KR101761755B1

KR101761755B1 - Transfer coating material with excellent low gloss and releasability and transfer method using the same

Info

Publication number: KR101761755B1
Application number: KR1020150043555A
Authority: KR
Inventors: 정신혜; 이상무; 김판수; 정연우
Original assignee: (주)건양
Priority date: 2015-03-27
Filing date: 2015-03-27
Publication date: 2017-07-27
Also published as: KR20160116269A

Abstract

And a transfer method using the same, which is excellent in mattness and releasability, which is capable of imparting a matt effect to the surface of a coating material coated with a transfer agent by exhibiting excellent releasability without a release agent treatment at the time of transfer.
The non-glare coating material having excellent gloss and releasability according to the present invention comprises a carrier base layer made of any one of PET (Polyethyleneterephthalate), PE (Polyethylene) and PP (Polypropylene) films, and an acrylic matte coating composition applied on the carrier base layer And a matte acrylic coating layer formed by curing, wherein the acrylic matte coating composition comprises: a main body portion composed of 20 to 50% by weight of an acrylic polyol resin, 0.5 to 3% by weight of a filler, 0.5 to 1% by weight of a dispersant, And 5 to 10 parts by weight based on 100 parts by weight of the topical part, wherein the curing agent is composed of a curing accelerator and a solvent, and the wax and the quencher are added together as the filler.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a coating material for non-light-fast transfer which is excellent in mattness and releasability and a transfer method using the same. BACKGROUND ART [0002]

The present invention relates to a coating material for non-light-transmitting transfer, and a transfer method using the same, and more particularly, to a method for transferring a matting carrier film for use in a carrier substrate layer, which comprises a matting acrylic coating layer formed by a two- Which exhibits excellent releasability irrespective of treatment or disposal, and thus exhibits excellent releasability even without a releasing agent treatment at the time of transferring, thereby providing a matting effect on the surface of the coated material by transfer, and a matte- Transfer method.

Generally, coating means coating the surface of an object with a coating agent to protect the surface of the object. That is, the coating is carried out for the purpose of keeping the appearance of the object clean for a long period of time by preventing the surface of the object from being scratched by external impact or the like.

The method for forming the hard coat layer for protecting the surface of the interior sheet and the insert film of the automobile may be a UV curing method or a direct coating method by applying a coating composition or an indirect coating method by transfer or the like.

The UV curing method is a coating method which complements the thermosetting coating method. Since it can be completely cured for a short time, it does not require high temperature and long time curing condition, and since it is cured by ultraviolet ray irradiation, It is possible to hard coat a hard material such as wood, paper, etc., which is difficult to heat-cure at high temperature.

In addition, there is an advantage that the solvent can be minimized. However, it is difficult to cure an angular portion or a concavo-convex portion instead of a flat surface, and heat generated in a UV lamp may cause thermal deformation of the product, and there is a large difference in curing speed depending on the difference in thickness. In addition, although the UV curing method is not directly applied heat, it is a method of directly coating the material to be adhered through ultraviolet ray irradiation, which may cause the surface of the material to be damaged.

In addition, the direct coating method using the coating composition may cause surface damage of the material by the solvent or the like and warping during drying of the solvent.

In order to solve this problem, a hard coat is applied using a transfer method, which is an indirect coating method, and a release agent coated with a releasing material to prevent the coating material from sticking to a transfer film is used at the time of transferring.

However, the PET surface which is not coated with the releasing agent has a high gloss, and thus the surface of the PET surface is very bright, and thus the surface light can be displayed.

A related prior art is Korean Patent Laid-Open Publication No. 10-2011-0034928 (published on Apr. 26, 2011), which discloses a transferring surface material coated on an adhering material.

It is an object of the present invention to provide a matte carrier film which is formed by a two-part acrylic matte coating composition having improved releasability and which exhibits excellent releasability regardless of whether or not the matting carrier film used in the carrier substrate layer is treated with the releasing agent, The present invention also provides a matte-free coating material having excellent mattness and releasability that can exhibit excellent releasability even without treatment and can impart a matting effect to the surface of a coated material coated with a transfer, and a transfer method using the same.

In order to accomplish the above object, there is provided a matte-releasing coating material excellent in matting and releasability according to an embodiment of the present invention includes a carrier base layer made of any one of PET (Polyethyleneterephthalate), PE (Polyethylene) and PP Wherein the acrylic matting coating composition comprises 20 to 50% by weight of an acrylic polyol resin, 0.5 to 3% by weight of a filler, 0.5 to 1% by weight of a dispersing agent, A top part composed of the remaining solvent; And 5 to 10 parts by weight based on 100 parts by weight of the topical part, wherein the curing agent is composed of a curing accelerator and a solvent, and the wax and the quencher are added together as the filler.

In order to accomplish the above object, there is provided a transfer method using a matte-releasing coating material excellent in matting property and releasability according to an embodiment of the present invention, which comprises: (a) a step of transferring a film formed of any one of PET (polyethylene terephthalate), PE Applying and curing an acrylic matte coating composition on an upper surface of the carrier substrate layer to form a matte acrylic coating layer; (b) applying and curing a primer on the surface of the matte acrylic coating layer to form a primer layer; (c) adhering the primer layer to the adhering material and thermally transferring the primer layer; And (d) removing the carrier substrate layer from the matte acrylic coating layer and the primer layer.

The matte-free coating material having excellent matting properties and releasability according to the present invention and the transferring method using the same can be produced by forming a matte acrylic coating layer formed by a two-pack type acrylic matte coating composition having improved mattness and releasability on a carrier substrate layer, Layer exhibits excellent releasability irrespective of whether or not the matting carrier film used in the layer has been treated. Thus, excellent releasability can be exhibited even without a releasing agent treatment at the time of transfer, and a matte effect can be imparted to the surface of the adherend material coated by transfer. As a result, the surface roughness of the carrier base layer is so severe that even when the adhesion between the carrier base layer and the matte acrylic coating layer is increased, excellent transferability can be exhibited.

In addition, the matte-free coating material having excellent matting properties and releasability according to the present invention can impart a matting effect to a matte acrylic coating layer coated on a carrier substrate layer even when a matte-treated carrier base layer is used, .

1 is a flowchart showing a transfer method using a non-light-transmittable coating material according to an embodiment of the present invention.
2 is a schematic view of a process for illustrating a transfer method using a matte-free coating material according to an embodiment of the present invention.

BRIEF DESCRIPTION OF THE DRAWINGS The advantages and features of the present invention, and how to accomplish them, will become apparent by reference to the embodiments described in detail below with reference to the accompanying drawings. It should be understood, however, that the invention is not limited to the disclosed embodiments, but may be embodied in many different forms and should not be construed as being limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art. Is provided to fully convey the scope of the invention to those skilled in the art, and the invention is only defined by the scope of the claims. Like reference numerals refer to like elements throughout the specification.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, the present invention will be described in detail with reference to the accompanying drawings, in which a matte-free coating material having excellent matte and releasability and a transfer method using the same are described in detail.

A matte-free coating material with excellent matte and releasability

The non-light-transmittable coating material having excellent matte and releasability according to an embodiment of the present invention includes a carrier base layer composed of any one of PET (Polyethyleneterephthalate), PE (polyethylene) and PP (polypropylene) And a matte acrylic coating layer formed by coating and curing.

Particularly, the non-light-transmittable coating material having excellent matting property and releasability according to the embodiment of the present invention includes the matte acrylic coating layer formed by the two-part type acrylic matte coating composition having improved releasability, It exhibits excellent releasability irrespective of whether it is treated or not, and thus exhibits excellent releasability even without a releasing agent treatment at the time of transfer, so that a matting effect can be imparted to the surface of the adherend material coated by transfer.

As a result, the surface roughness of the carrier base layer is so severe that even when the adhesion between the carrier base layer and the matte acrylic coating layer is increased, excellent transferability can be exhibited.

Further, according to the embodiment of the present invention, a matte-free coating material having excellent matting properties and releasability can impart a matting effect to a matte acrylic coating layer coated on a carrier substrate layer even if a matte- .

In the present invention, the acrylic matte coating composition comprises 20 to 50% by weight of an acrylic polyol resin, 0.5 to 3% by weight of a filler, 0.5 to 1% by weight of a dispersant, and 5 to 10 And a curing agent part composed of a curing accelerator and a solvent, wherein the filler is added together with a wax and a light extinction agent.

The acrylic polyol resin corresponds to the main component of the acrylic matte coating composition.

Such an acrylic polyol resin may be selected from the group consisting of methyl methacrylate, styrene, n-butyl methacrylate, t-butyl methacrylate, isobutyl methacrylate, Acrylate, isobutyl methacrylate, isopropyl methacrylate, isobonyl acrylate, acrylonitrile, isobonyllacrylate, and ethyl methacrylate. ) And having a hydroxyl value of 10 to 100, is used.

At this time, it is preferable to add a wax and a light-quenching agent together as a filler in order to simultaneously improve matting property and releasability. It is preferable that such a filler is added at a content ratio of 0.5 to 3% by weight based on the total weight of the main part based on the sum of the wax and the quencher. If the addition amount of the filler is less than 0.5% by weight, the addition amount is insufficient, so that it may be difficult to exhibit the above effect properly. On the contrary, when the amount of the filler added is more than 3% by weight, the releasability is excessively increased and the adhesion with the adhering material is reduced.

The wax is added for mold release. And, the quencher is added to realize a matte effect, and it plays a role of controlling the glossiness. At this time, as the wax, at least one selected from polyethylene, polytetrafluoroethylene and polyamide can be used. As the quencher, at least one of silica, boride, nitride, carbide and alumina may be used.

It is more preferable that the wax and the quencher are added in a weight ratio of 5: 1 to 1: 5. This is because if the addition ratio of the wax and the quencher is added within the above range, the desired releasability is secured and at the same time, What we can do is confirmed through experiments.

Also, in the present invention, the curing agent part may be selected from the group consisting of hexamethylene diisocyanate trimer (HDT), isophorone diisocyanate (IPDI), cyclohexylmethanediisocyanate (H12MDI), methylene diphenyl diisocyanate MDI) and toluene diisocyanate (TDI), and an isocyanate having an NCO equivalent of 10 to 23%.

At this time, it is preferable that the curing agent is added in an amount of 5 to 10 parts by weight based on 100 parts by weight of the main portion. When the curing agent is added in an amount of less than 5 parts by weight based on 100 parts by weight of the main portion, there is a problem that the workability of the acrylic matte coating composition is good but the surface hardness is low. On the contrary, when the curing agent is added in a large amount in excess of 10 parts by weight with respect to 100 parts by weight of the main portion, there is a problem that the viscosity of the acrylic matte coating composition increases and coating workability is lowered.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, with reference to the accompanying drawings, a description will be made of a transfer method using a matte-releasing coating material having excellent matte and releasability according to an embodiment of the present invention.

FIG. 1 is a process flow chart illustrating a transfer method using a non-light-use coating material according to an embodiment of the present invention, and FIG. 2 is a process diagram illustrating a transfer method using a non-light-use coating material according to an embodiment of the present invention.

Referring to FIGS. 1 and 2, a transfer method using a matte-releasing coating material having excellent matte and releasability according to an embodiment of the present invention includes a step of forming a matte acrylic coating layer (S110) on a carrier base layer, (S120), a primer layer thermal transfer step (S130), and a carrier substrate layer removal step (S140) on the adherend.

Forming a matte acrylic coating layer on the carrier base layer

In step S110 of forming a matte acrylic coating layer on the carrier base layer, an acrylic matte coating composition is applied and cured on the upper surface of the carrier base layer 110 made of any one of PET (polyethylene terephthalate), PE (polyethylene) and PP Thereby forming a matte acrylic coating layer 120.

As described above, the acrylic matte coating composition is a coating composition comprising 20 to 50% by weight of an acrylic polyol resin, 0.5 to 3% by weight of a filler, 0.5 to 1% by weight of a dispersant, 10 parts by weight, and contains a curing accelerator and a curing agent part composed of a solvent, and wax and a quencher are added together as a filler.

Formation of primer layer on matte acrylic coating layer

In the primer layer forming step (S120) on the matte acrylic coating layer, a primer layer 130 is formed by applying and curing a primer on the upper surface of the matte acrylic coating layer 120.

In this case, the primer is applied in order to enhance adhesion with the adherend, and it is necessary to change the resin component of the primer so that the matte acrylic coating layer 120 can be adhered to the adherend 200 depending on the type of the adherend 200 It is important. Specifically, an acrylic / vinyl primer is used when the material of the adherend 200 is either PVC or ABS, and an ester / vinyl primer is used when the material 200 of the adherend 200 is PETG desirable.

It is preferable that such a primer is added in a content ratio of 10 to 30% by weight of the total weight based on the solid content. If the solid content of the primer is less than 10% by weight, the adhesion may be weakened during the continuous transfer process, which may cause a release problem or peeling of the coating layer after transfer. On the contrary, when the solid content of the primer exceeds 30% by weight, the coating mark of the adhesive may pass through the transparent coating layer to damage the surface appearance and reduce the surface hardness.

The primer layer thermal transfer

In the primer layer thermal transfer step (S130), the primer layer 130 is closely adhered to the adherend 200 and is thermally transferred. Thus, the primer layer 130 is laminated on the adherend 200 and transferred.

Removal of carrier substrate layer

In the step of removing the carrier substrate layer (S140), the carrier substrate layer 110 is removed from the matte acrylic coating layer 120 and the primer layer 130. The removal of the carrier substrate layer 110 exposes the matte acrylic coating layer 120 to the outside.

As described above, in the present invention, the matte acrylic coating layer 120 formed by the two-pack type acrylic matte coating composition having improved matte properties and releasability is formed on the carrier substrate layer 110, Regardless of whether or not the carrier film is treated with the releasing agent, thereby exhibiting excellent releasability even without the releasing agent treatment at the time of transferring, thereby imparting a matting effect to the surface of the adherend 200 coated by the transferring.

As a result, even if the surface roughness of the carrier substrate layer 110 is severe and the adhesion between the interface between the carrier substrate layer 110 and the matte acrylic coating layer 120 is increased, excellent transferability can be exhibited.

Example

Hereinafter, the configuration and operation of the present invention will be described in more detail with reference to preferred embodiments of the present invention. It is to be understood, however, that the same is by way of illustration and example only and is not to be construed in a limiting sense.

The contents not described here are sufficiently technically inferior to those skilled in the art, and a description thereof will be omitted.

1. Manufacture and transfer of coating materials for non-matt coatings

Example 1

40 wt% of acrylic polyol resin, 0.5 wt% of polyethylene and silica as a filler in a weight ratio of 1: 1, 0.5 wt% of BYK dispersant and 59 wt% of MEK (methyl ethyl ketone) were mixed to form a main part.

Next, 100 parts by weight of the main portion and 7 parts by weight of the curing agent portion having 11 isocyanate were mixed with 100 parts by weight of the main portion, and then coated on the PET film to a thickness of 6 탆 (dry) to prepare a matte acrylic coating layer .

Next, a primer composed of 10 wt% of a PMMA resin, 10 wt% of a Pvc-Vinyl acetate copolymer and 80 wt% of a mixed solution diluted with an organic solvent in a weight ratio of toluene and MEK 1: 1 was applied on a matte acrylic coating layer to a thickness of 2 μm And then cured at 50 DEG C for 24 hours to form a matte acrylic coating layer and a primer layer.

Next, the primer layer was adhered to the adhered material of PVC to thermally transfer the coating layer, and then the PET film was removed from the matte acrylic coating layer and the primer layer.

Example 2

Except that 42 wt% of acrylic polyol resin, 1.0 wt% of polyethylene and silica as a filler in a weight ratio of 1: 1, 0.5 wt% of BYK dispersant and 56.5 wt% of MEK (Methyl ethyl ketone) 1, the coating material for non-light-transmittable was prepared and transferred.

Example 3

Except that 45 wt% of an acrylic polyol resin, 2.0 wt% of polyethylene and silica as a filler, 0.5 wt% of BYK dispersant and 52.5 wt% of MEK (Methyl ethyl ketone) were mixed to form a main part, Preparation and transfer of transfer coating materials were carried out.

Example 4

Except that 44 wt% of acrylic polyol resin, 3.0 wt% of polyethylene and silica as a filler, 0.5 wt% of BYK dispersant and 52.5 wt% of MEK (Methyl ethyl ketone) were mixed to form a main part, Preparation and transfer of transfer coating materials were carried out.

Example 5

A primer composed of 15 wt% of PMMA resin, 15 wt% of Pvc-Vinyl acetate copolymer and 70 wt% of a mixed solution diluted with an organic solvent in a weight ratio of toluene and MEK of 1: 1 was coated on a matte acrylic coating layer prepared in Example 3, , And then cured at 50 DEG C for 24 hours to form a primer layer.

Next, the matte acrylic coating layer and the primer layer were adhered to the adhered material of PVC and thermally transferred, and then the PET film was removed from the matte acrylic coating layer and the primer layer.

Example 6

A primer composed of 15 wt% of a polyester resin, 11 wt% of a Pvc-Vinyl acetate copolymer and 74 wt% of a mixed solution diluted with an organic solvent in a weight ratio of toluene and MEK of 1: 1 was coated on a matte acrylic coating layer prepared in Example 3, , And then cured at 50 DEG C for 24 hours to form a primer layer.

Next, the matte acrylic coating layer and the primer layer were closely adhered to the adherend of PETG, and then the PET film was removed from the matte acrylic coating layer and the primer layer.

Comparative Example 1

Except that 42 wt% of acrylic polyol resin, 3.5 wt% of polyethylene and silica as a filler in a weight ratio of 1: 1, 0.5 wt% of BYK dispersant, and 54 wt% of MEK (Methyl ethyl ketone) The coating material for non-light-transmittable coating was prepared and transferred.

Comparative Example 2

Except that 45 wt% of acrylic polyol resin, 0.1 wt% of polyethylene and silica as a filler in a weight ratio of 1: 1, 0.5 wt% of BYK dispersant and 54.4 wt% of MEK (methyl ethyl ketone) 1, the coating material for non-light-transmittable was prepared and transferred.

Comparative Example 3

The PET film was removed from the matte acrylic coating layer after the thermal adhesion with the adhered material of PVC without forming the primer layer on the matte acrylic coating layer prepared according to Example 3.

Comparative Example 4

The PET film was removed from the matte acrylic coating layer prepared in Example 3 after the PET film was adhered to the adhered material of the PETG material without forming the primer layer, and then the PET film was removed from the matte acrylic coating layer.

2. Property evaluation

Table 1 shows the final physical properties after adhering the non-light-emitting coating material according to Examples 1 to 6 and Comparative Examples 1 to 4 to the adherend.

1) scratch resistance

The scratch resistance was judged visually by scratching with a nail.

2) Glossiness

For gloss evaluation, the gloss of the specimen was measured at an incident angle of 60 DEG using a gloss meter.

3) Adhesiveness

The adhesiveness was evaluated by cross-cutting 100 square (10 × 10) squares with 11 equi-spaced parallel lines at 1 mm intervals and 11 equi-spaced parallel lines crossing the same using a diamond needle. The KS M ISO It was judged as to whether or not the tape peeled off and fell off according to the 5981 standard.

[Table 1]

Referring to Table 1, in Examples 1 to 6, it was confirmed that both of the properties in terms of transferability, adhesion and scratch resistance were excellent, or good physical properties were exhibited. Particularly, in the case of Examples 1 to 6, the glossiness was measured to be 10 to 34. In this case, the gloss of Example 4 was the lowest of 10, but the scratch resistance was only a moderate level. On the other hand, in Example 3, while exhibiting desired gloss properties, excellent properties in terms of transferring property, scratch resistance, .

On the other hand, in the case of Comparative Example 1, it was confirmed that the wax and the extinction agent were added in a large amount exceeding the range suggested by the present invention, and thus the transfer property, gloss and adhesion were excellent, but the scratch resistance was poor .

In addition, in the case of Comparative Example 2, when a small amount of the wax + quencher was added in an amount of 0.1 wt%, the transfer property, scratch resistance and adhesion were excellent, but it was confirmed that the desired gloss property was not satisfied.

Also, as in the case of Comparative Examples 3 and 4, it was confirmed that when the primer treatment was not carried out, the adhesion was poor.

Although the preferred embodiments of the present invention have been disclosed for illustrative purposes, those skilled in the art will appreciate that various modifications, additions and substitutions are possible, without departing from the scope and spirit of the invention as disclosed in the accompanying claims. These changes and modifications may be made without departing from the scope of the present invention. Accordingly, the scope of the present invention should be determined by the following claims.

S110: Step of forming a matte acrylic coating layer on the carrier base layer
S120: Step of forming a primer layer on a matte acrylic coating layer
S130: Thermal transfer of the primer layer to the adherend
S140: Carrier substrate layer removal step
110: carrier substrate layer
120: Matte acrylic coating layer
130: primer layer
200: adhered material

Claims

And a matte acrylic coating layer formed by coating and curing an acrylic matte coating composition on the carrier base layer composed of any one of PET (polyethylene terephthalate), PE (polyethylene) and PP (polypropylene)
The acrylic matte coating composition comprises:
20 to 50% by weight of an acrylic polyol resin, 0.5 to 3% by weight of a filler, 0.5 to 1% by weight of a dispersant, and the balance solvent; And
And 5 to 10 parts by weight based on 100 parts by weight of the main portion, and a curing agent portion comprising a curing accelerator and a solvent,
Wherein the wax and the quencher are added together as the filler, and the wax and the quencher are added in a weight ratio of 5: 1 to 1: 5.

The method according to claim 1,
The acrylic polyol resin
But are not limited to, methyl methacrylate, styrene, n-butyl methacrylate, t-butyl methacrylate, isobutyl methacrylate, One selected from isopropyl methacrylate, isobonyllacrylate, acrylonitrile, isobonyllacrylate and ethyl methacrylate is used as the solvent. By weight based on 100% by weight of the acrylic monomer, and has a hydroxyl value of 10 to 100. The coating material for non-light-fast transferability is excellent in mattness and releasability.

delete

The method according to claim 1,
The wax
And at least one selected from the group consisting of polyethylene, polytetrafluoroethylene, and polyamide.

The method according to claim 1,
The quencher
Silica, boride, nitride, carbide, and alumina. The matting and coating material according to claim 1,

delete

A transfer method using the non-light-sensitive transfer coating material having excellent matte properties and releasability according to any one of claims 1, 2, 4, and 5,
(a) coating and curing an acrylic matte coating composition on a top surface of a carrier substrate layer made of any one of PET (polyethylene terephthalate), PE (polyethylene) and PP (polypropylene) films to form a matte acrylic coating layer;
(b) applying and curing a primer on the surface of the matte acrylic coating layer to form a primer layer;
(c) adhering the primer layer to the adhering material and thermally transferring the primer layer; And
(d) removing the carrier substrate layer from the matte acrylic coating layer and the primer layer,
Wherein the wax and the quencher are added together as a filler of the matte acrylic coating layer, and the wax and the quencher are added in a weight ratio of 5: 1 to 1: 5. Transcription method.

8. The method of claim 7,
In the step (c)
The adherend
PVC, ABS, and PETG resin. The method of claim 1, wherein the matting agent is a polyester resin.

8. The method of claim 7,
When the material of the adhering material is either PVC or ABS, an acrylic or vinyl copolymer type primer is used,
Wherein when the material of the adhering material is PETG, an ester and a vinyl copolymer type primer are used.