KR101030717B1 - Anti-sticking paints composition, anti-sticking sheet using thereof - Google Patents
Anti-sticking paints composition, anti-sticking sheet using thereof Download PDFInfo
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- KR101030717B1 KR101030717B1 KR1020090090597A KR20090090597A KR101030717B1 KR 101030717 B1 KR101030717 B1 KR 101030717B1 KR 1020090090597 A KR1020090090597 A KR 1020090090597A KR 20090090597 A KR20090090597 A KR 20090090597A KR 101030717 B1 KR101030717 B1 KR 101030717B1
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- 239000000203 mixture Substances 0.000 title claims abstract description 20
- 239000003973 paint Substances 0.000 title abstract description 8
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- 238000004383 yellowing Methods 0.000 description 2
- DPBYCORQBMMFJZ-UHFFFAOYSA-N 20-episilicine Natural products O=C1CC2C(CC)CN(C)CC2CC2=C1NC1=CC=CC=C21 DPBYCORQBMMFJZ-UHFFFAOYSA-N 0.000 description 1
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- 241000196324 Embryophyta Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C08K2003/321—Phosphates
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Abstract
본 발명은 광고물 부착 방지 도료 조성물 및 이를 이용한 광고물 부착 방지 시트에 관한 것으로서, 더욱 상세하게는 각종 구조물 또는 각종 시설물의 외벽에 점착제나 접착제가 도포된 홍보물, 광고지, 스티커 (이하 광고물이라 함)의 부착을 원천적으로 방지하고, 각종 매연이나 유기 오염 물질을 쉽게 제거할 수 있는 광고물 부착 방지 도료 조성물 및 이를 이용한 광고물 부착 방지 시트에 관한 것이다. The present invention relates to an anti-adhesive coating composition and an anti-adhesive sheet using the same, and more specifically, an advertisement, an adhesive paper, a sticker (hereinafter referred to as an advertisement material) in which an adhesive or an adhesive is applied to an outer wall of various structures or various facilities. The present invention relates to an advertisement adhesion preventing coating composition capable of preventing the attachment of the original, and easily removing various soot and organic contaminants, and an advertisement adhesion preventing sheet using the same.
본 발명의 도료조성물은 무독성 수분산 수지 40 내지 70중량%, 가교제 1 내지 10중량%, 충진재 5 내지 20중량%, 변성실리콘 1 내지 5중량%, 광촉매제 1 내지 5중량%, 소포제 0.1 내지 0.5 중량%, 방부제 0.01 내지 0.1 중량%, 및 여분의 물이 혼합하여 이루어진다.The paint composition of the present invention is 40 to 70% by weight non-toxic water dispersion resin, 1 to 10% by weight crosslinking agent, 5 to 20% by weight filler, 1 to 5% by weight modified silicone, 1 to 5% by weight photocatalyst, antifoaming agent 0.1 to 0.5 Weight percent, preservative 0.01 to 0.1 weight percent, and excess water.
광고물, 시트, 도료, 무독성 수분산수지, 변성실리콘, 광촉매제 Advertisements, Sheets, Paints, Non-Toxic Water Dispersants, Modified Silicones, Photocatalysts
Description
본 발명은 광고물 부착 방지 도료 조성물 및 이를 이용한 광고물 부착 방지 시트에 관한 것으로서, 더욱 상세하게는 각종 구조물 또는 각종 시설물의 외벽에 점착제나 접착제가 도포된 홍보물, 광고지, 스티커 (이하 광고물이라 함)의 부착을 원천적으로 방지하고, 각종 매연이나 유기 오염 물질을 쉽게 제거할 수 있는 광고물 부착 방지 도료 조성물 및 이를 이용한 광고물 부착 방지 시트에 관한 것이다. The present invention relates to an anti-adhesive coating composition and an anti-adhesive sheet using the same, and more specifically, an advertisement, an adhesive paper, a sticker (hereinafter referred to as an advertisement material) in which an adhesive or an adhesive is applied to an outer wall of various structures or various facilities. The present invention relates to an advertisement anti-stick coating composition that can prevent the attachment of the original, and to easily remove various soot and organic contaminants, and to prevent the ad attachment sheet using the same.
현대인들은 헤아릴 수 없이 수많은 광고매체를 통해 선전되어지는 광고물을 접하면 살아가고 있고, 광고매체 역시 다양하다.Modern people live when they encounter advertisements advertised through countless advertisement media, and the advertisement media are diverse.
상기 광고는 영업방법의 한 가지 수단으로써, 광고 형태 또한 다양하다.The advertisement is one means of sales method, the advertisement form also varies.
상기의 광고형태 중 하나가 광고 인쇄가 되어 있는 인쇄물을 통한 각종 홍보물로써, 상기 홍보물은 사람들에게 직접 나누어주거나 구조물, 전주 또는 각종 시설물에 부착되어 사용된다. One of the forms of advertising is a variety of promotional materials through printed matter printed advertising, the promotional materials are directly distributed to people or used to attach to structures, poles or various facilities.
상기 인쇄물을 통한 광고는 광고에 따른 비용이 저렴하여 가장 선호하는 광고방법 중의 하나이기도 하나, 이렇게 상업적으로 사용되는 광고물이 난무하게 되면 미관을 해치게 되므로 광고물 부착장소를 지정하여 부착하도록 법제화 되어 있는 바, 그럼에도 불구하고 일반인에 나누어준 인쇄물 및 불법으로 부착되는 광고물은 마구 버려져 길거리를 지저분하게 하는 요인이 되기도 하고, 구조물이나 시설물에 부착되어지는 광고물은 도시미관(都市美觀)를 해치게 된다.Advertisement through the printed matter is one of the most preferred advertising method because the cost according to the advertisement is low, but when commercially used advertisements are disturbed, it hurts the aesthetics. Nevertheless, printed matters distributed to the general public and advertisements that are illegally attached may be thrown away and become messy on the streets, and advertisements attached to structures or facilities may damage the city's beauty.
상기 광고물은 주로 시야확보가 우수한 지역의 구조물(건물, 다리, 축대, 터널)이나 시설물(가로등, 전신주, 신호등지주)을 그 대상이 되게 되는데, 그 이유는 시야확보가 양호한 구조물과 시설물은 광고대로써의 훌륭한 기능을 발휘하기 때문이다. 구조물의 외벽이나 시설물의 외측면에 부착되어진 불법 광고물을 방치할 경우, 상기에서 기술한 도시미관(都市美觀)을 해침은 물론 길거리로 떨어져 불법 광고물에 의한 주변 환경을 오염이 가속화되어 각 지방자치단체나 국가에서는 사람을 고용하여 이러한 광고물을 많은 시간과 비용을 들여 제거 하고 있는 실정이다. The advertisement mainly targets structures (buildings, bridges, shafts, tunnels) or facilities (street lamps, telephone poles, traffic lights, etc.) with excellent visibility because the structures and facilities with good visibility are classified as advertisements. This is because it has a great function. In case of leaving illegal advertisements attached to the outer wall of the structure or the outside of the facility, the city is not only damaged by the above-mentioned city aesthetics, but also falls into the street, accelerating the pollution of the surrounding environment by illegal advertisements, Local governments and countries employ people to remove these advertisements in large amounts of time and money.
상기와 같이 부착된 불법 광고물을 떼어내는 작업은 임시 방편에 그치게 된다. 그 이유는 불법광고부착물을 떼어낸 자리에 다시 다른 불법광고부착물이 붙기 때문이고, 불법광고부착물의 반복적인 부착은 예산낭비를 불러오는 2차적인 요인이 되기도 한다.The removal of the illegal advertisements attached as described above is only temporary. The reason for this is that another illegal advertisement attachment is attached to the place where the illegal advertisement attachment is removed, and repeated attachment of the illegal advertisement attachment may be a secondary factor causing budget waste.
따라서, 구조물이나 시설물에 불법 광고물을 근본적으로 부착할 수 없도록 하는 것이 중요하다.Therefore, it is important not to fundamentally attach illegal advertisements to structures or facilities.
이러한 광고물은 일단 부착되면 강한 접착력에 의해 제거하기 곤란하게 되므 로 광고물 부착을 방지하기 위한 여러 가지 방법들이 제시되고 있으며 그 일 예로서 한국특허공보 제2005-0032032호가 있으며, 이는 폴리우레탄 수지를 주 수지 성분으로 하고 충진제로는 풀리에틸렌 파우더와 실리크린 첨가제를 크실렌과 톨루엔에 혼합하여 사용하는 것으로 구성되어 있다. 이 발명에 사용된 크실렌과 톨루엔의 유기 용제는 환경적으로 유해한 용제들로 규제되어지고 있는 실정이라서 정부 친환경적인 정책에 반하는 제품이라 할 수 있다. 또한, 도로상 구조물에 시공됨에 따라 매연이나 먼지 등의 오염에 대한 내구성이 있어야 하지만 이 발명의 경우는 초기에는 그 효과가 있을 수 있으나 시간이 지남에 따라 주요 기능인 부착 방지 효과가 저하되는 문제점이 있었다.Once advertised, it is difficult to remove it by strong adhesive force once attached, and various methods for preventing adhering have been proposed. For example, Korean Patent Publication No. 2005-0032032 describes a polyurethane resin. It is composed of the main resin component and the filler used by mixing pulley ethylene powder and silicine additive in xylene and toluene. The organic solvents of xylene and toluene used in the present invention are regulated by environmentally harmful solvents and thus may be said to be contrary to the government environmentally friendly policy. In addition, the construction of the road structure should be durable against pollution such as smoke or dust, but in the case of the present invention may have an effect in the early stage, but there was a problem that the anti-sticking effect, which is a main function, deteriorates over time. .
종래에 플라스틱을 이용한 방법으로 한국특허출원 2000-0186914에 소개된 것은 플라스틱 의 표면에 다수의 돌출 부위를 만들어 광고물의 부착을 어렵게 만들었으나, 이는 미관상 좋지 않으며 겨울에는 플라스틱이 깨져 주위에 나쁜 영향을 미칠 수 있으며, 작업 시공비가 일반 코팅제에 비하여 4배정도 비싼 단점이 있었다.Conventionally, the method of using plastic was introduced in Korean Patent Application No. 2000-0186914, which made a large number of protrusions on the surface of the plastic, making it difficult to adhere to the advertisement. And, the construction cost was about four times more expensive than the general coating.
또 한국특허공보 제2000-0036990에 소개된 식용유를 이용한 부착방지제는 일시적으로 불법 광고물이 부착되는 것을 방지하는 효과는 있지만 사용된 피착체의 오염도가 너무 심할 뿐만 아니라 코팅물이 시간이 경과함에 따라 먼지 등의 이물질이 다량으로 달라붙어 미관상 혐오감을 주는 경향이 있다.In addition, the anti-sticking agent using cooking oil introduced in Korean Patent Publication No. 2000-0036990 temporarily prevents illegal advertisements from adhering, but the degree of contamination of the adherend used is too severe, and the coating material has elapsed over time. There is a tendency to attach a large amount of foreign matter such as dust and give aesthetic disgust.
본 발명은 상기와 같은 종래 문제점을 해결하기 위해 안출한 것으로, 그 목 적은 작은 입자로 분무하여 구조물이나 시설물의 외벽에 도포하여 광고물의 부착을 차단할 수 있도록 한 것으로서, 1차적으로 부착 방지 기능을 가지고 2차적으로는 자체 세정 작용을 가짐으로써 1차 기능인 부착 방지 효과를 장기간 유지할 수 있으며, 광고물 부착 방지제의 도포작업시간의 단축함과 함께 노동력의 사용을 최소화하여 광고물 차단에 따른 예산을 현저하게 줄였을 뿐만 아니라, 광고물의 부착이 근본적으로 차단되어 광고물 부착으로 구조물이나 시설물을 사후 관리해야 했던 번거러움을 해소시킨 스프레이 도포 가능한 광고물 부착 방지 도료 조성물을 제공함에 있다. The present invention has been made to solve the conventional problems as described above, the purpose of which is to spray on the small particles to apply to the outer wall of the structure or facility to block the adhesion of the advertisement, and has a function of preventing the attachment primarily Secondly, it has a self-cleaning effect to maintain the primary anti-sticking effect for a long time. It also shortens the application work time of the anti-sticking agent and minimizes the use of labor force. In addition to reducing the adhesion of the advertisement is fundamentally blocked to provide a spray-applicable advertising anti-adhesive coating composition that eliminates the hassle of having to follow up the structure or facility by ad attachment.
또한,본 발명의 다른 목적은 본 발명에 따른 도료 조성물을 이용하여 상기 조성물의 도포층이 형성된 광고물 부착 방지 시트를 제공하는 것이다.In addition, another object of the present invention is to provide an advertisement attachment prevention sheet having a coating layer of the composition using the coating composition according to the present invention.
상기한 기술적 과제를 달성한 본 발명은 무독성 수분산 수지 40 내지 70중량%, 가교제 1 내지 10중량%, 충진재 5 내지 20중량%, 변성실리콘 1 내지 5중량%, 광촉매제 1 내지 5중량%, 소포제 0.1 내지 0.5 중량%, 방부제 0.01 내지 0.1 중량%, 및 여분의 물이 혼합하여 된 광고물 부착 방지 도료 조성물을 제공한다. The present invention to achieve the above technical problem is a non-toxic water dispersion resin 40 to 70% by weight, crosslinking agent 1 to 10% by weight, filler 5 to 20% by weight, modified silicone 1 to 5% by weight, photocatalyst 1 to 5% by weight, An anti-adhesion coating composition comprising 0.1 to 0.5% by weight of antifoam, 0.01 to 0.1% by weight of preservative, and excess water is provided.
또한, 본 발명은 상기 무독성 수분산 수지로 규소 변성 아크릴 에멀젼수지, 우레탄 에멀젼 수지 또는 아크릴 에멀젼 수지로 이루어진 군에서 선택된 1종 또는 2종 이상의 혼합물을 사용하는 광고물 부착 방지 도료 조성물이 제공된다..In addition, the present invention provides an advertisement adhesion preventing coating composition using one or two or more mixtures selected from the group consisting of silicon-modified acrylic emulsion resins, urethane emulsion resins or acrylic emulsion resins as the non-toxic water-dispersible resin.
또한, 본 발명은 상기 가교제로 아지리딘 화합물을 사용한 광고물 부착 방지 도료 조성물을 제공한다.In addition, the present invention provides an advertisement adhesion preventing coating composition using an aziridine compound as the crosslinking agent.
또한, 본 발명은 상기 충진재로 입자크기 50 내지 300미크론 범위의 입자분포를 가지는 폴리에틸렌, 폴리메틸메타아클릴레이트 또는 폴리비닐클로이드로 이루어진 군에서 선택된 1종을 사용한 광고물 부착 방지 도료 조성물을 제공한다.In another aspect, the present invention provides a coating material for preventing the adhesion of the advertisement using one selected from the group consisting of polyethylene, polymethyl methacrylate or polyvinylcloroid having a particle size in the particle size range of 50 to 300 microns. .
또한, 본 발명은 상기 광촉매 코팅제로 TiO2, ZnO, WO3, SnO2, CaTiO3, Fe2O3, MoO3, Nb2O5, TixZr(1-x)O2, SiC, SrTiO3, CdS, GaP, InP, GaAs, BaTiO3, KNbO3, Ta2O5, Bi2O3, NiO, Cu2O, SiO2, MoS2, InPb, RuO2, CeO2, Ti(OH)4로 이루어진 군에서 선택된 1종 또는 2종 이상의 혼합물을 사용한 광고물 부착 방지 도료 조성물을 제공한다.In addition, the present invention is the photocatalyst coating agent TiO 2 , ZnO, WO 3 , SnO 2 , CaTiO 3 , Fe 2 O 3 , MoO 3 , Nb 2 O 5 , TixZr (1-x) O 2 , SiC, SrTiO 3 , CdS, GaP, InP, GaAs, BaTiO 3 , KNbO 3 , Ta 2 O 5 , Bi 2 O 3 , NiO, Cu 2 O, SiO 2 , MoS 2 , InPb, RuO 2 , CeO 2 , Ti (OH) 4 Provided is an advertisement adhesion preventing paint composition using one or two or more mixtures selected from the group consisting of.
또한, 본 발명은 상기 소포제와 방부제를 1:1 내지 5:1의 비율로 혼합하여 된 혼합물을 사용한 광고물 부착 방지 도료 조성물을 제공한다.In addition, the present invention provides an anti-adhesion coating composition using a mixture obtained by mixing the antifoaming agent and the preservative in a ratio of 1: 1 to 5: 1.
본 발명은 또한 광고물 부착 방지 시트에 있어서, 일면에 구조물이나 시설물에 부착되도록 접착층이 형성된 시트의 반대측 면에 상기에서 제공되는 어느 하나의 광고물 부착 방지 도료 조성물을 도포한 후, 상온에서 건조하여 광고물 부착 방지 도료 조성물층이 형성된 광고물 부착 방지 시트를 제공한다.The present invention also in the anti-adhesive sheet for advertisement, after applying any one of the anti-adhesive coating composition provided above to the opposite side of the sheet formed with an adhesive layer to adhere to the structure or facilities on one side, and then dried at room temperature Provided is an advertisement attachment prevention sheet having an advertisement adhesion prevention coating composition layer formed.
본 발명의 광고물 부착방지 도료 조성물 및 이를 이용한 광고물 부착 방지 시트는 산업 전반의 시설물에 사용할 수 있는 각종 소재에 대해 부착이 우수하며 불법 부착물의 부착을 사전에 차단하고 각종 매연이나 유기 오염 물질을 쉽게 제거하는 기능을 갖는다.The anti-adhesive coating composition of the present invention and the anti-adhesive sheet using the same have excellent adhesion to various materials that can be used in facilities throughout the industry, and prevent the attachment of illegal deposits in advance and prevent various smoke or organic pollutants. Has the function of easy removal.
이하, 본 발명을 보다 상세히 설명하기로 한다.Hereinafter, the present invention will be described in more detail.
본 발명에 따른 광고물 부착방지 도료 조성물은 무독성 수분산 수지, 가교제, 충진재, 변성실리콘, 광촉매제, 첨가제 및 여분의 물을 혼합하여 되는 것으로, 그 조성비는 무독성 수분산 수지 40 내지 70중량%, 가교제 1 내지 10중량%, 충진재 5 내지 20중량%, 변성실리콘 1 내지 5중량%, 광촉매제 1 내지 5중량%, 소포제 0.1 내지 0.5 중량%, 방부제 0.01 내지 0.1 중량%, 및 여분의 물이 혼합하여 된다. Advertisement anti-stick coating composition according to the present invention is a non-toxic water dispersion resin, crosslinking agent, filler, modified silicone, photocatalyst, additives and extra water to be mixed, the composition ratio of the non-toxic water dispersion resin 40 to 70% by weight, 1 to 10% by weight of crosslinking agent, 5 to 20% by weight of filler, 1 to 5% by weight of modified silicone, 1 to 5% by weight of photocatalyst, 0.1 to 0.5% by weight of antifoam, 0.01 to 0.1% by weight of preservative, and excess water You should.
본 발명을 구성하는 상기 무독성 수분산 수지는 규소 변성 아크릴 에멀젼수지, 우레탄 에멀젼수지 또는 아크릴 에멀젼수지로 이루어진 군에서 선택된 1종 또는 2종 이상의 혼합물을 사용한다. The non-toxic water-dispersible resin constituting the present invention uses one or a mixture of two or more selected from the group consisting of silicon-modified acrylic emulsion resin, urethane emulsion resin or acrylic emulsion resin.
상기 무독성 수분산 수지의 사용량이 40 중량% 미만일 경우 그 사용량이 너무 적어 도료 형성에 어려움이 있고, 70 중량%를 초과하여 사용하게 되면 그 사용량이 너무 많아 타 성분을 적게 사용해야 함으로 그에 따른 문제점이 발생한다. 따라서 상기 무독성 수분산 수지의 사용량은 40 내지 70 중량%로 함이 바람직하다.When the amount of the non-toxic water-dispersion resin is less than 40% by weight, the amount is too small, so it is difficult to form a paint. When the amount is used in excess of 70% by weight, the amount of the non-toxic water-based resin is too high, so that other components must be used less. do. Therefore, the amount of the non-toxic water-dispersible resin is preferably 40 to 70% by weight.
본 발명을 구성하는 상기 가교제는 상기 무독성 수분산 수지를 경화하기 위해 사용되는 것으로, 본 발명에서는 아지리딘 화합물을 사용한다. The crosslinking agent constituting the present invention is used to cure the non-toxic water-dispersible resin, and an aziridine compound is used in the present invention.
상기 아지리딘 화합물로는 아지리딘 관능기가 경화반응에 참여하기 때문에 crosslinker로서 적합한 화합물을 사용하는 것이 바람직하며, crosslinker로서 적합한 아지리딘 화합물은 어느 것을 사용하여도 무방하다. As the aziridine compound, it is preferable to use a compound suitable as a crosslinker because the aziridine functional group participates in the curing reaction, and any suitable aziridine compound may be used as the crosslinker.
본 발명에서는 폴리펑셔널 아지리딘 리퀴드 크로스링커(Polyfunctional aziridine liquid crosslinker)로서 NeoResin사의 제품인 CX-100을 사용하였다. In the present invention, CX-100, a product of NeoResin, was used as the polyfunctional aziridine liquid crosslinker.
본 발명에 따르면, 상기 가교제는 1 내지 10 중량% 사용하는데, 그 이유는 1 중량% 미만을 사용하면 경화 밀도가 너무 낮아 도막의 내구성을 향상시킬 수 없으며 10 중량%를 초과하여 사용할 경우에는 경화 반응에 참여하지 않는 가교제가 남을 수 있게 되어 이로 인하여 도막이 끈적일 수 있고 내수성도 약화될 수 있는 문제가 있다.According to the present invention, the crosslinking agent is used in 1 to 10% by weight, because the use of less than 1% by weight of the curing density is too low to improve the durability of the coating film when used in excess of 10% by weight of the curing reaction There is a problem that the crosslinking agent that does not participate in can remain, which may cause the coating to be sticky and weaken the water resistance.
본 발명의 광고물 부착 방지 도료 조성물에는 상기 아지리딘 화합물로 다관능기의 아지리딘 경화제로서 네오레진 사의 CX-100 제품을 사용하여 본 발명을 완성하였다.In the anti-adhesion coating composition of the present invention, the present invention was completed by using CX-100 product of Neoresin as the aziridine curing agent of a polyfunctional group as the aziridine compound.
본 발명을 구성하는 상기 충진재는 폴리에틸렌, 폴리메틸메타아크릴레이트 또는 폴리비닐클로이드로 이루어진 군에서 선택된 1종을 사용하는 바람직하다. The filler constituting the present invention is preferably used one selected from the group consisting of polyethylene, polymethyl methacrylate or polyvinylcloroid.
본 발명에 따르면, 상기 충진재의 사용량은 5 내지 20중량%가 바람직하다. 그 이유는 5 중량% 미만을 사용하게 되면 충진재로의 역할을 발휘하지 못하는 문제점이 있고, 20 중량%를 초과하여 사용하게 되면 충진재의 역할은 충분히 발휘될 수 있으나 도막이 불투명해지는 문제점이 발생되며 또한 상대적으로 타 성분을 적게 사용해야 함으로 그에 따른 문제점이 발생한다. According to the present invention, the amount of the filler used is preferably 5 to 20% by weight. The reason is that if the use of less than 5% by weight, there is a problem that can not play a role as the filler, if the use of more than 20% by weight can play a sufficient role of the filler, but the problem that the coating is opaque occurs and also the relative As other components should be used less, problems arise.
또한, 본 발명에 사용되는 충진재는 입자 크기가 50 내지 300미크론의 입자크기를 가지는 것을 사용하는 것이 바람직하며, 만일 50미크론 미만일 경우는 충진재의 역할을 발휘하지 못하고 300미크론 이상일 경우는 스프레이나 롤러 도장시 문제점이 발생된다. In addition, the filler used in the present invention is preferably to use a particle size having a particle size of 50 to 300 microns, if less than 50 microns does not play the role of the filler and 300 or more micron spray or roller coating Problem occurs.
본 발명에 사용되는 상기 변성실리콘은 소수성과 친유성을 증가시키며 발수성 및 발유성을 향상시키고 오염물질의 부착을 줄여주며 도막 표면의 이지클리닝(easy cleaning)을 향상시킨다. 또한, 소재 습윤성, 레벨링성, 표면 슬립성, 내수성, 내점착성, 내후성을 향상시키고 낙서 방지 및 점착제가 도포된 광고물의 릴리징(releasing)을 향상시킨다.The modified silicone used in the present invention increases hydrophobicity and lipophilic properties, improves water repellency and oil repellency, reduces adhesion of contaminants, and improves easy cleaning of the coating surface. In addition, it improves the material wettability, leveling, surface slip resistance, water resistance, adhesion resistance, weather resistance, and prevents graffiti and releasing the adhesive-adhesive advertising.
본 발명에 따르면, 상기의 변성 실리콘은 1 내지 5 중량%를 사용하는데, 그 이유는 1 중량% 미만을 사용하게 되면 상기에서 설명한 변성실리콘의 역할을 발휘하지 못하는 문제점이 있고, 5 중량%를 초과하여 사용하게 되면 상기에서 설명한 첨가제의 역할은 충분히 발휘될 수 있으나 도막이 불투명해질 수 있고 또한 주 수지와의 상용성 문제가 발생되어 저장 안정성이 취약해질 수 있는 문제점이 있다.According to the present invention, the modified silicone is used in 1 to 5% by weight, the reason is that when using less than 1% by weight does not exhibit the role of the modified silicone described above, more than 5% by weight If used, the role of the additives described above may be sufficiently exhibited, but the coating may become opaque, and there is a problem in that compatibility with the main resin may occur and storage stability may be weak.
본 발명에 사용되는 광촉매제는 도료형과 졸겔형 2종류로 크게 나눌 수 있다. 도료형은 결정성 광촉매 입자(많게는 아나타제형)와 광분해하기 어려운 바인더 성분을 조합한 것으로, 바인더에는 폴리시로키산을 골격으로 하는 실리카계 무기 바인더가 많이 사용되어, 상온 건조에서도 촉매 활성을 얻을 수 있는 이점이 있다. 졸겔형은 티탄 알코키시드 등의 티탄 화합물을 원료로 하고, 산촉매로 가수 분해시켜, 도포 후에 400~600℃로 소성하는 것에 의해 이산화티탄을 결정화 시키는 것으로 바인더 성분을 첨가할 필요가 없는 이점이 있다. 이산화티탄(TiO2) 광촉매의 기본 Mechanism은 식물잎의 표면에서 이루지는「광합성」과 유사한 작용으로, 엽록소를 촉매로서 이산화탄소와 물에서 산소를 생성하는「식물의 광합성」과 같이 광촉매는 TiO2를 촉매로서 공기 중의 물과 산소에서 ２ 종류의 활성 산소를 생성 한다．이 활성 산소는 다양한 효과를 나타내며 빛을 이용한 반응이기 때문에 반영구적이다．TiO2 표면에 빛이 비추어지면 TiO2의 전자가 활성화 되고 정공이 생성된다. 이 정공은 강한 산화력을 가지므로 산화티타늄 표면에 있는 다양한 물질을 산화 시킬 수 있다. 따라서 악취물질, 오염물, 먼지, 기름 등이 표면에 붙으면 TiO2가 광촉매 효과를 발휘하여 이산화탄소와 물로 분해하기 때문에 표면에 흡착된 먼지나 더러운 물질, 잡균 등의 유기화합물이 제거된다Photocatalysts used in the present invention can be broadly divided into two types: paint and sol-gel. The paint type is a combination of crystalline photocatalyst particles (often anatase type) and a binder component that is difficult to photodecompose. As a binder, many silica-based inorganic binders having polyshirokiic acid as a skeleton can be used to obtain catalytic activity even at room temperature drying. There is an advantage. The sol-gel type has the advantage that it is not necessary to add a binder component by crystallizing titanium dioxide by using titanium compounds such as titanium alkoxyside as a raw material, hydrolyzing with an acid catalyst and firing at 400 to 600 ° C after coating. . The basic mechanism of titanium dioxide (TiO 2 ) photocatalysts is similar to the photosynthesis that occurs on the surface of plant leaves.The photocatalyst, like chlorophyll as a catalyst for photosynthesis that produces oxygen from carbon dioxide and water, uses TiO 2 as a catalyst. and generates free radicals in the two types of water and oxygen in the air as a catalyst. this active oxygen is a semi-permanent because the reaction exhibits a variety of effects with light .TiO the light of the light when electrons of TiO 2 is activated on the second surface of the hole Is generated. These holes have a strong oxidizing power and can oxidize various materials on the titanium oxide surface. Therefore, when odorous substances, contaminants, dust, oils, etc. adhere to the surface, TiO 2 exerts photocatalytic effect and decomposes into carbon dioxide and water, so that organic compounds such as dust, dirty substances, and various germs adsorbed on the surface are removed.
광촉매의 핵심 원료로 이산화티탄을 사용하며 1차 입자크기가 중요한데 수나노 내지 수십나노급을 사용할 수 있으나 광촉매 성능을 최대화하기 위해서 수나노급의 초미세분을 사용하여 비표면적(100m²/g이상)을 극대화한다. 이산화티탄의 순도는 99.5%이상이어야 한다. 수나노급의 이산화티탄 안료를 사용함으로서 광촉매 기능인 친수성 도막화와 자정작용이 발현되어 도막 표면에 단지 빗물과 같은 수분이 닿게 되더라도 친유성 오염물질이 간단히 세정된다. 대표적인 제품으로는 Degussa의 P-25를 들 수 있는데 이 제품은 약 75%의 아나타제상과 25%의 루틸상으로 구성되어져 있다.Titanium dioxide is used as the core raw material of the photocatalyst, and the primary particle size is important, but it can be used from several nanoscales to several tens of nanoscale grades. Maximize. The purity of titanium dioxide should be at least 99.5%. By using sun nano-class titanium dioxide pigment, hydrophilic coating and self-cleaning function, which are photocatalytic functions, are expressed, so that lipophilic contaminants are simply washed even if only water such as rain water touches the surface of the coating film. A typical example is Degussa's P-25, which consists of about 75% anatase and 25% rutile.
본 발명에 사용되는 바람직한 광촉매제로는 자체 세정기능을 갖는 TiO2, ZnO, WO3, SnO2, CaTiO3, Fe2O3, MoO3, Nb2O5, TixZr(1-x)O2, SiC, SrTiO3, CdS, GaP, InP, GaAs, BaTiO3, KNbO3, Ta2O5, Bi2O3, NiO, Cu2O, SiO2, MoS2, InPb, RuO2, CeO2, Ti(OH)4로 이루어진 군에서 선택된 1종 또는 2종 이상의 혼합물을 사용하는 것이 좋다.Preferred photocatalysts used in the present invention include TiO 2 , ZnO, WO 3 , SnO 2 , CaTiO 3 , Fe 2 O 3 , MoO 3 , Nb 2 O 5 , TixZr (1-x) O 2 , SiC, SrTiO 3 , CdS, GaP, InP, GaAs, BaTiO 3 , KNbO 3 , Ta 2 O 5 , Bi 2 O 3 , NiO, Cu 2 O, SiO 2 , MoS 2 , InPb, RuO 2 , CeO 2 , Ti It is preferable to use one or a mixture of two or more selected from the group consisting of (OH) 4 .
본 발명에 따르면, 상기 광촉매제는 1 내지 5 중량%를 사용하는 것이 바람직한데, 그 이유는 1 중량% 미만을 사용하게 되면 만족스러운 자기 세정 효과를 얻을 수 없으며, 10 중량%를 초과하여 사용하게 되면 그 효과는 충분히 발휘되나 제품의 제조원가에 크게 영향을 미쳐 제품의 경쟁성이 취약해질 수 있는 문제점이 있다.According to the present invention, it is preferable to use 1 to 5% by weight of the photocatalyst, because if it is used less than 1% by weight, a satisfactory self-cleaning effect cannot be obtained, and more than 10% by weight is used. If the effect is fully exerted, but there is a problem that can greatly affect the manufacturing cost of the product, the competitiveness of the product may be weak.
본 발명에서는 첨가제로서 소포제와 방부제를 사용하는 데, 이들을 단독으로 사용하여도 좋으며, 바람직하게는 상기 소포제와 방부제를 일정비율로 혼합한 혼합물을 사용하는 것이 더 좋다. In this invention, although an antifoamer and an antiseptic | preservative are used as an additive, these may be used independently, It is more preferable to use the mixture which mixed the said antifoamer and the preservative in a fixed ratio.
이때, 상기 소포제와 방부제의 혼합비는 크게 제한을 두는 것은 아니나, 바람직하게는 소포제와 방부제를 1:1 내지 5:1의 비율로 혼합하여 된 혼합물을 사용하는 것이 바람직하다. At this time, the mixing ratio of the antifoaming agent and the preservative is not particularly limited, but it is preferable to use a mixture obtained by mixing the antifoaming agent and the preservative in a ratio of 1: 1 to 5: 1.
본 발명에 따르면, 상기 소포제는 전체 조성물 중 0.1 내지 0.5 중량%가 되도록 사용하는 것이 바람직하며 0.5 중량% 이상 사용할 경우에는 가격적인 상승이 우려되며 또한 핀홀과 같은 외관 불량 현상이 발생할 수 있고 0.1 중량% 이하로 사용할 경우에는 소포 성능이 떨어져 도장 작업 시 기포 발생으로 작업에 어려움이 있을 수 있다.According to the present invention, the antifoaming agent is preferably used to be 0.1 to 0.5% by weight of the total composition, when using more than 0.5% by weight is concerned about the price increase and also appearance defects such as pinhole may occur 0.1% by weight In the case of using less than the defoaming performance may be difficult to work due to bubbles generated during painting work.
또한, 상기 방부제는 전체 조성물 중 0.01 내지 0.1 중량%가 되도록 사용하는 것이 바람직하다. 만일 0.01중량% 미만을 사용할 경우 방부효과를 얻을 수 없고, 0.1중량%를 초과하여 사용할 경우에는 가격상승이 우려되고, 타 성분을 적게 사용하여야 하는 문제가 있다.In addition, the preservative is preferably used to be 0.01 to 0.1% by weight of the total composition. If less than 0.01% by weight can not be used to achieve the preservation effect, when used in excess of 0.1% by weight is concerned about the price rise, there is a problem that you need to use less other components.
본 발명에 사용되는 소포제는 수용성 제품 특징 상 주 용매가 물이기 때문에 작업 중 기포 발생으로 인하여 외관이나 품질적인 면에서 불량을 야기할 수 있기 때문에 소량의 소포제를 사용하며, 또한, 장기 저장 안정성을 위하여 미량의 방부제를 사용하는 것이다.The antifoaming agent used in the present invention is water-soluble because the main solvent is water, which may cause defects in terms of appearance and quality due to air bubbles during operation, and thus a small amount of antifoaming agent is used. Use a small amount of preservatives.
상기 소포제와 방부제의 종류에 있어서는 제한을 둘 필요는 없다.There is no need to limit the type of antifoaming agent and preservative.
이상에서 설명한 본 발명의 광고물 부착 방지 도료조성물은 그 자체로 스프레이 도포하는 방식으로 각종 시설물에 일정하게 도포하여 사용할 수 있으며, 본 발명에 따르면, 상기 도료조성물을 종래의 광고물 부착 방지 시트의 일측면에 일정두께를 가지도록 광고물 부착 방지층을 형성시켜 시트를 제작하고, 이 시트를 각종 시설물에 부착하여 사용하게 된다. Advertisement adhesion preventing paint composition of the present invention described above can be applied to a variety of facilities in a manner that is spray coating itself in accordance with the present invention, according to the present invention, the coating composition of the conventional The sheet is formed by forming an advertisement adhesion prevention layer to have a predetermined thickness on the side, and the sheet is attached to various facilities and used.
상기 시트의 구성을 보다 상세히 설명하면 상기 광고물 부착 방지층이 형성된 이면에는 각종 시설물의 표면에 안착되도록 접착제층이 형성되고 상기 접착제층의 상면에 이면지가 부착되어 구성된다. When explaining the configuration of the sheet in more detail the adhesive layer is formed on the back surface is formed on the surface of the various facilities of the anti-adhesion layer is attached to the back surface is attached to the upper surface of the adhesive layer.
이때, 상기 광고물 부착 방지층에는 도시미관을 높이기 위하여 주변환경과 조화를 이룰 수 있는 다양한 그림 또는 각종 마크 등을 형성하여 제작 할 수 있다.In this case, in order to enhance the aesthetics of the advertisement, the advertisement attachment layer may be formed by forming various pictures or various marks that can be harmonized with the surrounding environment.
이하, 본 발명의 바람직한 실시예를 들어 보다 상세히 설명하면 다음과 같으며, 하기의 실시예로 본 발명이 한정되는 것은 아니다.Hereinafter, a preferred embodiment of the present invention will be described in more detail as follows, but the present invention is not limited to the following examples.
<실시예><Examples>
1. 수분산 우레탄 수지 601. Water Dispersed Urethane Resin 60
2. CX-100 52.CX-100 5
3. 폴리메틸메타아크릴레이트 파우더 103. Polymethylmethacrylate Powder 10
4. 변성 실리콘 첨가제 34. Modified Silicone Additives 3
5. TiO2계 광촉매 25.TiO 2 Photocatalyst 2
6. 소포제(BYK-020) 0.26. Defoamer (BYK-020) 0.2
7. 방부제 0.057. Preservative 0.05
8. 물 잔량8. Water level
* 단위는 중량%이다.* Unit is weight percent.
상기 실시 예의 조성물을 광고 시트에 스프레이 도장한 후 상온에서 7일간 건조시킨 다음 하기와 같은 물성 시험을 진행하였다.After spray-coating the composition of the embodiment on the advertising sheet and dried at room temperature for 7 days, the following physical property test was carried out.
1) 테이프 부착 방지 성능1) Tape adhesion prevention performance
시중에 유통되는 녹색 테이프를 도막 면에 밀착시킨 후 박리하는 시험을 10회 이상 평가하였다. 그 결과, 테이프의 점착제가 전혀 광고시트에 부착이 이루어지지 않았고 외부의 힘을 가하지 않아도 저절로 박리되었다.The test which peeled after sticking the commercially available green tape on the coating film surface was evaluated 10 times or more. As a result, the adhesive of the tape did not adhere to the advertisement sheet at all and peeled by itself without applying external force.
2) 도막의 내자외선성 시험2) UV resistance test of coating film
광고 시트가 외부에 시공되므로 상기의 도료 조성물로 형성된 도막은 내자외선이 우수해야 한다. 따라서 UV 경화기에서 400mJ * 30회 통과한 후 도막의 황변성 및 테이프 부착 방지 성능을 평가하였다. 시험 후의 도막은 황변 현상이 발생되지 않았고 테이프 부착 방지 성능 또한 시험 전과 대등한 결과를 보였다.Since the advertisement sheet is constructed on the outside, the coating film formed of the coating composition should be excellent in ultraviolet light. Therefore, after passing 400mJ * 30 times in the UV curing machine, the yellowing and tape adhesion prevention performance of the coating film was evaluated. After the test, the yellowing did not occur, and the tape adhesion prevention performance was also comparable to that before the test.
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| CN107267013A (en) * | 2017-06-28 | 2017-10-20 | 常州市顺旭商贸有限公司 | A kind of environment-friendly type road gage mark coating |
| CN109777243A (en) * | 2019-03-26 | 2019-05-21 | 马鞍山采石矶涂料有限公司 | A kind of preparation method of zinc oxide composite photocatalyst coating |
| CN111560216A (en) * | 2020-05-28 | 2020-08-21 | 深圳市法纳科技发展有限公司 | Self-cleaning coating applied to doors and windows and preparation method thereof |
| CN113831017B (en) * | 2021-07-28 | 2022-12-30 | 景德镇陶瓷大学 | Application to improving anatase TiO 2 Super-hydrophilic self-cleaning ceramic glaze coating and application method thereof |
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