KR101023437B1 - Advanced Water Treatment System using Biofilm Filtration and Membrane Separation - Google Patents
Advanced Water Treatment System using Biofilm Filtration and Membrane Separation Download PDFInfo
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- KR101023437B1 KR101023437B1 KR1020050005227A KR20050005227A KR101023437B1 KR 101023437 B1 KR101023437 B1 KR 101023437B1 KR 1020050005227 A KR1020050005227 A KR 1020050005227A KR 20050005227 A KR20050005227 A KR 20050005227A KR 101023437 B1 KR101023437 B1 KR 101023437B1
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- C02F3/00—Biological treatment of water, waste water, or sewage
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Abstract
본 발명은 기존 응집-침전-급속모래여과지를 이용한 정수처리시스템이 갖고 있는 약품사용과 침전슬러지의 처리에 따른 비용 문제, 약품주입에 따른 부산물생성 문제, 응집·침전지 사용에 의한 소요부지면적의 문제, 공정의 세균, 바이러스의 유출에 의한 감염 문제, 염소소독에 의한 THMs과 같은 소독부산물의 생성 문제, 소독부산물의 전구물질인 천연유기물질(NOM)의 제거효율 문제점을 개선하기 위하여 생물막 여과 공정과 막분리 공정을 도입한 중대형 규모의 막분리 고도정수처리 장치에 관한 것이다. The present invention is a problem of using the chemical treatment and sediment sludge treatment cost, the production of by-products due to the injection of the drug, the required land area by the use of flocculation and sedimentation And biofilm filtration processes to improve the problem of infection caused by bacterial, virus outflow of the process, generation of disinfection by-products such as THMs by chlorination, and removal efficiency of NOM, a precursor of disinfection by-products. The present invention relates to a medium-to-large scale membrane separation advanced water treatment device using a membrane separation process.
본 발명은 생물막여과 공정과 막여과 공정을 이용하여 미량유해물질제거와 이에 따른 소독부산물의 제거, 병원성 미생물의 제거를 가능하게 한다. 또한, 막여과 공정 단독으로 해결하기 힘든 DOC, 암모니아성 질소, 색도, 맛·냄새물질을 생물막여과 공정으로 제거하여 막의 오염부하량을 감소시켜 막수명 연장을 통한 경제적인 정수시스템의 구성과 염소(Cl2)의 사용으로 인한 소독부산물의 생성 억제 그리고 맛있고 안전한 음용수 생산이라는 환경기술적인 문제 해결을 위한 고도정수처리시스템의 개발을 기대할 수 있게 한 것이다.
The present invention enables the removal of trace harmful substances and consequent disinfection by-products and the removal of pathogenic microorganisms using a biofilm filtration process and a membrane filtration process. In addition, biofilm filtration process removes DOC, ammonia nitrogen, color, taste and odor, which are difficult to solve by membrane filtration process alone, and reduces the pollutant load of the membrane. It is expected to develop advanced water treatment system to solve the environmental and technical problems such as suppression of disinfection byproducts and production of delicious and safe drinking water.
생물막여과(Biofilter), 막여과, 고도정수처리시스템 Biofilter, Membrane Filtration, Advanced Water Treatment System
Description
도 1은 본 발명의 실시예에 따른, 생물막 여과 및 막분리를 이용한 고도정수처리 장치의 시스템 개략도이다.1 is a system schematic diagram of an advanced water treatment apparatus using biofilm filtration and membrane separation according to an embodiment of the present invention.
<도면의 주요부분에 대한 부호의 설명><Description of the symbols for the main parts of the drawings>
1; 원수조 2;혼화조 3;응집조 4;침전조 5;생물막여과조 6;막여과조 7;소독조One; Raw water tank 2; mixing
8;응집약품저장조 9;역세정조 10;송풍기 11,12,13;교반기 14;Bypass관 15;소독약품저장조
8; coagulant storage tank 9;
본 발명은 상수원수 전처리 및 고도정수처리를 위한 생물막 여과와 막분리 여과장치에 관한 것으로 상수원수(표류수 또는 지하수)의 수질을 생물막 여과공정으로 1,2급수로 개선하여 막의 오염부하량을 감소시켜 막수명 연장을 가능하게 하고, 막분리 여과를 통하여 고도의 정수처리를 함으로써 경제적이며 맛있고 안전한 음용수 생산이라는 환경기술적인 문제점을 해결하려는데 있다.The present invention relates to a biofilm filtration and membrane separation filtration device for the pre-treatment and advanced water treatment of purified water to improve the water quality of purified water (drift or groundwater) to 1,2 grade water by the biofilm filtration process to reduce the fouling load of the membrane It is intended to solve the environmental and technical problems of economical, delicious and safe drinking water production by enabling membrane life extension and by performing highly purified water treatment through membrane filtration.
자연유기물질 NOM은 정수처리공정에서 발생하는 소독부산물(DBPS ; THMS, HAAS 등)의 전구물질이며, 고도정수처리공정으로 새로이 부각되고 있는 막여과 공정에 있어서는 막오염(fouling)을 유발시키는 주요오염원이기도 하다. D/DBP Rule (EPA, US)의 Phase Ⅱ (2001년부터 시행)에 따르면 THMS의 경우 현재의 80㎍/L에서 40㎍/L로, HAAS(HAA5)의 경우 60㎍/L에서 30㎍/L로 더욱 강화 될 전망이다. 또한 기존의 응집·침전+급속모래여과지를 이용한 정수처리시스템은 약품사용과 침전슬러지의 처리에 따른 비용 문제, 약품주입에 따른 부산물생성 문제, 응집·침전지 사용에 의한 소요부지면적의 문제, 공정의 세균, 바이러스의 유출에 의한 감염 문제, 염소소독에 의한 THMs과 같은 소독부산물의 생성 문제, 소독부산물의 전구물질인 NOM의 제거효율 문제 등으로 안전하고 경제적인 정수장 운영이 어려운 실정이다.Natural organic substance NOM is a precursor of disinfection by-products (DBP S; THM S , HAA S, etc.) generated in the water treatment process, and causes fouling in the membrane filtration process newly emerging as a high water treatment process. It is also a major source of pollution. According to the Phase II of the D / DBP Rule (EPA, US) (since 2001), THM S is now 40 µg / L at 80 µg / L and 30 µs at 60 µg / L for HAA S (HAA5). It is expected to be further strengthened to μg / L. In addition, the existing water treatment system using the flocculation sedimentation + rapid sand filter has the cost of using the chemicals and the treatment of sediment sludge, the generation of by-products due to the injection of the chemicals, the problem of the required area due to the use of the flocculation and sedimentation, and the process. It is difficult to operate a safe and economical water treatment plant due to the problem of infection by leakage of bacteria and viruses, generation of disinfection by-products such as THMs by chlorine disinfection, and removal efficiency of NOM, a precursor of disinfection by-products.
막여과 공정의 전처리 공정으로 응집, 응집-침전, 모래여과 등 여러 형태로 막여과 공정의 전처리에 대한 연구가 활발히 진행 중에 있지만 외국의 사례와 비교해 볼 때 생물막여과를 이용한 막여과의 전처리 공정에 대한 국내의 연구 사례는 아직까지 발표되고 있지 않은 실정이다.
The pretreatment process of membrane filtration is being actively researched for the pretreatment of membrane filtration in various forms such as coagulation, flocculation-sedimentation and sand filtration.However, compared with foreign cases, the pretreatment of membrane filtration using biofilm filtration Domestic research cases have not been published yet.
본 발명은 상기와 같은 문제점을 해결하기 위해 생물막 여과와 막분리를 이용한 고도정수처리 장치를 발명한 것으로,In order to solve the above problems, the present invention invents an advanced water treatment apparatus using biofilm filtration and membrane separation.
첫째, 생물막 여과를 통해 막여과 단독 공정만으로 제거하기 힘든 암모니아성 질소, 색도, 용존성 유기물, 맛·냄새물질을 제거하여 처리효율을 향상키며, 막의 오염부하량을 줄임으로써 막 fouling 현상을 감소시켜 막의 수명연장을 제공하고자 한다.First, biofilm filtration improves treatment efficiency by removing ammonia nitrogen, color, dissolved organic matter, taste and odor that are difficult to remove by membrane filtration alone process, and reduces membrane fouling by reducing membrane fouling load. We want to provide a life extension.
둘째, 막분리 여과를 통하여 기존의 급속모래여과법에 의한 정수처리에서 얻기 힘들었던 수질인 탁도 0.1NTU이하, 크기 2㎛ 입자수 20개 이하, 맛·냄새 물질(2-MIB, Geosmin)의 원인인 조류의 제거가 가능하여 초고도의 음용수 수질을 제공하고자 한다.Second, through membrane separation filtration, the turbidity of water, which is difficult to obtain by conventional rapid sand filtration, is less than 0.1 NTU, the number of particles having a size of 2㎛ 2㎛ 20 or less, algae that causes taste and smell substances (2-MIB, Geosmin) It can be removed to provide ultra-high drinking water quality.
셋째, 생물막 여과와 막분리 여과를 이용한 고도정수처리 장치를 통하여 기존 급속모래여과법에 의한 정수시스템을 간략화 하고, 설치면적 축소, 슬러지발생량 감소, 동력비 감소를 통하여 경제적인 정수기술을 제공하고자 한다.
Third, through the advanced water treatment system using biofilm filtration and membrane separation filtration, we will simplify the existing water purification system by the rapid sand filtration method, and provide economic water purification technology by reducing the installation area, reducing the sludge generation, and reducing the power cost.
본 발명은 상수원수조(1)에서 유입원수의 탁도 농도에 따라 저탁도(20NTU이하)의 경우 생물막 여과조(5)-막여과조(6)-소독조(7), 중탁도(20-50NTU, 50-100NTU)의 경우 혼화조(2)-생물막 여과조(5)-막여과조(6)-소독조(7), 혼화조(2)-응집조(3)-생물막 여과조(5)-막여과조(6)-소독조(7), 고탁도(100NTU이상)의 경우 혼화조(2)-응집조(3)-침전조(4)-생물막 여과조(5)-막여과조(6)-소독조(7)로 구성되며, 유입 탁도 변화에 따른 각 공정의 운전 흐름은 bypass관(14)를 통하여 제어된다.In the present invention, in the case of low turbidity (less than 20 NTU) according to the turbidity concentration of influent water in the water supply tank (1), biofilm filtration tank (5)-membrane filtration tank (6)-sterilization tank (7), medium turbidity (20-50 NTU, 50- 100 NTU): mixing tank (2)-biofilm filtration tank (5)-membrane filtration tank (6)-disinfection tank (7), mixing tank (2)-flocculation tank (3)-biofilm filtration tank (5)-membrane filtration tank (6) -Sterilization tank (7), high turbidity (100NTU or more), mixing tank (2)-flocculation tank (3)-sedimentation tank (4)-biofilm filtration tank (5)-membrane filtration tank (6)-sterilization tank (7) , The operation flow of each process according to the change in inlet turbidity is controlled through the bypass pipe (14).
하기 표"1"은 생물막 여과와 막여과의 운전조건 표이다.
Table "1" below is a table of operating conditions of biofilm filtration and membrane filtration.
·생물활성탄 공정의 파과된 입상활성탄
·섬유 BallZeocarbon
Breakthrough granular activated carbon of bioactive carbon process
Fiber Ball
UFMF or
UF
삭제delete
상수원수 전처리 공정인 생물막 여과조(5)에 유입하는 원수는 생물막 여과재료(제오카본, 생물활성탄공정의 파과된 입상활성탄, 섬유 Ball) 표면에 부착된 미생물의 산화, 분해, 억류의 작용으로 오염물질이 제거되고, 탁도 95%이상, 색도 80%이상, 암모니아성 질소 90%이상, DOC 50%이상, 이·취미(異·臭味) 85% 이상, 조류 90%이상, KMnO4 소비량 50%이상의 제거효율을 나타낸다.Raw water flowing into the biofilm filtration tank (5), which is a pre-treatment of purified water, is contaminated by the action of oxidation, decomposition and detention of microorganisms attached to the surface of the biofilm filtration material (zeocarbon, broken granular activated carbon of the bioactive carbon process, and fiber ball). 95% or more of turbidity, 80% or more of color, 90% or more of ammonia nitrogen, 50% or more of DOC, 85% or more of odor or taste, 90% or more of algae, 50% or more of KMnO 4 consumption It shows the removal efficiency.
원수의 탁도가 20-50NTU로 생물막 여과조(5)에 유입되면 약품저장조(8)를 통하여 혼화조(2)에 응집약품이 공급되고 교반기(11)를 이용하여 형성된 응집 플록은 bypass관(14)을 통하여 생물막 여과조(5)로 유입되어 막여과조(6)와 소독조(7)를 거쳐 최종 처리된다.When turbidity of raw water flows into the biofilm filtration tank 5 at 20-50 NTU, the flocculation chemical is supplied to the mixing tank 2 through the
원수의 탁도가 50-100NTU로 생물막 여과조(5)에 유입되면 약품저장조(8)를 통하여 응집약품이 혼화조(2)에 유입되고, 유입수는 교반기(11)를 이용하여 미세플록이 형성되어, 측변의 교반기(12)를 이용하여 조대 플록을 형성시키는 응집조(3)를 거쳐 bypass관(14)을 통하여 생물막 여과조(5)로 유입되고 막여과조(6)와 소독조(7)를 거쳐 최종 처리된다.When turbidity of the raw water is introduced into the biofilm filtration tank 5 at 50-100 NTU, the flocculating chemical is introduced into the mixing tank 2 through the
원수의 탁도가 100NTU 이상으로 유입되면 약품저장조(8)를 통하여 응집약품이 혼화조(2)에 유입되고, 유입수는 교반기(11)를 이용하여 미세플록이 형성되어 측변의 교반기(12)를 이용하여 조대 플록을 형성시키는 응집조(3)로 유입되고 형성된 조대플록은 측변의 침전조(4)로 유입되어 침강한 후 침전 상등액이 생물막 여과조(5)로 유입되고 막여과조(6)와 소독조(7)를 거쳐 최종 처리된다.When turbidity of raw water flows into 100NTU or more, coagulant drug flows into the mixing tank 2 through the
하기 표 "2"는 본 발명의 생물막 여과와 막분리를 이용한 고도정수처리 장치의 처리 특성표이다.
Table "2" is a treatment characteristic table of the advanced water treatment apparatus using the biofilm filtration and membrane separation of the present invention.
위와 같이 생물막 여과와 막분리를 이용한 고도정수처리 장치는 탁도 0.03-0.05NTU, 색도 1도 이하, 암모니아성 질소 0.02-0.05, DOC 0.2-0.5mg/L, Chl-a 불검출, KMnO4 소비량 0.5-1.3mg/L, THMFP 0.5-1㎍/L, Mn 0.01-0.03mg/L, 대장균 불검출로써 초고도의 음용수 수질을 확보할 수 있었다.
As above, the high-purity water treatment device using biofilm filtration and membrane separation has turbidity 0.03-0.05 NTU, chromaticity less than 1 degree, ammonia nitrogen 0.02-0.05, DOC 0.2-0.5mg / L, Chl-a not detected, KMnO 4 consumption 0.5- Ultra high drinking water quality was obtained by 1.3mg / L, THMFP 0.5-1µg / L, Mn 0.01-0.03mg / L, and E. coli detection.
이와같이 된 본 발명은 기존의 급속모래여과법에 의한 정수처리시스템을 생물막 여과와 막여과 공정으로 간략화시켜 정수장 설치 부지 면적이 최소화 될 수 있고, 생물막 여과를 통해 원수수질을 1,2급수 수준으로 개선시킴으로써 기존 정수처리시스템에서 제거가 어려웠던 암모니아성 질소, DOC와 같은 미량 용존물질, 맛·냄새 물질, 중금속의 오염물질이 제거되어 후속되는 막여과 공정의 fouling 원인물질이 저감되므로 막여과로 인한 초고도의 음용수 수질 확보뿐만 아니라 막 사용수명을 연장시키는 경제적인 장점이 있어 물환경개선에 크게 기여할 수 있다.
The present invention as described above can simplify the existing water treatment system by rapid sand filtration into biofilm filtration and membrane filtration process, thereby minimizing the site area of water purification plant installation, and improving the raw water quality to the first and second water level through biofilm filtration. Ultra-high drinking water due to membrane filtration is reduced because trace impurities such as ammonia nitrogen and DOC, trace dissolved substances such as DOC, taste and smell substances, and heavy metals, which were difficult to remove in existing water treatment systems, are removed. In addition to securing water quality, there is an economic advantage of extending the service life of the membrane, which can greatly contribute to improving the water environment.
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