KR101616251B1 - Composite for Shampoo with High Bubble Generation Capability - Google Patents

Abstract

The present invention relates to a shampoo composition with excellent usability and bubble power. The shampoo composition is produced by mixing a first external agent comprising a pH controller consisting of sodium bicarbonates, and a second external agent comprising vegetable natural organic acids including citric acid, thereby carbon dioxide is generated by reacting the citric acid of the vegetable natural organic acids and the sodium bicarbonates. The present invention significantly increases the bubble power while generating a large amount of carbon dioxide when using a shampoo, and improves usability while maintaining viscosity.

Description

{Composite for Shampoo with High Bubble Generation Capability}

The present invention relates to a shampoo composition having excellent usability and foaming power, and more particularly, to a shampoo composition which is excellent in usability when used on skin such as scalp by increasing the bubble power and maintaining an appropriate viscosity by generating a large amount of carbon dioxide The present invention relates to a shampoo composition having excellent foaming power.

BACKGROUND ART It is known that carbon dioxide gas (CO 2) acts to expand the blood vessels of human body. For this reason, pack products using carbon dioxide gas generated by mixing carbonates and acids as skin care products are known.

However, since the carbon dioxide gas generated by this method is released into the air in a short time, there is a problem that it is difficult to keep the carbon dioxide gas in continuous contact with the skin of the human body.

In order to solve the above problems, a viscous composition comprising a water-soluble thickener such as alginate or carboxymethyl cellulose sodium is added to a product containing a carbonate, so that a water-soluble acid is mixed with a water-soluble acid in advance to a certain degree of viscosity, And pack products in which the gas is generated to improve the collecting property of carbon dioxide gas have been developed.

However, when a suitable adhesive force is added to improve the usability of the external preparation for skin such as the packed product as described above, the composition constituting the external preparation becomes paste-like. Therefore, when mixed with a water-soluble acid, the generation of carbon dioxide gas is considerably soft and occurs quietly It is not easy for the user to recognize whether or not carbon dioxide is being generated.

In order to solve such a problem, there is a method of increasing the amount of generated carbon dioxide by changing the type of carbonate or water-soluble acid to prepare an external preparation for skin. In this case, although the generation of carbon dioxide gas can be easily recognized, The viscosity of the composition is remarkably lowered. As a result, when the composition is applied to the skin, the external preparation can not be adhered to the skin and can easily flow down from the skin to contaminate the clothes.

In other words, when the amount of generated carbonic acid gas is increased so that the user can easily confirm the generation of carbon dioxide gas, the conventional external skin application agent has high visibility but low usability. On the contrary, when the amount of carbon dioxide gas is lowered, usability is improved, I have a problem.

The inventors of the present invention have found that when a liquid second external agent containing a natural organic acid is mixed with a liquid external carboxy-containing agent (first external agent) containing hydroxyethyl cellulose, a large amount of carbon dioxide gas is generated, The inventors of the present invention have confirmed through experiments that the bubble caused by the bubbles is small and homogeneous,

KR 10-0802888 B1 KR 10-2005-0024510 A KR 10-1333245 B1

DISCLOSURE OF THE INVENTION Accordingly, it is an object of the present invention to provide a shampoo composition having excellent usability and bubble power by causing a large amount of carbon dioxide to be generated, There is a purpose.

It is an object of the present invention to provide a shampoo composition which comprises a first external preparation containing a pH adjusting agent composed of sodium bicarbonate and a second external preparation containing a plant-derived natural organic acid containing citric acid, And the sodium bicarbonate react with each other to generate carbon dioxide.

According to the present invention, the plant natural organic acid is selected from the fermented goji juice concentrate, the fermentation browse juice concentrate, the fermented citrus juice concentrate, the fermented apple concentrate, and the fermented bokbule concentrate.

The present invention also relates to a composition for oral administration, wherein the first external preparation contains a group A containing purified water and xanthan gum as a thickening agent, a group B containing ammonium laureth sulfate as a cleansing agent, a group C comprising a flavoring agent and polyquaternium- D group, and an E group containing sodium bicarbonate as a pH adjusting agent.

In addition to this, the present invention provides a method for the preparation of the second external preparation, wherein the second external preparation comprises a group A containing purified water and butylene glycol, a group B containing ammonium laureth sulfate as a detergent, a group C containing fragrance, And a D group including the D group.

The present invention can easily detect the generation of carbon dioxide by the user because sodium bicarbonate constituting the first external preparation and citric acid contained in the plant natural organic acid react with each other to generate a large amount of carbon dioxide when used for washing the scalp, Also, since the viscosity is maintained, the shampoo does not flow easily from the head during use, and the clothes are not easily contaminated.

The present invention is advantageous in that it is more environmentally friendly and has excellent skin reaction because it uses a vegetable natural organic acid such as Gujia, Chengyang, citrus, apple, and concentrate obtained by fermenting bokbunja.

 In addition, the present invention provides a large amount of carbonic acid gas to the scalp, thereby recognizing that the scalp is deficient in oxygen gas by the supplied carbon dioxide, thereby vitalizing blood flow and VEGF (Vascular Endothelial Groth Factor) There is an effect to promote.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a production flow chart showing a method of manufacturing a shampoo composition excellent in usability and foamability according to the present invention.

Hereinafter, the structure and operation of the present invention will be described in more detail with reference to the accompanying drawings showing preferred embodiments of the present invention.

The present invention provides a shampoo composition which is excellent in usability and foaming power while having a large amount of carbon dioxide gas generated. The shampoo composition of the present invention is obtained by mixing a first external preparation and a second external preparation, Explain.

≪ The first external application >

The first external agent may be selected from the group consisting of purified water, hydroxyethylcellulose, trihydroxystearin, glycerin, disodium iodide, methylparaben, panthenol, glycollosteralate, cocamidate, sodium laureth sulfate, sodium lauroylgluta- Mica, cocamidopropyl betaine, fragrance, phenoxyethanol, polycotanium-7, dimethicone and sodium bicarbonate, wherein stearase-2 or stearase-20 may be used instead of dimethicone.

When preparing the first external preparation having the above composition, each composition is divided into A, B, C, D and E groups as shown in FIG. 1 and Table 1 below, The composition of the group A was added to the solution of the group A, and the composition of the group B, C and D was added to the composition in the order of the solution (S300) by stirring with a stirrer, and slowly adding the composition of the E group (S500) while cooling to 45 ° C or less (S400).

division Composition Usage Content (% by weight) Group A Purified water menstruum 25.069 Hydroxyethylcellulose A binder, an emulsion stabilizer, a film former, a thickener- 0.16 Trihydroxystearin Moisture blocking agent, thickener - non-water soluble 0.55 glycerin Deodorants, fragrances, hair conditioners, moisturizers, skin moisturizers, skin protectants, viscosity reducers One Group B Disodium iodide Metal ion sequestrant 0.02 Methylparaben Spices, sterilizing preservative 0.2 Panthenol Hair Conditioner 0.001 Glycollosteralate Emulsifying stabilizer, opacifier, skin softener 0.5 Cocamide dihey Surfactants - Foam formers, thickeners - Water soluble 4 Sodium laureth sulfate Surfactants - Cleaners, Surfactants - Emulsifiers 30 Sodium lauroyl glutamate Hair conditioner 10 Cocamidopropyl betaine Antistatic agent, hair conditioning agent, skin conditioner, surfactant-detergent, surfactant-foaming agent, thickener-water-soluble 5 C group Spices Spices 0.2 Phenoxyethanol Spices, sterilizing preservative 0.3 D group Polyquaternium-7 Antistatic agents, film formers, hair fixatives One Dimethicone
(Or Stearase-2, or Stearase-20) Dimethicone: Moisture blocking agent, skin protection agent
Stearas-2: Surfactants - Emulsifiers
Stearas-20: Surfactant - Cleaner, Surfactant - Emulsifier, Surfactant - Solubilizer One E group Purified water menstruum 15 Sodium bicarbonate Scouring agent, pH buffering agent, deodorant, pH adjusting agent, skin protecting agent 6

In the composition of the above group A, hydroxyethylcellulose is used as a gelling agent, an emulsion stabilizer, a film forming agent, a thickener and the like, and such hydroxyethyl cellulose is added to foods or cosmetics, And to improve the viscosity.

And trihydroxystearin is a vegetable which is used as a water-evaporating and thickening agent, has a skin-smoothing and oil-feeding effect, and glycerophosphoric acid is a modifier, a fragrance, a hair conditioner, It is widely used as a skin moisturizer, a skin protective agent, a viscosity reducing agent and a moisturizer, and is used for supplying moisture to hair or skin and preventing the shampoo from drying.

Also, in the composition of the B group, di-sodium EDTA is widely used in cosmetics as a metal ion sequestrant (corrosion inhibitor) for preventing acidosis, bacterial infection, and deposit of cosmetics from occurring , Methylparaben is a preservative with bactericidal effect against all bacteria. It is known that there is little irritation to the human body and there is little toxicity.

Panthenol is a hair conditioning agent that promotes cell growth, has skin moisturizing properties, is known to be effective in providing shine to the mucous membranes of the skin and treating wounds. Glycol stearate is mainly used as an emulsifying stabilizer, opacifying agent and skin softening agent, and cocamide DEA is an alkylolamide formed by condensing coconut fatty acid with an equivalent amount of diethanolamine, (A foam promoter) and a thickener. Sodium laureth sulfate is an anionic surfactant, sodium lauroyl glutamate is a hair conditioning agent, and cocamidopropyl betaine is a synthetic surfactant, Foaming and cleaning effect, and are used as detergents, skin conditioners, hair conditioners and thickeners.

Also, in the composition of the C group, phenoxyethanol is used as a chemical preservative to inhibit the growth of microorganisms and bacteria and prevent the cosmetic from being spoiled.

Polyquaternium-7 is widely used as a hair conditioning agent, an antistatic agent, a film-forming agent and a hair fixative, and a di-methicone is a linear siloxane polymer. As a kind of silicone oil obtained by completely methylation, it is used as a foam inhibitor, a water vapor barrier and a skin protecting agent, and Stearase-2 and Stearase-20 are used as synthetic emulsifiers and solubilizing agents.

Also in the composition of the E group, sodium bicarbonate is used as a pH controlling agent, a pH buffering agent, a skin protecting agent and a deodorant.

≪ Second External Use Agent >

The second external agent is selected from the group consisting of purified water, xanthan gum, trihydroxystearin, butyleneglycol, ammonium laureth sulfate, disodium iodide, menthol, ammonium lauryl sulfate, cocamide miei, (Or trideceth 12), dimethicone, and vegetable natural organic acids, wherein stearase-2 or stearase-20 may be used instead of dimethicone.

When preparing a second external preparation having the above composition, each composition is divided into A, B, C, and D groups as shown in Table 2 below, and then a predetermined amount is prepared (S100) (S200) using a stirrer rotating at a speed of 200 rpm while being warmed to 75 DEG C, and then the composition of group B and group C was added to the composition of the dissolved group A, (S500) slowly adding the composition of the D group under the condition that the mixture is uniformly stirred (S300) and then cooled to 45 占 폚 or lower (S400).

division ingredient Usage Content (% by weight) Group A Purified water menstruum 12.65 Xanthan gum Binders, emulsifying stabilizers, skin conditioners, surfactants - emulsifiers, thickeners - water soluble 0.1 Trihydroxystearin Moisture blocking agent, thickener - non-water soluble 0.4 Butylene glycol Fragrances, skin conditioners, solvents, viscosity reducers One Group B Ammonium laureth sulfate Surfactant - Cleaner 26 Disodium iodide Metal ion sequestrant 0.05 menthol Degenerators, sweeteners, fragrances 0.3 Ammonium lauryl sulfate Surfactant - Cleaner 28 Cocamide miai Surfactants - Foam formers, thickeners - Water soluble 2 Set rimonium chloride Antistatic agent, Sterilization preservative, Surfactant - Emulsifier 3 Sodium lauroyl glutamate Hair conditioner 0.05 Methylparaben Spices, sterilizing preservative 0.2 C group
Phenoxyethanol Spices, sterilizing preservative 0.3 Beauty Spices 0.2 Chloride (or trideceth 12) Chloride: antistatic agent, antiseptic preservative, surfactant - emulsifier
Trideceth 12: Surfactant - Emulsifier 0.05 Dimethicone (or Stearase-2 or Stearase-20) Dimethicone: Antifoam agent, water vaporizer, skin protector.
Stearas-2: Surfactants - Emulsifiers
Stearas-20: Surfactant - Cleaner, Surfactant - Emulsifier, Surfactant - Solubilizer 2.7 D group Purified water menstruum 15 Vegetable natural organic acid 8

In the above-mentioned composition of group A, xanthan gum is a natural thickener which is well soluble in water, increases tackiness and viscosity, improves emulsion stability and improves physical properties and feel, , Binders, high-settling agents, and foaming agents. And trihydroxystearin is used for vegetable skin conditioning agent, water vapor barrier and thickener, it is used to smooth skin and to supply oil, and butylene glycol is used in cosmetics It is mainly used as a wetting agent to keep moisture on skin.

In addition, in the composition of group B, ammonium laureth sulfate (ALES) is widely used as a shampoo composition as an anionic surfactant, and disodium EDTA is a metal ion sequestering agent, Menthol is widely used as an additive for adding a cooling sensation to medicines, confectionary, and cosmetics, and is a substance obtained through distillation or synthesis of mint leaves or stems.

Ammonium lauryl sulfate is a surfactant and detergent. Cocamide MEA is an alkylolamide obtained by condensation of palm oil fatty acid with monoethanol amine. It is mainly used as a surfactant (foam promoter) It is used as a thickener. Cetrimonium chloride is also used as a surfactant (emulsifier), as an antistatic agent, as a disinfectant for use in the human body, and as a preservative.

In addition, sodium lauroyl glutamate is used as a hair conditioning agent in shampoos and cosmetics, and methylparaben is widely used as a sterilizing preservative.

On the other hand, in the composition of the C group, phenoxyethanol is a flavoring agent, a sterilizing preservative, chloride functions as an antistatic agent sterilizing preservative or a surfactant, trideceth-12 is a surfactant .

In the composition of the D group, the vegetable natural organic acid functions as the vegetable natural organic acid. The vegetable natural organic acid used in the present invention is a natural natural fruit such as gugija, Fruit concentrate made by adding sugar by weight% and fermenting for about 3 months is used.

The inventors of the present invention found that when the shampoo composition is prepared by mixing the first external preparation and the second external preparation prepared by the above process, the sodium bicarbonate of the first external preparation and the hydroxyl group (-OH) contained in the vegetable natural organic acid, Citric acid, which is one of the polybasic carboxylic acids having a large amount of carbonic acid, reacts with each other to generate a large amount of carbon dioxide. As a result, the foaming power when the shampoo is used is greatly improved.

The applicant of the present invention conducted an experiment to confirm the difference in the degree of bubble formation according to the type of vegetable natural organic acid. In the experiment, first, the first external preparation in the form of liquid was prepared according to the above procedure, and then, Four second external solutions containing the fermented fruit concentrate (vegetable natural organic acid) were prepared, and then the second external solution and the first external solution were mixed to prepare shampoos. These four shampoos The amount of bubble generation was measured, and the measurement results are shown in Table 3 below.

division Fermented fruit concentrate (natural organic acid) Gugija Cheerful room Citrus Apple Bokbunja pH 5.9 6.3 6.5 6.3 6.5 After 5 shakes
The amount of bubbles (ml) 190 180 174 165 158 After 5 minutes
The amount of bubbles (ml) 180 168 158 145 138

As can be seen from the above Table 3, the amount of bubbles after 5 times in the upper and lower portions and the amount of bubbles after 5 minutes in the shampoo containing the Gugija concentrate were found to be relatively larger than those in the shampoos containing other fruit concentrates.

The inventors of the present invention selected 50 panels without discrimination between male and female to determine the usability of the shampoo prepared by adding the fermented goji juice concentrate having the highest foaming power based on the above experimental results. After using the manufactured shampoo more than 3 times, the user was asked to evaluate his / her feelings through the questionnaire about the viscosity, spreadability, bubble generation quality, bubble quality, hair feel, washing power, Are shown in Table 4 below.

division
(frequency%) Very good good usually Poor Very bad Shampoo Viscosity 16 43 33 8 0 Bubble forming power 36 45 18 One 0 Bubble retention 19 72 8 One 0 Cleaning power 42 55 3 0 0

As shown in Table 4 above, most of the panels were evaluated positively regarding the viscosity, bubble forming ability, bubble retention and the trimming of the shampoo added with the fermented Goji juice concentrate.

In addition, the inventors of the present invention selected a panel of 100 persons without discriminating between male and female, to determine the usability of the shampoo prepared by adding the fermented Gujarin concentrate, and then, these panels were made to use the manufactured shampoo more than 3 times, 5 points for 'very good' and 1 point for 'very bad' were given to the questionnaire about the viscosity, spreadability, bubble generation ability, bubble quality, hair feel, washing power, And the results are shown in Table 5 below.

division Number of Evaluators Average Shampoo Viscosity 50 2.65 Spreadability 50 2.45 Bubble forming power 50 2.5 Bubble quality 50 1.83 Feeling of hair 50 2.54 Cleaning power 50 1.65 Moisture power 50 1.9 Hair gloss 50 1.85 Average 50 2.35

In Table 5 above, it was found that the external preparation for skin according to the present invention is relatively superior in viscosity and bubble forming power, especially in terms of the viscosity, bubble forming power and hair feel of the shampoo.

Claims (4)

CLAIMS 1. A shampoo composition for use in hair wrapping,
Wherein the composition is composed of a first external preparation containing a pH adjusting agent composed of sodium bicarbonate and a second external preparation containing a vegetable natural organic acid containing citric acid so that the citric acid of the plant natural organic acid and the sodium bicarbonate react with each other, Respectively,
Wherein the first external preparation comprises purified water and a group A containing hydroxyethyl cellulose or trihydroxystearin as a thickening agent, a group B containing ammonium laureth sulfate as a detergent, a C group containing a flavoring agent, a polyquaternium -7, and an E group comprising sodium bicarbonate as a pH adjusting agent,
Wherein the second external preparation contains purified water, xanthane gum as thickener, group B containing butylalanylcyclohexyl, ammonium group sulfate as a detergent, group C containing flavorings, purified water and vegetable natural organic acid Wherein the shampoo composition comprises at least one of D groups.
The method according to claim 1,
Wherein the vegetable natural organic acid is selected from the group consisting of a fermented goji juice concentrate, a fermented browning concentrate, a fermented citrus juice concentrate, a fermented apple concentrate, and a fermented bokbule concentrate.
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