KR101714731B1 - Compact type NDIR gas analyzer - Google Patents
Compact type NDIR gas analyzer Download PDFInfo
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- KR101714731B1 KR101714731B1 KR1020150160721A KR20150160721A KR101714731B1 KR 101714731 B1 KR101714731 B1 KR 101714731B1 KR 1020150160721 A KR1020150160721 A KR 1020150160721A KR 20150160721 A KR20150160721 A KR 20150160721A KR 101714731 B1 KR101714731 B1 KR 101714731B1
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- infrared
- gas
- sample gas
- source
- detector
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- 238000001745 non-dispersive infrared spectroscopy Methods 0.000 title description 2
- 230000003287 optical effect Effects 0.000 claims abstract description 67
- 239000006096 absorbing agent Substances 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 9
- 238000005259 measurement Methods 0.000 abstract description 12
- 239000003344 environmental pollutant Substances 0.000 abstract description 3
- 231100000719 pollutant Toxicity 0.000 abstract description 3
- 230000035945 sensitivity Effects 0.000 abstract description 3
- 230000015556 catabolic process Effects 0.000 abstract description 2
- 238000006731 degradation reaction Methods 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 148
- 239000006185 dispersion Substances 0.000 description 12
- 238000004868 gas analysis Methods 0.000 description 6
- 230000006866 deterioration Effects 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 241000282414 Homo sapiens Species 0.000 description 1
- 239000000809 air pollutant Substances 0.000 description 1
- 231100001243 air pollutant Toxicity 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910001120 nichrome Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
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Classifications
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
- G01N21/3504—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing gases, e.g. multi-gas analysis
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/01—Arrangements or apparatus for facilitating the optical investigation
- G01N21/03—Cuvette constructions
- G01N21/031—Multipass arrangements
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/01—Arrangements or apparatus for facilitating the optical investigation
- G01N21/03—Cuvette constructions
- G01N21/05—Flow-through cuvettes
- G01N2021/052—Tubular type; cavity type; multireflective
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2201/00—Features of devices classified in G01N21/00
- G01N2201/06—Illumination; Optics
- G01N2201/063—Illuminating optical parts
- G01N2201/0636—Reflectors
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2201/00—Features of devices classified in G01N21/00
- G01N2201/06—Illumination; Optics
- G01N2201/063—Illuminating optical parts
- G01N2201/0636—Reflectors
- G01N2201/0637—Elliptic
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2201/00—Features of devices classified in G01N21/00
- G01N2201/06—Illumination; Optics
- G01N2201/068—Optics, miscellaneous
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- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
Abstract
Description
The present invention relates to a non-dispersive infrared gas analyzer, and more particularly, to a compact non-dispersive infrared gas analyzer capable of preventing light loss and a decrease in detector sensitivity.
While the rapid development of modern industrial society has improved the quality of life of human beings, it caused various environmental problems due to indiscreet natural degradation and development. Particularly, due to the rapid increase of energy consumption due to industrial development, the emission of air pollutant gas has increased rapidly, and the pollution problem caused by this is facing serious situation.
In order to prevent this, it is essential to understand the type and concentration of the gas emitted from various pollutants such as factories or automobile exhaust pipes.
Non-dispersive infrared (NDIR) analysis is widely used as a method of measuring the composition and concentration of such gases. The gas analyzer using non-dispersive infrared spectroscopy is a method of measuring the gas concentration by measuring the light absorptance with respect to the concentration using the characteristic that gas molecules absorb light (infrared rays) having a specific wavelength. That is, since specific gas molecules have a characteristic of absorbing only light of a specific wavelength band, it is possible to measure light by irradiating gas molecules with light of various wavelengths and filtering out only the light of the wavelength band absorbed by the gas molecules.
The nondispersive infrared gas analyzer requires only optical filters that transmit only the wavelengths to the photodetector, so that the system is simple and less costly than the dispersion system, and the gas selectivity and measurement reliability are high.
A commonly used non-dispersive infrared gas analyzer includes an infrared source, a rotating sector, an infrared detector, an optical filter, and a sample gas chamber. The light emitted from the infrared source is brought into contact with the gas molecules to be measured in the sample gas chamber, and light of a specific wavelength is absorbed by the gas molecules. The gas concentration can be measured using the principle that the amount of light absorbed increases as the concentration of the gas to be measured increases and the output voltage of the detector decreases.
However, the non-dispersive infrared gas analyzer not only causes optical loss due to deterioration of the infrared source over time, but also causes deviation of the measured value according to the intensity of the initially incident light, The accurate measurement value can not be obtained. Therefore, there is a problem in that it is necessary to carry out calibration from time to time to correct it, or to additionally provide a pretreatment and management facility.
In order to solve such a problem, Korean Unexamined Patent Publication No. 2009-0034668 discloses a comparative cell packed with SPAN gas in addition to a reference cell and a sample cell. In the process of analyzing the sample gas, Using measured values measured using infrared rays passed through the reference cell and infrared rays passing through the comparison cell and infrared rays passing through the comparison cell and the sample cell, Discloses an NDIR gas analyzer capable of simultaneously correcting a zero point deviation and a span deviation.
However, it is possible to correct the deviation of measured values due to optical loss and other external environment. However, since the reference cell and the comparative cell for calibrating the minimum and maximum values of the analysis sensor are provided, the measured values of the component and concentration of the sample There is a problem in that not only the time to obtain is prolonged but also the additional economical cost is incurred as the size of the whole apparatus is increased.
Disclosure of Invention Technical Problem [8] The present invention has been made in an effort to solve the above-mentioned problems, and it is an object of the present invention to provide a gas analyzer which is simple in comparison with a conventional gas analyzer, And an infrared gas analyzer for analyzing the infrared gas.
In order to achieve the above object, the compact non-dispersive infrared gas analyzer according to the present invention comprises an
The compact non-dispersive infrared gas analyzer according to the present invention includes an
The compact non-dispersive infrared gas analyzer according to the present invention includes an
In the compact non-dispersive infrared gas analysis apparatus according to the present invention, the
In the compact non-dispersive infrared gas analysis apparatus according to the present invention, the
In the compact non-dispersion infrared gas analysis apparatus according to the present invention, the
In the compact non-dispersive IR gas analyzer according to the present invention, the
The compact non-dispersive IR gas analyzing apparatus according to the present invention has an advantage that the entire apparatus can be small-sized because one zero gas is used.
Further, the gas analyzing apparatus according to the present invention has the effect of shortening the measuring time because the path of the light for correcting the zero point deviation is short.
Further, the gas analyzing apparatus according to the present invention can periodically intercept infrared rays traveling to the infrared detector, thereby extending the service life of the apparatus.
Further, the gas analyzer according to the present invention has an effect that it is possible to easily measure various types of polluted gas.
1 is a top view of a compact non-dispersive IR gas analyzer according to a first embodiment of the present invention.
Fig. 2 is an enlarged view of the dotted line portion in Fig. 1. Fig.
3 is a stereoscopic view of Fig.
4 is a front view of a) rotating sector and b) a front view of an optical filter according to a first embodiment of the present invention.
5 is a front view of a) rotating sector and b) front view of an optical filter according to a second embodiment of the present invention.
Hereinafter, a compact non-dispersion infrared gas analyzer according to the present invention will be described in detail with reference to the accompanying drawings.
Fig. 1 is a plan view of a compact type non-dispersion infrared gas analysis apparatus according to the first embodiment of the present invention, Fig. 2 is an enlarged view of a dotted line portion of Fig. 1, and Fig. 3 is a stereoscopic view of Fig.
1 to 3, the compact non-dispersion infrared gas analyzer according to the first embodiment of the present invention includes an
The
The
The
The
Meanwhile, the zero
Here, the
Since the
The
The
The
The rotating
The rotating
In order to continuously contact the infrared ray irradiated from the
The
The absorber 502 functions to absorb infrared rays emitted from the
The
The
The
As shown in the drawing, the first
The first transparent window transmits infrared rays that have passed through the
Here, the
5 is a diagram illustrating an
The
That is, the
Although FIG. 5 shows four types of filters, this is only an example, and it is obvious to those skilled in the art that the type of filter can be selected in consideration of the kind of gas to be analyzed.
In order to have the path of the infrared ray reflected by the
[Formula 1]
L = a x tan (180-2 alpha)
In Equation 1, L represents the length between the
The
Hereinafter, the principle of measurement of gaseous pollutants using the compact type non-dispersion infrared gas analyzer of the present invention will be described.
First, the principle of measurement according to the non-dispersion infrared gas analyzer in which the
The sample gas to be measured is introduced into the
At this time, in the
On the other hand, when the infrared ray passing through the
When the infrared ray passing through the
On the other hand, when the infrared ray passing through the
The following is a description of a measurement principle according to a non-dispersion infrared gas analyzer in which an
The sample gas to be measured is introduced into the
Hereinafter, the flow of the infrared rays is the same as that of the non-dispersion infrared gas analysis apparatus having the
Next, the principle of measurement according to the non-dispersion infrared gas analyzer having the
The sample gas to be measured is introduced into the
When the infrared ray hits the
When the infrared ray passes straight through the
Hereinafter, the flow of the infrared rays is the same as that of the non-dispersion infrared gas analysis apparatus having the
Hereinafter, the principle of measuring various kinds of polluted gas according to the second embodiment of the present invention will be described.
When the
That is, the zero point deviation is corrected by the same principle as described in the first embodiment, and the infrared ray having passed through the zero
When the
By rotating the
It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the spirit and scope of the invention will be.
100: Infrared source 200: Infrared detector
300: zero gas 400: optical filter
401: first optical filter 402: second optical filter
403: third optical filter 404: fourth optical filter
500: rotating sector
501: reflector 502: absorber
503: hollow part
600: sample gas chamber
601: Gas inlet 602: Gas outlet
603: first concave mirror 604: second concave mirror
605: first transparent window 606: second transparent window
607: reflector
700: motor
Claims (7)
An infrared ray detector 200 spaced apart from the infrared ray source 100 by a predetermined distance;
A zero gas (300) located in front of the infrared source (100) and the infrared detector (200);
An optical filter (400) located in front of the zero gas (300) and selectively transmitting only a desired wavelength region of infrared rays irradiated from the infrared source (100);
A rotating sector 500 located in front of the optical filter 400 and modulating the infrared ray passing through the optical filter 400 into intermittent light; And
And a sample gas chamber (600) having a space portion capable of receiving a sample gas to be analyzed which is located on a traveling path of infrared rays that has passed through the rotating sector (500)
The rotating sector 500 has a conical shape including a reflector 501 capable of reflecting infrared rays, an absorber 502 capable of absorbing infrared rays, and a hollow portion 503 through which infrared rays pass, Is reflected by the infrared detector 200 and the infrared light irradiated to the hollow portion 503 is reflected by the infrared detector 200 after passing through the sample gas chamber 600 A compact non-dispersive infrared gas analyzer.
An infrared ray detector 200 spaced apart from the infrared ray source 100 by a predetermined distance;
A zero gas (300) located in front of the infrared source (100) and the infrared detector (200);
An optical filter 400 positioned between the infrared source 100 and the zero gas 300 and selectively transmitting only a desired wavelength region of the infrared light irradiated from the infrared source 100;
A rotating sector 500 located in front of the zero gas 300 and modulating the infrared ray having passed through the zero gas 300 into intermittent light; And
And a sample gas chamber (600) having a space portion capable of receiving a sample gas to be analyzed which is located on a traveling path of infrared rays that has passed through the rotating sector (500)
The rotating sector 500 has a conical shape including a reflector 501 capable of reflecting infrared rays, an absorber 502 capable of absorbing infrared rays, and a hollow portion 503 through which infrared rays pass, Is reflected by the infrared detector 200 and the infrared light irradiated to the hollow portion 503 is reflected by the infrared detector 200 after passing through the sample gas chamber 600 A compact non-dispersive infrared gas analyzer.
An infrared ray detector 200 spaced apart from the infrared ray source 100 by a predetermined distance;
A zero gas (300) located in front of the infrared source (100) and the infrared detector (200);
A rotating sector 500 located in front of the zero gas 300 and modulating the infrared ray having passed through the zero gas 300 into intermittent light;
A sample gas chamber 600 having a space portion capable of receiving a sample gas to be analyzed which is located on a traveling path of infrared rays that has passed through the rotating sector 500; And an optical filter (400) disposed between the rotating sector (500) and the sample gas chamber (600) and selectively transmitting only a desired wavelength region of infrared rays irradiated from the infrared source (100)
The rotating sector 500 has a conical shape including a reflector 501 capable of reflecting infrared rays, an absorber 502 capable of absorbing infrared rays, and a hollow portion 503 through which infrared rays pass, Is reflected by the infrared detector 200 and the infrared light irradiated to the hollow portion 503 is reflected by the infrared detector 200 after passing through the sample gas chamber 600 A compact non-dispersive infrared gas analyzer.
The reflector 501, the absorber 502, and the hollow portion 503 are disposed adjacent to each other to form a group, and at least two of the same groups as described above are provided in the rotating sector 500 A compact, non-dispersive infrared gas analyzer featuring features.
Wherein the optical filter (400) comprises a plurality of unit filters having different wavelength regions to be removed.
The sample gas chamber 600 includes a gas inlet 601 through which a sample gas to be analyzed flows; A gas outlet 602 through which the introduced sample gas is discharged; A first concave mirror 603 and a second concave mirror 604 for reflecting infrared rays irradiated from the infrared ray source 100 to the infrared ray detector 200; A first transparent window (605) for transmitting infrared rays that have passed through the rotating sector (500) to the sample gas chamber (600); And a second transparent window (606) through which the infrared ray passed through the sample gas chamber (600) is transmitted to the infrared detector (200).
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020150160721A KR101714731B1 (en) | 2015-11-16 | 2015-11-16 | Compact type NDIR gas analyzer |
PCT/KR2016/004904 WO2017086555A1 (en) | 2015-11-16 | 2016-05-11 | Compact-type non-dispersive infrared gas analysis device |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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KR1020150160721A KR101714731B1 (en) | 2015-11-16 | 2015-11-16 | Compact type NDIR gas analyzer |
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Publication Number | Publication Date |
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KR101714731B1 true KR101714731B1 (en) | 2017-03-09 |
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KR1020150160721A KR101714731B1 (en) | 2015-11-16 | 2015-11-16 | Compact type NDIR gas analyzer |
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KR (1) | KR101714731B1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20230030741A (en) * | 2021-08-26 | 2023-03-07 | (주)켄텍 | Apparatus for simultaneously measuring carbon monoxide and carbon dioxide |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07151685A (en) * | 1993-01-08 | 1995-06-16 | Fuji Electric Co Ltd | Non-dispersion type infrared gas analyzer |
US20030230716A1 (en) * | 2002-04-12 | 2003-12-18 | Infrared Industries, Inc. | Multi-gas analyzer |
KR20090034668A (en) | 2007-10-04 | 2009-04-08 | (주)다산알앤디 | Ndir gas analyzer and gas analyzing method using the same |
KR101041768B1 (en) * | 2009-04-10 | 2011-06-17 | (주)켄텍 | Apparatus for simultaneously measuring carbon monoxide and carbon dioxide |
-
2015
- 2015-11-16 KR KR1020150160721A patent/KR101714731B1/en active IP Right Grant
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07151685A (en) * | 1993-01-08 | 1995-06-16 | Fuji Electric Co Ltd | Non-dispersion type infrared gas analyzer |
US20030230716A1 (en) * | 2002-04-12 | 2003-12-18 | Infrared Industries, Inc. | Multi-gas analyzer |
KR20090034668A (en) | 2007-10-04 | 2009-04-08 | (주)다산알앤디 | Ndir gas analyzer and gas analyzing method using the same |
KR100897279B1 (en) * | 2007-10-04 | 2009-05-14 | (주)다산알앤디 | NDIR gas analyzer and gas analyzing method using the same |
KR101041768B1 (en) * | 2009-04-10 | 2011-06-17 | (주)켄텍 | Apparatus for simultaneously measuring carbon monoxide and carbon dioxide |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20230030741A (en) * | 2021-08-26 | 2023-03-07 | (주)켄텍 | Apparatus for simultaneously measuring carbon monoxide and carbon dioxide |
KR102545561B1 (en) | 2021-08-26 | 2023-06-20 | (주)켄텍 | Apparatus for simultaneously measuring carbon monoxide and carbon dioxide |
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