KR101138828B1 - A light weight block and method formanufacturing the same - Google Patents

A light weight block and method formanufacturing the same Download PDF

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KR101138828B1
KR101138828B1 KR1020100096037A KR20100096037A KR101138828B1 KR 101138828 B1 KR101138828 B1 KR 101138828B1 KR 1020100096037 A KR1020100096037 A KR 1020100096037A KR 20100096037 A KR20100096037 A KR 20100096037A KR 101138828 B1 KR101138828 B1 KR 101138828B1
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weight
block
lightweight
binder
chitosan
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KR20120034457A (en
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박승주
류수착
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박승주
오리온산업(주)
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/26Producing shaped prefabricated articles from the material by slip-casting, i.e. by casting a suspension or dispersion of the material in a liquid-absorbent or porous mould, the liquid being allowed to soak into or pass through the walls of the mould; Moulds therefor ; specially for manufacturing articles starting from a ceramic slip; Moulds therefor
    • B28B1/265Producing shaped prefabricated articles from the material by slip-casting, i.e. by casting a suspension or dispersion of the material in a liquid-absorbent or porous mould, the liquid being allowed to soak into or pass through the walls of the mould; Moulds therefor ; specially for manufacturing articles starting from a ceramic slip; Moulds therefor pressure being applied on the slip in the filled mould or on the moulded article in the mould, e.g. pneumatically, by compressing slip in a closed mould
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/38Polysaccharides or derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

본 발명은 경량 무기소재 분말인 진주석, 규회석의 주원료에 결합제인 물유리, 키토산, 시멘트를 혼합하여 열처리 공정을 거치지 않고 프레스 성형한 것을 특징으로 하는 경량블록 및 그 제조방법에 관한 것으로, 기계적 강도가 높은 경량블록으로, 인체에 무해한 소재의 결합제인 물유리, 키토산 등을 사용하여 친환경적이며, 소성공정을 거치지 아니하여 화석연료를 사용하지 않음에 따라 탄소배출량이 없는 친환경적 공법인 것을 장점이다. The present invention relates to a light weight block and a method for manufacturing the same, characterized in that the press-molded without undergoing a heat treatment process by mixing water glass, chitosan, cement as a binder in the main raw material of pearlite, wollastonite, which is a lightweight inorganic material powder, mechanical strength is It is a light weight block that is eco-friendly using water glass, chitosan, etc., which is a material that is harmless to the human body, and is an eco-friendly method without carbon emissions because it does not use fossil fuel without undergoing a firing process.

Description

경량블록 및 그 제조방법{A light weight block and method formanufacturing the same}Light weight block and method for manufacturing the same {A light weight block and method formanufacturing the same}

본 발명은 경량블록 및 그 제조방법에 관한 것으로, 더욱 상세하게는 경량 무기소재 분말의 주원료에 결합제인 물유리, 키토산, 시멘트를 혼합하여 열처리 공정을 거치지 않고 프레스 성형하여 경량블록을 제조함으로써, 기계적 강도가 높은 경량 무기소재를 사용한 경량블록 및 그 제조방법에 관한 것이다.
The present invention relates to a light weight block and a method for manufacturing the same, and more particularly, by mixing water glass, chitosan, and cement, which are binders, in the main raw material of a light weight inorganic material powder, and manufacturing a light weight block by pressing a heat treatment without mechanically performing a heat treatment. It relates to a light weight block using a high weight lightweight inorganic material and a method of manufacturing the same.

건축물은 일반적으로 적벽돌이나 또는 시멘트 블록 등을 쌓아 건물 벽체를 시공하며, 건물의 단열성을 높이기 위해 벽체 시공시 단열재를 사용함에 따라 단열재 내외부에 중량감이 있는 블록을 이중으로 적층시켜 시공함에 따라 건축물에 가해지는 하중에 의해 벽체에 균열 등이 발생하는 문제점이 있었다.
Buildings generally build red bricks or cement blocks to build the walls of the building, and in order to increase the insulation of the building, the insulation is used to build the walls. There was a problem that a crack or the like occurred in the wall due to the applied load.

따라서, 최근에는 건축물에 가해지는 하중을 최대한 줄이기 위해 경량화시킨 벽돌이나 또는 블록의 개발이 다양하게 진행되고 있으며, 이와 같이 다양하게 개발되고 있는 경량블록에 관한 특허들을 살펴보면, 국내 등록실용신안공보 제384157호의 경량 콘크리트 블록과, 국내 등록실용신안공보 제317115호의 건축용 경량 블록 등이 알려져 있지만, 상기와 같은 블록들의 경우에는 등과 같이 블록 내부에 다수의 관통공들을 형성시켜 블록을 경량화시킴에 따라 블록의 압축강도, 휨강도 및 인장강도 등과 같은 물리적 특성이 저하할 우려가 있다.
Therefore, in recent years, various developments of lightweight bricks or blocks have been underway in order to minimize the load on buildings. Looking at the patents for lightly developed blocks, the registered Korean Utility Model Publication No. 384157 Although lightweight concrete blocks of No. 1 and light weight blocks for building of Korea Registered Utility Model Publication No. 317115 are known, in the case of the blocks as described above, a plurality of through-holes are formed in the block to reduce the weight of the blocks by making them lighter. There is a fear that physical properties such as strength, flexural strength, tensile strength, and the like deteriorate.

따라서, 상기와 같은 문제점을 해결하기 위하여, 블록 내부에 관통공들을 형성시키지 않고 섬유를 혼입하여 블록을 경량화시키는 기술이 개발되고 있으며, 관련 특허들로써, 국내 공개특허공보 제10-2005-0081782호의 강섬유 보강 시멘트 복합체와, 국내 공개특허공보 제10-2007-0120174호의 초고강도 섬유 보강 시멘트 조성물과, 국내 공개특허공보 제10-2005-0122153호의 탄소섬유보강 시멘트 복합재료 등이 공개되어 있다.
Therefore, in order to solve the above problems, a technology for lightening a block by incorporating fibers without forming through holes in the block has been developed. As related patents, steel fibers of Korean Patent Publication No. 10-2005-0081782 The reinforcing cement composite, the ultra-high strength fiber reinforcing cement composition of JP 10-2007-0120174, the carbon fiber reinforcing cement composite material of JP 10-2005-0122153, etc. are disclosed.

하지만, 상기와 같은 기술의 경우, 콘크리트의 취성파괴 등을 방지하기 위해 일반 콘크리트의 배합에 강섬유 및 유기섬유 등을 혼입하여 제조하는 섬유 보강 콘크리트(fiber reinfored concrete)로써, 일반 콘크리트의 배합에 섬유를 투입하므로 콘크리트의 점성 부족으로 섬유를 다량으로 투입하지 못하여 만족할 만할 인성을 확보하지도 못할 뿐더러, 섬유 뭉침(fiber ball) 현상이 발생하여 오히려 콘크리트의 성능을 저하시키는 경우도 발생하고 있다.
However, in the case of the above technique, in order to prevent the brittle fracture of the concrete, such as fiber reinfored concrete manufactured by mixing steel fibers and organic fibers in the mixing of the general concrete (fiber reinfored concrete), Due to the low viscosity of the concrete, a large amount of fiber could not be added and sufficient toughness could not be secured. Also, a fiber ball phenomenon occurred and the performance of the concrete was deteriorated.

또한, 섬유 혼입으로는 고강도 콘크리트의 취성파괴를 완전히 방지하지 못하여, 지진 또는 차량의 반복 및 충격하중, 화재 및 자연 열화현상 등이 발생하였을 때 곧바로 구조물이 파괴되는 등 기계적 강도와 같은 물리적 특성에 여전히 취약점을 안고 있다.
In addition, fiber incorporation does not completely prevent brittle fracture of high-strength concrete and is still affected by physical properties such as mechanical strength, such as structural destruction immediately after an earthquake, repetitive and impact load of a vehicle, fire, and natural deterioration. It has a vulnerability.

따라서, 본 발명은 상기와 같은 문제점들을 해결하기 위한 방안으로 경량 무기소재 분말인 진주석 및 규회석에 결합제인 물유리, 키토산, 시멘트를 혼합하여 열처리 공정을 거치지 않고 프레스 성형하여 경량블록을 제조함으로써, 기계적 강도가 높은 경량 무기소재를 사용한 것을 특징으로 하는 경량블록을 제공함을 과제로 한다.
Therefore, the present invention is a solution for solving the above problems by mixing water glass, chitosan, cement as a binder in the pearlite and wollastonite as a light weight inorganic material powder, and manufacturing a lightweight block by press molding without undergoing a heat treatment process, mechanical An object of the present invention is to provide a lightweight block characterized by using a high strength lightweight inorganic material.

특히 본 발명은 인체에 무해한 소재의 결합제인 물유리, 키토산 등을 사용하여 경량 블록을 제조함으로써, 친환경적이며, 소성공정을 거치지 아니하여 화석연료를 사용하지 않음에 따라 탄소배출량이 없는 친환경적 공법인 것을 특징으로 하는 경량블록의 제조방법을 제공함을 다른 과제로 한다.
In particular, the present invention by manufacturing a lightweight block using water glass, chitosan, etc., a binder of a harmless material to the human body, it is environmentally friendly, environmentally friendly method without carbon emissions by not using fossil fuel without undergoing a firing process Another object of the present invention is to provide a manufacturing method of a light weight block.

상기의 과제를 해결하기 위한 본 발명은 경량 무기소재 분말 40~60 중량%와 물유리 15~25 중량% 및 키토산 25~35 중량%로 이루어진 혼합 바인더와, The present invention for solving the above problems is a mixed binder consisting of 40 to 60% by weight of lightweight inorganic material powder, 15 to 25% by weight of water glass and 25 to 35% by weight of chitosan,

상기 혼합 바인더 100 중량부에 대하여, 포틀랜트 시멘트 10~30 중량부를 혼합하여 프레스 성형하여 제조한 것을 특징으로 하는 경량블록을 과제 해결 수단으로 한다.
A light weight block characterized in that it is manufactured by press molding by mixing 10-30 parts by weight of portland cement with respect to 100 parts by weight of the mixed binder is a problem solving means.

그리고 본 발명은 경량 무기소재 분말과 결합제를 혼합하여 혼합 바인더를 제조하는 단계와;And the present invention comprises the steps of preparing a mixed binder by mixing the lightweight inorganic material powder and the binder;

상기 혼합 바인더에 포틀랜트 시멘트를 혼합하여 모르타르를 제조하는 단계와;Preparing a mortar by mixing portland cement with the mixed binder;

상기 모르타르를 몰드에 충진하고 프레스 성형하는 단계 및;Filling the mortar with a mold and press molding;

성형한 경량블록을 건조 및 양생시키는 단계;Drying and curing the molded lightweight block;

를 거치는 것을 특징으로 하는 경량블록의 제조방법을 다른 과제 해결 수단으로 한다.
Method for manufacturing a light weight block, characterized in that through the other means to solve the problem.

본 발명에서 상기 경량 무기소재 분말은 진주석 45~55 중량%와 규회석 45~55 중량%로 이루어지고, In the present invention, the lightweight inorganic material powder is made of 45-55% by weight of pearlite and 45-55% by weight of wollastonite,

상기 키토산은 물에 쉽게 용해되는 수용성 키토산올리고당이 바람직하며, The chitosan is preferably a water-soluble chitosan oligosaccharide that is easily dissolved in water,

상기 모르타르는 혼합 바인더 100 중량부에 대하여, 포틀랜트 시멘트 10~30 중량부와, 물 45~55 중량부를 혼합하는 것이 바람직하다.
It is preferable that the said mortar mixes 10-30 weight part of portland cement with 45-55 weight part of water with respect to 100 weight part of mixed binders.

상기의 과제 해결 수단에 의한 본 발명은 경량 무기소재 분말인 진주석 및 규회석에 결합제 등을 혼합하여 열처리 공정을 거치지 않고 프레스 성형하여 경량블록을 제조함으로써, 기계적 강도가 높은 경량블록으로, 인체에 무해한 소재의 결합제인 물유리, 키토산 등을 사용하여 친환경적이며, 소성공정을 거치지 아니하여 화석연료를 사용하지 않음에 따라 탄소배출량이 없는 친환경적 공법인 것을 장점이다.
The present invention by the above-mentioned means to solve the problem is to form a light weight block by mixing the binder and the like in a light weight inorganic material powder, and the like without pressing a heat treatment process to produce a light weight block, high mechanical strength, harmless to the human body It is eco-friendly using water glass, chitosan, etc. as a binder of the material, and it is an eco-friendly method without carbon emissions because it does not use fossil fuel without undergoing the firing process.

이하, 본 발명의 바람직한 실시예를 상세히 설명하며, 상세한 설명에서 일반적인 블록 제조분야로부터 이 분야의 종사자들이 용이하게 알 수 있는 구성 및 작용에 대한 언급은 간략히 설명하고, 본 발명의 기술적 특징과 직접적으로 연관되지 않는 요소의 구체적인 기술적 구성 및 작용에 대한 상세한 설명은 생략하였다.
Hereinafter, preferred embodiments of the present invention will be described in detail, and in the detailed description, reference to configurations and operations easily understood by those skilled in the art from the general block manufacturing art will be briefly described and directly related to the technical features of the present invention. Detailed descriptions of specific technical configurations and operations of unrelated elements are omitted.

본 발명에 따른 경량블록을 상세히 설명하면 아래의 내용과 같다.
Hereinafter, the lightweight block according to the present invention will be described in detail.

본 발명은 경량 무기소재 분말 40~60 중량%와 물유리 15~25 중량% 및 키토산 25~35 중량%로 이루어진 혼합 바인더와, The present invention is a mixed binder consisting of 40 to 60% by weight of lightweight inorganic material powder, 15 to 25% by weight of water glass and 25 to 35% by weight of chitosan,

상기 혼합 바인더 100 중량부에 대하여, 포틀랜트 시멘트 10~30 중량부를 혼합하여 프레스 성형하여 제조한 것을 특징으로 한다.
10 to 30 parts by weight of the portland cement is mixed and manufactured by press molding with respect to 100 parts by weight of the mixed binder.

본 발명에서 사용하는 경량 무기소재 분말은 블록을 경량화시키는 무기소재분말로서, 경량 무기소재 분말의 혼합량은 40~60 중량%인 것이 바람직하다. 경량 무기소재 분말의 혼합량이 40 중량% 미만이 될 경우에는 압축강도, 휨강도, 인장강도 등의 기계적 강도의 향상을 기대하기 어려우며, 경량 무기소재 분말의 혼합량이 60 중량%를 초과할 경우에는 비중이 증가하여 경량블록을 제조할 수 없을 뿐만 아니라 가격경쟁력이 떨어지기 때문에 일부 특수한 분야에만 사용할 수 있다는 단점이 있다.
The lightweight inorganic material powder used in the present invention is an inorganic material powder for reducing the weight of the block, and the mixing amount of the lightweight inorganic material powder is preferably 40 to 60% by weight. When the mixed amount of the lightweight inorganic material powder is less than 40% by weight, it is difficult to expect the improvement of the mechanical strength such as the compressive strength, the bending strength, the tensile strength, and when the mixed amount of the lightweight inorganic material powder exceeds the 60% by weight, the specific gravity is high. In addition, it is not possible to manufacture a lightweight block due to the increase in price competitiveness is disadvantageous that can be used only in some special fields.

그리고 상기 경량 무기소재 분말은 진주석 45~55 중량%와 규회석 45~55 중량%로 이루어지는 것이 바람직하다.
And the lightweight inorganic material powder is preferably made of 45 ~ 55% by weight of pearlite and 45 ~ 55% by weight wollastonite.

상기 진주석은 경량블록의 기계적 강도를 향상시키면서도 경량화시키는 기능을 하며, 진주석의 혼합량이 45 중량% 미만이 될 경우에는 기계적 강도의 향상 효과가 미비하며, 진주석의 혼합량이 55 중량%를 초과할 경우에는 후술되어질 결합제와의 균일한 혼합이 어려워지는 단점이 있다.
The pearlite has a function of reducing the weight while improving the mechanical strength of the lightweight block, and when the mixing amount of pearlite is less than 45% by weight, the effect of improving the mechanical strength is insufficient, and when the mixing amount of the pearlite exceeds 55% by weight There is a disadvantage that uniform mixing with the binder to be described later becomes difficult.

또한 규회석은 경량블록의 기계적 강도를 향상시키면서도 경량화시키는 기능을 하며, 규회석의 혼합량이 45 중량% 미만이 될 경우에는 기계적 강도의 향상 효과가 미비하며, 규회석의 혼합량이 55 중량%를 초과할 경우에는 후술되어질 결합제와의 균일한 혼합이 어려워지는 단점이 있다.
In addition, the wollastonite functions to reduce the weight while improving the mechanical strength of the lightweight block.If the wollastonite mixture is less than 45 wt%, the effect of improving the mechanical strength is insignificant, and the wollastonite mixture exceeds 55 wt%. There is a disadvantage that uniform mixing with the binder to be described later becomes difficult.

그리고 본 발명에서 상기 물유리는 결합성, 내열성, 조막성 및 흡착성을 향상시키는 기능을 하며, 물유리의 혼합량은 15~25 중량%인 것이 바람직하다. 물유리의 혼합량이 15 중량% 미만이 될 경우에는 상기 기능을 발현시킬 수 없으며, 물유리의 혼합량이 25 중량%를 초과할 경우에는 성형 및 작업성이 떨어지는 단점이 있다.
And in the present invention, the water glass has a function to improve the bonding, heat resistance, film formation and adsorption properties, the mixing amount of the water glass is preferably 15 to 25% by weight. When the mixing amount of the water glass is less than 15% by weight, the above function cannot be expressed. When the mixing amount of the water glass exceeds 25% by weight, moldability and workability are inferior.

그리고 본 발명에서 상기 키토산은 결합성, 조막성 및 흡착성을 향상시킬 뿐만 아니라 항균, 방충 기능을 하며, 키토산의 혼합량은 25~35 중량%인 것이 바람직하다. 키토산의 혼합량이 25 중량% 미만이 될 경우에는 상기 기능을 발현시킬 수 없으며, 키토산의 혼합량이 35 중량%를 초과할 경우에는 성형 및 작업성이 떨어지는 단점이 있다.
And in the present invention, the chitosan not only improves the binding, film formation and adsorption, but also has an antibacterial and insect repellent function, and the mixing amount of chitosan is preferably 25 to 35% by weight. If the mixing amount of chitosan is less than 25% by weight can not express the function, when the mixing amount of chitosan exceeds 35% by weight has a disadvantage of poor moldability and workability.

한편, 상기 키토산은 물에 쉽게 용해되는 수용성 키토산올리고당인 것이 바람직하다. On the other hand, the chitosan is preferably a water-soluble chitosan oligosaccharide easily dissolved in water.

이때, 상기 키토산은 증류수가 담긴 비커에 빙초산을 50:1의 질량비로 첨가한 후, 열판자력교반기로 가열하고 교반시키면서 증류수 대비 키토산을 100:3의 질량비로 첨가하고 온도를 40~60℃로 유지시키면서, 농도가 변하지 않도록 밀봉하고, 10~12시간 이상 키토산이 완전히 녹을 때까지 가열교반시킨 후, 밀봉을 풀고 용액을 증발시켜 제조하는 것이 바람직하다.
At this time, the chitosan is added to the beaker containing the distilled water glacial acetic acid in a mass ratio of 50: 1, then heated and stirred with a hot plate magnetic stirrer while adding chitosan in a mass ratio of 100: 3 and maintaining the temperature at 40 ~ 60 ℃ It is preferable to make it seal so that a density | concentration will not change, heat-stirring until chitosan melt | dissolves completely for 10 to 12 hours or more, and to manufacture by evaporating a sealing and evaporating a solution.

그리고 본 발명은 혼합 바인더 100 중량부에 대하여, 포틀랜트 시멘트 10~30 중량부를 혼합하여 프레스 성형하여 제조한다. 본 발명에서 포트랜트 시멘트의 혼합량이 10 중량% 미만이 될 경우에는 프레스 성형을 통한 블럭제조 방법을 적용할 수 없으며, 포트랜트 시멘트의 혼합량이 30 중량%를 초과할 경우에는 혼합 바인더에 의한 경량화 및 기계적 강도의 향상 효과가 미비하게 되는 단점이 있다.
And the present invention is manufactured by press molding by mixing 10-30 parts by weight of portland cement with respect to 100 parts by weight of the mixed binder. In the present invention, when the mixing amount of the port cement is less than 10% by weight, the block manufacturing method through the press molding is not applicable, and when the mixing amount of the port cement exceeds 30% by weight, the weight of the mixing binder is reduced and There is a disadvantage that the effect of improving the mechanical strength is insufficient.

본 발명은 상기의 구성성분과 구성비에 의해 경량블록이 제조되어지며, 본 발명에 따른 경량블록의 제조방법을 상세히 설명하면 아래의 내용과 같다.
The present invention is a lightweight block is manufactured by the above components and the ratio, and the manufacturing method of the lightweight block according to the present invention in detail as follows.

본 발명에 따른 경량블록은 경량 무기소재 분말과 결합제를 혼합하여 혼합 바인더를 제조하는 단계와; 상기 혼합 바인더에 포틀랜트 시멘트를 혼합하여 모르타르를 제조하는 단계와; 상기 모르타르를 몰드에 충진하고 프레스 성형하는 단계 및; 성형한 경량블록을 건조 및 양생시키는 단계;를 거쳐 제조되어진다.
The lightweight block according to the present invention comprises the steps of preparing a mixed binder by mixing a lightweight inorganic material powder and a binder; Preparing a mortar by mixing portland cement with the mixed binder; Filling the mortar with a mold and press molding; It is manufactured through the step of drying and curing the molded lightweight block.

상기 혼합 바인더를 제조하는 단계에서 혼합 바인더는 경량 무기소재 분말 40~50 중량%와 물유리 15~25 중량% 및 키토산 25~35 중량%로 이루어지는 것이 바람직하며, 상기 각 구성성분에 대해서는 상기에서 이미 상세히 설명한 바 있으므로 여기서는 그 설명을 생략하기로 한다.
In the step of preparing the mixed binder, the mixed binder is preferably composed of 40 to 50% by weight of the lightweight inorganic material powder, 15 to 25% by weight of water glass and 25 to 35% by weight of chitosan. Since it has been described, the description thereof will be omitted here.

그리고 상기 모르타르를 제조하는 단계에서 모르타르는 혼합 바인더 100 중량부에 대하여, 포틀랜트 시멘트 10~30 중량부와, 물 45~55 중량부를 혼합하는 것이 바람직하다.
And it is preferable to mix 10-30 weight part of portland cement, and 45-55 weight part of water with respect to 100 weight part of mortar mixed mortar in the said mortar manufacturing process.

상기에서 물의 혼합량이 45 중량부 미만이 될 경우에는 점도가 필요 이상으로 증가하여 작업성이 떨어지며, 물의 혼합량이 55 중량부를 초과할 경우에는 점도가 낮아 블럭으로 프레스 성형할 수 없는 단점이 있다.
When the mixing amount of water is less than 45 parts by weight, the viscosity is more than necessary to increase the workability, when the mixing amount of water exceeds 55 parts by weight has a disadvantage that can not be press-molded into a low block viscosity.

그리고 상기 프레스 성형하는 단계에서는 전 단계에서 제조한 모르타르를 내부 공간이 블럭 형상을 갖는 몰드에 충진시킨 다음 50~200kgf/㎠의 압력으로 1~60초간 프레스 성형한 후, 30~60℃의 온도에서 24시간 동안 자연 양생하여 경량블럭을 제조한다.
In the press molding step, the mortar prepared in the previous step is filled into a mold having an internal space block shape, and then press-molded for 1 to 60 seconds at a pressure of 50 to 200 kgf / cm 2, at a temperature of 30 to 60 ° C. Natural curing for 24 hours to produce a light block.

이하 본 발명에 따른 경량블록은 아래의 실시 예를 통해 구체적으로 설명하면 다음과 같으며, 본 발명은 아래의 실시 예에 의해서만 반드시 한정되는 것이 아니다.
Hereinafter, the lightweight block according to the present invention will be described in detail with reference to the following embodiments, and the present invention is not necessarily limited only to the following embodiments.

1. 경량블록의 제조
1. Manufacturing of Lightweight Blocks

(실시예 1)(Example 1)

진주석 45 중량%와 규회석 55 중량%로 이루어진 경량 무기소재 분말 60 중량%에 물유리 15 중량%(주물2호,(주)영일화성)를 혼합하고 30분간 숙성시킨 후, 수용성 키토산올리고당 25 중량%를 혼합하여 30분간 숙성시켜 혼합 바인더를 제조하고, 상기 혼합 바인더 100중량부에 대하여 포틀랜트 시멘트 10 중량부를 혼합하고 30분간 숙성시켜 모르타르를 제조한 후, 상기 모르타르를 몰드에 충진하고 200kgf/㎠의 압력으로 45초간 프레스 성형한 후, 40℃에서 24시간 동안 자연 양생하여 경량블록을 제조하였다.
60% by weight of lightweight inorganic material powder consisting of 45% by weight of pearlite and 55% by weight of wollastonite was mixed with 15% by weight of water glass (Cast No. 2, Yeongil Hwaseong) and aged for 30 minutes, and then 25% by weight of water-soluble chitosan oligosaccharides. After mixing for 30 minutes to prepare a mixed binder, 10 parts by weight of Portland cement is mixed with respect to 100 parts by weight of the mixed binder and aged for 30 minutes to prepare a mortar, the mortar is filled into a mold and 200kgf / ㎠ After press-molding for 45 seconds under pressure, light curing was prepared by natural curing at 40 ° C. for 24 hours.

(실시예 2)(Example 2)

진주석 55 중량%와 규회석 45 중량%로 이루어진 경량 무기소재 분말 40 중량%에 물유리 25 중량%(주물2호,(주)영일화성)를 혼합하고 30분간 숙성시킨 후, 수용성 키토산올리고당 35 중량%를 혼합하여 30분간 숙성시켜 혼합 바인더를 제조하고, 상기 혼합 바인더 100중량부에 대하여 포틀랜트 시멘트 30 중량부를 혼합하고 30분간 숙성시켜 모르타르를 제조한 후, 상기 모르타르를 몰드에 충진하고 200kgf/㎠의 압력으로 45초간 프레스 성형한 후, 40℃에서 24시간 동안 자연 양생하여 경량블록을 제조하였다.
40% by weight of lightweight inorganic material powder consisting of 55% by weight of pearlite and 45% by weight of wollastonite was mixed with 25% by weight of water glass (Cast No. 2, Yeongil Hwaseong) and aged for 30 minutes, followed by 35% by weight of water-soluble chitosan oligosaccharides. After mixing for 30 minutes to prepare a mixed binder, 30 parts by weight of portland cement is mixed with respect to 100 parts by weight of the mixed binder and aged for 30 minutes to prepare a mortar, the mortar is filled into a mold and 200kgf / ㎠ After press-molding for 45 seconds under pressure, light curing was prepared by natural curing at 40 ° C. for 24 hours.

(비교예 1)(Comparative Example 1)

포틀랜트 시멘트 100 중량%로 이루어진 모르타르를, 측면 전체 길이의 1/3에 해당하는 관통홀이 한 쌍으로 형성된 몰드에 충전시킨 후, 40℃에서 24시간 동안 자연 양생하여 경량블록을 제조하였다.
Mortar made of 100% by weight of Portland cement was filled in a mold formed with a pair of through holes corresponding to 1/3 of the side length, and then naturally cured at 40 ° C. for 24 hours to prepare a light block.

(비교예 2)(Comparative Example 2)

포틀랜트 시멘트 100 중량부에 대하여, 직경이 0.2mm이고 길이가 12mm인 강섬유 1 중량부 및 직경이 0.35mm이고 길이가 30mm인 강섬유 2 중량부를 투입하여 모르타르를 제조하고, 상기 제조된 모르타르를 40℃에서 24시간 동안 자연 양생한 후, 100℃의 온도에서 48시간 동안 증기양생을 실시하여 경량블럭을 제조하였다.
Mortar was prepared by adding 1 part by weight of steel fiber having a diameter of 0.2 mm and a length of 12 mm and 2 parts by weight of steel fiber having a diameter of 0.35 mm and a length of 30 mm, based on 100 parts by weight of portland cement. After natural curing for 24 hours at, by performing steam curing for 48 hours at a temperature of 100 ℃ to produce a light block.

상기와 같이, 실시예 1 및 실시예 2는 경량 무기소재 분말과 결합제로 이루어진 혼합바인더에 포틀랜트시멘트를 혼합하여 경량블록을 제조한 것이며, 비교예 1은 포틀랜트 시멘트로 이루어진 블록에 관통홀을 형성시켜 경량블록을 제조한 것이고, 비교예 2는 포틀랜트 시멘트에 강섬유를 혼합하여 경량블록을 제조한 것으로, 상기 각 실시예 및 비교예의 구성성분을 아래 [표 1]에 나타내었다.
As described above, Example 1 and Example 2 is to manufacture a lightweight block by mixing the portant cement in a mixed binder consisting of a lightweight inorganic material powder and a binder, Comparative Example 1 is a through-hole in a block made of Portland cement Formed to prepare a lightweight block, Comparative Example 2 was prepared by mixing a steel fiber in Portland cement to produce a lightweight block, the components of each of the above Examples and Comparative Examples are shown in Table 1 below.

(단위 : 중량부)  (Unit: parts by weight) 실시예 1Example 1 실시예 2Example 2 비교예 1Comparative Example 1 비교예 2Comparative Example 2 혼합바인더Mixed Binder 100주1) 100 Note 1) 100주2) 100 Note 2) -- -- 포틀랜트 시멘트Portland Cement 1010 3030 100주3) 100 Note 3) 100100 강섬유Steel fiber -- -- -- 3주4) 3 Note 4)
주 1) 진주석 45 중량%와 규회석 55 중량%로 이루어진 경량 무기소재 분말 60 중량%에 결합제로써 물유리 15 중량% 및 수용성 키토산올리고당 25 중량%를 혼합

주 2) 진주석 55 중량%와 규회석 45 중량%로 이루어진 경량 무기소재 분말 40 중량%에
결합제로써 물유리 25 중량% 및 수용성 키토산올리고당 35 중량%를 혼합

주 3) 블럭의 측면에, 측면 전체 길이의 1/3에 해당하는 관통홀을 한 쌍으로 형성

주 4) 직경이 0.2mm이고 길이가 12mm인 강섬유 1 중량부 및
직경이 0.35mm이고 길이가 30mm인 강섬유 2 중량부를 투입

Note 1) Mix 15 wt% water glass and 25 wt% water-soluble chitosan oligosaccharides as a binder to 60 wt% of a lightweight inorganic material powder composed of 45 wt% pearlite and 55 wt% wollastonite.

Note 2) To 40% by weight of a lightweight inorganic material powder consisting of 55% by weight pearlite and 45% by weight wollastonite
25 wt% water glass and 35 wt% water-soluble chitosan oligosaccharides are mixed as a binder.

Note 3) A pair of through-holes corresponding to 1/3 of the total length of the sides is formed on the side of the block.

4) 1 part by weight of steel fiber 0.2 mm in diameter and 12 mm in length;
2 parts by weight of steel fiber 0.35 mm in diameter and 30 mm in length

2. 압축강도, 휨강도 및 인장강도 측정
2. Measurement of compressive strength, flexural strength and tensile strength

상기 실시예 1, 2 및 비교예 1, 2에 의해 제조된 경량블록을 KS F 2405(콘크리트 압축강도 시험방법)에 의한 압축강도 시험을 수행하였고, KS F 2408(콘크리트의 휨강도 시험방법)에 의하여 휨강도 시험을 수행하였고, KS F 2423(콘크리트의 인장강도 시험방법)에 의하여 인장강도 시험을 수행하였으며, 재령 3일을 기준으로 그 결과를 [표 2]에 나타내었다.
The lightweight blocks prepared in Examples 1 and 2 and Comparative Examples 1 and 2 were subjected to a compressive strength test by KS F 2405 (concrete compressive strength test method), and according to KS F 2408 (conductivity test method of concrete). The flexural strength test was carried out, and the tensile strength test was performed by KS F 2423 (test method for tensile strength of concrete), and the results are shown in [Table 2] on the basis of 3 days of age.

(단위 : kgf/㎠)(Unit: kgf / ㎠) 실시예 1Example 1 실시예 2Example 2 비교예 1Comparative Example 1 비교예 2Comparative Example 2 압축강도Compressive strength 109109 121121 8686 102102 휨강도Flexural strength 1111 1313 66 77 인장강도The tensile strength 88 99 33 44

상기와 같이, 진주석 및 규회석으로 이루어진 경량 무기소재 분말에, 물유리 및 키토산로 이루어진 결합제를 혼합한 혼합바인더에 포틀랜트 시멘트를 혼합한 실시예 1 및 실시예 2가, 포틀랜트 시멘트로 이루어진 블록에 관통홀을 형성시킨 비교예 1 및 포틀랜트 시멘트에 강섬유를 혼합한 비교예 2보다 압축강도, 휨강도, 인장강도가 월등히 우수함을 알 수 있다.
As described above, Example 1 and Example 2, in which the port binder cement was mixed with a light binder made of pearlite and wollastonite, and a binder of water glass and chitosan, were mixed in a block made of portland cement. It can be seen that the compressive strength, the flexural strength, and the tensile strength were much better than those of Comparative Example 1 in which the through-holes were formed and Comparative Example 2 in which the steel fibers were mixed in the portland cement.

한편, 실시예 1 및 실시예 2의 경우, 포틀랜트시멘트의 첨가량 비율이 30중량부에서 강도 향상이 크게 나타났으며, 압축강도의 경우 임계 첨가량은 25중량부 이상으로 추정되고, 휨강도 및 인장강도의 경우 포틀랜트시멘트의 첨가량에 따라 강도 향상이 비례해서 나타났다.
On the other hand, in the case of Example 1 and Example 2, the increase in the strength of the addition amount of the portant cement was 30 parts by weight, the critical addition amount in the case of compressive strength is estimated to be 25 parts by weight or more, bending strength and tensile strength In the case of, the strength improvement was proportional to the amount of portant cement added.

뿐만 아니라 본 발명은 경량 무기소재 분말인 진주석 및 규회석에 결합제 등을 혼합하여 열처리 공정을 거치지 않고 프레스 성형하여 경량블록을 제조함으로써, 기계적 강도가 높은 경량블록으로, 인체에 무해한 소재의 결합제인 물유리, 키토산 등을 사용하여 친환경적이며, 소성공정을 거치지 아니하여 화석연료를 사용하지 않음에 따라 탄소배출량이 없는 친환경적 공법이다.
In addition, the present invention by mixing the binder with pearlite and wollastonite, which is a lightweight inorganic material powder, and press-molded without going through a heat treatment process to produce a lightweight block, water glass, which is a lightweight block with high mechanical strength, is a material harmless to the human body It is eco-friendly using chitosan, etc., and does not use fossil fuel without going through the firing process.

상술한 바와 같은, 본 발명의 바람직한 실시예에 따른 경량블록을 상기한 설명에 따라 상세히 설명하였지만, 이는 예를 들어 설명한 것에 불과하며 본 발명의 기술적 사상을 벗어나지 않는 범위 내에서 다양한 변화 및 변경이 가능하다는 것을 이 분야의 통상적인 기술자들은 잘 이해할 수 있을 것이다.As described above, the light weight block according to the preferred embodiment of the present invention has been described in detail according to the above description, but this is merely described, for example, and various changes and modifications can be made without departing from the technical spirit of the present invention. It will be appreciated by those skilled in the art.

Claims (6)

경량 무기소재 분말 40~60 중량%와 물유리 15~25 중량% 및 키토산 25~35 중량%로 이루어진 혼합 바인더와,
상기 혼합 바인더 100 중량부에 대하여, 포틀랜트 시멘트 10~30 중량부를 혼합하여 프레스 성형하여 제조한 것을 특징으로 하는 경량블록.
A mixed binder consisting of 40 to 60 wt% of lightweight inorganic material powder, 15 to 25 wt% of water glass and 25 to 35 wt% of chitosan,
Lightweight block, characterized in that manufactured by press molding by mixing 10 to 30 parts by weight of portland cement with respect to 100 parts by weight of the mixed binder.
제 1항에 있어서,
상기 경량 무기소재 분말은 진주석 45~55 중량%와 규회석 45~55 중량%로 이루어지는 것을 특징으로 하는 경량블록.
The method of claim 1,
The lightweight inorganic material powder is a lightweight block, characterized in that consisting of 45-55% by weight of pearlite and 45-55% by weight of wollastonite.
제 1항에 있어서,
상기 키토산은 물에 쉽게 용해되는 수용성 키토산올리고당인 것을 특징으로 하는 경량블록.
The method of claim 1,
The chitosan is a lightweight block, characterized in that the water-soluble chitosan oligosaccharides are easily dissolved in water.
경량 무기소재 분말과 결합제를 혼합하여 혼합 바인더를 제조하는 단계와;
상기 혼합 바인더에 포틀랜트 시멘트를 혼합하여 모르타르를 제조하는 단계와;
상기 모르타르를 몰드에 충진하고 프레스 성형하는 단계 및;
성형한 경량블록을 건조 및 양생시키는 단계;를 포함하되,
상기 혼합 바인더는 경량 무기소재 분말 40~50 중량%와 물유리 15~25 중량% 및 키토산 25~35 중량%로 이루어지는 것을 특징으로 하는 경량블록의 제조방법.
Preparing a mixed binder by mixing the lightweight inorganic material powder and the binder;
Preparing a mortar by mixing portland cement with the mixed binder;
Filling the mortar with a mold and press molding;
Including; drying and curing the molded lightweight block;
The mixed binder is 40 to 50% by weight of the lightweight inorganic material powder, 15 to 25% by weight of water glass and 25 to 35% by weight of chitosan manufacturing method of the light block.
삭제delete 제 4항에 있어서,
상기 모르타르는 혼합 바인더 100 중량부에 대하여, 포틀랜트 시멘트 10~30 중량부와, 물 45~55 중량부를 혼합하는 것을 특징으로 하는 경량블록의 제조방법.
The method of claim 4, wherein
The mortar is a method for producing a light weight block, characterized in that 10 to 30 parts by weight of portland cement and 45 to 55 parts by weight of water are mixed with respect to 100 parts by weight of the mixed binder.
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KR102079898B1 (en) 2019-05-30 2020-02-20 주식회사 네이처 Manufacturing method of functional lightweight board for non-firing construction finishing material and functional lightweight board for non-firing construction finishing material manufactured by the same

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