KR101596470B1 - Composition for adhesion using radon mitigation materials, panel and adhesion method of panel using the same - Google Patents

Composition for adhesion using radon mitigation materials, panel and adhesion method of panel using the same Download PDF

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Publication number
KR101596470B1
KR101596470B1 KR1020150107727A KR20150107727A KR101596470B1 KR 101596470 B1 KR101596470 B1 KR 101596470B1 KR 1020150107727 A KR1020150107727 A KR 1020150107727A KR 20150107727 A KR20150107727 A KR 20150107727A KR 101596470 B1 KR101596470 B1 KR 101596470B1
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South Korea
Prior art keywords
mineral
panel
plate
composition
adhesive
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KR1020150107727A
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Korean (ko)
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차용선
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주식회사 모던우드
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00—Presence of inorganic and organic materials
    • C09J2400/10—Presence of inorganic materials

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Finishing Walls (AREA)

Abstract

The present invention relates to a method for producing a slag comprising 67 to 80 wt% of a feldspar mineral, 8 to 16 wt% of a silicon dioxide mineral, 6 to 8 wt% of a clay mineral, 3 to 5 wt% of an aluminum hydrate, 1 to 2 wt% of a carbonate mineral, By weight of a granular additive mixed with an adhesive used for bonding logs or artificial necks, and a method for adhering panels and panels using the composition.
According to the present invention, by adding an additive for improving the environment to an adhesive used for manufacturing or constructing a building material, it is possible to reduce the radiation amount of formaldehyde, reduce or block radon, and reduce the generation of volatile organic compounds And can contribute to prevention of pollution in an indoor environment, and in addition, it can provide favorable surrounding environment by emitting far infrared ray.

Description

TECHNICAL FIELD [0001] The present invention relates to a composition for bonding using a radon reducing material, and a method for adhering a panel and a panel using the same.

The present invention relates to a bonding composition and a bonding method for a panel and a panel using the bonding composition. More particularly, the present invention relates to an adhesive for use in manufacturing or constructing a building material, And a method of bonding panels and panels using the same.

Generally, architectural panels, especially interior materials, are used by using wood or by attaching a large number of artificial wood plates such as MDF, PB, etc., and these building panels are adhered to the floor or walls of buildings, Is used.

Such a construction panel requires the use of an adhesive having various components and properties in the manufacturing process and the construction process. In the prior art related thereto, Korean Patent Laid-Open No. 10-2005-0063973 "Adhesive composition" . A main adhesive comprising 50 to 100% by weight of a BPA-based epoxy resin, 0.5 to 5% by weight of a dispersant as an additive, 0.5 to 5% by weight of a flow control agent, and 0 to 50% by weight of a filler; 1 to 99% by weight of an amine-terminated reactive rubber as an additive, 0.5 to 5% by weight of an anti-settling agent, 0.1 to 10% by weight of a tertiary amine as a catalyst, To 60% by weight of a filler, and the main adhesive component and the curing agent component are mixed in a weight ratio of 1: 2 to 2: 1.

Most of currently used adhesives including conventional adhesives contain harmful substances to the human body by using chemical substances for imparting adhesiveness. Particularly, there are many kinds of adhesives which are made of cement in residential space, office space, The indoor environment pollution and the deterioration of the surrounding environment are getting worse because it does not help to reduce or prevent the generation of harmful substances such as formaldehyde, lardon gas and volatile organic compounds (VOC). This is a serious social problem, .

In order to solve the problems of the prior art as described above, the present invention provides a method for reducing the generation of harmful substances generated from an adhesive, a panel itself, or a building by adding an additive for improving environment to an adhesive used for manufacturing or constructing a building material Thereby contributing to prevention of contamination of the indoor environment. Other objects of the present invention will become readily apparent from the following description of the embodiments.

In accordance with an aspect of the present invention, there is provided a method of manufacturing a honeycomb structure including 67 to 80 wt% of a cobalt mineral, 8 to 16 wt% of a silicon dioxide mineral, 6 to 8 wt% of a clay mineral, 3 to 5 wt% , 1 to 2 wt% of carbonate minerals and 1 to 2 wt% of molten slag are mixed in an adhesive to provide a bonding composition using a radon reducing material.

The additive is obtained by mixing the pyroxene mineral, the silicon dioxide mineral, the clay mineral, the aluminum hydrate, the carbonate mineral and the molten slag in a heating furnace at 200 to 280 ° C. for 8 to 12 minutes, , A surface area of 80 to 160 m < 2 > / g and a nanocrystal size of 70 to 100 nm were measured by applying a heat drying and electrical stimulation at 60 to 80 DEG C while pulverizing to 325 mesh Respectively.

The additive, SiO 2 70 ~ 75 wt% , Al 2 O 3 13 ~ 18 wt%, CaO 4 ~ 6 wt%, K 2 0 1 ~ 2 wt%, Na 2 O 1 ~ 2wt%, MgO 0.1 ~ 1 wt%, Fe 2 O 3 0.1 to 1 wt%.

The bulseok minerals, Cleveland Smirnoff teal to light (Clinoptilolite, (Na, K, Ca) 2-3 Al 3 (Al, Si) 2 Si 13 O 36 · 12H 2 O), and trawl light (Natrolite, Na 2 Al 2 Si 3 O 10 .2H 2 O), mordenite ((Ca, Na 2 , K 2 ) Al 2 Si 10 O 24 .7H 2 O) The silicon dioxide mineral is composed of any one selected from the group consisting of quartz (SiO 2 ) and albite (NaAlSi 3 O 8 ) or a mixture thereof and the clay mineral is montmorillonite (Al, Mg) 2 Si 4 O 10 (OH) 2 · 4H 2 O), illite (Iliite, (K, H 3 O) Al 2 (Si, Al) 4 O 10 any one selected from (H 2 O, OH) 2 ) Or a mixture thereof, and the aluminum hydrate is at least one selected from the group consisting of bauxite (Al 2 O 3 .2H 2 O), gibbsite (Al (OH) 3 ) Wherein the carbonate mineral is selected from the group consisting of: Comprise a (Dolomite, CaMg (CO 3) 2), the molten slag may be made of a mixture of SiO 2, Al 2 O 8, Fe 2 O 8, FeO, CaO.

The additive and the adhesive may be mixed in a weight ratio of 2 to 30:70 to 98.

The adhesive may be composed of a water-soluble adhesive used for adhering logs or artificial necks.

The adhesive may be a liquid material containing a mixture of VAE (Vinyl Acetate Ethylene) resin, PVA (Poly Vinyl Acetate) resin, calcium carbonate and water in a weight ratio of 15 to 85:15 to 85: 2 to 8: ≪ / RTI >

According to another aspect of the present invention, there is provided a panel for use in a building interior material, exterior material, or furniture, wherein a plurality of plate members constituting the panel are adhered with a bonding composition using a radon reducing material according to one aspect of the present invention, Panel is provided.

The panel may be a floorboard or a closet plate, and the plurality of plates may be made of a plywood, a High Pressure Melamine Laminates (HPL) plate, or a circular plate coated with a surface.

The panel may be a door or a wall, and the plate may be composed of a medium density fiberboard (MDF), a high pressure melamine laminate (HPL) plate adhered to both sides of the MDF, or a circular plate coated with a surface.

The HPL plate or the original wood board may contain the additive in a part or whole area.

The panel may be coated with a composition for bonding using the radon reducing material on a surface facing the installation surface.

According to another aspect of the present invention, there is provided a method of manufacturing a floor panel, comprising the steps of: adhering a panel used in a building interior material, exterior material, or furniture to an adhesive site using a composition for bonding using a radon reduction material according to an aspect of the present invention; And curing the adhesive composition using the radon reducing material.

According to the adhesive composition using the radon reducing material according to the present invention and the method for adhering panels and panels using the same, an additive for improving the environment is added to an adhesive used for manufacturing or constructing a building material, It is possible to contribute to reduction of radiation amount of radon, reduction or interruption of radon, and generation of volatile organic compounds, contributing to prevention of contamination of the indoor environment, and also providing favorable surrounding environment by emitting far infrared rays.

1 is a sectional view showing a panel according to a first embodiment of the present invention.
2 is a sectional view showing a panel according to a second embodiment of the present invention.
3 is a sectional view showing a panel according to a third embodiment of the present invention.
4 is a sectional view showing a panel according to a fourth embodiment of the present invention.
5 is a cross-sectional view illustrating a panel adhering method according to an embodiment of the present invention.

The present invention is capable of various modifications and various embodiments, and specific embodiments are illustrated and described in detail in the drawings. It is to be understood, however, that the invention is not to be limited to the specific embodiments, but is to be understood to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the invention, And the scope of the present invention is not limited to the following examples.

Hereinafter, embodiments according to the present invention will be described in detail with reference to the accompanying drawings, wherein like or corresponding elements are denoted by the same reference numerals, and redundant explanations thereof will be omitted.

The composition for bonding using a radon reducing material according to an embodiment of the present invention is characterized in that it comprises 67 to 80 wt% of brittle mineral, 8 to 16 wt% of silicon dioxide mineral, 6 to 8 wt% of clay mineral, 3 to 5 wt% of aluminum hydrate, 1 to 2 wt% of carbonate mineral and 1 to 2 wt% of molten slag may be mixed with an adhesive.

The additives were fired and dried in a furnace at 200 ~ 280 ℃ for 8 ~ 12 minutes, and then pulverized to 325 mesh in a pulverizer. (CEC) of 210-280 meq / 100g, a surface area of 80-160 m < 2 > / g and a nanocrystal size of 70-100 nm, respectively, by thermal drying and electrical stimulation at 80 deg. Here, as a heating process by a heating furnace, for example, a rotary kiln can be used as a heating furnace, and the heating can increase the void content by 3% or less by heating. Also, for example, a raymond mill may be used as a pulverizer for grinding by a pulverizer, and particle size composition mixing and substitution can be performed.

Additive is SiO 2 70 ~ 75 wt%, Al 2 O 3 13 ~ 18 wt%, CaO 4 ~ 6 wt%, K 2 0 1 ~ 2 wt%, Na 2 O 1 ~ 2wt%, MgO 0.1 ~ 1 wt% , And Fe 2 O 3 0.1 to 1 wt%.

In participant form, a wide variety of minerals can be applied in the range of minerals involved. For example, the minerals are clinoptilolite (Na, K, Ca) 2-3 Al 3 (Al, Si) 2 Si 13 O 36 · 12H 2 O), natrolite (Na 2 Al 2 Si 3 O 10 · 2H 2 O), mordenite ((Ca, Na 2 , K 2 ) Al 2 Si 10 O 24 · 7H 2 O), and the silicon dioxide mineral may be any one selected from quartz (SiO 2 ), albite (NaAlSi 3 O 8 ), or a mixture thereof. (K, H 3 O) Al 2 (Si, Al), and the clay minerals are montmorillonite (Al, Mg) 2 Si 4 O 10 (OH) 2 .4H 2 O, 4 O 10 (H 2 O, OH) 2 ), or a mixture thereof. The aluminum hydrate may be Bauxite, Al 2 O 3 .2H 2 O, Gibbsite , Al (OH) 3 ) And the carbonate mineral may be composed of dolomite, CaMg (CO 3 ) 2 , and the molten slag may be composed of SiO 2 , Al 2 O 8 , Fe 2 O 8 , FeO, and CaO.

The additive and the adhesive may be mixed in a weight ratio of 2 to 30:70 to 98. If the additive is below this range, the environment improving effect can not be exhibited properly. If the additive exceeds this range, the amount of the adhesive Is lacking.

Adhesive is used to bond wood or artificial wood, which is used to attach wood or artificial wood to other wood, artificial wood or other materials such as plate, floor or wall, Do not. The artificial neck may include glued wood, compressed wood, or synthetic wood made of synthetic resin or various other materials.

The adhesive may be made of, for example, a water-soluble adhesive, and may be made of a water-soluble adhesive of EVA (Ethylene-Vinyl Acetate Copolymer), for example, VAE (Vinyl Acetate Ethylene) resin, PVA , Calcium carbonate and water in a weight ratio of 15 to 85: 15 to 85: 2 to 8: 2 to 8 by weight.

1 is a sectional view showing a panel according to a first embodiment of the present invention.

Referring to FIG. 1, the panel 10 according to the first embodiment of the present invention can be formed by adhering a plurality of plates constituting the panel with the adhesive composition 13 using the radon reducing material. In the example, it can be used as a floorboard. Here, the plurality of plate materials may be composed of a plywood 11, a high pressure melamine laminate (HPL) plate, or a circular plate 12 coated with a surface. For example, 11.5 mm or 14.5 mm in the case of the HPL board, 0.5 mm in the case of the HPL board, and 0.2 to 0.8 mm in the case of the original board.

The HPL plate or the original wood plate 12 may contain the above additives in some or all of the areas. For this purpose, in the manufacturing process of the HPL plate or the circular wood plate 12, the additives may be mixed so as to contain the additives in an amount of 2 to 15% by weight based on the total weight. In addition, the above additives can be contained over the entire HPL plate or the original wood plate 12. Alternatively, the additives can be contained only on a part of the HPL plate or the original plate 12, for example, the front side.

2 is a sectional view showing a panel according to a second embodiment of the present invention.

Referring to FIG. 2, the panel 20 according to the second embodiment of the present invention may be formed by adhering a plurality of plates constituting the panel with the adhesive composition 23 using the radon reducing material. In the example, it can be used as a closet plate attached to a wall. Here, the plurality of plate materials may be composed of a plywood 21 and a high pressure melamine laminates (HPL) plate or a circular plate 22 whose surface has been coated. In order to be used as a closet plate by adhesion, ), It may have a thickness of 11.5 mm or 14.5 mm, and in the case of the HPL plate, it may have a thickness of 0.5 mm, and in the case of the original wood plate, it may have a thickness of 0.2 to 0.8 mm. Further, the HPL plate or the original wood plate 22 may contain the above additives in some or all of the areas as in the previous embodiment.

3 is a sectional view showing a panel according to a third embodiment of the present invention.

Referring to FIG. 3, the panel 30 according to the third embodiment of the present invention may be formed by adhering a plurality of plates constituting the panel with the adhesive composition 33 using the radon reducing material. In the example, it can be used as a floorboard. Here, the plurality of plate materials may be composed of a plywood 31, a high pressure melamine laminate (HPL) plate, or a circular wood plate 32 coated with a surface, which is made of a door or a wall such as a toilet of a building, A plate material may be composed of a high pressure melamine laminate (HPL) plate or a circular wood plate 32 bonded to both sides of a MDF (Medium Density Fiberboard) 31 and MDF 31, and used as a door or a wall For example, in the case of the MDF 31, it may have a thickness of 18 mm or the like. In the case of the HPL plate, it may have a thickness of 0.8 mm, and in the case of the original wood plate, it may have a thickness of 0.2 to 0.8 mm. Further, the HPL plate or the original wood plate 32 may contain the above additives in some or all of the areas as in the previous embodiment.

4 is a sectional view showing a panel according to a fourth embodiment of the present invention.

4, a panel according to a fourth embodiment of the present invention, for example one of the panels 10, 20, 30 according to the first through third embodiments of the present invention, To the surface facing the installation position (1) is coated with the adhesive composition (41) using a radon reducing material to form a coating layer by curing. The panel according to the fourth embodiment of the present invention can be used for a bonding composition using a radon reducing material or another bonding composition using a radon reducing material such that the side coated with the radically- Or may be installed in a stringed manner by concave-convex coupling or the like.

5 is a cross-sectional view illustrating a panel adhering method according to an embodiment of the present invention.

5, in addition to the panels 10, 20 and 30 described above, the method of adhering panels according to an embodiment of the present invention may be applied to a panel used for building interior materials, exterior materials, or furniture using the above- (42) to the bonding position (1) such as a mounting surface or a mounting surface, and curing the bonding composition (42) using the radon reducing material.

The step of curing the adhesive composition 42 using the radon reducing material can be performed by, for example, at least 12 to 36 hours.

The adhesive composition using the radon reducing material according to the present invention and the method for adhering the panel and panel using the radon reducing material according to the present invention can be applied to the adhesives used for building materials and construction by adding additives for improving the environment, And it can contribute to the prevention of contamination of the indoor environment. In particular, it can contribute to prevention of contamination of the indoor environment, And can be used for the adsorption of toxic substances. By easily substituting heavy metal cations, it is possible to exert excellent performance in removing harmful heavy metals. In addition, by emitting far infrared rays from minerals, a favorable surrounding environment can be provided.

Although the present invention has been described with reference to the accompanying drawings, it is to be understood that various changes and modifications may be made without departing from the spirit of the invention. Therefore, the scope of the present invention should not be limited to the described embodiments, but should be determined by the scope of the appended claims and equivalents thereof.

1: Adhesion location
11,21: Plywood
12, 22, 32: HPL plate or circular plate
13,23,33,41,42: composition for bonding using radon reducing material
31: MDF

Claims (14)

Mixed with 6 to 8 wt% of clay minerals, 3 to 5 wt% of aluminum hydrate, 1 to 2 wt% of carbonate mineral and 1 to 2 wt% of molten slag were mixed with 67 to 80 wt% of pyroxene mineral, 8 to 16 wt% of silicon dioxide mineral, Wherein one granular additive is mixed with an adhesive,
Preferably,
The calcite mineral, the silicon dioxide mineral, the clay mineral, the aluminum hydrate, the carbonate mineral, and the molten slag are mixed and dried in a heating furnace at 200 to 280 ° C. for 8 to 12 minutes and then pulverized to 325 mesh And then subjected to thermal drying and electric stimulation at 60 to 80 캜 while being pulverized to obtain a radon having a cation exchange capacity (CEC) of 210 to 280 meq / 100 g, a surface area of 80 to 160 m 2 / g and a nanocrystal size of 70 to 100 nm, A composition for bonding using a reducing substance. delete delete The method according to claim 1,
The above-
Cleveland Smirnoff teal to light (Clinoptilolite, (Na, K, Ca) 2- 3 Al 3 (Al, Si) 2 Si 13 O 36 · 12H 2 O), and trawl light (Natrolite, Na 2 Al 2 Si 3 O 10 2H 2 O), and mordenite ((Ca, Na 2 , K 2 ) Al 2 Si 10 O 24 .7H 2 O)
The above-
Quartz (SiO 2 ), and albite (Albite, NaAlSi 3 O 8 ), or a mixture thereof,
The clay mineral,
Montmorillonite (Montmorillonite, (Al, Mg) 2 Si 4 O 10 (OH) 2 · 4H 2 O), illite (Iliite, (K, H 3 O) Al 2 (Si, Al) 4 O 10 (H 2 O , OH) 2 ), or a mixture thereof,
The aluminum hydrate,
(Bauxite, Al 2 O 3 .2H 2 O), gibbsite (Al (OH) 3 ), or a mixture thereof.
The carbonate mineral,
Dolomite, CaMg (CO 3 ) 2 )
The molten slag,
SiO 2 , Al 2 O 8 , Fe 2 O 8 , FeO, and CaO. The method according to claim 1,
The additive and the adhesive may be mixed,
2 to 30: 70 to 98 by weight. The method according to claim 1,
Preferably,
Wherein the water-soluble adhesive is used for bonding wood or synthetic wood. The method of claim 6,
Preferably,
A liquid material comprising a mixture of vinyl ether acetate (VAE) resin, polyvinyl acetate (PVA) resin, calcium carbonate and water in a weight ratio of 15 to 85:15 to 85: 2 to 8: 2 to 8, A composition for bonding using a reducing substance. A panel for use in a building interior material, exterior material or furniture,
Wherein a plurality of plates constituting the panel are adhered with an adhesive composition using the radon reducing material according to any one of claims 1 to 7. The method of claim 8,
Wherein:
A floorboard or a closet plate, wherein the plurality of plates are composed of a plywood and a high pressure melamine laminates (HPL) plate or a circular plate whose surface is coated. The method of claim 9,
Wherein the HPL plate or the original wood plate comprises:
Wherein the additive is contained in some or all of the areas. The method of claim 8,
Wherein:
A door or a wall, wherein the plate comprises a medium density fiberboard (MDF) and a high pressure melamine laminate (HPL) plate bonded to both sides of the MDF, or a circular plate whose surface is coated. The method of claim 11,
Wherein the HPL plate or the original wood plate comprises:
Wherein the additive is contained in some or all of the areas. The method of claim 8,
Wherein:
Wherein the adhesive composition using the radon reducing material is coated on a surface facing the installation surface. Adhering a panel used for a building interior material, an exterior material, or furniture to an adhering position using a composition for adhesion using the radon reducing material according to any one of claims 1 to 7; And
Curing the adhesive composition using the radon reducing material;
And bonding the panel.
KR1020150107727A 2015-07-30 2015-07-30 Composition for adhesion using radon mitigation materials, panel and adhesion method of panel using the same KR101596470B1 (en)

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Cited By (5)

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Publication number Priority date Publication date Assignee Title
KR20190008620A (en) * 2017-07-17 2019-01-25 소병명 Wood panels for furniture, and a method of manufacturing the same
KR20190030447A (en) * 2017-09-14 2019-03-22 우은심 a built-in cabinet
KR20190030445A (en) * 2017-09-14 2019-03-22 이성철 kitchen furniture
KR102040964B1 (en) 2019-06-04 2019-11-06 성화파인세라믹주식회사 A coating composition manufacturing method of silica aerogel for radon mitigation
KR102509740B1 (en) * 2022-09-30 2023-03-16 (주) 라돈앤홈 Coating composition for blocking radon and construction method using the coating composition

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KR20070010993A (en) * 2005-07-20 2007-01-24 주식회사 이파엘지종합특수방수 Coating for building materials and manufacturing method thereof
KR20110075884A (en) * 2009-12-29 2011-07-06 김영일 The inorganic adhesive composition for furnitures and the inorganic adhesive for furnitures utilizing thereof

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JP2004041317A (en) * 2002-07-09 2004-02-12 Seietsu Kikuchi Manufacturing method of deodorizing and antimicrobial material
KR20050076577A (en) * 2004-01-20 2005-07-26 삼중건설화학 주식회사 Inorganic bio ceramic glue and method for manufaturing it
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20190008620A (en) * 2017-07-17 2019-01-25 소병명 Wood panels for furniture, and a method of manufacturing the same
KR101961556B1 (en) * 2017-07-17 2019-03-25 소병명 Method of manufacturing a wood panel for furniture
KR20190030447A (en) * 2017-09-14 2019-03-22 우은심 a built-in cabinet
KR20190030445A (en) * 2017-09-14 2019-03-22 이성철 kitchen furniture
KR102008573B1 (en) * 2017-09-14 2019-08-07 이성철 kitchen furniture
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KR102040964B1 (en) 2019-06-04 2019-11-06 성화파인세라믹주식회사 A coating composition manufacturing method of silica aerogel for radon mitigation
KR102509740B1 (en) * 2022-09-30 2023-03-16 (주) 라돈앤홈 Coating composition for blocking radon and construction method using the coating composition

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