KR101879449B1 - Filtering structure for hydrogen water production - Google Patents

Filtering structure for hydrogen water production Download PDF

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Publication number
KR101879449B1
KR101879449B1 KR1020160167916A KR20160167916A KR101879449B1 KR 101879449 B1 KR101879449 B1 KR 101879449B1 KR 1020160167916 A KR1020160167916 A KR 1020160167916A KR 20160167916 A KR20160167916 A KR 20160167916A KR 101879449 B1 KR101879449 B1 KR 101879449B1
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South Korea
Prior art keywords
hydrogen
water
contact
liters
inlet
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KR1020160167916A
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Korean (ko)
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KR20180066733A (en
Inventor
김미숙
김혜미
김혜빈
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김미숙
김혜미
김혜빈
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Publication of KR20180066733A publication Critical patent/KR20180066733A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D35/00Filtering devices having features not specifically covered by groups B01D24/00 - B01D33/00, or for applications not specifically covered by groups B01D24/00 - B01D33/00; Auxiliary devices for filtration; Filter housing constructions
    • B01D35/30Filter housing constructions
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/08Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • C02F1/003Processes for the treatment of water whereby the filtration technique is of importance using household-type filters for producing potable water, e.g. pitchers, bottles, faucet mounted devices
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

The present invention relates to a hydrogen-producing filter structure, and more particularly, to a hydrogen-generating filter structure applied to a water purifier, a shower, a water softener and a water bottle to reduce the water to hydrogen peroxide, The present invention relates to a hydrogen-producing filter structure for preventing generation of excessive magnesium oxide (MGO) due to chemical reaction and turbidity of water, as well as for generating hydrogen (H2) stably and smoothly for a long period of time.
In order to achieve the above object, the present invention for achieving this object is characterized in that the present invention for achieving such an object has an internal space, a first stopper formed with an inlet for introducing raw water to be supplied from the outside, An external filter unit to which the second stopper is attached and filters the magnesium oxide and impurities contained in the reduced hydrogen water through the hydrogen generating unit; And a hydrogen generating unit provided in an internal space of the external filter unit to reduce the raw water flowing into the inlet through a water inlet.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a hydrogen-

The present invention relates to a hydrogen-producing filter structure, and more particularly, to a hydrogen-generating filter structure applied to a water purifier, a shower, a water softener and a water bottle to reduce the water to hydrogen peroxide, (H2O) water is stably and smoothly generated for a long period of time as well as preventing turbidity of water due to excessive formation of magnesium oxide (MgO) due to chemical reaction .

In general, active oxygen is a highly oxidizing oxygen that occurs in the metabolism of the body and causes various diseases and aging.

Therefore, it is necessary to remove active oxygen in the body to prevent disease and prevent aging.

Examples of active antioxidants that remove active oxygen include active hydrogens.

Hydrogen molecules that are saturated in hydrogen water are present in the molecular state (H2) in which two hydrogen atoms are bonded. However, rarely, molecular bonds of hydrogen atoms are broken and hydrogen atoms alone exist. This single hydrogen atom (H) is referred to as active hydrogen, and this active hydrogen combines with active oxygen in the body to generate water, thereby enabling to remove active oxygen in the body.

On the other hand, water having an increased active concentration of water is referred to as " hydrogenated water ", and a water-containing water purifier for generating hydrogenated water is provided.

There are two types of electrolyzed water electrolysis method and electrolytic electrolysis method using metal having a tendency to ionize more than hydrogen. The electroless electrolysis method has a merit of simple structure of the water purifier compared to the electrolysis method requiring electrolytic bath have.

The electroless method uses a metal having a tendency to ionize more than hydrogen such as magnesium or calcium. When these metals are brought into contact with water, a metal having a higher ionization tendency than hydrogen is oxidized to a cation, and water is dissociated into OH- and H + .

Then, a part of the dissociated H + remains in the ionic state or the hydrogen atom state in the water, so that the active hydrogen concentration is raised, and a part of the H + is released as hydrogen gas. In this process, the pH of the water increases as OH- is generated.

According to the drinking water quality standard, the pH of the drinking water is specified as 5.8 to 8.5. However, as described above, as the active hydrogen is generated, the pH of the hydrogenated water is increased. Therefore, when the active hydrogen is produced at a relatively high level, the pH of the water becomes higher than the drinking water quality standard, and the water can not be used as drinking water.

Korean Patent Publication No. 0104596 has been disclosed. Registered utility model 0397418 registered in Korea has been registered. Korean Utility Model No. 0003194 has been disclosed.

SUMMARY OF THE INVENTION The present invention has been made to overcome the above problems of the prior art, and it is an object of the present invention to improve the structure of a water-producing filter applied to a water purifier, a shower, a water softener and a water bottle, The present invention is to provide a hydrogen-producing filter structure that prevents excessive generation of magnesium oxide (MgO) due to chemical reaction and prevents water from being contaminated with turbidity, as well as allowing hydrogen (H2) molecules to stably and smoothly generate for a long period of time.

In order to achieve the above object, the present invention has an internal space, a first stopper formed with an inlet for introducing raw water supplied from the outside, and a second stopper for blocking the internal space at the other end, An external filter unit for filtering and discharging magnesium oxide and impurities contained in the reduced hydrogen water through a prime generating unit; And a hydrogen generating unit provided in an internal space of the external filter unit to reduce the raw water flowing into the inlet through a water inlet.

In addition, the hydrogen generating means may include a plurality of through grooves along the longitudinal direction so as to be contacted with the raw water while being reduced to the hydrogen water while the raw water passes, and a plurality of spaced apart projections formed so as to be spaced apart from the inside of the external filter portion .

The hydrogen generating unit may include a first hydrogen generating unit having a first contact pin and a second contact pin protruding from the inner side surface and the outer side surface, A third contact pin and a fourth contact pin protruding from the inner side surface and the outer side surface are formed so as to face each other and the third contact pin is formed so as to intersect the second contact pin protruding from the outer surface of the first hydrogen generation portion A second hydrogen generating portion to be positioned; And a fifth contact pin and a sixth contact pin protruding from the inner side surface and the outer side surface, respectively, the fifth contact pin protruding from the outer surface of the second hydrogen generating part, And a third hydrogen generating unit positioned so as to be positioned.

In addition, a first flow path space is formed between the second contact pin and the third contact pin, and a second flow path space is formed between the fourth contact pin and the fifth contact pin.

Also, the hydrogen generating unit may include a fourth hydrogen generating unit having a plurality of flow vanes formed so that raw water is uniformly dispersed and flows smoothly, and is reduced in surface contact and reduced to hydrofluoric acid; And a fifth hydrogen generator enclosing the fourth hydrogen generator and having a plurality of micropores formed therein to increase the concentration of hydrogenated water as the reduced hydrogen is contacted again through the fourth hydrogen generator, .

In addition, the flow path of the fourth hydrogen generating part is formed with a curved surface so that the raw water flowing through the inlet can vortex and quickly and smoothly come into surface contact with each other.

The plurality of contact protrusions are protruded to increase the contact area of the raw water in the flow path blades of the fourth hydrogen generating portion.

The micropores are formed to have a width of 1 mm to 2 mm and are regularly arranged at intervals of 3 mm to 5 mm.

In addition, the inside of the hydrogen-water generating means has an internal space, a first cap having an inlet port through which raw water flows is installed at one end, and a second cap is installed at the other end to close the internal space. And an internal filter portion for filtering out impurities contained in the raw water to be introduced and discharging the filtered water.

The inner space of the inner filter portion is filled with a plurality of solid magnesium balls.

In addition, a filter net for filtering impurities is formed on the bottom of each of the inlet and the inlet.

The first cap, the second cap, and the first and second plugs are detachably mounted.

Further, the hydrogen-containing water generating means is characterized in that the whole is made of magnesium.

According to the present invention, magnesium (MgO) is excessively generated due to an excessive chemical reaction between water and magnesium to prevent water from turbidly polluting, and hydrogen (H2) molecules are stably and smoothly generated for a long period of time It is effective.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is an exploded perspective view of a hydrogen-generating filter structure according to an embodiment of the present invention; FIG.
Figure 2 is a cross-sectional view of Figure 1;
FIG. 3 is an exploded perspective view showing a state in which a hydrogen-producing means according to another embodiment of the present invention is applied to the hydrogen-producing filter structure of the present invention. FIG.
4 is a partially enlarged perspective view showing a hydrogen generating means of Fig.
FIG. 5 is a perspective view illustrating a state in which the first hydrogen generating unit, the second hydrogen generating unit, and the third hydrogen generating unit are separated from each other in the state of FIG. 4;
FIG. 6 is a plan view of the hydrogen generating means of FIG. 3; FIG.
FIG. 7 is an exploded perspective view showing a state in which a hydrogen-producing means according to another embodiment of the present invention is applied to the hydrogen-producing filter structure of the present invention. FIG.
8 is a longitudinal sectional view of Fig.
Figure 9 is a cross-sectional view of Figure 7;
10 is a perspective view showing only the fourth hydrogen generator of FIG.
FIG. 11 is a perspective view for explaining another embodiment of the fourth hydrogen generator of FIG. 10; FIG.
FIG. 12 is a perspective view for explaining another embodiment of the fourth hydrogen generator of FIG. 10; FIG.
13 is an exploded perspective view showing a state in which the internal filter portion is applied to the hydrogen-producing filter structure of the present invention.
Fig. 14 is a longitudinal sectional view of Fig. 13; Fig.
15 is a cross-sectional view of Fig.
FIG. 16 is a side sectional view showing a state in which a solid magnesium ball is filled in the inner filter portion of FIG. 13; FIG.
FIG. 17 is a perspective view of the combined assembly of FIGS. 1, 3, 7, and 13; FIG.

Hereinafter, preferred embodiments of the present invention will be described in more detail with reference to the accompanying drawings.

In the following description of the present invention, a detailed description of known functions and configurations incorporated herein will be omitted when it may make the subject matter of the present invention rather unnecessary.

It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory and are intended to provide further explanation of the invention as claimed.

Also, the size and thickness of each component shown in the drawings are arbitrarily shown for convenience of explanation, and the present invention is not necessarily limited to those shown in the drawings.

First, the present invention improves the structure of a hydrogen-producing filter to prevent excessive oxidation of magnesium oxide (MgO) due to a sensitive chemical reaction between water and magnesium to turbidly pollute water (hereinafter referred to as 'raw water') The present invention relates to a hydrogen-producing filter structure (10) capable of stably and smoothly producing hydrogen (H2) for a long period of time. The hydrogen-producing filter structure (10) Means (200) and an internal filter portion (300).

The outer filter unit 100 has an inner space and is wrapped around the outer side of the hydrogen generating unit 200. One end of the outer filter unit 100 has a water inlet 111 through which raw water supplied from the outside flows The formed first stopper 110 is mounted.

A second stopper 120 is installed at the other end of the outer filter unit 100 to close the inner space.

Meanwhile, a filter net 130 for filtering impurities may be formed at the lower end of the inlet 111.

In addition, the first plug 110 and the second plug 120 are preferably detachably mounted.

At this time, the shape of the first plug 110 and the second plug 120 may be changed to a shape suitable for the installation conditions of the devices when they are applied to devices such as a water purifier, a water softener, a water bottle, desirable.

That is, the external filter unit 100 filters and discharges magnesium oxide (MgO) and impurities contained in the hydrogen water reduced and discharged through the hydrogen water generating unit 200.

The hydrogen generating means 200 is provided in the inner space of the external filter unit 100 to reduce the raw water introduced into the water inlet 111 through the inlet 111 and discharge the hydrogenated water. May be constructed in a number of embodiments.

As shown in FIGS. 1 and 2, in the embodiment of the hydrogen generating means 200, raw water flowing through the inlet 111 passes through a plurality of Holes 210 are formed.

At this time, the plurality of through grooves 210 are shown as a hexagonal honeycomb shape in the drawing, but the shape is not limited thereto and may be circular or polygonal.

In addition, the hydrogen peroxide generating means 200 is provided at an outer periphery of the outer filter portion 100 at a predetermined distance from the outer periphery of the outer filter portion 100, and the hydrogen water, which is reduced and passed through the through holes 210, A plurality of spacing protrusions 220 are formed so as to protrude so as to form a flow path space (not shown)

That is, the hydrogen generating means 200 having the above-described configuration is formed in a channel space (not shown) formed by the spacing protrusions 220 after the water is passed through the plurality of through grooves 210, .

3 to 6, another embodiment of the hydrogen generating means 200 includes a first contact pin 231 and a second contact pin 231, And a first hydrogen generator 230 having a plurality of pins 232 protruding therefrom.

The third contact pin 241 and the fourth contact pin 242, which are wrapped around the first hydrogen generator 230 and are in contact with the inner and outer surfaces, respectively, A hydrogen generator 240 is provided.

At this time, the third contact pin 241 is positioned to intersect the second contact pin 232 protruding from the outer surface of the first hydrogen generator 230.

The fifth contact pin 251 and the sixth contact pin 252, which are surrounded on the outside of the second hydrogen generator 240 and whose source water is in surface contact with the inner and outer surfaces, respectively, A hydrogen generator 250 is provided.

At this time, the fifth contact pin 251 is positioned to cross the fourth contact pin 242 protruding from the outer surface of the second hydrogen generator 240.

In addition, a first flow path space 234 through which raw water passes is formed inside the first hydrogen generating part 230, and a first flow path 234 is formed between the second contact pin 232 and the third contact pin 241, A plurality of second flow path spaces 245 through which the raw water flows are formed between the fourth contact pins 242 and the fifth contact pins 251 do.

Although the hydrogen generators 230, 240 and 250 are illustrated as being coupled in triplicate in the drawing, the hydrogen generators 230, 240 and 250 may be coupled in multiple depending on the width of the filter.

That is, the hydrogen generating means 200 having the above-described configuration is configured such that the raw water is passed through the first flow path space 234, the second flow path space 245, and the third flow path space 254, 230, 240, and 250, and the contact pins are brought into contact with each other to be reduced and discharged into hydrogenated water having an increased concentration.

Next, as shown in FIGS. 7 to 12, in another embodiment of the hydrogen generating means 200, the raw water is uniformly dispersed and flow smoothly, And a fourth hydrogen generating unit 260 in which the hydrogen generating unit 261 is formed.

In addition, the third hydrogen generator 260 is surrounded by the fourth hydrogen generator 260. When the reduced hydrogen is re-contacted through the fourth hydrogen generator 260, the concentration of hydrogen- And a fifth hydrogen generator 270 in which the first hydrogen generator 271 is formed.

11, a curved surface 262 may be formed on the channel vane 261 so that raw water flowing through the inlet 111 can vortex quickly and smoothly.

As shown in FIG. 12, a plurality of contact protrusions 263 may protrude from the flow path blade 261 to increase the contact area of the raw water.

Although the contact protrusions 263 are formed only on one surface of each of the channel vanes 261 and the shape of the contact protrusions 263 is shown in a semicircular shape in the drawing, the present invention is not limited thereto. The contact protrusions 263 may protrude from both sides of the channel vanes 261, The protrusion 263 may be formed in a polygonal shape.

That is, the hydrogen-water generating means 200 according to the above-described construction firstly reduces the surface water contact between the plurality of flow path blades 621 and the flow path blades 261 while the raw water flows smoothly, And is brought into surface contact with the fine holes 271 of the fifth hydrogen generating unit 270 to be reduced to hydrogenated water having an increased concentration and discharged.

Finally, the hydrogen generating means 200 composed of many embodiments as described above is formed entirely of magnesium, and reacts with water according to the following chemical formula to produce reduced water.

Figure 112016121142945-pat00001

The inner filter unit 300 is provided inside the fifth hydrogen generating unit 270 to filter out impurities contained in raw water flowing through the inlet 111. The inner filter unit 300 includes an inner space A first cap 310 having an inlet 311 through which raw water flows is mounted and a second cap 320 is installed at the other end to block the internal space.

In addition, a plurality of solid magnesium balls (not shown) may be embedded in the inner space of the inner filter unit 300 to generate hydrogen (H2), or magnesium such as a stick type may be embedded therein.

In addition, at the lower end of the inlet 111, a solid magnesium ball (not shown), which is filled in the inner space of the inner filter unit 300, is separated from the outside as well as the impurities contained in the raw water supplied from the outside A filter network 130 may be formed.

Meanwhile, the inner filter unit 300 and the outer filter unit 100 may be applied with a sediment filter or a nanofilter made of high-density polypropylene having a thickness of 1 to 5 탆. However, the present invention is not limited thereto, Any filter that is effective in removing complex particles can be applied.

14, when the raw water flowing through the inlet 111 flows into the interior of the internal filter 300 through the inlet 311, impurities contained in the raw water are removed and discharged, and impurities are removed And the discharged raw water is exhausted at the same time as it is reduced to and discharged to the hydrogen water in the surface contact with the fine holes 271 of the fifth hydrogen water generating means 270. The reduced and discharged hydrogen water passes through the external filter unit 100, (MgO) contained in the impurities and impurities.

The hydrogen-generating filter structure (1) of the present invention having the above-described respective constitutions is used as a filter applied to a water purifier, a water softener, a water bottle, and a shower used in the home. Magnesium (MgO) is excessively generated to prevent turbid water pollution, and hydrogen (H2) is used to stably and smoothly generate molecules for a long period of time.

The results of the experiment on the water quality of the water, which is obtained by precipitating the water-producing filter structure (10) according to the present invention in a water bottle to determine the turbidity, hardness, pH (PH) As follows.

(Example 1)

1. Exam date: December 11, 2015 to December 28, 2015

2. Test purpose: Hydrogen water generation filter passage number 58 water quality safety inspection

3. Testing institution: Korea Environment Water Research Institute

4. Test method: Water quality test standard for drinking water (Ministry of Environment notification No. 2015-214)

5. Test environment: Temperature: (minimum 23 ℃, maximum 25 ℃), Humidity: (minimum 18%, maximum 25% PH)

6. Test items and results

1. General bacteria: Not detected

2. Total coliforms: Not detected

3. E. coli: Not detected

4. Lead (Pb): Not detected

5. Boron (F): Not detected

6. Arsenic (As): Not detected

7. Selenium (Se): Not detected

8. Mercury (Hg): Not detected

9. Cyan (CN): Not detected

10. Chromium (Cr): Not detected

11. Mononitic nitrogen: Not detected

12. Nitrate Nitrogen: Below 1.8 (standard value 10 or less)

13. Cardium (Cd): Not detected

14. Boron: Below 0.01 standard (below the standard value of 1.0)

15. Phenol: Not detected

16. Diazinon: Not detected

17. Para Town: Not detected

18. Phenitrothion: Not detected

19. Cavalier: Not detected

20. 1.1.1 Trichloroethane: Not detected

21. Tecrachlorethylene (POE): Not detected

22. Trachlorethylene (TOE): Not detected

23. Dipromomethane: Not detected

24. Benzene: Not detected

25. Toluene: Not detected

26. Ethylbenzene: Not detected

27. Xylene: Not detected

28. 1.1-Diproethylene: Not detected

29. Carbon tetrachloride: Not detected.

30. 1,2-Dibromo-3-fluoropropane: Not detected

31. 1,4-Dioxane: Not detected

32. Free residual chlorine: Not detected

33. Total trihalomethane: Below 0.028 standard (Below 0.1 standard)

34. Fluoroform: Below 0.015 standard (reference value 0.08 or less)

35. Bromodichloromethane: Not more than 0.009 standard (Not more than 0.03 standard value)

36. Dipromochloromethane: Not more than 0.004 standard (not more than 0.1 standard value)

37. Chloral hydrate: Not more than 0.0013 standard (not more than 0.03 standard)

38. Diboroacetonitrile: Not detected

39. Dichloroacetonitrile: Not detected

40. Trifluoroacetonitrile: Not detected

41. Halo Washing Acid: Less than 0.006 standard (Below 0.1 standard value)

42. Formaldehyde: Not detected

43. Hardness: Less than 84 standard (Below 300 standard)

44. Consumption of potassium permanganate: below 0.9 standard (below 10 standard value)

45. Odor: Odorless

46. Taste: tasteless

47. Copper (Cu): Not detected

48. Chromaticity: Not detected

49. Detergent (ABS): Not detected

50. Hydrogen ion concentration (Ph) 7.5 (reference value 5.8 to 8.5)

51. Zinc (Zn): Not more than 0.009 standard (not more than 3 standard value)

52. Chloride ion (Cl): Below 29.6 standard (below the standard value of 250)

53. Evaporation residue: Below 147 standards (below the standard value of 500)

54. Iron (Fe): Not detected

55. Manganese (Mn): Not detected

56. Turbidity: Below 0.06 standard (below the standard value of 0.5)

57. Sulfate ion: Below 19 standards (Below 200 standard)

58. Al (Al): Not detected

As a result of the test, turbidity, hardness and pH of the water were stabilized and no harmful substances were detected. As described above, the hardness, chromaticity, turbidity, hydrogen ion concentration, and other items of the water-producing filter structure (10) applied to the present invention are suitable for the water quality of the water to be consumed.

(Example 2)

(A) the concentration of dissolved hydrogen (H2), (b) the oxidation conversion potential and (c) the lower limit (Ph) test for the applied hydrogen-producing filter structure 10 of the present invention were carried out as follows.

(A) Hydrogen production test

1. Exam date: October 28, 2015

2. Test Purpose: To test molecular hydrogen (H2) production over time of hydrogen-producing filter structure

3. Testing institute: Japan Far Infrared Association affiliated Water Science Institute

4. Test method: Hydrogen (H2) molecule measurement after residual water of 600cc for 2 hours in the filter structure

5. Test environment: Temperature 22 ℃, Humidity 41%

6. Measuring instrument: ENH-1000 manufactured by Trustex Co., Ltd.

7. Test Results: Dissolved hydrogen (H2) concentration 318 ppb

(B) Oxidation-reduction potential (ORP) test

1. Exam date: October 28, 2015

2. Sample name: Antioxidant capacity test

3. Testing institute: Japan Far Infrared Association affiliated Water Science Institute

4. Test method: ORP +640 Mv of raw water in Japan Water (600 cc) was added to the water-producing filter structure, and the antioxidant capacity (ORP) test

5. Test environment: Temperature 22 ℃, Humidity 41%

6. Measuring instrument: ORP meter TL-60 manufactured by Trust Rex Co., Ltd.

7. Test Results: Redox Potential - 149 mV

(C) The PH test

1. Exam date: October 28, 2015

2. Sample name: Antioxidant capacity test

3. Testing institute: Japan Far Infrared Association affiliated Water Science Institute

4. Test method: Raw water of Ph. 7.3 in Japan

5. Test environment: Temperature 22 ℃, Humidity 41%

6. Measuring instrument: pH meter manufactured by Sato Corporation, Japan

7. Test results: pH 7.38

(Example 3)

An experiment in which a certain constant water was passed through the hydrogen-producing filter structure 10 according to the present invention for a long time and then changed was carried out as follows.

(A) dissolved hydrogen (H2) concentration, (b) oxidative exchange potential, and (c) manganese (Ph) test were carried out as follows.

1. Date of Examination: May 27, 2016

2. Purpose of test: After constant water passing continuously for a long period of time,

3. Test method: Cylindrical magnesium pipe with inner diameter of 20 mm, outer diameter of 40 mm and length of 240 mm was attached to the filter housing, and after passing 5 liters of tap water per 1 liter per minute, ) Hydrogen (H2) by time elapsed after 120 hours continuous flow on the basis of 1 liter per minute, (b) Oxidation reduction potential (ORP) (B) Determination of redox potential (ORP), (c) Determination of pH value (see Table 2)

4. Tap water temperature: 25 ℃

5. Experimental equipment

A) Molecular Hydrogen (H2) Molecular Meter (ppb)

- Model Name: ENH-1000

- Usage: Dissolved hydrogen (H2) molecule measurement in water

- Measurement unit: PPM / PPB

- Country of origin: Japan

B) Redox potential (ORP) meter (mV)

- Model: EUTECH INSTRUMENTS 'OAKION'

- Usage: Measurement of 'ORP (redox potential)' in water

- Country of origin: United States

C) pH meter

- Model name: PH-009 (I)

- Usage: Measurement of pH value in water

- Country of Origin: China

D) Water temperature (℃) measuring instrument

- Model name: JR-1 (DIGITAL THERMOMETER)

- Usage: Contact temperature measurement of all liquids

- Country of Origin: China

Experimental time Number of progressive passes Number of passes The amount of hydrogen (H2) ORP PH Total measuring time 11:38 5 liters 5 liters 458 -136 9.9 About 5 minutes 11:43 10 liters 5 liters 457 -193 9.3 About 10 minutes 11:53 15 liters 5 liters 460 -143 9.3 About 15 minutes 12:03 20 liters 5 liters 379 -144 8.8 About 20 minutes 12:08 25 liters 5 liters 348 -92 8.7 About 25 minutes 12:13 30 liters 5 liters 293 -104 8.5 About 30 minutes 12:18 35 liters 5 liters 274 -73 8.5 About 35 minutes 12:23 40 liters 5 liters 283 -46 8.3 About 40 minutes 12:28 45 liters 5 liters 272 -38 8.2 About 45 minutes 12:33 50 liters 5 liters 261 -31 8.3 About 50 minutes 12:38 55 liters 5 liters 255 -26 8.3 About 55 minutes 12:43 60 liters 5 liters 234 -27 8.3 About 60 minutes 12:48 65 liters 5 liters 259 -55 8.3 About 65 minutes 12:53 70 liters 5 liters 289 -23 8.3 About 70 minutes 12:58 75 liters 5 liters 276 -21 8.3 About 75 minutes 13:03 80 liters 5 liters 302 -40 8.4 About 80 minutes 13:08 85 liters 5 liters 299 -35 8.3 About 85 minutes 13:13 90 liters 5 liters 243 -58 8.2 About 90 minutes 13:18 95 liters 5 liters 249 -14 8.1 About 95 minutes 13:23 100 liters 5 liters 239 -14 8.0 About 100 minutes 13:28 105 liters 5 liters 268 -14 8.2 About 105 minutes 13:33 110 liters 5 liters 277 -11 8.2 About 110 minutes 13:38 115 liters 5 liters 260 -17 8.0 About 115 minutes 13:43 120 liters 5 liters 244 -53 7.8 About 120 minutes 13:48 125 liters 5 liters 264 -45 8.1 About 125 minutes 13:53 130 liters 5 liters 272 -9 7.9 About 130 minutes 13:58 135 liters 5 liters 280 -19 7.9 About 135 minutes 14:03 140 liters 5 liters 290 -16 7.8 About 140 minutes 14:08 145 liters 5 liters 288 -17 7.9 About 145 minutes 14:13 150 liters 5 liters 279 -15 7.8 About 150 minutes

Date of experiment Franchisee and number Number of passes The amount of hydrogen (H2) ORP pH Time lapse 1,440 liters 1,440 liters 315 -83 7.7 24 hours elapsed 2,880 liters 1,440 liters 251 -47 7.8 48 hours elapsed 4,320 liters 1,440 liters 247 -43 8.1 72 hours elapsed 5,760 liters 1,440 liters 235 -34 8.1 96 hours elapsed 7,200 liters 1,440 liters 178 -98 7.4 120 hours elapsed

Table 1 shows the measurement result after passing 5 liters of tap water through the filter structure 10 according to the present invention on a 1-liter basis per minute for 5 minutes. Table 2 shows the results of the measurement of the hydrogen- The results are shown in Table 1. As shown in the results of Tables 1 and 2, hydrogen (H2) is continuously generated when the tap water is passed through the hydrogen-producing filter structure 10, .

As described above, the hydrogen-generating filter structure 10 according to the present invention has a structure in which a magnesium ball or a raw material of a particle state is contained in a housing and the turbidity, chromaticity, hardness and hydrogen ion Ph) concentration is increased by 9.0 to 12, and thus the problem of being unsuitable for use in a drinking water filter for a water purifier, a shower, a water softener and a water bottle has been solved.

The technical idea of the hydrogen-generating filter structure according to the present invention is that the same results can be repeatedly practiced. Particularly, by implementing the present invention as described above, technology development can be promoted and contributed to industrial development.

10: Hydrogen-generating filter structure
100: External filter section
110: first stopper 111: inlet port 120: second stopper 130: filter mesh
200: Hydrophobicity generating means
210: through groove 220:
230: first hydrogen generator 231: first contact pin 232: second contact pin
233: first engaging groove 234: first channel space
240; Second hydrogen generating portion 241: Third contact pin 242: Fourth contact pin
243: first engaging projection 244: second engaging groove 245: second channel space
250: third hydrogen generator 251: fifth contact pin 252: sixth contact pin
253: second engaging projection 254: third channel space
260: fourth hydrogen generator 261: flow path blade 262: curved surface 263: contact projection
270: fifth hydrogen generator 271:
300: internal filter section
310: First cap 311: Inlet port 320: Second cap 330: Magnesium ball

Claims (14)

And a second stopper for closing the inner space is installed at the other end of the first stopper so as to be connected to the first stopper through which the reduced water An external filter portion for filtering out magnesium oxide and impurities contained in the prime water; And
And water generating means provided in an internal space of the external filter portion for reducing raw water flowing into the water inlet through hydrogen inlet water,
Wherein the hydrogen-
A first hydrogen generating unit having a plurality of first contact pins and second contact pins protruding from an inner side surface and an outer side surface, respectively;
A plurality of third contact pins and fourth contact pins protruding from the inner side surface and the outer side surface of the first contact member and protruding from the outer surface of the first hydrogen generation unit, A second hydrogen generating unit positioned to intersect; And
A plurality of fifth contact pins and sixth contact pins protruding from the outer surface of the second hydrogen generating part are formed on the inner and outer surfaces of the first and second contact pins, And a third hydrogen generator positioned to intersect the first hydrogen generator.
The method according to claim 1,
Wherein the hydrogen-
And a plurality of spaced apart protrusions protruding from the inner side of the outer filter portion so as to be spaced from the inner side of the outer filter portion by a predetermined distance. .
delete The method according to claim 1,
A first flow path space is formed inside the first hydrogen generation portion,
A plurality of second flow path spaces are formed between the second contact pins and the third contact pins,
And a plurality of third flow path spaces are formed between the fourth contact pin and the fifth contact pin.
The method according to claim 1,
A plurality of first coupling grooves and a plurality of second coupling grooves are formed on outer surfaces of the first hydrogen generator and the second hydrogen generator,
And a plurality of first engaging protrusions and second engaging protrusions, which are fitted in the first engaging grooves and the second engaging grooves, are protruded and formed on inner surfaces of the second hydrogen generating portion and the third hydrogen generating portion, respectively Hydrogen production filter structure.
The method according to claim 1,
Wherein the hydrogen-
A fourth hydrogen generating unit in which a plurality of flow channels are formed so that raw water is uniformly dispersed and smoothly flowed into surface contact and reduced to hydrofluoric acid; And
And a fifth hydrogen generator enclosing the fourth hydrogen generator and having a plurality of micropores formed to increase the concentration of hydrogenated water as the reduced hydrogen is contacted again through the fourth hydrogen generator, Wherein the hydrogen-absorbing filter structure is formed of a metal.
The method according to claim 6,
Wherein a flow surface of the flow path blade of the fourth hydrogen generating part is formed so that raw water flowing through the inlet port swirls quickly and smoothly in surface contact.
The method according to claim 6,
Wherein a plurality of contact protrusions are protruded to increase the contact area of the raw water in the channel wing of the fourth hydrogen generating part.
The method according to claim 6,
Wherein the micropores are formed in a width of 1 mm to 2 mm and are uniformly arranged at intervals of 3 mm to 5 mm.
The method according to claim 1,
Inside the hydrogen-water generating means,
A first cap having an inner space and having an inlet port through which raw water flows is installed at one end thereof and a second cap which closes the inner space at the other end thereof to filter out impurities contained in the raw water flowing through the inlet port Wherein the inner filter portion comprises an inner filter portion.
11. The method of claim 10,
Wherein a plurality of solid magnesium balls are filled in the inner space of the inner filter portion.
11. The method of claim 10,
And a filter net for filtering impurities are formed on the bottom of the inlet and the bottom of the inlet, respectively.
11. The method of claim 10,
Wherein the first cap and the second cap, and the first cap and the second cap are removably mounted.
The method according to claim 1,
Wherein the hydrogen-producing means is made entirely of magnesium.
KR1020160167916A 2016-12-09 2016-12-09 Filtering structure for hydrogen water production KR101879449B1 (en)

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Publication number Priority date Publication date Assignee Title
KR102238625B1 (en) * 2020-10-23 2021-04-09 원스타산업 주식회사 Shower appratus for generating hydrogen for People and Pets combined use

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6227382B1 (en) * 1997-12-19 2001-05-08 Corning Incorporated Water filtration apparatus
KR20080104911A (en) * 2007-05-29 2008-12-03 웅진코웨이주식회사 Water cleaning filter and filter cartridge
KR20110096632A (en) * 2010-02-23 2011-08-31 강원 Functional composite filter cartridge
KR20160066176A (en) * 2014-12-02 2016-06-10 안종섭 Apparatus for manufacturing hydrogen water

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6227382B1 (en) * 1997-12-19 2001-05-08 Corning Incorporated Water filtration apparatus
KR20080104911A (en) * 2007-05-29 2008-12-03 웅진코웨이주식회사 Water cleaning filter and filter cartridge
KR20110096632A (en) * 2010-02-23 2011-08-31 강원 Functional composite filter cartridge
KR20160066176A (en) * 2014-12-02 2016-06-10 안종섭 Apparatus for manufacturing hydrogen water

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