KR101723213B1 - Functional compositions for the dyeing or printing of the fabric - Google Patents
Functional compositions for the dyeing or printing of the fabric Download PDFInfo
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- KR101723213B1 KR101723213B1 KR1020160014016A KR20160014016A KR101723213B1 KR 101723213 B1 KR101723213 B1 KR 101723213B1 KR 1020160014016 A KR1020160014016 A KR 1020160014016A KR 20160014016 A KR20160014016 A KR 20160014016A KR 101723213 B1 KR101723213 B1 KR 101723213B1
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0076—Dyeing with mineral dye
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/655—Compounds containing ammonium groups
- D06P1/66—Compounds containing ammonium groups containing quaternary ammonium groups
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67383—Inorganic compounds containing silicon
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/14—Dyeability
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
Abstract
Description
본 발명은 원단의 염색 또는 나염을 위한 기능성 조성물에 관한 것으로, 보다 상세하게는 원단을 전면 염색하는 침염이나 혹은 부분 염색하는 나염시 첨가물로 첨가되어 원단으로 제직 또는 편직된 직물의 기능성을 향상시킨 원단의 염색 또는 나염을 위한 기능성 조성물에 관한 것이다.The present invention relates to a functional composition for dyeing or printing fabrics, and more particularly, to a functional composition for dyeing or printing fabrics, which comprises a fabric which is added as an additive during dyeing or partial dyeing, To a functional composition for dyeing or printing.
섬유제품은 원단을 제직 또는 편직하여 만들어진다.Textile products are made by weaving or knitting fabrics.
이때, 섬유제품에 색상을 내기 위해서는 원단을 염색하여야 한다.At this time, in order to give a color to the textile product, the fabric should be dyed.
원단의 염색은 전면 염색하는 침염과, 부분 염색하는 나염이 있으며, 염색 재료 측면에서는 자연계에 존재하는 동식물 및 광물로부터 색소를 얻고 이것을 이용하여 염색하는 자연염색과, 합성염료를 이용하여 염색하는 합성염색이 있다.Dyeing of fabrics is dyed with full dyeing and dyeing with partial dyeing. On the aspect of dyeing materials, natural dyes are obtained by obtaining dye from flora, fauna and minerals present in nature, dyeing using this, and synthetic dyeing .
오늘날 대부분은 합성염색 방식으로 염색이 이루어지며, 이를 통해 풍부한 색상과 염색공정의 용이성, 견뢰도가 높은 염색물을 획득하고 있다.Today, most of them are dyed with synthetic dyeing method, and they have obtained a rich coloring, easiness of dyeing process, and fast dyeing.
때문에, 염색과 관련된 염료의 개발은 주로 색감을 다양하고 미려하면서 화려하게 내는 방법이나 혹은 인체 무해한 염료를 합성하는 방법이나 혹은 염색공정에서 발생되는 부산물, 폐기물에 의한 환경오염 방지방법 등에 국한되어 왔다.Therefore, the development of dyes related to dyeing has mainly been limited to a method of producing colorful, beautiful and gorgeous colors, a method of synthesizing harmless dyes or a method of preventing environmental pollution caused by by-products and wastes generated in a dyeing process.
그런데, 최근 웰빙의 문화가 확산되면서 패션제품의 고급화, 친환경화, 기능성화 되면서 다양한 기능성 특성, 이를 테면 제직 또는 편직된 직물을 사용하는 사람의 혈액순환을 촉진하거나 항균성을 높이거나 소취성, 항알레르기성, 음이온 방출, 원적외선 방출을 통한 건강 증진에 기여할 수 있는 기술 개발은 미진한 상태이다.However, recently, as the culture of well-being has spread, fashion products have become more sophisticated, environmentally friendly, and functionalized, and various functional characteristics such as promoting blood circulation of a person using a woven or knitted fabric, increasing antimicrobial activity, , Development of technologies that can contribute to health promotion through anion emission and far-infrared radiation emission is in a state of insufficient.
본 발명은 상술한 바와 같은 종래 기술상의 제반 문제점을 감안하여 이를 해결하고자 창출된 것으로, 원단을 전면 염색하는 침염이나 혹은 부분 염색하는 나염시 첨가물로 첨가되어 원단의 기능성을 향상시킨 원단의 염색 또는 나염을 위한 기능성 조성물을 제공함에 그 주된 목적이 있다.The present invention has been made in view of the above-mentioned problems in the prior art, and has been made to overcome the above-mentioned problems, and it is an object of the present invention to provide a method for dyeing or printing dyed fabrics, The present invention is directed to a functional composition comprising
본 발명은 상기한 목적을 달성하기 위한 수단으로, 원단을 염색하는 염료에 상기 염료 100중량부에 대하여 2-10중량부의 범위로 첨가되는 기능성 조성물로서, 원단의 염색 또는 나염을 위한 상기 기능성 조성물은, 기능성 조성물 100중량부에 대하여 계피유에 녹차 미분을 3:1의 중량비로 섞은 제1혼합물 3-5중량부, 백금 미분 2-4중량부, 토르말린 미분 2-4중량부, 제올라이트 미분 2-4중량부, 위치하젤 잎 추출액 10-15중량부, 실리카 나노입자 5-10중량부, 실리콘유 15-20중량부, 아민 4차 암모늄 2-4중량부, 2-(2'-하이드록시-5'메틸페닐)벤조트리아졸 3-5중량부, 트라가칸타 1-2중량부, 자수정 미분 2-4중량부를 포함하여 이루어진 것을 특징으로 하는 원단의 염색 또는 나염을 위한 기능성 조성물을 제공한다.The present invention provides a functional composition added to a dye for dyeing a fabric in a range of 2-10 parts by weight with respect to 100 parts by weight of the dye. The functional composition for dyeing or printing a fabric includes 3-5 parts by weight of a first mixture obtained by mixing green tea fine powder in a weight ratio of 3: 1 to cinnamon oil, 2-4 parts by weight of platinum fine powder, 2-4 parts by weight of tourmaline fine powder, 2-4 parts by weight of zeolite fine powder 10-15 parts by weight of HAZEL LEAF extract, 5-10 parts by weight of silica nanoparticles, 15-20 parts by weight of silicone oil, 2-4 parts by weight of quaternary ammonium amine, 2- (2'-hydroxy-5 3-5 parts by weight of methylphenyl) benzotriazole, 1-2 parts by weight of tragacanth and 2-4 parts by weight of an amethyst fine powder.
이때, 상기 기능성 조성물에는 상기 기능성 조성물 100중량부에 대하여, 규회석 미분과 CMC(CarboxyMethyl Cellulose)가 1:1의 중량비로 혼합된 제2혼합물이 4-6중량부 더 첨가될 수 있다.At this time, 4-6 parts by weight of a second mixture in which a wollastonite powder and CMC (CarboxyMethyl Cellulose) are mixed at a weight ratio of 1: 1 relative to 100 parts by weight of the functional composition may be further added.
또한, 상기 기능성 조성물에는 상기 기능성 조성물 100중량부에 대하여, 카올린이 2-3중량부 더 첨가될 수 있다.The functional composition may further contain 2-3 parts by weight of kaolin based on 100 parts by weight of the functional composition.
본 발명에 따르면, 천연물질이어서 친환경적이고 인체에 무해하며, 첨가 혼합시 염료의 성질을 전혀 변화시키지 않으면서 첨가물 각각이 갖는 특성들이 원단에 그대로 표출되게 하여 직물의 기능성을 향상시키는 효과를 얻을 수 있다.According to the present invention, it is possible to obtain the effect of improving the functionality of the fabric by allowing the properties of each additive to be expressed directly on the fabric without changing the properties of the dye at the time of addition and mixing as it is natural and environmentally friendly and harmless to the human body .
이하에서는, 본 발명에 따른 바람직한 실시예를 보다 상세하게 설명하기로 한다.Hereinafter, preferred embodiments according to the present invention will be described in detail.
본 발명 설명에 앞서, 이하의 특정한 구조 내지 기능적 설명들은 단지 본 발명의 개념에 따른 실시예를 설명하기 위한 목적으로 예시된 것으로, 본 발명의 개념에 따른 실시예들은 다양한 형태로 실시될 수 있으며, 본 명세서에 설명된 실시예들에 한정되는 것으로 해석되어서는 아니된다.Before describing the present invention, the following specific structural or functional descriptions are merely illustrative for the purpose of describing an embodiment according to the concept of the present invention, and embodiments according to the concept of the present invention may be embodied in various forms, And should not be construed as limited to the embodiments described herein.
또한, 본 발명의 개념에 따른 실시예는 다양한 변경을 가할 수 있고 여러 가지 형태를 가질 수 있으므로, 특정 실시예들은 본 명세서에 상세하게 설명하고자 한다. 그러나, 이는 본 발명의 개념에 따른 실시예들을 특정한 개시 형태에 한정하려는 것이 아니며, 본 발명의 사상 및 기술 범위에 포함되는 모든 변경물, 균등물 내지 대체물을 포함하는 것으로 이해되어야 한다.In addition, embodiments according to the concept of the present invention can make various changes and have various forms, so that specific embodiments are described in detail herein. However, it should be understood that the embodiments according to the concept of the present invention are not intended to limit the present invention to specific modes of operation, but include all modifications, equivalents and alternatives falling within the spirit and scope of the present invention.
본 발명에 따른 원단의 염색 또는 나염을 위한 기능성 조성물은 원단을 제직 또는 편직하여 제조되는 직물에 함유되는 첨가제로 작용하여 직물 본연의 기능은 해치지 않으면서 특유한 기능만 보강하되, 친환경적이면서 인체 유익성분을 방출할 수 있도록 구성된다.The functional composition for dyeing or printing fabrics according to the present invention acts as an additive contained in fabrics produced by weaving or knitting fabrics so that only the specific functions are reinforced without harming the original function of the fabric and the environmentally friendly, And the like.
특히, 원단으로 제직 또는 편직되는 직물을 만들기 위해 염료를 이용하여 원단을 염색할 때 염색성, 부착성, 경화성 및 고정안정성을 저해하지 않아야 하고, 또한 수축이 일어나지 않도록 하여 직물의 고품질화를 유도하면서 첨가제 고유의 기능적 특성이 발현되도록 구성하여야 한다.In particular, when dyeing a fabric using a dye to make a fabric that is woven or knitted with the fabric, it should not hinder dyeability, adhesion, curability, and fixing stability, Should be constructed so that the functional characteristics of the material can be expressed.
이를 위해, 본 발명에 따른 원단의 염색 또는 나염을 위한 기능성 조성물은 염색을 위한 염료 100중량부에 대하여 2-10중량부의 범위로 첨가된다.For this purpose, the functional composition for dyeing or printing the fabric according to the present invention is added in the range of 2-10 parts by weight based on 100 parts by weight of the dye for dyeing.
이것은 최소량을 함유케 하여 염료 본연의 특성을 저해하지 않으면서 효과적으로 기능성만 강화시키기 위한 것이다. 여기에서, 염료는 합성염료를 의미한다.This is intended to contain only the minimum amount and effectively enhance the functionality without impairing the inherent properties of the dye. Here, the dye means a synthetic dye.
이러한 기능성 조성물은 상기 기능성 조성물 100중량부에 대하여, 계피유에 녹차 미분을 3:1의 중량비로 섞은 제1혼합물 3-5중량부, 백금 미분 2-4중량부, 토르말린 미분 2-4중량부, 제올라이트 미분 2-4중량부, 위치하젤 잎 추출액 10-15중량부, 실리카 나노입자 15-20중량부, 실리콘유 1-3중량부, 아민 4차 암모늄 2-4중량부, 2-(2'-하이드록시-5'메틸페닐)벤조트리아졸 3-5중량부, 트라가칸타 1-2중량부, 자수정 미분 2-4중량부를 포함하여 이루어진다.This functional composition was prepared by mixing 3-5 parts by weight of a first mixture obtained by mixing green tea powder with cinnamon oil in a weight ratio of 3: 1, 2-4 parts by weight of platinum fine powder, 2-4 parts by weight of tourmaline fine powder, 2 to 4 parts by weight of a zeolite derivative, 10 to 15 parts by weight of a hydrogel extract, 15 to 20 parts by weight of a silica nanoparticle, 1-3 parts by weight of a silicone oil, 2-4 parts by weight of an amine quaternary ammonium, -5-methylphenyl) benzotriazole, 1-2 parts by weight of tragacanth and 2-4 parts by weight of an amethyst fine powder.
이때, '미분'은 미세한 분말이라는 의미로서, 본 발명에서는 0.1-0.3㎛의 입도를 갖는 것으로 한정되며, 혼합된 기능성 조성물은 콜로이드에 가까운 리퀴드 상태를 유지한다.Herein, 'fine powder' means fine powder, and in the present invention is limited to having a particle size of 0.1-0.3 μm, and the mixed functional composition maintains liquid state close to colloid.
그리고, 상기 계피유는 정유(Essential oil)로서 계피 나무껍질 혹은 계피잎으로부터 추출되는 액상의 기름이며, 혼용성을 증대시키기 위해 녹차 미분을 계피유에 혼합하여 제1혼합물을 만들어 일정비율로 첨가되도록 구성된다.In addition, the cinnamon oil is a liquid oil extracted from cinnamon bark or cinnamon leaf as an essential oil. In order to increase compatibility, a green tea fraction is mixed with cinnamon oil to form a first mixture to be added at a certain ratio .
이는 녹차의 효능을 극대화시키기 위한 것으로, 계피나무 자체도 황색포도상구균, 병원성 대장균인 O-157, 고초균, 적리균, 티푸스균, 폐렴구균, 탄저균, 살모넬라균, 콜레라균 등을 사멸시키는데 효과가 있는 것으로 학계에 보고되어 있다.This is to maximize the efficacy of green tea. Cinnamon tree itself is also effective in killing Staphylococcus aureus, O-157 which is pathogenic Escherichia coli, Bacillus subtilis, Agrobacterium, Typhoid, Streptococcus pneumoniae, Anthrax, Salmonella and Cholera It is reported in academia.
또한, 고래로 계피는 충치균의 성장과 억제에 효과가 있어 소금 대용으로 많이 사용되어 온 성분인 바, 옛날에는 정제수에 계피분말을 분산시켜 활용했지만, 본 발명에서는 계피유를 추출하여 여기에다 녹차 미분을 분산시킴으로써 계피가 갖는 항균성, 감미성, pH조절기능과 함께 녹차가 갖는 항균성을 배가시킬 수 있도록 일종의 에멀젼 형태로 첨가 구성된다.In addition, cinnamon as a whale has an effect on the growth and inhibition of the deciduous germs and is a component that has been widely used as a substitute for salt. In the past, cinnamon powder was dispersed and used in purified water. In the present invention, And thus, it is added in the form of an emulsion so as to double the antimicrobial properties of green tea with the antimicrobial properties, sweetness and pH controlling function of cinnamon.
이때, 제1혼합물의 중량비를 3:1로 한정하는 이유는 염색시 염료의 부착성, 고정안정성 및 분산성을 저해하지 않도록 하면서 녹차 미분이 수지와 잘 혼용되게 하기 위한 것이다.In this case, the reason why the weight ratio of the first mixture is limited to 3: 1 is that the green tea powder is mixed well with the resin while preventing the dye adhesion, fixing stability and dispersibility during dyeing.
그리고, 상기 녹차 미분은 5월 중순에서 6월 하순 사이에 채엽한 잎을 찐 다음 냉각 건조시킨 후 빻아서 낸 가루를 사용함이 바람직하다.It is preferable that the green tea powder is used in the middle of May to the end of June, and the dried leaf is steamed, followed by cooling and drying.
이러한 녹차는 주지된 바와 같이, 차로 복용하였을 때 정신적인 활력을 주어 기분을 상쾌하게 만들어 주고 각종 세균의 성장을 억제하며 중독과 감기를 예방하여 식후의 차는 입안 세균의 번식을 억제하는 효과가 있으며, 청의 콜레스테롤 함량을 감소시켜 고혈압과 동맥경화의 발병을 억제함은 물론, 암을 예방하고 암세포의 증식을 억제하는 효과와 간장의 독성물질을 분해 배설시켜 주는 것으로 알려져 있다.As is well known, such green tea has the effect of refreshing the mood by giving mental vitality when taken by car, inhibiting the growth of various bacteria, preventing poisoning and cold, and preventing the reproduction of mouth bacteria, It is known to reduce the cholesterol content of blue to inhibit the development of hypertension and arteriosclerosis, to prevent cancer, to inhibit cancer cell proliferation, and to excrete toxins of liver.
이것은 녹차에 함유된 발암억제 물질인 폴리페놀 성분이 풍부하기 때문인 것으로 알려져 있으며, 녹차 속 카테킨이 몸속 중금속이나 니코틴과 결합해 체외로 배출하는 효과가 있으며 음식을 과다섭취해 쌓이는 글리코겐을 분해해 신진대사를 촉진시켜 주어 체중을 줄이는 비만방지 효과까지 있다고 보고되어 있다.It is known to be due to the abundance of polyphenols, which are carcinogenic inhibitors contained in green tea. It is known that catechin in green tea binds with heavy metals or nicotine in the body and excretes it out of the body. It decomposes glycogen, To reduce weight and to prevent the effect of obesity is reported.
특히, 본 발명에서는 녹차에 함유된 사포닌의 항균작용과, 탄닌과 시스틴에 의한 방사능 등 중금속 억제작용을 적극적으로 활용하도록 구성된다.Particularly, in the present invention, the antimicrobial activity of saponin contained in green tea and the action of inhibiting heavy metals such as radioactivity due to tannin and cystine are actively utilized.
다만, 녹차에 포함된 색소성분은 항균제 첨가물로 사용될 때 원재료의 색상을 변색시킬 수 있으므로 녹차의 색소성분을 제거하고 사용함이 바람직하다.However, it is preferable to remove the coloring component of green tea because the coloring component contained in green tea may discolor the color of the raw material when used as an antimicrobial additive.
때문에, 본 발명에서는 이러한 녹차를 피부와 접촉되는 수지 용기 혹은 아기 용품 등의 플라스틱 제품에 활용하면 친환경적이면서 인체 무해하고, 염료의 특성을 변화시키지 않으면서 항균성을 증대시킬 수 있게 된다.Therefore, in the present invention, such a green tea can be applied to plastic products such as resin containers or baby articles which are in contact with the skin, thereby being environmentally friendly and harmless to the human body, and the antimicrobial properties can be increased without changing the characteristics of the dyes.
하지만, 본 발명은 원단의 염색 또는 나염을 위한 기능성 조성물로서 주된 성분이 아닌 첨가제(물)이기 때문에 과량 함유시킬 수 없고, 특히 항균효능을 발휘할 수 있는 범위내에서 최적정량인 3-5중량부 범위로 한정됨이 바람직하다.However, since the present invention is a functional composition for dyeing or printing fabrics, it can not be contained in an excessive amount because it is an additive (water) which is not a main ingredient. In the range of 3-5 parts by weight .
그리고, 상기 백금 미분도 탁월한 항균력과 산화력으로 의료기구, 공기청정기 필터, 항균코팅제 등으로 사용되는 백금을 분말화시킨 것으로, 상기 제1혼합물과 함께 특히, 곰팡이균, 미생물의 서식 억제를 위해 첨가 사용된다. Also, the platinum fine powder is obtained by pulverizing platinum used as a medical instrument, an air purifier filter, an antibacterial coating agent or the like with excellent antimicrobial and oxidative power, and in addition to the first mixture, it is added for the inhibition of fungi and microorganisms do.
다만, 고가이기 때문에 적정량을 사용해야 함은 물론이거니와 더 분명한 이유는 압출 성형시 흐름성을 저해하지 않아야 하기 때문에 상기 범위로 한정하여야 한다.However, since it is expensive, it is necessary to use an appropriate amount, and more clearly, the flowability should not be inhibited during extrusion molding.
또한, 상기 토르말린 미분은 수정과 같은 결정구조를 가지는 육방정계에 속하는 광물로서, 대략 4~14 미크론의 파장대역의 전자파를 영구적으로 발생시키는 물질로 알려져 있다.Further, the tourmaline fine powder is a mineral belonging to the hexagonal system having a crystal structure such as crystal, and is known as a material which permanently generates electromagnetic waves having a wavelength band of approximately 4 to 14 microns.
알려진 바에 따르면, 4-14 미크론의 파장대역의 전자파는 동ㆍ식물의 세포를 활성화하거나, 단백질을 합성하거나, 오염수를 정화하는 효능이 있다고 보고되어 있는 바, 본 발명에서는 이러한 효능이 염료를 통해 염색되는 것에 의해 직물 상에 표출되게 함으로써 사용자의 건강 증진에 기여하도록 하기 위한 것으로 염색성, 즉 부착성과 전자파 방출특성을 고려하여 상기 범위로 한정되어 첨가된다.It has been reported that electromagnetic waves in the wavelength band of 4 to 14 microns have been reported to activate cells of plants and plants, to synthesize proteins, and to purify contaminated water. In the present invention, To be displayed on the fabric by being dyed, thereby contributing to the health promotion of the user, and is limited to the above range in consideration of dyeability, i.e., adhesion and electromagnetic wave emission characteristics.
그리고, 상기 제올라이트 미분은 비석이라고도 알려진 알루미늄 규산염 광물의 일종으로, 대표적인 원적외선 방사물질이고, 이온교환성을 갖는 물질이다.The zeolite fine powder is a kind of aluminum silicate mineral, also known as zeolite, and is a typical far-infrared ray emitting material, and is a material having ion exchangeability.
본 발명에서는 이러한 이온교환성을 이용하여 항균성을 더 강화시키면서 인체에 유익한 원적외선 방사 기능이 함께 구현되도록 하기 위해 첨가되며, 4중량부를 초과하면 흡착성이 강하여 다른 성분들의 분산성을 떨어뜨리고, 2중량부 미만으로 첨가되면 원적외선 방사능력이 떨어지므로 상기 범위로 한정하여야 한다.In the present invention, it is added in order to enhance the antimicrobial activity by using the ion exchange property and simultaneously realize the far-infrared radiation function beneficial to the human body. If it exceeds 4 parts by weight, the adsorption property is strong, , The far-infrared ray emission capability is deteriorated. Therefore, the range should be limited to the above range.
또한, 상기 위치하젤 잎 추출액은 아열대에 서식하는 낙엽수의 일종인 위치하젤(Witch Hazel, 학명:Hamamelis Virginiana)에서 약용으로 쓰는 부위인 잎에서 추출된 추출액을 사용하며, 소취 및 항균 기능을 가지고 있다.In addition, the above-mentioned Huzel leaf extract uses extracts extracted from leaves, which are used for medicinal purposes, in Witch Hazel (Hamamelis Virginiana), a kind of deciduous tree that lives in the subtropical zone, and has a deodorizing and antibacterial function.
특히, 소취 기능은 냄새를 잡아 주기 때문에 성형되는 제품에 영향을 미치지 않도록 하는 아주 중요한 성분이며, 항균성도 보조하는 성분인 바, 본 발명에서는 소취성과 성형성을 모두 고려하여 10-15중량부 범위로 한정되어야 한다.In particular, the deodorizing function is a very important component that prevents odor from affecting the molded product and is a component that also assists the antibacterial property. In the present invention, the deodorizing function is in the range of 10-15 parts by weight Should be limited.
아울러, 상기 실리카 나노입자는 수산화기로 표면이 개질된 실리카 나노입자를 사용함이 바람직하다.In addition, it is preferable that the silica nanoparticles are silica nanoparticles whose surface is modified with a hydroxyl group.
이러한 실리카 나노입자는 투명성, 기계적 강도(부착성) 및 내열성을 향상시키기 위해 첨가되는데, 특히 원단 표면에 피막을 형성시켜 표피를 보호하는 역할을 하므로 5중량부 미만으로 첨가되면 피막 효과를 얻기 힘들고, 10중량부를 초과하면 분산성을 약화시키므로 상기 범위로 한정되어야 한다.These silica nanoparticles are added in order to improve transparency, mechanical strength (adhesion) and heat resistance. In particular, the silica nanoparticles serve to protect the epidermis by forming a coating on the surface of the fabric, so that when it is added in an amount of less than 5 parts by weight, If the amount is more than 10 parts by weight, the dispersibility is deteriorated.
또한, 상기 실리콘유는 수지와의 혼합시 윤활성을 증대시킬 뿐만 아니라, 혼합물의 콜로이드상에 가까운 리퀴드화를 위한 것으로 15-20중량부로 한정되어 첨가되어야 하는데, 15중량부 미만은 윤활성을 기대하기 어렵고, 20중량부를 초과하면 점도를 떨어뜨리므로 상기 범위로 한정되어야 한다.In addition, the silicone oil not only increases the lubricity upon mixing with the resin but also is added in a limited amount to 15-20 parts by weight for liquidification close to the colloid of the mixture. When the amount is less than 15 parts by weight, , And if it exceeds 20 parts by weight, the viscosity is lowered.
그리고, 상기 아민 4차 암모늄은 질소기를 함유한 일종의 계면활성 기능을 갖는 정전방지제로서 대전 방지 기능을 증대시켜 정전기 발생을 억제하게 된다.The amine quaternary ammonium is a type of antistatic agent having a surfactant function containing a nitrogen group, thereby enhancing the antistatic function and suppressing the generation of static electricity.
나아가, 상기 2-(2'-하이드록시-5'메틸페닐)벤조트리아졸은 자외선 차단 효과를 얻기 위해 첨가되는 것으로, 3-5중량부 범위가 바람직하다.Further, the 2- (2'-hydroxy-5'methylphenyl) benzotriazole is added to obtain an ultraviolet blocking effect, and it is preferably in the range of 3-5 parts by weight.
아울러, 상기 트라가칸타는 일종의 고무성분으로서 점도 조절을 위해 첨가되면, 과량 첨가되면 점도 조절기능이 유명무실해지므로 1-2중량부 범위에서 첨가되어야 한다.In addition, when the above-mentioned tragacantha is added as a kind of rubber component for viscosity control, if it is added in an excess amount, viscosity control function becomes unfavorable, so it should be added in the range of 1-2 parts by weight.
또한, 상기 자수정(紫水晶,amethyst) 미분은 자주색의 여러 색조를 가진 수정으로서, 규산염광물에 속하는 육방정계 화강암이고, 육각형 구조를 가지며 1초에 32786 Khz에 해당하는 규칙적인 진동과 94%의 원적외선 방출량을 가지고 있어 체온유지, 심장강화, 진통, 염증 치료 등에 탁월한 것으로 보고되어 있다.The amethyst is a hexagonal granite belonging to the silicate mineral. It has a hexagonal structure and has regular vibration corresponding to 32786 Khz per second and 94% far infrared ray It has been reported to excel in maintaining body temperature, strengthening the heart, treating pain, and treating inflammation.
본 발명에서는 원적외선 방출 기능을 극대화시키기 위해 2-4중량부의 범위 내에서 미분 형태로 첨가된다.In the present invention, it is added in the form of a fine powder within a range of 2-4 parts by weight in order to maximize the far-infrared ray emitting function.
덧붙여, 상기 원단의 염색 또는 나염을 위한 기능성 조성물에는 치수안정성을 증대시키기 위해 상기 기능성 조성물 100중량부에 대하여, 규회석 미분과 CMC(CarboxyMethyl Cellulose)가 1:1의 중량비로 혼합된 제2혼합물이 4-6중량부 더 첨가될 수 있다.In order to increase the dimensional stability of the functional composition for dyeing or kneading the fabric, a second mixture in which a wollastonite powder and CMC (CarboxyMethyl Cellulose) were mixed at a weight ratio of 1: 1 relative to 100 parts by weight of the functional composition was 4 -6 parts by weight may be further added.
여기에서, 상기 규회석 미분은 바늘형태의 침상구조를 하고 있는 규회석을 분말화 한 것을 사용하는데, 이는 인장강도 및 굴곡강도를 증대시키며 폴리머 바인더인 CMC(CarboxyMethyl Cellulose)와 혼용하여 함량을 증가시켜도 점성을 크게 증가시키지 않기 때문이다.Here, the wollastonite fine powder is obtained by pulverizing wollastonite having a needle-like needle-like structure, which increases the tensile strength and flexural strength, and is mixed with a polymer binder, CarboxyMethyl Cellulose (CMC) It does not greatly increase.
이러한 규회석은 저흡습성이고, 결정수가 없으므로 치수안정성이 뛰어나 수지 제품의 성형 후 안정화를 유도한다. 이를 위해, 본 발명에서는 혼합물 형태로 첨가된다.Such wollastonite is low in hygroscopicity and excellent in dimensional stability since there is no crystal number, thereby inducing stabilization after molding of a resin product. For this purpose, they are added in the form of a mixture in the present invention.
뿐만 아니라, 염료의 부착성과 고정안정성 및 경화성을 향상시키기 위해 상기 기능성 조성물 100중량부에 대하여, 카올린을 2-3중량부 더 첨가할 수 있다.In addition, 2-3 parts by weight of kaolin may be added to 100 parts by weight of the functional composition in order to improve the adhesion of the dye, the fixing stability and the curability.
이때, 카올린은 카올리나이트와 할로이사나이트를 주성분으로 하고, 습기를 가지면 점력이 생겨나 가소성을 갖게 되고, 건조하면 굳어지는 성질을 갖고 있기 때문에 기계적 강도(부착성, 고정안정성 등)를 향상시키는 특성도 있다.At this time, kaolin has characteristics that kaolinite and halonsanite are the main components, and when it has moisture, there is a tendency to generate a softening force and a hardness when dried, thereby improving the mechanical strength (adhesion, fixing stability, etc.) .
하지만, 3중량부를 초과하면 가소성이 우수해지는 장점은 있으나 결정화되기 쉬워 오히려 분산성을 저해하고, 2중량부 미만으로 첨가되면 기계적 강도 향상에 기여할 수 없으므로 상기 범위로 한정되어야 한다.However, if the amount is more than 3 parts by weight, it is advantageous that the plasticity is excellent, but it is easy to be crystallized, which deteriorates the dispersibility. If the amount is less than 2 parts by weight, it can not contribute to the improvement of mechanical strength.
이하, 실시예에 대하여 설명한다.Hereinafter, examples will be described.
[실시예 1][Example 1]
본 발명 실시예 1은 기능성 조성물 100중량부에 대하여 계피유에 녹차 미분을 3:1의 중량비로 섞은 제1혼합물 4중량부, 백금 미분 3중량부, 토르말린 미분 3중량부, 제올라이트 미분 3중량부, 위치하젤 잎 추출액 12중량부, 실리카 나노입자 8중량부, 실리콘유 20중량부, 아민 4차 암모늄 3중량부, 2-(2'-하이드록시-5'메틸페닐)벤조트리아졸 5중량부, 트라가칸타 2중량부, 자수정 미분 4중량부로 이루어진 원단의 염색 또는 나염을 위한 기능성 조성물을 만든 후, 원단 염색을 위한 염료 100중량부에 상기 기능성 조성물을 5중량부 첨가시켜 염색하고, 건조 후 편직하여 직물 샘플을 만들었다.In Example 1 of the present invention, 4 parts by weight of a first mixture in which green tea fine powder was mixed with cinnamon oil in a weight ratio of 3: 1, 3 parts by weight of platinum fine powder, 3 parts by weight of tourmaline fine powder, 3 parts by weight of zeolite fine powder, Location: 12 parts by weight of Hezel Leaf Extract, 8 parts by weight of silica nanoparticles, 20 parts by weight of silicone oil, 3 parts by weight of amine quaternary ammonium, 5 parts by weight of 2- (2'-hydroxy-5'methylphenyl) benzotriazole, 2 parts by weight of gum arabic, 4 parts by weight of amethyst fine powder, and 5 parts by weight of the above-mentioned functional composition were added to 100 parts by weight of a dye for fabric dyeing, followed by drying and knitting A fabric sample was made.
[실시예 2][Example 2]
실시예 1과 동일하게 구성하되, 원단의 염색 또는 나염을 위한 기능성 조성물을 규회석 미분과 CMC가 혼합된 제2혼합물이 5중량부 더 첨가된 것을 사용하였다.A functional composition for fabric dyeing or printing was prepared in the same manner as in Example 1 except that 5 parts by weight of a second mixture in which wollastonite powder and CMC were mixed was used.
[실시예 3][Example 3]
실시예 1과 동일하게 구성하되, 원단의 염색 또는 나염을 위한 기능성 조성물을 카올린이 3중량부 더 첨가된 것을 사용하였다.A functional composition for fabric dyeing or printing was prepared in the same manner as in Example 1 except that 3 parts by weight of kaolin was added.
[실시예 4][Example 4]
실시예 2와 동일하게 하되, 원단의 염색 또는 나염을 위한 기능성 조성물에 카올린을 2중량부 더 첨가하였다.2 parts by weight of kaolin was added to the functional composition for fabric dyeing or printing in the same manner as in Example 2.
[비교예 1][Comparative Example 1]
염색되지 않은 원단을 이용하여 편직한 직물 샘플을 만들었다.A fabric sample was knitted using an unstained fabric.
먼저, 본 발명에 따른 원단의 염색 또는 나염을 위한 기능성 조성물의 첨가로 인해 항균성이 있는지 여부를 확인하였다.First, it was confirmed whether antimicrobial activity was caused by the addition of the functional composition for dyeing or printing the fabric according to the present invention.
이를 위해, 실시예 1,2,3,4 및 비교예 1의 샘플 표면에 곰팡이 균주를 각각 1㎖씩 3군데 나누어 떨어뜨린 후 5일, 10일, 15일간 항균 활성여부를 체크하였다.To this end, 1 ml of each of the fungal strains was divided into three portions on the surface of the samples of Examples 1, 2, 3, 4 and Comparative Example 1, and the antibacterial activity was checked for 5, 10, and 15 days.
이때, 시험방법은 ASTMG-21에 따랐고, 활성여부는 배양된 균주의 성장 유무로 확인하였으며, 시험한 곰팡이 균주는 아스퍼질러스 나이거(Aspergillus niger) ATCC 9642, 페니실리움 피노필럼(Penicillium pinophilum) ATCC 11797, 캐토미움 글로보솜(Chaetomium globosom) ATCC 6205 였다.At this time, the test method was according to ASTMG-21, and the activity was confirmed by the presence or absence of the growth of the cultured strain. The tested fungus strains were Aspergillus niger ATCC 9642, Penicillium pinophilum, ATCC 11797, Chaetomium globosom ATCC 6205.
시험 결과, 5일, 10일, 15일간 실시예 1,2,3,4의 샘플 모두에서 균주의 성장이 관찰되지 않았다. 그러나, 비교예 1의 샘플에서는 균주의 성장이 관측되었다.As a result of the test, no growth of the strain was observed in all of the samples of Examples 1, 2, 3 and 4 for 5 days, 10 days and 15 days. However, the growth of the strain was observed in the sample of Comparative Example 1.
이를 통해, 본 발명에 따른 원단의 염색 또는 나염을 위한 기능성 조성물의 첨가로 인해 항균성을 확보할 수 있는 것으로 확인하였다.Thus, it was confirmed that the antimicrobial properties can be ensured by adding the functional composition for dyeing or printing the fabric according to the present invention.
또한, 원적외선 방사특성을 확인하기 위해, FT-IR 스펙트로메터를 이용하여 KFIA-F1-1005에 의거 원적외선 방사시험을 실시하였다.Further, in order to confirm the far-infrared radiation characteristic, a far-infrared ray emission test was conducted according to KFIA-F1-1005 using an FT-IR spectrometer.
실시결과, 30℃에서 원적외선 방사율(유효 원적외선 파장대: 5-20㎛)은 실시예 1,2,3,4의 경우, 각각 0.742, 0.458, 0.801, 0.800으로 확인되었으나, 비교예 1의 경우는 거의 제로에 가까웠다.As a result, far infrared ray emissivity (effective far infrared ray wavelength band: 5-20 μm) at 30 ° C. was confirmed to be 0.742, 0.458, 0.801 and 0.800 in Examples 1, 2, 3 and 4, It was near zero.
그리고, 방사에너지(W/㎡)에 있어서도 실시예 1,2,3,4는 각각 2.33×102, 2.42×102, 2.49×102, 2.88×102로 나타났으나, 비교예 1은 거의 측정되지 않았다.In Examples 1, 2 , 3 and 4, the radiant energy (W / m 2) was 2.33 × 10 2 , 2.42 × 10 2 , 2.49 × 10 2 and 2.88 × 10 2 , Little was measured.
아울러, 자외선에 장시간(36시간) 노출시 변색 여부를 확인하였으나, 실시예 1,2,3,4는 변색되지 않았으나, 비교예 1은 약간 변색되었다.In addition, when it was exposed to ultraviolet rays for a long period of time (36 hours), it was confirmed whether or not discoloration occurred. In Examples 1, 2, 3 and 4, discoloration was not observed.
Claims (3)
상기 기능성 조성물은,
기능성 조성물 100중량부에 대하여 계피유에 녹차 미분을 3:1의 중량비로 섞은 제1혼합물 3-5중량부, 백금 미분 2-4중량부, 토르말린 미분 2-4중량부, 제올라이트 미분 2-4중량부, 위치하젤 잎 추출액 10-15중량부, 실리카 나노입자 5-10중량부, 실리콘유 15-20중량부, 아민 4차 암모늄 2-4중량부, 2-(2'-하이드록시-5'메틸페닐)벤조트리아졸 3-5중량부, 트라가칸타 1-2중량부, 자수정 미분 2-4중량부를 포함하여 이루어진 것을 특징으로 하는 원단의 염색 또는 나염을 위한 기능성 조성물.
A functional composition to be added to a dye for dyeing a fabric in a range of 2-10 parts by weight based on 100 parts by weight of the dye,
The above-
3-5 parts by weight of a first mixture obtained by mixing green tea fine powder at a weight ratio of 3: 1 with respect to 100 parts by weight of the functional composition, 2-4 parts by weight of platinum fine powder, 2-4 parts by weight of tourmaline fine powder, 2-4 parts by weight of zeolite fine powder 10-15 parts by weight of HAZEL LEAF extract, 5-10 parts by weight of silica nanoparticles, 15-20 parts by weight of silicone oil, 2-4 parts by weight of quaternary ammonium amine, 2- (2'-hydroxy-5 ' Methylphenyl) benzotriazole, 1-2 parts by weight of tragacanth and 2-4 parts by weight of an amethyst fine powder.
상기 기능성 조성물에는 상기 기능성 조성물 100중량부에 대하여, 규회석 미분과 CMC(CarboxyMethyl Cellulose)가 1:1의 중량비로 혼합된 제2혼합물이 4-6중량부 더 첨가되는 것을 특징으로 하는 원단의 염색 또는 나염을 위한 기능성 조성물.
The method of claim 1,
Wherein 4-6 parts by weight of a second mixture of wollastonite powder and CMC (carboxymethyl cellulose) in a weight ratio of 1: 1 is further added to the above-mentioned functional composition. Functional composition.
상기 기능성 조성물에는 상기 기능성 조성물 100중량부에 대하여, 카올린이 2-3중량부 더 첨가되는 것을 특징으로 하는 원단의 염색 또는 나염을 위한 기능성 조성물.The method of claim 1,
Wherein the functional composition further comprises 2-3 parts by weight of kaolin per 100 parts by weight of the functional composition.
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