KR101888813B1 - A method for manufacturing environmentally-friendly smoke fogging agent using vegetable oil - Google Patents

Abstract

The present invention relates to a method for manufacturing an environmentally-friendly smoke and fog screening agent using vegetable oil. Especially, the present invention relates to a method for manufacturing an environmentally-friendly smoke and fog screening agent, which can solve environmental pollution fundamentally by using pure vegetable oil and biodegrading the vegetable oil, is safe for the human body, enables mixing to be made quickly and uniformly when a user uses the agent mixed with a filler and a homogenizer, and maximizes a medicinal effect at the time of spraying; to an environmentally-friendly smoke and fog screening agent manufactured by the method, and to a manufacturing device for effectively manufacturing the environmentally-friendly smoke and fog screening agent.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a method for manufacturing an environmentally-friendly smoke fogging agent using vegetable oil,

The present invention relates to a method for manufacturing an environmentally friendly fogging smoke film using vegetable oil, and in particular, it is possible to solve environmental pollution by using pure vegetable oil and biodegrade it, and is safe for human body, The present invention also relates to a method for producing an environmentally friendly mist film and an environmentally friendly mist film produced by the method. The environmentally friendly mist film can be effectively To a manufacturing apparatus that can be manufactured. The present invention also relates to an eco-friendly biosimilant including the environmentally-friendly fogging smoke-curing agent.

The following description merely provides background information related to the present invention and does not constitute the prior art.

Recently, various kinds of pests and viruses including bird flu and bird flu have been increasingly present. As a result, diseases and infectious diseases occurring in people, plants and animals have been greatly increased, and there has been a growing interest in the prevention and control technology thereof. It is not enough to take effective countermeasures.

Conventionally, water spraying has been used for dilution and spraying of various kinds of disinfecting and controlling chemicals.

There has been a problem that the water spraying method is a method of spraying water with a sprayer by diluting a medicine with water, a spraying efficiency to a wide space is lowered, and a medicament can not be delivered to the pests and pests in the lower part of the crop.

In order to solve the problems of the spraying of the water spraying agent, a method of increasing the scattering distance and the spraying time of the spraying liquid by adding a small amount of a high viscosity liquid raw material when diluting water and medicine has been devised and used, There has been a problem that the spreading efficiency of the chemicals is low due to the scattering and diffusibility of the dispersing agent.

On the other hand, a spray coating method has been used in which a diluent is diluted with a petroleum-based liquid and heated by a heating type smoke-coating machine. However, the petroleum-based liquid has high toxicity and carcinogenic properties such as benzene, xylene and toluene, There is a problem that suspected substances of environmental hormones are injected.

In order to solve the problems of the petroleum-based liquid spraying method, a prior patent (Korean Patent Registration No. 10-0930653) in which biodiesel and water are mixed with a surfactant uses 67 to 75% by weight of biodiesel (BD100) The use of 28 to 22% by weight of water was used. However, since biodiesel has a too high vaporization rate in a film-forming machine, it is not vaporized in the film, and there are few effective components to be sprayed into fine particles, And it is difficult to use in winter season due to low pour point, and there are problems such as clogging of filter, phase separation of distribution phase, and change of physical properties.

In addition, as social demand for instant food explosively increases, the consumption of vegetable cooking oil increases, and a large amount of waste cooking oil is generated from the vegetable cooking oil. Therefore, there is no suitable use for recycling of such waste cooking oil, Although the waste cooking oil is recycled to the smoke smoke-curing agent, there is a problem that the environmental hormone suspected substances may be contained.

Patent Document 001: Korean Patent Registration No. 10-0930653 (Fogging Diffusion Agent)

The object of the present invention is to use pure vegetable oil without using light oil or kerosene, which is a large inducing factor of environmental pollution, to biodegrade and to solve environmental pollution fundamentally, to be safe for human body, The present invention provides a process for producing an environmentally friendly mist smoke film which can be uniformly carried out when mixing a homogenizer and an excipient and can achieve the best fermentation of medicinal efficacy at the time of spraying and to provide an environmentally friendly mist smoke film produced by the above method .

It is still another object of the present invention to provide an apparatus for manufacturing an environmentally friendly mist smoke film, which can efficiently and efficiently produce the environmentally-friendly mist smoke film.

It is another object of the present invention to provide an eco-friendly bio-insecticide which is eco-friendly and high in insecticidal power, including the eco-friendly mist film.

In order to solve such a problem,

S1) preparing a pure vegetable oil;

S2) < / RTI >

S3) mixing and stirring the vegetable oil and the catalyst solution;

S4) separating glycerin, water, and fatty acid methyl ester from the stirred product of S3), respectively;

S5) mixing the separated glycerin and fatty acid methyl ester; And

S6) mixing an emulsifier in the mixture of S5);

The present invention also provides a method for producing an environmentally friendly mist film.

Preferably, the vegetable oil is a pure vegetable oil not mixed with waste cooking oil.

The mixing and stirring of the above S3) may be carried out at 40 to 60 占 폚.

Specifically, the emulsifier is a phospholipid surfactant.

Preferably, neopentyl glycol dicaprylate can be further mixed before and after the mixing of the emulsifier.

A material selected from the group consisting of an insecticide, a bactericide, a disinfectant, a deodorant, a microbial agent, a mineral agent and a plant nutrient may be further mixed before and after mixing the emulsifier.

The present invention also provides an environmentally-friendly mist film produced by the above-described method.

The environmentally friendly mist smoke-

a) fatty acid methyl esters;

b) glycerin;

c) emulsifiers;

. ≪ / RTI >

The eco-friendly mist film may further include neopentyl glycol dicaprylate.

Also,

Vegetable oil supply;

A vegetable biodiesel supply;

A catalyst supply unit;

An emulsifier supply unit;

A catalyst solution preparation unit for mixing the plant biodiesel supplied from the plant biodiesel supply unit and the catalyst supplied from the catalyst supply unit;

A reaction unit for mixing and stirring the vegetable oil supplied from the vegetable oil supply unit and the catalyst solution supplied from the catalyst solution production unit;

A glycerin storage part for storing the glycerin supplied from the reaction part;

A fatty acid methyl ester storage part for storing the fatty acid methyl ester provided from the reaction part;

A water tank for containing water supplied from the reaction unit;

A mixing unit for mixing the glycerin provided from the glycerin storage unit, the fatty acid methyl ester provided from the fatty acid methyl ester storage unit and the emulsifier supplied from the emulsifier supply unit;

The present invention also provides an apparatus for manufacturing an environmentally friendly mist film.

The mixing part may further include a neopentyl glycol dicaprylate supplying part for providing neopentyl glycol dicaprylate.

The mixing part may further include a chemical supply part for supplying a chemical solution. The glycerin storage portion and the fatty acid methyl ester storage portion may further include flushing means.

The present invention also provides an eco-friendly bio-insecticide including the environmentally-friendly fogging smoke film.

The eco-friendly bio-insecticide may be one prepared by mixing water, potassium hydroxide, and saliva oil with stirring, first aging, and then mixing the water with the environmentally-friendly mist smoke-aging agent followed by secondary aging.

Specifically, the insecticidal oil is canola oil or cashew nut oil.

According to the present invention, pure vegetable oil is used and biodegraded to solve the environmental pollution, and it is safe for the human body, and the user can quickly and uniformly mix the filler and the herbicide when they are mixed, The present invention can provide a method for manufacturing an environmentally friendly mist smoke film and an environmentally friendly mist film manufactured by the method.

Further, the apparatus for manufacturing an environmentally friendly mist smoke film can efficiently produce the environmentally-friendly mist smoke film with high productivity.

Further, the present invention can provide an eco-friendly bio-insecticide which is eco-friendly and highly insecticidal by using pure vegetable oil having an eco-friendly biosurfactant effect.

1 is a schematic view showing a method of manufacturing an environmentally-friendly mist smoke diffusing agent according to an embodiment of the present invention.
2 is a schematic view showing an apparatus for manufacturing an environmentally-friendly mist smoke spreading agent according to an embodiment of the present invention.
Reference numerals
110: Vegetable oil supply part
120: Biodiesel supplier
130: catalyst solution producing part
140:
150: Reaction part
160: glycerin storage
170: Water tank
180: fatty acid methyl ester storage
190: mixing part
200: Emulsifier supplier
210: neopentyl glycol dicaprylate supply part
220: Eco-friendly mist smoke storage unit

Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings so that those skilled in the art can easily carry out the present invention. The present invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. In order to clearly illustrate the present invention, parts not related to the description are omitted, and similar parts are denoted by like reference characters throughout the specification.

Throughout the specification, when an element is referred to as " comprising ", it means that it can include other elements as well, without excluding other elements unless specifically stated otherwise.

1 is a schematic view showing a method of manufacturing an environmentally-friendly mist smoke diffusing agent according to an embodiment of the present invention.

The manufacturing method of the environmentally friendly mist smoke-

S1) preparing a pure vegetable oil;

S2) < / RTI >

S3) mixing and stirring the vegetable oil and the catalyst solution;

S4) separating glycerin, water, and fatty acid methyl ester from the stirred product of S3), respectively;

S5) mixing the separated glycerin and fatty acid methyl ester; And

S6) mixing an emulsifier in the mixture of S5);

.

Preferably, the vegetable oil of S1) is a pure vegetable oil. The present invention does not recycle vegetable waste cooking oil, and uses pure vegetable oil to prevent environmental pollution, and to produce an environmentally friendly mist smoke-free agent which is harmless to people, plants and animals, with high productivity and high efficiency. Specifically, the vegetable oil may be a vegetable oil derived from rapeseed oil, sunflower oil, soybean oil, coconut oil, jatropha oil or cashew nut oil. Preferably, the vegetable oil of S1) is maintained at 40 to 60 DEG C through a heating means and a warming means.

The catalyst solution of S2) can be prepared by mixing a catalyst with a plant biodiesel. The catalyst of step S2) may be a substance that allows methanol and vegetable oil to react with each other to form a fatty acid methyl ester (FAME). Specifically, the catalyst may be sodium hydroxide or potassium hydroxide, and the plant biodiesel may be ethanol .

Step S3) is a step of mixing and stirring the prepared vegetable oil and the catalyst solution, and when the stirring is completed, the stirred product is separated into glycerin, water and fatty acid methyl ester. Preferably, the temperature of the reaction part is maintained at 40 to 60 DEG C during the mixing and stirring. In this case, the reaction rate can be maximized and the amount of unreacted vegetable oil and methoxide can be minimized. When the temperature is lowered to room temperature after stirring, the glycerin layer, the water layer and the fatty acid methyl ester layer The separation between layers is clearly made so that the separation process can be carried out easily and the washing process can be reduced.

Specifically, after mixing the vegetable oil and the catalyst solution into the reaction part, the mixture is homogeneously mixed with stirring at a stirring speed of 50 to 500 rpm for about 5 to 30 minutes and then mixed at a speed of 1,500 to 2,000 rpm for 30 minutes to 1 hour With stirring, and allowed to stand at room temperature for 1 to 12 hours. The fraction may be separated into 10 to 15 parts by weight of glycerin, 0.01 to 5 parts by weight of water and 80 to 90 parts by weight of fatty acid methyl ester by a specific gravity difference.

Then S4) separates the fractions separated from the reactor into glycerin, water, and fatty acid methyl esters, respectively, into respective reservoirs. The separated fractions, glycerin and fatty acid methyl esters are preferably purified by removing impurities (glyceride, free fatty acid, salt, methanol, water, etc.) through a distillation process (100-120 ° C). In the case of the present invention, particularly when ethanol-modified catalyst solution is used, the productivity can be further improved by refining without washing.

Step S5) is a step of mixing the separated glycerin and the fatty acid methyl ester. The mixing ratio may be arbitrarily controlled in the range of 5 to 50 parts by weight of glycerin and 50 to 95 parts by weight of fatty acid methyl ester, preferably 10 to 20 parts by weight of glycerin and 80 to 90 parts by weight of fatty acid methyl ester good. When the amount is within the above range, the particle size of the aerosol spraying agent sprayed is appropriate and the spraying range is wide, and the best efficacy can be exhibited.

Step S6) is a step of further mixing an emulsifier with a mixture of glycerin and fatty acid methyl esters. The mixing of the emulsifier in the step S6) may be performed simultaneously with the step S5). The emulsifying agent may be a known emulsifying agent used in the aerosol spraying agent. Preferably, the emulsifying agent is a phospholipid surfactant. The emulsifying agent is used in an amount of 1 to 10 parts by weight per 100 parts by weight of the mixture of glycerin and fatty acid methyl ester It is good. In this case, the particle size of the aerosol spraying agent sprayed is appropriate, and the spraying range is wide, and the best efficacy can be exhibited.

Preferably, the manufacturing method of the environmentally friendly mist smoke film of the present invention may further comprise mixing neopentyl glycol dicaprylate in step S5) or step S6). The neopentyl glycol dicaprylate is preferably 5 to 20 parts by weight per 100 parts by weight of the mixture of glycerin and fatty acid methyl ester. The neopentyl glycol dicaprylate facilitates uniform mixing of fatty acid methyl esters and glycerin and improves storage stability. In addition, when neopentyl glycol dicaprylate is used as a smoke haze agent, it can facilitate uniform mixing even in the course of mixing with water, It is possible to exhibit the best efficacy efficiency with a wide range of the sprayed particle size of the smoke smoke film.

Further, the method for producing an environmentally friendly mist smoke film of the present invention is characterized in that at least one selected from the group consisting of a pesticide, a bactericide, a disinfectant, a deodorant, a microbial agent, a mineral agent and a plant nutrient is selected before or after the mixing of the emulsifier in the step S5) or S6) The material can be further mixed. These materials may be any of the known materials used in aerosol formulations. In addition, the process for producing an environmentally-friendly mist film of the present invention may further include known substances used in aerosol films such as lecithin-based water-soluble liquid fatty acids or propylene glycol.

The present invention provides an eco-friendly mist film produced by the method of manufacturing the environmentally friendly mist film. Specifically, the eco-friendly mist film according to the present invention comprises a) 50 to 95 parts by weight of a fatty acid methyl ester; b) 5 to 50 parts by weight of glycerin; c) 1 to 10 parts by weight of an emulsifier. Preferably, the eco-friendly mist film according to the present invention further comprises neopentyl glycol dicaprylate. The neopentyl glycol dicaprylate is preferably 5 to 20 parts by weight per 100 parts by weight of the mixture of glycerin and fatty acid methyl ester. The neopentyl glycol dicaprylate facilitates uniform mixing of fatty acid methyl esters and glycerin and improves storage stability. In addition, when neopentyl glycol dicaprylate is used as a smoke haze agent, it can facilitate uniform mixing even in the course of mixing with water, It is possible to exhibit the best efficacy efficiency with a wide range of the sprayed particle size of the smoke smoke film.

The eco-friendly mist film according to the present invention may further comprise at least one material selected from the group consisting of an insecticide, a bactericide, a disinfectant, a deodorant, a microbial agent, a mineral agent and a plant nutrient.

The eco-friendly mist film according to the present invention may be used by mixing the water and the water with the water. In this case, the water and the water may be mixed in a weight ratio of 1: 0.5 to 3. In this case, it is more advantageous to maximize the smoke diffusing property of the aerosol smoke film and the active ingredient of the medicinal substance contained in the aerosol smoke film.

The present invention provides an apparatus for manufacturing an environmentally-friendly mist smoke film, which can efficiently produce the environmentally-friendly mist smoke film with high productivity.

2 is a schematic view showing an apparatus for manufacturing an environmentally-friendly mist smoke spreading agent according to an embodiment of the present invention.

The apparatus for manufacturing an environmentally friendly mist smoke film according to the present invention comprises

A vegetable oil supply unit 110;

A vegetable biodiesel feeder 120;

A catalyst supply unit 140;

An emulsifier supply unit 200;

A catalyst solution producing unit 130 for mixing the vegetable biodiesel supplied from the vegetable biodiesel supply unit 120 and the catalyst supplied from the catalyst supply unit 140;

A reaction unit 150 for mixing and stirring the vegetable oil supplied from the vegetable oil supply unit 110 with the catalyst solution supplied from the catalyst solution production unit 130;

A glycerin storage 160 for storing the glycerin supplied from the reaction unit 150;

A fatty acid methyl ester storage part 180 for storing the fatty acid methyl ester provided from the reaction part;

A water tank 170 for containing water provided from the reaction unit;

A mixing part 190 for mixing the glycerin provided from the glycerin storage part 160, the fatty acid methyl ester provided from the fatty acid methyl ester storage part 180 and the emulsifier supplied from the emulsifier supply part 200;

. ≪ / RTI >

The apparatus for manufacturing an environmentally friendly mist smoke film may further include a neopentyl glycol dicaprylate supply unit 210 in which the mixing unit 190 provides neopentyl glycol dicaprylate.

The apparatus for manufacturing an environmentally friendly mist film according to the present invention is characterized in that the mixing unit 190 comprises a chemical liquid supply unit (not shown) for providing a material selected from the group consisting of an insecticide, a bactericide, a disinfectant, a deodorant, a microbial, a mineral, As shown in FIG.

The glycerin storage portion and the fatty acid methyl ester storage portion may further include water washing means and distillation means.

Specifically, the vegetable oil supplying portion 110 is a storage portion of a rape oil, sunflower oil, soybean oil, coconut oil, jatropha oil or cashew nut oil,

And a heating means capable of maintaining the temperature at 40 to 60 DEG C and a warming means to supply the vegetable oil to the reaction portion 150 through the automatic regulating pump 111. [

The vegetable biodiesel supplier 120 supplies the vegetable biodiesel to the catalyst solution producing unit 130 through the automatic regulating pump 121 and the catalyst supplier 140 supplies the calculated catalyst to the automatic regulating pump 130. [ Is supplied to the catalyst solution producing unit (130) through the catalyst (141). The catalyst solution producing unit 130 may include an agitator to easily dissolve the catalyst in the plant biodiesel and may include a heating means and a warming means capable of maintaining the temperature at 40 to 60 ° C, To the reaction part (150).

The reaction part 150 is a reaction part 150 which reacts the vegetable oil supplied from the vegetable oil supply part 110 and the catalyst solution supply part 130 with the catalyst solution to produce glycerin, water and fatty acid methyl ester, A heating means capable of maintaining the temperature at 40 to 60 DEG C and a heating means, and a cooling means may be provided for rapid cooling of the reaction portion 150 during the standing state. In addition, the reaction unit 150 may include stirring means for uniform mixing and rapid reaction of the mixture.

Upon completion of the reaction in the reaction part 150, the glycerin, water and fatty acid methyl esters are fractionated into the glycerin layer, the water layer and the fatty acid methyl ester layer, respectively, by the specific gravity difference. The glycerin layer is separated from the reaction part 150 into the glycerin storage part 160. The water layer is separated into the water tank 170 and the fatty acid methyl ester layer is separated into the fatty acid methyl ester storage part 180. [

The glycerin storage unit 160 and the fatty acid methyl ester storage unit 180 may be equipped with flushing means capable of performing a flushing process, A distillation means may further be provided. The water tank 170 may be washed with water supplied from the water tank 170.

The glycerin stored in the glycerol storage unit 160 is supplied to the mixing unit 190 through the automatic regulating pump 161 and the fatty acid methyl ester stored in the fatty acid methyl ester storage unit 180 is automatically regulated And supplies it to the mixer 190 through the pump 181. [ An emulsifier supplying unit 200 is connected to the mixing unit 190 so that the emulsifying agent is supplied to the mixing unit 190 through the automatic regulating pump 201. The neopentyl glycol dicaprylate feeding part 210 is connected to the mixing part 190 so that neopentyl glycol dicaprylate is supplied to the mixing part 190 through the automatic regulating pump 211. A chemical liquid supply unit (not shown) is connected to the mixing unit 190, and the chemical liquid is supplied to the mixing unit 190 through the automatic control valve. The mixing unit 190 may further include a stirrer for homogenous mixing of materials to be mixed.

The eco-friendly mist paint mixed in the mixing portion 190 is transferred to the environmentally-friendly mist smoke storage portion 220 through the automatic regulating pump 191 and becomes a packaged product.

The manufacturing and disposing of the environmentally-friendly mist smoke film according to the present invention is advantageous in that it is possible to manufacture a mist smoke film agent safely at a low temperature and high productivity.

The present invention also provides an eco-friendly bio-insecticide including the environmentally-friendly fogging smoke film. Specifically, the eco-friendly biosimilant according to the present invention is prepared by mixing water, potassium hydroxide, and saliva oil with stirring, firstly aging the mixture, mixing the water and the environmentally-friendly mist smoke-fouling agent, and then aging the mixture for a second time. Preferably, the content of the substance used for the preparation of the primary aged product is 1 to 4 parts by weight of water, 1.5 to 5 parts by weight of potassium hydroxide and 15 to 20 parts by weight of saliva oil, Followed by primary aging for 2 to 4 days. Specifically, the saliva oil may be canola oil or cashew nut oil. Also, 15 to 25 parts by weight of water and 50 to 70 parts by weight of the environmentally-friendly fogging smoke film are slowly added to the primary aged aged material, stirred until completely dissolved, and then aged for 12 to 24 hours. The prepared eco-friendly bio-insecticide stock solution may be diluted so that the undiluted solution may be 0.5 to 3% by weight in the water.

The eco-friendly bio-insecticide according to the present invention does not recycle vegetable waste cooking oil, which is safe for human and livestock and is a major cause of environmental pollution, uses only pure vegetable oil, and can be quickly and uniformly mixed when water is mixed with water. , The fermentation of the medicinal effect at the time of spraying is the best, and it is naturally decomposed after a lapse of a certain time, thereby being environmentally friendly.

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed exemplary embodiments, It belongs to the scope of right.

Claims (15)

S1) preparing vegetable oil;
S2) preparing a catalyst solution;
S3) mixing and stirring the vegetable oil and the catalyst solution;
S4) separating glycerin, water, and fatty acid methyl ester from the stirred product of S3), respectively;
S5) mixing the separated glycerin and fatty acid methyl ester; And
S6) mixing an emulsifier in the mixture of S5);
/ RTI >
Wherein neopentyl glycol dicaprylate is further mixed before and after mixing the emulsifier. The method according to claim 1,
Wherein the vegetable oil does not contain waste cooking oil. The method according to claim 1,
Wherein the mixing and stirring of step S3) is carried out at 40 to 60 < 0 > C. The method according to claim 1,
Wherein the emulsifier is a phospholipid surfactant. delete The method according to claim 1,
Further comprising a substance selected from the group consisting of an insecticide, a bactericide, a disinfectant, a deodorant, a microbial agent, a mineral agent, and a plant nutrient before and after mixing the emulsifier. A process for producing a polyurethane foam comprising the steps of:
a) 50 to 95 parts by weight of a fatty acid methyl ester;
b) 5 to 50 parts by weight of glycerin;
c) 1 to 10 parts by weight of an emulsifier;
/ RTI >
Further comprising 5 to 20 parts by weight of neopentyl glycol dicaprylate per 100 parts by weight of the mixture of glycerin and fatty acid methyl ester. delete delete Vegetable oil supply;
A vegetable biodiesel supply;
A catalyst supply unit;
An emulsifier supply unit;
A catalyst solution preparation unit for mixing the plant biodiesel supplied from the plant biodiesel supply unit and the catalyst supplied from the catalyst supply unit;
A reaction unit for mixing and stirring the vegetable oil supplied from the vegetable oil supply unit and the catalyst solution supplied from the catalyst solution production unit;
A glycerin storage part for storing the glycerin supplied from the reaction part;
A fatty acid methyl ester storage part for storing the fatty acid methyl ester provided from the reaction part;
A water tank for containing water supplied from the reaction unit;
A mixing unit for mixing the glycerin provided from the glycerin storage unit, the fatty acid methyl ester provided from the fatty acid methyl ester storage unit and the emulsifier supplied from the emulsifier supply unit;
/ RTI >
Wherein the mixing part further comprises a neopentyl glycol dicaprylate supplying part for providing neopentyl glycol dicaprylate. delete 11. The method of claim 10,
Wherein the glycerin storage part and the fatty acid methyl ester storage part further comprise a water washing means and a distillation means. An eco-friendly biosimilant comprising the eco-friendly mist film of claim 7. 14. The method of claim 13,
The eco-friendly bio-insecticide is prepared by mixing water, potassium hydroxide, and saliva oil with stirring, firstly aging the mixture, and then mixing the water and the environmentally-friendly fire-retardant agent, followed by secondary aging. 14. The method of claim 13,
Wherein the vegetable oil is a canola oil or a cashew nut oil.

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