KR101404966B1 - Cosmetic composition containing natural coloring - Google Patents

Abstract

More particularly, the present invention relates to an eye make-up composition containing natural pigments, and more particularly, to an eye make-up composition containing natural pigments, The present invention relates to an eye makeup composition which improves dispersion stability and promotes uniform spreading. When the eye makeup composition according to the present invention is applied to the eyeliner of the envelope structure container, a uniform line can be easily drawn.

Eye makeup * Natural coloring * Safety * Wrapping * Sign-paper structure

Description

Cosmetic composition containing natural coloring < RTI ID = 0.0 >

More particularly, the present invention relates to an eye make-up composition containing natural pigments, and more particularly, to an eye make-up composition containing natural pigments, The present invention relates to an eye makeup composition which improves dispersion stability and promotes uniform spreading. When the eye makeup composition according to the present invention is applied to the eyeliner of the envelope structure container, a uniform line can be easily drawn.

In general, eye makeup products include mascara, eyeliner, eye shadow and eyebrow. These products contain a large amount of coloring matter (coloring material). The purpose of the blending is to discard the spots around the eyes and freckles, I am in the process of developing healthy and attractive eyes. Dyes (colorants) that can be used in cosmetics can be largely divided into organic synthetic dyes, natural dyes and inorganic dyes. In particular, pigments that can be used around the eyes are more limited and safety must be guaranteed.

There are three kinds of organic synthetic dyes: Dye, lake and pigment.

Dyes are substances that give color effect in the state of being dissolved in water or oil alcohol. Red 230 and Red 223 belong to xanthene dyes. In general, dyes are more colored than skin pigment There are drawbacks that are difficult to cleanse.

Rake refers to a dye insoluble in water with a salt of calcium or the like and slightly soluble in water, such as Red No. 201, and there are Red No. 204, No. 206, No. 207, No. 208 and No. 220. In general, rake has a disadvantage in that sufficient stability test is required because the acid has less acid resistance and alkali resistance than pigments and elutes from neutral to water.

Pigment is a colorless powder that does not dissolve in water and oil solvents, and is superior in coloring power and light fastness to rake, and is widely used in makeup products.

On the other hand, natural pigments that are more safe than synthetic pigments include animal pigments, vegetable pigments, and pigments derived from microorganisms. These natural pigments can be divided into carotenoid, flavonoid, flavone, quinone, porphyrin, diketone and betacyanidine from the viewpoint of chemical structure.

For example, the yellow-reddish color which is mainly present in carrots, tomatoes, trout, shrimp and silkworms is a carotinoid pigment, and the brown cacao pigment present in cacao is a coloring matter such as a flavonoid pigment, a cochinil pigment Etc. belong to an anthraquinone system which is a quinone system. Representative natural pigments used in cosmetics include yellow β-carotene extracted from carrots, cochineal extracts extracted from leafhopper worms, and extracts from rock worms. Reddish purple laccaic acid dye, Caffeine pigment extracted from caffeine, cathamin, paprika and yellow crocin pigment extracted from gardenia fruit.

The conventional techniques used for various types of eye makeups include dyeing organic pigments such as dyes and organic pigments, extender pigments such as organic pigments and coloring pigments (5 to 30%) as colorants, wax Have used botanical waxes such as rice wax, bees wax and hydrogenated caster oil (5-25%).

Korean Patent Application No. 2002-0034229 discloses an aqueous dispersion type eye makeup composition having excellent viscosity stability using iron oxide and tetrasodium pyrophosphate. The water-dispersible eye makeup composition is suitable as a liquid type eyeliner using a general brush (brush) as a high-viscosity composition using ordinary iron oxide without chemical and physical treatment, but is not suitable as an eyeliner composition of a cartridge It is limited in the use of materials.

Korean Patent Application No. 1991-0020741 discloses a sieve-shaped oily eyeliner composition containing black iron oxide and liquid isoparaffin having a fine particle size of 100 nm or less. In the case of this sine-shaped oil-based eyeliner composition, the viscosity of the composition is low (50 cp or less), and thus it is suitable for a composition of a pen-type or a sieve-pen structure, but it is oil-based, so it is difficult to cleanse water and volatile liquid isoparaffin is used. There is a disadvantage that the safety is poor.

Conventional eye makeup patents are related to composition patents containing pigments such as synthetic pigments and color pigments as pigments. In the past, the development of products using synthetic pigments rather than natural pigments has been limited because of the difficulty of extracting natural pigments and the limited use of materials and applications. However, recently, natural pigments are superior to synthetic colorants, have excellent physiologically active effects and effects, and have been studied in mass production. Therefore, product development using natural pigments is increasing not only in foods and clothing but also in cosmetics.

Korean Patent Application No. 1998-007678 discloses a cosmetic composition containing natural pigments such as β-carotene and caramel in terms of skin protection and safety on the lips and balls, There is no example of an eye makeup composition using a pigment, and the claim of harmfulness of a synthetic pigment is coming out, and it is demanded that a safer substitution of a natural coloring agent is required.

The inventors of the present invention have found that it is easier to disperse in oil phase and water phase than black iron oxide which is a synthetic pigment or a colored pigment and to produce an eye makeup composition having a safe and uniform wetting ability in eyes, And to apply it to an eye makeup composition.

The inventors of the present invention have found that the use of natural pigments such as gardenia yellow color, gardenia blue color, bit red pigment, cochineal extract color pigment, rock color pigment, red cabbage color pigment, high color pigment and caramel color pigment, It has been found that an eye makeup composition which is easy to disperse in an aqueous phase and is safe to eyes and uniformly dispersed evenly can be prepared, and furthermore, when the composition is applied to an eye liner of an ink pen structure using the composition, The present inventors have found that the present invention provides a feeling of being able to draw an eyeliner.

Accordingly, the present invention provides an eye makeup composition containing a natural pigment pre-treated to be well dispersed in water or oil.

According to the present invention, it is possible to provide a more safe eye makeup composition that is free from harmful substances such as heavy metals and has uniform spreadability by improving the lubrication and flaking of existing iron oxide and organic synthetic pigments due to uniform dispersion through pre-treatment of natural pigments .

Further, when the eye makeup composition of the present invention is applied to an eye liner of a sieve-like structure, it is possible to easily draw a uniform line.

Hereinafter, the present invention will be described more specifically.

Examples of natural pigments used in place of iron oxide in the present invention include a gardenia yellow color, a gardenia blue color, a bit red color, a cochineal extract color, a rock color, a red cabbage color, a high color pigment and a caramel color. The natural coloring matter used in the present invention exhibits natural coloring power as compared with the synthetic coloring agent, so it is preferable to use 1.5 to 2 times the amount of the synthetic coloring agent to express a dark color. Accordingly, the content of natural pigments is preferably 5 to 80% by weight based on the total weight of the pigments, and when the respective natural pigments are mixed at less than 5% by weight, the specific pigments are not expressed. The pigments do not dissolve uniformly, so they are lumpy and stick together and can not draw a clean line.

The gardenia yellow color used in the present invention is a sulfur-reddish brown liquid, agglomerate, powder or paste material with a slight peculiar odor, and the aqueous solution has a clear yellow color. It is obtained by extracting or hydrolyzing the fruit of the gardenia with water or ethyl alcohol as a carotenoid-based coloring agent among natural bitter-based pigments.

The flower of the gardenia blue used in the present invention has a slight peculiar odor on a dark blue liquid, lump, powder or paste, and the aqueous solution has a clear blue color. It is a carotenoid-based coloring matter among natural bitter-based coloring matter and is obtained by applying β-glucosidase to a mixture of Iridoid glycoside and proteolytic substance contained in fruit juice extract of gardenia. It dissolves in water and does not dissolve in ethanol or oil.

The bit red pigment used in the present invention is a purple-dark purple liquid, lump, powder, or paste-like substance with a slight peculiar odor. It is a natural bitter-purple coloring matter based on betaine (C ₂₄ H ₂₆ O ₁₃ N ₂ ) as a main component. It is soluble in water and does not dissolve in ethanol and fat. It is obtained by extraction with water or ethanol from the roots of Beta vulgaris .

The cochineal extract pigment used in the present invention is a bitart-based natural pigment, which is used as a coloring agent for red beverages, ice cream, fruit drinks and milk, and is also used for dyeing fabrics. There is a slight peculiar odor in red-brown liquid, lump, powder or paste. The extract of Cochinil extract, which is a natural bitart coloring agent, is a concentrate obtained by extracting the dry embryo of Dactylopius coccus costa ( Coccus cacti . L.), a parasitic female insect parasitic to Nopalea coccinellifera and the like, with a water-alcoholic solution, (C ₂₂ H ₂₀ O ₁₃ ). It is soluble in water, slightly soluble in ethanol, and almost insoluble in oil. It is stable to heat and light and has excellent acid resistance but has a property of binding to protein.

The Lac Color used in the present invention is a red-dark reddish brown liquid, powder, lump or pasty substance with a slight unusual odor. Rock of non-tar dye coloring is natural rakkeu paegakcheung (Laccifer lacca KERR. Coccidae ) is extracted with water. The main dye is laccaic acid (C ₂₆ H ₁₉ NO ₁₂ ) of the anthraquinone system. It is slightly soluble in water and soluble in ethanol or propylene glycol. The aqueous solution shows an orange-reddish color from acidity, a reddish color from neutral to red, and a purplish reddish from alkaline. Especially diluted ethanol solution has red color and is stable to heat, light, oxidation, reduction and so on.

The red cabbage pigment used in the present invention is a dark red liquid, powdery or paste-like substance and has a slight unusual odor. The red cabbage pigment, which is a flavonoid-based coloring in the natural bitter-based coloring matter, is obtained by extracting the leaves of red cabbage with water, and the main coloring matter is anthocyanin. It dissolves in water, alcohol, propylene glycol, etc. and does not dissolve in oil. It is stable to light or heat and is not strong in dyeability, but its salt resistance is comparatively excellent.

The high-color pigment used in the present invention is a dark brown powder or liquid, and has a slight peculiar odor. The aqueous solution shows a neutral-alkaline to reddish brown-brown color. The high coloring matter, which is a natural coloring material based on bitter, is a coloring matter obtained by extracting the fruit of sorghum with water or ethanol. The main coloring matter is a flavonoid-based apigenin (C ₁₅ H ₁₀ O ₅ ). The high coloring matter is dissolved in water, hydrous ethanol, propylene glycol and alkali solution but not dissolved in oil.

The caramel coloring matter used in the present invention is a dark brown-black lump, powder, or paste-like substance, which is suitable as a coloring agent for brown color. It has no odor or has a peculiar odor of sugar carbonization and has a refreshing bitter taste. The aqueous solution shows light brown-dark brown color. It is a bitter natural coloring agent. It is soluble in water and hardly soluble in ethanol, acetone, ether or chloroform.

In the present invention, a black color is expressed by mixing natural pigments of a blue colorant, a yellow colorant and a red colorant In order to express the black color, the mixing ratio of the mixed blue pigment, yellow pigment and red pigment is 1: 1: 1 to 4: 3: 2, If it is more than pigment, dark color is expressed. As a blue coloring matter satisfying this, MSC Korea's gardenia and gardenia green were used. As yellow coloring matter, MSC Korea's gardenia yellow, water-soluble paprika and water-soluble Anna were used, and a red coloring matter was MSC Korea's MSC Red Pigment red, red cabbage pigment and MSC color Kettenbi were used. In order to further enhance the black color, other brown color caramel dyes and high color dyes of MSC Korea Co., Ltd. were added, but the present invention is not limited thereto.

The natural pigment is preferably contained in an amount of 0.1 to 80% by weight, and most preferably 1 to 50% by weight, based on the total weight of the eye makeup composition. When the content of the natural pigment is more than 80% by weight, the stirrer can not be operated properly due to an increase in viscosity at the time of production, and dispersion can not be achieved. A composition that is not properly dispersed in this way causes layer separation and does not uniformly float.

In the present invention, in order to facilitate the dispersion of the natural pigment in the aqueous phase, the natural pigment of the powder is subjected to a pretreatment in which it is liquefied with polyol and water.

The polyol used in the present invention includes glycerin, propylene glycol, and 1,3-butylene glycol. The content of the polyol varies depending on the content of the natural coloring matter, and is 20% by weight or less of the natural coloring matter. If the content of polyol is excessive, the drying speed is delayed and becomes frustrating. In addition, when a formulation requiring moisture persistence such as mascara or eyeliner is used in an amount of more than 20% by weight of a polyol having a large number of hydroxyl groups (-OH), a phenomenon of sticking may occur. Therefore, it is preferable that the polyol contains 1 to 20% by weight of the weight of the natural pigment. When the natural pigment is used without pretreatment to liquefy the polyol and the water, the natural pigment, the polymer and other components are entangled and the dispersion itself can not proceed. Therefore, the natural pigment of the present invention pretreated with the polyol is water-soluble.

In addition, the natural pigment according to the present invention can be used through a pretreatment process which becomes useful as an emulsifier to facilitate dispersion in an oil phase. At this time, the emulsifier used in the pretreatment is preferably used in an amount of 0.5 to 5% by weight based on the total weight of the entire eye makeup composition, wherein the HLB (Hydrophilic-Lipophilic Balance) is 4 to 5. The HLB value best represents the nature of the surfactant and essentially determines the nature of the system. Generally, the emulsifier with HLB of 1.5-3 is used as defoamer, the emulsifier with 4-6 is the W / O emulsifier, The emulsifier of ~9 is used as a humectant, and the emulsifiers 8-18 are used as an O / W emulsifier. In the present invention, an emulsifier capable of utilizing a natural coloring matter may be glyceryl stearate, sorbitan sesquioleate, sorbitan stearate and sorbitan isostearate having an HLB of 4 to 5, By weight to 30% by weight. That is, the natural pigment of the present invention pretreated with an emulsifier as described above is characterized as usefulness.

In general, natural pigments are more unstable to heat and light depending on the nature of the raw material compared to general synthetic pigments, and sometimes are discolored or discolored. Therefore, in order to improve the light resistance of natural pigments, a benzophenone derivative, It is preferable to add the benzoic acid derivative, the methoic timepinic acid derivative or the salicylic acid derivative in an amount of 0.1 to 5.0% by weight based on the total weight of the composition to improve the light resistance, more preferably the butylmethoxydibenzoylmethane (Parsol # 1789) and benzophenone-5 (benzophenone-5).

The eye makeup composition according to the present invention can be produced by being put on a container of a general squeeze pen structure made up of a filter and a container in which a natural pigment is absorbed (Figs. 1A and 1B), but the present invention is not limited thereto.

Hereinafter, the present invention will be described in more detail with reference to Examples and Test Examples, but the present invention is not limited thereto.

[Test Example 1] Dispersion of natural pigments with and without pretreatment

Table 1 shows the dispersibility of natural pigments with and without pretreatment.

Pretreatment material X
(none) glycerin  Propylene glycol  1,3-butylene glycol Sorbitan isostearate Gardenia Blue Small Mineral Acid X ○ ○ ○ ○ Gardenia yellow small disperse acid X ○ ○ ○ ○ Bit red pigment dispersion X ○ ○ ○ ○ Cochineal pigment dispersibility X ○ ○ ○ ○ Caramel colorant dispersibility X ○ ○ ○ ○

○: Dispersed in medium

X: Not distributed

For use in water-soluble products, it is pre-treated with glycerin, propylene or 1,3-butylene glycol. In this case, 50% by weight of natural pigments are mixed at room temperature for 10 minutes in order to sufficiently wet the pigment with 10% by weight of 1,3- 40% by weight, and the mixture was mixed for 10 minutes and then pretreated with a water-soluble dye.

Also, it is useful by pretreatment with emulsifier for use in oil - soluble products. At this time, 60 to 70% by weight of hydrocarbons such as isododecane or liquid paraffin (LP) were added to 1 to 2% by weight of sorbitan isostearate as an emulsifier, and the mixture was mixed at 70 캜 for 5 minutes, 30% by weight of a natural dye pretreated with glycol was added, and the mixture was mixed at 70 캜 for 10 minutes and then cooled to 30 캜.

As shown in Table 1, it can be seen that the dispersion itself can not proceed unless the natural pigment is pretreated in advance. Samples using pretreated natural pigments were able to produce uniformly dispersed and emulsified surfaces compared to the samples using iron oxide. This showed a particularly smooth spreading property at the time of application.

[Examples 1 to 5 and Comparative Examples 1 and 2]

The following Table 2 shows the compositions of Examples 1 to 5 and Comparative Examples 1 and 2 as production examples of eyeliner and mascara. The natural pigment black-A used in Examples 1 and 2 was prepared by pretreating natural pigment black of MSC Co. with 1,3-butylene glycol, and the water-soluble eyeliner was produced in the same amount as the conventional iron oxide. In Examples 3 to 5 The natural pigment Black-B used was a water-in-oil (O / W) emulsified type eyeliner and mascara which was pretreated with oiliness using sorbitan isostearate, which is an emulsifier, MSC's natural pigment black. In Examples 2 and 4, benzophenone-5 and parcel # 1789 were added to improve the light resistance, and the light resistance was compared with Examples 1 and 3, respectively. Comparative Example 1 was prepared as a control group for comparing the spreadability with Examples 1 to 4 and 30% by weight of iron oxide, which is a colorant mainly used in the past.

Comparative Example 2 was prepared as a mascara preparation example and a control group for comparison of the spreadability with Example 5. [

Ingredients Example
One Example
2 Example
3 Example
4 Example
5 Comparative Example
One Comparative Example
2 1. Purified water Balance Balance Balance Balance Balance Balance Balance 2. Butylene glycol 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3. Hydroxylethylcellulose 0.5 0.5 0.5 0.5 0.5 0.5 0.5 4. Ester oil - - 10.0 10.0 - - - 5. Beads wax - - - - 8.0 - 8.0 6. Cetearyl alcohol - - 1.5 1.5 2.5 - 2.5 7. Cetearyl glucoside - - 1.5 1.5 1.0 - 1.0 8. Ethanol 2.0 2.0 2.0 2.0 2.0 2.0 2.0 9. Acrylate Copolymer 15.0 15.0 15.0 15.0 15.0 15.0 15.0 10. Natural pigment black (MSC) -A 30.0 30.0 - - - - - 11. Natural pigment black (MSC) -B - - 30.0 30.0 15.0 - - 12. Iron oxide - - - - - 30.0 15.0 13. Benzophenone-5 - 1.0 - - - - - 14. Pasol # 1789 - - - 1.0 1.0 - - 15. Preservatives Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount

≪ Preparation methods of Examples 1 and 2 and Comparative Example 1 &

1) Components 1 to 3 were stirred at room temperature.

2) Component 10 (or component 12) was added to 1) and stirred, followed by stirring components 9, 13 and 15.

3) Component 8 was added to the above 2), stirred and then degassed.

4) The composition of the above 3) was filled in an eyeliner container.

≪ Preparation methods of Examples 3 to 5 and Comparative Example 2 >

1) Components 1 to 3 were heated to 70 占 폚.

2) Components 4-7 and 14-15 were heated to 80 < 0 > C.

3) The natural pigment component 11 (or 12) of the pretreated black was added to the mixture of 2) and stirred.

4) Components 8 to 9 were added to the mixture of 1), emulsified while gradually adding 1) to 3), and then cooled to 35 ° C.

5) The composition of the above 4) was filled into an eyeliner and a mascara container.

[Test Example 2] Comparative feeling (feeling of uniformity)

≪ Comparative experiment of feeling of eyeliner &

In order to compare the feeling of use of Examples 1 to 4 and Comparative Example 1, the uniformity of eye lines was measured by sensory evaluation. Table 3 shows the results of sensory evaluations of the length and shape of the lines and shapes drawn on 30 points of the women in their 20s and 30s who use the eyeliner daily or more than three times a week. The eyeliner of Examples 1 to 4 was used in the sensory evaluation by placing it in a container of a squeeze-type structure which can be drawn easily. However, the contents of Comparative Example 1 were not suitable for the sign pen structure,

Item Example 1 Example 2 Example 3 Example 4 Comparative Example 1 Brittle 8 8 8 8 5 Line length 9 9 8 8 4 Color representation 6 8 6 8 8 Overall assessment ○ ◎ ○ ◎ △

◎: Excellent (8 points or more), ○: Excellent (6 points or more)

△: Normal (5 points or more), X: Poor (4 points or less)

≪ Test of uniformity of mascara '

Viscosity data at the time of application were measured in order to evaluate the uniform spreadability of the mascara of Example 5 and Comparative Example 2. The AR2000 Rheometer was used as the instrument. The accessory used here was designed to measure the high viscosity of cream, mascara and the like due to its short radius. The instrument was used with a radius of 1 cm and a tilt angle of 1 ° Viscosity at a shear rate of 1000 (1 / s) was measured. Generally, when the cosmetic composition is applied, the transmission rate is 1 to 1000 (1 / s), and the viscosity at this time is the value of the resistance against movement when the fluid moves, and the larger the value is, On the contrary, when the viscosity is low, the resistance which interferes with the movement is small and can easily flow. Therefore, the value of viscosity at the time of application means that the content is easily spread in the direction of application.

Table 4 below shows the viscosity values measured at a transmission rate of 1000 (1 / s) for Example 5 and Comparative Example 2. In addition, the sensory evaluation of the mascara application was also carried out.

Test substance Viscosity (Pa · s) Brittle sensory evaluation Color representation Overall assessment Example 5 0.23 9 7 ◎ Comparative Example 2 8.24 4 9 ○

◎: Excellent (8 points or more), ○: Excellent (6 points or more)

△: Normal (5 points or more), X: Poor (4 points or less)

Unlike the composition of Comparative Example 2 using iron oxide, when the force of the composition of Example 5 using the natural pigment is applied, the natural pigments are dissolved in water or oil so that there is no particle feeling of the pigment (pigment) ) Was low, so that the contents could be easily spread, and as a result, the spreadability was improved. The spreadability through the values of these viscosities was also consistent with the evaluation of feeling through the panel.

[Test Example 3] An inner stimulation test

HETCAM-HEN'S EGG TEST ON THE CHORIOALLANTOIC MEMBRANE was conducted to test the mascara of the compositions of Examples 1 to 5 and Comparative Examples 1 and 2 for eye irritation. For the test method, the test method specified in CTFA SAFETY TESTING GUIDELINES was used. When the white hatching was hatched at 37 ± 0.5 ° and 55 ± 7% for 10 days, only the well-developed chorioallantoic membrane (CAM) cells were removed and the egg shell and the egg shell were removed. 2 was applied to PARAFILM, the test substance was applied to CAM for a predetermined time (30 seconds) with the test substance facing downward, and CAM was washed with physiological saline to evaluate the reaction. The results were evaluated according to the evaluation criteria in the preliminary experiments of Table 5 below. The evaluation by HET-CAM was expressed by the sum of S (hemorrhage, hemorrhage), L (lysis, dissolution) and C (coagulation)

Reference substance Judgment Reaction aspect score 0.5% Texason ASV Weak Bleeding and dissolving
(Hemorrhage and Lysis) 1 (0 if no response) 1.0% Texason ASV Moderate 2 5.0% Texason ASV Strong 3

The test was carried out six times each, and the results are summarized in Table 6 below. In Table 6, the total number of irritation points is less than 6, which is "SLIGHTLY IRRITATING", "O" for 6-12, "O" for MOERATELY IRRITATING, and "IRRITATING" Quot ;, and those exceeding 16 were marked with " x " as severe irritation (SEVERELY IRRITATING).

Test substance HET-CAM test results Example 1 ◎ Example 2 ◎ Example 3 ◎ Example 4 ◎ Example 5 ◎ Comparative Example 1 O Comparative Example 2 O

As shown in Table 7, in comparison with Comparative Examples 1 and 2 using iron oxide, Examples 1 to 5 according to the present invention showed a slight stimulation level. Thus, it was confirmed that the composition of the present invention can be used more safely without stimulating the eye than existing products.

Figs. 1A and 1B are photographs of an eyeliner having an eye-makeup cosmetic composition according to the present invention. Fig.

Claims (12)

Blue pigment such as gardenia blue; Yellow as a yellow pigment; And at least one selected from the group consisting of bit red pigment, cochineal pigment, rock pigment, red cabbage pigment, high color pigment and caramel pigment in a ratio of 1: 1: 1 to 4: 3: 2 Containing pigment, The natural pigment may be pretreated by immersing it in water together with a polyol selected from the group consisting of glycerin, propylene glycol and 1,3-butylene glycol, or pretreated with an emulsifier having 4 to 5 HLB (Hydrophilic-Lipophilic Balance) ≪ / RTI > delete The eye makeup composition according to claim 1, wherein the natural coloring matter is contained in an amount of 0.1 to 80% by weight based on the total weight of the eye makeup composition. delete The eye makeup composition according to claim 1, wherein the polyol is contained in an amount of 1 to 20% by weight based on the total weight of the natural coloring matter. The eye makeup composition according to claim 1, wherein the natural pigment pretreated with the polyol is water-soluble. delete The eye makeup composition according to claim 1, wherein the emulsifier is contained in an amount of 0.5 to 5% by weight based on the total weight of the composition. The eye makeup composition according to claim 1, wherein the natural pigment pretreated with the emulsifier is oil-soluble. The eye makeup composition according to claim 1, wherein the composition further comprises at least one ultraviolet absorber selected from the group consisting of a benzophenone derivative, a p-aminobenzoic acid derivative, a methotrexate derivative, and a salicylic acid derivative. The eye makeup composition according to claim 10, wherein the ultraviolet absorbent is contained in an amount of 0.1 to 5.0% by weight based on the total weight of the composition. 11. A makeup-type eye makeup cosmetic comprising an eye makeup composition according to any one of claims 1, 3, 5, 6 and 8 to 11.

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