KR101836757B1

KR101836757B1 - Resin foam sheet and electric or electronic device with the same

Info

Publication number: KR101836757B1
Application number: KR1020167022648A
Authority: KR
Inventors: 히데유키 도쿠야마; 가즈미치 가토; 고헤이 도이; 다다오 다카하시
Original assignee: 닛토덴코 가부시키가이샤
Priority date: 2015-04-03
Filing date: 2016-03-31
Publication date: 2018-03-08
Also published as: JP6058870B1; WO2016159227A1; JPWO2016159227A1; CN106414055A; KR20170037876A

Abstract

The foamed resin sheet (X) of the present invention has a laminated structure including the foamed resin layer (10) and the surface layer (20). The surface layer 20 has an exposed surface 21 having a surface roughness of 1.0 占 퐉 or more and also contains a filler. The foamed resin layer 10 includes, for example, an acrylic resin as a subject. The surface layer 20 includes, for example, a urethane resin as a subject. The electric and electronic device of the present invention comprises such a foamed resin sheet (X).

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a foamed resin sheet,

The present invention relates to a foamed resin sheet which can be used as a shock absorber and an electric / electronic apparatus comprising such a foamed resin sheet.

Recently, shock absorbers in the form of thin sheets have been used in various technical fields. For example, in the technical field of a portable device having a touch panel on a display, it has been proposed to provide a shock absorber (cushioning material) at a predetermined position in the device in order to prevent breakdown or breakage of the touch panel or its associated parts For example, Patent Documents 1 and 2). Such a shock absorber is made of, for example, a foamed resin.

Patent Document 1: Japanese Patent Laid-Open Publication No. 2011-205539 Patent Document 2: Japanese Patent Application Laid-Open No. 2014-17718

With the thinness of the equipment in which the shock absorber is installed, the shock absorber is required to be thin. In the case of thinning the shock absorber made of a foamed resin, it is considered to employ a resin material having a low glass transition temperature as a constituent material of the shock absorber in order to ensure shock absorbability in a thin foamed resinous body. However, resin materials having a low glass transition temperature generally have high adhesiveness at room temperature. The higher the tackiness of the adhesion surface of the shock absorber (the surface on which the adhesion at a predetermined portion is planned), the more the unintended adhesion of the shock absorber to a portion other than the expected adhesion portion And it becomes difficult to handle.

In order to cope with such a handling problem, it is considered to provide a surface layer made of a material exhibiting adhesiveness lower than that of the foamed resin body on the adhesion surface of the thin foamed resin article or the shock absorber. However, such a shock absorber provided with such a surface layer has a relatively low adhesiveness on the adherend, but it may be difficult to align the adherend to a portion to be adhered in an installation process for the device. When the position of the shock absorber is shifted and aligned while bringing the surface of the shock absorber in surface contact with the portion to be adhered, that is, a relatively large frictional force between the to-be-adhered portion and the adherend It is thought that it tends to occur. Even if the surface layer made of a material having a lower tackiness than the foamed resin matrix is a shock absorber provided on the bonding surface, there still remains a problem with handling in terms of alignment.

Further, in order to form a surface layer or an adhesive surface made of a material exhibiting lower adhesiveness than the foamed resin matrix, for example, it is considered to adhere a resin film to the foamed resin matrix. However, the impact absorber whose surface layer is formed of a resin film has relatively low adhesiveness to the surface layer or the adhesion surface, so that it may be difficult to follow the concavo-convex shape when the expected adhesion portion has a surface irregularity shape.

An object of the present invention is to provide a foamed resin sheet suitable for realizing a thin layered shock absorber having good handling properties and excellent followability, which is conceived based on such circumstances, and an electric / .

According to a first aspect of the present invention, there is provided a foamed resin sheet. The foamed resin sheet has a laminated structure including a foamed resin layer and a surface layer. The foamed resin layer is a layer containing a foamed resin material as a main agent. The surface layer has an exposed surface with a surface roughness of 1.0 占 퐉 or more and further contains a filler. The surface roughness in the present invention is represented by an arithmetic mean roughness (Ra). The exposed surface of the surface layer can constitute the adhesion surface (surface on which the adhesion to the predetermined portion is to be made) of the present expanded resin sheet, and the present expanded resin sheet can be adhered to a predetermined portion on the surface layer side and used.

The foamed resin sheet has a surface layer separately from the foamed resin layer. Therefore, in the foamed resin sheet, it is possible to employ a resin material for the foamed resin layer, which has a comparatively low glass transition temperature and thus has relatively high adhesiveness, while employing a material having a relatively low tackiness for the surface layer. The surface layer has an exposed surface or an adhesive surface and the present foamed resin sheet capable of setting a comparatively low glass transition temperature with respect to the foamed resin layer independently of the adhesion of the adhesive surface is suitable for achieving thinness while ensuring impact absorbability . That is, the foamed resin sheet is suitable for realizing a thin layered shock absorber having a high shock absorbing property.

In this foamed resin sheet, in which the tackiness of the surface layer can be set independently of the tackiness of the foamed resin layer, in order to suppress unintended attachment to a portion other than the portion to be adhered, It is possible to set a low tackiness. Such a foamed resin sheet is suitable for realizing a thin layered shock absorber having a good handling property in that unintended adhesion is suppressed.

The surface layer of the foamed resin sheet has an exposed surface or an adhesive surface with a surface roughness of 1.0 占 퐉 or more. In such a configuration, a frictional force generated between the intended bonding site and the bonding surface at the time of alignment and alignment, that is, at the time of alignment with the main foamed resin sheet in surface contact with the intended bonding site It is relatively small. It is considered that the so-called true contact area between the place to be adhered and the adhesive surface is relatively small. Therefore, the present foamed resin sheet can be easily aligned with respect to a portion to be adhered in an installation process or the like with respect to an apparatus. Such a main foamed resin sheet is suitable for realizing a thin layered shock absorber having good handling property in that it is easy to align in the bonding process.

Incidentally, the foamed resin sheet contains a filler in its surface layer. The filler in the surface layer functions as a branch point for inhibiting the continuity of the polymer structure when the surface layer has a polymer structure including a so-called binder component and the like. Such a configuration is suitable for facilitating the deformation of the surface layer. Therefore, this foamed resin sheet is suitable for making it easier to follow the concavo-convex shape when the portion to be adhered has a surface uneven shape. Such a main foamed resin sheet is suitable for realizing a thin layered shock absorber having excellent followability.

As described above, this foamed resin sheet is suitable for realizing a thin layered shock absorber having good handling properties and excellent followability.

Preferably, the exposed surface of the surface layer is a surface of polyethylene terephthalate having a surface of 8 cm < 2 > in an interfacial state, under a load of 50 g toward the test surface, at a rate of 300 mm / min Is not more than 10 kN / m < 2 >, preferably not more than 2.0 kN / m < 2 >. The foamed resin sheet having such a constitution is suitable for realizing a thin layered shock absorber having good handling property in that it is easy to align in the bonding process.

Preferably, the surface roughness of the exposed surface of the surface layer is 1.5 占 퐉 or more. This constitution is suitable for realizing, for example, 2.0 kN / m < 2 > with respect to the frictional force, and therefore the present foamed resin sheet having the above structure is advantageous in that it is easy to align in the bonding process, It is suitable for realizing an absorbing material.

Preferably, the surface roughness of the exposed surface of the surface layer is 10 mu m or less. Such a configuration contributes to uniformity of the thickness of the surface layer. The more uniform the thickness of the surface layer to be adhered to the adherend, the higher the adhesion reliability of the surface layer or its exposed surface to the adherend tends to be.

Preferably, the foamed resin sheet of the present invention has a peak top in a range of -50 to 50 占 폚 in loss tangent (tan?), Which is a ratio of the loss elastic modulus at room temperature to the storage elastic modulus at an oscillating speed of 1 rad / s in dynamic viscoelasticity measurement. The strength of the peak top is preferably 0.2 or more. Such a configuration is suitable for achieving thinness of the foamed resin sheet while ensuring shock absorption.

Preferably, the average cell diameter of the bubbles contained in the foamed resin layer is 10 to 150 mu m. The structure in which the average cell diameter in the foamed resin layer is 10 占 퐉 or more is suitable for realizing a high shock absorption property with respect to the foamed resin layer. The structure in which the average cell diameter in the foamed resin layer is 150 占 퐉 or less is suitable for realizing sufficient compression recoverability with respect to the foamed resin layer.

Preferably, the thickness of the foamed resin layer is 30 to 200 mu m. The structure in which the thickness of the foamed resin layer is 30 占 퐉 or more is suitable for realizing the uniformity of dispersion of the bubbles in the foamed resin layer. The uniform distribution of the bubbles in the foamed resin layer contributes to realize a high impact absorbing property with respect to the foamed resin layer. The constitution in which the thickness of the foamed resin layer is 200 m or less contributes to the thinning of the foamed resin layer, and thus the main foamed resin sheet.

Preferably, the ratio of the average cell diameter of the bubbles contained in the foamed resin layer to the thickness of the foamed resin layer (former / latter) is 0.2 to 0.9. Such a configuration is suitable for realizing a high impact absorbing property with respect to the foamed resin layer.

Preferably, the apparent density of the foamed resin layer is 0.2 to 0.7 g / cm 3. The constitution in which the apparent density of the foamed resin layer is 0.2 g / cm 3 or more is suitable for realizing sufficient strength for the foamed resin layer. The constitution in which the apparent density of the foamed resin layer is 0.7 g / cm 3 or less is suitable for realizing a high shock absorption property with respect to the foamed resin layer.

Preferably, the foamed resin layer includes an acrylic resin as a subject. Such a configuration is suitable for realizing a thin-layer shock absorber having a high shock absorbing property.

Preferably, the surface layer includes a urethane-based resin as a subject. Preferably, the filler is carbon black and / or titanium oxide. This constitution is suitable for achieving the above-described good followability together with the above-mentioned good handleability in the present expanded resin sheet.

Preferably, the foamed resin layer and the surface layer are in contact with each other. That is, it is preferable that the foamed resin layer and the surface layer form a laminated structure directly contacting with each other. According to such a constitution in which no other layer intervenes between the foamed resin layer and the surface layer, the surface layer formed by, for example, a printing method is transferred onto a foamed resin layer having a high surface sticking property, It is possible to manufacture the sheet appropriately.

According to a second aspect of the present invention, there is provided an electric / electronic device comprising the foamed resin sheet according to the first aspect of the present invention. The present electric / electronic apparatus includes, for example, a display unit and the foamed resin sheet bonded to the display unit. The present electric / electronic apparatus is suitable for realizing an electric / electronic apparatus having a thin layered shock absorber having good handling property and excellent followability.

BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a partial cross-sectional schematic diagram of a foamed resin sheet according to one embodiment of the present invention. Fig.
2 is a schematic sectional view of an electric / electronic apparatus according to one embodiment of the present invention.
Fig. 3 is a diagram schematically showing an observation point concerning the followability evaluation.

1 is a partial cross-sectional schematic diagram of a foamed resin sheet X according to one embodiment of the present invention. The foamed resin sheet (X) has a laminated structure including a foamed resin layer (10) and a surface layer (20). The foamed resin layer 10 is a layer containing a foamed resin material as a subject and has a first face 11 and a second face 12. The subject is a component that occupies the largest mass ratio among constituent components. The surface layer 20 is formed on the side of the first surface 11 of the foamed resin layer 10 and has the exposed surface 21. The exposed surface 21 of the surface layer 20 can form the adhesion surface of the foamed resin sheet X (the surface on which the adhesion to the predetermined portion is to be expected), and the foamed resin sheet X is the surface layer 20 To be used at a predetermined position.

The foamed resin layer 10 is a portion for exerting an impact-absorbing function in the foamed resin sheet X and comprises a resin material and has an open cell structure, a closed cell structure or a semicontinuous free-flowing cell structure ( The bubble structure is not shown). Examples of the resin material for constituting the foamed resin layer 10 include acrylic resin, rubber and urethane-based resin. As the constituent material of the foamed resin layer 10, one type of resin material or two or more kinds of resin materials may be used.

The acrylic resin is a resin containing, as a main monomer unit, an acrylic monomer unit derived from an acrylic monomer having at least one acryloyl group or methacryloyl group in the molecule. Hereinafter, "(meth) acryl" refers to "acrylic" and / or "methacryl" (ie, both "acrylic", "methacrylic" or "acrylic" and "methacrylic").

Examples of the acrylic monomer for forming the acrylic resin include (meth) acrylic acid, (meth) acrylonitrile and (meth) acrylobenzyl acrylate. Examples of the acrylic monomer for forming the acrylic resin include (meth) acrylic acid alkyl esters such as methyl methacrylate, ethyl methacrylate, ethyl acrylate, butyl acrylate and 2-ethylhexyl acrylate, (meth) acrylamide and N- Containing vinyl monomers such as N-vinyl-2-pyrrolidone and the like, and hydroxyl group-containing acrylic monomers such as 2-hydroxyethyl methacrylate, . As the monomer for forming the acrylic resin, one kind of acrylic monomer may be used, or two or more kinds of acrylic monomers may be used.

The rubber for forming the foamed resin layer 10 may be either natural rubber or synthetic rubber. Examples of the rubber include nitrile rubber (NBR), methyl methacrylate-butadiene rubber (MBR), styrene-butadiene rubber (SBR), acrylic rubber (ACM, ANM), urethane rubber (AU) . Of these, nitrile rubber (NBR), methyl methacrylate-butadiene rubber (MBR) and silicone rubber are preferable.

Examples of the urethane-based resin for forming the foamed resin layer 10 include polycarbonate-based polyurethane, polyester-based polyurethane and polyether-based polyurethane.

The foamed resin layer 10 has a bubble structure as described above and the lower limit of the average cell diameter with respect to the bubbles contained in the foamed resin layer 10 is higher than that of the foamed resin layer 10 Is preferably 10 占 퐉, more preferably 15 占 퐉, and still more preferably 20 占 퐉, from the viewpoint of realizing the above-mentioned effect. The upper limit of the average cell diameter is preferably 150 占 퐉, more preferably 140 占 퐉, still more preferably 130 占 퐉, from the viewpoint of realizing sufficient compression recovery with respect to the foamed resin layer 10 , And particularly preferably 100 m. The average cell diameter can be obtained by using a microscope such as a scanning electron microscope (SEM) or a digital microscope. For example, first, the cross section of the foamed resin layer 10 is observed using a microscope, and an image including 20 to 40 cells including bubbles is taken in the cross section. Thereafter, with respect to the cells in the image, 20 or more areas are measured in order from the cells having a large diameter, and an average value of the diameters of the circles is calculated based on the measured areas by image analysis.

With respect to the thickness of the foamed resin layer 10, the lower limit is preferably 30 占 퐉, more preferably 40 占 퐉, more preferably 40 占 퐉 in view of realizing uniformity of dispersion of bubbles in the foamed resin layer 10 Preferably 50 m. The uniform dispersion of bubbles in the foamed resin layer 10 is preferable for realizing a high impact absorbing property with respect to the foamed resin layer 10. The upper limit of the thickness of the foamed resin layer 10 is preferably 200 占 퐉, more preferably 150 占 퐉, and still more preferably 200 占 퐉, from the viewpoint of thinning of the foamed resin layer 10 and further the foamed resin sheet X Is 120 탆, and particularly preferably 100 탆.

The lower limit of the apparent density of the foamed resin layer 10 is preferably 0.2 g / cm 3, more preferably 0.21 g / cm 3, in view of realizing sufficient strength for the foamed resin layer 10 , More preferably 0.22 g / cm < 3 >. The upper limit of the apparent density is preferably 0.7 g / cm 3, more preferably 0.6 g / cm 3, still more preferably 0.5 g / cm 3 from the viewpoint of realizing a high shock absorbing property with respect to the foamed resin layer 10. Cm < 3 >, and particularly preferably 0.4 g / cm < 3 &

From the viewpoint of achieving a high impact absorbing property with respect to the foamed resin layer 10, the ratio (the former / the latter) of the average cell diameter (占 퐉) and the thickness (占 퐉) in the foamed resin layer 10 is preferably 0.2 to 0.9 , More preferably in the range of 0.25 to 0.85, and still more preferably in the range of 0.3 to 0.8.

The impact absorbency of the foamed resin body is determined by the peak of the loss tangent (tan delta), which is the ratio of the loss elastic modulus at room temperature to 1 at rad / s and the storage elastic modulus in the dynamic viscoelasticity measurement (former / latter) The temperature at which the saw is located may also be affected. The peak top of the loss tangent (tan?) In the foamed resin layer 10 is preferably set in the range of -50 to 50 占 폚. The peak top of the loss tangent in the foamed resin sheet (X) containing the foamed resin layer (10) as a main structural element is also preferably in the range of -50 to 50 캜. As the foaming resin body is thinner, the bubbles in the foamed resin body are liable to be crushed by the impact, and the crushed bubbles lose the shock buffering ability, and the foamed resin layer 10 and the foamed resin sheet (X) When the top is in the above-mentioned temperature range, the constituent material of the foamed resin layer 10 can exhibit a function of buffering or absorbing the impact even after the bubble is crushed. The lower limit of the temperature range in which the peak top of loss tangent exists is preferably -40 占 폚 in view of realizing sufficient compression recoverability with respect to the foamed resin layer 10 to the foamed resin sheet X, Is -30 deg. C, and more preferably -20 deg. The upper limit of the temperature range is preferably 40 占 폚, more preferably 30 占 폚, from the viewpoint of realizing high flexibility or high impact absorbing property with respect to the foamed resin layer 10 to the foamed resin sheet X Preferably 20 [deg.] C. The peak of the loss tangent (tan?), Which is the ratio of the loss elastic modulus at room temperature to the storage elastic modulus at an oscillating speed of 1 rad / s in the measurement of the dynamic viscoelasticity of the resin material solidified without foaming the resin composition for forming the foamed resin layer 10 The top surface is preferably in the range of -50 to 50 占 폚. In the case of a material having two or more peak tops of loss tangent, it is preferable that at least one peak top is within the temperature range.

The peak top strength (maximum value) of the loss tangent is preferably higher, for example, 0.2 or more, and more preferably 0.3 or more from the viewpoint of achieving a high impact absorbability. The upper limit of the peak top strength is, for example, 2.0. In addition, the peak top strength of the loss tangent (tan?) In the range of -50 to 50 占 폚 of the resin material solidified without foaming the resin composition for forming the foamed resin layer 10 is higher in view of impact absorbability desirable. The peak top strength of the loss tangent in the resinous article corresponds to the value obtained by dividing the peak top strength of loss tangent in the foamed resin layer 10 by the apparent density of the foamed resin layer 10. [

In setting the peak top of the loss tangent of the foamed resin layer (10) to the temperature of the foamed resin sheet (X) within the above-mentioned temperature range, it is preferable to use a monomer having a Tg of -10 ° C or higher and a Tg of -10 Lt; 0 > C as a monomer unit is preferably used as the subject of the foamed resin layer 10. For example, when an acrylic resin is employed, the acrylic resin containing an acrylic monomer having a Tg of the homopolymer of -10 占 폚 or higher and an acrylic monomer having a Tg of the homopolymer of lower than -10 占 폚 as an essential monomer unit is used as the foaming resin layer 10 . The term "Tg of the homopolymer" means "glass transition temperature (Tg) of the homopolymer of the monomer in question", and more specifically, "Polymer Handbook" (3rd edition, John Wiley & Sons, Inc, 1987) . The Tg of a homopolymer relating to a monomer not described in this document refers to a value obtained by the following measurement method (for example, see Japanese Patent Application Laid-Open No. 2007-51271). First, 100 parts by weight of a monomer, 0.2 part by weight of 2,2'-azobisisobutyronitrile, and 200 parts by weight of ethyl acetate as a polymerization solvent were charged into a reactor equipped with a thermometer, a stirrer, a nitrogen inlet tube and a reflux condenser tube And the input is stirred for 1 hour while nitrogen gas is introduced. After the oxygen in the polymerization system was removed in this manner, the temperature was raised to 63 캜 and the reaction was carried out for 10 hours. Next, the solution is cooled to room temperature to obtain a homopolymer solution having a solid concentration of 33% by weight. Next, this homopolymer solution is applied on a separator in a pourable manner and then dried to produce a test sample (homopolymer of sheet form) having a thickness of about 2 mm. The test samples were punched into a disc having a diameter of 7.9 mm, sandwiched between parallel plates, and subjected to a shear deformation at a frequency of 1 Hz using a viscoelasticity tester (ARES, Rheometrics Co.) . The temperature range for measurement is -70 to 150 캜, and the rate of temperature rise for measurement is 5 캜 / min. The peak top temperature of the loss tangent (tan?) Obtained by this measurement is taken as the Tg of the homopolymer.

Examples of the acrylic monomer having a Tg of the homopolymer of -10 ° C or higher include (meth) acrylonitrile, (meth) acrylic acid and isobornyl (meth) acrylate. Examples of the acrylic monomer having a Tg of the homopolymer of -10 캜 or more include monomers containing an amide group such as (meth) acrylamide and N-hydroxyethyl (meth) acrylamide, homomers such as methyl methacrylate and ethyl methacrylate (Meth) acrylic acid alkyl ester having a Tg of the polymer of -10 占 폚 or higher, a vinyl monomer containing a heterocyclic ring such as N-vinyl-2-pyrrolidone and the like, and a hydroxyl group-containing acrylic monomer such as 2-hydroxyethyl methacrylate . Of these, (meth) acrylonitrile (especially acrylonitrile) is particularly preferable. When (meth) acrylonitrile (particularly acrylonitrile) is used as a monomer having a Tg of the homopolymer of -10 ° C or higher for forming an acrylic resin for constituting a foamed resin layer, 10, it is easy to obtain a large peak top strength. As the acrylic monomer having a homopolymer Tg of -10 占 폚 or higher, one kind of acrylic monomer may be used, or two or more kinds of acrylic monomers may be used.

Examples of the acrylic monomer having a Tg of the homopolymer of less than -10 占 폚 include (meth) acrylic acid alkyl esters having a Tg of less than -10 占 폚 of homopolymers such as ethyl acrylate, butyl acrylate and 2-ethylhexyl acrylate. Of these, C _2-8 alkyl acrylate esters are particularly preferred. As the acrylic monomer having a Tg of the homopolymer of less than -10 占 폚, one kind of acrylic monomer may be used, or two or more kinds of acrylic monomers may be used.

The content of the acrylic monomer having a Tg of the homopolymer of -10 캜 or higher with respect to the total monomer component (the total amount of the monomer components) for forming the acrylic resin is, for example, 2 to 30% by weight. The content of the acrylic monomer having a Tg of the homopolymer of less than -10 占 폚 with respect to the total monomer component (total amount of the monomer components) for forming the acrylic resin is, for example, 70 to 98% by weight.

The foamed resin layer 10 may contain a surfactant, a crosslinking agent, a thickening agent, a rust inhibitor and other additives, if necessary, in addition to the above-mentioned resin material. The foamed resin layer 10 may further contain other components within a range that does not impair the impact absorbability. Examples of such other components include a resin component other than the above, a softening agent, an antioxidant, an antioxidant, a gelling agent, a hardener, a plasticizer, a filler, a reinforcing agent, a foaming agent Light stabilizers, ultraviolet absorbers, colorants (such as pigments and dyes), pH adjusters, solvents (organic solvents), thermal polymerization initiators and photopolymerization initiators.

The surface layer 20 of the foamed resin sheet X has the exposed surface 21 as described above and also contains a filler (not shown). The exposed surface 21 of the surface layer 20 can form the bonding surface of the foamed resin sheet X and has a surface roughness of 1.0 to 10 mu m. The surface roughness is expressed by an arithmetic average roughness (Ra). The lower limit of the surface roughness of the exposed surface 21 is 1.0 占 퐉, preferably 1.5 占 퐉, more preferably 3.0 占 퐉, more preferably 4.0 占 퐉, and still more preferably 4.0 占 퐉, from the viewpoint of realizing a small coefficient of friction on the exposed surface 21, Particularly preferably 4.5 m. The upper limit of the surface roughness of the exposed surface 21 is 10 占 퐉 from the viewpoint of the uniformity of the thickness of the surface layer 20. With such a surface roughness, the exposed surface 21 is in contact with the test surface of polyethylene terephthalate in an area of 8 cm 2 and is parallel to the test surface under a load of 50 g toward the test surface The friction force defined as the stress generated when tension is applied at a speed of 300 mm / min is 10 kN / m 2 or less. The frictional force is preferably 2.0 kN / m 2 or less, more preferably 1.5 kN / m 2 or less, and further preferably 1.0 kN / m 2 or less.

Examples of the matrix resin material or binder resin material for forming the surface layer 20 containing the filler include urethane resin, phenol resin, epoxy resin, urea melamine resin, silicone resin, phenoxy resin, methacrylic resin, Acrylic resin, polyester resin (polyethylene terephthalate and the like), polyolefin resin (polyethylene, polypropylene, ethylene-propylene copolymer and the like), polystyrene resin (polystyrene, styrene- acrylonitrile copolymer, styrene- , Styrene-maleic anhydride copolymer, acrylonitrile-butadiene-styrene resin, etc.), polyvinyl chloride, vinyl chloride-vinyl acetate copolymer, polyvinyl acetate, polyvinylidene chloride, polycarbonate, celluloses , Ethyl cellulose resin, etc.), and resins such as polyacetal (thermoplastic resins, There may be mentioned a curable resin, photo-curable resin or the like). Of these, from the viewpoints of environmental friendliness and prevention of malfunction of electronic equipment, a resin containing no halogen or sulfur is preferable, and a urethane-based resin is particularly preferable. As the matrix resin material for forming the surface layer 20, one kind of binder resin or two or more kinds of binder resins may be used.

As the filler contained in the surface layer 20, for example, pigments and other additives can be used. Examples of such additives include carbon black, graphite, titanium oxide, copper oxide, manganese dioxide, aniline black, perylene black, ferrite, magnetite, chromium oxide, iron oxide, molybdenum disulfide and chromium complexes. Of these, carbon black is preferable from the viewpoints of cost and availability. Further, titanium oxide is also preferable because the particle diameter is stably maintained. One type of filler may be used, or two or more kinds of fillers may be used. The content of the filler in the surface layer 20 is, for example, 20 to 60% by weight. The filler content is preferably 20% by weight or more from the viewpoint of suppressing an excessive content of the binder resin material in the surface layer 20 and appropriately realizing the surface roughness on the exposed surface 21. Further, from the viewpoint of properly forming the homogeneous surface layer 20, the filler content is preferably 60% by weight or less.

The foamed resin sheet X can be produced by separately forming the foamed resin layer 10 and the surface layer 20 and then transferring the surface layer 20 to the foamed resin layer 10, for example.

The foamed resin layer 10 for the foamed resin sheet X can be formed by foam molding a resin composition containing the above-mentioned predetermined resin material. As the resin composition for foam molding, a resin solution in which a resin material is dissolved in a solvent may be used, or an emulsion (emulsion resin composition) containing a resin material may be used. From the viewpoint of forming bubbles appropriately, it is preferable to use an emulsion resin composition. As the emulsion resin composition, two or more kinds of emulsions may be blended. The solid content concentration of the emulsion is preferably higher in view of the film formability, for example, 30% by weight or more.

As the foaming method (bubble formation method), a physical method or a chemical method can be employed. In a physical method, generally, gas components are dispersed in the resin composition by mechanical stirring to form bubbles. In the chemical method, bubbles are formed by the gas generated by thermal decomposition of the foaming agent added to the resin material.

From the viewpoint of good foaming, the foamed resin layer 10 is preferably formed through a step of foaming the emulsion resin composition by mechanical stirring to foam it. Examples of the apparatus usable for foaming include a high-speed shearing type apparatus, a vibration type apparatus, and a pressurized gas discharge type apparatus. From the viewpoint of miniaturization of bubble diameter and production of a large capacity, a high-speed shearing method is preferable. The bubbles when foamed by mechanical stirring are those in which the gas (gas) has entered the emulsion. As the gas, a gas inert to the emulsion can be used. Examples of such gases include air, nitrogen and carbon dioxide.

In the formation of the foamed resin layer 10, after the bubble process, a bare-saturated resin composition (for example, an emulsion resin composition) is coated on a substrate and dried (a coating and drying step). Examples of the substrate include a peeled plastic film (such as a peeled polyethylene terephthalate film), a plastic film (such as a polyethylene terephthalate film), and a thermally conductive layer. The present step includes a preliminary drying step of drying a bubble-containing resin composition (for example, an emulsion resin composition) coated on a substrate at a temperature of 50 ° C or higher and lower than 125 ° C, and then a final drying step of drying at 125 ° C or higher and 200 ° C or lower . By providing the preliminary drying step and the main drying step, it is possible to prevent the coalescence and rupture of the bubbles due to the rapid temperature rise. Particularly in the formation of the foamed resin layer 10 having a small thickness, it is easy to form a preliminary drying step because the bubbles tend to be united or ruptured due to a rapid rise in temperature. As described above, the foamed resin layer 10 can be formed.

On the other hand, the surface layer 20 for the foamed resin sheet X can be formed as a print layer by, for example, a printing method. Specifically, it can be formed by applying a composition containing the above-mentioned binder resin, the above-mentioned filler and a predetermined solvent on a support, drying it, and then curing it if necessary. The surface (coated surface) to which the composition is applied on the support has a surface roughness for realizing the above-described surface roughness on the surface layer 20 to the exposed surface 21. The surface roughness of the surface to be coated of the support is, for example, 1.0 to 10.0 占 퐉. Examples of the method for applying the composition in the present step include various coating methods, gravure printing method, flexographic printing method, offset printing method, iron plate printing method, and screen printing method.

In the production of the foamed resin sheet (X), the surface layer (20) formed as described above is transferred to the surface of the foamed resin layer (10). Specifically, first, the surface layer 20 formed on the support is bonded to the first surface 11 of the foamed resin layer 10 formed on the substrate as described above, as described above. Thus, the surface layer 20 is appropriately transferred to the foamed resin layer 10 having high surface tackiness. For example, the foamed resin sheet X can be produced as described above. The foamed resin sheet X that can be produced in this manner may be circulated on the market in a rolled-up state. The support is peeled from the surface layer 20 immediately before use, for example, of the foamed resin sheet (X).

The foamed resin sheet (X) has a surface layer (20) separately from the foamed resin layer (10). Therefore, in the foamed resin sheet (X), a resin material having relatively low glass transition temperature and relatively high adhesiveness is used as the foamed resin layer (10) while employing a material having a relatively low tackiness for the surface layer It is possible to adopt it for. The foamed resin sheet X capable of setting a relatively low glass transition temperature with respect to the foamed resin layer 10 independently of the adhesion of the adhesive surface has the surface layer 20 having the exposed surface 21 to the adhesive surface, It is suitable for achieving thinness while ensuring water absorption. That is, the foamed resin sheet X is suitable for realizing a thin layered shock absorber having high impact absorbability.

In the foamed resin sheet (X) capable of setting the tackiness of the surface layer (20) independently of the tackiness of the foamed resin layer (10), in order to suppress unintended adhesion of the foamed resin sheet (X) It is possible to select a constituent material with respect to the surface layer 20 to set a low stickiness. Such a foamed resin sheet X is suitable for realizing a thin layered shock absorber having a favorable handling property in view of suppression of unintended adhesion.

The surface layer 20 of the foamed resin sheet X has an exposed surface 21 to an adhesive surface with a surface roughness of 1.0 占 퐉 or more. In such a configuration, when the pre-adhesion position and the positioning of the foamed resin sheet X are performed while the pre-adhesion is performed, that is, when the foamed resin sheet X is aligned while making face- The frictional force is relatively small. It is considered that the so-called true contact area between the place to be adhered and the adhesive surface is relatively small. For this reason, the foamed resin sheet X is easily aligned with respect to the position to be adhered in the installation process or the like for the apparatus. Such a foamed resin sheet X is suitable for realizing a thin layered shock absorber having good handleability in that it is easy to align in the bonding process.

In addition, the foamed resin sheet (X) contains a filler in its surface layer (20). The filler in the surface layer 20 functions as a branch point for inhibiting the continuity of the polymer structure when the surface layer 20 has a polymer structure including a so-called binder component and the like. This configuration is suitable for making the surface layer 20 easily deformable. Therefore, the foamed resin sheet X is suitable for making it easier to follow the concavo-convex shape when the portion to be adhered has a surface irregularity shape. Such a foamed resin sheet (X) is suitable for realizing a thin layered shock absorber having excellent followability.

As described above, the foamed resin sheet (X) is suitable for realizing a thin layered shock absorber having good handling properties and excellent followability.

2 is a schematic sectional view of an electric / electronic device Y according to another embodiment of the present invention. The electric / electronic device Y is configured as a portable device and includes a case 31, a panel 32, a display unit 33, and the above-described foamed resin sheet X. Examples of the portable device include a mobile phone, a smart phone, and a tablet PC. The case 31 is an element for receiving the panel 32, the display unit 33, the foamed resin sheet X, and various other components (not shown) therein. The panel 32 is configured as a touch panel, for example. The display unit 33 is a unit configured to function as, for example, a liquid crystal display (LCD), an organic EL display (organic electroluminescence display) or a plasma display, Respectively. The foamed resin sheet X is bonded to the back surface (the surface opposite to the image display surface) of the display unit 33 and is sandwiched between the case 31 and the display unit 33 in the present embodiment. The foamed resin sheet X is bonded to the display unit 33 on the side of the above-described exposed surface 21 (not shown in Fig. 2). Such electric / electronic apparatus Y is suitable for realizing an electric / electronic apparatus having a thin layered shock absorber (foamed resin sheet X) having good handling property and excellent followability.

Example

Hereinafter, the present invention will be described in more detail by way of examples, but the present invention is not limited at all by these examples. Hereinafter, unless otherwise stated, "%" indicating the content means weight%, and the number of parts (parts by weight) is a solid content (nonvolatile content) conversion value.

[Example 1]

A foamed resin layer for a foamed resin sheet was formed as follows. First, 100 parts by weight of an acrylic emulsion solution (solids content of 55%, ethyl acrylate-butyl acrylate-acrylonitrile copolymer [weight ratio 45: 48: 7]) and a fatty acid ammonium surfactant 2 parts by weight of a carboxybetaine type amphoteric surfactant (trade name: Amogen CB-H, manufactured by Daiichi Kogyo Pharmaceutical Co., Ltd.), 2 parts by weight of an oxazoline crosslinking agent (trade name: Epochros WS-500, (Trade name: NAF-5091, manufactured by Daiichi Seika Kogyo Co., Ltd.), and 10 parts by weight of a polyacrylic acid thickener (acrylic acid-acrylic acid copolymer [acrylic acid 20 By weight), 0.6 part by weight of solid content (28.7% by weight) were mixed with stirring using a disperser (trade name: Robomix, manufactured by Freimix Co., Ltd.) Next, the thus obtained foam composition (foam composition (F)) was applied on a PET (polyethylene terephthalate) film (thickness 38 탆, trade name: MRF # 38, manufactured by Mitsubishi Plastics, Inc.) . Next, the coated film of the foamed composition (F) on the PET was dried by a preliminary drying process at 70 캜 for 4.5 minutes and a main drying process at 140 캜 for 4.5 minutes. Thus, a foamed resin layer having a closed-cell structure and having a thickness of 130 탆 was formed.

The average cell diameter of the foamed resin layer formed as described above was 75 占 퐉. An enlarged image of the cross section of the foamed resin layer was input by a low-vacuum scanning electron microscope (trade name: S-3400N type scanning electron microscope, Hitachi High-Tech Science Systems Co.), and an image analysis was performed to obtain an average cell diameter (占 퐉).

The apparent density of the foamed resin layer formed as described above was 0.28 g / cm 3. The apparent density was obtained as follows. First, the foamed resin layer was punched with a 100 mm x 100 mm punching blade, and the dimensions of the punched sample were measured. Next, the thickness was measured with a 1/100 dial gauge having a measurement terminal diameter (?) Of 20 mm. The volume of the foamed resin layer was calculated from these values. On the other hand, the weight of the foamed resin layer was measured with an upper dish balance of 0.01 g or less on the minimum scale. The apparent density (g / cm 3) of the foamed resin layer was calculated from the measured weight and the calculated volume.

The initial elastic modulus of the foamed resin layer formed as described above was 1.15 N / mm 2. The initial elastic modulus (N / mm < 2 >) was calculated from the slope at 10% strain in a tensile test at a tensile rate of 300 mm / min under an environment of 23 deg.

On the other hand, a surface layer was formed on a separator (made of polyethylene, thickness: 25 mu m). The surface on which the surface layer is formed in the separator has a surface roughness of 5.2 占 퐉 for generating a surface roughness of 4.0 占 퐉 or more on the surface of the surface layer (the surface forming the exposed surface in the surface layer of the foamed resin sheet). This surface roughness of the separator is caused by the irregular surface irregularities formed on the surface of the mold for separator molding by the sand blast method. The surface layer is formed on the separator by a printing method and is a printing layer having a thickness of 1 占 퐉 including a urethane resin as a binder component and carbon black as a filler.

Then, the surface layer was transferred to the foamed resin layer by bonding a foamed resin layer (having adhesiveness) on the PET film and a surface layer on the PE separator. Thus, the foamed resin sheet of Example 1 was produced.

[Example 2]

And a surface layer was formed on a separator (made of polyethylene, thickness: 25 mu m). The surface on which the surface layer is formed in the separator has a surface roughness of 4.5 占 퐉 for generating a surface roughness of 4.0 占 퐉 or more on the surface of the surface layer (the surface forming the exposed surface in the surface layer of the foamed resin sheet). This surface roughness of the separator is caused by surface irregularities regularly formed on the surface of the mold for separator molding by laser micro-groove processing. The surface layer is a printed layer having an average thickness of 1 占 퐉 which is formed on the separator by a printing method and contains a urethane resin as a binder component, carbon black as a filler, and titanium oxide (average particle diameter 1 占 퐉). Then, the surface layer was transferred onto the foamed resin layer on the PET film in the same manner as in Example 1, except that the surface layer on the PE separator was used in place of the surface layer according to Example 1, and the foamed resin sheet of Example 2 was produced.

[Example 3]

And a surface layer was formed on a separator (made of polyethylene, thickness 50 탆, trade name: PE-50-SU-C1, manufactured by Fujiko). The surface roughness of the surface on which the surface layer is formed in the separator is 1.6 占 퐉. The surface layer is a printing layer having a thickness of 1 占 퐉, which is formed by a printing method on a separator, and contains a urethane resin as a binder component and carbon black as a filler in the same manner as in Example 1. [ Then, the surface layer was transferred to the foamed resin layer on the PET film in the same manner as in Example 1, except that the surface layer on the PE separator was used in place of the surface layer according to Example 1. Thus, a foamed resin sheet of Example 3 was produced.

[Example 4]

And a surface layer was formed on a separator (polyethylene terephthalate, thickness 50 탆, trade name: PET-50-SU-C1, manufactured by Fujiko). The surface roughness of the surface on which the surface layer is formed in the separator is 1.2 mu m. The surface layer is a printing layer having a thickness of 1 占 퐉, which is formed by a printing method on a separator, and contains a urethane resin as a binder component and carbon black as a filler in the same manner as in Example 1. [ Then, the aforementioned foam composition (F) was applied onto the print layer of the separator with the print layer. Next, the coating film of the foamed composition (F) was dried by a preliminary drying process at 70 캜 for 4.5 minutes and a main drying process at 140 캜 for 4.5 minutes. Thus, the foamed resin sheet of Example 4 was produced.

[Comparative Example 1]

A polyethylene separator (thickness: 25 mu m, trade name: PE-25-SU-C1, manufactured by Fujiko Corp.) was bonded to the foamed resin layer on the above-mentioned PET film according to Example 1, To prepare a foamed resin sheet.

[Comparative Example 2]

And a surface layer was formed on a separator (made of polyethylene terephthalate, thickness 50 占 퐉) whose surface was smooth. The surface layer was formed by bonding a PET film (thickness: 4.5 mu m, trade name: PET-4.5, manufactured by Fujiko) to the above separator. Then, the aforementioned foam composition (F) was applied onto the PET film of the separator to which the PET film was attached. Next, the coating film of the foamed composition (F) was dried by a preliminary drying process at 70 캜 for 4.5 minutes and a main drying process at 140 캜 for 4.5 minutes. Thus, a foamed resin sheet of Comparative Example 2 was produced.

[Measurement and evaluation]

The following measurements and evaluations were conducted. Measurement results and evaluation results are shown in Table 1.

The exposed surfaces of the surface layers of the respective foamed resin sheets of Examples 1 to 4 and Comparative Examples 1 and 2 were evaluated by using a confocal laser microscope (OLS-4000, manufactured by Olympus Corporation) And the average surface roughness (Ra) was calculated.

<Re-peelability test>

Each of the foamed resin sheets of Examples 1 to 4 and Comparative Examples 1 and 2 was obtained by bonding a sample sheet (100 mm x 100 mm square) cut from a foamed resin sheet onto a glass plate. The glass plate and the sample sheet were squeezed by reciprocating a 2 kg roller once to the horizontally placed measurement sample. After leaving for 30 minutes, the sample sheet was peeled in the direction of 180 degrees at room temperature (23 DEG C). A case where no shape change occurred in the sample sheet after peeling was evaluated as good (O), and a case where a shape change of less than 10% in the direction along the sheet side occurred in the peeled sample sheet was evaluated as acceptable (O) A case where a shape change of 10% or more in the direction along the sheet side occurred in the sample sheet after peeling was evaluated as poor (X).

The frictional force of each of the foamed resin sheets of Examples 1 to 4 and Comparative Examples 1 and 2 was measured using a universal tensile compression tester (trade name: TCM-1kNB, manufactured by Minneapolis). Specifically, first, a sample sheet of 8 cm 2 cut from the foamed resin sheet was placed on the frictional force test surface made of polyethylene terephthalate in such a manner that the surface layer of the sample sheet was in surface contact with the test surface. Then, a weight of 50 g was placed on the foamed resin layer of the sample sheet placed thereon and fixed. Then, this weight was stretched at a speed of 300 mm / min in the horizontal direction, and the stress (kN / m 2) applied at that time was measured.

The following properties of the foamed resin sheets of Examples 1 to 4 and Comparative Examples 1 and 2 were evaluated as follows. First, a pair of spaced-apart spacers were fixed on a glass plate to form a stepped shape on the surface of the glass plate. At this time, spacers were arranged so that the end portions of the spacers coincided with the edge portions of the glass plate (the edge ends described below were observed). Next, in a mode in which the surface layer of the foamed resin sheet is in surface contact with the glass plate, a foamed resin sheet is placed on the glass plate so as to cover the pair of spacers. Next, another glass plate was placed on the foamed resin sheet on the glass plate, and a load was applied between the glass plates. Then, the followability of the foamed resin sheet was observed at the edge of the edge. For example, as shown schematically in FIG. 3 (a), the case where the voids are not visible is evaluated as good (O) at the spacer portion on the glass plate, and the spacer portion on the glass plate is schematically shown in FIG. 3 The case where the gap G was observed was evaluated as poor (X). 3, a spacer 42 is provided on a glass plate 41, and a foamed resin sheet 44 is sandwiched between the glass plate 41 and the glass plate 43.

Using a viscoelasticity measuring apparatus (trade name: ARES 2KFRTN1-FCO, manufactured by TA Instruments Japan), the foamed resin layers having the surface layers on each of the foamed resin sheets of Examples 1 to 4 were subjected to a tensile test And the temperature (° C) and strength (maximum value) of the peak top of the loss tangent (tan delta), which is a ratio of the loss elastic modulus and the storage elastic modulus at that time, were measured. The foamed resin layers to which the surface layers of the respective foamed resin sheets of Examples 1 to 4 were adhered had a peak of loss tangent at -8 캜. The peak top strength (maximum value) was 0.35. Further, regarding the respective foamed resin sheets, the apparent density of the foamed resin layer having the surface layer attached was considered to be equal to the apparent density of 0.28 g / cm 3 of the foamed resin layer, and the peak top strength was divided by 0.35 The value is 1.25.

[evaluation]

All the foamed resin sheets of Examples 1 to 4 were evaluated as good or acceptable in the re-peelability test described above. This means that the foamed resin sheets of Examples 1 to 4 do not adhere to the surface layer side as they are excessively deformed at re-peeling. Therefore, the foamed resin sheets of Examples 1 to 4 are suitable for realizing a thin layered shock absorber having a favorable handling property in that unintended adhesion is suppressed. In all of the foamed resin sheets of Examples 1 to 4, the frictional force generated in the above-mentioned frictional force measurement is less than 10 kN / m < 2 > Therefore, the foamed resin sheets of Examples 1 to 4 are suitable for realizing a thin layered shock absorber having good handling property in that it is easy to align in the bonding process. In addition, all of the foamed resin sheets of Examples 1 to 4 were evaluated as good in the followability test described above. Therefore, the foamed resin sheets of Examples 1 to 4 are suitable for realizing a thin layered shock absorber having excellent followability. As described above, the foamed resin sheets of Examples 1 to 4 are suitable for realizing a thin layered shock absorber having good handling properties and excellent followability.

X: foamed resin sheet
10: foamed resin layer
20: Surface layer
21: Exposed surface
Y: Electrical and electronic equipment

Claims

A foamed resin layer having an apparent density of 0.2 to 0.7 g / cm < 3 > and an average cell diameter of 10 to 150 mu m, and a surface layer having an exposed surface with a surface roughness of 1.0 m or more and containing a filler ,
Wherein a loss tangent (tan delta), which is a ratio of a loss elastic modulus at a radial vibration of 1 rad / s to a storage elastic modulus in a dynamic viscoelasticity measurement, has a peak top in a range of -50 to 50 占 폚.

The test piece according to claim 1, wherein the exposed surface is a surface of polyethylene terephthalate having a surface area of 8 cm < 2 > Wherein the frictional force defined as a stress generated when the elastic member is stretched at a speed of 10 kN / m 2 or less.

The foamed resin sheet according to claim 2, wherein the frictional force is 2.0 kN / m 2 or less.

The foamed resin sheet according to any one of claims 1 to 3, wherein the surface roughness is 1.5 탆 or more.

The foamed resin sheet according to any one of claims 1 to 3, wherein the surface roughness is 10 占 퐉 or less.

The foamed resin sheet according to any one of claims 1 to 3, wherein the strength of the peak top is 0.2 or more.

delete

The foamed resin sheet according to any one of claims 1 to 3, wherein the thickness of the foamed resin layer is 30 to 200 占 퐉.

The foamed resin sheet according to any one of claims 1 to 3, wherein the ratio of the average cell diameter of the bubbles contained in the foamed resin layer to the thickness of the foamed resin layer (former / latter) is 0.2 to 0.9.

The foamed resin sheet according to any one of claims 1 to 3, wherein the foamed resin layer includes an acrylic resin as a subject.

The foamed resin sheet according to any one of claims 1 to 3, wherein the surface layer contains a urethane resin as a main component.

The foamed resin sheet according to any one of claims 1 to 3, wherein the filler is either or both of carbon black and titanium oxide.

The foamed resin sheet according to any one of claims 1 to 3, wherein the foamed resin layer and the surface layer are in contact with each other.

An electric machine comprising the foamed resin sheet according to any one of claims 1 to 3.

An electronic device comprising the foamed resin sheet according to any one of claims 1 to 3.

delete