Fig. Place the two copper electrodes in an insulated inner quartz tube, arrange them side by side, and place them in an outer quartz tube with the inner quartz tube in it. Both ends of the quartz tube are fixed with a silicone tube inserted and plugged with an insulating plug (for example, rubber, plastic, etc.).

In the case of Fig. 9, an auxiliary electrode made of copper was wound around the outer wall of the outer quartz tube and connected to both ends of the power source. One terminal of the power source is also connected to the copper electrode wound on the outer wall of the outer quartz tube. That is, any one of the electrodes to which the AC power is applied may be inserted into the inner quartz tube and wound around the outer wall of the outer quartz tube. A main discharge occurs between the electrodes arranged side by side in the inner quartz tube and an auxiliary discharge occurs between the electrode wrapped around the outer quartz tube and the counter electrode in the inner quartz tube so that the efficiency of the plasma discharge can be expected, Radicals can be generated. The counter electrode means an electrode to which the auxiliary terminal and the same terminal of the power source are not connected.

After such an electrode structure, a bubble diffuser may be connected to one end of the electrode to be used for water treatment. In the present embodiment, the bubble diffuser is made of porous ceramics, which is commercially available and can be easily purchased for aquarium.

In this case, the electrode may be made of a conductor other than copper, and the inner quartz tube and the outer quartz tube may be made of other dielectric materials such as glass, ceramics and the like.

FIG. 10 shows photographs of the electrodes and the electrodes in which the main discharge and the auxiliary discharge are taking place.

On the other hand, radicals may be present in the treated water after cleaning and / or sterilizing the foodstuffs and the like with the plasma-treated water constructed as in the above embodiment, but they have a very short half-life and are discharged without being subjected to a separate wastewater treatment step It is industrially advantageous and environmentally friendly.

In addition, it is possible to obtain the effect of sterilization cleaning by immersing or flowing a food processing tool such as a cutting board using residual radicals in the remaining processed water. That is, after the recycled residual water is recycled, it can be discharged as ordinary water (water) instead of wastewater.

The electrode of this structure can obtain a very rich plasma discharge and active species, thus enabling more efficient disinfection of foodstuffs and utensils, food processing equipment, food processing environment (referring to space for handling foodstuffs), medical equipment, medical instruments, Can be performed.

It is to be understood that the invention is not limited to the disclosed embodiment, but is capable of many modifications and variations within the scope of the appended claims. It is self-evident.

100: electrode (first electrode, second electrode)
200: dielectric tube (internal dielectric tube)
300: Gas pipe (outer dielectric pipe)
400: Fixing member
500: gas connection pipe
600: diffuser

Claims (7)

A first electrode and a second electrode placed in respective inner dielectric tubes;
An outer dielectric tube in which the first electrode and the second electrode are arranged side by side in a state that they are inserted into the respective inner dielectric tubes and to which a discharge gas is supplied;
An auxiliary electrode wound around the outer wall of the outer dielectric tube;
A bubble diffuser connected to the outer dielectric tube end and immersed in water; And
And a power source connected to the first electrode, the second electrode, and the auxiliary electrode,
The object to be treated is put into water,
The plasma generating device is a DBD (Dielectric Barrier Discharge) plasma generating device. The plasma is discharged between a first electrode and a second electrode, and between an auxiliary electrode and the first electrode and a second electrode,
The plasma is discharged through the gas injected into the outer dielectric tube due to the voltage applied to the electrode to generate active species including at least one of hydroxyl group, reactive oxygen species or active nitrogen species, and is injected through the fine bubbles into the water, Respectively,
The plasma is generated by the plasma generator at a plasma energy of 100 to 150 mJ / sec, and active species including at least one of the hydroxyl group, the reactive oxygen species, and the active nitrogen species generated from the generated plasma are injected into the water, The cleaning method comprising: The cleaning method according to claim 1, wherein the object to be treated includes at least one of a food material, a food material processing tool, a food material processing environment, a medical instrument, a medical instrument, or a cover. The cleaning method according to claim 1, wherein the active species generated from the plasma is injected into water for at least 30 seconds to sterilize and clean. The cleaning method according to claim 1, wherein the plasma is generated at an energy of 120 to 150 mJ / sec to lower the concentration of ozone in the generated active species and increase the concentration of hydroxyl groups or active nitrogen species to sterilize and clean. A first electrode and a second electrode placed in respective inner dielectric tubes;
An outer dielectric tube in which the first electrode and the second electrode are arranged side by side in a state that they are inserted into the respective inner dielectric tubes and to which a discharge gas is supplied;
An auxiliary electrode wound around the outer wall of the outer dielectric tube;
A bubble diffuser connected to the outer dielectric tube end and immersed in water; And
And a power source connected to the first electrode, the second electrode, and the auxiliary electrode,
The water tank is filled with water, the bubble diffuser is put into water,
The plasma is discharged through the gas injected into the outer dielectric tube due to the voltage applied to the first electrode, the second electrode and the auxiliary electrode, and active species including at least one of hydroxyl group, reactive oxygen species or active nitrogen species are generated, Is injected into the water through the bubble to form plasma-treated water,
And the object to be treated is washed with the plasma-treated water. A first electrode and a second electrode placed in respective inner dielectric tubes;
An outer dielectric tube in which the first electrode and the second electrode are arranged side by side in a state that they are inserted into the respective inner dielectric tubes and to which a discharge gas is supplied;
An auxiliary electrode wound around the outer wall of the outer dielectric tube;
A bubble diffuser connected to the outer dielectric tube end and
And a power source connected to the first electrode, the second electrode, and the auxiliary electrode,
A water tank,
The object to be treated is placed in water in the water tank,
The bubble diffuser is placed in the water,
The plasma is discharged through the gas injected into the outer dielectric tube due to the voltage applied to the first electrode, the second electrode and the auxiliary electrode, and active species including at least one of hydroxyl group, reactive oxygen species or active nitrogen species are generated, Is injected into the water through the bubble to form a plasma treatment water,
Characterized in that a plasma having an energy of 100 to 150 mJ / sec is generated with respect to the object to be treated, and the active species containing at least one hydroxyl group, active oxygen species or active nitrogen species generated therefrom is sterilized and cleaned by supplying water thereto. .










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