KR101698171B1 - a manufacturing method of electroconductive leather - Google Patents

a manufacturing method of electroconductive leather Download PDF

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KR101698171B1
KR101698171B1 KR1020150103822A KR20150103822A KR101698171B1 KR 101698171 B1 KR101698171 B1 KR 101698171B1 KR 1020150103822 A KR1020150103822 A KR 1020150103822A KR 20150103822 A KR20150103822 A KR 20150103822A KR 101698171 B1 KR101698171 B1 KR 101698171B1
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fabric
solvent
artificial leather
conductive
weight ratio
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KR1020150103822A
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Korean (ko)
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김성우
허한창
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(주) 현대식모
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B1/00Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C3/00Stretching, tentering or spreading textile fabrics; Producing elasticity in textile fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C7/00Heating or cooling textile fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D06N3/0077Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/12Decorative or sun protection articles
    • D06N2211/28Artificial leather

Abstract

The present invention relates to a method for manufacturing electrically conductive artificial leather. The method for manufacturing electrically conductive artificial leather according to the present invention includes: a step in which a polyester tricot fabric is immersed into a first solvent having a viscosity of 40 to 1,000 cP with 1 to 10% weight ratio of electrically conductive agent and 6 to 20% weight ratio of aqueous polyurethane solid mixed with water; a step in which the immersed fabric is mangled; a coating step in which a second solvent having a viscosity of 2,000 to 20,000 cP with 1 to 20% weight ratio of electrically conductive agent and 20 to 50% weight ratio of aqueous polyurethane solid mixed with water is applied to an upper surface of the fabric and an upper conductive layer is formed by the second solvent being coated to a thickness of 0.1 to 0.3 mm by coating night; a drying step in which the coated fabric is dried; and an embossing step in which the upper surface of the fabric is embossed by a roller heated to a temperature of 150 to 200 degrees Celsius being used.

Description

도전성 인공피혁의 제조방법{a manufacturing method of electroconductive leather}TECHNICAL FIELD The present invention relates to a manufacturing method of electroconductive leather,

본 발명은 도전성 인공피혁의 제조방법에 관한 것으로서, 도전성을 띠는 인공피혁을 제작할 수 있는 도전성 인공피혁의 제조방법에 관한 것이다.TECHNICAL FIELD The present invention relates to a method for producing conductive artificial leather, and more particularly, to a method for producing conductive artificial leather capable of producing conductive artificial leather having conductivity.

천연피혁과 인공피혁은 구조적 형태에 따라 은면(Grain-layer)이 있는 스무드(smooth)형과 표면에 섬유층이나 극세 합성 섬유층이 형성되는 스웨이드(suede)형으로 나뉘며, 스무드형은 강한 물성의 갑피용 등으로 널리 사용되고, 스웨이드형은 표면의 부드러움, 패션성 등이 높이 평가되어 의류용으로 많이 이용된다. Natural leather and artificial leather are divided into a smooth type with a grain-layer depending on the structural form and a suede type having a fibrous layer or a microfibre layer formed on the surface. The smooth type has a strong physical property And the suede type is widely used for clothes because of its high surface smoothness and fashionability.

인공피혁 제조의 기술적 특징을 보면 특수 섬유의 사용, 유성 폴리우레탄계 수지 및 가공개발 기술, 후가공 개발 기술의 융합으로 이루어져 있고, 공정의 종류는 함침법, 직접 도포법, 필름법 등이 이용되어 왔다.Technological characteristics of artificial leather production consist of use of special fibers, oil based polyurethane resin, process development technology, and fusion of post-processing development technology, and the type of process has been used impregnation method, direct application method, film method and the like.

이러한 각종 피혁에 도전성을 띠도록 하는 도전성 피혁의 제조 방법에 대한 선행기술에는 대한민국 특허청에 출원된 출원번호 제10-2011-0110084호, 제10-2013-0096103호 및 본 출원인에 의한 출원번호 제10-2013-0134997호 등이 있다.Prior arts relating to a method for producing conductive leather to be conductive to various kinds of leather include Application Nos. 10-2011-0110084 and 10-2013-0096103 filed in the Korean Intellectual Property Office and Application No. 10 -2013-0134997.

특히 최근에는 터치 스크린용 장갑, 패션용 옷, 장판, 신발 등에 도전성 인공 피혁을 이용하고자 하는 노력에 계속되고 있다.Recently, efforts have been made to use conductive artificial leather for gloves for touch screen, clothes for fashion, floor coverings, and shoes.

그러나, 이러한 종래의 도전성 피혁을 제조하는 방법은 유성 폴리우레탄계를 이용하여 디메틸포름아미드(DMF)가 발생되어 작업장의 근로 환경이 나빠지고, 원단에 디메틸포름아미드가 잔존하는 문제점이 있다.However, such a conventional method for producing conductive leather has the problem that dimethylformamide (DMF) is generated using an oil-based polyurethane system, and the working environment of the workplace is deteriorated, and dimethylformamide remains in the fabric.

이러한 문제점을 해결하기 위하여 접착제를 사용하는 방식은 제품의 품질을 저하시키고 용도가 제한된다는 문제점이 있다.In order to solve such a problem, there is a problem that the method of using an adhesive deteriorates the quality of the product and its application is limited.

본 발명에 따른 도전성 인공피혁의 제조방법은 디메틸포름아미드의 발생을 방지하면서도 도전성을 띄는 인공피혁을 제조할 수 있는 방법을 제공하는 데 그 목적이 있다.The object of the present invention is to provide a method for producing artificial leather having conductivity while preventing generation of dimethylformamide.

본 발명에 따른 도전성 인공피혁의 제조방법은 도전성 인공피혁의 제조방법에 있어서, 폴리에스테르 트리코트 원단을 도전성 제제 1 내지 10% 중량비와 수성 폴리우레탄 고형분 6 내지 20% 중량비로 물과 혼합되어 점도 40 내지 1,000cP를 갖는 제1용제에 함침하는 단계와, 상기 함침된 원단을 맹글하는 단계와, 도전성 제제 1 내지 20% 중량비와 수성 폴리우레탄 고형분 20 내지 50% 중량비로 물과 혼합되어 점도 2,000 내지 20,000cP를 갖는 제2용제를 상기 원단 상부면에 도포하고, 코팅 나이트를 통해서 0.1 내지 0.3 mm 두께로 제2용제를 코팅하여 상부 도전층을 형성시키는 코팅 단계와, 상기 코팅된 원단을 건조시키는 건조 단계와, 150 내지 200도씨로 가열된 롤러를 이용하여 상기 원단 상부면을 엠보싱하는 엠보싱 단계를 포함하는 것을 특징으로 한다.In the method for producing conductive artificial leather according to the present invention, polyester tricot fabric is mixed with water at a weight ratio of 1 to 10% by weight of a conductive agent and an aqueous polyurethane solid content of 6 to 20% Impregnating the impregnated fabric with a conductive agent mixed with water at a weight ratio of 1 to 20% by weight and an aqueous polyurethane solid content of 20 to 50% by weight and having a viscosity of 2,000 to 20,000 cP on the upper surface of the fabric and coating the second solvent to a thickness of 0.1 to 0.3 mm through the coating knight to form an upper conductive layer; and a drying step of drying the coated fabric And an embossing step of embossing the upper surface of the fabric using a roller heated to 150 to 200 degrees.

여기서, 상기 제2용제의 점도를 조절하기 위해서 수성용 점정제를 이용하는 것을 특징으로 한다.The present invention is characterized by using an aqueous point-of-view tablet to adjust the viscosity of the second solvent.

삭제delete

본 발명에 따른 도전성 인공피혁의 제조방법은 디메틸포름아미드의 발생을 방지하기 위하여 수용성 용제를 이용하여 1차 함침을 하고, 수용성 제2용제를 이용하여 원단 상부에 상부 도전층을 형성시키되, 건조 단계와 엠보싱 단계를 통해서 강도가 보강된 도전성 인공피혁을 제조할 수 있는 장점이 있다.In order to prevent the formation of dimethylformamide, a method of manufacturing a conductive artificial leather according to the present invention includes the steps of: impregnating a primary aqueous solution using a water-soluble solvent; forming an upper conductive layer on the upper side of the fabric using a water- And an embossing step to produce a conductive artificial leather reinforced with strength.

도 1은 본 발명의 바람직한 일실시예에 따른 도전성 인공피혁의 제조방법을 도시하는 순서도.
도 2는 본 발명의 바람직한 일실시예에 따른 도전성 인공피혁의 제조 방법을 도시하는 개념도.
도 3은 본 발명의 바람직한 일실시예에 따른 도전성 인공피혁의 제조 방법에 의해서 제작된 도전서 인공피혁의 단면도.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a flow chart showing a method for manufacturing conductive artificial leather according to a preferred embodiment of the present invention. FIG.
2 is a conceptual diagram showing a method of manufacturing conductive artificial leather according to a preferred embodiment of the present invention.
3 is a cross-sectional view of a conductive artificial leather produced by a method of manufacturing conductive artificial leather according to a preferred embodiment of the present invention.

이하에서는 첨부된 도면을 참조하여 본 발명의 바람직한 일 실시 예를 상세하게 설명하고자 한다.Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.

도 1은 본 발명의 바람직한 일실시예에 따른 도전성 인공피혁의 제조방법을 도시하는 순서도이다.1 is a flowchart showing a method of manufacturing conductive artificial leather according to a preferred embodiment of the present invention.

도 1에 도시된 바와 같이 본 발명에 따른 도전성 인공피혁의 제조방법은 원단 준비 단계, 제1용제 배합 단계, 함침 단계, 맹글 단계, 제2용제 도포 및 코팅 단계, 건조 단계 및 엠보싱 단계를 포함한다.As shown in FIG. 1, the method for manufacturing conductive artificial leather according to the present invention includes a fabric preparation step, a first solvent compounding step, an impregnation step, a mangling step, a second solvent application and coating step, a drying step and an embossing step .

먼저, 도전성 인공피혁을 제조하기 위한 원단으로 폴리에스테르 트리코트(Polyester Tricot) 원단을 이용하는 것이 바람직하며, 사용 용도에 따라서 다양한 종류의 인공 피혁을 이용할 수도 있다.First, it is preferable to use a polyester tricot fabric as a fabric for producing conductive artificial leather. Various types of artificial leather may be used depending on the use.

다음으로, 제1용제 배합 단계에서 사용되는 도전성 제제로 카본 블랙을 사용하였으나 도전성 제제는 적어도 일부가 비금속성 도전성 제제 및 바인더를 포함하는 조성물로 현탁하게 혼합된 재료를 포함하게 된다. 상기 도전성 제제는 함침된 재료의 일부에 도전성을 제공하기에 충분한 농도로 존재한다.Next, although carbon black is used as the conductive agent used in the first solvent compounding step, the conductive agent will include a material that is suspended and mixed with a composition including at least a part of a non-metallic conductive agent and a binder. The conductive formulation is present at a concentration sufficient to provide conductivity to a portion of the impregnated material.

또한 도전성 제제는 비금속성 또는 금속성 또는 비금속성 도전성 제제는 중합체 일수도 있다.The conductive agent may also be a non-metallic or metallic or non-metallic conductive agent.

카본 블랙 도전성 제제를 사용하여 제조된 제1용제는 도전성 제제 1 내지 10% 중량비와 수성 폴리우레탄 고형분 6 내지 20% 중량비로 물과 혼합되어 점도 40 내지 1,000cP를 갖도록 제조한다.The first solvent prepared using the carbon black conductive agent is prepared to have a viscosity of 40 to 1,000 cP by mixing the conductive agent with water at a weight ratio of 1 to 10% and an aqueous polyurethane solid content of 6 to 20% by weight.

여기서, 중요한 점은 종래의 도전성 인공 피혁의 제조 방법과 달리 수분 폴리우레탄 고형분을 이용하고 이를 물과 혼합하여 도전성 제제를 제작한다는 점이다.The important point is that, unlike the conventional method for producing conductive artificial leather, a water-based polyurethane solid is used and mixed with water to prepare a conductive agent.

따라서, 종래의 디메틸포름아미드의 사용을 방지할 수 있다. 다만, 충분한 도전성을 확보하기 위해서 다음 단계를 필수적으로 거쳐야 한다.Thus, the use of conventional dimethylformamide can be prevented. However, the following steps are essential to ensure sufficient conductivity.

상기 방식으로 제조된 제1용제에 원단이 함침되면 맹글 단계를 거치게 되고, 제2용제라 원단의 상부면에 도포된다.When the first solvent prepared in this manner is impregnated with a fabric, it is subjected to a mangling step and is applied to the upper surface of the second solvent la fabric.

여기서 제2용제는 도전성 제제 1 내지 20% 중량비와 수성 폴리우레탄 고형분 20 내지 50% 중량비로 물과 혼합되어 점도 2,000 내지 20,000cP를 갖는 것이 바람직하며, 상기 제2용제의 점도를 조절하기 위해서 수성용 점정제를 이용하는 것이 바람직하다. 여기서, 제1용제 및 제2용제는 동일 저항의 범위 내에서 제조되는 것이 바람직하다.The second solvent is preferably mixed with water at a weight ratio of 1 to 20% by weight of the conductive agent and 20 to 50% by weight of an aqueous polyurethane solid to have a viscosity of 2,000 to 20,000 cP. In order to control the viscosity of the second solvent, It is preferable to use a point refining agent. Here, it is preferable that the first solvent and the second solvent are produced within the same resistance range.

이러한 제2용제는 코팅 나이트를 통해서 0.1 내지 0.3 mm 두께로 제2용제를 코팅하여 원단의 상부에 상부 도전층을 형성시키는 코팅 단계를 거치게 된다.The second solvent is coated with a second solvent through the coating knit to a thickness of 0.1 to 0.3 mm to form a top conductive layer on the top of the fabric.

나이프의 간격을 조절하여 상부 도전층의 높이가 0.1 내지 0.3 mm 층이 형성 되도록 한다. 이는 제1 도전층(제1용제를 통해서 원단에 형성된)에서 형성된 표면의 요철과 표면 저항의 단절을 보완하고 또한 균일한 표면 저항을 위하여 나이프를 이용하게 된다.The interval of the knife is adjusted so that the height of the upper conductive layer is 0.1 to 0.3 mm. This compensates for the breakage of the surface irregularities and surface resistances formed on the first conductive layer (formed on the raw material through the first solvent) and uses knives for uniform surface resistance.

상기 과정을 거치게 되면, 열풍 건조기를 이용하여 원단을 건조시키는 건조 단계를 거치되고, 이때 상기 건조 단계는 원단의 지지 형태를 유지한 상태에서 최소한의 장력을 가한 후에 열풍 건조기를 이용하여 100 내지 130도씨에서 건조시키는 텐터 건조 과정을 거치는 것이 바람직하다.After the above process, the fabric is dried by using a hot air dryer. In this drying step, the fabric is supported at a minimum tension in a state of supporting the fabric, and then dried in a hot air drier at 100 to 130 degrees Celsius It is preferable to carry out a drying process of the tenter which is then dried.

이러한 건조 과정을 거친 원단은 150 내지 200 도씨로 가열된 롤러를 이용하여 상기 원단 상부면을 엠보싱하는 엠보싱 단계를 거친다.The fabric having undergone this drying process is subjected to an embossing step of embossing the upper surface of the fabric using a roller heated to 150 to 200 degrees Celsius.

즉, 상기 엠보싱 단계는 원단 표면의 불균일성을 보완하고 제품의 내부에 생긴 공극을 최소화하여 균일한 도전성을 가지도록 한다.That is, the embossing step compensates for the unevenness of the surface of the fabric and minimizes the voids formed inside the product, so that the embossing step has uniform conductivity.

상기 과정이 완료된 인공피혁은 표면에 도전성을 가지게 되며, 인공피혁의 표면저항 약 1.0 × 106 Ω/sq (Ohm per square) 미만이다.The finished artificial leather has conductivity on the surface and is less than about 1.0 x 10 6 Ω / sq (Ohm per square) of the artificial leather.

여기서, 도전성 제제의 양을 선택 시 원하는 도전성이 고려되어야 하며, 표면저항 1.0 × 102 Ω/sq 보다 우수한 도전성을 요구한다면 보다 많은 양의 도전성 제제를 혼합 사용하여 상기와 같이 동일한 방식의 작업을 수행하면 된다.Here, when the amount of the conductive agent is selected, the desired conductivity should be considered. If the conductivity is required to be higher than 1.0 × 10 2 Ω / sq, a larger amount of the conductive agent may be mixed to perform the same operation as described above .

도 2는 본 발명의 바람직한 일실시예에 따른 도전성 인공피혁의 제조 방법을 도시하는 개념도이다.2 is a conceptual diagram showing a method of manufacturing conductive artificial leather according to a preferred embodiment of the present invention.

감겨진 원단(1)은 제1용제(10)가 함침되고, 맹글 장치(100)를 통해서 제1용제의 함침량을 조절하게 되고, 제2용제(20)가 도포 및 나이프(200)를 통해서 코팅된다.The rolled fabric 1 is impregnated with the first solvent 10 to adjust the impregnation amount of the first solvent through the mangerezing apparatus 100 and the second solvent 20 is applied through the kneading apparatus 200 Coated.

상기 코팅 단계를 거친 원단은 건조기(300)와 엠보싱 장치(400)를 각각 통과하여 최종 도전성 인공피혁(2)을 완성하게 된다.The fabric having passed through the coating step passes through the dryer 300 and the embossing device 400 to complete the final conductive artificial leather 2.

도 3은 본 발명의 바람직한 일실시예에 따른 도전성 인공피혁의 제조 방법에 의해서 제작된 도전서 인공피혁의 단면도이다.3 is a cross-sectional view of a conductive artificial leather fabricated by a method of manufacturing conductive artificial leather according to a preferred embodiment of the present invention.

도 3에 도시된 바와 같이 트리코트 인공피혁 원단을 이용한 도전성 인공피혁은 기모층(L3), 원단 지지층(L2) 및 뒷면 기모층(L1)으로 구분되며, 내부 도전층은제1용제의 함침을 통해서 형성되고, 상부 도전층은 제2용제의 도포와 나이프를 이용한 코팅 단계를 통해서 형성되며, 상기 상부 도전층은 엠보싱 단계를 거치면 필름형태로 강도가 향상된다.As shown in FIG. 3, the conductive artificial leather using the tricot artificial leather fabric is divided into a bristle layer L3, a cloth support layer L2 and a back brushed layer L1, and the inner conductive layer is impregnated with the first solvent And the upper conductive layer is formed through the application of the second solvent and the coating step using the knife, and the upper conductive layer is strengthened in film form after the embossing step.

여기서, 기모층(L3) 및 뒷면 기모층(L1) 양쪽에 기모 작업을 한 양면 기모 원단과 상기 기모층(L3) 한쪽에만 기모 작업을한 단면 기모 원단을 사용할 수 있다.Here, a double-sided brushed fabric subjected to a brushed operation on both of the brushed layer L3 and the back brushed layer L1 and a brushed fabric having a brushed layer on one side of the brushed layer L3 can be used.

이상과 같이 본 발명은 도전성 인공피혁의 제조방법을 제공하는 것을 주요한 기술적 사상으로 하고 있으며, 도면을 참고하여 상술한 실시 예는 단지 하나의 실시 예에 불과하므로 본 발명의 진정한 범위는 특허청구범위에 의해 결정되어야 한다.As described above, the present invention provides a method for manufacturing conductive artificial leather, and it is a main technical idea to make the artificial leather, and since the above-described embodiment is only one embodiment with reference to the drawings, .

1: 원단
2: 도전성 원단
10: 제1용제
20: 제2용제
100: 맹글 장치
200: 나이프
300: 건조기
400: 엠보싱 장치
1: Fabric
2: Conductive fabric
10: First solvent
20: Second solvent
100: Mangle device
200: Knife
300: dryer
400: embossing device

Claims (3)

도전성 인공피혁의 제조방법에 있어서,
폴리에스테르 트리코트 원단을 도전성 제제 1 내지 10% 중량비와 수성 폴리우레탄 고형분 6 내지 20% 중량비로 물과 혼합되어 점도 40 내지 1,000cP를 갖는 제1용제에 함침하는 단계와;
상기 함침된 원단을 맹글하는 단계와;
도전성 제제 1 내지 20% 중량비와 수성 폴리우레탄 고형분 20 내지 50% 중량비로 물과 혼합되어 점도 2,000 내지 20,000cP를 갖는 제2용제를 상기 원단 상부면에 도포하고, 코팅 나이트를 통해서 0.1 내지 0.3 mm 두께로 제2용제를 코팅하여 상부 도전층을 형성시키는 코팅 단계와;
상기 코팅된 원단을 건조시키는 건조 단계와;
150 내지 200도씨로 가열된 롤러를 이용하여 상기 원단 상부면을 엠보싱하는 엠보싱 단계;를 포함하는 것을 특징으로 하는 도전성 인공피혁의 제조방법.
A method for producing conductive artificial leather,
Impregnating the polyester tricot fabric with a first solvent having a viscosity of 40 to 1,000 cP, mixed with water at a weight ratio of 1 to 10% by weight of a conductive agent and an aqueous polyurethane solid content of 6 to 20% by weight;
Dangling the impregnated fabric;
A second solvent mixed with water at a weight ratio of 1 to 20% by weight of a conductive agent and an aqueous polyurethane solid content of 20 to 50% by weight and having a viscosity of 2,000 to 20,000 cP is applied to the upper surface of the fabric, A coating step of coating a first solvent with a second solvent to form an upper conductive layer;
Drying the coated fabric;
And embossing the upper surface of the fabric using a roller heated to 150 to 200 degrees.
제 1 항에 있어서,
상기 제2용제의 점도를 조절하기 위해서 수성용 점증제를 이용하는 것을 특징으로 하는 도전성 인공피혁의 제조방법.
The method according to claim 1,
Wherein an aqueous thickener is used to adjust the viscosity of the second solvent.
삭제delete
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101834441B1 (en) 2017-10-13 2018-03-05 (주)현대식모 Eco-friendly water-repellent suede manufacturing method with improved wicking water-repellent performance
KR20190096485A (en) 2018-02-09 2019-08-20 동아대학교 산학협력단 Environmentally friendly conductive composite based on waterborne polyurethane, manufacturing method thereof and use using the same
CN115179625A (en) * 2021-04-06 2022-10-14 南亚塑胶工业股份有限公司 Leather material and automobile instrument board composite structure
CN115467174A (en) * 2022-08-10 2022-12-13 苏州瑞高新材料有限公司 Conductive PU synthetic leather and preparation method thereof

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KR101220687B1 (en) * 2012-06-29 2013-01-10 코오롱인더스트리 주식회사 Textile coating solution with graphite, manufacturing method of textile coated with graphite and textile coated with graphite
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JPH06340805A (en) * 1993-04-01 1994-12-13 Bayer Ag Polyurethane thickener composition
KR20050099338A (en) * 2004-04-09 2005-10-13 우상욱 Method for producing embossing leather and embossing leather made therewith
KR101220687B1 (en) * 2012-06-29 2013-01-10 코오롱인더스트리 주식회사 Textile coating solution with graphite, manufacturing method of textile coated with graphite and textile coated with graphite
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101834441B1 (en) 2017-10-13 2018-03-05 (주)현대식모 Eco-friendly water-repellent suede manufacturing method with improved wicking water-repellent performance
KR20190096485A (en) 2018-02-09 2019-08-20 동아대학교 산학협력단 Environmentally friendly conductive composite based on waterborne polyurethane, manufacturing method thereof and use using the same
CN115179625A (en) * 2021-04-06 2022-10-14 南亚塑胶工业股份有限公司 Leather material and automobile instrument board composite structure
CN115467174A (en) * 2022-08-10 2022-12-13 苏州瑞高新材料有限公司 Conductive PU synthetic leather and preparation method thereof

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