KR101278180B1 - Filter Composition for Vehicle and Its Manufacturing Method - Google Patents
Filter Composition for Vehicle and Its Manufacturing Method Download PDFInfo
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- KR101278180B1 KR101278180B1 KR1020110087541A KR20110087541A KR101278180B1 KR 101278180 B1 KR101278180 B1 KR 101278180B1 KR 1020110087541 A KR1020110087541 A KR 1020110087541A KR 20110087541 A KR20110087541 A KR 20110087541A KR 101278180 B1 KR101278180 B1 KR 101278180B1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J127/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers
- C09J127/02—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J127/04—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09J127/06—Homopolymers or copolymers of vinyl chloride
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
Abstract
PVC수지와 나일론 재질이 잘 부착할 수 있도록 PVC수지와 가소제, 레졸시놀, 칼슘카보네이트 및 칼슘옥사이드를 적절하게 배합하여 제조되는 자동차 필터용 접착제 조성물 및 그 제조방법에 관한 것이다.The present invention relates to an adhesive composition for an automobile filter and a method of manufacturing the same, which are prepared by appropriately mixing a PVC resin with a plasticizer, resorcinol, calcium carbonate, and calcium oxide so that the PVC resin and nylon material can adhere well.
Description
본 발명은 자동차 필터용 접착제 조성물 및 그 제조방법에 관한 것으로 보다 상세하게는 자동차 필터의 여과지를 캡에 접착할 수 있는 자동차 필터용 접착제 조성물 및 그 제조방법에 관한 것이다.
BACKGROUND OF THE
일반적으로, 자동차용 필터는 자동차 엔진에 공급되는 오일에 포함된 불순물을 정화시키기 위해 자동차에 장착되는데, 도 1에서 보는 바와 같이 크게 자동차 필터(1)의 양단부가 수용되는 캡(10)과 종이 또는 나일론 수지로 제조되고 지그재그형으로 반복적으로 접혀진 여과지(20)로 구성된다. 한편, 상기 캡(10)은 다수의 통공이 형성되는 원통형상의 내륜망(11)과 역시 다수의 통공이 형성되는 원통형상의 외륜망(12)으로 구성되며, 상기 여과지(20)는 내륜망(11)의 안쪽에 위치하여 내륜망(12)에 접착된다.In general, an automobile filter is mounted on an automobile to purify impurities contained in oil supplied to an automobile engine, and as shown in FIG. 1, a
여기서, 상기 여과지(20)가 자동차용 필터(1) 양단부의 캡(10)에 견고하게 고정될 수 있도록 캡(10) 내주연의 내륜망(11)에 접착제를 도포하게 되는데, 이 작업에 쓰이는 접착제는 에폭시계 또는 핫멜트 접착제로서 대부분 외제를 수입하여 사용하고 있다.Here, an adhesive is applied to the
그러나 여과지(20)는 통상 나일론 수지이고 캡(10)은 PVC수지재이므로 통상의 접착제로는 잘 접착이 되지 않는다.
However, since the
따라서 PVC수지와 나일론 재질, 스틸에 잘 부착할 수 있는 접착제의 개발이 요망되고 있다.
Therefore, the development of adhesives that can adhere well to PVC resin, nylon and steel is desired.
본 발명은 상기와 같은 과제를 달성하기 위하여 개발한 것으로서 PVC수지와 가소제, 레졸시놀, 칼슘카보네이트 및 칼슘옥사이드를 적절하게 배합하여 접착제를 개발함으로써 해결할 수 있게 되었다.
The present invention has been developed in order to achieve the above problems can be solved by developing an adhesive by properly blending PVC resin and plasticizer, resorcinol, calcium carbonate and calcium oxide.
본 발명의 자동차 필터용 접착제 조성물을 개발함으로써 PVC수지와 나일론 재질, 스틸이 잘 부착할 수 있게 되었다. 또 그간 외국으로부터 접착제를 수입하여 사용하던 것을 본 발명의 자동차 필터용 접착 조성물로 대체할 수 있게 되어 외화를 절약할 수 있게 되었다.By developing the adhesive composition for automobile filters of the present invention, PVC resin, nylon material, and steel can be attached well. In addition, it has become possible to replace the adhesive composition for automobile filters of the present invention used to import and use the adhesive from foreign countries to save foreign currency.
제 1도 : 자동차용 필터의 사시도1: Perspective view of the automotive filter
본 발명은 PVC수지와 가소제, 레졸시놀, 칼슘카보네이트 및 칼슘옥사이드를 적절하게 배합하여 제조된 자동차 필터용 접착제 조성물 및 그 제조방법에 관한 것이다.The present invention relates to an adhesive composition for automobile filters prepared by appropriately mixing PVC resin with a plasticizer, resorcinol, calcium carbonate and calcium oxide, and a method of manufacturing the same.
이하, 본 발명에 대하여 상세하게 설명한다.EMBODIMENT OF THE INVENTION Hereinafter, this invention is demonstrated in detail.
본 발명의 자동차 필터용 접착제 조성물은 PVC수지와 가소제, 레졸시놀, 칼슘카보네이트 및 칼슘옥사이드를 적절하게 배합하여 제조된다. Adhesive composition for automobile filters of the present invention is prepared by appropriately blending a PVC resin with a plasticizer, resorcinol, calcium carbonate and calcium oxide.
PVC(Polyvinyl chloride) 수지는 열가소성 플라스틱의 하나로 '폴리염화비닐', '염화비닐수지'라고도 하며 PVC로 약칭한다. Polyvinyl chloride (PVC) resin is one of thermoplastics, also called 'polyvinyl chloride' and 'vinyl chloride resin'.
염화비닐을 주성분으로 하는 플라스틱으로 필름, 시트, 성형품, 캡 등 광범위한 제품으로 가공된다. 플라스틱의 대표적인 PVC 수지는 원래 딱딱한 물질로 프탈산계(phthalates, DEHP, DINP, DBP 등) 가소제나 아디핀산계(adipates,DHEA 등) 가소제를 사용해 유연성과 탄력성을 높인 뒤 제품화된다. Plastics based on vinyl chloride are processed into a wide range of products such as films, sheets, molded products, and caps. Plastic PVC is typically a hard material and is manufactured after increasing its flexibility and elasticity by using a phthalate plasticizer (phthalates, DEHP, DINP, DBP, etc.) or adipic acid (adipates, DHEA, etc.).
PVC 수지는 가소제를 다양한 함량으로 섞어서 딱딱한 특성부터 고무 같은 특성까지 다양하게 낼 수 있다. 가소제는 많이 넣을수록 부드럽고 물러진다.PVC resins can be mixed with plasticizers in varying amounts to give a variety of properties, from hard to rubbery. The more plasticizer you put in, the softer and receding you will be.
본 발명에서는 접착제조성물의 주원료로서 상기와 같이 가소제로 인하여 부드럽고 물러진 PVC수지를 5∼24 중량% 사용하였다. In the present invention, as the main raw material of the adhesive composition was used 5 to 24% by weight of the PVC resin soft and receded by the plasticizer as described above.
가소제는 PVC 수지를 부드럽게 하기 위하여 사용하였다. PVC 수지는 긴 끈 같은 분자가 모여서 된 것으로, 분자 사이에 서로 끌어당기는 힘이 강할수록 딱딱해진다. 이때 분자 사이에 가소제가 끼어들면 PVC 수지의 분자 사이의 직접 끌어당기는 힘이 약해져 부드럽게 된다. Plasticizers were used to soften the PVC resin. PVC resin is made up of long string-like molecules, and the stronger the force pulling each other between molecules, the harder it becomes. At this time, when the plasticizer is inserted between the molecules, the direct pulling force between the molecules of the PVC resin is weakened and softened.
본 발명에서는 가소제를 25∼30 중량% 사용하였다.In this invention, 25-30 weight% of plasticizers were used.
레졸시놀(resorcinol)은 벤젠핵의 메타 위치에 하이드록시기가 결합한 2가 페놀을 가리킨다. 방부제·살균제로 사용되고, 합성수지와 염료의 원료로도 쓰이며, 나일론에 대해서는 접착력을 가진다.Resorcinol refers to a dihydric phenol having a hydroxyl group bonded to the meta position of the benzene nucleus. It is used as a preservative and disinfectant. It is also used as a raw material for synthetic resins and dyes. It has adhesion to nylon.
본 발명에서는 나일론 재질과 잘 접착되도록 하기 위하여 레졸시놀을 1∼5 중량% 사용하였다. In the present invention, 1-5% by weight of resorcinol was used in order to adhere well to the nylon material.
칼슘카보네이트(Carcium Carbonate)는 칼슘의 일종으로 대리석·석회석·방해석·조개껍질 등의 주성분인 탄산염 칼슘이다. 순수한 물에는 녹지 않으나 탄산이 포함된 물에는 용해되며, 817℃에서 분해하면 탄산가스가 발생한다. 용도가 다양하나 점도를 가지고 접착강도에도 관여하므로 본 발명에서는 충전제(充塡劑)로서 25∼30 중량% 사용하였다. Calcium Carbonate (Carcium Carbonate) is a kind of calcium Calcium Carbonate, which is a major component of marble, limestone, calcite and shell shell. Insoluble in pure water, but soluble in water containing carbonic acid, carbon dioxide gas is generated when decomposed at 817 ℃. Although various uses are involved in viscosity and adhesive strength, in the present invention, 25 to 30% by weight was used as the filler.
칼슘옥사이드(Calcium Oxide)는 수용성 규산염 중 규산나트륨과 함께 가장 널리 사용되고 있는 무기화합물이다. 칼슘옥사이드는 여러 가지 성질을 가지고 있으며, 접착제의 수분을 흡수하는 기능도 있다. Calcium Oxide is the most widely used inorganic compound with sodium silicate among water-soluble silicates. Calcium oxide has a variety of properties, and also has the function of absorbing the moisture of the adhesive.
본 발명에서는 접착제의 수분을 흡수하기 위하여 25∼30 중량% 사용하였다. In the present invention, 25 to 30% by weight was used to absorb the moisture of the adhesive.
이하에서는 상기 원료를 사용하여 접착제를 제조하는 과정에 대하여 설명한다. Hereinafter, a process of manufacturing an adhesive using the raw material will be described.
우선 PVC수지와 가소제, 레졸시놀, 칼슘카보네이트 및 칼슘옥사이드를 준비한다.First, prepare PVC resin, plasticizer, resorcinol, calcium carbonate and calcium oxide.
이어 가소제 25∼30 중량%와 레졸시놀 1∼5 중량%을 교반탱크에 투입하여 10∼20분간 교반하여 가소제와 레졸시놀의 혼합물(1차)을 제조한다.Subsequently, 25 to 30% by weight of plasticizer and 1 to 5% by weight of resorcinol were added to the stirring tank, and stirred for 10 to 20 minutes to prepare a mixture (primary) of the plasticizer and resorcinol.
이어 상기 혼합물에 분말형태의 PVC수지 5∼24 중량%를 투입하여 20∼40분간 2차 혼합물을 제조한다. Subsequently, 5 to 24% by weight of a PVC resin in powder form was added to the mixture to prepare a secondary mixture for 20 to 40 minutes.
이어 칼슘카보네이트 25∼30 중량%를 투입한 후 분산시키면서 칼슘옥사이드 25∼30 중량%를 투입하여 3차 혼합물을 제조한다.Subsequently, 25-30% by weight of calcium carbonate was added thereto, followed by dispersing 25-30% by weight of calcium oxide to prepare a tertiary mixture.
이어 기포를 제거한다.The bubble is then removed.
이어 상기 3차 혼합물을 40℃이하의 상온에서 교반하여 자동차 필터용 접착제 조성물을 제조한다.
Subsequently, the tertiary mixture is stirred at room temperature below 40 ° C. to prepare an adhesive composition for automobile filters.
1 : 자동차용 필터 10 : 캠
11 : 내륜망 12 : 외륜망
20 : 여과지1: automotive filter 10: cam
11: inner ring network 12: outer ring network
20 filter paper
Claims (3)
이어 가소제 25∼30 중량%와 레졸시놀 1∼5 중량%를 교반탱크에 투입하여 10∼20분간 교반하여 가소제와 레졸시놀의 1차 혼합물을 제조하는 단계;
이어 상기 1차 혼합물에 분말형태의 PVC수지 5∼24 중량%를 투입하여 20∼40분간 교반하여 2차 혼합물을 제조하는 단계;
이어 상기 2차 혼합물에 칼슘카보네이트 25∼30 중량%를 투입한 후 분산시키면서 칼슘옥사이드 25∼30 중량%를 투입하여 3차 혼합물을 제조하는 단계;
이어 기포를 제거하는 단계; 및
상기 3차 혼합물을 40℃이하의 상온에서 교반하여 제조되는 것을 특징으로 하는 자동차 필터용 접착제 조성물 제조방법
Preparing a PVC resin and a plasticizer, resorcinol, calcium carbonate and calcium oxide;
Subsequently, 25 to 30% by weight of a plasticizer and 1 to 5% by weight of resorcinol were added to a stirring tank, and stirred for 10 to 20 minutes to prepare a primary mixture of the plasticizer and resorcinol;
Subsequently, 5 to 24% by weight of a PVC resin in powder form was added to the primary mixture, followed by stirring for 20 to 40 minutes to prepare a secondary mixture;
After preparing 25-30% by weight of calcium carbonate in the secondary mixture, and dispersing 25-30% by weight of calcium oxide to prepare a tertiary mixture;
Then removing the bubbles; And
Adhesive method for automobile filter adhesive composition, characterized in that the tertiary mixture is prepared by stirring at room temperature below 40 ℃
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KR20190088605A (en) | 2018-01-19 | 2019-07-29 | 이병길 | Adhesive composition for filter of an internal combustion engine |
CN114045128B (en) * | 2021-10-20 | 2022-12-23 | 广州集泰化工股份有限公司 | Welding seam sealant |
Citations (1)
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US5714030A (en) * | 1992-12-07 | 1998-02-03 | Tsuchiya Mfg. Co., Ltd. | Plastisol type adhesive composition used in filter for alcohol-containing fuel |
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Publication number | Priority date | Publication date | Assignee | Title |
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US5714030A (en) * | 1992-12-07 | 1998-02-03 | Tsuchiya Mfg. Co., Ltd. | Plastisol type adhesive composition used in filter for alcohol-containing fuel |
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