KR101782784B1 - Laser induced breakdown spectroscopy apparatus and highly sensitive handpiece - Google Patents
Laser induced breakdown spectroscopy apparatus and highly sensitive handpiece Download PDFInfo
- Publication number
- KR101782784B1 KR101782784B1 KR1020160023734A KR20160023734A KR101782784B1 KR 101782784 B1 KR101782784 B1 KR 101782784B1 KR 1020160023734 A KR1020160023734 A KR 1020160023734A KR 20160023734 A KR20160023734 A KR 20160023734A KR 101782784 B1 KR101782784 B1 KR 101782784B1
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- South Korea
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- light
- handpiece
- elliptical cavity
- focus
- disposed
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- 238000002536 laser-induced breakdown spectroscopy Methods 0.000 title description 8
- 239000013307 optical fiber Substances 0.000 claims abstract description 51
- 230000005855 radiation Effects 0.000 claims abstract description 42
- 238000001228 spectrum Methods 0.000 claims abstract description 18
- 230000003287 optical effect Effects 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 19
- 239000002184 metal Substances 0.000 claims description 6
- 230000001678 irradiating effect Effects 0.000 claims description 4
- 239000007769 metal material Substances 0.000 claims description 3
- 239000012780 transparent material Substances 0.000 claims description 3
- 241000239226 Scorpiones Species 0.000 claims 1
- 238000004611 spectroscopical analysis Methods 0.000 abstract description 24
- 238000011282 treatment Methods 0.000 description 11
- 238000012545 processing Methods 0.000 description 7
- 238000010586 diagram Methods 0.000 description 6
- 230000005540 biological transmission Effects 0.000 description 4
- 230000035945 sensitivity Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000003685 thermal hair damage Effects 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000003796 beauty Effects 0.000 description 2
- 238000000295 emission spectrum Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 208000007256 Nevus Diseases 0.000 description 1
- 238000001069 Raman spectroscopy Methods 0.000 description 1
- 208000000453 Skin Neoplasms Diseases 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000001636 atomic emission spectroscopy Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000037311 normal skin Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 201000000849 skin cancer Diseases 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 230000017423 tissue regeneration Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B5/00—Measuring for diagnostic purposes; Identification of persons
- A61B5/0059—Measuring for diagnostic purposes; Identification of persons using light, e.g. diagnosis by transillumination, diascopy, fluorescence
- A61B5/0075—Measuring for diagnostic purposes; Identification of persons using light, e.g. diagnosis by transillumination, diascopy, fluorescence by spectroscopy, i.e. measuring spectra, e.g. Raman spectroscopy, infrared absorption spectroscopy
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B5/00—Measuring for diagnostic purposes; Identification of persons
- A61B5/0059—Measuring for diagnostic purposes; Identification of persons using light, e.g. diagnosis by transillumination, diascopy, fluorescence
- A61B5/0077—Devices for viewing the surface of the body, e.g. camera, magnifying lens
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S3/00—Lasers, i.e. devices using stimulated emission of electromagnetic radiation in the infrared, visible or ultraviolet wave range
- H01S3/0014—Monitoring arrangements not otherwise provided for
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/28—Investigating the spectrum
- G01J3/42—Absorption spectrometry; Double beam spectrometry; Flicker spectrometry; Reflection spectrometry
- G01J2003/423—Spectral arrangements using lasers, e.g. tunable
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2201/00—Features of devices classified in G01N21/00
- G01N2201/06—Illumination; Optics
- G01N2201/061—Sources
- G01N2201/06113—Coherent sources; lasers
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2201/00—Features of devices classified in G01N21/00
- G01N2201/08—Optical fibres; light guides
Abstract
The present invention provides a laser induced discharge spectroscopy device and a laser handpiece. This laser induced discharge spectroscopy apparatus comprises a pulse laser light source for outputting a pulsed laser beam; A handpiece which receives the pulsed laser beam and irradiates the pulsed laser beam on the object to be processed, and collects the generated radiation of the plasma; An optical fiber for transmitting the radiation light collected from the handpiece; A spectroscope for receiving a radiated light from the optical fiber and measuring a radiation spectrum according to a wavelength; And a processor for analyzing the radiation spectrum. The handpiece includes a handpiece body portion having an elliptical cavity therein; And a light collector disposed at a first focus of the elliptical cavity to collect the reflected radiation reflected from the elliptical cavity. The handpiece body has a cut surface that is not perpendicular to the central axis of the elliptical cavity, and the second focus of the elliptical cavity is disposed on the article to be treated.
Description
The present invention relates to a laser induced discharge spectroscopy apparatus, and more particularly, to a laser induced discharge spectroscopy apparatus including a handpiece that efficiently irradiates the skin and collects light emitted from the skin.
Laser Induced Breakdown Spectroscopy (LIBS) is a technique for analyzing an atomic emission spectroscopy of a substance to be irradiated by irradiating a laser beam onto a substance to be irradiated. Generally, a pulsed laser having a pulse duration of several fs to ns is condensed by a lens and irradiated to the target surface at the target surface. When the energy density at the target surface becomes 1 GW / cm 2 or more, a very small amount of the target surface is ablated and plasmaized. At this time, the electron emission spectrum of the emitted atoms is measured by a spectrometer. Since specific elements generate light of a specific wavelength, LIBS can grasp elemental components in real time. When the laser beam is directly applied to a bio sample or human skin, the energy density of the irradiated laser should be minimized in order to reduce the thermal damage of unnecessary biological tissue. Therefore, there is a need for a technique for efficiently collecting light emitted from a laser-induced plasma.
SUMMARY OF THE INVENTION It is an object of the present invention to provide a laser induced discharge spectroscopy with improved light collecting capability.
SUMMARY OF THE INVENTION It is an object of the present invention to provide a handpiece having improved light collection capability for laser induced discharge spectroscopy.
Disclosure of Invention Technical Problem [8] The present invention provides a laser induced discharge spectroscopy which can be used in a conventional laser skin treatment apparatus.
A laser induced discharge spectroscopy apparatus according to an embodiment of the present invention includes a pulse laser light source for outputting a pulsed laser beam; A handpiece which receives the pulsed laser beam and irradiates the pulsed laser beam on the object to be processed, and collects the generated radiation of the plasma; An optical fiber for transmitting the radiation light collected from the handpiece; A spectroscope for receiving a radiated light from the optical fiber and measuring a radiation spectrum according to a wavelength; And a processor for analyzing the radiation spectrum. The handpiece includes a handpiece body portion having an elliptical cavity therein; And a light collector disposed at a first focus of the elliptical cavity to collect the reflected radiation reflected from the elliptical cavity. The handpiece body has a cut surface that is not perpendicular to the central axis of the elliptical cavity, and the second focus of the elliptical cavity is disposed on the article to be treated.
According to an embodiment of the present invention, the handpiece body may include a light inlet connected to the elliptical cavity and through which the pulsed laser beam passes, and a light outlet through which the radiant light collected by the light collector is transmitted to the outside .
In one embodiment of the present invention, the cut surface may provide a plane in contact with the object to be processed.
In one embodiment of the present invention, the light inlet may be disposed obliquely with respect to the central axis of the elliptical cavity.
In one embodiment of the present invention, the light outlet may be disposed on the central axis of the elliptical cavity.
In one embodiment of the present invention, the cut surface may be cut so as to pass through the second focal point.
In one embodiment of the present invention, the angle between the light inlet and the central axis of the elliptical cavity may be between 5 and 45 degrees.
In one embodiment of the present invention, the light collecting portion includes a hemispherical lens having a spherical surface disposed at a first focal point of the elliptical cavity while looking at the second focal point; And a tapered optical fiber optic plate disposed in contact with the plane of the hemispherical lens.
In one embodiment of the present invention, one end of the tapered optical fiber optical plate is disposed in contact with a plane of the hemispherical lens, and the other end of the tapered optical fiber optical plate is disposed at the light outlet of the handpiece body.
According to an embodiment of the present invention, a focusing lens having a plane-convex structure may be further provided, which connects the other end of the tapered optical fiber plate and the optical fiber.
In one embodiment of the present invention, the handpiece body is in the form of a cylinder, the light inlet and the light outlet are disposed on the upper surface of the cylinder, and the cut surface is disposed on the lower surface of the cylinder.
In one embodiment of the present invention, the surface of the elliptical cavity may be coated with a metal.
In one embodiment of the present invention, the handpiece body portion includes a first body portion and a second body portion, and the first body portion may be made of a metal material or the elliptical surface of the elliptical cavity may be coated with a metal. The second body portion may have a surface cut perpendicularly to the center line at a first focus of the elliptical cavity, and may be formed of a transparent material.
A laser handpiece according to an embodiment of the present invention receives a laser beam from a laser light source and irradiates the laser beam to the object to collect the signal light generated from the object. The handpiece includes a handpiece body portion having an elliptical cavity therein; And a light collector disposed at a first focus of the elliptical cavity to collect the signal light reflected from the elliptical cavity. The handpiece body has a cut surface that is not perpendicular to the central axis of the elliptical cavity, and the second focus of the elliptical cavity is disposed on the article to be treated.
According to an embodiment of the present invention, the handpiece body may include a light inlet connected to the elliptical cavity and through which the pulsed laser beam passes, and a light outlet through which the radiant light collected by the light collector is transmitted to the outside . The cut surface may provide a plane in contact with the object to be processed. A spherical lens having a spherical surface disposed at a first focal point of the elliptical cavity while looking at the second focal point; And a tapered optical fiber optic plate disposed in contact with the plane of the hemispherical lens.
A laser induced discharge spectroscopy apparatus according to an embodiment of the present invention includes a handpiece for receiving a pulsed laser beam from a pulsed laser source and collecting radiated radiation of a plasma generated by irradiating the pulsed laser beam onto an object to be processed; An optical fiber for transmitting the radiation light collected from the handpiece; A spectroscope for receiving a radiated light from the optical fiber and measuring a radiation spectrum according to a wavelength; And a processor for analyzing the radiation spectrum. The handpiece includes a handpiece body portion having an elliptical cavity therein; And a light collector disposed at a first focus of the elliptical cavity to collect the reflected radiation reflected from the elliptical cavity. The handpiece body has a cut surface that is not perpendicular to the central axis of the elliptical cavity, and the second focus of the elliptical cavity is disposed on the article to be treated.
In one embodiment of the present invention, the handpiece further includes a parallel optical lens for converging the light that has been focused through the focusing lens into parallel light, and an auxiliary focusing lens for focusing the parallel light passing through the parallel optical lens can do.
According to one embodiment of the present invention, a handpiece with an elliptical cavity enhances light collection capability, minimizes the loss of a target specimen with less laser power, and provides stable, reproducible laser induced discharge spectroscopy .
According to an embodiment of the present invention, the laser induced discharge spectroscopy apparatus may be attached to a conventional laser skin treatment apparatus to perform laser induced discharge spectroscopy.
1 is a conceptual diagram illustrating a laser induced discharge spectroscopy apparatus according to an embodiment of the present invention.
2 is a cross-sectional view illustrating a handpiece of the laser induced discharge spectroscopy apparatus of FIG.
3 is a conceptual diagram illustrating a laser induced discharge spectroscopy apparatus according to an embodiment of the present invention.
4 is a conceptual diagram illustrating a laser induced discharge spectroscopy apparatus according to another embodiment of the present invention.
Generally, a plasma generated by a laser focused by a focusing lens is generated when a minute crater is generated in the traveling direction of the laser. Therefore, the radiation emitted from the plasma or plasma is not perfectly radial, but has a high optical density in the laser advancing direction. For this reason, the plasma radiation is collected by the focusing lens in the same path as the incident path irradiated with the laser on the workpiece, and the plasma radiation is transmitted to the optical fiber by using a beam splitter such as a dichroic mirror.
However, in this conventional technique, loss of plasma radiation light can not be avoided in an area not covered by the focusing lens, and a method of recovering the lost light to the maximum is required in order to increase the sensitivity of the spectroscopic signal.
According to one embodiment of the present invention, in the elliptical cavity composed of the reflective surface, when the light collecting portion is disposed at the first focus and the object to be processed is disposed at the second focus, The object to be processed generates plasma radiated light. In this case, the plasma radiation is collected at the first focus through reflection, and the light collecting unit disposed at the first focus can collect plasma radiation efficiently to increase the signal sensitivity.
In particular, such a structure can increase the efficiency of light collection and the elliptical reflector tilts with respect to the incident beam. Thus, the optical path of the laser incident beam is separated from the optical path of the plasma radiated light. By the separation of the optical path, the LIBS signal can be extracted by replacing all or part of the handpiece of the conventional skin-beauty laser or adding the handpiece according to the present invention to the handpiece of the existing skin-beauty laser . Therefore, the handpiece according to an embodiment of the present invention can be attached to a conventional skin-beauty laser device and can inspect the condition of the skin by extracting the LIBS signal at the same time or at the same time as the skin-beauty treatment at an inexpensive price.
Increasing the efficiency of light collection by using this handpiece can reduce the energy of the light source (laser), and in particular, in the case of the pulsed laser, unnecessary thermal damage (thermal damage) to the skin can be minimized by reducing energy, Shot-to-shot variation of the laser is reduced and a uniform spectral signal can be obtained.
This handpiece can maximize reflected light, scattered light, and fluorescent light generated simultaneously with not only plasma light (LIBS signal) generated from the skin mounted on the beauty laser, but also physically generated, and can be transmitted to a light analysis module such as a spectroscope.
In addition, the present hand piece can be applied to a light source having a continuous spectrum such as white light. In this case, white light reflected on the skin can be maximized and extracted. In addition, it can be applied not only to pulse lasers including Nd: YAG lasers but also to various CW (conical wave) lasers including a UV region, a visible light region and an IR region. In this case, Raman scattering by skin tissues and molecules, fluorescence light excitation generated by specific molecules can be maximized and focused and transmitted to the optical analysis module. Also in this case, by increasing the light condensing efficiency, the energy of the light source of white light or continuous light can be reduced, and an additional expensive and complicated optical fiber structure for increasing the light condensing efficiency can be minimized.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, embodiments of the present invention will be described with reference to the accompanying drawings. The following examples and results are provided so that the disclosure of the present invention will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art. Also, for convenience of explanation, the components may be exaggerated or reduced in size.
1 is a conceptual diagram illustrating a laser induced discharge spectroscopy apparatus according to an embodiment of the present invention.
2 is a cross-sectional view illustrating a handpiece of the laser induced discharge spectroscopy apparatus of FIG.
1 and 2, a laser induced
The pulsed
The transmission
The
The
The
The angle between the straight line passing through the light inlet and the central axis of the elliptical cavity may be between 5 and 45 degrees. The cut surface may be perpendicular to a straight line passing through the light entrance.
Radial light is gathered around the first focal point. There is a need for an optical system to efficiently transfer collected light to a fiber of limited numerical aperture (NA) value without loss.
Specifically, the
Light converging at the first focus is refracted through the hemispherical lens 124a and the angle of incidence of the light incident on the tapered
One end of the tapered optical fiber
The light transmitted through the other end of the tapered optical fiber
The
The
The
The
The
3 is a conceptual diagram illustrating a laser induced discharge spectroscopy apparatus according to an embodiment of the present invention. A description overlapping with those described in Figs. 1 and 2 will be omitted.
3, the laser induced
The pulsed
The
The ellipsoidal cavity of the
The
4 is a conceptual diagram illustrating a laser induced discharge spectroscopy apparatus according to another embodiment of the present invention. Description of duplicate description to those described in Figs. 1 to 3 will be omitted.
Referring to FIG. 4, the laser induced
The laser induced discharge spectroscopy apparatus according to an embodiment of the present invention can be performed using a conventional laser
According to one embodiment of the present invention, the
The LIBS handpiece 320 according to the present invention is continuously coupled to the conventional handpiece for
While the invention has been shown and described with reference to certain preferred embodiments thereof, it will be understood by those skilled in the art that various changes and modifications may be made therein without departing from the spirit and scope of the invention as defined by the appended claims. And all of the various forms of embodiments that can be practiced without departing from the spirit of the invention.
110: Pulsed laser light source
112: laser control section
120: Handpiece
122: Handpiece body part
124:
126: Optical fiber
136: spectroscope
138:
Claims (17)
A handpiece which receives the pulsed laser beam and irradiates the pulsed laser beam on the object to be processed, and collects the generated radiation of the plasma;
An optical fiber for transmitting the radiation light collected from the handpiece;
A spectroscope for receiving a radiated light from the optical fiber and measuring a radiation spectrum according to a wavelength; And
And a processor for analyzing the radiation spectrum,
The handpiece comprises:
A handpiece body portion having an elliptical cavity inside; And
And a light collecting portion disposed at a first focus of the elliptical cavity to collect the reflected light reflected from the elliptical cavity,
Wherein the handpiece body has a cut surface that is not perpendicular to the central axis of the elliptical cavity,
The cut surface passes through a second focus,
The cut surface does not pass the first focus and the second focus at the same time,
Wherein the second focus of the elliptical cavity is disposed in the article to be treated.
Wherein the handpiece body portion includes a light inlet connected to the elliptical cavity and through which the pulsed laser beam passes, and a light outlet communicated to the outside with radiation radiated by the light collecting portion. Spectrocopy device.
Wherein the cut surface provides a plane in contact with the object to be processed.
Wherein the light entrance is arranged obliquely with respect to the central axis of the elliptical cavity.
Wherein the light exit is located at a central axis of the elliptical cavity.
And the cut surface is cut so as to pass through the second focal point.
Wherein the angle between the light inlet and the central axis of the elliptical cavity is between 5 and 45 degrees.
The light collecting unit includes:
A hemispherical lens having a spherical surface disposed at a first focal point of the elliptical cavity while facing the second focal point; And
And a tapered optical fiber optic plate disposed in contact with a plane of the hemispherical lens.
Wherein one end of the tapered optical fiber optical plate is disposed in contact with a plane of the hemispherical lens,
And the other end of the tapered optical fiber optical plate is disposed at the light outlet of the handpiece body.
Further comprising a focusing lens having a plane-convex structure connecting the other end of the tapered optical fiber optical plate and the optical fiber.
The handpiece body portion is in the form of a cylinder,
Wherein the light inlet and the light outlet are disposed on an upper surface of the cylinder,
Wherein the cut surface is disposed on a lower surface of the cylinder.
Wherein the surface of the elliptical cavity is coated with a metal.
Wherein the handpiece body portion includes a first body portion and a second body portion,
The first body portion may be made of a metal material or an elliptic surface of the elliptic cavity may be coated with a metal,
Wherein the second body portion has a surface cut perpendicularly to a center line connecting the first focus and the second focus at a first focus of the elliptical cavity and is formed of a transparent material. .
The laser handpiece comprises:
A handpiece body portion having an elliptical cavity inside; And
And a light collecting portion disposed at a first focus of the elliptical cavity to collect the reflected light reflected by the elliptical cavity,
Wherein the handpiece body has a cut surface that is not perpendicular to the central axis of the elliptical cavity,
The cut surface passes through a second focus,
The cut surface does not pass the first focus and the second focus at the same time,
Wherein the second focus of the elliptical cavity is disposed in the article to be treated.
Wherein the handpiece body portion includes a light inlet connected to the elliptical cavity and through which the pulsed laser beam passes, and a light outlet communicated to the outside of the radiant light collected by the light collecting portion,
The cut surface providing a plane in contact with the object to be processed,
The light collecting unit includes:
A hemispherical lens having a spherical surface disposed at a first focal point of the elliptical cavity while facing the second focal point; And
And a tapered optical fiber optic plate disposed in contact with a plane of the hemispherical lens.
An optical fiber for transmitting the radiation light collected from the handpiece;
A spectroscope for receiving a radiated light from the optical fiber and measuring a radiation spectrum according to a wavelength; And
And a processor for analyzing the radiation spectrum,
The handpiece comprises:
A handpiece body portion having an elliptical cavity inside; And
And a light collecting portion disposed at a first focus of the elliptical cavity to collect the reflected light reflected from the elliptical cavity,
Wherein the handpiece body has a cut surface that is not perpendicular to the central axis of the elliptical cavity,
The cut surface passes through a second focus,
The cut surface does not pass the first focus and the second focus at the same time,
Wherein the second focus of the elliptical cavity is disposed in the article to be treated.
Wherein the handpiece further comprises a parallel optical lens for focusing the parallel light through the collimating lens and for converting the emitted light into parallel light after focusing through the collimating lens, Scorpion device.
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KR1020160023734A KR101782784B1 (en) | 2016-02-26 | 2016-02-26 | Laser induced breakdown spectroscopy apparatus and highly sensitive handpiece |
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WO2019237242A1 (en) * | 2018-06-12 | 2019-12-19 | 深圳达闼科技控股有限公司 | Detection system and signal enhancement device |
CN113624733A (en) * | 2021-06-25 | 2021-11-09 | 港湾之星健康生物(深圳)有限公司 | High-efficiency scattered light condensing assembly |
CN113390509B (en) * | 2021-08-16 | 2021-12-10 | 港湾之星健康生物(深圳)有限公司 | Ultra-micro Raman-Stokes scattered light sensor |
CN117420120B (en) * | 2023-12-19 | 2024-04-09 | 哈尔滨工业大学 | Pulse photoelectric probe monitoring device for intermediate product of plasma chemical reaction |
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JP2006061683A (en) * | 2004-07-30 | 2006-03-09 | Olympus Corp | Endoscopic apparatus |
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JP2006061683A (en) * | 2004-07-30 | 2006-03-09 | Olympus Corp | Endoscopic apparatus |
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