KR101268530B1 - Method for preparing a colloidal ionic material using an extracts of acorn and products containing the same - Google Patents

Abstract

The present invention provides a method for producing a colloidal ionic material using acorn starch and a product containing the ionic material. The present invention can be used to prepare the colloidal ionic minerals produced through the fermentation process from the acorns and add them to cosmetic soaps, basic cosmetics and the like to remove the contaminants of the skin and prevent aging of the skin. have.

Description

Method for preparing a colloidal ionic material using acorn starch and product containing the ionic material {Method for preparing a colloidal ionic material using an extracts of acorn and products containing the same}

The present invention relates to a method for producing a colloidal ionic material using acorn starch and to a product containing the ionic material.

Acorns have long been used to remove heavy metals in heavy metal wastewater by washing them with powder, making them into powdered jelly, or using tannin in acorns. In addition, it is recorded that the consent of oriental medicine doctors is easy to treat the cause even if one takes acorn jelly for people who are always hungry and hungry, irregularly or immediately after the meal, people who stool urine frequently, and those who swell frequently. have. In addition, acorns themselves are said to control hemorrhoids, stop bleeding and lineage, strengthen the intestines, dry people gain weight, and manage diarrhea.

Meanwhile, in recent years, as consumers' interest in skin health increases, there is an attempt to apply acorn extract to skin beauty or cosmetics. For example, Patent Document 1 discloses a method for producing an acorn extract having a cell membrane protective action, an antioxidant action, an astringent action, and an excellent whitening action, and a novel useful cosmetic containing the same to provide anti-aging and whitening functions.

However, the patent simply uses acorn extract as a cosmetic, and the effect tends to be inferior.

Patent Document 1: Korean Patent Publication No. 1999-0084488

Thus, in the present invention, the acorn extract was converted into colloidal ionic substances to suppress the cleanliness of skin cells and aging of the skin in daily life, and the present invention was completed based on this.

Accordingly, it is an object of the present invention to provide a method for preparing colloidal ionic materials using acorn starch which is environmentally friendly and removes contaminants causing skin diseases using natural products and can supply ionic minerals of the skin.

It is another object of the present invention to provide a product containing the above ionic substance which can provide functional benefits for skin health through daily life.

Method for producing a colloidal ionic material using acorn starch to achieve the above object is to remove the tannin component by immersing the acorn powder in water; Mixing the acorn starch from which the tannin is removed and water, and then adding an enzyme to decompose the protein and the starch; Inactivating the enzyme, followed by filtration to obtain a filtrate; Fermenting the filtrate by adding seawater salt and yeast; And killing the yeast, and then filtering after centrifugation.

In the method for producing a colloidal ionic material of the present invention, the mixing ratio of starch and water is characterized in that 1: 2.

In the method of the present invention, the enzyme is a protease and amylase enzyme, characterized in that added to 0.3 to 0.5% by weight relative to the mixture of starch and water.

In the method of the present invention, the addition amount of the filtrate, seawater salt and yeast is 79 to 90% by weight, 9 to 20% by weight and 1 to 1.5% by weight, respectively.

In the method of the present invention, the yeast is Saccharomyces cerevisiae .

A product for achieving another object of the present invention contains a colloidal ionic material prepared by the above method.

In the product of the present invention, the product is a cosmetic soap, a lotion lotion, or a skin cleanser.

When the product containing the colloidal ionic substance of the present invention is used in cosmetic soap, cosmetic lotion, etc., there is no skin trouble, the skin regenerating ability and recovery is quick, and skin diseases such as acne due to secondary contamination by bacteria The recovery shows a rapid recovery process, and it is excellent in functionality and excellent in preventing various skin. In addition, after use, it is possible to increase the utilization of the product according to the present invention by showing a refreshing and fresh. Therefore, it will be able to contribute not only to the income increase of farmers using acorns, but also to provide a preventive product for skin diseases such as atopic acne, which is a skin disease that is likely to occur to modern people.

1 is a process chart showing a process for preparing a colloidal ionic mineral component in a fermentation process using acorns according to an embodiment of the present invention.

Hereinafter, the present invention will be described in more detail with reference to the accompanying drawings.

As described above, the present invention removes the outer shell using the oak fruit (acorn) grown in the oak family Quercus acutissima CARRUTH in our country, and washed with water to remove the tannin component to the components extracted with water Season with salt and yeast Saccharomyces obtained from seawater in my busy access Sergio (Saccharomyces cerevisiae ), and a method for producing a colloidal ionized mineral component produced during the fermentation process and a product containing the same.

1 is a process chart showing a process for preparing a colloidal ionic mineral component in a fermentation process using acorns according to an embodiment of the present invention.

Referring to FIG. 1, acorn fruit contains a large amount of tannin components, on average about 3% by weight protein, about 40% by weight carbohydrate, about 5.5% by weight fat and oil, and about 10 to 20% by weight tannin. Such a large amount of tannin components can suppress the fermentation of yeast, which is a microorganism. Since the final component is a mineral component, a high tannin content decreases the yield of minerals that can be ionized by combining minerals with tannins. In order to reduce the weight to 3% by weight, the acorns are sun-dried to make powder, and then the water and the powder are finely starved through a fine filter net, and after natural immersion, the astringent taste of tannins is removed.

The starch thus obtained is mixed with a solvent, preferably water, in a ratio of 1: 2 and the enzyme is mixed through a routine method used in a food factory, for example, about 0.5: 1 of a protease and amylase enzyme. After mixing the mixture by weight ratio of 0.3 to 0.5% by weight relative to the total weight of the mixture of about 0.3 to 0.5% by weight and about 8 hours at 40 ℃ to 50 ℃ starch and proteolytic step, about 30 minutes at 75 ℃ to 90 ℃ After going through a sterilization and enzyme inactivation process, the filtrate is obtained by filtration.

Next, the fermentation process is performed using the filtrate, seawater salt, and yeast, preferably Saccharomyces cerevisiae , which is the main agent of fermentation. After 79 to 90% by weight of the filtrate, 9 to 20% by weight of seawater salt and 1 to 1.5% by weight of yeast, the mixture (W / W) ratio was incubated for about 48 hours at 30 ° C to 35 ° C, followed by fermentation. The yeast was killed at 75 ° C. to 80 ° C., and then the cell wall of the yeast was destroyed by ultrasonic and high pressure homogeneous 2.0 mbar to 2.5 mbar pressure, followed by centrifugation, followed by filtration through a fine filter network to obtain a filtrate. .

The seawater salt is very preferable to form colloidal ionic substances because it contains little impurities and contains a large amount of minerals. The amount of the seawater salt is 9 to 20% by weight, less than 9% by weight of the mineral content is lowered, exceeds 20% by weight of the fermentation of yeast is suppressed, the fermentation time is long, as well as the proliferation of microorganism yeast tends to be difficult There is this. In addition, if the addition amount of the yeast is less than 1% by weight, the fermentation rate is slowed, and the fermentation time is long, and even if it is added in excess of more than 1.5% by weight, it is preferable in terms of economics.

As described above, in the present invention, the acorn extract is fermented using seawater salt and yeast to form particles of the fermentation broth with nano-sized colloid. In colloids, particles spread evenly and float in a 'solvent'. In other words, the particles are small enough to exhibit the same physical properties in any part of the colloid, and minerals derived from the seawater salt act as useful components for the skin and the like, and the components liberated from acorns adsorb harmful substances such as heavy metals well. It performs the function.

According to the present invention, the filtrate can be easily obtained when the filtrate is at a temperature of 30 ° C to 35 ° C at all times, and a long time to obtain the filtrate when the temperature is filtered at a temperature of 10 ° C to 20 ° C. Will cost.

When the material obtained through the process of the present invention is analyzed, 1,3,4-trigalloyl acid (1.3.4-Tri-O-Galloylquinic) in the acorn extract is increased after the fermentation process. The 1,3,4-trigalloyl acid is a compound of polyphenols having an inhibitory effect on the antioxidant, antiviral and parasites of the skin and is a useful ingredient for skin beauty.

The colloidal ionic material thus obtained can be used as a cosmetic soap, lotion lotion, or skin cleanser. The product containing the colloidal ionic substance has no skin troubles when used in cosmetic soaps, cosmetics, etc., and has a fast skin regeneration ability and recovery, and also recovers skin diseases such as acne due to secondary contamination by bacteria. By showing a rapid recovery, it is excellent in functionality and excellent in preventing various skin. In addition, after use, it is possible to increase the utilization of the product according to the present invention by showing a refreshing and fresh.

Hereinafter, the present invention will be described in more detail with reference to the following examples. However, the following examples are not intended to limit the scope of the present invention.

Example 1

Preparation of Colloidal Ionic Materials by Fermentation Using Acorn Starch

Step 1-1: Extraction of Acorns

The acorns are dried well in the sun to make powder, and then the water and the powders are fine starch particles through a fine filter net. After 6 hours of soaking, the astringent tannins are removed to about 2%. The starch thus obtained was mixed with water at a ratio of 1: 2, and 0.4 weight of a protease (Denmark's Novo Nordisk company: Nutrase) and amylase at a weight ratio of 0.5: 1 with respect to 100% by weight of the mixture. Add% Then, after starch and proteolysis for about 8 hours at about 45 ℃, sterilization and enzyme deactivation for about 30 minutes at about 80 ℃. The constituent ratio of the filtrate obtained by filtration thereof contains the components shown in Table 1 below. The analysis method of this component was analyzed using TLC method of AOAC method.

ingredient Content (% by weight) Tannin acid 1.5 to 2.5 Gallic acid 0.05 to 0.1 1,3,4-tri galloyl acid (1.3.4-Tri-O-Galloylquinic) 0.01 to 0.02 Crude protein 1.0 to 1.5 carbohydrate 35.0-38.0 moisture 62.0-59.0

Step 1-2: Extraction method of colloidal ionic substance through fermentation

This 1-2 process is a fermentation using 85% by weight of the filtrate obtained in step 1-1, 14% by weight of seawater salt, and 1% by weight of Saccharomyces cerevisiae , the yeast that is the main ingredient of the fermentation. After about 48 hours incubation and fermentation process at about 33 ℃, the yeast was killed at about 80 ℃. Then, after breaking the cell wall of the yeast by ultrasonic and high pressure homogeneous about 2.0 mbar pressure, after centrifugation, the filtrate obtained through a fine filtering network at about 31 ℃ was obtained.

The results of analyzing the filtrate obtained through this process are shown in Table 2 below. This assay method was analyzed by AOAC method.

ingredient Content (% by weight) Crude protein 6.0-8.0 carbohydrate 30.0-40.0 Tannic acid 1.0 to 2.0 Garlic acid grain 1,3,4-tri galloyl acid 0.05 to 0.1 salt 1.0-2.0mg Goat 2.0-4.0 mg Cerium 1.0-1.5mg calcium 1.5-2.0 mg

As a result, the fermentation process was found to increase the 1,3,4-tri galloyl acid in the acorn extract than in the 1-1 process.

Examples 2-6

Beauty soap manufacturing process

After adding the vegetable fatty acid, vegetable oil, glycerin, and purified water to dissolve the oil well at 65 ° C. to 75 ° C., adding potassium hydroxide to the saponification reaction, and adjusting the pH with citric acid as an acidic agent. The extract and the perfume of Example 1 was added to prepare a cosmetic water soap, this was adjusted in five stages as shown in Table 3.

ingredient
Example (weight ratio) One 2 3 4 5 Extract of the Invention One 2 4 6 8 Purified water 55 54 52 50 48 Vegetable fatty acids 20 20 20 20 20 vegetable oil 5 5 5 5 5 glycerin 15 15 15 15 15 Potassium hydroxide 4 4 4 4 4 PH regulators and
Drug (lavender) a very small amount a very small amount a very small amount a very small amount a very small amount

Comparative Examples 1 to 5

Without adding the extract obtained in Example 1, the cosmetic soap was treated in the same manner, and then chitosan, which is generally used as a moisturizing and cleansing effect, was added to prepare cosmetic soap as shown in Table 4 below.

ingredient
Comparative example (weight ratio) One 2 3 4 5 Chitosan 0 2 4 6 8 Purified water 56 54 52 50 48 Vegetable fatty acids 20 20 20 20 20 vegetable oil 5 5 5 5 5 glycerin 15 15 15 15 15 Potassium hydroxide 4 4 4 4 4 PH regulators and
Drug (lavender) a very small amount a very small amount a very small amount a very small amount a very small amount

Examples 7 to 10 and Comparative Example 6

Cosmetic lotion manufacturing process of basic cosmetics

Vegetable oil, glycerin, purified water was dissolved in the oil well at 65 ℃ ~ 75 ℃, the emulsifier was added to complete the emulsification process, after adjusting the pH with citric acid as an acidic agent, the extract and perfume of Example 1 was added To prepare a lotion of the basic cosmetics, it was adjusted in five stages as shown in Table 5.

Mixing ratio of the lotion produced by the present invention ingredient
Comparative Example and Example (weight ratio) Comparative Example 6 Example 7 8 9 10 Extract of the Invention One 2 4 6 8 Purified water 90 89 87 85 83 vegetable oil 5 5 5 5 5 glycerin 3 3 3 3 3 Emulsifier (Olive Ester) 4 4 4 4 4 PH regulators and
Drug (lavender) a very small amount a very small amount a very small amount a very small amount a very small amount

Comparative Examples 7 to 11

In addition to the extract obtained by the present invention, the treatment was carried out by the same method of the preparation of the lotion in the basic cosmetics, and then the skin lotion was prepared in five steps as shown in Table 6 by adding chitosan, which is generally used as a moisturizing and cleansing effect. .

ingredient
Comparative example (weight ratio) 7 8 9 10 11 Chitosan One 2 4 6 8 Purified water 90 89 87 85 83 vegetable oil 5 5 5 5 5 glycerin 3 3 3 3 3 Emulsifier (Olive Ester) 4 4 4 4 4 PH regulators and
Drug (lavender) a very small amount a very small amount a very small amount a very small amount a very small amount

Experimental Example 1

The skin soaps of the cosmetic soaps prepared in Examples 2 to 6 and Comparative Examples 1 to 5 were used in the following manner. In addition, the skin condition after the use of the lotion prepared in Examples 7 to 10 and Comparative Examples 6 to 11 were tested in the following manner.

The skin condition is 13 points for optimal condition, 4 points for skin recovery due to bacterial nature, 3 points for road hardness, and 0 points for no road, targeting 50 adult men and women under the age of 18 to 25 who have trouble or have acne. By using Example 60 days, Comparative Example 60 days, the recovery test was carried out to take the average value, the results were as shown in Table 7, Table 8, Table 9, and Table 10 below. .

Item Optimal Bacterial Skin Recovery Roadway No car Example 2 11 2 2 Example 3 12 2 2 Example 4 12 3 3 Example 5 13 3 3 Example 6 13 3 3

Item Skin condition Bacterial Skin Recovery Roadway No car Comparative Example 1 0 0 0 Comparative Example 2 5 One One Comparative Example 3 5 One One Comparative Example 4 6 One One Comparative Example 5 6 2 2

Item Skin condition Bacterial Skin Recovery Roadway No car Comparative Example 6 8 2 2 Example 7 13 2 2 Example 8 13 3 3 Example 9 13 3 3 Example 10 13 3 3

Item Skin condition Bacterial Skin Recovery Roadway No car Comparative Example 7 0 0 0 Comparative Example 8 8 2 2 Comparative Example 9 8 2 2 Comparative Example 10 12 3 3 Comparative Example 11 13 3 3

As shown in Table 7 and Table 8, the cosmetic water soap to which the colloidal ion extract prepared according to the present invention prepared by Example 5 in Example 1 is added, the general cosmetic soap prepared by Comparative Example 5 in Comparative Example 1 Compared to the quick regeneration and effect of the skin was found to be excellent.

In addition, in the case of the lotion, as shown in Table 9 and Table 10, the lotion to which the colloidal ion extract prepared according to the present invention prepared in Example 7 to Example 10 is added Comparative Example 6 and Comparative Example 7-11 It was shown that the skin regeneration and the effect was excellent compared to the general chitosan added to the lotion prepared by the fast time.

However, it can be seen that the cosmetic soap of the colloidal ionic substance extracted by the present invention is preferably added at least 2% by weight. In addition, as a result of using this experiment, the recovery of the skin was faster, but after using the general beauty soap after recovery, the skin trouble occurred again in the dry season, but after using the product according to the present invention, the skin was recovered again. .

Claims (7)

Immersing the acorn powder in water to remove the tannin component;
Mixing the acorn starch from which the tannin is removed and water, and then dissolving the protein and starch by adding neutrases and amylases;
Inactivating the enzyme, followed by filtration to obtain a filtrate;
Adding seawater salt and Saccharomyces cerbizi to the filtrate to ferment to produce a colloidal ionic material; And
Killing the yeast, and then centrifuging and filtering to obtain a colloidal ionic material.
Method for producing a colloidal ionic material using acorn starch. The method according to claim 1,
Mixing ratio of the starch and water is 1: 2. The method according to claim 1,
0.3 to 0.5% by weight relative to the mixture of starch and water. The method according to claim 1,
The amount of the filtrate, seawater salt and yeast is 79 to 90% by weight, 9 to 20% by weight and 1 to 1.5% by weight, respectively. delete An article containing a colloidal ionic material prepared by the method of claim 1. The method of claim 6,
The product is a cosmetic soap, lotion lotion, or skin cleansing agent.

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