KR101153650B1 - Method for manufacturing thermal spray powders, swash plate of car air conditioning system and thermal coating material of swash plate - Google Patents

Abstract

The present invention is Si: 2 to 2.5% by weight, P: 5 to 6% by weight, Cr: 2 to 3% by weight, Mo: 5 to 6% by weight, B: 1 to 2% by weight, and Fe (including impurities): Mixing each component of an amorphous powder having 80.5 to 85 wt%; And it provides a method for producing a mixed spray powder comprising the step of mixing the amorphous powder of 80 to 95% by weight and molybdis sulfide 5 to 20% by weight. According to the present invention, by using the thermal spray coating with the mixed spray powder of the present invention on a swash plate used to compress a refrigerant for an automotive air conditioner, it is possible to manufacture a swash plate having improved wear resistance and low friction even without the use of lead which is very harmful to the environment. Excellent characteristics provide the effect of extending the service life of the swash plate.

Swash plate, spray coating for car air conditioner

Description

Manufacturing method of mixed spray powder, swash plate and swash plate coating material for automobile air conditioning {METHOD FOR MANUFACTURING THERMAL SPRAY POWDERS, SWASH PLATE OF CAR AIR CONDITIONING SYSTEM AND THERMAL COATING MATERIAL OF SWASH PLATE}

The present invention relates to a method for producing a mixed spray powder and a spray coating material for a swash plate and a swash plate for an automobile air conditioner.

In general, the swash plate for the car air conditioner is used under high load and high speed rotation, and high wear resistance is required along with the low friction property of the material.

Recently, in accordance with the trend of lighter weight and higher functionality of automobiles, the situation is gradually changing to a variable swash plate which is superior in refrigerant cooling efficiency than the fixed swash plate used in the past.

The variable swash plate is characterized by high load and high speed rotation compared with the conventional fixed type, and requires low friction and excellent wear resistance compared to the fixed swash plate composed of the existing Al-Si casting structure.

In response to the required characteristics of the variable swash plate, U.S. Patent No. 5,875,702 has abrasion resistant alumina, silica and the like mixed with a base of Sn, Al, etc. centering on Pb, which is a low friction material, to form a coating layer of swash plate. In No. 6,123,009, a low friction material such as MoS ₂ was coated with epoxy resin on Cu + Sn base. In US Patent No. 6,344,280, a large amount (60%) of Si was added to Al base to obtain light weight and high wear resistance. Low friction materials such as MoS ₂ and carbon were added to realize low frictional wear characteristics of the swash plate.

In addition, Korean Patent Application No. 2000-99642 prepared a swash plate by forming a thermal spraying coating layer by mixing Cu-Pb-Sn powder and Al-Si powder, wherein the Cu-Pb-Sn powder Pb was used as a low friction material, and the Al-Si alloy powder was alloyed with a large amount of Si to improve the wear resistance of the swash plate by using the high hardness property of Si.

However, although many efforts have been made as described above, in forming the thermal spray coating layer on the variable swash plate, it is inadequate to improve the anti-sintering characteristics, and in order to improve such characteristics, a large amount of lead (Pb) is inevitably increased (10% to 16%). As it is well known, lead is a very harmful element to the environment, and its use is strictly regulated around the world, so there is a serious demand for a new alternative to solve it.

The present invention is to solve the above problems, it is possible to improve the low friction characteristics of the coating layer even if the removal of harmful lead to the environment, as well as the excellent molybdenum powder and the excellent lubrication characteristics of the amorphous powder that has been difficult to coat by thermal spray coating The powder mixed with sulfide (MoS ₂ ) is thermally coated using an ultra-fast spraying machine to provide high abrasion and low friction characteristics, which are general characteristics of amorphous materials, as well as lubricating properties of molybdi sulfide, thereby providing wear resistance and low friction characteristics. It is an object of the present invention to provide a method for manufacturing a swash plate for an automobile air conditioner.

As a means for solving the above problems,

The present invention is Si: 2 to 2.5% by weight, P: 5 to 6% by weight, Cr: 2 to 3% by weight, Mo: 5 to 6% by weight, B: 1 to 2% by weight, and Fe (including impurities): Mixing each component of an amorphous powder having 80.5 to 85 wt%; And it provides a method for producing a mixed spray powder comprising the step of mixing the amorphous powder of 80 to 95% by weight and molybdis sulfide 5 to 20% by weight.

In addition, the amorphous powder mixed with each of the components provides a method for producing a mixed spray powder, characterized in that further comprising the step of adding a corresponding component by weighing the content of the deficiency of each component in the pig iron (Pig iron).

In addition, the amorphous powder mixed with each of the components provides a method for producing a mixed spray powder comprising the step of dissolving each component and then tapping and cooling by spraying nitrogen gas at the same time and then finely divided.

In addition, after the micronization provides a method for producing a mixed spray powder, characterized in that the classification by particle size through the sieving.

In addition, the tapping provides a method for producing a mixed spray powder, characterized in that at a temperature of 40 ~ 120 ℃ higher than the melting temperature of each component of the amorphous powder.

The present invention also provides a thermal spray coating material for a swash plate for automobile air conditioners, wherein the thermal spray coating powder for thermal spray coating the swash plate is a mixed thermal spray powder prepared from the manufacturing method.

In addition, the mixed spray powder provides a thermal spray coating material for a swash plate for an automotive air conditioner, characterized in that the thermal spraying at a high speed through the supersonic nozzle using a hydrogen gas as a heat source during the thermal spray coating of the swash plate.

The present invention also provides a swash plate for a car air conditioner having a coating layer formed by spray coating the mixed spray powder, the friction coefficient is in the range of 1.6 to 2.5, Vickers hardness is in the range of 600 to 900 Provide the swash plate.

The present invention having the above constituent features by using the thermal spray coating on the swash plate used to compress the refrigerant for automobile air conditioner with the mixed spray powder of the present invention, to produce a swash plate with improved wear resistance even without the use of lead very harmful to the environment In addition to excellent low friction properties, the service life of the swash plate can be extended.

Hereinafter, the present invention will be described in more detail with reference to the drawings and embodiments. The following descriptions are for specific examples of the present invention, but are not intended to limit the scope of the rights set forth in the claims, even if there is an assertive or limited expression.

Method for producing a mixed spray powder according to an embodiment of the present invention is Si: 2 to 2.5% by weight, P: 5 to 6% by weight, Cr: 2 to 3% by weight, Mo: 5 to 6% by weight, B: 1 ~ 2% by weight, and Fe (including impurity): 80.5 to 85% by weight of each component of the amorphous powder provided with, and mixing 80 to 95% by weight of the amorphous powder and 5 to 20% by weight of molybdi sulfide Characterized in that it comprises a step.

1 is a flow chart illustrating a manufacturing method according to an embodiment of the present invention.

First, the production method of the present invention is subjected to a basis weight process for forming an amorphous powder (S10). In preparing the amorphous powder, it is important to prepare each component and its content. The above-described components and their contents greatly influence the coefficient of friction, hardness, and wear resistance after thermal spraying. The above-described component composition is composed of the results of the study to achieve the improvement of the adhesion, wear resistance and slip resistance of the coating layer to be formed on the swash plate. In addition, by removing lead that is harmful to the environment, the environmental regulations are further advanced.

Basis weight process is basis weight so that each of the above-described components through a basis weight to meet a predetermined amount, that is, a predetermined reference amount. The method for preparing the desired composition by weighing the components of the amorphous powder may vary and is not limited. Preferably, using a pig iron (Pig iron) as a main material, it is preferable to include a step of further adding the corresponding components by weighing the content of the shortage of each component in the molten iron. Here, Cr, Mo, B addition and its content facilitate the amorphous formation of the powder. It was confirmed that the amorphous powder was superior in hardness to the crystalline powder. Therefore, in the present invention, an amorphous powder is adopted. As a result, it was confirmed that the amorphous powder and the sprayed coating layer using the mixed spray powder using the same showed the amorphous characteristics.

When the basis weight of each component is completed, it is good to include the step (S20) of dissolving each component, followed by tapping and atomizing nitrogen gas by spray cooling. That is, after melting in the furnace (preferably induction path) is subjected to the process of tapping. In the tapping process, it is preferable to keep tapping at a temperature higher than a desired temperature in order to secure the fluidity of the melted tapping, preferably at a temperature higher than 40 ~ 120 ℃ than the melting temperature of each component of the amorphous powder. . In particular, tapping at a temperature of about 70 ~ 90 ℃ higher than the melting temperature is preferred.

In addition, the amorphous powder in which each component is mixed in the tapping process undergoes a process of cooling the molten metal by spouting high-speed nitrogen gas at the same time as tapping with each component and simultaneously cooling the molten metal (S30).

When the undifferentiation is completed, the coarse particles are separated by the particle size classification process, which is mainly classified through the constitution (S40).

When the classification is completed, a mixed spray powder is prepared by mixing 80 to 95 wt% of the obtained amorphous powder and 5 to 20 wt% of molly disulfide (S50).

The present invention also provides a thermal spray coating material of a swash plate for a car air conditioner comprising the step of thermally coating the swash plate for a car air conditioner to form a coating layer, and a swash plate for a car air conditioner coated therefrom. .

That is, by using the prepared sprayed powder is subjected to ultra-fast spray coating on the swash plate for automobile air conditioner to form a coating layer (S60).

When the sprayed spray powder is sprayed on the swash plate by spraying hydrogen, which is a heat source, through the supersonic nozzle and sprayed at a high speed with the mixed sprayed powder, the sprayed coating is performed. Thus, the swash plate for the automotive air-conditioning coated with the thermal sprayed powder has a coefficient of friction in the range of 1.6 to 2.5, and the hardness (Hv) is formed within the range of 600 to 900 based on the Vickers hardness Hv300. Provide the characteristics. This property is due to the microstructure of the coating layer obtained by performing the mixed spray powder of the specific component by the ultra-fast spray coating method.

Hereinafter, the present invention will be described in more detail with reference to Examples.

[Example]

A mixed spray powder was prepared before the thermal spray coating on the swash plate used to compress the refrigerant for automobile air conditioners.

Fe-Si-P-Cr-Mo-B-based amorphous powder was prepared for the preparation of the mixed spray powder, and the composition of the amorphous powder has excellent amorphous forming ability, and when the high-speed spray coating was used, the adhesion resistance of the coating layer It was designed for the purpose of improving wear resistance and slip resistance, and the powder was prepared by determining the composition through the desired alloy design and weighing it, and then dissolving it through an induction furnace. Simultaneous and micronizing process was carried out, and an amorphous powder was obtained through a sifting process using a sieve. The mixed spray powder was mixed with molybdis sulfide to further improve the lubricating properties of the amorphous powder and the coating layer as shown in Table 1. Got it.

After that, an ultra-fast spray coating method was used to spray-coated the swash plate used to compress the refrigerant for the automotive air conditioner. The super high speed spray coating was sprayed with the spray powder while hydrogen gas was used as the heat source and the hydrogen was burned through the supersonic nozzle so that the high speed molten spray powder was attached to the base metal and coated.

In order to measure the friction characteristics of the thermal spray coated swash plate, after performing the spray coating experiment according to the powder composition (% by weight) after measuring the coefficient of friction in dry wear conditions are shown in Table 1 below.

[Comparative Example]

In the above embodiment, it was carried out in the same manner except for changing the composition as shown in Table 1.

TABLE 1

division Furtherance Coefficient of friction Remarks Example 1 95% (Fe-Si-P-Cr-Mo-B type) + 5% MoS ₂ 0.218 Invention Example 2 90% (Fe-Si-P-Cr-Mo-B type) + 10% MoS ₂ 0.189 Invention Example 3 80% (Fe-Si-P-Cr-Mo-B type) + 20% MoS ₂ 0.184 Invention Comparative Material 1 Fe-Si-P-Cr-Mo-B 0.296 Comparative Material 2 SKD 61 0.785 Comparative Material 3 Cu-Si-Pb 0.589 Comparative Material 4 Al-Si 0.458

As shown in Table 1, as shown in Comparative Material 1, the amorphous powder used in the present invention has a very low coefficient of friction as a characteristic element of the amorphous material, but is coated by mixing molybdi sulfide powder as in the present invention. In this way, the coefficient of friction in dry wear was lower than that of conventional comparable materials.

Then, the wear test was performed to measure the wear characteristics of the sprayed coating layer on the swash plate.

Abrasion test In the marginal lubrication area of 28kgf, RPM 1000, which is the wear test standard of the swash plate use company, the weight loss after the abrasion test was measured and shown in Table 2 below.

<Table 2>

division Furtherance Hardness (Hv 300) Wear (mg) Remarks Example 1 95% (Fe-Si-P-Cr-Mo-B type) + 5% MoS ₂ 820 1.3 Invention Example 2 90% (Fe-Si-P-Cr-Mo-B type) + 10% MoS ₂ 750 1.6
Invention
Example 3 80% (Fe-Si-P-Cr-Mo-B type) + 20% MoS ₂ 652 1.8
Invention
Comparative Material 1 Fe-Si-P-Cr-Mo-B 882 1.2
Comparative Material 2 SKD 61 201 2.0 Comparative Material 3 Cu-Si-Pb 120 22 Comparative Material 4 Al-Si 150 18

As shown in Table 2, the wear resistance of the coating layer according to the present invention showed a slightly higher result than the Fe-Si-P-Cr-Mo-B-based amorphous coating layer having excellent hardness characteristics, as shown in Table 1 Since the lubrication properties are much better than that of other comparative materials, it is expected that the difference in wear amount will not cause a great difference in actual use.

As mentioned above, since the above description is an example for better understanding of the present invention, modifications, substitutions, modifications, omissions, etc. of configurations that can be applied within the scope of the technical idea of the present invention are defined by the claims. It is included in a range.

1 is a flow chart illustrating a manufacturing method according to the present invention.

Claims (8)

Si: 2 to 2.5% by weight, P: 5 to 6% by weight, Cr: 2 to 3% by weight, Mo: 5 to 6% by weight, B: 1 to 2% by weight, and Fe (including impurities): 80.5 to 85 Mixing each component of the amorphous powder in a weight percent; And Method for producing a mixed spray powder, characterized in that it comprises the step of mixing the amorphous powder of 80 to 95% by weight and molybdis sulfide 5 to 20% by weight. The method of claim 1, wherein the amorphous powder in which each component is mixed comprises adding a corresponding component by weighing a deficiency of each component in pig iron. The method of claim 1, wherein the amorphous powder in which each component is mixed comprises a step of dissolving each component, followed by tapping each other and simultaneously spraying nitrogen gas to cool and then finely powder the powder. . The method of claim 3, wherein after the micronization is performed, classification by particle size is carried out through a sieving method. The method of claim 3, wherein the tapping is performed at a temperature 40 to 120 ° C. higher than the dissolution temperature of each component of the amorphous powder . In the thermal spray coating material of swash plate for automobile air conditioner, The thermal spray coating material for the thermal spray coating of the swash plate is a mixed thermal spray powder prepared from the manufacturing method of any one of claims 1 to 5. The thermal spray coating material of the swash plate for automobile air conditioner according to claim 6, wherein the mixed spray powder is sprayed at a high speed through a supersonic nozzle while burning hydrogen which is a heat source during the thermal spray coating of the swash plate. A swash plate for an automotive air conditioner having a coating layer formed by thermally coating the mixed spray powder of any one of claims 1 to 5, wherein the friction coefficient is within the range of 1.6 to 2.5, and the Vickers hardness is within the range of 600 to 900. Swash plate for car air conditioning.

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