KR101269893B1 - Composite fiber consisting rayon filament and heat melted synthetic filament with excellent volume and cooling feel, and fabric manufactured thereby - Google Patents

Composite fiber consisting rayon filament and heat melted synthetic filament with excellent volume and cooling feel, and fabric manufactured thereby Download PDF

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KR101269893B1
KR101269893B1 KR1020110028573A KR20110028573A KR101269893B1 KR 101269893 B1 KR101269893 B1 KR 101269893B1 KR 1020110028573 A KR1020110028573 A KR 1020110028573A KR 20110028573 A KR20110028573 A KR 20110028573A KR 101269893 B1 KR101269893 B1 KR 101269893B1
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filament
heat
fiber
rayon
sealed
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KR20120110610A (en
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지 미 김
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(주)시마
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    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/36Cored or coated yarns or threads
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/28Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30Conjugate filaments; Spinnerette packs therefor
    • D01D5/32Side-by-side structure; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/28Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30Conjugate filaments; Spinnerette packs therefor
    • D01D5/34Core-skin structure; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/02Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • D02G3/045Blended or other yarns or threads containing components made from different materials all components being made from artificial or synthetic material
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/208Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based
    • D03D15/225Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based artificial, e.g. viscose
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/44Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads with specific cross-section or surface shape

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Multicomponent Fibers (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Abstract

본 발명은 볼륨감과 청량감이 우수한 레이온 필라멘트-열융착 합성 필라멘트 복합섬유 및 이로 제조된 원단에 관한 것으로서, 상기 레이온 필라멘트-열융착 합성 필라멘트 복합섬유는 (ⅰ) 융점이 서로 상이한 2종의 섬유형성성 폴리머들이 원사단면 상에서 열융착되어있는 열융착 합성 필라멘트와 (ⅱ) 상기 2종의 섬유형성성 폴리머들 중에서 융점이 상대적으로 낮은 1종의 섬유형성성 폴리머와 열융착되어 있는 레이온 필라멘트로 구성되며, 상기 2종의 섬유형성성 폴리머들 중 적어도 하나의 섬유형성성 폴리머 내에 무기입자가 함유되어 있는 것을 특징으로 한다.
본 발명은 레이온 필라멘트와 열융착 합성 필라멘트 간의 열수축 차이로 인해 레이온 필라멘트가 부출되어 볼륨감이 향상되고, 열융착 합성 필라멘트를 구성하는 2종의 섬유형성성 폴리머들 중 1종 또는 2종 모두에 무기입자가 함유되어 청량감도 향상되는 효과가 있다.
The present invention relates to a rayon filament-heat-sealed synthetic filament composite fiber and a fabric made therefrom, which are excellent in volume and coolness. It consists of a heat-sealed synthetic filament in which the polymers are heat-sealed on the yarn cross section, and (ii) one of the two fiber-forming polymers having a relatively low melting point and a rayon filament heat-sealed. At least one of the two fiber-forming polymers is characterized in that the inorganic particles are contained in the fiber-forming polymer.
According to the present invention, due to the difference in thermal contraction between the rayon filament and the heat-sealed synthetic filament, the rayon filament is ejected to improve the volume, and the inorganic fiber is used as one or both of the two fiber-forming polymers constituting the heat-sealed synthetic filament. There is an effect that the particles are contained, the refreshing feeling is also improved.

Description

볼륨감과 청량감이 우수한 레이온 필라멘트-열융착 합성 필라멘트 복합섬유 및 이로 제조된 원단{Composite fiber consisting rayon filament and heat melted synthetic filament with excellent volume and cooling feel, and fabric manufactured thereby}Composite fiber consisting rayon filament and heat melted synthetic filament with excellent volume and cooling feel, and fabric manufactured according to the present invention.

본 발명은 볼륨감과 청량감이 우수한 레이온 필라멘트-열융착 합성 필라멘트 복합섬유(이하 "레이온-열융착 필라멘트 복합섬유"라고 약칭한다) 및 이로 제조된 원단에 관한 것이다.The present invention relates to a rayon filament-heat-sealed synthetic filament composite fiber (hereinafter referred to as "rayon-heat-sealed filament composite fiber") excellent in volume and coolness, and a fabric made therefrom.

보다 구체적으로, 본 발명은 볼륨감과 청량감을 동시에 발현할 수 있는 레이온-열융착 필라멘트 복합섬유 및 이를 경사의 전부 또는 일부나 위사의 전부 또는 일부로 사용하여 제조된 원단에 관한 것이다.
More specifically, the present invention relates to a rayon-heat-sealed filament composite fiber capable of expressing a sense of volume and a refreshing feeling at the same time and a fabric manufactured by using all or part of the warp yarn or all or part of the weft yarn.

의류용 원단의 경우에는 우수한 볼륨감과 청량감이 요구되고 있으나, 종래 기술로서는 볼륨감과 청량감이 동시에 우수한 원단을 제조하는데에는 한계가 있었다.In the case of the fabric for clothes, excellent volume and refreshing feeling are required, but there is a limitation in manufacturing a fabric having excellent volume and refreshing feeling at the same time.

구체적으로, 면 방적사 또는 양모 방적사의 경우에는 어느정도의 볼륨감은 얻을 수 있으나 청량감이 부족한 문제점이 있었다.Specifically, in the case of cotton yarn or wool yarn we can get some sense of volume, but there was a problem of lack of cooling.

또한, 합성섬유 필라멘트의 경우에는 어느정도의 청량감을 얻을 수 있으나 볼륨감이 부족한 문제점이 있었다.In addition, in the case of synthetic fiber filament can be obtained a certain degree of cooling feeling, there was a problem of lack of volume.

또한, 면 방적사 또는 양모 방적사와 합성섬유 필라멘트를 합사 또는 연사한 복합섬유의 경우에는 복합섬유내 면 방적사 또는 양모 방적사가 효과적으로 복합섬유 표면으로 부출하지 못해서 만족스런 볼륨감을 얻을 수 없으며, 청량감도 합성섬유 필라멘트 단독 사용시 보다 떨어지는 문제가 있었다.
In addition, in the case of a composite fiber in which yarn or yarn is spun or twisted with cotton spun yarn or wool spun yarn, the cotton spun yarn or wool spun yarn in the composite fiber is not effectively fed to the surface of the composite fiber, and a satisfactory volume feeling is not obtained. There was a problem of lowering when using the filament alone.

이와같은 종래의 문제점들을 해결할 수 있도록, 본 발명에서는 볼륨감과 청량감이 동시에 우수한 레이온-열융착 필라멘트 복합섬유 및 이로 제조된 원단을 제공하는 것을 과제로 한다.
In order to solve such problems in the prior art, the present invention is to provide a rayon-heat-sealed filament composite fiber and a fabric made therefrom excellent in volume and coolness at the same time.

이와같은 과제를 달성하기 위해서, 본 발명에서는 (ⅰ) 융점이 서로 상이한 2종의 섬유형성성 폴리머들이 원사단면 상에서 열융착되어있는 열융착 합성 필라멘트와 (ⅱ) 상기 2종의 섬유형성성 폴리머들 중에서 융점이 상대적으로 낮은 1종의 섬유형성성 폴리머와 열융착되어 있는 레이온 필라멘트로 구성되며, 상기 2종의 섬유형성성 폴리머들 중 적어도 하나의 섬유형성성 폴리머 내에 무기입자가 함유되어 볼륨감과 청량감이 우수한 레이온 필라멘트-열융착 합성 필라멘트 복합섬유 및 이로 제조된 원단을 제공한다.
In order to achieve the above object, in the present invention, (i) two types of fiber-forming polymers having different melting points from each other are heat-sealed on the yarn cross section, and (ii) the two types of fiber-forming polymers. Consists of one fiber-forming polymer having a relatively low melting point and rayon filaments heat-sealed, and inorganic particles are contained in at least one fiber-forming polymer of the two fiber-forming polymers. This excellent rayon filament-heat fusion synthetic filament composite fiber and fabric made therefrom are provided.

본 발명은 레이온 필라멘트와 열융착 합성 필라멘트 간의 열수축 차이로 인해 레이온 필라멘트가 부출되어 볼륨감이 향상되고, 열융착 합성 필라멘트를 구성하는 2종의 섬유형성성 폴리머들 중 1종 또는 2종 모두에 무기입자가 함유되어 청량감도 향상되는 효과가 있다.
According to the present invention, due to the difference in thermal contraction between the rayon filament and the heat-sealed synthetic filament, the rayon filament is ejected to improve the volume, and the inorganic fiber is used as one or both of the two fiber-forming polymers constituting the heat-sealed synthetic filament. There is an effect that the particles are contained, the refreshing feeling is also improved.

도 1은 본 발명에 따른 레이온-열융착 필라멘트 복합섬유 제조에 사용되는 시스-코어(Sheath core) 형태인 열융착 합성 필라멘트의 단면도.
도 2는 본 발명에 따른 레이온-열융착 필라멘트 복합섬유 제조에 사용되는 사이드 바이 사이드(Side by side) 형태인 열융착 합성 필라멘트의 단면도.
1 is a cross-sectional view of a heat-sealed synthetic filament in the form of a sheath-core (Sheath core) used for producing a rayon-heat-sealed filament composite fiber according to the present invention.
Figure 2 is a cross-sectional view of a heat-sealed synthetic filament in the form of side by side (side by side) used in the production of rayon-heat-sealed filament composite fiber according to the present invention.

이하, 첨부한 도면 등을 통하여 본 발명을 상세하게 설명한다.Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

본 발명에 따른 레이온-열융착 필라멘트 복합섬유는 (ⅰ) 융점이 서로 상이한 2종의 섬유형성성 폴리머(A와 B 또는 C와 S)들이 원사 단면상에서 열융착되어 있는 열융착 합성 필라멘트와 (ⅱ) 레이온 필라멘트로 구성된다.The rayon-heat-sealed filament composite fiber according to the present invention comprises (i) a heat-sealed synthetic filament in which two kinds of fiber-forming polymers having different melting points (A and B or C and S) are heat-sealed on a yarn cross-section, and (ii) ) Consists of rayon filament.

상기 열융착 합성 필라멘트는 도 1 내지 도 2에 도시된 바와 같이 2종의 섬유형성성 폴리머(A와 B 또는 C와 S)들이 원사 단면상에서 시스-코어(Sheath core) 형태 또는 사이드 바이 사이드(Side by side) 형태로 열융착되어 있는 단면구조를 갖는다.The heat-sealed synthetic filament is a two-fiber forming polymer (A and B or C and S) in the form of a sheath-core (Sheath core) or side-by-side (Side) on the yarn cross-section as shown in FIG. It has a cross-sectional structure that is heat-sealed in the form of by side).

도 1 내지 도 2는 열융착 합성 필라멘트의 단면도이다.1 to 2 are cross-sectional views of heat-sealed synthetic filaments.

열융착 합성 필라멘트의 단면형태가 도 2와 같은 사이드 바이 사이드 형태인 경우에는 레이온 필라멘트의 열융착이 잘 일어나도록 시스(S) 부분을 융점이 상대적으로 낮은 섬유형성성 폴리머로 형성하는 것이 바람직하다.When the cross-sectional shape of the heat-sealed synthetic filament is a side-by-side shape as shown in FIG. 2, it is preferable to form the sheath (S) portion of the fiber-forming polymer having a relatively low melting point so that the thermal fusing of the rayon filament occurs well.

상기 2종의 섬유형성성 폴리머들 간의 융점차이는 30~130℃인 것이 열융착 합성 필라멘트의 잠재권축성을 향상시켜 레이온 필라멘트를 원사 표면으로 효과적으로 부출시키고, 레이온 필라멘트와 열융착 합성 필라멘트를 효과적으로 융착시키는데 바람직하다.The melting point difference between the two fiber-forming polymers is 30 to 130 ° C. to improve the latent crimpability of the heat-sealed synthetic filament, thereby effectively blowing the rayon filament to the yarn surface, and effectively fusing the rayon filament and the heat-sealed synthetic filament. It is preferable to.

상기 2종의 섬유형성성 폴리머들은 융점이 상이한 동일계 폴리머 이거나 융점이 상이한 이성질계 폴리머로서, 나일론계 폴리머, 폴리에스테르계 폴리머 또는 폴리프로필렌계 폴리머 등이다.The two fiber-forming polymers are in-situ polymers having different melting points or isomeric polymers having different melting points, such as nylon polymers, polyester polymers, or polypropylene polymers.

상기 열융착 합성 필라멘트를 구성하는 2종의 섬유형성성 폴리머들 중 적어도 하나의 섬유형성성 폴리머에는, 다시말해 2종의 섬유형성성 폴리머 모두 또는 2종의 섬유형성성 폴리머 중 1종의 섬유형성성 폴리머에는, 청량감을 향상시킬 목적으로 무기입자가 함유되어 있다.At least one of the fiber-forming polymers of the two fiber-forming polymers constituting the heat-sealed synthetic filament, that is, all of the two fiber-forming polymers or one of the two fiber-forming polymers The polymer contains inorganic particles for the purpose of improving the refreshing feeling.

상기 무기입자로는 산화티탄, 황산바륨, 산화아염, 실리카, 알루미나 수화물 또는 이들의 혼합물 등이 사용될 수 있다.Titanium oxide, barium sulfate, zinc oxide, silica, alumina hydrate or a mixture thereof may be used as the inorganic particles.

섬유형성성 폴리머내 무기입자의 함유량은 섬유형성성 폴리머 전체중량대비 1~10 중량%인 것이 바람직하다.The content of the inorganic particles in the fiber-forming polymer is preferably 1 to 10% by weight based on the total weight of the fiber-forming polymer.

상기 함유량이 1 중량% 미만이면 청량감 개선효과가 미미하게 되고, 10 중량%를 초과하게 되면 제사 조업성이 나빠질 우려가 있다.If the content is less than 1% by weight, the effect of improving the refreshing feel is insignificant, and if the content is more than 10% by weight, there is a concern that deterioration of the manufacturing operation is deteriorated.

상기 무기입자의 평균직경은 실험결과 0.15~2 ㎛인 것이 청량감 향상에 바람직하다.The average diameter of the inorganic particles is preferably 0.15 ~ 2 ㎛ as a result of the experiment to improve the refreshing feeling.

본 발명에 따른 레이온-열융착 필라멘트 복합섬유는 레이온 섬유와 열융착섬유를 합사, 연사 또는 커버링 한 후에 열판 또는 열튜브를 통과시키면서 상기 열융착 필라멘트 복합섬유를 구성하는 2종의 섬유형성성 폴리머들 중에서 융점이 상대적으로 낮은 섬유형성성 폴리머(A 또는 S)를 용융시켜 상기 복합섬유내 레이온 필라멘트와 열융착 합성 필라멘트 상호간을 열융착시키는 방법 등으로 제조할 수 있다.Rayon-heat-sealed filament composite fiber according to the present invention comprises two types of fiber-forming polymers constituting the heat-sealed filament composite fiber while passing through a hot plate or a heat tube after weaving, twisting or covering the rayon fiber and the heat-sealed fiber. It can be prepared by melting a relatively low melting point fiber-forming polymer (A or S) in the heat-bonding between the rayon filament and the heat-sealed synthetic filament in the composite fiber.

그로인해, 상기 레이온 필라멘트는 상기 열융착 합성 필라멘트와 열융착 되어진다.Thereby, the rayon filament is thermally fused with the thermal fusion synthetic filament.

상기 레이온 필라멘트와 열융착 합성 필라멘트의 복합 비율(중량기준)은 레이온 필라멘트 20~80 중량%와 열융착 합성 필라멘트 80~20 중량%인 것이 청량감과 볼륨감을 동시에 향상시키는데 바람직하다.The composite ratio (weight basis) of the rayon filament and the heat-sealed synthetic filament is 20 to 80% by weight of the rayon filament and the 80 to 20% by weight of the heat-sealed synthetic filament is preferable to improve the refreshing feel and the volume.

레이온 필라멘트 복합비율이 20 중량% 미만인 경우에는 볼륨감이 저하되고, 80 중량%를 초과하는 경우에는 청량감이 저하될 수 있다.If the rayon filament composite ratio is less than 20% by weight, the feeling of volume may be lowered, and if it exceeds 80% by weight, the cooling feeling may be reduced.

레이온 필라멘트와 열융착 합성 필라멘트의 복합비율은 상기 범위내에서 용도 등에 따라 적절하게 조절된다.The composite ratio of the rayon filament and the heat-sealed synthetic filament is appropriately adjusted according to the use and the like within the above range.

본 발명에서 볼륨감이 향상되는 원리를 살펴보면, 레이온 필라멘트의 열수축율 보다는 열융착 합성 필라멘트의 열수축율이 상대적으로 높기 때문에, 열처리시 열수축율이 상대적으로 큰 열융착 합성 필라멘트가 보다 많이 수축되면서 열수축율이 상대적으로 작은 레이온 필라멘트를 레이온-열융착 필라멘트 복합섬유의 표면으로 부출시키기 때문에 볼륨감이 향상된다.Looking at the principle of improving the sense of volume in the present invention, since the heat shrinkage of the heat-sealed synthetic filament is relatively higher than the heat shrinkage of the rayon filament, the heat shrinkage rate as the heat-shrinkage synthetic filament relatively large shrinkage during heat treatment The relatively small rayon filament is ejected to the surface of the rayon-heat-sealed filament composite fiber, thereby improving the volume.

이하, 실시예 및 비교실시예를 통하여 본 발명을 상세하게 설명한다.Hereinafter, the present invention will be described in detail with reference to examples and comparative examples.

그러나, 본 발명은 하기 실시예 만으로 보호범위가 한정되는 것은 아니다.However, the present invention is not limited to the protection scope only in the following examples.

실시예 1Example 1

융점이 255℃이며 입자직경이 0.35 ㎛인 이산화티탄을 2.5 중량% 함유하는 폴리에스테르 폴리머로 구성된 코어(C)와 융점이 178℃인 공중합 폴리에스테르 폴리머로 구성된 시스(S)가 원사 단면상에 열융착되어 있는 75데니어/24필라멘트의 열융착 합성 필라멘트(시스-코어 형태)와 75데니어/24필라멘트의 레이온 필라멘트를 연사기에서 500 T/M(미터당 꼬임수)으로 합연사한 후 185℃의 연사기내 열판을 120 m/분의 속도로 통과시켜 레이온-열융착 필라멘트 복합섬유를 제조하였다.The core (C) consisting of a polyester polymer containing 2.5% by weight of titanium dioxide having a melting point of 255 ° C. and a particle diameter of 0.35 μm and a sheath (S) consisting of a co-polyester polymer having a melting point of 178 ° C. are heat-sealed on the yarn cross section. Heat-sealed synthetic filament of 75 denier / 24 filament (sheath-core form) and rayon filament of 75 denier / 24 filament were twisted together at 500 T / M (twist per meter) in a twisting machine and then heated at 185 ℃ Was passed at a speed of 120 m / min to prepare a rayon-heat-sealed filament composite fiber.

이와같이 제조한 레이온-열융착 필라멘트 복합섬유를 경사 및 위사로 사용하여 위사밀도가 76 본/인치이고 경사밀도가 108 본/인치인 평직직물을 제조하였다.Using the rayon-heat-sealed filament composite fiber thus prepared as warp and weft yarn, a plain weave fabric having a weft density of 76 bones / inch and a warp density of 108 bones / inch was prepared.

제조된 직물의 볼륨감, 청량감 및 외관을 측정한 결과는 표 1과 같았다.The results of measuring the volume, coolness and appearance of the fabric were as shown in Table 1.

실시예 2Example 2

융점이 255℃이며 입자직경이 0.35 ㎛인 이산화티탄을 2.5 중량% 함유하는 폴리에스테르 폴리머로 구성된 코어(C)와 융점이 178℃인 공중합 폴리에스테르 폴리머로 구성된 시스(S)가 원사 단면상에 열융착되어 있는 120데니어/24필라멘트의 열융착 합성 필라멘트(시스-코어 형태)와 150데니어/30필라멘트의 레이온 필라멘트를 연사기에서 850 T/M(미터당 꼬임수)으로 합연사한 후 185℃의 연사기내 열판을 120 m/분의 속도로 통과시켜 레이온-열융착 필라멘트 복합섬유를 제조하였다.The core (C) consisting of a polyester polymer containing 2.5% by weight of titanium dioxide having a melting point of 255 ° C. and a particle diameter of 0.35 μm and a sheath (S) consisting of a co-polyester polymer having a melting point of 178 ° C. are heat-sealed on the yarn cross section. Heat-bonded synthetic filament of 120 denier / 24 filament (sheath-core form) and rayon filament of 150 denier / 30 filament in a twisting machine at 850 T / M (twist per meter) Was passed at a speed of 120 m / min to prepare a rayon-heat-sealed filament composite fiber.

이와같이 제조한 레이온-열융착 필라멘트 복합섬유를 경사 및 위사로 사용하여 위사밀도가 55 본/인치이고 경사밀도가 77 본/인치인 평직직물을 제조하였다.Using the rayon-heat-sealed filament composite fiber thus prepared as warp and weft yarn, a plain weave fabric having a weft density of 55 bones / inch and a warp density of 77 bones / inch was prepared.

제조된 직물의 볼륨감, 청량감 및 외관을 측정한 결과는 표 1과 같았다.The results of measuring the volume, coolness and appearance of the fabric were as shown in Table 1.

실시예 3Example 3

융점이 255℃이며 입자직경이 0.35 ㎛인 이산화티탄을 2.5 중량% 함유하는 폴리에스테르 폴리머로 구성된 코어(C)와 융점이 125℃이며, 입자직경이 0.30 ㎛인 이산화티탄을 2.0 중량% 함유하는 폴리프로필렌 폴리머로 구성된 시스(S)가 원사 단면상에 열융착되어 있는 75데니어/24필라멘트의 열융착 합성 필라멘트(시스-코어 형태)와 75데니어/24필라멘트의 레이온 필라멘트를 연사기에서 500 T/M(미터당 꼬임수)으로 합연사한 후 140℃의 연사기내 열판을 120 m/분의 속도로 통과시켜 레이온-열융착 필라멘트 복합섬유를 제조하였다.Core (C) consisting of a polyester polymer containing 2.5% by weight of titanium dioxide having a melting point of 255 ° C. and a particle diameter of 0.35 μm and a polycarbonate containing 2.0% by weight of titanium dioxide having a melting point of 125 ° C. and a particle diameter of 0.30 μm. Sheath (S) made of propylene polymer is heat-sealed 75 f / m filament heat-sealed synthetic filament (sheath-core type) and 75 d / f filament rayon filament at 500 T / M (per meter) After the twisted yarns were twisted and twisted, the rayon-heat-sealed filament composite fiber was manufactured by passing a hot plate in a twisting machine at 140 ° C. at a speed of 120 m / min.

이와같이 제조한 레이온-열융착 필라멘트 복합섬유를 경사 및 위사로 사용하여 위사밀도가 76 본/인치이고 경사밀도가 108 본/인치인 평직직물을 제조하였다.Using the rayon-heat-sealed filament composite fiber thus prepared as warp and weft yarn, a plain weave fabric having a weft density of 76 bones / inch and a warp density of 108 bones / inch was prepared.

제조된 직물의 볼륨감, 청량감 및 외관을 측정한 결과는 표 1과 같았다.The results of measuring the volume, coolness and appearance of the fabric were as shown in Table 1.

실시예 4Example 4

융점이 245℃이며 입자직경이 0.35 ㎛인 이산화티탄을 2.5 중량% 함유하는 나일론 66 폴리머로 구성된 제1의 섬유형성성 폴리머(A)와 융점이 215℃인 나일론 6 폴리머로 구성된 제2의 섬유형성성 폴리머(B)가 원사 단면상에 열융착되어 있는 120데니어/24필라멘트의 열융착 합성 필라멘트(사이드 바이 사이드 형태)와 150데니어/30필라멘트의 레이온 필라멘트를 연사기에서 500 T/M(미터당 꼬임수)으로 합연사한 후 220℃의 연사기내 열판을 120 m/분의 속도로 통과시켜 레이온-열융착 필라멘트 복합섬유를 제조하였다.First fiber forming polymer (A) consisting of nylon 66 polymer containing 2.5% by weight of titanium dioxide having a melting point of 245 ° C. and a particle diameter of 0.35 μm, and forming a second fiber consisting of nylon 6 polymer having a melting point of 215 ° C. Heat-sealed synthetic filaments of 120 denier / 24 filaments (side by side) and rayon filaments of 150 denier / 30 filaments, in which the polymeric polymer (B) is heat-sealed on the cross section of the yarn, and 500 T / M (twist per meter) in the twisting machine After the twisted yarns were prepared, rayon-heat-sealed filament composite fibers were manufactured by passing a hot plate in a twisting machine at 220 ° C. at a speed of 120 m / min.

이와같이 제조한 레이온-열융착 필라멘트 복합섬유를 경사 및 위사로 사용하여 위사밀도가 76 본/인치이고 경사밀도가 108 본/인치인 평직직물을 제조하였다.Using the rayon-heat-sealed filament composite fiber thus prepared as warp and weft yarn, a plain weave fabric having a weft density of 76 bones / inch and a warp density of 108 bones / inch was prepared.

제조된 직물의 볼륨감, 청량감 및 외관을 측정한 결과는 표 1과 같았다.The results of measuring the volume, coolness and appearance of the fabric were as shown in Table 1.

비교실시예 1Comparative Example 1

융점이 255℃인 폴리에스테르 폴리머로 구성된 75데니어/24필라멘트의 정규 폴리에스테르 필라멘트와 75데니어/24필라멘트의 레이온 필라멘트를 연사기에서 500 T/M(미터당 꼬임수)으로 합연사한 후 185℃의 연사기내 열판을 120 m/분의 속도로 통과시켜 레이온-폴리에스테르 필라멘트 복합섬유를 제조하였다.75-denier / 24 filament regular polyester filament and 75-denier / 24 filament rayon filament composed of a polyester polymer having a melting point of 255 ° C. were twisted together at 500 T / M (twist per meter) in a twisting machine and then twisted at 185 ° C. Rayon-polyester filament composite fibers were produced by passing an in-flight hot plate at a speed of 120 m / min.

이와같이 제조한 레이온-폴리에스테르 필라멘트 복합섬유를 경사 및 위사로 사용하여 위사밀도가 76 본/인치이고 경사밀도가 108 본/인치인 평직직물을 제조하였다.Using the prepared rayon-polyester filament composite fiber as a warp and weft yarn, a plain weave fabric having a weft density of 76 bones / inch and a warp density of 108 bones / inch was prepared.

제조된 직물의 볼륨감, 청량감 및 외관을 측정한 결과는 표 1과 같았다.The results of measuring the volume, coolness and appearance of the fabric were as shown in Table 1.

비교실시예 2Comparative Example 2

굵기가 40'S인 면 방적사를 경사 및 위사로 사용하여 위사밀도가 76 본/인치이고 경사밀도가 108 본/인치인 평직직물을 제조하였다.A cotton weave having a thickness of 40'S was used as the warp and weft yarn to prepare a plain weave fabric having a weft density of 76 bones / inch and a warp density of 108 bones / inch.

제조된 직물의 볼륨감, 청량감 및 외관을 측정한 결과는 표 1과 같았다.
The results of measuring the volume, coolness and appearance of the fabric were as shown in Table 1.

구분division 청량감Refreshing feeling 볼륨감Volume sense 원단품위Fabric 실시예 1Example 1 우수Great 우수Great 우수Great 실시예 2Example 2 우수Great 우수Great 우수Great 실시예 3Example 3 우수Great 우수Great 우수Great 실시예 4Example 4 우수Great 우수Great 우수Great 비교실시예 1Comparative Example 1 우수Great 불량Bad 우수Great 비교실시예 2Comparative Example 2 불량Bad 우수Great 우수Great

표 1의 청량감, 볼륨감 및 원단품위는 전문가 10명의 평가결과 전문가 6명 이상이 양호한 것으로 판단하면 "우수"로 구분하였고, 전문가 5명 이하가 양호한 것으로 판단하면 "불량"으로 구분하였다.
The cooling, volume and fabric quality of Table 1 were classified as "excellent" when six or more experts judged to be good as a result of 10 experts, and classified as "poor" when less than five experts were good.

S : 융점이 상대적으로 낮은 섬유형성성 폴리머인 쉬스(Sheath)
C : 융점이 상대적으로 높은 섬유형성성 폴리머인 코어(Core)
A : 융점이 상대적으로 낮은 제1의 섬유형성성 폴리머
B : 융점이 상대적으로 높은 제2의 섬유형성성 폴리머
S: Sheath, a fibrous polymer having a relatively low melting point
C: Core, a fiber-forming polymer with a relatively high melting point
A: first fibrous polymer having a relatively low melting point
B: second fiber-forming polymer having a relatively high melting point

Claims (6)

(ⅰ) 융점이 서로 상이한 2종의 섬유형성성 폴리머들이 원사단면 상에서 열융착되어있는 열융착 합성 필라멘트와 (ⅱ) 상기 2종의 섬유형성성 폴리머들 중에서 융점이 상대적으로 낮은 1종의 섬유형성성 폴리머와 열융착되어 있는 레이온 필라멘트로 구성되며, 상기 2종의 섬유형성성 폴리머들 중 적어도 하나의 섬유형성성 폴리머 내에 무기입자가 함유되어 있는 것을 특징으로 하는 볼륨감과 청량감이 우수한 레이온 필라멘트-열융착 합성 필라멘트 복합섬유.(Iii) two types of fibrous polymers having different melting points from each other, wherein the heat-sealed synthetic filaments are thermally fused on the yarn cross-section, and (ii) one of the two fiber forming polymers having a relatively low melting point. Rayon filament-heat having excellent volume and refreshing feeling, comprising inorganic polymers and rayon filaments thermally fused to the polymer and containing inorganic particles in at least one of the two fiber-forming polymers. Fusion synthetic filament composite fiber. 제1항에 있어서, 상기 2종의 섬유형성성 폴리머들 간의 융점차이가 30~130℃인 것을 특징으로 하는 볼륨감과 청량감이 우수한 레이온 필라멘트-열융착 합성 필라멘트 복합섬유.The rayon filament-heat-sealed synthetic filament composite fiber excellent in volume and refreshing feel according to claim 1, wherein the melting point difference between the two fiber-forming polymers is 30 to 130 ° C. 제1항에 있어서, 상기 열융착 합성 필라멘트는 2종의 섬유형성성 폴리머들이 원사 단면상에서 시스-코어(Sheath-core) 형태 및 사이드 바이 사이드(Side by side) 형태 중에서 선택된 1종의 형태로 열융착되어 있는 것을 특징으로 하는 볼륨감과 청량감이 우수한 레이온 필라멘트-열융착 합성 필라멘트 복합섬유.The method of claim 1, wherein the heat-sealed synthetic filament is heat-treated in the form of one of the two fiber-forming polymers selected from a sheath-core form and a side by side form on the yarn cross-section Rayon filament-heat-sealed synthetic filament composite fiber excellent in volume and coolness, characterized by being fused. 제1항에 있어서, 섬유형성성 폴리머 내 무기입자의 함유량이 섬유형성성 폴리머 전체중량대비 1~10 중량%인 것을 특징으로 하는 볼륨감과 청량감이 우수한 레이온 필라멘트-열융착 합성 필라멘트 복합섬유.The rayon filament-heat-sealed synthetic filament composite fiber excellent in volume and refreshing feel according to claim 1, wherein the content of the inorganic particles in the fiber-forming polymer is 1 to 10% by weight based on the total weight of the fiber-forming polymer. 제1항 또는 제4항에 있어서, 무기입자의 평균직경이 0.15~2.00㎛인 것을 특징으로 하는 볼륨감과 청량감이 우수한 레이온 필라멘트-열융착 합성 필라멘트 복합섬유.The rayon filament-heat-sealed synthetic filament composite fiber excellent in volume and refreshing feeling according to claim 1 or 4, wherein the average particle diameter of the inorganic particles is 0.15 to 2.00 µm. 제1항의 레이온 필라멘트-열융착 합성 필라멘트 복합섬유를 포함하는 것을 특징으로 하는 원단.
A fabric comprising the rayon filament-heat fusion synthetic filament composite fiber of claim 1.
KR1020110028573A 2011-03-30 2011-03-30 Composite fiber consisting rayon filament and heat melted synthetic filament with excellent volume and cooling feel, and fabric manufactured thereby KR101269893B1 (en)

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JP3563483B2 (en) 1995-03-31 2004-09-08 日本バイリーン株式会社 Air filter medium and method of manufacturing the same

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