KR101380218B1 - Master batch and product for using the same - Google Patents

Master batch and product for using the same Download PDF

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KR101380218B1
KR101380218B1 KR1020120074964A KR20120074964A KR101380218B1 KR 101380218 B1 KR101380218 B1 KR 101380218B1 KR 1020120074964 A KR1020120074964 A KR 1020120074964A KR 20120074964 A KR20120074964 A KR 20120074964A KR 101380218 B1 KR101380218 B1 KR 101380218B1
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masterbatch
polyethylene
density polyethylene
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KR20140008044A (en
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양지유
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미르하이텍 주식회사
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/22Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B11/00Making preforms
    • B29B11/06Making preforms by moulding the material
    • B29B11/10Extrusion moulding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00Making granules
    • B29B9/02Making granules by dividing preformed material
    • B29B9/06Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/01Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/14Glass
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C08L67/03Polyesters derived from dicarboxylic acids and dihydroxy compounds the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10Homopolymers or copolymers of propene
    • C08J2323/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2467/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2467/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C08J2467/03Polyesters derived from dicarboxylic acids and dihydroxy compounds the dicarboxylic acids and dihydroxy compounds having the hydroxy and the carboxyl groups directly linked to aromatic rings

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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

본 발명은 분쇄 가공 후 800 ~ 1,100℃로 가열 소성하여 부피를 팽창시켜서 분쇄한 질석(vermiculite)과 진주암(perlite) 중 어느 하나 또는 모두의 혼합물 10 ~ 85중량%와, 폴리뷰틸렌테레프랄레이트(PolybutyleneTerephthalate,PBT), ABS(Acrylonitrile, Butadiene, Styrene), nylon, PC/ABS((polycarbonate,Acrylonitrile, Butadiene, Styrene), PC(Polycarbonate), 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET), 폴리프로필렌(polypropylene, PP), 폴리올레핀(polyolefin)류에 속하는 열가소성수지, 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), LDPE(Low Density Polyethylene), LLDPE(Linear low-density polyethylene) 중에서 단독 또는 같은 계열에 속하는 다수의 혼합물 10 ~ 85중량%와, 산화방지제 0.01 ~ 0.5중량%와, 유동파라핀오일 0.1 ~ 5중량%를 혼합하고 교반하여 블랜딩하여, 압출시키는 것을 특징으로 하는 마스터뱃치에 관한 것이다. 본 발명에 따르면, 경량이면서도 고강도 및 내충격성이 뛰어나도록 하고, 친환경적이면서 원가 절감이 가능하도록 할 수 있다.The present invention is 10 to 85% by weight of a mixture of any one or both of vermiculite and perlite, which is pulverized by heating and calcining at 800 to 1,100 ° C. after crushing to expand the volume, and polybutylene terephthalate (Polybutylene Terephthalate, PBT), ABS (Acrylonitrile, Butadiene, Styrene), nylon, PC / ABS ((polycarbonate, Acrylonitrile, Butadiene, Styrene), PC (Polycarbonate), Polyethylene Terephthalate (PET), Polypropylene, PP), thermoplastics belonging to polyolefins, polyethtylene (PE), high density polyethylene (HDPE), low density polyethylene (LDPE), and linear low-density polyethylene (LLDPE) Mixture of 10 to 85% by weight, 0.01 to 0.5% by weight of antioxidant, 0.1 to 5% by weight of liquid paraffin oil is mixed, stirred and blended to extrude the masterbatch, characterized in that A In accordance with the present invention, light-weight and yet to be highly high strength and impact resistance, can be environmentally friendly, yet to allow cost reduction.

Description

마스터뱃치 및 이를 이용하여 제조되는 제품{Master batch and product for using the same}Master batch and product manufactured using the same {Master batch and product for using the same}

본 발명은 마스터뱃치 및 이를 이용하여 제조되는 제품에 관한 것으로서, 보다 상세하게는 경량이면서도 고강도, 내열성, 단열성, 방음성 및 내충격성이 뛰어나도록 하고, 친환경적이면서 원가 절감이 가능하도록 하는 마스터뱃치 및 이를 이용하여 제조되는 제품에 관한 것이다.The present invention relates to a master batch and a product manufactured using the same, and more specifically, to a lightweight, high strength, heat resistance, heat insulation, soundproofing and impact resistance, the master batch to enable eco-friendly and cost reduction and use thereof It relates to a product manufactured by.

일반적으로, 마스터뱃치(master batch)라 함은, 원료 고무에 배합제를 혼합하는 공정에서 배합제를 미리 처방보다 높은 농도로 섞어 반죽한 것으로 고무에 혼입하여 각 배합제의 계량을 정확하게 할 수 있고, 분산을 좋게 하며, 작업 중의 흩날림도 방지할 수 있으며, 이러한 고무 제품 뿐만 아니라, 플라스틱의 성형가공 시, 안료의 분산을 좋게 하는데에도 사용된다.In general, a master batch is a process of mixing a compounding agent with a higher concentration than a prescription in the process of mixing the compounding agent with the raw rubber, and mixing the compounding agent into the rubber to accurately measure each compounding agent. It can be used to improve the dispersion of pigments during the molding process of plastics as well as such rubber products.

이러한 마스터뱃치는 플라스틱 등의 성형가공시 가공제품의 성질이나 특성에 미치는 영향이 상당하다. 따라서, 최근 경량의 고강도, 내열성, 단열성, 방음성 및 내충격성이 뛰어난 마스터뱃치의 개발이 필요하게 되었다.This masterbatch has a significant effect on the properties and properties of processed products during molding processing of plastics and the like. Therefore, in recent years, development of a masterbatch excellent in light weight, high strength, heat resistance, heat insulation, sound insulation and impact resistance has been required.

또한, 종래의 마스터뱃치는 제조함에 있어서 많은 화석연료의 사용을 필요로 하고, 이로 인해 많은 양의 이산화탄소를 배출시키는 원인이 되었다. 따라서, 친환경적이면서 원가 절감형의 마스터뱃치와 이를 이용한 제품의 개발이 필요하게 되었다.In addition, the conventional masterbatch requires the use of a large amount of fossil fuel in the manufacturing, which causes a large amount of carbon dioxide emissions. Therefore, it is necessary to develop eco-friendly and cost-saving master batches and products using the same.

상기한 바와 같은 종래의 문제점을 해결하기 위하여, 본 발명은 경량의 고강도, 내열성, 단열성, 방음성 및 내충격성이 뛰어나고, 친환경적이면서 원가 절감이 가능하도록 하는 마스터뱃치 및 이를 이용한 제품을 개발하는데 목적이 있다.In order to solve the conventional problems as described above, an object of the present invention is to develop a masterbatch and a product using the same, which are excellent in light weight, high strength, heat resistance, heat insulation, sound insulation and impact resistance, and are environmentally friendly and cost-effective. .

본 발명의 다른 목적들은 이하의 실시예에 대한 설명을 통해 쉽게 이해될 수 있을 것이다.Other objects of the present invention will become readily apparent from the following description of the embodiments.

상기한 바와 같은 목적을 달성하기 위해, 본 발명의 일 측면에 따르면, 마스터뱃치에 있어서, 분쇄 가공 후 800 ~ 1,100℃로 가열 소성하여 부피를 팽창시켜서 분쇄한 질석(vermiculite)과 진주암(perlite) 중 어느 하나 또는 모두의 혼합물 10 ~ 85중량%와, 폴리뷰틸렌테레프랄레이트(PolybutyleneTerephthalate,PBT), ABS(Acrylonitrile, Butadiene, Styrene), nylon, PC/ABS((polycarbonate,Acrylonitrile, Butadiene, Styrene), PC(Polycarbonate), 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET), 폴리프로필렌(polypropylene, PP), 폴리올레핀(polyolefin)류에 속하는 열가소성수지, 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), LDPE(Low Density Polyethylene), LLDPE(Linear low-density polyethylene) 중에서 단독 또는 같은 계열에 속하는 다수의 혼합물 10 ~ 85중량%와, 산화방지제 0.01 ~ 0.5중량%와, 유동파라핀오일 0.1 ~ 5중량%를 혼합하고 교반하여 블랜딩하여, 압출시키는 것을 특징으로 하는 마스터뱃치가 제공된다.In order to achieve the object as described above, according to an aspect of the present invention, in the master batch, after pulverizing processing by heating and calcining at 800 ~ 1,100 ℃ to expand the volume of crushed vermiculite and perlite (perlite) 10 to 85% by weight of any or all of the mixture, polybutylene terephthalate (PBT), ABS (Acrylonitrile, Butadiene, Styrene), nylon, PC / ABS (polycarbonate, Acrylonitrile, Butadiene, Styrene) , Polycarbonate (PC), polyethylene terephthalate (PET), polypropylene (PP), thermoplastic resins belonging to polyolefins, polyethylene (polyethtylene, PE), HDPE (High Density Polyethylene), LDPE (Low) Density Polyethylene), LLDPE (Linear low-density polyethylene) mixed 10 to 85% by weight of a plurality of mixtures alone or in the same series, 0.01 to 0.5% by weight antioxidant and 0.1 to 5% by weight of liquid paraffin oil By stirring and by blending a master batch comprising a step of extrusion, is provided.

상기 마스터뱃치는, 상기 가열 소성하여 팽창시켜서 분쇄할 때의 질석 또는 진주암의 입자 크기가 1nm ~ 0.5mm일 수 있다.The master batch may have a particle size of 1 nm to 0.5 mm of vermiculite or pearlite when it is swelled by expansion by heating and calcining.

상기 마스터뱃치는, 상기 블랜딩 전에 칼라 무기 안료를 0.01~0.5중량% 부가하여 블랜딩하여 압출될 수 있다.The master batch may be extruded by blending with 0.01 to 0.5% by weight of a color inorganic pigment before the blending.

상기 마스터뱃치는, 상기 블랜딩 전에 폐타이어 또는 폐고무 분말을 0.1~30중량% 부가하여 블랜딩하여 압출될 수 있다.The master batch may be extruded by blending 0.1-30% by weight of waste tire or waste rubber powder before blending.

본 발명의 다른 측면에 따르면, 상기 마스터배치 10 ~ 70중량%와, 폴리프로필렌(polypropylene, PP), 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET) 중에서 하나 또는 같은 계열에 속하는 다수의 혼합물 30 ~ 90중량%와, 유리장섬유 또는 합침된 유리장섬유 0 ~ 30중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형되는 것을 특징으로 하는 마스터뱃치를 이용하여 제조되는 드럼세탁기 터브가 제공된다.According to another aspect of the invention, the master batch 10 to 70% by weight, polypropylene (polypropylene, PP), polyethylene (polyethtylene, PE), HDPE (High Density Polyethylene), one of polyethylene terephthalate (PolyethyleneTerephthalate, PET) Or a mixture of 30 to 90% by weight of a plurality of mixtures belonging to the same series and 0 to 30% by weight of glass filament or glass fiber flocked together, or blended or extruded, and then put into an injection molding machine and formed into a pressure mold. Provided are drum washing machine tubs made using batches.

본 발명의 또 다른 측면에 따르면, 마스터배치를 이용하여 제조되는 전자동세탁기 맥동부재(pulsator)에 있어서, 상기 마스터배치 10 ~ 70중량%와, 폴리에틸렌테레프탈레이트(polyethyleneterephthalate, PET), 폴리프로필렌(polypropylene, PP), 폴리에틸렌(polyethtylene, PE) 중에서 하나 또는 모두의 혼합물 30 ~ 90중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형되는 것을 특징으로 하는 마스터뱃치를 이용하여 제조되는 전자동세탁기 맥동부재가 제공된다.According to another aspect of the invention, in a fully automatic washing machine pulsator manufactured using a masterbatch, 10 to 70% by weight of the masterbatch, polyethyleneterephthalate (PET), polypropylene (polypropylene, 30% to 90% by weight of a mixture of one or all of PP) and polyethylene (polyethtylene, PE), blended or extruded, and then injected into an injection molding machine. The member is provided.

본 발명의 또 다른 측면에 따르면, 마스터배치를 이용하여 제조되는 전자동 세탁기 베이스(base)에 있어서, 상기 마스터배치 10 ~ 70중량%와, 폴리프로필렌(polypropylene, PP), 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), LDPE(Low Density Polyethylene), LLDPE(Linear low-density polyethylene) 중에서 하나 또는 같은 계열에 속하는 다수의 혼합물 30 ~ 90중량%와, 유리장섬유 또는 합침된 유리장섬유 0 ~ 30중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형되는 것을 특징으로 하는 마스터뱃치를 이용하여 제조되는 전자동 세탁기 베이스가 제공된다.According to another aspect of the present invention, in a fully automatic washing machine base manufactured using a master batch, the master batch 10 to 70% by weight, polypropylene (polypropylene, PP), polyethylene (polyethtylene, PE), 30 to 90% by weight of a plurality of mixtures belonging to one or the same family of high density polyethylene (HDPE), low density polyethylene (LDPE) or linear low-density polyethylene (LDDPE), and glass filaments or impregnated glass filaments 0 to Provided is a fully automatic washing machine base manufactured by using a master batch characterized in that the blend is 30% by weight, blended or extruded, put into an injection molding machine and pressure molded.

본 발명의 또 다른 측면에 따르면, 마스터배치를 이용하여 제조되는 전자동 세탁기 볼(bowl)에 있어서, 상기 마스터배치 10 ~ 70중량%와, 폴리프로필렌(polypropylene, PP), 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), LDPE(Low Density Polyethylene), LLDPE(Linear low-density polyethylene) 중에서 하나 또는 같은 계열에 속하는 다수의 혼합물 30 ~ 90중량%와, 유리장섬유 또는 합침된 유리장섬유 0 ~ 30중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형되는 것을 특징으로 하는 마스터뱃치를 이용하여 제조되는 전자동 세탁기 볼이 제공된다.According to another aspect of the present invention, in a fully automatic washing machine bowl prepared using a masterbatch, the masterbatch 10 to 70% by weight, polypropylene (polypropylene, PP), polyethylene (polyethtylene, PE), 30 to 90% by weight of a plurality of mixtures belonging to one or the same family of high density polyethylene (HDPE), low density polyethylene (LDPE) or linear low-density polyethylene (LDDPE), and glass filaments or impregnated glass filaments 0 to Provided is a fully automatic washing machine ball manufactured by using a master batch characterized in that the mixture is blended or extruded 30% by weight, put into an injection molding machine and pressure molded.

본 발명의 또 다른 측면에 따르면, 마스터배치를 이용하여 제조되는 전자동 세탁기 탑커버(top cover)에 있어서, 상기 마스터배치 10 ~ 70중량%와, 폴리프로필렌(polypropylene, PP), 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), 폴리뷰틸렌테레프랄레이트(PolybutyleneTerephthalate,PBT), ABS(Acrylonitrile, Butadiene, Styrene), PC/ABS((polycarbonate,Acrylonitrile, Butadiene, Styrene), PC(Polycarbonate) 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET) 중에서 하나 또는 같은 계열에 속하는 다수의 혼합물 30 ~ 90중량%와, 유리장섬유 또는 합침된 유리장섬유 0 ~ 30중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형되는 것을 특징으로 하는 마스터뱃치를 이용하여 제조되는 전자동 세탁기 탑커버가 제공된다.According to another aspect of the present invention, in a fully automatic washing machine top cover manufactured using a masterbatch, the masterbatch 10 to 70% by weight, polypropylene (polypropylene, PP), polyethylene (polyethtylene, PE) ), HDPE (High Density Polyethylene), Polybutylene Terephthalate (PBT), ABS (Acrylonitrile, Butadiene, Styrene), PC / ABS ((polycarbonate, Acrylonitrile, Butadiene, Styrene), PC (Polycarbonate) Polyethylene 30 to 90% by weight of a mixture of terephthalate (polyethylene terephthalate (PET) in one or the same series, and 0 to 30% by weight of glass filament or combined glass filament are blended or extruded and injected into the injection molding machine Provided is a fully automatic washing machine top cover manufactured by using a master batch characterized in that the molding.

본 발명의 또 다른 측면에 따르면, 마스터배치를 이용하여 제조되는 전자동 세탁기 아웃터브(out-tub)에 있어서, 상기 마스터배치 10 ~ 70중량%와, 폴리프로필렌(polypropylene, PP) 30 ~ 90중량%와, 폴리에틸렌테레프탈레이 트( PolyethyleneTerephthalate , PET ), 유리장섬유 또는 합침된 유리장섬유 0 ~ 30중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형되는 것을 특징으로 하는 마스터뱃치를 이용하여 제조되는 전자동 세탁기 아웃터브가 제공된다.According to another aspect of the present invention, in a fully automatic washing machine out-tub manufactured using a masterbatch, the masterbatch 10 to 70% by weight, polypropylene (polypropylene, PP) 30 to 90% by weight and a polyethylene terephthalate-ray agent (PolyethyleneTerephthalate, PET), with a mixture of glass fiber or combining the glass fiber 0 to 30% by weight of blend or extrusion, followed by putting into an injection molding machine using a master batch, characterized in that the press-molding Provided is a fully automatic washing machine out manufactured.

본 발명의 또 다른 측면에 따르면, 마스터배치를 이용하여 제조되는 상자에 있어서, 상기 마스터배치 10 ~ 70중량%와, 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET), 폴리프로필렌(polypropylene, PP), 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), LDPE(Low Density Polyethylene), LLDPE(Linear low-density polyethylene) 중에서 하나 또는 같은 계열에 속하는 다수의 혼합물 30 ~ 90중량%와, 유리장섬유 또는 합침된 유리장섬유 0 ~ 30중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형되는 것을 특징으로 하는 마스터뱃치를 이용하여 제조되는 상자가 제공된다.According to another aspect of the invention, in a box manufactured using a masterbatch, 10 to 70% by weight of the masterbatch, polyethylene terephthalate (polyethylene terephthalate, PET), polypropylene (polypropylene, PP), polyethylene (polyethtylene) , PE), HDPE (High Density Polyethylene), LDPE (Low Density Polyethylene), LLDPE (Linear low-density polyethylene) 30 to 90% by weight of a plurality of mixtures belonging to the same or the same series, glass fiber or impregnated glass There is provided a box manufactured by using a master batch, characterized in that the blend of 0 to 30% by weight of long fibers is blended or extruded, and then put into an injection molding machine and press-molded.

본 발명의 또 다른 측면에 따르면, 마스터배치를 이용하여 제조되는 식품 저장 용기에 있어서, 상기 마스터배치 10 ~ 70중량%와, 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET), 폴리프로필렌(polypropylene, PP) 중에서 하나 또는 모두의 혼합물 30 ~ 90중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형되는 것을 특징으로 하는 마스터뱃치를 이용하여 제조되는 식품 저장 용기가 제공된다.According to another aspect of the present invention, in the food storage container manufactured using a masterbatch, 10 to 70% by weight of the masterbatch, polyethylene terephthalate (polyethylene terephthalate (PET), polypropylene (polypropylene, PP) one of Or 30 to 90% by weight of all mixtures are blended or extruded, the food storage container is prepared using a master batch characterized in that the injection molding machine is pressure-molded.

본 발명의 또 다른 측면에 따르면, 마스터배치를 이용하여 제조되는 파렛트(pallet)에 있어서, 상기 마스터배치 10 ~ 70중량%와, 폴리프로필렌(polypropylene, PP), 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), LDPE(Low Density Polyethylene), LLDPE(Linear low-density polyethylene) 중에서 하나 또는 같은 계열에 속하는 다수의 혼합물 30 ~ 90중량%와, 유리장섬유 또는 합침된 유리장섬유 0 ~ 30중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형되는 것을 특징으로 하는 마스터뱃치를 이용하여 제조되는 파렛트가 제공된다.According to another aspect of the present invention, in a pallet prepared using a masterbatch (pallet), the masterbatch 10 to 70% by weight, polypropylene (polypropylene, PP), polyethylene (polyethtylene, PE), HDPE ( 30 to 90% by weight of a plurality of mixtures belonging to one or the same series of High Density Polyethylene (LDPE), Low Density Polyethylene (LDPE) or Linear Low-density Polyethylene (LLDPE); Pallets are prepared using a master batch, characterized in that the mixture is blended or extruded, and put into an injection molding machine to be press-molded.

본 발명의 또 다른 측면에 따르면, 마스터배치를 이용하여 제조되는 자동차 엔진커버에 있어서, 상기 마스터배치 10 ~ 70중량%와, 폴리뷰틸렌테레프랄레이트(PolybutyleneTerephthalate,PBT), nylon, PC(Polycarbonate), 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET) 중에서 하나 또는 같은 계열에 속하는 다수의 혼합물 30 ~ 90중량%와, 유리장섬유 또는 합침된 유리장섬유 0 ~ 50중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형되는 것을 특징으로 하는 마스터뱃치를 이용하여 제조되는 자동차 엔진커버가 제공된다.According to another aspect of the present invention, in the automobile engine cover manufactured using a master batch, the master batch 10 to 70% by weight, polybutylene terephthalate (Polybutylene Terephthalate (PBT), nylon, PC (Polycarbonate) ), Blended or extruded by mixing 30 to 90% by weight of a plurality of mixtures belonging to one or the same series of polyethylene terephthalate (PET) and 0 to 50% by weight of glass filament or impregnated glass filament Provided is an automobile engine cover manufactured using a masterbatch, which is press-molded by a molding machine.

본 발명에 따른 마스터뱃치 및 이를 이용하여 제조되는 제품에 의하면, 경량이면서도 고강도, 내열성, 단열성, 방음성 및 내충격성이 뛰어나도록 하고, 친환경적이면서 원가 절감이 가능하도록 할 수 있다.According to the master batch and the product manufactured using the same according to the present invention, it is possible to make light weight, high strength, heat resistance, heat insulation, sound insulation and impact resistance, and environmentally friendly and cost-saving.

도 1은 본 발명에 따른 마스터뱃치의 제조 방법을 도시한 흐름도이고,
도 2는 본 발명에 따른 마스터뱃치를 이용한 제품을 나타낸 블록도이다.
1 is a flowchart illustrating a method of manufacturing a master batch according to the present invention,
2 is a block diagram showing a product using a master batch according to the present invention.

본 발명은 다양한 변경을 가할 수 있고, 여러 가지 실시예를 가질 수 있는 바, 특정 실시예들을 도면에 예시하고, 상세하게 설명하고자 한다. 그러나, 이는 본 발명을 특정한 실시 형태에 대해 한정하려는 것이 아니고, 본 발명의 기술 사상 및 기술 범위에 포함되는 모든 변경, 균등물 내지 대체물을 포함하는 식으로 이해 되어야 하고, 여러 가지 다른 형태로 변형될 수 있으며, 본 발명의 범위가 하기 실시예에 한정되는 것은 아니다. While the invention is susceptible to various modifications and alternative forms, specific embodiments thereof are shown by way of example in the drawings and will herein be described in detail. It is to be understood, however, that the invention is not to be limited to the specific embodiments, but is to be understood to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the invention, And the scope of the present invention is not limited to the following examples.

이하, 첨부된 도면을 참조하여 본 발명에 따른 실시예를 상세히 설명하며, 도면 부호에 관계없이 동일하거나 대응하는 구성요소에 대해서는 동일한 참조 번호를 부여하고, 이에 대해 중복되는 설명을 생략하기로 한다.Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings, wherein like or corresponding elements are denoted by the same reference numerals, and redundant explanations thereof will be omitted.

도 1은 본 발명에 따른 마스터뱃치의 제조 방법을 도시한 흐름도이고, 도 2는 본 발명에 따른 마스터뱃치를 이용한 제품을 나타낸 블록도이다.1 is a flowchart illustrating a method of manufacturing a master batch according to the present invention, Figure 2 is a block diagram showing a product using a master batch according to the present invention.

도 1 및 도 2에 도시된 바와 같이, 본 발명의 일 실시예에 따른 마스터뱃치(1)는 분쇄 가공 후 800 ~ 1,100℃로 가열 소성하여 부피를 팽창시켜서 분쇄한 질석(vermiculite)과 진주암(perlite) 중 어느 하나 또는 모두의 혼합물 10 ~ 85중량%와, 폴리뷰틸렌테레프랄레이트(PolybutyleneTerephthalate, PBT), ABS(Acrylonitrile, Butadiene, Styrene), nylon, PC/ABS((polycarbonate,Acrylonitrile, Butadiene, Styrene), PC(Polycarbonate), 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET), 폴리프로필렌(polypropylene, PP), 폴리올레핀(polyolefin)류에 속하는 열가소성수지, 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), LDPE(Low Density Polyethylene), LLDPE(Linear low-density polyethylene) 중에서 단독 또는 같은 계열에 속하는 다수의 혼합물 10 ~ 85중량%와, 산화방지제 0.01 ~ 0.5중량%와, 유동파라핀오일 또는 실리콘오일 0.1 ~ 5중량%를 혼합하고 교반하여 블랜딩하여, 압출시킨 것이다.As shown in Figure 1 and 2, the master batch 1 according to an embodiment of the present invention is pulverized by vermiculite and perlite (pulliteulite) pulverized by expanding the volume by heating and calcining at 800 ~ 1,100 ℃ after grinding processing 10 to 85% by weight of a mixture of any one or both of the above, polybutylene terephthalate (PBT), ABS (Acrylonitrile, Butadiene, Styrene), nylon, PC / ABS ((polycarbonate, Acrylonitrile, Butadiene, Styrene), PC (Polycarbonate), polyethylene terephthalate (PET), polypropylene (PP), thermoplastic resins belonging to polyolefins, polyethylene (polyethtylene, PE), HDPE (High Density Polyethylene), LDPE (Low Density Polyethylene), LLDPE (Linear low-density polyethylene) 10 to 85% by weight of a plurality of mixtures alone or in the same series, 0.01 to 0.5% by weight antioxidant, 0.1 to 5% by weight of liquid paraffin oil or silicone oil % It is mixed, stirred, blended, and extruded.

또한, 마스터뱃치(1)는 가열 소성하여 팽창시켜서 분쇄할 때의 질석 또는 진주암의 입자 크기가 1nm ~ 0.5mm일 수 있고, 블랜딩 전에 칼라 무기 안료를 0.01~0.5중량% 부가하여 블랜딩하여 압출될 수 있으며, 블랜딩 전에 폐타이어 또는 폐고무 분말을 0.1 ~ 30중량% 부가하여 블랜딩하여 압출될 수 있다.In addition, the master batch 1 may have a particle size of 1 nm to 0.5 mm of vermiculite or pearlite when thermally calcined to expand and pulverize, and may be extruded by adding 0.01 to 0.5% by weight of a color inorganic pigment before blending. In addition, 0.1 to 30% by weight of waste tire or waste rubber powder may be blended and extruded before blending.

이와 같은 마스터뱃치(1)에 대한 제조 방법을 구체적으로 설명하면 다음과 같다. 도 1에 도시된 바와 같이, 본 발명에 따른 마스터뱃치(1)에 대한 제조 방법은, 팽창 및 분쇄하는 단계(S11,S12)와, 블랜딩하는 단계(S13)와, 압출하는 단계(S14)를 포함할 수 있다.Referring to the manufacturing method for such a master batch 1 in detail. As shown in FIG. 1, the manufacturing method for the masterbatch 1 according to the present invention includes the steps of expanding and crushing (S11, S12), blending (S13), and extruding (S14). It may include.

팽창 및 분쇄하는 단계(S11,S12)에 의하면, 질석(vermiculite)과 진주암(perlite) 중 어느 하나 또는 모두를 분쇄 가공 후, 800 ~ 1,100℃로 가열 소성하여 부피를 팽창시켜서(S11), 분쇄기로 분쇄하게 된다(S12). 이때, 질석과 진주암을 모두 분쇄 및 소성 팽창시키는 경우, 질석과 진주암을 별개로 하여 분쇄 및 팽창시키거나, 질석과 진주암을 혼합하여 분쇄 및 팽창시킬 수도 있다. According to the step of expanding and crushing (S11, S12), after pulverizing any one or both of vermiculite and perlite (heat) to 800 ~ 1,100 ℃ by heating and baking to expand the volume (S11), It is crushed (S12). In this case, when both vermiculite and pearlite are pulverized and plastically expanded, the vermiculite and pearlite may be separately pulverized and expanded, or vermiculite and pearlite may be mixed and pulverized and expanded.

분쇄를 마치면(S12), 질석과 진주암에 수분이 존재하는 경우, 수분 제거를 위한 건조 과정을 수행할 수 있다. 한편, 질석은 운모와 같은 결정구조를 가지는 단사정계에 속하는 광물로서, 색깔은 회백색 또는 갈색이며, 진주광택이 나고, 산에 쉽게 분해되고, 양이온 교환능력이 크며 가열하면 팽창한다. 또한, 진주석은 화성암의 일종인 진주암을 8~12 메시 이하로 분쇄하고, 예열 후 급속히 가열하면 함유하는 결정수는 발포하여 팽창한다. 이것을 냉각시키면 백색 진주 모양의 가벼운 미립자, 예컨대 겉보기 비중 0.38~0.60을 얻을 수 있으며, 내화나 내열, 방음 등에 뛰어나기 때문에 시멘트 모르타르 단열재 외에 여재 등으로도 사용될 수 있다.When the grinding is finished (S12), if water is present in vermiculite and pearlite, it can be carried out a drying process for water removal. Vermiculite, on the other hand, is a mineral belonging to a monoclinic system having a mica-like crystal structure. The color is grayish white or brown, has a pearl luster, is easily decomposed by acid, has a large cation exchange capacity, and expands when heated. In addition, pearlite pulverizes pearlite, which is a kind of igneous rock, to 8-12 mesh or less, and when heated rapidly after preheating, the crystal water contained foams and expands. When this is cooled, white pearl-shaped light fine particles, such as an apparent specific gravity of 0.38 to 0.60, can be obtained, and because it is excellent in fire resistance, heat resistance, sound insulation, etc., it can be used as a filter material in addition to a cement mortar insulation material.

팽창 및 분쇄하는 단계(S11,12)에서 분쇄 과정에서 분쇄 입자의 크기는 분쇄 입자의 크기가 1nm(나노입자) ~ 0.5mm임이 바람직하다. 여기서, 분쇄 입자의 크기가 1nm ~ 0.5mm를 벗어나는 경우, 블랜딩의 균일성과 제품의 강도 증대에 장애를 초래하게 된다.In the swelling and crushing step (S11, 12), the size of the crushed particles in the crushing process is preferably 1nm (nanoparticles) ~ 0.5mm size of the crushed particles. In this case, when the size of the pulverized particles deviates from 1 nm to 0.5 mm, the uniformity of the blending and the increase in the strength of the product are caused.

블랜딩하는 단계(S13)에 의하면, 부피를 팽창시켜서 분쇄한 질석과 진주암 중 어느 하나 또는 모두의 혼합물 10 ~ 85중량%와, 폴리뷰틸렌테레프랄레이트(PolybutyleneTerephthalate,PBT), ABS(Acrylonitrile, Butadiene, Styrene), nylon, PC/ABS((polycarbonate,Acrylonitrile, Butadiene, Styrene), PC(Polycarbonate), 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET), 폴리프로필렌(polypropylene, PP), 폴리올레핀(polyolefin)류에 속하는 열가소성수지, 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), LDPE(Low Density Polyethylene), LLDPE(Linear low-density polyethylene) 중에서 단독 또는 같은 계열에 속하는 다수의 혼합물 10 ~ 85중량%와, 산화방지제 0.01 ~ 0.5중량%와, 유동파라핀오일 0.1 ~ 5중량%를 혼합하고 교반하여 블랜딩하게 된다. According to the blending step (S13), 10 to 85% by weight of the mixture of any one or both of the vermiculite and pearlite crushed by expanding the volume, polybutylene terephthalate (PBT), ABS (Acrylonitrile, Butadiene) , Styrene), nylon, PC / ABS (polycarbonate, Acrylonitrile, Butadiene, Styrene), PC (Polycarbonate), polyethylene terephthalate (PET), polypropylene (PP), thermoplastics belonging to polyolefins 10 to 85% by weight of a mixture of resins, polyethylene (PE), high density polyethylene (HDPE), low density polyethylene (LDPE), linear low-density polyethylene (LDPE) alone or in the same series, and antioxidants 0.01 to 0.5% by weight, 0.1 to 5% by weight of the liquid paraffin oil is mixed and stirred to blend.

한편, 블랜딩하는 단계(S13)에서 인체에 무해한 칼라 무기 안료를 0.01 ~ 0.5중량% 부가하여 혼합하고 교반하여 블랜딩할 수 있고, 폐타이어 또는 폐고무 분말을 0.1 ~ 30중량% 부가하여 혼합하고 교반하여 블랜딩할 수 있다.Meanwhile, in the blending step (S13), 0.01 to 0.5% by weight of the color inorganic pigment, which is harmless to the human body, may be added, mixed and stirred to blend, and 0.1 to 30% by weight of the waste tire or waste rubber powder may be added and mixed and stirred. Can be blended

압출하는 단계(S14)는 블랜딩 결과물을 압출기에 의해 압출함으로써 마스터뱃치의 제조를 마치게 된다.Extrusion step (S14) is to finish the production of the masterbatch by extruding the blending result by the extruder.

도 2에 도시된 바와 같이, 마스터배치(1)를 이용하여 제품으로 제작될 수 있는데, 본 발명에 따른 마스터배치를 이용하여 제조되는 드럼세탁기 터브(tub)(11)는, 상기한 마스터배치(1) 10 ~ 70중량%와, 폴리프로필렌(polypropylene, PP), 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET) 중에서 하나 또는 같은 계열에 속하는 다수의 혼합물 30 ~ 90중량%와, 유리장섬유 또는 합침된 유리장섬유 0 ~ 30중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형될 수 있다.As shown in Figure 2, it can be produced as a product using the masterbatch (1), the drum washing machine tub (11) manufactured using the masterbatch according to the present invention, the masterbatch ( 1) 10 to 70% by weight, and a mixture of polypropylene (PP), polyethylene (polyethtylene, PE), HDPE (High Density Polyethylene), and polyethylene terephthalate (PET) ~ 90% by weight, and 0-30% by weight of the glass filament or the combined glass filament may be blended or extruded, and may be press-molded by injection into an injection molding machine.

또한, 본 발명에 따른 마스터배치를 이용하여 제조되는 전자동세탁기 맥동부재(pulsator)(12)는, 상기한 마스터배치(1) 10 ~ 70중량%와, 폴리에틸렌테레프탈레이트(polyethyleneterephthalate, PET), 폴리프로필렌(polypropylene, PP), 폴리에틸렌(polyethtylene, PE) 중에서 하나 또는 모두의 혼합물 30 ~ 90중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형될 수 있다.In addition, the fully automatic washing machine pulsator (12) manufactured using the masterbatch according to the present invention, the masterbatch (1) 10 to 70% by weight, polyethylene terephthalate (polyethyleneterephthalate, PET), polypropylene 30 to 90% by weight of a mixture of one or both of (polypropylene, PP) and polyethylene (polyethtylene, PE) may be blended or extruded and injected into an injection molding machine to be press-molded.

또한, 본 발명에 따른 마스터배치를 이용하여 제조되는 전자동 세탁기 베이스(base)(13)는, 상기한 마스터배치(1) 10 ~ 70중량%와, 폴리프로필렌(polypropylene, PP), 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), LDPE(Low Density Polyethylene), LLDPE(Linear low-density polyethylene) 중에서 하나 또는 같은 계열에 속하는 다수의 혼합물 30 ~ 90중량%와, 유리장섬유 또는 합침된 유리장섬유 0 ~ 30중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형될 수 있다.In addition, the fully automatic washing machine base (13) manufactured using the masterbatch according to the present invention, the masterbatch (1) 10 to 70% by weight, polypropylene (polypropylene, PP), polyethylene (polyethtylene, 30 to 90% by weight of a plurality of mixtures belonging to one or the same family of PE), HD Density Polyethylene (HDPE), Low Density Polyethylene (LDPE), or Linear Low-density Polyethylene (LDLPE); 0 to 30% by weight of the fiber may be mixed, blended or extruded, and may be press molded into an injection molding machine.

또한, 본 발명에 따른 마스터배치를 이용하여 제조되는 전자동 세탁기 볼(bowl)(14)은, 상기한 마스터배치(1) 10 ~ 70중량%와, 폴리프로필렌(polypropylene, PP), 폴리에틸렌(polyethtylene, PE), 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET) 중에서 하나 또는 같은 계열에 속하는 다수의 혼합물 30 ~ 90중량%와, 유리장섬유 또는 합침된 유리장섬유 0 ~ 30중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형될 수 있다.In addition, a fully automatic washing machine bowl 14 manufactured using a masterbatch according to the present invention includes 10 to 70% by weight of the masterbatch 1, polypropylene (PP), polyethylene (polyethtylene, PE), polyethylene terephthalate (polyethylene terephthalate (PET) 30 to 90% by weight of a plurality of mixtures belonging to the same or the same series and blended or extruded by mixing 0 to 30% by weight of glass filaments or glass filaments, It can be press-molded by injection into an injection molding machine.

또한, 본 발명에 따른 마스터배치를 이용하여 제조되는 전자동 세탁기 탑커버(top cover)(15)는, 상기한 마스터배치(1) 10 ~ 70중량%와, 폴리프로필렌(polypropylene, PP), 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), 폴리뷰틸렌테레프랄레이트(PolybutyleneTerephthalate,PBT), ABS(Acrylonitrile, Butadiene, Styrene), PC/ABS((polycarbonate,Acrylonitrile, Butadiene, Styrene), PC(Polycarbonate), 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET) 중에서 하나 또는 같은 계열에 속하는 다수의 혼합물 30 ~ 90중량%와, 유리장섬유 또는 합침된 유리장섬유 0 ~ 30중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형될 수 있다.In addition, the automatic washing machine top cover (15) manufactured using the master batch according to the present invention, the master batch (1) above 10 to 70% by weight, polypropylene (polypropylene, PP), polyethylene ( polyethtylene, PE), HDPE (High Density Polyethylene), polybutylene terephthalate (PBT), ABS (Acrylonitrile, Butadiene, Styrene), PC / ABS (polycarbonate, Acrylonitrile, Butadiene, Styrene), PC ( Polycarbonate), polyethylene terephthalate (PET) 30 to 90% by weight of a plurality of mixtures belonging to one or the same series and blended or extruded by mixing 0 to 30% by weight of glass filament or glass fiber combined; It can be press-molded by injection into an injection molding machine.

또한, 본 발명에 따른 마스터배치를 이용하여 제조되는 전자동 세탁기 아웃터브(out-tub)(16)는, 상기한 마스터배치(1) 10 ~ 70중량%와, 폴리프로필렌(polypropylene, PP) 30 ~ 90중량%와, 폴리에틸렌테레프탈레이트( PolyethyleneTerephthalate, PET)과 , 유리장섬유 또는 합침된 유리장섬유 0 ~ 30중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형될 수 있다.In addition, the fully automatic washing machine out-tub 16 manufactured using the masterbatch according to the present invention includes 10 to 70% by weight of the masterbatch 1 and polypropylene (PP) 30 to 30%. to a mixture of 90% by weight, and a polyethylene terephthalate (polyethyleneTerephthalate, PET) and glass sheets of a fiber or glass fiber combining 0-30% by weight of blend or extrusion, press-molding can be put into an injection molding machine.

또한, 본 발명에 따른 마스터배치를 이용하여 제조되는 상자(17)는, 상기한 마스터배치(1) 10 ~ 70중량%와, 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET), 폴리프로필렌(polypropylene, PP), 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), LDPE(Low Density Polyethylene), LLDPE(Linear low-density polyethylene) 중에서 하나 또는 같은 계열에 속하는 다수의 혼합물 30 ~ 90중량%와, 유리장섬유 또는 합침된 유리장섬유 0 ~ 30중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형될 수 있다.In addition, the box 17 manufactured using the masterbatch according to the present invention, the masterbatch (1) 10 to 70% by weight, polyethylene terephthalate (polyethylene terephthalate (PET), polypropylene (polypropylene, PP), 30 to 90% by weight of a plurality of mixtures belonging to one or the same series among polyethylene (PE), high density polyethylene (HDPE), low density polyethylene (LDPE), linear low-density polyethylene (LDDPE), and glass fiber or 0-30% by weight of the combined glass filament may be blended or extruded, and then put in an injection molding machine to be press-molded.

또한, 본 발명에 따른 마스터배치를 이용하여 제조되는 식품 용기, 예컨대 보냉김치통(18), 된장통, 고추장통은, 상기한 마스터배치(1) 10 ~ 70중량%와, 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET), 폴리프로필렌(polypropylene, PP) 중에서 하나 또는 모두의 혼합물 30 ~ 90중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형될 수 있다.In addition, food containers produced using the masterbatch according to the present invention, such as cold storage kimchi (18), miso barrel, hot pepper barrel, 10 to 70% by weight of the masterbatch (1) and polyethylene terephthalate (polyethylene terephthalate) , PET), 30 to 90% by weight of a mixture of one or all of polypropylene (polypropylene, PP) may be blended or extruded, and then injected into an injection molding machine to be press-molded.

또한, 본 발명에 따른 마스터배치를 이용하여 제조되는 파렛트(pallet)(19)는, 상기한 마스터배치(1) 10 ~ 70중량%와, 폴리프로필렌(polypropylene, PP), 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), LDPE(Low Density Polyethylene), LLDPE(Linear low-density polyethylene) 중에서 하나 또는 같은 계열에 속하는 다수의 혼합물 30 ~ 90중량%와, 유리장섬유 또는 합침된 유리장섬유 0 ~ 30중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형될 수 있다.In addition, the pallet (19) produced using the masterbatch according to the present invention, the masterbatch (1) 10 to 70% by weight, polypropylene (polypropylene, PP), polyethylene (polyethtylene, PE) , 30 to 90% by weight of a plurality of mixtures belonging to one or the same series of HDPE, High Density Polyethylene (LDPE), Low Density Polyethylene (LDPE), or linear low-density polyethylene (LLDPE); ~ 30% by weight of the mixture may be blended or extruded, and then put into an injection molding machine to be press-molded.

또한, 본 발명에 따른 마스터배치를 이용하여 제조되는 자동차 엔진커버(20)는, 상기한 마스터배치(1) 10 ~ 70중량%와, 폴리뷰틸렌테레프랄레이트(PolybutyleneTerephthalate, PBT), nylon, PC/ABS((polycarbonate,Acrylonitrile, Butadiene, Styrene), PC(Polycarbonate) 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET) 중에서 하나 또는 같은 계열에 속하는 다수의 혼합물 30 ~ 90중량%와, 유리장섬유 또는 합침된 유리장섬유 0 ~ 50중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형될 수 있다.In addition, the automotive engine cover 20 manufactured using the master batch according to the present invention, the master batch (1) 10 to 70% by weight, polybutylene terephthalate (Polybutylene Terephthalate (PBT)), nylon, 30 to 90% by weight of a plurality of mixtures belonging to one or the same family of PC / ABS (polycarbonate, Acrylonitrile, Butadiene, Styrene), PC (Polycarbonate) polyethylene terephthalate (PET), glass fiber or impregnated glass 0 to 50% by weight of long fibers may be mixed, blended or extruded, and may be press-molded by injection into an injection molding machine.

한편, 본 발명에 따른 마스터뱃치를 이용한 제품 중에서 전자동세탁기 맥동부재(12), 전자동세탁기 베이스(13), 전자동세탁기 볼(14), 전자동세탁기 탑커버(15), 전자동세탁기 아웃터브(16), 상자(17), 식품 용기, 예컨대 보냉김치통(18), 된장통, 고추장통, 그리고 파렛트(19)는 칼라 무기 안료가 부가하여 혼합된 마스터뱃치(1)가 사용될 수 있고, 본 발명에 따른 마스터뱃치를 이용한 제품(11 내지 20)은 마스터뱃치(1)와 블랜딩되는 수지가 신생수지뿐만 아니라, 재생수지일 수 있고, 신생수지와 재생수지가 혼합될 수도 있으며, 상기한 동일계열로는 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), LDPE(Low Density Polyethylene)를 들 수 있다. 또한, 유리장섬유의 경우 3 ~ 15mm로 절단된 상태로 마스터뱃치(1)와 수지에 블랜딩될 수 있으며, 마스터배치(1)와 수지에 혼합시 이들 중량비율에 대하여 0 ~ 30중량%로 혼합될 수 있는데, 이는 마스터배치(1)와 수지에 선택적으로 혼합됨을 의미하고, 혼합시에는이들 중량비율에 대하여 0.1 ~ 30중량%로 혼합하여 블랜드 또는 압출될 수 있다. On the other hand, among the products using the master batch according to the present invention, the automatic washing machine pulsation member 12, the automatic washing machine base 13, the automatic washing machine ball 14, the automatic washing machine top cover 15, the automatic washing machine outer tub 16, Boxes 17, food containers, such as cold kimchi container 18, miso, hot pepper and pallet 19 can be used a master batch (1) mixed with a color inorganic pigment, according to the present invention The products 11 to 20 using the master batch may be a resin blended with the master batch 1 as well as a new resin, a recycled resin, and a new resin and a recycled resin may be mixed. (polyethtylene, PE), HDPE (High Density Polyethylene), LDPE (Low Density Polyethylene). In addition, in the case of glass filaments can be blended to the master batch (1) and the resin in a state of being cut into 3 ~ 15mm, when mixing in the master batch (1) and the resin mixed with 0 to 30% by weight relative to these weight ratio This means that it is optionally mixed with the masterbatch (1) and the resin, and when mixed, it can be blended or extruded by mixing at 0.1 to 30% by weight relative to these weight ratio.

또한, 본 발명에 따른 마스터뱃치를 이용한 제품 중에서 전자동 세탁기의 베이스(13)와 파렛트(19)는 폐타이어 또는 폐고무 분말을 부가하여 혼합된 마스터뱃치(1)가 사용될 수 있다.In addition, among the products using the master batch according to the present invention, the base 13 and the pallet 19 of the fully automatic washing machine may use a mixed master batch 1 by adding waste tires or waste rubber powder.

이와 같이, 본 발명에 의해 제조된 마스터뱃치(1) 및 제품(11 내지 20)은 경량의 고강도 및 내충격성이 뛰어나고, 친환경적이면서 원가 절감이 가능하도록 하며, 친환경 재료로서, 화석연료의 사용을 억제하도록 함과 아울러 연소가스의 배출량을 줄이는데 기여할 수 있다.As described above, the master batch 1 and the products 11 to 20 manufactured according to the present invention are excellent in light weight, high strength and impact resistance, and can be eco-friendly and cost-effective, and suppress the use of fossil fuels as eco-friendly materials. It can also contribute to reducing emissions of combustion gases.

이와 같이 첨부된 도면을 참조하여 본 발명을 설명하였으나, 본 발명의 기술적 사상을 벗어나지 않는 범위 내에서 다양한 수정 및 변형이 이루어질 수 있음은 물론이다. 그러므로, 본 발명의 범위는 설명된 실시예에 국한되어 정해져서는 안되며, 후술하는 특허청구범위뿐만 아니라 이러한 특허청구범위와 균등한 것들에 의해 정해져야 한다.Although the present invention has been described with reference to the accompanying drawings, it is to be understood that various changes and modifications may be made without departing from the spirit of the invention. Therefore, the scope of the present invention should not be limited to the described embodiments, but should be determined by the equivalents of the claims, as well as the following claims.

1 : 마스터뱃치
11 : 드럼세탁기 터브
12 : 전자동세탁기 맥동부재
13 : 전자동세탁기 베이스
14 : 전자동세탁기 볼
15 : 전자동세탁기 탑커버
16 : 전자동세탁기 아웃터브
17 : 상자
18 : 보냉김치통
19 : 파렛트
20 : 자동차 엔진커버
1: Masterbatch
11: drum washing machine tub
12: fully automatic washing machine pulsation member
13: fully automatic washing machine base
14: automatic washing machine ball
15: automatic washing machine top cover
16: fully automatic washing machine out tub
17: box
18: cold kimchi container
19: Pallet
20: car engine cover

Claims (14)

마스터뱃치에 있어서,
분쇄 가공 후 800 ~ 1,100℃로 가열 소성하여 부피를 팽창시켜서 분쇄한 질석(vermiculite)과 진주암(perlite) 중 어느 하나 또는 모두의 혼합물 10 ~ 85중량%와, 폴리뷰틸렌테레프랄레이트(PolybutyleneTerephthalate,PBT), ABS(Acrylonitrile, Butadiene, Styrene), nylon, PC/ABS((polycarbonate,Acrylonitrile, Butadiene, Styrene), PC(Polycarbonate), 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET), 폴리프로필렌(polypropylene, PP), 폴리올레핀(polyolefin)류에 속하는 열가소성수지, 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), LDPE(Low Density Polyethylene), LLDPE(Linear low-density polyethylene) 중에서 단독 또는 다수의 혼합물 10 ~ 85중량%와, 산화방지제 0.01 ~ 0.5중량%와, 유동파라핀오일 0.1 ~ 5중량%를 혼합하고 교반하여 블랜딩하여, 압출시키는 것을 특징으로 하는 마스터뱃치.
In the masterbatch,
10 to 85% by weight of a mixture of any or all of vermiculite and perlite, which are pulverized by heating and calcining at 800 to 1,100 ° C. after pulverization, and polybutylene terephthalate (Polybutylene Terephthalate, PBT), ABS (Acrylonitrile, Butadiene, Styrene), nylon, PC / ABS (polycarbonate, Acrylonitrile, Butadiene, Styrene), PC (Polycarbonate), Polyethylene terephthalate (PET), polypropylene (PP), thermoplastic resins belonging to polyolefins, polyethylene (polyethtylene, PE), HDPE (High Density Polyethylene), LDPE (Low Density Polyethylene), LLDPE ( Linear low-density polyethylene) 10 to 85% by weight of a mixture of a single or multiple, 0.01 to 0.5% by weight of antioxidant, 0.1 to 5% by weight of liquid paraffin oil is mixed, stirred and blended, characterized in that the extruded Masterbatch.
제 1 항에 있어서, 상기 마스터뱃치는,
상기 가열 소성하여 팽창시켜서 분쇄할 때의 질석 또는 진주암의 입자 크기가 1nm ~ 0.5mm인 것을 특징으로 하는 마스터뱃치.
The method of claim 1, wherein the master batch,
Masterbatch, characterized in that the particle size of vermiculite or pearlite when sintered by the expansion by heating and calcining is 1nm ~ 0.5mm.
제 1 항에 있어서, 상기 마스터뱃치는,
상기 블랜딩 전에 칼라 무기 안료를 0.01~0.5중량% 부가하여 블랜딩하여 압출되는 것을 특징으로 하는 마스터뱃치.
The method of claim 1, wherein the master batch,
Masterbatch characterized in that the blending is extruded by adding 0.01 to 0.5% by weight of the color inorganic pigment before the blending.
제 1 항에 있어서, 상기 마스터뱃치는,
상기 블랜딩 전에 폐타이어 또는 폐고무 분말을 0.1~30중량% 부가하여 블랜딩하여 압출되는 것을 특징으로 하는 마스터뱃치.
The method of claim 1, wherein the master batch,
Masterbatch characterized in that the blended and extruded by adding 0.1 to 30% by weight of the waste tire or waste rubber powder before blending.
마스터배치를 이용하여 제조되는 드럼세탁기 터브(tub)에 있어서,
제 1 항 내지 제 3 항 중 어느 한 항에 기재된 상기 마스터배치 10 ~ 70중량%와, 폴리프로필렌(polypropylene, PP), 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET) 중에서 하나 또는 다수의 혼합물 30 ~ 90중량%와, 유리장섬유 또는 합침된 유리장섬유 0 ~ 30중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형되는 것을 특징으로 하는 마스터뱃치를 이용하여 제조되는 드럼세탁기 터브.
In a drum washing machine tub manufactured using a masterbatch,
10 to 70% by weight of the masterbatch according to any one of claims 1 to 3, polypropylene (PP), polyethylene (polyethtylene, PE), HDPE (High Density Polyethylene), polyethylene terephthalate (Polyethylene Terephthalate) , PET) 30 to 90% by weight of one or a plurality of mixtures, 0 to 30% by weight of the glass filament or the combined glass filament is blended or extruded, characterized in that the injection molding machine is press-molded Drum washing machine tub manufactured using a master batch.
마스터배치를 이용하여 제조되는 전자동세탁기 맥동부재(pulsator)에 있어서,
제 1 항 내지 제 3 항 중 어느 한 항에 기재된 상기 마스터배치 10 ~ 70중량%와, 폴리에틸렌테레프탈레이트(polyethyleneterephthalate, PET), 폴리프로필렌(polypropylene, PP), 폴리에틸렌(polyethtylene, PE) 중에서 하나 또는 모두의 혼합물 30 ~ 90중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형되는 것을 특징으로 하는 마스터뱃치를 이용하여 제조되는 전자동세탁기 맥동부재.
In a fully automatic washing machine pulsator manufactured using a masterbatch,
10 to 70% by weight of the masterbatch according to any one of claims 1 to 3, polyethylene terephthalate (polyethyleneterephthalate (PET), polypropylene (polypropylene, PP), polyethylene (polyethtylene, PE) one or both 30 to 90% by weight of the mixture is blended or extruded, the automatic washing machine pulsating member manufactured by using a master batch, characterized in that the injection molding machine.
마스터배치를 이용하여 제조되는 전자동 세탁기 베이스(base)에 있어서,
제 1 항 내지 제 3 항 중 어느 한 항에 기재된 상기 마스터배치 10 ~ 70중량%와, 폴리프로필렌(polypropylene, PP), 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), LDPE(Low Density Polyethylene), LLDPE(Linear low-density polyethylene) 중에서 하나 또는 다수의 혼합물 30 ~ 90중량%와, 유리장섬유 또는 합침된 유리장섬유 0 ~ 30중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형되는 것을 특징으로 하는 마스터뱃치를 이용하여 제조되는 전자동 세탁기 베이스.
In a fully automatic washing machine base manufactured using a masterbatch,
10 to 70% by weight of the masterbatch according to any one of claims 1 to 3, polypropylene (PP), polyethylene (polyethtylene, PE), HDPE (High Density Polyethylene), LDPE (Low Density Polyethylene) ), 30 to 90% by weight of one or more mixtures of linear low-density polyethylene (LLDPE) and 0 to 30% by weight of glass filaments or impregnated glass filaments are blended or extruded, and then injected into an injection molding machine. Fully automatic washing machine base manufactured using a master batch, characterized in that the molding.
마스터배치를 이용하여 제조되는 전자동 세탁기 볼(bowl)에 있어서,
제 1 항 내지 제 3 항 중 어느 한 항에 기재된 상기 마스터배치 10 ~ 70중량%와, 폴리프로필렌(polypropylene, PP), 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), LDPE(Low Density Polyethylene), LLDPE(Linear low-density polyethylene) 중에서 하나 또는 다수의 혼합물 30 ~ 90중량%와, 유리장섬유 또는 합침된 유리장섬유 0 ~ 30중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형되는 것을 특징으로 하는 마스터뱃치를 이용하여 제조되는 전자동 세탁기 볼.
In a fully automatic washing machine bowl manufactured using a masterbatch,
10 to 70% by weight of the masterbatch according to any one of claims 1 to 3, polypropylene (PP), polyethylene (polyethtylene, PE), HDPE (High Density Polyethylene), LDPE (Low Density Polyethylene) ), 30 to 90% by weight of one or more mixtures of linear low-density polyethylene (LLDPE) and 0 to 30% by weight of glass filaments or impregnated glass filaments are blended or extruded, and then injected into an injection molding machine. Fully automatic washing machine ball manufactured using a master batch characterized in that the molding.
마스터배치를 이용하여 제조되는 전자동 세탁기 탑커버(top cover)에 있어서,
제 1 항 내지 제 3 항 중 어느 한 항에 기재된 상기 마스터배치 10 ~ 70중량%와, 폴리프로필렌(polypropylene, PP), 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), 폴리뷰틸렌테레프랄레이트(PolybutyleneTerephthalate,PBT), ABS(Acrylonitrile, Butadiene, Styrene), PC/ABS((polycarbonate,Acrylonitrile, Butadiene, Styrene), PC(Polycarbonate) 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET) 중에서 하나 또는 다수의 혼합물 30 ~ 90중량%와, 유리장섬유 또는 합침된 유리장섬유 0 ~ 30중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형되는 것을 특징으로 하는 마스터뱃치를 이용하여 제조되는 전자동 세탁기 탑커버.
In a fully automatic washing machine top cover manufactured using a masterbatch,
10 to 70% by weight of the master batch according to any one of claims 1 to 3, polypropylene (PP), polyethylene (polyethtylene, PE), HDPE (High Density Polyethylene), polybutylene tereph One or more mixtures of polybutylene terephthalate (PBT), ABS (Acrylonitrile, Butadiene, Styrene), PC / ABS (polycarbonate, Acrylonitrile, Butadiene, Styrene), PC (Polycarbonate) polyethylene terephthalate (PET) 30 ~ 90% by weight, 0-30% by weight of glass filament or impregnated glass filament is blended or extruded, and then fully injected into an injection molding machine and manufactured by using a master batch characterized in that it is press-molded. cover.
마스터배치를 이용하여 제조되는 전자동 세탁기 아웃터브(out-tub)에 있어서,
제 1 항 내지 제 3 항 중 어느 한 항에 기재된 상기 마스터배치 10 ~ 70중량%와, 폴리프로필렌(polypropylene, PP) 30 ~ 90중량%와, 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET), 유리장섬유 또는 합침된 유리장섬유 0 ~ 30중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형되는 것을 특징으로 하는 마스터뱃치를 이용하여 제조되는 전자동 세탁기 아웃터브.
In a fully automatic washing machine out-tub manufactured using a masterbatch,
10 to 70% by weight of the masterbatch according to any one of claims 1 to 3, 30 to 90% by weight of polypropylene (PP), polyethylene terephthalate (PET), glass filament or A fully automatic washing machine outer tub manufactured by using a master batch, characterized in that the blended 0 to 30% by weight of the combined glass filament fibers, blended or extruded, and put into an injection molding machine.
마스터배치를 이용하여 제조되는 상자에 있어서,
제 1 항 내지 제 3 항 중 어느 한 항에 기재된 상기 마스터배치 10 ~ 70중량%와, 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET), 폴리프로필렌(polypropylene, PP), 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), LDPE(Low Density Polyethylene), LLDPE(Linear low-density polyethylene) 중에서 하나 또는 다수의 혼합물 30 ~ 90중량%와, 유리장섬유 또는 합침된 유리장섬유 0 ~ 30중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형되는 것을 특징으로 하는 마스터뱃치를 이용하여 제조되는 상자.
In a box manufactured using a masterbatch,
10 to 70% by weight of the masterbatch according to any one of claims 1 to 3, polyethylene terephthalate (PET), polypropylene (PP), polyethylene (polyethtylene, PE), HDPE (High) Blend of 30 to 90% by weight of one or more mixtures of Density Polyethylene (LDPE), Low Density Polyethylene (LDPE) or Linear Low-density Polyethylene (LDDPE) with 0 to 30% by weight of glass filament or impregnated glass filament Or by extrusion, a box manufactured by using a master batch, characterized in that the injection molding machine is pressure-molded.
마스터배치를 이용하여 제조되는 식품 저장 용기에 있어서,
제 1 항 내지 제 3 항 중 어느 한 항에 기재된 상기 마스터배치 10 ~ 70중량%와, 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET), 폴리프로필렌(polypropylene, PP) 중에서 하나 또는 모두의 혼합물 30 ~ 90중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형되는 것을 특징으로 하는 마스터뱃치를 이용하여 제조되는 식품 저장 용기.
In a food storage container manufactured using a masterbatch,
30 to 90% by weight of a mixture of 10 to 70% by weight of the masterbatch according to any one of claims 1 to 3 and one or all of polyethylene terephthalate (PET) and polypropylene (PP). Mixing the blend or extruded, the food storage container manufactured by using a master batch, characterized in that the injection molding machine is pressure-molded.
마스터배치를 이용하여 제조되는 파렛트(pallet)에 있어서,
제 1 항 내지 제 3 항 중 어느 한 항에 기재된 상기 마스터배치 10 ~ 70중량%와, 폴리프로필렌(polypropylene, PP), 폴리에틸렌(polyethtylene, PE), HDPE(High Density Polyethylene), LDPE(Low Density Polyethylene), LLDPE(Linear low-density polyethylene) 중에서 하나 또는 다수의 혼합물 30 ~ 90중량%와, 유리장섬유 또는 합침된 유리장섬유 0 ~ 30중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형되는 것을 특징으로 하는 마스터뱃치를 이용하여 제조되는 파렛트.
In a pallet produced using a masterbatch,
10 to 70% by weight of the masterbatch according to any one of claims 1 to 3, polypropylene (PP), polyethylene (polyethtylene, PE), HDPE (High Density Polyethylene), LDPE (Low Density Polyethylene) ), 30 to 90% by weight of one or more mixtures of linear low-density polyethylene (LLDPE) and 0 to 30% by weight of glass filaments or impregnated glass filaments are blended or extruded, and then injected into an injection molding machine. Pallet produced by using a master batch, characterized in that the molding.
마스터배치를 이용하여 제조되는 자동차 엔진커버에 있어서,
제 1 항 내지 제 3 항 중 어느 한 항에 기재된 상기 마스터배치 10 ~ 70중량%와, 폴리뷰틸렌테레프랄레이트(PolybutyleneTerephthalate,PBT), nylon, PC(Polycarbonate), 폴리에틸렌테레프탈레이트(PolyethyleneTerephthalate, PET) 중에서 하나 또는 다수의 혼합물 30 ~ 90중량%와, 유리장섬유 또는 합침된 유리장섬유 0 ~ 50중량%를 혼합하여 블랜드 또는 압출하여, 사출성형기에 투입하여 가압 성형되는 것을 특징으로 하는 마스터뱃치를 이용하여 제조되는 자동차 엔진커버.
In the automobile engine cover manufactured using a masterbatch,
10 to 70% by weight of the masterbatch according to any one of claims 1 to 3, polybutylene terephthalate (PBT), nylon, PC (Polycarbonate), polyethylene terephthalate (Polyethylene Terephthalate, PET 30-90% by weight of one or a plurality of mixtures and 0-50% by weight of the glass filament or the combined glass filament are blended or extruded, and then put into an injection molding machine, and a master batch is formed. Automobile engine cover manufactured using.
KR1020120074964A 2012-07-10 2012-07-10 Master batch and product for using the same KR101380218B1 (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010104010A (en) * 2000-05-12 2001-11-24 김상근 Functional plastic products having superior food stuff preservation ability prepared from ceramic compositions
JP2003192840A (en) 2001-12-26 2003-07-09 Sekisui Chem Co Ltd Adhesive fireproof rubber composition and sheet
KR100872859B1 (en) 2007-11-29 2008-12-10 호남석유화학 주식회사 Fabrication of high strength polypropylene/nanoclay composite using high contents of nanoclay masterbatch

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010104010A (en) * 2000-05-12 2001-11-24 김상근 Functional plastic products having superior food stuff preservation ability prepared from ceramic compositions
JP2003192840A (en) 2001-12-26 2003-07-09 Sekisui Chem Co Ltd Adhesive fireproof rubber composition and sheet
KR100872859B1 (en) 2007-11-29 2008-12-10 호남석유화학 주식회사 Fabrication of high strength polypropylene/nanoclay composite using high contents of nanoclay masterbatch

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