KR101449026B1 - Hair cosmetic composition for hair anti-aging effects - Google Patents

Abstract

The present invention relates to a hair cosmetic composition for preventing aging of hair containing a black pearl extract, a blueberry extract and a royal jelly extract, which comprises a conchiolin hydrolyzate obtained by hydrolyzing conchiolin, a protein component of a black pearl liquor, an antioxidant Contains 10-HDA (10-hydroxy-2-decenoic acid), lysine, and pantothenic acid components contained in anthocyanin and royal jelly to give nutrition and shine to weakened and tapered hair as it ages To a hair cosmetic composition.

Black jelly extract, blueberry extract, royal jelly extract, hair cosmetic composition, hair nutrition, hair gloss

Description

[0001] The present invention relates to a hair cosmetic composition for hair anti-

The present invention relates to a hair cosmetic composition for preventing aging of hair containing a black pearl extract, a blueberry extract and a royal jelly extract, which comprises a conchiolin hydrolyzate obtained by hydrolyzing conchiolin, a protein component of a black pearl liquor, It contains 10-HDA (10-hydroxy-2-decenoic acid), lysine and pantothenic acid, which are contained in the antioxidant component of royal jelly and antioxidant. To a hair cosmetic composition which imparts gloss.

As the hair grows older, it becomes aged like skin. As the aging progresses, various changes and problems appear. The aging of hair is generally judged to be a healthy cuticle layer outside of the hair, and the area of the cuticle is broad and soft and glossy hair is called healthy hair. The cause and phenomenon of hair aging are largely known as the following three.

First, the hair is easily broken and the elasticity is lowered due to lack of elasticity due to lack of oil and moisture inside the hair. Second, due to lack of oil and water in the hair, the cuticle layer is floated and static electricity is generated, and the hair ends are cracked. Third, the cuticle layer outside the hair is damaged, and the inner layer of the hair is destroyed, so that the diffuse reflection due to the light is severe, and the gloss of the entire hair is lowered.

Factors that promote hair aging include coloring and perming, excessive drying of the hair, ultraviolet light, unbalanced nutritional status and stress. Recently, in hair cosmetics such as shampoos and conditioners, in addition to cleaning and anti-static, attempts have been made to improve the nutrition and gloss of the hair. In general, conditioning agents such as silicone, hydrocarbon water, fatty esters or a combination thereof are used To enhance these effects. However, these ingredients are deposited on the hair to show a damp and oily feel and lack of recovery effect of the hair, so there is a limit to effectively provide nutrition and shine to weakened and tapered hair.

It is an object of the present invention to provide a hair cosmetic composition containing black pearl extract, blueberry extract and royal jelly extract, which can impart nutrition and shine to weakened and tapered hair while aging is progressed, and recover damaged hair with health.

In order to attain the above object, the present invention provides a cosmetic composition for preventing hair deterioration containing a black pear extract, a blueberry extract and a royal jelly extract. The black pearl extract is a conchiolin protein hydrolyzate which is obtained by hydrolyzing conchiolin protein obtained after acidic addition of an acid to a black pearl.

The hair cosmetic composition according to one embodiment of the present invention may contain black pearl extract, blueberry extract and royal jelly extract to impart nutrition and shine to weakened and tapered hair as it ages, and restore damaged hair to health .

In the hair cosmetic composition according to one embodiment of the present invention, the black pear extract may be contained in an amount of 0.01 to 10.0% by weight based on the total weight of the composition. This is because if the content of the extract is more than 10.0% by weight, the stability of the formulation and the feeling of use may be impaired. If the content is less than 0.01% by weight, the effect is insufficient.

In the hair cosmetic composition according to an embodiment of the present invention, the blueberry extract may be contained in an amount of 0.01 to 10.0% by weight based on the total weight of the whole composition. This is because if the content of the extract is more than 10.0% by weight, the stability of the formulation and the feeling of use may be impaired. If the content is less than 0.01% by weight, the effect is insufficient.

In the hair cosmetic composition according to an embodiment of the present invention, the royal jelly extract may be contained in an amount of 0.01 to 10.0% by weight based on the total weight of the composition. This is because if the content of the extract is more than 10.0% by weight, the stability of the formulation and the feeling of use may be impaired. If the content is less than 0.01% by weight, the effect is insufficient.

Conchiolin, a bright yellow thin layer that remained insoluble after the calcium carbonate dissolved in the diluted acid solution, was found to be a kind of scleroprotein, It is composed of amino acids of species, similar to moisturizing and natural moisturizing factor (NMF) of the stratum corneum. These conchiolins contain 863.23mg / 100ml of 20 mixed amino acids that supplement hair loss amino acids to increase hair density and make hair healthier and healthier. Most of these proteins are more preferable because they are in the form of peptides having a molecular weight of 500 to 1000, which is known to give excellent moisturizing effect to hair.

The black pearl extract used in the hair cosmetic composition according to one embodiment of the present invention is a natural pearl extract obtained from a black papule. The brown pear extract is distributed in the Indian Ocean or an equatorial region of the Pacific Ocean, and in Okinawa, Japan. Tahiti, Fiji, etc. Micronesia and Polynesia are famous as Darsan, and others can be found in Panama, Egypt and Madagascar.

In the hair cosmetic composition according to one embodiment of the present invention, the black pearl shell and the black pearl are made into a fine powder, and the acid is added to the resulting mixture for demineralization, filtration and washing with water to obtain conchiolin. The conchiolin is again hydrolyzed by acid addition, followed by desalting and discoloration purification by ion exchange resin to finally obtain a black pearl extract.

There are about 20 species of blueberries native to North America, mainly from the Northern Hemisphere. In Korea, there are also pure gold trees and corn cherry trees, all of which can be eaten. Blueberries are classified as high bush berry (V. corymbosum) growing up to about 5m in height and low bush berry (V. angustifolium var. Laevifolium) growing up to about 30cm in height. Blueberries contain bluish purple anthocyanin pigment, sugar, and viscous pectin. Among the ingredients, 4.5 g per 100 g of plant fiber, minerals, calcium, iron, and manganese are many. The anthocyanin of blueberry peel is composed of five kinds of anthocyanidins: dellpyridine, cyanidin, malbidin, pethonide, pheonidine and three sugars (glucose, galactose and arabinose) It is known that there is an anthocyanin of the kind. Blueberry fruit and leaf extract are used in the treatment of scurvy, urinary disease, diabetes, and vascular disorders, and promote the activation of rhodopsin re-synthesis in the retina of the eye and have the function of promoting cancer adaptation. It also helps the skin to maintain its health by antioxidant and anti-inflammatory action of the skin.

The blueberry extract used in the hair cosmetic composition according to an embodiment of the present invention was mixed with blueberry fruit and a hydroglycolic solvent (butylen glycol: water = 50: 50) at a ratio of 1: 4 And then repeatedly circulated.

Royal jelly is a substance made by eating a lot of roots and pollen and is a nutrient containing protein, fat, carbohydrate and various trace elements. Among the raw royal jelly, vitamins, neurotransmitters such as acetylcholine which enriches the skin of women, and parotine-like substances which are the salivary glands of the muscles, bones, teeth, It also contains 10-HDA components that inhibit the growth of cancer cells and R-substance, which is an unknown substance, so it has an excellent effect on mental anxiety menopausal disorder, blood pressure abnormality and the like. In addition, it calms the skin stimulated by various external environments and activates damaged tissues, soothing effect of rehabilitation, prevention of skin damage caused by bacteria or pathogens, treatment of wound area, antibacterial effect which is effective on troublesome skin, Enhances resistance to pathogens, strengthens skin health and boosts vitality, gives tension to skin tissue that has lost elasticity, prevents and delays tissue oxidation caused by harmful oxygen, Convergence and anti-aging effects.

The hair cosmetic composition according to an embodiment of the present invention may have a conventional formulation and may be formulated into, for example, shampoo, rinse, pomade, hair treatment, hair lotion and the like. The hair cosmetic composition of each of these formulations may contain various components to be blended in a conventional hair cosmetic composition according to the above-mentioned formulations or for a final purpose, and the kind and amount of these components may be easily selected by those skilled in the art .

The hair shampoo composition according to one embodiment of the present invention may be added with appropriate components according to the type of the hair shampoo composition. For example, a synthetic surfactant, a conventional cleansing component, preservatives, thickeners and viscosity adjusting agents, pH adjusting agents, Dyes, hair conditioning agents and water may be added.

The synthetic surfactant used in one embodiment of the present invention may be any selected from anionic, amphoteric, and nonionic surfactants. The synthetic surfactant may be contained in an amount of 10 to 70% by weight, preferably 10 to 30% by weight, based on the total weight of the composition.

As the synthetic anionic surfactant, alkyl and alkyl ether sulfates can be used. Specific examples thereof include sodium lauryl sulfate, ammonium lauryl sulfate, triethanolamine lauryl sulfate, sodium polyoxyethylene lauryl sulfate, ammonium polyoxyethylene lauryl sulfate Etc. may be used.

As the synthetic amphoteric surfactant, alkyl betaine and alkylamidopropyl betaine may be used. Specific examples thereof include cocodimethylcarboxymethylbetaine, lauryldimethylcarboxymethylbetaine, lauryldimethyl alpha-carboxyethylbetaine, Cetyl dimethyl carboxymethyl betaine, and cocamidopropyl betaine.

As the synthetic nonionic surfactant, alkanolamide and amine oxide can be used. Specific examples thereof include lauryldiethylamine oxide, palm oil alkyldimethylamine oxide, lauric acid diethanolamide, palm oil fatty acid diethanolamide, palm oil fatty acid Monoethanolamide and the like can be used.

The above-mentioned surfactants may be used alone or in combination in the hair cosmetic composition according to one embodiment of the present invention.

Optional ingredients used in hair cosmetic compositions according to one embodiment of the present invention are well known to those skilled in the art as conventional optional ingredients to maintain basic properties and quality. Such optional ingredients include pearlizing agents, preservatives, viscosity modifiers, pH adjusting agents, perfumes, dyes, hair conditioning agents, and the like.

As the pearlizing agent, glycol distearate, glycol monostearate, fatty acid and the like can be used.

As the preservative, p-hydroxybenzoic acid methyl, p-hydroxybenzoic acid, sodium benzoate, methylchloroisothiazolinone, methylisothiazolinone, etc. may be used alone or in combination of two or more.

As the viscosity modifier, amide type nonionic surfactants such as cocamide mie (CME), cocamide dihee (CDE), sodium chloride and the like can be used.

As the pH adjusting agent, sodium phosphate, disodium phosphate, citric acid, sodium citrate and the like can be used.

As the hair conditioning agent, it is preferable to use 0.1 to 10%, preferably 0.5 to 5% by weight, based on the total weight of the composition, of a dimethicone base and a cationic polymer alone or in combination of two or more.

The conditioner composition for hair according to one embodiment of the present invention may be added with appropriate components according to the type thereof. For example, as typical conditioner components, cationic surfactants such as tertiary amidoamine and quaternary ammonium compounds, A compound, and a silicone compound may be added. As optional components, preservatives, thickeners, viscosity adjusting agents, pH adjusting agents, perfumes, and the like may be contained.

The quaternary ammonium compound as a cationic surfactant in the hair conditioning agent composition is selected from alkyl (14-22) trimethylammonium chloride, dialkyl (14-22) dimethylammonium chloride, hydrogenated tallowalkyltrimethylammonium chloride, ditallowalkyldimethylammonium chloride And the like. Examples of the tertiary amidoamine include cocamidopropyldimethylamine, stearamidopropyldimethylamine, behenylamidopropyldimethylamine, oleamidopropyldimethylamine, isostearamidopropyldimethylamine, etc. . The amines are preferably neutralized with acids such as L-glutamic acid, lactic acid, hydrochloric acid, malic acid, succinic acid, acetic acid, fumaric acid, citric acid and EDTA. These cationic surfactants may be used alone or in admixture of two or more thereof in an amount of 1 to 30% by weight, preferably 5 to 20% by weight based on the total weight of the composition.

Examples of the high melting point compound include compounds composed of a fatty alcohol type, a fatty acid type, a fatty alcohol derivative, a hydrocarbon type, and a mixture thereof, and include, for example, cetyl alcohol, stearyl alcohol and cetostearyl alcohol. May be 1 to 10% by weight of the total weight of the composition.

The silicone compound used in one embodiment of the present invention may be selected from the group consisting of polyalkylsiloxane-based, polyarylsiloxane-based, polyalkylarylsiloxane-based, polyether siloxane copolymers and mixtures thereof, cyclopolysiloxane and suitable alkylamino substituted compounds, And the like, and may be 1-10% by weight of the total weight of the conditioner composition.

The optional ingredients used in one embodiment of the present invention are well known to those skilled in the art as conventional optional ingredients for maintaining basic properties and quality. Specific examples thereof include preservatives, pH adjusting agents, perfumes, and the like.

As the preservative, p-hydroxybenzoic acid methyl, p-hydroxybenzoic acid, sodium benzoate, methylchloroisothiazolinone, methylisothiazolinone, etc. may be used alone or in combination of two or more.

As the pH adjusting agent, sodium phosphate, disodium phosphate, citric acid, sodium citrate and the like can be used.

Hereinafter, the hair cosmetic compositions containing the black pear extract, blueberry extract and royal jelly extract according to the present invention will be described in more detail with reference to Examples and Test Examples, but the scope of the present invention is not limited to these examples.

[Example 1 and Comparative Example 1] Shampoo formulation

In order to confirm the effects of the extracts used in the present invention, a shampoo formulation containing the above extract was prepared according to the composition of the following Table 1 according to a conventional shampoo manufacturing method (Example 1). In addition, a shampoo formulation not containing the above extract was prepared according to the composition shown in Table 1 (Comparative Example 1).

Composition (% by weight) Comparative Example 1 Example 1 Ammonium laureth sulfate 10 10 Glycol distearate 2.0 2.0 Cetyl alcohol 0.6 0.6 Cocamide miai 0.5 0.5 Ammonium lauryl sulfate 6 6 Guar hydroxypropyltrimonium chloride 0.15 0.15 silicon 0.5 0.5 Spices 1.0 1.0 antiseptic 0.03 0.03 Citric acid 1.0 1.0 Black Pearl Extract / Blueberry Extract / Royal Jelly Extract - 10.0 Dilution number To 100 To 100

[Example 2 and Comparative Example 2] An active ingredient solution

To confirm the effect of the extracts used in the present invention, an aqueous solution containing 50 wt% of the total weight of the extract was prepared (Example 2). Comparative Example 2 was prepared with only diluted water.

[Test Example 1] Confirmation of hair damage repair using SEM (Scanning Electron Microscopy)

The shampoo prepared in Comparative Example 1 and Example 1 and the active ingredient solution prepared in Comparative Example 2 and Example 2 were treated with different kinds of hair for different ages and the degree of improvement of the hair condition was observed by SEM.

The hair of women in their 20s to 50s was collected, and each hair was washed with Comparative Example 1 and 5g of Example 1 shampoo, and then washed 10 times with constant flowing ionized water. In addition, each of the hairs was immersed in the solution of Comparative Example 2 and Example 2 for 24 hours, taken out, and washed 10 times with ionized water. The hair thus washed was allowed to stand for 24 hours or longer under constant temperature and humidity (relative humidity: 40%, temperature: 25 ° C) and sufficiently dried. Samples were randomly picked from fully dried hair strands and their surfaces were observed by SEM.

The observed photographs are shown in Figures 1A-1D. A is the diluted water of Comparative Example 2, B is the active ingredient solution of Example 2, C is the shampoo of Comparative Example 1, and D is the photograph of the hair treated with the shampoo of Example 1.

1A to 1D, shampoos containing black pearl extract, blueberry extract, royal jelly extract and hair treated with the solutions (Examples 1 and 2) contained black pearl extract, blueberry extract and royal jelly extract It can be seen that the cuticle on the surface is smooth and smoothly arranged compared to the hair treated with the non-shampoo and the solution (Comparative Examples 1 and 2). Particularly, when comparing the hair (B) treated with the active ingredient solution and the hair (D) treated with the shampoo, in the case of the hair treated with the shampoo, the surface of the hair becomes smoother due to the role of the conditioning agent, . These results show that the extracts of black pearl juice, blueberry extract and royal jelly extract act on the inside and outside of the hair to arrange the excised cuticles in order to smooth the surface of the hair and thereby improve the glossiness.

[Test Example 2] Measurement of tensile strength of hair

The shampoos prepared in Comparative Example 1 and Example 1, and the active ingredient solutions prepared in Comparative Example 2 and Example 2 were treated with different kinds of hair for respective ages and tensile strength was measured.

The hair of women in their 20s to 50s was collected, and each hair was washed with Comparative Example 1 and 5g of Example 1 shampoo, and then washed 10 times with constant flowing ionized water. In addition, the respective hair was immersed in the solutions of Comparative Examples 2 and 2 for 24 hours, taken out, and washed 10 times with ionized water. The hair thus washed was allowed to stand for 24 hours or longer under constant temperature and humidity (relative humidity: 40%, temperature: 25 ° C) and sufficiently dried. Samples were randomly picked from sufficiently dried hair strands and their tensile strengths were measured using a rheometer (CR-500DX, SUN SCIENTIFIC CO., LTD., Japan).

The measurement results are shown in Figs. Fig. 2 shows the result of measuring the change in tensile strength after washing the hair with the shampoo prepared in Example 1 and Comparative Example 1, Fig. 3 shows the result of measuring the change in tensile strength of the hair with the active ingredient solution of Example 2 and the diluted water of Comparative Example 2 And the change in tensile strength after immersion was measured. As shown in Figs. 2 and 3, the shampoo containing the black pear extract, the blueberry extract and the royal jelly extract and the hair treated with the solution (Example 1 of Fig. 2 and Example 2 of Fig. 3) It can be seen that the breaking point, that is, the strength is increased as compared with the hair treated with the shampoo which does not contain the extract and the royal jelly extract and the solution (Comparative Example 1 of FIG. 2 and Comparative Example 2 of FIG. 3) . These results show that the extracts of black pearl juice, blueberry extract and royal jelly penetrate the hair to increase the hair strength, and that the shampoo and the solution treatment increase the hair strength.

[Test Example 3] Quality test results using shampoo

The results are shown in Table 1. The results are shown in Table 1. The results are shown in Table 1. The results are shown in Table 1. The results are shown in Table 1. The results are shown in Table 1. The results are shown in Table 1. The quality of use was evaluated by the simple monadic test and the following results were obtained.

Survey item Comparative Example 1 Example 1 1. Bubbles are fine and bubbles are good. 5.4 5.5 2. Feels good when rinse and finger passes well 5.7 5.7 3. It is easy to comb and smooth when semi-dry. 5.2 5.6 4. It is easy and soft to care after hair drying 5.2 5.8 5. After drying hair's moisture is long 5.1 6.0 6. I feel the shine of hair after drying. 5.3 6.1

The result of the above evaluation shows that the shampoo containing the black jelly extract, the blueberry extract, and the royal jelly extract did not show shampoo (Example 1) containing the black jung ju extract, blueberry extract and royal jelly extract 1) was used, the result shows that the hair has a good moisturizing effect and excellent shine on the hair. This shows that it is possible to impart moisturizing and shine to the hair when using the black jangju extract, blueberry extract and royal jelly extract in the shampoo.

[Test Example 4] Hair gloss measurement result

The shine of the hair was measured using the shampoo prepared in Example 1 and Comparative Example 1. First, prepare a normal hair stress. This stress is blurred and damaged. 5 g of each shampoo is applied to hair tress and then washed 10 times with constant flowing ionized water. Leave the washed hair tress for 24 hours or longer under constant temperature and humidity (relative humidity: 40%, temperature: 25 ℃) and dry thoroughly. A hair with a thickness of 80 ± 10 μm is taken from the fully dried tress. Hairy hair was sampled using the SAMBA system (CHVAS 1.0) [Bossa Nova Tech.]. The higher the number, the better the gloss.

The measurement results are shown in Table 3 and FIG.

Comparative Example  One Polish( Luster ) Example  One Polish( Luster ) 1-1 16.013 1-3 17.192 1-2 15.807 1-4 16.875

As shown in Table 3 and FIG. 4, gloss values in each group of Comparative Example 1 and Example 1 were almost the same, but shampoo containing black bean extract, blueberry extract and royal jelly extract in damaged hair (Example 1) was used, it was confirmed that the gloss was increased by about 7.1% as compared with the case of using a black shampoo extract, a blueberry extract, and a shampoo containing no royal jelly extract (Comparative Example 1). It can be seen that there is a significant difference between the two data according to the P value (= 0.106).

1A to 1D are diagrams showing hair compositions of women in their twenties to fifty years old who were treated with shampoo and solutions (Examples 1 and 2) containing black pearl extract, blueberry extract and royal jelly extract, black pear extract, blueberry extract and royal jelly extract (A: Comparative Example 2, B: Example 2, and C: Comparative Example 2). The results are shown in Table 1. The shampoo and solution 1, D: Example 1).

FIG. 2 shows the hair washed with a shampoo (Example 1) containing a black pearl extract, a blueberry extract and a royal jelly extract (Example 1) and a shampoo containing a black pear extract, a blueberry extract and a royal jelly extract (Comparative Example 1) And the result of measuring the change of the tensile strength.

FIG. 3 shows that hair is immersed in a dilution water (Comparative Example 2) which does not contain a solution containing a black pear extract, a blueberry extract and a royal jelly extract (Example 2) and a black pear extract, a blueberry extract and a royal jelly extract. And the tensile strength was measured.

FIG. 4 shows that the hair was washed with a shampoo (Example 1) containing a black pear extract, a blueberry extract and a royal jelly extract (Example 1) and a shampoo containing no black pear extract, a blueberry extract and a royal jelly extract (Comparative Example 1) This is the result of measurement of the posterior hairs.

Claims (8)

A hair cosmetic composition for preventing aging of hair, comprising a black pearl extract, a blueberry extract and a royal jelly extract. The hair cosmetic composition according to claim 1, wherein the black pearl extract is a conchiolin protein obtained by dissolving an acid in a black pearl after demineralization, or a conchiolin protein hydrolyzate obtained by hydrolyzing the protein. The hair cosmetic composition according to claim 1, wherein the black pearl extract is contained in an amount of 0.01 to 10.0% by weight based on the total weight of the composition. The hair cosmetic composition according to claim 1, wherein the blueberry extract is contained in an amount of 0.01 to 10.0% by weight based on the total weight of the composition. The hair cosmetic composition according to claim 1, wherein the royal jelly extract contains 0.01 to 10.0% by weight based on the total weight of the composition. The hair cosmetic composition according to claim 1, wherein the composition is a shampoo, a rinse, a pomade, a treatment, a serum, a hair lotion or an essence formulation. 7. The hair cosmetic composition according to any one of claims 1 to 6, wherein the composition enhances the strength of the hair. 7. The hair cosmetic composition according to any one of claims 1 to 6, wherein the composition promotes moisturization and gloss of the hair.

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