CN104231430A - Preparation method and product of stain-resistant anti-aging wood-plastic material - Google Patents
Preparation method and product of stain-resistant anti-aging wood-plastic material Download PDFInfo
- Publication number
- CN104231430A CN104231430A CN201410424245.7A CN201410424245A CN104231430A CN 104231430 A CN104231430 A CN 104231430A CN 201410424245 A CN201410424245 A CN 201410424245A CN 104231430 A CN104231430 A CN 104231430A
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- CN
- China
- Prior art keywords
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- parts
- wood
- plastic material
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- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 75
- 239000004033 plastic Substances 0.000 title claims abstract description 54
- 229920003023 plastic Polymers 0.000 title claims abstract description 54
- 238000002360 preparation method Methods 0.000 title claims abstract description 31
- 230000003712 anti-aging effect Effects 0.000 title abstract 4
- 238000002156 mixing Methods 0.000 claims abstract description 40
- 239000004743 Polypropylene Substances 0.000 claims abstract description 33
- 239000000843 powder Substances 0.000 claims abstract description 31
- -1 polypropylene Polymers 0.000 claims abstract description 21
- 239000002023 wood Substances 0.000 claims abstract description 21
- 229920001155 polypropylene Polymers 0.000 claims abstract description 19
- 229910052901 montmorillonite Inorganic materials 0.000 claims abstract description 16
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 14
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 14
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000006229 carbon black Substances 0.000 claims abstract description 13
- 229910021392 nanocarbon Inorganic materials 0.000 claims abstract description 13
- 239000004709 Chlorinated polyethylene Substances 0.000 claims abstract description 11
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 11
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 11
- 239000008116 calcium stearate Substances 0.000 claims abstract description 11
- 238000001816 cooling Methods 0.000 claims abstract description 11
- 238000000748 compression moulding Methods 0.000 claims abstract description 10
- 238000007731 hot pressing Methods 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 38
- 238000012986 modification Methods 0.000 claims description 33
- 230000004048 modification Effects 0.000 claims description 32
- 239000008367 deionised water Substances 0.000 claims description 31
- 229910021641 deionized water Inorganic materials 0.000 claims description 31
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 27
- 238000000967 suction filtration Methods 0.000 claims description 25
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 18
- 238000010792 warming Methods 0.000 claims description 16
- 239000007822 coupling agent Substances 0.000 claims description 14
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 14
- 229910001701 hydrotalcite Inorganic materials 0.000 claims description 14
- 229960001545 hydrotalcite Drugs 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 14
- 239000000047 product Substances 0.000 claims description 12
- 238000005352 clarification Methods 0.000 claims description 9
- 238000001556 precipitation Methods 0.000 claims description 9
- 230000003252 repetitive effect Effects 0.000 claims description 9
- 238000005201 scrubbing Methods 0.000 claims description 9
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 9
- 239000004925 Acrylic resin Substances 0.000 claims description 8
- 229920000178 Acrylic resin Polymers 0.000 claims description 8
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 8
- 239000003365 glass fiber Substances 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 238000002425 crystallisation Methods 0.000 claims description 7
- 230000008025 crystallization Effects 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 239000012065 filter cake Substances 0.000 claims description 7
- 238000010899 nucleation Methods 0.000 claims description 7
- 230000006911 nucleation Effects 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 3
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 3
- 241001330002 Bambuseae Species 0.000 claims description 3
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 3
- 239000011425 bamboo Substances 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 3
- 239000003643 water by type Substances 0.000 claims 1
- 238000013329 compounding Methods 0.000 abstract 2
- 235000012054 meals Nutrition 0.000 abstract 2
- 238000000227 grinding Methods 0.000 abstract 1
- 238000010298 pulverizing process Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 42
- 230000032683 aging Effects 0.000 description 7
- 239000003063 flame retardant Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- 239000002086 nanomaterial Substances 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229920001587 Wood-plastic composite Polymers 0.000 description 2
- 230000003373 anti-fouling effect Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000011155 wood-plastic composite Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004643 material aging Methods 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 230000003446 memory effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 230000005476 size effect Effects 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/58—Measuring, controlling or regulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
Abstract
Description
? | Embodiment 2 | Embodiment 3 | Embodiment 5 | Embodiment 6 | Embodiment 7 |
Tensile strength/MPa | ≥14 | ≥18 | ≥19 | ≥19 | ≥23 |
Flexural strength/MPa | ≥35 | ≥40 | ≥45 | ≥47 | ≥50 |
Tensile strength/MPa | Embodiment 2 | Embodiment 3 | Embodiment 5 | Embodiment 6 | Embodiment 7 | Normal wood is moulded |
1 month | 15 | 17 | 22 | 20 | 25 | 17 |
6 months | 17 | 19 | 23 | 22 | 19 | 15 |
12 months | 13 | 15 | 18 | 18 | 18 | 7 |
18 months | 11 | 11 | 15 | 16 | 16 | 5 |
24 months | 10 | 11 | 13 | 11 | 15 | 5 |
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410424245.7A CN104231430B (en) | 2014-08-26 | 2014-08-26 | The preparation method of anti-soiling aging-resisting Wood-plastic material and goods |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410424245.7A CN104231430B (en) | 2014-08-26 | 2014-08-26 | The preparation method of anti-soiling aging-resisting Wood-plastic material and goods |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104231430A true CN104231430A (en) | 2014-12-24 |
CN104231430B CN104231430B (en) | 2016-09-07 |
Family
ID=52220400
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410424245.7A Expired - Fee Related CN104231430B (en) | 2014-08-26 | 2014-08-26 | The preparation method of anti-soiling aging-resisting Wood-plastic material and goods |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104231430B (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104589525A (en) * | 2014-12-30 | 2015-05-06 | 东莞市高能磁电技术有限公司 | Preparation method for injection-molding type bonded permanent magnetic material and product |
CN106167580A (en) * | 2016-08-10 | 2016-11-30 | 浙江铧淳塑料有限公司 | A kind of low-corrosiveness easily processes bamboo-plastic composite material |
CN107082991A (en) * | 2017-06-13 | 2017-08-22 | 合肥大麦灯箱器材有限公司 | A kind of environmentally friendly anti-soiling aging-resisting high-intensity wood plastic composite material and preparation method thereof |
WO2019061757A1 (en) * | 2017-09-26 | 2019-04-04 | 苏州市一木包装材料有限公司 | Aging-resistant wood-plastic packaging material and preparation method therefor |
CN112175274A (en) * | 2020-11-03 | 2021-01-05 | 浙江尚元塑木制品有限公司 | Outdoor plastic-wood floor with good antifouling effect in oil pollution environment |
CN113634580A (en) * | 2021-07-30 | 2021-11-12 | 中国化学工程第六建设有限公司 | Environment-friendly treatment method for construction waste |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030087996A1 (en) * | 2001-10-25 | 2003-05-08 | Hutchison Herbert L | Cellulose/polyolefin composite pellet |
CN101054466A (en) * | 2007-05-19 | 2007-10-17 | 西北师范大学 | Super branched polyamine/montmorillonite/graphite nano composite material and preparation thereof |
CN102174270A (en) * | 2011-03-17 | 2011-09-07 | 华东理工大学 | Plasticized and toughened wood flour/polypropylene composite and method for preparing same |
CN103059408A (en) * | 2012-12-24 | 2013-04-24 | 上海普利特复合材料股份有限公司 | High heat-resisting and low diffusing polypropylene composite materials and preparation method thereof |
-
2014
- 2014-08-26 CN CN201410424245.7A patent/CN104231430B/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030087996A1 (en) * | 2001-10-25 | 2003-05-08 | Hutchison Herbert L | Cellulose/polyolefin composite pellet |
CN101054466A (en) * | 2007-05-19 | 2007-10-17 | 西北师范大学 | Super branched polyamine/montmorillonite/graphite nano composite material and preparation thereof |
CN102174270A (en) * | 2011-03-17 | 2011-09-07 | 华东理工大学 | Plasticized and toughened wood flour/polypropylene composite and method for preparing same |
CN103059408A (en) * | 2012-12-24 | 2013-04-24 | 上海普利特复合材料股份有限公司 | High heat-resisting and low diffusing polypropylene composite materials and preparation method thereof |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104589525A (en) * | 2014-12-30 | 2015-05-06 | 东莞市高能磁电技术有限公司 | Preparation method for injection-molding type bonded permanent magnetic material and product |
CN104589525B (en) * | 2014-12-30 | 2017-05-31 | 广州尚牛设计有限公司 | The preparation method and product of injection molding binding electromagnetic material |
CN106167580A (en) * | 2016-08-10 | 2016-11-30 | 浙江铧淳塑料有限公司 | A kind of low-corrosiveness easily processes bamboo-plastic composite material |
CN107082991A (en) * | 2017-06-13 | 2017-08-22 | 合肥大麦灯箱器材有限公司 | A kind of environmentally friendly anti-soiling aging-resisting high-intensity wood plastic composite material and preparation method thereof |
WO2019061757A1 (en) * | 2017-09-26 | 2019-04-04 | 苏州市一木包装材料有限公司 | Aging-resistant wood-plastic packaging material and preparation method therefor |
CN112175274A (en) * | 2020-11-03 | 2021-01-05 | 浙江尚元塑木制品有限公司 | Outdoor plastic-wood floor with good antifouling effect in oil pollution environment |
CN113634580A (en) * | 2021-07-30 | 2021-11-12 | 中国化学工程第六建设有限公司 | Environment-friendly treatment method for construction waste |
Also Published As
Publication number | Publication date |
---|---|
CN104231430B (en) | 2016-09-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20160802 Address after: 523000, Guangdong Province, Dongguan City, Dongcheng District province cattle Hill Industrial Park by the outer flame industrial zone Applicant after: GUANGDONG HONGYUN FURNITURE Co.,Ltd. Applicant after: GUANGDONG HONGQI FURNITURE Co.,Ltd. Applicant after: Guangdong Huasong Furniture Group Co.,Ltd. Applicant after: Guangdong Songtai Network Technology Co.,Ltd. Address before: 523000, Dongguan, Guangdong province Dongcheng District science and Technology Industrial Park, set up new cross Ling Industrial Zone Applicant before: GUANGDONG HONGQI FURNITURE Co.,Ltd. |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CP01 | Change in the name or title of a patent holder | ||
CP01 | Change in the name or title of a patent holder |
Address after: 523000, Guangdong Province, Dongguan City, Dongcheng District province cattle Hill Industrial Park by the outer flame industrial zone Co-patentee after: GUANGDONG HONGQI FURNITURE Co.,Ltd. Patentee after: GUANGDONG HONGYUN FURNITURE Co.,Ltd. Co-patentee after: Guangdong Huasong home furnishing Group Co.,Ltd. Co-patentee after: Guangdong Songtai Network Technology Co.,Ltd. Address before: 523000, Guangdong Province, Dongguan City, Dongcheng District province cattle Hill Industrial Park by the outer flame industrial zone Co-patentee before: GUANGDONG HONGQI FURNITURE Co.,Ltd. Patentee before: GUANGDONG HONGYUN FURNITURE Co.,Ltd. Co-patentee before: Guangdong Huasong Furniture Group Co.,Ltd. Co-patentee before: Guangdong Songtai Network Technology Co.,Ltd. |
|
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160907 |