KR101390748B1 - Sewage and wastewater treatment apparatus for removal of nitrogen and phosphorus - Google Patents

Abstract

A wastewater treatment apparatus for nitrogen and phosphorus removal is disclosed. The disclosed wastewater treatment apparatus is a wastewater treatment facility where raw water containing at least one microorganism and an organic matter is introduced, an anaerobic tank in which a biological release reaction proceeds in an anaerobic state, an effluent discharged from the anaerobic tank and a nitrate- An anoxic tank in which a biological denitrification reaction of the nitrate nitrogen proceeds in an anoxic state, a first transport pipe for transporting a part of the activated sludge discharged from the anoxic tank to the anaerobic tank, a second transport pipe for discharging the effluent discharged from the anoxic tank, A membrane separation aerobic tank for separating the effluent discharged from the anoxic tank into treated water and sludge, and a part of the activated sludge discharged from the membrane separation aeration tank, An anoxic tank, and the second anoxic tank The counter to be treated the supernatant with the MLSS concentration of the low MLSS concentration provided with the MLSS concentration means to separate the higher the lower layer liquid.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a waste water treatment apparatus for removing nitrogen and phosphorus,

A wastewater treatment apparatus for removing nitrogen and phosphorus is disclosed. The anoxic tank includes an MLSS (MLSS) which separates the water to be treated into a lower liquid having a mixed liquor suspended solid (MLSS) concentration and a lower MLSS having a higher MLSS concentration, and an anaerobic tank A wastewater treatment apparatus having an enrichment means is disclosed.

Industrialization and urbanization up to the second half of the 21st century caused many pollutants, and these pollutants came into watersheds and gradually worsened the water environment. In addition, due to the effects of climate change, the global village has become increasingly concerned about the water shortage problem and the interest in water conservation and reuse of water has increased, and it has gradually strengthened the water quality standard to be discharged to the river.

However, conventional wastewater treatment plants have been limited in meeting increasing water quality standards, addressing ever-increasing sources and water scarcity. Especially, the shortage of the river slope as Korea, the distinction between the wet season and the dry season became clear, and the problem became more serious when the water shortage was serious and the installation space of the wastewater treatment device was insufficient.

In recent years, MBR (membrane bioreactor) has attracted attention as an advanced treatment technology capable of overcoming such local problems and meeting the water quality standards which are gradually strengthened. MBR is a technology that can almost completely separate and remove oil / inorganic pollutants and microorganisms present in wastewater by using micropore size and membrane surface charge of membrane. The membrane is modular and can be easily combined with other physicochemical or biological treatment devices to form an efficient wastewater treatment device.

In advanced countries, the wastewater treatment apparatus is constructed by combining various devices and MBRs, and the wastewater is treated with high efficiency, and the treatment water obtained by the treatment is reused. As a result, the treated water has reached the technical level of reusing not only the water for landscape water, washing water, toilet water but also drinking water.

In recent years, interest in MBR technology has increased with the implementation of the total amount of pollutants in Korea, and membrane technology has been spread and spread.

Generally, it is known that MBR can maintain the concentration of microorganisms in the reaction tank at a high level, thereby enhancing the activity of microorganisms when the influent load is high, and thus has excellent water treatment efficiency, especially nitrogen and phosphorus removal efficiency.

However, due to membrane fouling, which is inevitably generated when the MBR is operated, periodic cleaning and replacement of the membrane is required, which increases operating costs.

Membrane fouling in MBR is caused by complicated phenomena in which various kinds of microorganisms survive in the water to be treated in the treatment facility and metabolites due to these microorganisms are present. In general, factors affecting membrane fouling include flux, crossflow velocity, and aeration intensity, as well as MLSS concentrations, physiological metabolites of microorganisms, and material of membranes have. Despite the efforts of many researchers, the problem of membrane fouling due to these various factors has yet to be solved.

In the past, MBR was operated at an extremely high MLSS concentration, maintaining the long sludge retention time for the purpose of producing a low excess sludge using the advantage of controlling the microbial concentration in the reactor. However, operation under these conditions can reduce the cost of sludge treatment by inducing the production of excess surplus sludge. However, by inducing competition and endogenous growth of microorganisms in the reaction tank, microbial activity is lowered, Causing the problem of raising the operating cost while accelerating. Studies have also been reported that operating with a long retention time (SRT) increases both the amount and composition of the dissolved microbial metabolites as well as the MLSS concentration.

The recent operation of the MBR is focused on minimizing membrane contamination while improving treatment efficiency while maintaining proper SRT. However, it is also a reality that a high MLSS concentration can not be maintained in order to maintain a high nitrogen and phosphorus removal efficiency while reducing the installation area.

Therefore, there is a need for a technique capable of increasing the concentration of microorganisms in the removal of nitrogen and phosphorus in the wastewater, reducing the contamination of the separation membrane, and ultimately improving the permeation flux.

An embodiment of the present invention includes an anaerobic tank, an anoxic tank and a membrane separation aquifer, which are serially connected in series, and the anoxic tank includes MLSS concentration means for separating the for-treatment water into a lower layer having a lower MLSS concentration and a lower layer having a higher MLSS concentration The wastewater treatment apparatus comprising:

According to an aspect of the present invention,

An anaerobic tank into which raw water including at least one microorganism and organic matter is introduced and in which an anaerobic phosphorus release reaction proceeds;

An anoxic tank in which biological nitrification reaction of the nitrate nitrogen proceeds in an anaerobic state to where effluent discharged from the anaerobic tank and nitrate nitrogen-containing sludge are introduced;

A first conveyance pipe for conveying a part of the activated sludge discharged from the anoxic tank to the anaerobic tank;

A membrane separation aerobic tank for separating the effluent discharged from the anoxic tank into treated water and sludge, a biological nitrification reaction and an excessive intake reaction proceed in a state where oxygen is supplied to the effluent discharged from the anoxic tank; And

And a second transport pipe for transporting part of the activated sludge discharged from the membrane separation aeration tank to the anoxic tank,

Wherein the anoxic tank is provided with MLSS concentration means for separating the for-treatment water into a supernatant having a low MLSS concentration and a supernatant having a high MLSS concentration.

The microorganism may comprise dPAO (denitrifying phosphorus accumulating organism).

The MLSS concentration means may be a porous plate or a non-porous plate disposed in the anoxic tank and bisecting the space in the anoxic tank.

The porous plate may have a diameter, a thickness and a porosity of 2 to 10 mm, 2 to 30 mm and 30 to 80%, respectively.

The membrane separation aeration tank may include an aerobic tank disposed at a rear stage of the anoxic tank, a separation membrane tank disposed at a rear stage of the aerobic tank, and a movable baffle or a fixed baffle disposed between the aerobic tank and the membrane tank.

Oxygen is supplied from the outside to the separation membrane bath, oxygen is supplied from the separation membrane bath to the oxic tank, and the water to be treated which is discharged from the anoxic tank and introduced into the membrane separation aeration tank is supplied to the mobile baffle or the fixed baffle, The space between the aerobic tank and the membrane separation tank can be circulated through the space and the space below the lower end thereof.

In the aerobic tank, a biological nitrification reaction and an excessive intake reaction proceed, and in the separation membrane bath, the for-treatment water can be separated into treated water and sludge.

The wastewater treatment apparatus may further include a chemical injector for injecting at least one of an external carbon source and an aggregating agent into the anoxic tank.

The external carbon source may include at least one selected from the group consisting of methanol, acetic acid, and methane, and the coagulant may include at least one selected from the group consisting of alum, polyaluminum chloride (PAC), and ferric chloride.

The wastewater treatment apparatus according to an embodiment of the present invention has the following advantages:

(1) Minimizing the use of external carbon sources and coagulants even under conditions of very low organic load, C / N ratio and C / P ratio, characteristic of domestic wastewater, It is possible to produce an ultra-high-grade treatment that produces treatment water sufficient to meet water quality standards required for reuse of water for maintenance and the like.

(2) By precipitating and concentrating MLSS at a high concentration in anoxic tank, denitrification ability is kept very high by MLSS concentrated in the bottom layer in anoxic tank, which is advantageous in maintaining anaerobic conditions in anaerobic tank.

(3) The lifetime (in particular, the lifetime of the separation membrane) is relatively long, the amount of cleaning air required at the time of membrane filtration is small and operation cost can be reduced, and productivity of treated water is high.

(4) Dissolved oxygen (DO) in a membrane separation aerobic tank can be controlled by using a separable plate (ie, baffle) or a fixed baffle installed in the membrane separation aeration tank.

1 is a view showing a wastewater treatment apparatus for nitrogen and phosphorus removal according to an embodiment of the present invention.
2 is a view showing a wastewater treatment apparatus used in Examples 1 and 2 and Comparative Examples 1 to 6.
FIG. 3 and FIG. 5 are graphs showing concentrations of phosphoric acid (PO ₄ ^{3 -} -P) measured at each step according to the presence of external carbon source and coagulant during operation of the wastewater treatment process using the wastewater treatment apparatus of FIG.
4 and 6 are graphs showing the concentrations of nitrate nitrogen (NO ₃ ^- N) measured at each step according to the presence of external carbon sources and coagulants during operation of the wastewater treatment process using the wastewater treatment apparatus of FIG.
7 is a view schematically showing a filtration apparatus having a separation membrane.
8 is a graph showing a change with time of the inter-membrane pressure difference depending on the MLSS concentration of the water to be treated (i.e., wastewater) in operation of the filtration apparatus of FIG.

Hereinafter, a wastewater treatment apparatus according to an embodiment of the present invention will be described in detail with reference to the drawings.

1 is a view showing a wastewater treatment apparatus for nitrogen and phosphorus removal according to an embodiment of the present invention.

1, the wastewater treatment apparatus 100 includes an anaerobic tank 1, an anoxic tank 2, and a membrane separation aeration tank 3. In this wastewater treatment apparatus 100, raw water FW is supplied to the anaerobic tank 1. A part of the activated sludge discharged from the anoxic tank 2 is transported to the anaerobic tank 1 through the first transport pipe 8 and part of the sludge separated from the film separation aquarium 3 is transported to the second transport pipe 9 To the anoxic tank (2). The raw water (FW) contains at least one kind of microorganism and organic matter. The microorganisms contained in the raw water (FW) may include an organism removing microorganism, a nitrifying microorganism, a denitrifying oxidizing microorganism, a phosphorus accumulating organism (PAO), and / or a denitrifying phosphorus accumulating organism (dPAO). Since the raw water (FW) normally contains only a very small amount of microorganisms, in order to save time for the microbes to reproduce at the beginning of operation of the wastewater treatment apparatus 100, the sludge collected at the sewage end treatment plant Is used instead of the raw water FW to fill each of the reaction vessels of the wastewater treatment apparatus 100. In the present specification, 'raw water' means wastewater flowing into the anaerobic tank 1 of the wastewater treatment apparatus 100. In this specification, 'for-treatment water' refers to all the wastewater in a state before being discharged after being introduced into each reaction tank included in the wastewater treatment apparatus 100. In this specification, the term "treated water" means effluent discharged from the membrane separation aeration tank 3 of the wastewater treatment apparatus 100.

Hereinafter, the configuration and operation of each component will be described in detail.

(1) Anaerobic tank (1)

The raw water FW discharged from the raw water tank FT and a part of the activated sludge discharged from the anoxic tank 2 (that is, microorganism-containing sludge) are introduced into the anaerobic tank 1. In the anaerobic tank (1), a biological release reaction proceeds, and this phosphorus release reaction proceeds in the absence of dissolved oxygen. In this connection, dissolved oxygen is prevented from flowing into the anaerobic tank 1 by introducing a part of the activated sludge discharged from the anoxic tank 2 into the anaerobic tank 1, and the concentration of the microorganisms in the anaerobic tank 1 and the concentration Can be increased to promote the biological release response.

In the present specification, the term "phosphorylation reaction" refers to a reaction in which phosphorus is released from an adenosine triphosphate (ADP) into adenosine diphosphate (ATP) contained in the cells of a microorganism. Stores organic matter in raw water (FW) in the form of polyhydroxybutyrate (PHB) / polyhydroxyvalerate (PHV). There is a small amount of nitrate nitrogen or oxygen (O ₂ ) in the raw water (FW) and the activated sludge returned to the anaerobic tank (1) in the anoxic tank (2). If nitrate nitrogen and / or oxygen (O ₂ ) are present in the activated sludge returned from the raw water (FW) and / or the anoxic tank 2, oxygen (O ₂ ) ) Is used as an electron acceptor, it is difficult to cause a phosphorus releasing reaction. In addition, if the phosphorus release reaction does not occur, an excessive intake reaction does not occur in the membrane separation aeration tank 3, and biological removal is not achieved.

When the BOD / TP (biological oxygen demand / total phosphorus) concentration ratio (hereinafter referred to as C / P ratio) in the raw water FW is stable (that is, BOD / TP is 25 or more) The phosphorus concentration in the treated water (TW) can be kept low due to the increase of the phosphorus intake by the ingestion reaction.

The anaerobic tank (1) may be equipped with a stirrer (4) and oxygen is not supplied.

(2) Anoxic tank (2)

In the anoxic tank 2, the effluent discharged from the anaerobic tank 1 and a part of the activated sludge discharged from the membrane separation aerobic tank 3 (specifically, the oxic tank 3-1) are transported and introduced.

The sludge returned to the anoxic tank 2 from the membrane separation aerobic tank 3 contains nitrate nitrogen. In this anoxic tank 2, a denitrifying bacteria using oxygen in nitrate nitrogen as an electron acceptor, for example, denitrifying phosphorus accumulating organism (dPAO) is added to the inside of the cell of dPAO in the form of PHB / PHV in the anaerobic tank 1 A biological denitrification reaction occurs in which the nitrate nitrogen is reduced to nitrogen gas and released to the atmosphere. Therefore, the nitrate nitrogen is present at a very low concentration in the sludge returned from the anoxic tank 2 to the anaerobic tank 1 (which contains the nitrate nitrogen of the same concentration as the sludge in the anoxic tank 2) The phenomenon of inhibiting the phosphorus releasing reaction does not occur. At this time, a biological dephosphorization reaction may also occur, in which phosphorus is removed by intrusion into the cell by an excessive intake reaction. Thus, since the biological denitrification reaction and the dephosphorylation reaction are carried out using PHB / PHV (that is, stored in dPAO), the amount of the organic matter supplied from the outside can be reduced. In the anoxic tank 2, since part of the PHB / PHV is oxidized without supplying oxygen, oxygen is used as an electron acceptor in the membrane separation aeration tank 3 to oxidize the remainder of the PHB / PHV, The amount of oxygen required can be reduced. Also, as in the anoxic tank 2, when the PHB / PHV is oxidized, oxygen in the nitrate nitrogen is used as the electron acceptor, because the cell synthesis amount is smaller than that in the case where dissolved oxygen is used, the amount of sludge generated can be reduced. In addition, the PHB / PHV stored in the cells during the phosphorus releasing reaction in the anaerobic tank (1) can be used for denitrification, so that the total amount of organic substances required for denitrification can be reduced.

The anoxic tank 2 is provided with an MLSS concentration means 12 for separating the for-treatment water into an upper layer liquid having a mixed liquor suspended solid (MLSS) concentration and a lower layer liquid having a higher MLSS concentration. The MLSS concentration of the underlayer liquid of the anoxic tank 2 is raised by the action of the MLSS concentration means 12 to promote the biological denitrification reaction described above and the MLSS concentration of the upper layer of the anoxic tank 2 is lowered The MLSS concentration in the water to be treated in the membrane separation tank 3 is automatically reduced to minimize the membrane contamination of the membrane separation tank 3-2 in the membrane separation aeration tank 3 to increase the permeation flow rate (i.e., the amount of treated water produced).

The MLSS concentration means 12 may be a porous plate or a non-porous plate which is disposed in the anoxic tank 2 and bisects the space in the anoxic tank 2. [ In this specification, " dividing a space " does not mean only a case where the space is bisected, but means all cases in which one space is divided into two spaces whose sizes (i.e., volumes) are equal to or different from each other. The porous plate may have a diameter, a thickness and a porosity of 2 to 10 mm, 2 to 30 mm and 30 to 80%, respectively. Here, " porosity " means the ratio (percentage) of the total volume of the holes formed in the porous plate to the total volume of the porous plate. The porous plate may be a lattice plate or a circular plate, and may have various shapes depending on the shape of the anoxic tank 2.

The porous plate may be disposed parallel to the bottom of the anoxic tank 2.

The non-porous plate may be an inclined plate. Such a swash plate may have a thickness of 2 to 30 mm and a slope of 10 to 60 degrees (°) based on the bottom of the anoxic tank 2. The swash plate may be disposed as a flat plate so that the anaerobic tank (1) is lower and the membrane separation aerobic tank (3) is higher.

The MLSS concentration means 12 serves to limit the fluid flow produced by the agitation of the agitator 5 in the transverse direction. That is, the MLSS concentration means 12 cuts off the fluid flow in the longitudinal direction due to the agitation of the agitator 5, thereby suppressing the mixing of the upper layer liquid and the lower layer liquid of the MLSS concentration unit 12. The operation and effect of the MLSS concentration means 12 are as follows: each reactor of the wastewater treatment apparatus 100 is pre-filled with the sludge collected at the sewage end treatment plant before operation. The raw water FW is supplied to the anaerobic tank 1 and the operation is started so that the effluent discharged from the anaerobic tank 1 flows into the anoxic tank 2 through the upper part of the MLSS concentration means 12. The effluent discharged from the anaerobic tank 1 forms a downward flow by the action of gravity so that a hole (not shown) of the MLSS concentrator 12 and / or a hole (not shown) of the MLSS concentrator 12 and the inner wall And flows down to the lower portion of the MLSS concentration means 12. [ However, since the lower layer liquid of the MLSS concentration means 12 is difficult to form an upward flow due to the action of gravity, it is difficult to move to the upper portion of the MLSS concentration unit 12. As a result, the MLSS is further concentrated in the lower layer liquid based on the MLSS concentration unit 12, and the upper layer liquid maintains a low MLSS concentration.

There is no dissolved oxygen in the anoxic tank 2, the stirrer 5 can be installed, and oxygen is not supplied.

1, surplus sludge (that is, contained in the lower layer liquid) accumulated in the anoxic tank 2 is periodically discharged to the outside in order to keep the concentration of the microorganisms in the for-treatment water constant, . Particularly, the reason why the excess sludge is discarded from the anoxic tank 2 is that MLSS concentration of the bottom liquid of the anoxic tank 2 is the highest among all the reaction tanks. This is distinguished from a conventional wastewater treatment apparatus for disposing excess sludge in a membrane separation aerosol tank or a degassing tank with the highest MLSS concentration.

(4) Membrane separation aerobic tank (3)

The membrane separation aerobic tank 3 includes an aerobic tank 3-1 disposed at the rear end of the anoxic tank 2, a separation membrane tank 3-2 disposed at the rear end of the aerobic tank 3-1, And a movable baffle or stationary baffle 13 disposed between the separator tank 3-2.

The effluent discharged from the anoxic tank 2 flows into the oxic tank 3-1. The effluent discharged from the anoxic tank 2, that is, the water to be treated in the aerobic tank 3-1 contains a large amount of ammonia nitrogen, and this ammonia nitrogen is converted into nitrate nitrogen by microbial action in the oxic tank 3-1 Oxidized (this is called biological nitrification).

Phosphorus released from the anaerobic tank 1 is removed by a biologically excessive intake reaction using oxygen as a final electron acceptor in the oxic tank 3-1.

Oxygen is supplied to the oxic tank 3-1, which is not separately supplied from the outside, but is supplied from the separation membrane tank 3-2.

A separation membrane module 7 is provided in the separation membrane tank 3-2 and the separation membrane module 7 may include at least one separation membrane 7a or a laminate thereof and an air diffuser 7b.

In the separation membrane tank 3-2, the untreated water is separated into sludge and treated water TW (that is, solid-liquid separated) by the separation membrane module 7, and ammonia nitrogen, which has not been treated in the oxic tank 3-1, Is further converted to acidic nitrogen, and the phosphorus not removed in the oxic tank (3-1) is further removed by an excessive intake reaction. The treated water TW having passed through the membrane module 7 is discharged or reused through the treated water discharge pipe 10.

Oxygen flows from the outside into the separation membrane bath (3-2). Specifically, air or oxygen discharged from the blower 11 flows into the separation membrane 7a through the air diffuser 7b. The air or oxygen is primarily used for cleaning the separation membrane 7a to control membrane contamination. Secondarily, oxygen is supplied to the aerobic tank 3-1 in an indirect manner in the form of dissolved oxygen, And an excessive intake reaction occurs smoothly. Specifically, air or oxygen introduced into the membrane separation tank 3-2 through the diffusion column 7b increases dissolved oxygen in the separation membrane separation tank 3-2. The concentration of dissolved oxygen in the membrane separation tank 3-2 is generally higher than the concentration required for the biological nitrification reaction and the excessive intake reaction because the amount of air or oxygen aeration tends to be excessively set for cleaning purpose. Thereafter, excessive dissolved oxygen in the separation membrane tank 3-2 is supplied to the oxic tank 3-1. Therefore, in the oxic tank 3-1 without additional additional air or oxygen, biological nitrification and excess intake Dissolved oxygen suitable for the reaction can be maintained. On the other hand, the concentration of dissolved oxygen is high in the separation membrane tank 3-2 and low in the oxic tank 3-1.

The separation membrane 7a may be an immersion type or an external pressure type and may be a hollow fiber, a flat plate, a tubular, a spiral-wound, or the like depending on its shape. The separation membrane 7a may be made of a material such as PP (polypropylene), PE (polyethylene), PES (polyethyl sulfone), PVDF (polyvinylidene difluoride), PTFE (polytetrafluoroethylene) Can be used. When the separation membrane 7a is classified according to the pore size, the microfiltration (pore size> 50 nm), UF (ultra filtration, pore size = 2-50 nm) or nano filtration ≪ 2 nm).

The water to be treated which has been discharged from the anoxic tank 2 and introduced into the membrane separation aeration tank 3 (concretely, the oxic tank 3-1) flows through the space above the upper end of the movable baffle or the fixed baffle 13, And circulates between the oxic tank 3-1 and the membrane separation tank 3-2. (I) the MLSS concentration in the membrane separation aeration tank 3 is uniformly maintained, and the sludge biasing phenomenon is minimized by the circulation of the for-treatment water, thereby making it possible to increase the uniformity of the membrane separation in the separation membrane bath 3-2, (ii) the oxygen required for the oxic tank 3-1 is not directly injected from the outside into the oxic tank 3-1, so that the blowing amount of the blower 11 can be reduced to improve the energy efficiency, (iii) 1) to the anoxic tank 2 can be minimized, thereby avoiding the use of a separate degassing tank.

The water to be treated in the oxic tank (3-1) has an MLSS concentration similar to that of the supernatant of the anoxic tank (2). The MLSS concentration in the separation membrane bath 3-2 is lower than the MLSS concentration in the oxic tank 3-1 and the MLSS concentration in the separation tank 3-2 And is also very low compared to the MLSS concentration in the membrane separation aerosol of conventional wastewater treatment systems. When the MLSS concentration is low, the amount of required air cleaning decreases and the permeate flux also increases. In addition, when the MLSS concentration is low, generation of substances such as extracellular polymeric substances (EPS), which exert a great influence on membrane contamination, is remarkably lowered, which is one of the biggest problems of the conventional wastewater treatment apparatus, Can be prevented.

The for-treatment water flowing into the membrane separation tank 3-2 from the aerobic tank 3-1 through the space below the lower end of the movable baffle or fixed baffle 13 is discharged to the separation membrane tank 3-2 Is separated into treated water (TW) and sludge by the installed separation membrane (7a). Specifically, the sludge does not pass through the separation membrane 7a and is concentrated inside the separation membrane tank 3-2. The degree of concentration of the sludge in the separation membrane tank 3-2 is determined by the flow rate of the sludge conveyed from the aerobic tank 3-1 disposed at the front end of the separation membrane tank 3-2 to the anoxic tank 2.

Dissolved oxygen is contained in the water to be treated flowing into the oxic tank 3-1 from the separation membrane tank 3-2 through the space on the upper end of the movable baffle or the fixed baffle 13, The microorganisms contained in the water to be treated in the aerobic tank 3-1 oxidize ammonia nitrogen to nitrate nitrogen by using the dissolved oxygen, and an excessive intake reaction occurs.

A movable baffle or stationary baffle 13 is arranged to be spaced a predetermined distance from the bottom of the membrane separation aeration tank 3. The distance between the lower end of the mobile baffle or stationary baffle 13 and the bottom of the membrane separation aerosol can be adjusted by adjusting the height of the mobile baffle or stationary baffle 13, -1) and the membrane separation tank 3-2 and the amount of oxygen flowing into the oxic tank 3-1 can be adjusted.

The wastewater treatment apparatus 100 may further include a chemical injection facility (not shown) for inputting at least one of an external carbon source and a coagulant to the anoxic tank 2. The drug injection system may include a drug reservoir, a conduit communicating with the drug reservoir, and a pump communicating with the conduit.

The external carbon source may include at least one selected from the group consisting of methanol, acetic acid, and methane.

The flocculant may comprise at least one selected from the group consisting of alum, polyaluminum chloride (PAC) and ferric chloride.

Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited to these embodiments.

Example

Manufacturing example  1: Fabrication of experimental equipment

The experimental apparatus of FIG. 2 having a configuration similar to (# 1 device) or different (# 2 to # 4 device) configuration of the wastewater treatment apparatus of FIG. 1 was produced. Specifically, the # 1 apparatus has the MLSS concentration unit 12, but the # 2 to # 4 apparatus does not have the MLSS concentration unit. Thus, except for the presence or absence of the MLSS concentration means 12, the # 1 device and the # 2 to # 4 devices have the same configuration. The treated wastewater treatment capacity of the experimental apparatus was 154 liter / day, and the specific composition is shown in Table 1 below. In Fig. 2, the same reference numerals as in Fig. 1 shown above refer to the same component or a part of the same component.

Component Volume material Anaerobic (One) - Size: 1.53 liter
- Retention time: 1.5 hr
- stirrer installed acryl Anoxic tank (2) - Size: 1.53 liter
- Retention time: 1.5 hr
- MLSS concentration apparatus (grid type porous plate: 160 mm × 130 mm × 20 mm, pore diameter = 5 mm, porosity = 40%) was installed
- stirrer installed acryl Membrane separation pump (3) - Size: 4.1 liter
- Retention time: 4.0 hr
- Location of movable baffle: The lower part is 8cm away from the floor, and the upper part is 8cm away from the water surface.
- Average pore size of the separator (econity, HDPE): 0.4 탆
- Average water permeability of membrane: 6.39 liter / m ² · hr
- stirrer installed
- Installed an agency acryl The first conveying line (8) - Flow rate: 1Q relative to raw water flow (Q) - The second conveying line (9) - Flow rate: 2Q relative to the raw water flow rate (Q) -

Example  1 and Comparative Example  1 ~ 3: Using experimental equipment Wastewater treatment (Out Carbon source  And no coagulant)

The experimental apparatus manufactured in Preparation Example 1 was installed in a sewage water treatment plant and treated with raw water having the characteristics shown in Table 2 below. Here, the measurement method of each evaluation item is additionally shown in Table 2.

Evaluation items Concentration range (mg / L) Average concentration (mg / L) How to measure TSS
(total suspended solids) 189.6 to 209.5 198.2 Measured using a drying oven (103-105 ° C) and a Muffle Furnace (550 ° C) according to the Gravimetric method (Standard Methods, 240). VSS
(volatile suspended solids) 152.5 to 169.2 164.9 TCOD
(total chemical oxygen demand) 372.7 to 399.5 388.3 Measured with Standard Methods (Closed Reflux, Titrimetric, 5220 C.). SCOD
(soluble chemical oxygen demand) 72.4-79.5 75.71 Filtered with GF / C filter and measured with Standard Methods (Closed Reflux, Titrimetric, 5220 C.). TN (total nitrogen) 38.3 to 43.5 41.2 Measured by water pollution process test method (Ultraviolet absorption spectrophotometer, ES 04358.1). TKN
(total kjeldahl nitrogen) 37.6 to 45.6 43.2 Standard Methods (Semi-Micro-Kjeldahl method, 4500-Norg C.). Ammonia nitrogen (NH ₄ ⁺ -N) 34 to 38.8 36.4 Measured by the Nessler method. Nitrate nitrogen (NO ₃ ^- N) 0.1 to 0.3 0.2 Measured by the method of water pollution process (absorption spectrophotometry, brucene method, ES 04361.2). Nitrite nitrogen (NO ₂ ^- N) 0.1 to 0.3 0.1 Measured by water pollution process test method (absorption spectrophotometry, ascorbic acid reduction method, ES 04362.1). TP (total phosphorus) 6.2 to 6.9 6.5 Measured by water pollution process test method (absorption spectrophotometry, ascorbic acid reduction method, ES 04362.1). Phosphorous phosphorus (PO ₄ ^{3 -} -P) 1.8 to 2.7 2.4 Measured by water pollution process test method (absorption spectrophotometry, ascorbic acid reduction method, ES 04360.2).

Specifically, after the experiment apparatus of FIG. 2 was operated for 9 months, raw water introduced into each experimental apparatus, treated water of each reaction tank, and treated water finally produced in each experimental apparatus were collected, the MLSS, TCOD, TN, NH ₄ ⁺ -N, NO ₃ contained in the treated water can be treated and ^- -N, TP and PO ₄ ^{3 -} and the concentration of each -P measured, the results are shown in Table 3 . In addition, PO ₄ ^{3 -} shows the density of the -N 3 and 4 ^respectively and the concentration of NO ₃ -P. 3 and 4, the results of the # 1 apparatus are shown in Embodiment 1, and the results of # 2 to # 4 apparatus are shown in Comparative Examples 1 to 3, respectively.

Evaluation items Collection point # 1 device
(Example 1) # 2 device
(Comparative Example 1) # 3 device
(Comparative Example 2) # 4 device
(Comparative Example 3) MLSS concentration
(mg / L) Anaerobic tank (1) 6,170 1,865 3,986 5,230 Anoxic tank (2)
(Upper layer solution / lower layer solution) 3,110 / 8,612 2,225 5,425 8,140 Membrane separation aerobic tank (3) 2,605 2,750 5,908 8,825 TCOD concentration
(mg / L) Enemy (FW) 389.7 Treated water (TW) 14.0 14.0 14.6 14.3 Removal efficiency (%) 96.4 96.4 96.3 96.3 TN concentration
(mg / L) Enemy (FW) 41.2 Treated water (TW) 5.1 6.2 5.9 5.6 Removal efficiency (%) 87.7 85.0 85.6 86.5 NH ₄ ⁺ -N concentration
(mg / L) Enemy (FW) 36.4 Treated water (TW) 1.2 1.4 1.4 1.3 Removal efficiency (%) 96.7 96.3 96.1 96.3 NO ₃ ^- N concentration
(mg / L) Enemy (FW) 0.2 Treated water (TW) 3.9 5.3 4.4 3.9 TP concentration
(mg / L) Enemy (FW) 6.6 Treated water (TW) 1.0 1.4 1.4 1.5 Removal efficiency (%) 85.1 79.0 78.0 76.6 PO ₄ ^{3 -} -P concentration
(mg / L) Enemy (FW) 2.4 Treated water (TW) 0.8 1.1 1.1 1.2 Removal efficiency (%) 68.4 55.4 55.2 50.7

Referring to Table 3, the MLSS concentration of the membrane separation aeration tank 3 was the lowest among # 1 to # 4 devices (Example 1). In addition, the nitrogen and phosphorus removal efficiencies were highest in the # 1 apparatus (Example 1). In particular, comparing # 1 and # 4 devices with similar MLSS concentrations in the anoxic tank (2), the # 1 device showed higher nitrogen removal efficiency than the # 4 device. In addition, the # 1 apparatus showed higher nitrification efficiencies than the # 2 to # 4 apparatuses despite the low MLSS concentration of the membrane separation aeration tank 3, It was indirectly proved that the concentration was not a problem in nitrification treatment.

Referring to FIG. 3, the concentration of PO ₄ ^{3 -} -P in the anaerobic tank 1 was highest in the case of Example 1 (# 1 apparatus). Since the efficiency of the excessive intake reaction in the membrane separation anoxic tank 3 is proportional to the efficiency of the phosphorus release reaction in the anaerobic tank 1, the result of FIG. 3 is the same as that of Example 1 (# 1 apparatus) This is in agreement with the results shown in Table 3, which shows the highest removal efficiency.

4, the concentration of nitrate nitrogen (NO ₃ ^- N) in the anoxic tank 2 is kept lowest in the case of Example 1, and the negative influence of nitrate nitrogen on the anaerobic tank 1 is the least appear. These results are in agreement with the results of Table 3 in which the efficiency of the phosphorus intake reaction was the highest in the case of Example 1 and the excess was finally obtained.

Example  2 and Comparative Example  4 ~ 6: Using experimental equipment Wastewater treatment (Out Carbon source  And coagulant loading)

Same as Example 1 and Comparative Examples 1 to 3 except that methanol and polyaluminum chloride (PAC) were added to the anoxic tank (2) at a rate of 1.5 ml / day and 5 ml / day, respectively, , The raw water flowing into each experimental apparatus, the water to be treated in each reaction tank and the treatment water finally produced in each of the experimental apparatuses are collected, and then the water contained in the raw water, the water to be treated, MLSS, TCOD, TN, NH ₄ ⁺ -N, NO ₃ ^- -N, TP and PO ₄ ^{3 -} -P measures the concentration of the results are shown in Table 4 below. In addition, PO ₄ ^{3 -} -N concentrations of the indicated 5 and 6 ^respectively and the concentration of NO ₃ -P. 5 and 6, the results of the # 1 apparatus are shown in Embodiment 2, and the results of the # 2 to # 4 apparatus are shown in Comparative Examples 4 and 6, respectively.

Evaluation items Collection point # 1 device
(Example 2) # 2 device
(Comparative Example 4) # 3 device
(Comparative Example 5) # 4 device
(Comparative Example 6) MLSS concentration
(mg / L) Anaerobic tank (1) 6,170 1,865 3,986 5,230 Anoxic tank (2)
(Upper layer solution / lower layer solution) 3,110 / 8,612 2,225 5,425 8,140 Membrane separation aerobic tank (3) 2,605 2,750 5,908 8,825 TCOD concentration
(mg / L) Enemy (FW) 383.2 Treated water (TW) 14.0 14.6 14.7 14.5 Removal efficiency (%) 96.3 96.2 96.2 96.2 TN concentration
(mg / L) Enemy (FW) 41.5 Treated water (TW) 1.0 2.9 2.0 1.1 Removal efficiency (%) 97.6 93.0 95.1 97.3 NH ₄ ⁺ -N concentration
(mg / L) Enemy (FW) 36.6 Treated water (TW) 0.1 1.5 1.0 0.4 Removal efficiency (%) 99.8 96.0 97.4 98.9 NO ₃ ^- N concentration
(mg / L) Enemy (FW) 0.2 Treated water (TW) 0.1 1.0 1.0 0.5 TP concentration
(mg / L) Enemy (FW) 6.6 Treated water (TW) 0.1 0.5 0.8 0.9 Removal efficiency (%) 97.9 92.0 87.8 85.7 PO ₄ ^{3 -} -P concentration
(mg / L) Enemy (FW) 2.4 Treated water (TW) 0.1 0.4 0.7 0.8 Removal efficiency (%) 98.6 82.9 71.0 65.2

Referring to Table 4, the MLSS concentration of the membrane separation aeration tank 3 was the lowest among # 1 to # 4 devices (Example 2). In addition, the nitrogen and phosphorus removal efficiencies were highest in the # 1 apparatus (Example 2). In particular, when comparing # 1 devices and # 4 devices with similar MLSS concentrations of the anoxic tank 2, the # 1 device has a slightly higher nitrogen removal efficiency than the # 4 device, but the phosphorus removal efficiency is much higher Respectively. The # 1 apparatus, which is a wastewater treatment apparatus according to an embodiment of the present invention, showed that TN and TP of the finally produced water were at levels of 1.0 mg / L and 0.1 mg / L, respectively.

Referring to FIG. 5, the PO ₄ ^{3 -} -P concentration of the anaerobic tank 1 was highest in the case of Example 2 (# 1 apparatus). Since the efficiency of the excessive intake reaction in the membrane separation aeration tank 3 is in proportion to the efficiency of the phosphorus release reaction in the anaerobic tank 1, the result of FIG. 5 is the same as that of Example 2 (# 1 apparatus) This is consistent with the results in Table 4, which shows the highest removal efficiency.

6, the concentration of nitrate nitrogen (NO ₃ ^- N) in the anoxic tank 2 is kept lowest in the case of Example 2, and the negative influence of nitrate nitrogen on the anaerobic tank 1 is the least appear. These results are consistent with the results of Table 4, which shows the highest efficiency of the excessive intake response in Example 2.

Example  3: In the filtration device MLSS  Interferences according to concentration Foreclosure  Change test

A filtration apparatus having the constitution of Fig. 7 was produced. The filtration apparatus of Fig. 7 has a separation membrane module 7 including a separation membrane 7a and an aeration tube 7b, a process water discharge pipe 10, and a blower 11.

The specific configuration of the filtration apparatus manufactured is shown in Table 5 below. In Fig. 7, the same reference numerals as in Fig. 1 shown above refer to the same component or a part of the same component.

Component Volume material The membrane module (7) - Size: 20 liter
- Average pore size of the separator (Econity, HDPE): 0.4 탆
- average permeability of membrane: 32 to 34 liter / m ² · hr
- Installed an agency
- Temperature of the water to be treated: 20 ° C acryl Blowers (11) - Cleaning air volume: 20 liter / min -

Experiments were carried out for 60 days by treating the wastewater with MLSS concentrations of 3000, 6000 and 9000 mg / L, respectively, using the filtration apparatus prepared above, and separating the wastewater into treated water (TW) and sludge. The intermembrane pressure differential was measured periodically when treating the respective wastewater with different MLSS concentrations, and the results are shown graphically in FIG. Here, the inter-membrane pressure difference means the pressure indicated on the pressure gauge p disposed between the separation membrane 7a and the pump P.

Referring to FIG. 8, the higher the MLSS concentration in the wastewater, the faster the disturbance rate of the inter-membrane pressure difference.

The viscosity of each wastewater and the crossflow velocity in the membrane module 7 were measured when treating the wastewater. The results are shown in Table 6 below. Here, the cross flow rate means the flow velocity of the fluid flowing upward in the membrane module 7 when the air discharged from the blower and injected into the separation membrane 7a through the diffuser 7b pushes up the wastewater. Here, the viscosity and the cross flow rate were measured using a viscosity measuring device (TDKI SANGYO CO., LTD., TVC-6) and a flow rate measuring device (SWOFFER, 2100-LX).

MLSS concentration (mg / L) Viscosity (mPa · S) Cross Flow Rate (m / s) 3,000 4.4 0.71 6,000 8.6 0.53 9,000 11.6 0.40

Referring to Table 6, as the MLSS concentration increases, the viscosity of the wastewater increases and the cross flow rate decreases. As the MLSS concentration increases, the cross flow rate decreases because the higher the MLSS concentration is, the lower the removal effect of membrane contaminants due to air cleaning, and the higher the intermembrane pressure difference is.

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, . Accordingly, the scope of protection of the present invention should be determined by the appended claims.

100: wastewater treatment apparatus 1: anaerobic tank
2: anoxic tank 3: membrane separation aeration tank
3-1: Aerobic tank 3-2: Membrane tank
4, 5, 6: stirrer 7: separator module
7a: separator 7b: diffuser 7b:
8: First conveying pipe 9: Second conveying pipe
10: treated water discharge pipe 11: blower
12: MLSS concentration means 13: baffle
FW: enemy FT: raw water tank
TW: Processed number M: Motor
P: pump TT: treated water tank

Claims (9)

a biological phosphorus release reaction is carried out in an anaerobic state where raw water containing at least one microorganism and organic matter including dPAO (denitrifying phosphorus accumulating organism) is introduced, and the organic matter is treated with polyhydroxybutyrate (PHB) An anaerobic tank stored in the cells of the dPAO in the form of polyhydroxyvalerate (PHV);
An anoxic tank in which the biological nitrification reaction of the nitrate nitrogen proceeds with use of the organic matter stored in the PHB / PHV form in the cells of the dPAO in an anoxic state, where the effluent discharged from the anaerobic tank and nitrate nitrogen-containing sludge are introduced;
A first conveyance pipe for conveying a part of the activated sludge discharged from the anoxic tank to the anaerobic tank;
A membrane separation aerobic tank for separating the effluent discharged from the anoxic tank into treated water and sludge, a biological nitrification reaction and an excessive intake reaction proceed in a state where oxygen is supplied to the effluent discharged from the anoxic tank; And
And a second transport pipe for transporting part of the activated sludge discharged from the membrane separation aeration tank to the anoxic tank,
Wherein the anoxic tank is provided with MLSS concentration means for separating the for-treatment water into a supernatant having a low MLSS concentration and a supernatant having a high MLSS concentration. delete The method according to claim 1,
Wherein the MLSS concentration means is a porous plate or non-porous plate disposed in the anoxic tank for bisecting the space in the anoxic tank, and for removing nitrogen and phosphorus. The method of claim 3,
Wherein the porous plate has a diameter, a thickness, and a porosity of 2 to 10 mm, 2 to 30 mm, and 30 to 80%, respectively. The method according to claim 1,
The membrane separation aeration tank is configured to remove nitrogen and phosphorus contained in an aerobic tank disposed at a rear stage of the anoxic tank, a separation membrane tank disposed at a rear stage of the oxic tank, and a movable baffle or a fixed baffle disposed between the oxi- The wastewater treatment device. 6. The method of claim 5,
Oxygen is supplied from the outside to the separation membrane bath, oxygen is supplied from the separation membrane bath to the oxic tank, and the water to be treated which is discharged from the anoxic tank and introduced into the membrane separation aeration tank is supplied to the mobile baffle or the fixed baffle, And the nitrogen and phosphorus circulating between the aerobic basin and the membrane separation tank through a space below the aerobic tank and the lower end thereof. 6. The method of claim 5,
Wherein the biological nitrification reaction and the excessive intake reaction proceed in the aerobic basin, and in the separation membrane bath, the for-treatment water is separated from the treated water and the sludge by nitrogen and phosphorus. The method according to claim 1,
Further comprising a chemical injector for injecting at least one of an external carbon source and an aggregating agent into the anoxic tank. 9. The method of claim 8,
Wherein the external carbon source comprises at least one selected from the group consisting of methanol, acetic acid and methane, and wherein the flocculant is selected from nitrogen and phosphorus containing at least one selected from the group consisting of alum, polyaluminum chloride (PAC) The wastewater treatment apparatus comprising:

Images