KR101146830B1 - Surface treated steel sheet having excellent anti oil-wettability and anti oil-diffusion - Google Patents

Surface treated steel sheet having excellent anti oil-wettability and anti oil-diffusion Download PDF

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KR101146830B1
KR101146830B1 KR1020107000474A KR20107000474A KR101146830B1 KR 101146830 B1 KR101146830 B1 KR 101146830B1 KR 1020107000474 A KR1020107000474 A KR 1020107000474A KR 20107000474 A KR20107000474 A KR 20107000474A KR 101146830 B1 KR101146830 B1 KR 101146830B1
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steel sheet
rust
lubricating oil
treated steel
contact angle
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KR20100028633A (en
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카즈히사 오카이
에츠오 하마다
아키라 마츠자키
사토루 안도
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제이에프이 스틸 가부시키가이샤
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/023Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
    • C23C28/025Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only with at least one zinc-based layer
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/02Parts of sliding-contact bearings
    • F16C33/04Brasses; Bushes; Linings
    • F16C33/06Sliding surface mainly made of metal
    • F16C33/10Construction relative to lubrication
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/02Parts of sliding-contact bearings
    • F16C33/04Brasses; Bushes; Linings
    • F16C33/06Sliding surface mainly made of metal
    • F16C33/12Structural composition; Use of special materials or surface treatments, e.g. for rust-proofing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2204/00Metallic materials; Alloys
    • F16C2204/60Ferrous alloys, e.g. steel alloys
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02KDYNAMO-ELECTRIC MACHINES
    • H02K5/00Casings; Enclosures; Supports
    • H02K5/02Casings or enclosures characterised by the material thereof
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02KDYNAMO-ELECTRIC MACHINES
    • H02K5/00Casings; Enclosures; Supports
    • H02K5/04Casings or enclosures characterised by the shape, form or construction thereof
    • H02K5/16Means for supporting bearings, e.g. insulating supports or means for fitting bearings in the bearing-shields

Abstract

표면처리강판은, 아연계 도금강판표면에 방청피막이 형성되어 있고, 적어도 강판편면측의 상기 방청피막의 표면(A)에 대한, 40℃에서의 동점도가 51 ~ 69㎟/s, 100℃에서의 동점도가 11.1 ~ 14.9㎟/s인 윤활유의 접촉각(단, 강판표면온도 30℃에서, 방청피막표면에 윤활유의 액적을 형성하고 나서 30초 후의 접촉각)이 10°이상이다. 바람직하게는, 상기 표면처리강판은, 그것을 연신률20%로 소성가공한 후의 방청피박표면(A)에 대한 상기 윤활유의 접촉각이 10°이상이고, 더욱 바람직하게는, 상기 방청피막표면(A) 및 상기 표면처리강판을 연신률20%로 소성가공한 후의 상기 방청피막표면(A)에 있어서의 크랙생성밀도가 100㎛당 200개 이하이다. 이들 표면처리강판은, 내 오일-젖음확산성이 우수하고, 베어링홀더부를 구비한 부품에 있어서, 베어링부의 윤활유부족을 발생시키는 윤활유의 삼출을 효과적으로 억제할 수 있다.In the surface-treated steel sheet, an antirust coating is formed on the surface of the zinc-based plated steel sheet, and the kinematic viscosity at 40 ° C is 51 to 69 mm2 / s at 100 ° C to at least the surface A of the antirust coating on the one side of the steel sheet. The contact angle of the lubricating oil having a kinematic viscosity of 11.1 to 14.9 mm 2 / s (however, the contact angle 30 seconds after forming droplets of lubricating oil on the surface of the rust-preventive coating at a steel plate surface temperature of 30 ° C.) is 10 ° or more. Preferably, the surface-treated steel sheet has a contact angle of the lubricating oil with respect to the rust-prevented thin surface A after plastic working at an elongation of 20%, more preferably 10 ° or more, and more preferably, the rust-prevented surface A and the The crack formation density in the said rustproof film surface A after plastic-processing the said surface-treated steel sheet at 20% of elongation is 200 or less per 100 micrometers. These surface-treated steel sheets are excellent in oil-wetting diffusion resistance, and can effectively suppress the bleeding of lubricating oil which causes a lack of lubricating oil in the bearing part in a component having a bearing holder portion.

Description

내 오일-젖음확산성이 우수한 표면처리강판{SURFACE TREATED STEEL SHEET HAVING EXCELLENT ANTI OIL-WETTABILITY AND ANTI OIL-DIFFUSION} SURFACE TREATED STEEL SHEET HAVING EXCELLENT ANTI OIL-WETTABILITY AND ANTI OIL-DIFFUSION}

본 발명은 내 오일-젖음확산성이 우수한 표면처리강판에 관한 것으로, 특히, 자동차나 AV?OA기기분야에서 사용되는 각종 모터의 모터케이스(베어링을 지지하기 위한 베어링홀더부를 구비한 모터케이스)에 적합한 표면처리강판에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a surface-treated steel sheet excellent in oil-wetting diffusion, and more particularly, to motor cases (motor cases having bearing holders for supporting bearings) of various motors used in automobiles and AV-OA equipment. It relates to a suitable surface treated steel sheet.

베어링은 구름 베어링과 미끄럼 베어링으로 크게 나누어지지만, 자동차에 사용되는 전장(電裝)모터나, HDD등의 전자기록기기, 카피기 등의 전자기기에 사용되는 각종 모터의 베어링의 다수는 미끄럼 베어링이다. 미끄럼 베어링은, 베어링부에 윤활유를 급유하여, 주로 회전시에 윤활유에 발생하는 유압으로 회전축과 베어링의 접촉?응착을 방지하는 것으로, 이 때문에, 급유된 윤활유가 베어링부(통상, 베어링부에는 윤활유를 함침(含浸)할 수 있는 베어링부재가 사용된다)에 적절하게 유지되는 것이 필요하다. 그러나, 종래의 모터에서는, 베어링부에서 윤활유가 삼출(渗出)하는 문제가 있어, 윤활유부족에 의한 회전축과 베어링의 접촉?응착이 발생하기 쉬워, 모터의 진동이나 소음의 원인이 되고 있다.The bearings are largely divided into rolling bearings and sliding bearings. However, many of the bearings of various motors used in electric motors used in automobiles, electronic recording devices such as HDDs, and electronic devices such as copying machines are sliding bearings. . In the sliding bearing, the lubricant is lubricated to the bearing part to prevent contact and adhesion between the rotating shaft and the bearing by the hydraulic oil generated mainly in the lubricating oil during rotation. Therefore, the lubricated oil supplied to the bearing part (usually the bearing part is lubricating oil). It is necessary to properly maintain the bearing member capable of impregnation. However, in the conventional motor, there is a problem of lubricating oil oozing out of the bearing part, and contact and adhesion between the rotating shaft and the bearing due to lack of lubricating oil easily occur, which causes vibration and noise of the motor.

종래, 예를 들면 특개평 7-238934호 공보나, 특개평 9-210065호 공보 등에는, 베어링부에서의 윤활유의 삼출을 방지하기 위해, 베어링재료나 베어링부 및 베어링부 주변의 구조 등의 개선이 제안되었지만, 베어링부에서의 윤활유의 삼출의 방지효과는 반드시 충분한 것은 아니었다.Conventionally, for example, Japanese Patent Application Laid-Open No. 7-238934, 9-210065, etc. improve the bearing material, the structure of the bearing portion, and the structure around the bearing portion, in order to prevent lubrication of lubricating oil from the bearing portion. Although this was proposed, the effect of preventing lubricating oil bleeding from the bearing portion was not necessarily sufficient.

그런데, 자동차, OA?AV기기 등에서 사용되는 각종 모터의 베어링(베어링부재)은, 모터케이스에 형성된 베어링홀더부에 지지?고정되는 구조가 일반적이고, 또한, 모터케이스는, 아연계 도금강판표면에 방청피막을 형성한 표면처리강판을 소성가공한 것이 널리 사용되고 있다.By the way, the bearings (bearing members) of various motors used in automobiles, OA and AV devices are generally supported and fixed to the bearing holders formed in the motor case, and the motor case is formed on the surface of the galvanized steel sheet. Plastic processing of surface treated steel sheets on which antirust coatings have been formed is widely used.

베어링부에서 윤활유가 삼출하는 경우, 윤활유는 베어링(베어링부재)에서 베어링홀더부 주변의 모터케이스 내면으로 삼출하여 퍼져간다. 이러한 윤활유의 삼출을 방지하기 위한 종래의 연구는, 오로지 베어링재료나 베어링부 및 베어링부 주변의 구조 등의 개선으로 향해 왔지만, 그 결과는 충분한 것이 아니었다.When lubricating oil is extruded from the bearing portion, the lubricating oil is extruded from the bearing (bearing member) to the inner surface of the motor case around the bearing holder portion. Conventional studies for preventing such lubricating oil leakage have been directed only to improvement of the bearing material, the bearing portion and the structure around the bearing portion, but the result was not sufficient.

이것에 대하여 본 발명자들은, 베어링홀더부가 형성된 모터케이스(표면처리강판)의 표면성상에 착안하여, 베어링에서 윤활유가 삼출하는 기구와 그 대책에 대하여 검토를 행했다. 그 결과, 베어링에서 윤활유가 삼출하는 것은, 베어링홀더부를 포함한 모터케이스 내면(표면처리강판표면)에 윤활유 젖음성이 있기 때문이고, 이 표면성상 때문에 베어링내의 윤활유가 주변의 케이스 내면으로 잇달아 삼출하여, 젖어 퍼져가는 것을 알았다. 따라서, 베어링홀더부를 포함한 모터케이스 내면(표면처리강판표면)의 윤활유 젖음성을 충분히 낮은 레벨로 억제함으로써, 베어링에서 모터케이스 내면으로의 윤활유의 침투를 억제(즉, 윤활유를 베어링 내에 봉입함)할 수 있고, 그 결과, 베어링부의 윤활유부족을 발생시키는 윤활유의 삼출을 효과적으로 억제할 수 있다는 것을 알았다.On the other hand, the present inventors paid attention to the surface property of the motor case (surface treatment steel plate) in which the bearing holder part was formed, and examined the mechanism and the countermeasure which the lubricant bleeds from a bearing. As a result, lubricating oil bleeds out of the bearing because lubricating oil is wetted on the inner surface of the motor case (surface-treated steel sheet surface) including the bearing holder portion. I knew it was spreading. Therefore, by suppressing the lubricating oil wettability of the inner surface of the motor case (surface treated steel plate surface) including the bearing holder portion to a sufficiently low level, the penetration of the lubricating oil from the bearing into the inner surface of the motor case can be suppressed (that is, the lubricating oil is enclosed in the bearing). As a result, it has been found that the exudation of the lubricating oil which causes the lack of lubricating oil in the bearing portion can be effectively suppressed.

따라서 본 발명의 목적은, 내 오일-젖음확산성이 우수하여, 모터케이스 등과 같은 베어링을 지지하기 위한 베어링홀더부를 구비한 부품에 적용한 경우에, 베어링부의 윤활유 부족을 발생시키는 윤활유의 삼출을 효과적으로 억제할 수 있는 표면처리강판을 제공하는 것에 있다.Accordingly, an object of the present invention is to effectively suppress the effusion of lubricating oil, which is excellent in oil-wetting diffusion, and applied to a part having a bearing holder portion for supporting a bearing such as a motor case or the like, which causes a lack of lubricating oil in the bearing portion. The present invention provides a surface-treated steel sheet that can be made.

발명의 개시DISCLOSURE OF INVENTION

본 발명은, 이하를 요지로 하는 것이다.This invention makes the following a summary.

[1] 아연계 도금강판표면에 방청피막이 형성된 표면처리강판으로서,[1] galvanized steel surface-treated steel sheet

적어도 강판 편면측의 방청피막표면(A)에 대한, 40℃에서의 동점도(動粘度)가 51 ~ 69㎟/s, 100℃에서의 동점도가 11.1 ~ 14.9㎟/s인 윤활유의 접촉각(단, 강판표면온도 30℃에서, 방청피막표면에 윤활유의 액적을 형성하고 나서 30초 후의 접촉각)이 10°이상인 것을 특징으로 하는, 내 오일-젖음확산성이 우수한 표면처리강판.The contact angle of the lubricating oil whose kinematic viscosity in 40 degreeC is 51-69mm <2> / s and the kinematic viscosity in 11.1-14.9mm <2> / s at least 100 degreeC with respect to the rust-proof film surface A on the one side of a steel plate (However, A surface-treated steel sheet having excellent oil-wet diffusion resistance, wherein the contact angle after 30 seconds after forming droplets of lubricating oil on the surface of the rust-preventive coating at a steel plate surface temperature of 30 ° C.

[2] 상기 [1]의 표면처리강판에 있어서, 표면처리강판을 연신률20%로 소성가공한 후의 방청피막표면(A)에 대한, 40℃에서의 동점도가 51 ~ 69 ㎟/s, 100℃에서의 동점도가 11.1 ~ 14.9㎟/s인 윤활유의 접촉각(단, 강판표면온도 30℃에서, 방청피막표면에 윤활유의 액적을 형성하고 나서 30초 후의 접촉각)이 10°이상인 것을 특징으로 하는, 내 오일-젖음확산성이 우수한 표면처리강판.[2] The kinematic viscosity at 40 ° C of the surface-treated steel sheet of the above item [1] at 40 ° C on the rust-preventive coating surface A after plasticizing the surface-treated steel sheet at 20% elongation is 51 to 69 mm 2 / s, 100 ° C. The contact angle of the lubricating oil having a kinematic viscosity of 11.1 to 14.9 mm2 / s (however, the contact angle 30 seconds after forming a droplet of lubricating oil on the surface of the rust preventive film at a steel plate surface temperature of 30 ° C.) is 10 ° or more. Surface-treated steel sheet with excellent oil-wet diffusion.

[3] 상기 [1] 또는 [2]의 표면처리강판에 있어서, 방청피막표면(A) 및 표면처리강판을 연신률20%로 소성가공한 후의 방청피막표면(A)에 있어서의 크랙(crack)생성밀도가 100㎛당 200개 이하인 것을 특징으로 하는, 내 오일-젖음확산성이 우수한 표면처리강판.[3] In the surface-treated steel sheet according to the above [1] or [2], a crack in the rust-preventive coating surface A after the rust-preventive coating surface A and the surface-treated steel sheet are plastically processed at an elongation of 20%. Surface-treated steel sheet having excellent oil-wet diffusion resistance, characterized in that the production density is 200 or less per 100㎛.

[4] 상기 [1] ~ [3]중 어느 하나에 기재된 방청피막표면(A)의 조건을 만족하는 것을 특징으로 하는, 베어링을 지지하기 위한 베어링홀더부를 구비한 부품용의 표면처리강판.[4] A surface-treated steel sheet for parts having a bearing holder portion for supporting a bearing, which satisfies the condition of the rustproof coating surface A according to any one of [1] to [3].

[5]상기 [1] ~ [3]중 어느 하나에 기재된 방청피막표면(A)의 조건을 만족하는 것을 특징으로 하는, 베어링을 지지하기 위한 베어링홀더부를 구비한 모터케이스용의 표면처리강판.[5] A surface-treated steel sheet for a motor case provided with a bearing holder portion for supporting a bearing, wherein the condition of the rust-preventive coating surface A according to any one of [1] to [3] is satisfied.

[6] 상기 [1] ~ [3]중 어느 하나에 기재된 표면처리강판을 소성가공하여 얻어진, 베어링을 지지하기 위한 베어링홀더부를 구비한 모터케이스로서, 방청피막표면(A)이 케이스 내면을 구성하는 것을 특징으로 하는 모터케이스.[6] A motor case comprising a bearing holder portion for supporting a bearing obtained by plastic working the surface-treated steel sheet according to any one of [1] to [3], wherein the rust-preventive coating surface A constitutes the case inner surface. Motor case characterized in that.

본 발명의 표면처리강판은, 내 오일-젖음확산성이 우수하고, 이 때문에 모터케이스 등과 같은 베어링을 지지하기 위한, 베어링홀더부를 구비한 부품에 적용한 경우에, 베어링부의 윤활유부족을 발생시키는 윤활유의 삼출을 효과적으로 억제할 수 있다. 이 때문에 모터케이스에 적용한 경우, 베어링에 대한 회전축의 원활한 미끄럼을 장시간 확보할 수 있고, 모터의 진동이나 소음의 저감화와 장수명화(長壽命化)를 도모할 수 있다.The surface-treated steel sheet of the present invention is excellent in oil-wetting diffusion property and, therefore, when applied to a part having a bearing holder part for supporting a bearing such as a motor case, the surface-treated steel sheet of lubricant Effusion can be effectively suppressed. For this reason, when applied to a motor case, the smooth sliding of the rotating shaft with respect to a bearing can be ensured for a long time, and the vibration and noise of a motor can be reduced, and long life can be aimed at.

도 1은, 고체표면에 윤활유의 액적을 형성하여 그 접촉각을 측정한 경우에 있어서, 액적형성 직후부터의 접촉각의 시간경과에 따른 변화의 전형적인 패턴을 나타낸 도면.
도 2는, 일반적인 모터케이스의 베어링홀더부 측의 단면도.
1 is a view showing a typical pattern of the change over time of the contact angle immediately after droplet formation when the droplets of lubricating oil are formed on the solid surface and the contact angle thereof is measured.
2 is a cross-sectional view of a bearing holder portion side of a general motor case.

발명을 실시하기Carrying out the invention 위한  for 최량의Best 형태 shape

본 발명자들은, 모터케이스 내면으로 되는 표면처리강판면에 대한 윤활유의 접촉각을 소정의 레벨이상으로 함으로써, 베어링부에서의 윤활유의 삼출을 효과적으로 억제할 수 있는 것을 알아내어, 본 발명에 이르렀다. 또한, 더욱 바람직하게는, 소정의 가공조건에서 소성가공된 후의 표면처리강판면에 대한 윤활유의 접촉각을 소정의 레벨이상으로 하는 것, 더욱이 피막표면에 존재하는 미소크랙의 생성밀도를 규제함으로써, 보다 우수한 윤활유의 삼출 억제효과를 얻을 수 있음을 알아냈다.MEANS TO SOLVE THE PROBLEM The present inventors discovered that the outflow of the lubricating oil in a bearing part can be suppressed effectively by setting the contact angle of the lubricating oil with respect to the surface-treated steel plate surface used as an inner surface of a motor case more than predetermined level, and came to this invention. More preferably, the contact angle of the lubricating oil with respect to the surface-treated steel sheet surface after plastic working under predetermined processing conditions is set to a predetermined level or more, and furthermore, by regulating the generation density of microcracks present on the surface of the film, It was found that excellent lubricity inhibitory effect can be obtained.

본 발명의 표면처리강판의 베이스가 되는 아연계 도금강판으로서는, 아연도금강판, Zn-Ni합금 도금강판, Zn-Al-Mg합금 도금강판 (예를 들면, Zn-6 mass% Al-3 mass% Mg합금 도금강판, Zn-11mass% Al-3mass%Mg 합금 도금강판), Zn-Al합금도금강판 (예를들면, Zn-5mass% Al합금 도금강판)등을 이용하는 것이 가능하다. 더욱이, 이들 각종 도금강판의 도금층 중에, 소량의 이종금속원소 또는 불순물로서 니켈, 코발트, 망간, 철, 몰리브덴, 텅스텐, 티탄, 크롬, 알루미늄, 마그네슘, 납, 안티몬, 주석, 동 등의 1종 또는 2종 이상을 함유한 도금강판을 이용하는 것도 가능하다. 또한, 상기와 같은 도금 중, 동종 또는 이종의 것을 2층이상 도금한 복층도금강판을 이용하는 것도 가능하다.Examples of the zinc-based plated steel sheet as a base of the surface-treated steel sheet of the present invention include a galvanized steel sheet, a Zn-Ni alloy plated steel sheet, and a Zn-Al-Mg alloy plated steel sheet (eg, Zn-6 mass% Al-3 mass%). Mg alloy plated steel sheet, Zn-11mass% Al-3mass% Mg alloy plated steel sheet), Zn-Al alloy plated steel sheet (for example, Zn-5mass% Al alloy plated steel sheet) and the like can be used. Further, in the plating layers of these various plated steel sheets, one kind of nickel, cobalt, manganese, iron, molybdenum, tungsten, titanium, chromium, aluminum, magnesium, lead, antimony, tin, copper, or the like as a small amount of dissimilar metal elements or impurities, or It is also possible to use a plated steel sheet containing two or more kinds. Moreover, it is also possible to use the multilayer plating steel plate which plated two or more layers of the same kind or a different kind among the above platings.

본 발명의 표면처리강판은, 상기 아연계 도금강판표면에 방청피막이 형성된 표면처리강판으로서, 적어도 강판편면측의 방청피막표면(A)에 대한, 40℃에서의 동점도가 51 ~ 69 ㎟/s, 100℃에서의 동점도가 11.1 ~ 14.9㎟/s 인 윤활유의 접촉각(단, 강판표면온도 30℃에서, 방청피막표면에 윤활유의 액적을 형성하고 나서 30초 후의 접촉각)을 10°이상, 바람직하게는 15°이상, 더욱 바람직하게는 25°이상으로 하는 것이다. 방청피막은, 소망의 방청성능을 얻기 위한 유기성분 또는/및 무기성분을 주성분으로 하는 것이다.The surface-treated steel sheet of the present invention is a surface-treated steel sheet having a rust-preventive coating formed on the surface of the zinc-based plated steel sheet, and has a kinematic viscosity at 40 ° C of 51 to 69 mm 2 / s, at least with respect to the rust-preventive coating surface A on the one side of the steel sheet. The contact angle of the lubricating oil having a kinematic viscosity of 11.1 to 14.9 mm 2 / s at 100 ° C. (but the contact angle 30 seconds after forming the droplets of the lubricating oil on the surface of the rust-preventive coating at a surface temperature of 30 ° C.) is preferably 10 ° or more, preferably 15 degrees or more, More preferably, it is 25 degrees or more. An antirust film has a main component as an organic component and / or an inorganic component for obtaining desired antirust performance.

도 1은, 고체표면에 윤활유의 액적을 형성하고 그 접촉각을 측정한 경우에 있어서, 액적 형성 직후부터의 접촉각의 시간경과에 따른 변화의 전형적인 패턴을 나타낸 것이다. 윤활유가 젖기 어려운 고체표면에서는 접촉각은 시간경과에 따라 거의 변화하지 않는 데에 대해, 윤활유가 젖기 쉬운 고체표면에서는, 접촉각은 액적형성 직후로 부터 급속하게 작게되고, 일정시간 경과하면 안정화한다. 여기서, 본 발명이 대상으로 하는 유기성분 또는/및 무기성분을 주성분으로 하는 방청피막에 대해서는, 액적을 형성하고 나서 적어도 30초 경과하면 접촉각은 안정화함을 알았으므로, 본 발명에서 사용하는 접촉각은, 방청피막표면에 윤활유의 액적을 형성하고나서 30초 후의 접촉각으로 했다.Fig. 1 shows a typical pattern of the change over time of the contact angle immediately after droplet formation when a droplet of lubricating oil is formed on the solid surface and the contact angle is measured. On the solid surface where lubricating oil is hard to get wet, the contact angle hardly changes with time. On the solid surface where lubricating oil is easy to get wet, the contact angle rapidly decreases immediately after droplet formation, and stabilizes after a certain time. Since the contact angle stabilizes at least 30 seconds after forming a droplet with respect to the rust-preventive coating which has an organic component and / or an inorganic component as a main component of this invention, since the contact angle used by this invention is The contact angle after 30 second was formed after the droplet of lubricating oil was formed on the surface of antirust film.

방청피막표면(A)에 대한 윤활유의 접촉각의 측정은, 예를 들면, 다음과 같이 하여 행한다. 강판표면온도가 30℃에서 방청피막(A)(표면처리강판)의 표면에, 40℃에서의 동점도가 51 ~ 69㎟/s, 100℃에서의 동점도가 11.1 ~ 14.9㎟/s인 윤활유의 액적을 형성하여, 접촉각계로 접촉각을 연속적으로 측정하고, 방청피막표면(A)에 액적을 형성하고나서 30초 후의 접촉각의 값을 당해 방청피막표면(A)의 접촉각으로 한다. 또한, 40℃에서의 동점도가 51 ~ 69㎟/s, 100℃에서의 동점도가 11.1 ~ 14.9㎟/s인 윤활유로서는, 예를 들면, NOK크류버(주)제「ALL TIME J652」(40℃에서의 동점도:60㎟/s, 100℃에서의 동점도:13㎟/s)나, 폴 라이트(주)제「PSL-7」(40℃에서의 동점도 :60㎟/s, 100℃에서의 동점도:13㎟/s)를 이용할 수 있다. 또한, 접촉각계로서는, 예를 들면, 협화계면과학(協和界面科學) (주) 제「Drop Master 500」을 사용할 수 있다.The measurement of the contact angle of the lubricating oil with respect to the rust-proof film surface A is performed as follows, for example. Lubricant liquid whose kinematic viscosity at 40 ° C is 51 to 69 mm2 / s and the kinematic viscosity at 100 ° C is 11.1 to 14.9 mm2 / s at the surface temperature of the steel sheet at 30 ° C. A drop is formed, the contact angle is continuously measured with a contact angle meter, and the value of the contact angle 30 seconds after the formation of the droplet on the rust-proof film surface A is the contact angle of the rust-proof film surface A. Moreover, as lubricating oil whose kinematic viscosity in 40 degreeC is 51-69mm <2> / s, and the kinematic viscosity in 100 degreeC is 11.1-14.9mm <2> / s, For example, "ALL TIME J652" made by NOK Cruber Co., Ltd. (40 degreeC) Kinematic Viscosity at: 60 mm2 / s, Kinematic Viscosity at 100 ° C: 13 mm2 / s and Polite-7 (PSL-7) (Kinematic Viscosity at 40 ° C: 60 mm2 / s, Kinematic Viscosity at 100 ° C) : 13 mm 2 / s) can be used. As the contact angle meter, "Drop Master 500" manufactured by Cooperative Interface Science Co., Ltd. can be used, for example.

이 방청피막표면(A)에 대한 윤활유의 접촉각은 본 발명에서 가장 중요한 요건이고, 이 접촉각이 상기 조건을 만족함으로써, 우수한 내 오일-젖음확산성을 얻을 수 있다. 접촉각을 크게하는 것은, 방청피막표면(A)에서의 윤활유의 계면장력을 크게하는 것이지만, 계면장력은 윤활유가 구상(球狀)으로 되려고 하는 방향으로 움직이는 힘이므로, 계면장력이 크게 되면, 젖기 어려운 상태로 되어, 내 오일-젖음확산성이 향상한다고 생각된다. 상기 윤활유의 접촉각을 10°이상, 바람직하게는 15°이상, 더욱 바람직하게는 25°이상으로 함으로써, 회전축과 베어링의 접촉?응착의 원인이 되는 윤활유 부족을 발생시키는 베어링에서의 윤활유의 삼출을 효과적으로 억제할 수 있다.The contact angle of the lubricating oil to this rust preventive coating surface A is the most important requirement in the present invention, and excellent oil-wet diffusion resistance can be obtained by satisfying the above condition. Increasing the contact angle increases the interfacial tension of the lubricating oil on the rust-preventive coating surface A. However, the interfacial tension is a force that moves in the direction in which the lubricating oil is to be spherical. It is thought that the oil-wet diffusion resistance is improved. By setting the contact angle of the lubricating oil to 10 ° or more, preferably 15 ° or more, more preferably 25 ° or more, the lubricating oil bleeding out of the bearing which causes a lack of lubricating oil which causes contact and adhesion between the rotating shaft and the bearing can be effectively prevented. It can be suppressed.

또한, 본 발명의 표면처리강판은, 적어도 모터케이스의 내면측이 되는 강판편면측의 방청피막표면(A)에 대하여, 윤활유의 접촉각을 상기 조건으로 하면 좋다.In the surface-treated steel sheet of the present invention, the contact angle of the lubricating oil may be set to the above condition with respect to the rust-preventive coating surface A on the one side of the steel sheet that is at least the inner surface side of the motor case.

베어링홀더부를 구비한 모터케이스는, 통상, 표면처리강판에 프레스 성형등의 소성가공을 실시하여 제조된다. 도 2는, 일반적인 모터케이스의 베어링홀더부측의 단면을 나타내는 것으로, 1은 표면처리강판을 프레스 성형하여 얻어진 모터케이스, 2는 이 모터케이스 (1)의 단부에 가공 성형된 베어링홀더부, 3은 이 베어링홀더부(2) 내에 지지?고정된 베어링(베어링부재), 4는 이 베어링(3)에 회전자유롭게 지지되는 모터회전축, 5는 와샤이다. 표면처리강판이 도 2에 나타낸 모터케이스(베어링홀더부를 갖는 모터케이스)의 형상까지 성형될 때, 많은 경우, 연신률 20%전후의 소성가공이 이루어지고, 이러한 소성가공에 의해 방청피막표면(A)에 대한 윤활유의 접촉각이 작게되는 경우가 많다. 따라서, 표면처리강판을 연신률 20%로 소성가공한 후의 방청피막표면(A)에 대한 상기 윤활유의 접촉각도 10°이상, 바람직하게는 15°이상, 더욱 바람직하게는 25°이상으로 하는 것이 바람직하다.The motor case provided with the bearing holder part is normally manufactured by performing plastic processing, such as press molding, on a surface-treated steel sheet. Fig. 2 shows a cross section of the bearing holder portion side of a general motor case, 1 is a motor case obtained by press molding a surface treated steel sheet, 2 is a bearing holder portion machined and formed at the end of the motor case 1, The bearing (bearing member) supported and fixed in the bearing holder portion 2, 4 is a motor rotation shaft freely supported by the bearing 3, and 5 is a washer. When the surface-treated steel sheet is molded to the shape of the motor case (motor case having a bearing holder portion) shown in Fig. 2, in many cases, plastic processing is performed before and after the elongation 20%, and the plastic working prevents the surface of the rust-preventive coating surface (A). The contact angle of the lubricating oil with respect to is often small. Therefore, it is preferable that the contact angle of the lubricating oil with respect to the rust-preventive coating surface A after the plastic working of the surface-treated steel sheet at 20% elongation is 10 ° or more, preferably 15 ° or more, more preferably 25 ° or more. .

방청피막표면(A)에 대한 상기 윤활유의 접촉각은 클수록 내 오일-젖음확산성이 양호하게 되지만, 한편으로, 프레스 성형 등의 소성가공시에 가공유를 튀기면 가공이 곤란해지므로, 방청피막표면(A)에 대한 상기 윤활유의 접촉각은 90°미만인 것이 바람직하다.The larger the contact angle of the lubricating oil to the rust-preventive coating surface A is, the better the oil-wet diffusion property is, but on the other hand, if the processing oil is splashed during plastic processing such as press molding, the processing becomes difficult. It is preferable that the contact angle of the said lubricating oil with respect to) is less than 90 degrees.

또한, 방청피막표면(A)에 존재하는 미소 크랙도 윤활유 젖음성에 영향을 주고 있으며, 상술한 윤활유의 접촉각의 제어만으로도 우수한 내 오일-젖음확산성을 얻을 수 있지만, 미소 크랙의 생성밀도를 규제함으로써, 보다 우수한 내 오일-젖음확산성을 얻을 수 있음을 알았다. 이것은, 미소크랙은, 그 모세관작용에 의해 윤활유의 젖음확산성을 촉진하기 때문이라고 생각된다.In addition, the micro cracks present on the rust-preventive coating surface A also influence the lubricating oil wettability, and excellent oil-wetting diffusion property can be obtained only by controlling the contact angle of the lubricating oil described above. It was found that better oil-wet diffusion resistance can be obtained. It is thought that this is because the microcracks promote the wetting and diffusibility of the lubricating oil by the capillary action.

구체적으로는, 방청피막표면(A)에 존재하는 크랙의 생성밀도를 100㎛당 200개 이하, 보다 바람직하게는 150개 이하, 더욱 바람직하게는 100개이하로 함으로써, 특히 우수한 내 오일-젖음확산성을 얻을 수 있다. 여기서 크랙의 생성밀도는, 전자현미경을 사용하여, 예를 들면, 가속전압 5kV, 2000배로 표면처리강판의 표면을 관찰하여, 100㎛당의 크랙수를 계수(計數)한다. 또한, 전자현미경으로서는, 예를 들면, 일본전자 (주) 제「JCM-5600 」을 사용할 수 있다.Specifically, the production density of cracks present on the rust-preventive coating surface A is 200 or less, more preferably 150 or less, and more preferably 100 or less, per 100 µm, thereby providing particularly excellent oil-wet diffusion. You can get the last name. Herein, the generation density of cracks is observed by using an electron microscope, for example, by observing the surface of the surface-treated steel sheet at an acceleration voltage of 5 kV and 2000 times, and counting the number of cracks per 100 µm. As the electron microscope, "JCM-5600" made by Nippon Electronics Co., Ltd. can be used, for example.

또한, 피막표면의 크랙은, 표면처리강판을 모터케이스 등에 소성가공(주로, 프레스 성형)한 경우에 도입되기 쉽고, 따라서, 표면처리강판을 연신률20%로 소성가공한 후의 방청피막표면(A)에 있어서의 크랙생성밀도에 대해서도, 100㎛당 200개 이하, 보다 바람직하게는 150개 이하, 더욱 바람직하게는 100개 이하로 하는 것이 바람직하다.In addition, cracks on the coating surface are easily introduced when the surface-treated steel sheet is plastically processed (mainly press-molded) in a motor case or the like, and therefore, the antirust film surface (A) after the surface-treated steel sheet is plastically processed at an elongation of 20%. Also about the crack generation density in, it is preferable to set it as 200 or less per 100 micrometers, More preferably, it is 150 or less, More preferably, it is 100 or less.

본 발명의 표면처리강판은, 방청피막의 하층에 1층 이상의 하지피막(下地皮膜)(예를 들면, 화성처리피막 등)을 가지고 있어도 좋다.The surface-treated steel sheet of the present invention may have one or more underlayers (for example, chemical conversion coatings) on the lower layer of the rust preventive coating.

본 발명의 표면처리강판은 적당한 용도로 사용할 수 있지만, 특히 베어링(미끄럼 베어링)을 지지하기 위한 베어링홀더부를 구비한 부품용, 특히, 도 2에 나타낸 모터 케이스용으로서 적합한 것이다.Although the surface-treated steel sheet of this invention can be used for a suitable use, it is especially suitable for the components provided with the bearing holder part for supporting a bearing (slide bearing), especially for the motor case shown in FIG.

본 발명의 표면처리강판을 이용하여, 베어링(미끄럼베어링)을 지지하기 위한 베어링홀더부를 구비한 모터케이스를 제조하는 경우, 그 방청피막표면(A)이 케이스 내면측이 되도록, 표면처리강판을 프레스 성형 등에 의해 가공하여, 도 2에 나타낸 모터케이스로 성형한다.When manufacturing the motor case provided with the bearing holder part for supporting a bearing (sliding bearing) using the surface-treated steel sheet of this invention, a surface-treated steel sheet is pressed so that the rustproof film surface A may become a case inner surface side. It processes by shaping | molding etc. and shape | molds to the motor case shown in FIG.

다음으로, 본 발명의 표면처리강판의 제조방법에 대해서 설명한다.Next, the manufacturing method of the surface-treated steel sheet of this invention is demonstrated.

본 발명의 표면처리강판은, 아연계 도금강판(하지피막이 형성되어 있는 경우를 포함한다)의 표면에 방청피막용의 표면처리액(표면처리조성물)을 부착시키고, 가열건조하여 방청피막을 형성함으로써 제조된다. 상기 표면처리액은, 피막에 방청성능을 부여하기 위한 유기성분 또는/및 무기성분을 주성분으로 하며, 본 발명조건을 만족하는 방청피막을 형성할 수 있는 것이면, 종류나 첨가성분은 특별히 한정되는 것은 아니지만, 본 발명 조건을 만족하는 윤활유의 접촉각을 확보하는 수단의 일예로서, (ⅰ) 계면활성제, (ⅱ) 입자경 0.05 ~ 5㎛의 미립자, (ⅲ) 불소계수지, 중에서 선택되는 1종 이상의 성분을 첨가하는 것을 예로 들수 있다.The surface-treated steel sheet of the present invention is formed by attaching a surface treatment liquid (surface treatment composition) for an rust-preventive coating on the surface of a zinc-based plated steel sheet (including a case where an undercoat is formed), and drying it to form an rust-preventive coating. Are manufactured. The surface treatment liquid is mainly composed of an organic component and / or an inorganic component for imparting antirust performance to the coating, and the type and additive components are particularly limited as long as the surface treatment liquid can form an antirust coating that satisfies the conditions of the present invention. However, as an example of the means for securing the contact angle of the lubricating oil that satisfies the conditions of the present invention, at least one component selected from (i) a surfactant, (ii) fine particles having a particle diameter of 0.05 to 5 μm, and (i) a fluorine resin Addition is an example.

상기 계면활성제로서는, 이온성 계면활성제, 비 이온성 계면활성제, 양성계면활성제를 예로 들수 있고, 이들의 1종 이상을 이용할 수 있다.Examples of the surfactant include ionic surfactants, nonionic surfactants, and amphoteric surfactants, and one or more kinds thereof can be used.

상기 입자경 0.05 ~ 5㎛의 미립자로서는, 예를 들면, 폴리에틸렌 왁스, 폴리프로필렌 왁스 등의 폴리올레핀 왁스, 라놀린계 왁스, 몬탄왁스, 마이크로 크리스타린 왁스, 파라핀 왁스, 카르나우바 왁스 등과 같은 고형윤활제를 예로 들수 있으며, 이들 중의 1종 이상을 이용할 수 있다.Examples of the fine particles having a particle diameter of 0.05 to 5 μm include solid lubricating agents such as polyolefin waxes such as polyethylene wax and polypropylene wax, lanolin wax, montan wax, micro-crystallin wax, paraffin wax, carnauba wax and the like. These can be mentioned and 1 or more types of these can be used.

상기 불소계 수지는, 수소원자 1개 이상이 불소로 치환된 에틸렌 및 그 유도체의 중합에 의해 얻어지는 수지이고, 폴리테트라플루오로에틸렌(PTFE), 테트라플루오로에틸렌?퍼플루오로알킬비닐에틸 공중합체수지(PFA),플루오로 에틸렌과 비닐에틸의 공중합체, 테트라플루오로에틸렌과 에틸렌 공중합체(4불화에틸렌?에틸렌 공중합수지:ETFE), 테트라플루오로에틸렌과 헥사플로오로프로필렌의 공중합체(FEP)등을 예로 들 수 있지만, C-F결합을 갖는 것이라면, 그 종류는 특별히 한정되지 않는다. 이들을 비이온 또는 양이온의 이온성을 갖게 하여, 물로 분산한 것의 1종 이상을 사용할 수 있다.The fluorine-based resin is a resin obtained by polymerization of ethylene and derivatives thereof in which at least one hydrogen atom is substituted with fluorine, and polytetrafluoroethylene (PTFE), tetrafluoroethylene-perfluoroalkylvinylethyl copolymer resin (PFA), copolymer of fluoroethylene and vinyl ethyl, tetrafluoroethylene and ethylene copolymer (ethylene tetrafluoroethylene-ethylene copolymer resin: ETFE), copolymer of tetrafluoroethylene and hexafluoropropylene (FEP), etc. Although it is mentioned as an example, if it has a CF bond, the kind is not specifically limited. One or more types of those which are made to be ionic or nonionic and are dispersed in water can be used.

또한, (ⅰ) 계면활성제, (ⅱ) 입자경0.05 ~ 5㎛의 미립자, (ⅲ)불소계 수지, 중에서 선택되는 1종이상의 첨가성분의 배합량은, 표면처리액 중의 고형분의 비율로 0.1 ~ 20mass%, 보다 바람직하게는 0.5 ~ 15mass%, 더욱 바람직하게는 1 ~ 10mass%정도로 하는 것이 적당하다. 배합량이 0.1mass%미만에서는 내 오일-젖음확산성이 불충분하게 되는 경우가 있고, 한편, 20mass%를 넘으면 내식성이 열화(劣化)하는 경우가 있다.In addition, the compounding quantity of 1 or more types of addition components chosen from (i) surfactant, (ii) microparticles | fine-particles of (0.0) -5 micrometers of particle diameters, (i) fluorine-type resin, is 0.1-20 mass% in the ratio of solid content in a surface treatment liquid, More preferably, it is suitable to set it as 0.5-15 mass%, More preferably, it is about 1-10 mass%. If the blending amount is less than 0.1 mass%, the oil-wet diffusion resistance may become insufficient, whereas if the blending amount exceeds 20 mass%, the corrosion resistance may deteriorate.

상술한 첨가성분을 포함하는 표면처리액을 이용하여 형성한 방청피막이, 윤활유의 접촉각이 높게 되는 메키니즘은 반드시 명확하지는 않지만, 상기 첨가성분을 함유시킨 방청피막은, 표면자유에너지가 저하하기 때문이라고 추정된다.The mechanism by which the rust-preventive film formed by using the surface treatment liquid containing the above-mentioned additives is not necessarily clear, but the surface-free energy of the rust-preventive coatings containing the additives decreases. It is estimated.

방청피막표면(A)에서의 크랙생성밀도, 특히 표면처리강판을 연신률20%로 소성가공한 후의 크랙생성밀도를 되도록 작게함에는, 방청피막의 피막두께를 3㎛이하로 하는 것이 바람직하다. 3㎛를 넘으면 피막 중의 잔류응력에 의해 크랙이 도입되기 쉽게 되기 때문이다. 피막두께는, 보다 바람직하게는 1.5㎛이하이고, 특히 바람직하게는 0.8㎛이하이다.In order to reduce the crack generation density at the rust-preventive coating surface A, in particular, the crack generation density after plastic processing of the surface-treated steel sheet at an elongation of 20%, the film thickness of the rust-preventive coating is preferably 3 µm or less. This is because if it exceeds 3 mu m, cracks are easily introduced due to residual stress in the film. The film thickness is more preferably 1.5 µm or less, and particularly preferably 0.8 µm or less.

본 발명의 방청피막은, 상술한 것 같은 표면처리액을, 예를 들면, 도포법, 침지법, 스프레이법 등에 의해 아연계 도금강판면(또는 하지피막표면)에 부착시킨 후, 가열건조를 행함으로써 형성된다. 가열건조수단으로서는, 드라이어, 열풍로, 고주파유도가열로, 적외선로 등을 이용할 수 있다. 또한, 고형윤활제를 첨가하는 경우는, 건조온도가 고형윤활제의 연화점(軟化點)이상인 것이, 방청피막의 표면자유에너지를 보다 저하시킬 수 있기 때문에 바람직하다.In the rust-preventive coating of the present invention, the surface treatment liquid as described above is attached to a zinc-based plated steel sheet surface (or base film surface) by, for example, a coating method, an immersion method, a spray method, or the like, followed by heating and drying. It is formed by. As the heat drying means, a dryer, a hot stove, a high frequency induction furnace, an infrared furnace, or the like can be used. In addition, when adding a solid lubricant, it is preferable that a drying temperature is more than the softening point of a solid lubricant, since it can lower the surface free energy of an antirust film more.

실시예Example

실리카, 실란커플링제 및 아크릴 수지를 주성분으로 하는 방청처리액에, 표2에 나타난 계면활성제, 표3에 나타난 미립자, 표4에 나타난 불소계 수지를 적당배합하여 표면처리액을 조제했다.The surface treatment liquid was prepared by mix | blending suitably the surfactant shown in Table 2, the microparticles shown in Table 3, and the fluorine-type resin shown in Table 4 to the antirust process liquid containing a silica, a silane coupling agent, and an acrylic resin as a main component.

처리원판인 표1에 나타난 아연계 도금강판을 알카리 탈지처리하고, 수세(水洗) 및 건조한 후, 상기 표면처리액을 바코터로 도포하고, 그 후, 즉시 강판표면온도가 수초 ~ 수십 초로 소정온도로 되도록 가열건조하여, 표면처리피막(방청피막)을 형성시켰다. 이 표면처리피막의 막 두께는 표면처리액의 농도에 의해 조정하고, 피막의 막 두께는 전자현미경으로 피막단면을 관찰하여 정량했다.Alkaline degreasing treatment of the zinc-based galvanized steel sheet shown in Table 1, which is a treated original, followed by water washing and drying, followed by coating the surface treatment liquid with a bar coater, and immediately afterwards, the surface temperature of the steel sheet is several seconds to several tens of seconds. It heat-dried so that it might become, and the surface treatment film (antirust film) was formed. The film thickness of this surface treatment film was adjusted by the concentration of the surface treatment liquid, and the film thickness of the film was quantified by observing the film cross section with an electron microscope.

얻어진 표면처리강판에 대해서, 피막표면에 대한 윤활유의 접촉각과 피막표면의 크랙생성밀도를 측정했다. 그 결과를, 표면처리강판의 피막구성 등과 함께 표5에 나타냈다. 또한, 표면처리강판의 내 오일-젖음확산성을 평가한 결과를 표6에 나타냈다.About the obtained surface-treated steel sheet, the contact angle of the lubricating oil with respect to the film surface, and the crack formation density of the film surface were measured. The results are shown in Table 5 together with the film structure of the surface treated steel sheet. In addition, the results of evaluating the oil-wet diffusion resistance of the surface-treated steel sheet are shown in Table 6.

피막표면에 대한 윤활유의 접촉각 및 피막표면의 크랙생성밀도의 측정과, 내 오일-젖음확산성의 평가는, 이하처럼 하여 행했다. 또한, 그것들의 측정?평가는, 소성가공을 실시하지 않은 시험재(미가공재)와 소성가공을 실시한 시험재(소성가공재)에 대해서 각각 행했다. 소성가공에서는, 전자식 만능시험기(YONEKURA (주) 제 「CATY」)를 이용하여, 표면처리강판을 연신속도 10mm/min, 연신률 20%로 연신했다. The measurement of the contact angle of the lubricating oil with respect to the film surface, the crack formation density of the film surface, and the evaluation of oil-wet diffusion resistance were performed as follows. In addition, these measurement and evaluation were performed about the test material (raw material) which did not perform plastic processing, and the test material (plastic processing material) which performed plastic processing, respectively. In the plastic working process, the surface-treated steel sheet was stretched at an elongation rate of 10 mm / min and an elongation rate of 20% using an electronic universal testing machine ("CATY" manufactured by YONEKURA Co., Ltd.).

(1) 피막표면에 대한 윤활유의 접촉각(1) Contact angle of lubricant to coating surface

접촉각 측정용의 윤활유로서는, 40℃에서의 동점도가 51 ~ 69㎟/s, 100℃에서의 동점도가 11.1 ~ 14.9㎟/s의 윤활유(NOK크류바 (주) 제「ALL TIME J 652」)를 사용했다. 이 윤활유에 의해 30℃의 시험재(표면처리강판)의 표면에 액적을 형성하여, 접촉각계(협화계면과학(주) 제「Drop Master 500」)를 이용하여 접촉각을 연속적으로 측정하고, 액적을 형성하고 나서 30초 후의 값을 접촉각으로 했다.As lubricating oil for contact angle measurement, a lubricating oil having a kinematic viscosity at 40 ° C of 51 to 69 mm2 / s and a kinematic viscosity at 100 ° C of 11.1 to 14.9 mm2 / s (`` ALL TIME J 652 '' manufactured by NOK Crew Bar Co., Ltd.) Used. With this lubricant, droplets are formed on the surface of the test material (surface treated steel sheet) at 30 ° C, and the contact angle is continuously measured using a contact angle meter (Drop Master 500, manufactured by Cooperative Interface Science). The value after 30 second was made into the contact angle after forming.

(2)피막표면의 크랙생성밀도(2) Crack formation density on the film surface

전자현미경(일본전자(주) 제「JCM-5600」)을 사용하여, 가속전압 5kV, 2000배로 시험재(표면처리강판)의 표면을 관찰하여, 크랙의 생성밀도가 높을 것 같은 5개소를 선택하고, 각각의 개소에서 20㎛길이의 부분(5개소의 합계로 길이 100㎛)의 크랙수를 계수(計數)하여, 5개소 합계의 크랙수를 100㎛당의 크랙생성밀도로 했다.Using an electron microscope (JCM-5600, manufactured by Nippon Electronics Co., Ltd.), the surface of the test specimen (surface treated steel sheet) was observed at an acceleration voltage of 5 kV and 2000 times, and five places where crack formation was likely to be high were selected. The number of cracks of the 20 micrometer-long portion (100 micrometers in length in total of 5 places) was counted in each place, and the crack number of the total of five places was made into the crack generation density per 100 micrometers.

(3) 내 오일-젖음확산성(3) oil-wet diffusion resistance

40℃에서의 동점도가 51 ~ 69㎟/s, 100℃에서의 동점도가 11.1 ~ 14.9㎟/s인 윤활유(NOK크류바 (주) 제「ALL TIME J 652」)를 용기에 넣고, 연직으로 세운 시험재의 하단부를 용기내의 윤활유에 담근 상태에서 실온 30℃로 3일간 방치하고, 윤활제의 스며 퍼지는 높이를 측정했다. 그 평가기준은, 이하와 같다.Lubricating oil having a kinematic viscosity of 51 to 69 mm2 / s at 40 ° C and a kinematic viscosity of 11.1 to 14.9 mm2 / s at 100 ° C was placed in a container and erected vertically. In the state which immersed the lower end part of the test material in the lubricating oil in a container, it was left to stand at room temperature 30 degreeC for 3 days, and the permeable spread of the lubricant was measured. The evaluation criteria are as follows.

◎ : 스며 퍼지는 높이 0.5㎝미만◎: less than 0.5 cm

○ : 스며 퍼지는 높이 0.5㎝이상, 1.0㎝미만○: height 0.5 cm or more, less than 1.0 cm

○-: 스며 퍼지는 높이 1.0㎝이상, 1.5㎝미만○-: permeate spread more than 1.0cm, less than 1.5cm

△ : 스며 퍼지는 높이 1.5㎝이상, 3.0㎝미만(Triangle | delta): The height which permeate spreads more than 1.5 cm and less than 3.0 cm

× : 스며 퍼지는 높이 3.0㎝이상
×: height of 3.0 cm or more

Figure 112010001324274-pct00001
Figure 112010001324274-pct00001

Figure 112010001324274-pct00002
Figure 112010001324274-pct00002

Figure 112010001324274-pct00003
Figure 112010001324274-pct00003

Figure 112010001324274-pct00004
Figure 112010001324274-pct00004

Figure 112010001324274-pct00005
Figure 112010001324274-pct00005

Figure 112010001324274-pct00006
Figure 112010001324274-pct00006

Claims (7)

아연계 도금강판의 표면에 방청피막이 형성된 표면처리강판으로서,
상기 방청피막은, 실리카, 실란커플링제 및 아크릴 수지를 주성분으로 하는 방청처리액에, 계면활성제, 입자경 0.05 ~ 5㎛의 미립자, 불소계 수지, 중에서 선택되는 1종 이상의 성분이 첨가된 표면처리액을 부착시켜, 가열건조하여 형성되는 것이며,
적어도 강판 편면(片面) 측의 방청피막표면(A)에 대한, 40℃에서의 동점도(動粘度)가 51 ~ 69㎟/s, 100℃에서의 동점도가 11.1 ~ 14.9㎟/s인 윤활유의 접촉각(단, 강판표면온도 30℃에서, 방청피막표면에 윤활유의 액적을 형성하고 나서 30초 후의 접촉각)이 10°이상 90°미만인 것을 특징으로 하는, 내(耐) 오일-젖음확산성이 우수한 표면처리강판.
A surface-treated steel sheet having a rust-proof film formed on the surface of a galvanized steel sheet,
The rust preventive coating includes a surface treatment liquid in which at least one component selected from a surfactant, fine particles having a particle diameter of 0.05 to 5 μm, and a fluorine-based resin is added to an rust preventing treatment solution mainly containing silica, a silane coupling agent and an acrylic resin. Is formed by adhering, heating and drying,
Contact angle of lubricating oil whose dynamic viscosity in 40 degreeC is 51-69mm <2> / s and the kinematic viscosity in 11.1-14.9mm <2> / s with respect to the rust-proof film surface A on the one side of steel plate at least. (However, the contact angle after 30 seconds after forming a droplet of lubricating oil on the surface of the rust-prevented coating film at a steel plate surface temperature of 30 ° C.) is a surface excellent in oil-wetting diffusion, characterized in that it is 10 ° or more and less than 90 °. Processed steel sheet.
아연계 도금강판의 표면에 방청피막이 형성된 표면처리강판으로서,
상기 방청피막은, 실리카, 실란커플링제 및 아크릴 수지를 주성분으로 하는 방청처리액에, 계면활성제, 입자경 0.05 ~ 5㎛의 미립자, 불소계 수지, 중에서 선택되는 1종 이상의 성분이 첨가된 표면처리액을 부착시켜, 가열건조하여 형성되는 것이며,
표면처리강판을 연신률20%로 소성가공한 후의 방청피막표면(A)에 대한, 40℃에서의 동점도가 51 ~ 69㎟/s, 100℃에서의 동점도가 11.1 ~ 14.9㎟/s인 윤활유의 접촉각(단, 강판표면온도 30℃에서, 방청피막표면에 윤활유의 액적을 형성하고나서 30초 후의 접촉각)이 10°이상 90°미만인 것을 특징으로 하는 내 오일-젖음확산성이 우수한 표면처리강판.
A surface-treated steel sheet having a rust-proof film formed on the surface of a galvanized steel sheet,
The rust preventive coating includes a surface treatment liquid in which at least one component selected from a surfactant, fine particles having a particle diameter of 0.05 to 5 μm, and a fluorine-based resin is added to an rust preventing treatment solution mainly containing silica, a silane coupling agent and an acrylic resin. Is formed by adhering, heating and drying,
Contact angle of lubricating oil having a kinematic viscosity of 51 to 69 mm2 / s at 40 ° C and a kinematic viscosity of 11.1 to 14.9 mm2 / s at 100 ° C to the rust-preventive film surface A after plastic working of the surface-treated steel sheet at 20% elongation. The surface-treated steel sheet having excellent oil-wetting diffusion resistance, wherein the contact angle after 30 seconds after forming droplets of lubricating oil on the surface of the rust-prevented coating film at a steel plate surface temperature of 30 ° C.
제1항에 있어서,
방청피막표면(A) 및 표면처리강판을 연신률20%로 소성가공한 후의 방청피막표면(A)에서의 크랙생성밀도가 100㎛당 200개 이하인 것을 특징으로 하는 내 오일-젖음확산성이 우수한 표면처리강판.
The method of claim 1,
The surface having excellent oil-wet diffusion resistance, characterized in that the crack formation density at the rust-preventive surface (A) after plastic processing of the rust-proof coating surface (A) and the surface-treated steel sheet at an elongation of 20% is 200 or less per 100 µm. Processed steel sheet.
제2항에 있어서,
방청피막표면(A) 및 표면처리강판을 연신률20%로 소성가공한 후의 방청피막표면(A)에 있어서의 크랙생성밀도가 100㎛당 200개 이하인 것을 특징으로 하는 내 오일-젖음확산성이 우수한 표면처리강판.
The method of claim 2,
The crack-producing density at the rust-preventive surface (A) after plastic processing of the rust-resistant coating surface (A) and the surface-treated steel sheet at an elongation of 20% is excellent in oil-wetting diffusion, characterized in that 200 or less per 100 µm. Surface-treated steel sheet.
제1항 내지 제4항 중 어느 한 항에 기재된 방청피막표면(A)의 조건을 만족하는 것을 특징으로 하는, 베어링을 지지하기 위한 베어링홀더부를 구비한 부품용의 표면처리강판.The surface treatment steel sheet for components provided with the bearing holder part for supporting a bearing characterized by satisfy | filling the conditions of the rustproof film surface (A) in any one of Claims 1-4. 제1항 내지 제4항 중 어느 한 항에 기재된 방청피막표면(A)의 조건을 만족하는 것을 특징으로 하는, 베어링을 지지하기 위한 베어링홀더부를 구비한 모터케이스용의 표면처리강판.The surface treatment steel sheet for motor cases provided with the bearing holder part for supporting a bearing characterized by satisfy | filling the conditions of the rustproof film surface (A) in any one of Claims 1-4. 제1항 내지 제4항 중 어느 한 항에 기재된 표면처리강판을 소성가공하여 얻은, 베어링을 지지하기 위한 베어링홀더부를 구비한 모터케이스로서, 방청피막표면(A)이 케이스 내면을 구성하는 것을 특징으로 하는 모터케이스.A motor case comprising a bearing holder portion for supporting a bearing obtained by plastic working the surface-treated steel sheet according to any one of claims 1 to 4, wherein the rust-preventive coating surface A constitutes the case inner surface. Motor case.
KR1020107000474A 2007-07-31 2008-07-30 Surface treated steel sheet having excellent anti oil-wettability and anti oil-diffusion KR101146830B1 (en)

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