KR100996261B1 - 석유 제품용 크리스탈 바이올렛 락톤 식별제 조성물 및이를 이용한 석유 제품의 식별방법 - Google Patents
석유 제품용 크리스탈 바이올렛 락톤 식별제 조성물 및이를 이용한 석유 제품의 식별방법 Download PDFInfo
- Publication number
- KR100996261B1 KR100996261B1 KR1020080052680A KR20080052680A KR100996261B1 KR 100996261 B1 KR100996261 B1 KR 100996261B1 KR 1020080052680 A KR1020080052680 A KR 1020080052680A KR 20080052680 A KR20080052680 A KR 20080052680A KR 100996261 B1 KR100996261 B1 KR 100996261B1
- Authority
- KR
- South Korea
- Prior art keywords
- crystal violet
- violet lactone
- identification
- benzofuran
- bis
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims abstract description 18
- LIZLYZVAYZQVPG-UHFFFAOYSA-N (3-bromo-2-fluorophenyl)methanol Chemical compound OCC1=CC=CC(Br)=C1F LIZLYZVAYZQVPG-UHFFFAOYSA-N 0.000 title claims abstract description 10
- 239000003550 marker Substances 0.000 title 1
- 239000003209 petroleum derivative Substances 0.000 claims abstract description 58
- -1 crystal violet lactone compound Chemical class 0.000 claims abstract description 25
- 239000003086 colorant Substances 0.000 claims abstract description 22
- 239000003960 organic solvent Substances 0.000 claims abstract description 13
- 239000003502 gasoline Substances 0.000 claims abstract description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 18
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 18
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 18
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 7
- 239000008096 xylene Substances 0.000 claims description 7
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- IPAJDLMMTVZVPP-UHFFFAOYSA-N Crystal violet lactone Chemical compound C1=CC(N(C)C)=CC=C1C1(C=2C=CC(=CC=2)N(C)C)C2=CC=C(N(C)C)C=C2C(=O)O1 IPAJDLMMTVZVPP-UHFFFAOYSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 239000000295 fuel oil Substances 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000003225 biodiesel Substances 0.000 claims description 3
- 239000003350 kerosene Substances 0.000 claims description 3
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 2
- KFVUXNKQQOUCAH-UHFFFAOYSA-N butan-1-ol;propan-2-ol Chemical compound CC(C)O.CCCCO KFVUXNKQQOUCAH-UHFFFAOYSA-N 0.000 claims description 2
- 230000031700 light absorption Effects 0.000 claims description 2
- 238000004811 liquid chromatography Methods 0.000 claims description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims 3
- KORQRBRMMOJMKD-UHFFFAOYSA-N 6-(diethylamino)-3,3-bis[4-(diethylamino)phenyl]-2-benzofuran-1-one Chemical compound C1=CC(N(CC)CC)=CC=C1C1(C=2C=CC(=CC=2)N(CC)CC)C2=CC=C(N(CC)CC)C=C2C(=O)O1 KORQRBRMMOJMKD-UHFFFAOYSA-N 0.000 claims 1
- POJLEMHHUAKOAS-UHFFFAOYSA-N C(C)C1=CC(=C(C=C1)C1(OC(C2=C1C=CC=C2)=O)C2=C(C=C(C=C2)CC)NCCC)NCCC Chemical compound C(C)C1=CC(=C(C=C1)C1(OC(C2=C1C=CC=C2)=O)C2=C(C=C(C=C2)CC)NCCC)NCCC POJLEMHHUAKOAS-UHFFFAOYSA-N 0.000 claims 1
- WKJMJTARAYRIFM-UHFFFAOYSA-N CC=1C=C(C2=C(C(OC2(C2=C(C=C(C=C2)C)NCC)C2=C(C=C(C=C2)C)NCC)=O)C1)NCC Chemical compound CC=1C=C(C2=C(C(OC2(C2=C(C=C(C=C2)C)NCC)C2=C(C=C(C=C2)C)NCC)=O)C1)NCC WKJMJTARAYRIFM-UHFFFAOYSA-N 0.000 claims 1
- OIBDCUPWXLFZPQ-UHFFFAOYSA-N CC=1C=C(C2=C(C(OC2(C2=C(C=C(C=C2)C)NCCC)C2=C(C=C(C=C2)C)NCCC)=O)C1)NCCC Chemical compound CC=1C=C(C2=C(C(OC2(C2=C(C=C(C=C2)C)NCCC)C2=C(C=C(C=C2)C)NCCC)=O)C1)NCCC OIBDCUPWXLFZPQ-UHFFFAOYSA-N 0.000 claims 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims 1
- 239000002270 dispersing agent Substances 0.000 claims 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 12
- 238000005259 measurement Methods 0.000 abstract description 6
- 238000009826 distribution Methods 0.000 abstract description 4
- 230000003313 weakening effect Effects 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 9
- 239000002283 diesel fuel Substances 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 5
- 101100172879 Caenorhabditis elegans sec-5 gene Proteins 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- ZHNUHDYFZUAESO-UHFFFAOYSA-N formamide Substances NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- VUFCFFITGVMSNB-UHFFFAOYSA-N 3,3-bis[4-(dimethylamino)phenyl]-6,6-bis(methylamino)-5H-2-benzofuran-1-one Chemical compound CN(C1=CC=C(C=C1)C1(OC(=O)C2=CC(CC=C12)(NC)NC)C1=CC=C(C=C1)N(C)C)C VUFCFFITGVMSNB-UHFFFAOYSA-N 0.000 description 1
- XBGHDTRESKVJLM-UHFFFAOYSA-N 3-[4-(dimethylamino)phenyl]-3h-2-benzofuran-1-one Chemical compound C1=CC(N(C)C)=CC=C1C1C2=CC=CC=C2C(=O)O1 XBGHDTRESKVJLM-UHFFFAOYSA-N 0.000 description 1
- XAGJPPDPZQWXNP-UHFFFAOYSA-N 6-(dimethylamino)-3,3-bis[4-(dimethylamino)phenyl]-2-benzofuran-1-one Chemical compound CN(C)c1ccc(cc1)C1(OC(=O)c2cc(ccc12)N(C)C)c1ccc(cc1)N(C)C.CN(C)c1ccc(cc1)C1(OC(=O)c2cc(ccc12)N(C)C)c1ccc(cc1)N(C)C XAGJPPDPZQWXNP-UHFFFAOYSA-N 0.000 description 1
- PWSATEWHTFIUBM-UHFFFAOYSA-N C(C)C=1C=C(C2=C(C(OC2(C2=C(C=C(C=C2)CC)NCCC)C2=C(C=C(C=C2)CC)NCCC)=O)C1)NCCC.C(C)C=1C=C(C2=C(C(OC2(C2=C(C=C(C=C2)CC)NCCC)C2=C(C=C(C=C2)CC)NCCC)=O)C1)NCCC Chemical compound C(C)C=1C=C(C2=C(C(OC2(C2=C(C=C(C=C2)CC)NCCC)C2=C(C=C(C=C2)CC)NCCC)=O)C1)NCCC.C(C)C=1C=C(C2=C(C(OC2(C2=C(C=C(C=C2)CC)NCCC)C2=C(C=C(C=C2)CC)NCCC)=O)C1)NCCC PWSATEWHTFIUBM-UHFFFAOYSA-N 0.000 description 1
- SFPCPCBEZFQBAS-UHFFFAOYSA-N C(C)N(C=1C=CC2=C(C(OC2(C2=CC=C(C=C2)N(CC)CC)C2=CC=C(C=C2)N(CC)CC)=O)C1)CC.C(C)N(C=1C=CC2=C(C(OC2(C2=CC=C(C=C2)N(CC)CC)C2=CC=C(C=C2)N(CC)CC)=O)C1)CC Chemical compound C(C)N(C=1C=CC2=C(C(OC2(C2=CC=C(C=C2)N(CC)CC)C2=CC=C(C=C2)N(CC)CC)=O)C1)CC.C(C)N(C=1C=CC2=C(C(OC2(C2=CC=C(C=C2)N(CC)CC)C2=CC=C(C=C2)N(CC)CC)=O)C1)CC SFPCPCBEZFQBAS-UHFFFAOYSA-N 0.000 description 1
- XSDTXNJAAOZTMH-UHFFFAOYSA-N CC=1C=C(C2=C(C(OC2(C2=C(C=C(C=C2)C)NCC)C2=C(C=C(C=C2)C)NCC)=O)C1)NCC.CC=1C=C(C2=C(C(OC2(C2=C(C=C(C=C2)C)NCC)C2=C(C=C(C=C2)C)NCC)=O)C1)NCC Chemical compound CC=1C=C(C2=C(C(OC2(C2=C(C=C(C=C2)C)NCC)C2=C(C=C(C=C2)C)NCC)=O)C1)NCC.CC=1C=C(C2=C(C(OC2(C2=C(C=C(C=C2)C)NCC)C2=C(C=C(C=C2)C)NCC)=O)C1)NCC XSDTXNJAAOZTMH-UHFFFAOYSA-N 0.000 description 1
- GJNFPDXRFFQUGL-UHFFFAOYSA-N CC=1C=C(C2=C(C(OC2(C2=C(C=C(C=C2)C)NCCC)C2=C(C=C(C=C2)C)NCCC)=O)C1)NCCC.CC=1C=C(C2=C(C(OC2(C2=C(C=C(C=C2)C)NCCC)C2=C(C=C(C=C2)C)NCCC)=O)C1)NCCC Chemical compound CC=1C=C(C2=C(C(OC2(C2=C(C=C(C=C2)C)NCCC)C2=C(C=C(C=C2)C)NCCC)=O)C1)NCCC.CC=1C=C(C2=C(C(OC2(C2=C(C=C(C=C2)C)NCCC)C2=C(C=C(C=C2)C)NCCC)=O)C1)NCCC GJNFPDXRFFQUGL-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 229940098779 methanesulfonic acid Drugs 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229940080818 propionamide Drugs 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/26—Oils; Viscous liquids; Paints; Inks
- G01N33/28—Oils, i.e. hydrocarbon liquids
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/29—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands using visual detection
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pathology (AREA)
- Immunology (AREA)
- General Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Medicinal Chemistry (AREA)
- Food Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
Description
구 분 | 크리스탈 바이올렛 락톤 화합물 20ppm 함유된 경유 (중량%) |
순수 경유 (중량%) |
합 계 | 최종 크리스탈 바이올렛 락톤 화합물 농도 (ppm) |
적용예 1 | 12.5 | 87.5 | 100 중량% |
2.5 |
적용예 2 | 25 | 75 | 5.0 | |
적용예 3 | 37.5 | 62.5 | 7.5 | |
적용예 4 | 50 | 50 | 10.0 | |
적용예 5 | 62.5 | 37.5 | 12.5 | |
적용예 6 | 75 | 25 | 15.0 | |
적용예 7 | 87.5 | 12.5 | 17.5 | |
적용예 8 | 100 | 0 | 20.0 |
구 분 | 30 초 | 1 분 |
1 분
30 초 |
2 분 |
2 분
30 초 |
3 분 |
3 분
30 초 |
4 분 |
4 분
30 초 |
5 분 |
적용예1 (2.5 ppm) | 0.116 | 0.123 | 0.120 | 0.116 | 0.114 | 0.114 | 0.114 | 0.116 | 0.116 | 0.116 |
적용예2 (5.0 ppm) | 0.182 | 0.184 | 0.186 | 0.184 | 0.183 | 0.183 | 0.184 | 0.183 | 0.184 | 0.183 |
적용예3 (7.5 ppm) | 0.280 | 0.268 | 0.265 | 0.275 | 0.274 | 0.271 | 0.270 | 0.274 | 0.270 | 0.270 |
적용예4 (10.0 ppm) | 0.297 | 0.297 | 0.296 | 0.296 | 0.296 | 0.296 | 0.296 | 0.296 | 0.296 | 0.296 |
적용예5 (12.5 ppm) | 0.381 | 0.381 | 0.381 | 0.381 | 0.380 | 0.380 | 0.380 | 0.380 | 0.380 | 0.379 |
적용예6 (15.0 ppm) | 0.457 | 0.456 | 0.456 | 0.456 | 0.456 | 0.456 | 0.456 | 0.456 | 0.457 | 0.457 |
적용예7 (17.5 ppm) | 0.518 | 0.518 | 0.518 | 0.518 | 0.517 | 0.517 | 0.517 | 0.517 | 0.516 | 0.516 |
적용예8 (20.0 ppm) | 0.577 | 0.576 | 0.576 | 0.576 | 0.575 | 0.575 | 0.575 | 0.574 | 0.574 | 0.574 |
구 분 | 30 초 | 1 분 |
1 분
30 초 |
2 분 |
2 분
30 초 |
3 분 |
3 분
30 초 |
4 분 |
4 분
30 초 |
5 분 |
적용예1 (2.5 ppm) | 0.140 | 0.140 | 0.138 | 0.138 | 0.139 | 0.139 | 0.139 | 0.139 | 0.138 | 0.139 |
적용예2 (5.0 ppm) | 0.186 | 0.186 | 0.186 | 0.186 | 0.186 | 0.186 | 0.186 | 0.186 | 0.186 | 0.186 |
적용예3 (7.5 ppm) | 0.253 | 0.253 | 0.253 | 0.253 | 0.252 | 0.253 | 0.253 | 0.253 | 0.253 | 0.253 |
적용예4 (10.0 ppm) | 0.280 | 0.280 | 0.280 | 0.280 | 0.280 | 0.280 | 0.280 | 0.280 | 0.280 | 0.280 |
적용예5 (12.5 ppm) | 0.395 | 0.395 | 0.396 | 0.395 | 0.394 | 0.394 | 0.394 | 0.394 | 0.393 | 0.393 |
적용예6 (15.0 ppm) | 0.466 | 0.465 | 0.465 | 0.465 | 0.464 | 0.464 | 0.464 | 0.464 | 0.464 | 0.464 |
적용예7 (17.5 ppm) | 0.531 | 0.529 | 0.529 | 0.529 | 0.529 | 0.528 | 0.528 | 0.528 | 0.527 | 0.528 |
적용예8 (20.0 ppm) | 0.604 | 0.604 | 0.604 | 0.603 | 0.603 | 0.603 | 0.603 | 0.602 | 0.602 | 0.602 |
구 분 | 30 초 | 1 분 |
1 분
30 초 |
2 분 |
2 분
30 초 |
3 분 |
3 분
30 초 |
4 분 |
4 분
30 초 |
5 분 |
적용예1 (2.5 ppm) | 0.143 | 0.143 | 0.143 | 0.143 | 0.142 | 0.142 | 0.142 | 0.142 | 0.142 | 0.142 |
적용예2 (5.0 ppm) | 0.198 | 0.197 | 0.197 | 0.197 | 0.197 | 0.197 | 0.197 | 0.197 | 0.197 | 0.197 |
적용예3 (7.5 ppm) | 0.283 | 0.283 | 0.283 | 0.283 | 0.282 | 0.282 | 0.282 | 0.282 | 0.281 | 0.282 |
적용예4 (10.0 ppm) | 0.310 | 0.310 | 0.309 | 0.309 | 0.309 | 0.309 | 0.309 | 0.309 | 0.309 | 0.309 |
적용예5 (12.5 ppm) | 0.414 | 0.415 | 0.414 | 0.415 | 0.414 | 0.414 | 0.414 | 0.414 | 0.414 | 0.413 |
적용예6 (15.0 ppm) | 0.492 | 0.491 | 0.491 | 0.491 | 0.491 | 0.490 | 0.490 | 0.490 | 0.489 | 0.489 |
적용예7 (17.5 ppm) | 0.546 | 0.546 | 0.546 | 0.546 | 0.545 | 0.545 | 0.545 | 0.545 | 0.545 | 0.545 |
적용예8 (20.0 ppm) | 0.613 | 0.612 | 0.613 | 0.613 | 0.612 | 0.612 | 0.612 | 0.612 | 0.612 | 0.612 |
평균값 | 30 초 | 1 분 |
1 분
30 초 |
2 분 |
2 분
30 초 |
3 분 |
3 분
30 초 |
4 분 |
4 분
30 초 |
5 분 |
적용예1 (2.5 ppm) | 0.133 | 0.135 | 0.134 | 0.132 | 0.132 | 0.132 | 0.132 | 0.132 | 0.132 | 0.132 |
적용예2 (5.0 ppm) | 0.189 | 0.189 | 0.190 | 0.189 | 0.189 | 0.189 | 0.189 | 0.189 | 0.189 | 0.189 |
적용예3 (7.5 ppm) | 0.272 | 0.268 | 0.267 | 0.270 | 0.269 | 0.269 | 0.268 | 0.270 | 0.268 | 0.268 |
적용예4 (10.0 ppm) | 0.296 | 0.296 | 0.295 | 0.295 | 0.295 | 0.295 | 0.295 | 0.295 | 0.295 | 0.295 |
적용예5 (12.5 ppm) | 0.397 | 0.397 | 0.397 | 0.397 | 0.396 | 0.396 | 0.396 | 0.396 | 0.396 | 0.395 |
적용예6 (15.0 ppm) | 0.472 | 0.471 | 0.471 | 0.471 | 0.470 | 0.470 | 0.470 | 0.470 | 0.470 | 0.470 |
적용예7 (17.5 ppm) | 0.532 | 0.531 | 0.531 | 0.531 | 0.530 | 0.530 | 0.530 | 0.530 | 0.529 | 0.530 |
적용예8 (20.0 ppm) | 0.598 | 0.597 | 0.598 | 0.597 | 0.597 | 0.597 | 0.597 | 0.596 | 0.596 | 0.596 |
구 분 | 분광학적 특성 | 초기열분해 온도 (℃) |
|
최대흡수파장(nm) 용매 메탄올 |
몰흡광계수 (Lmol-1cm-1) |
||
6-다이메틸아미노-3,3-비스(4-다이메틸아미노페닐)-2-벤조퓨란-1(3H)-온 | 600 | 18,000 | 181-182 |
대조군 | 600 | 19,000 | 180-181 |
Claims (7)
- 제 1 항에 있어서, 상기 크리스탈 바이올렛 락톤 화합물은 6-다이메틸아미노-3,3-비스(4-다이메틸아미노페닐)-2-벤조퓨란-1(3H)-온, 6-다이에틸아미노-3,3-비스(4-다이에틸아미노페닐)-2-벤조퓨란-1(3H)-온, 6-메틸에틸아미노-3,3-비스(4-메틸에틸아미노페닐)-2-벤조퓨란-1(3H)-온, 6-메틸프로필아미노-3,3-비스(4-메틸프로필아미노페닐)-2-벤조퓨란-1(3H)-온, 및 6-에틸프로필아미노-3,3-비스(4-에틸프로필아미노페닐)-2-벤조퓨란-1(3H)-온 중에서 선택된 단종 또는 2 종 이상 인 것을 특징으로 하는 석유제품용 식별제 조성물.
- 제 1 항에 있어서, 상기 비반응성 용매는 메탄올, 에탄올, 프로판올, 부탄올 아이소프로판올(isopropanol), t-부틸 알콜(tertbutyl alcohol), 헥산, 벤젠, 톨루엔, 자일렌, 1- 메틸 피롤리디논, N,N-디메틸포름아마이드 및 N,N-디메틸아세트아마이드 중에서 선택된 단종 또는 2 종 이상인 것을 특징으로 하는 석유제품용 식별제 조성물.
- 제 1 항 내지 제 3 항 중에서 선택된 어느 한 항의 상기 식별제 조성물을 이용하여 석유제품을 식별하는 방법.
- 제 4 항에 있어서,하기 화학식 1로 표시되는 크리스탈 바이올렛 락톤 화합물이 1 ~ 150 ppm 되도록 상기 식별제 조성물과 피식별체를 혼합하여 혼합물을 제조하는 단계;상기 혼합물 100 중량부에 대하여 발색제로서 산(acid)을 0.1 ~ 3 중량부 혼합 및 교반시키는 단계; 및상기 크리스탈 바이올렛 락톤 화합물을 발색시켜서 식별하는 단계;를포함하는 것에 그 특징으로 하는 석유제품을 식별하는 방법 :[화학식 1]상기 화학식 1에 있어서, R1 및 R2는 서로 다르거나 같은 것으로서, 수소원자 또는 탄소수 1 ~ 6의 직쇄형 또는 분쇄형 알킬기이다.
- 제 5 항에 있어서, 상기 피식별체는 가솔린, 경유, 중유, 등유, 바이오디젤, 바이오에탄올 및 유기용매인 자일렌, 톨루엔 및 벤젠 중에서 선택된 단종 또는 2 종 이상인 것을 특징으로 석유제품을 식별하는 방법.
- 제 6 항에 있어서, 육안, 색측정기기(colorimeter), 가시광선 흡수 분광 광도계 및 액체 크로마토그래피 중에서 선택된 어느 1 종을 이용하여 석유제품을 식별하는 방법.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020080052680A KR100996261B1 (ko) | 2008-06-04 | 2008-06-04 | 석유 제품용 크리스탈 바이올렛 락톤 식별제 조성물 및이를 이용한 석유 제품의 식별방법 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020080052680A KR100996261B1 (ko) | 2008-06-04 | 2008-06-04 | 석유 제품용 크리스탈 바이올렛 락톤 식별제 조성물 및이를 이용한 석유 제품의 식별방법 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20090126541A KR20090126541A (ko) | 2009-12-09 |
KR100996261B1 true KR100996261B1 (ko) | 2010-11-24 |
Family
ID=41687647
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020080052680A KR100996261B1 (ko) | 2008-06-04 | 2008-06-04 | 석유 제품용 크리스탈 바이올렛 락톤 식별제 조성물 및이를 이용한 석유 제품의 식별방법 |
Country Status (1)
Country | Link |
---|---|
KR (1) | KR100996261B1 (ko) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100953358B1 (ko) * | 2008-10-14 | 2010-04-20 | 오리엔트화학 (주) | 금속 착염 발색제를 이용하여 발색되는 유류 식별용 마커, 상기 마커를 이용하는 유류 식별 방법 |
PL3504546T3 (pl) * | 2016-08-24 | 2022-05-09 | United Color Manufacturing Inc. | Sposób identyfikacji płynu węglowodorowego |
CN108020381A (zh) * | 2016-10-31 | 2018-05-11 | 中国石油化工股份有限公司 | 一种快速检测水冷器泄漏的装置及检测方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3981735A (en) | 1973-04-16 | 1976-09-21 | Ncr Corporation | Process for making a stable, relatively high concentration, solution of an organic color-reactive colorless dye in oil |
US5145573A (en) | 1990-01-22 | 1992-09-08 | Basf Aktiengesellschaft | Marked mineral oils and method of marking mineral oils with basic dyes |
-
2008
- 2008-06-04 KR KR1020080052680A patent/KR100996261B1/ko active IP Right Grant
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3981735A (en) | 1973-04-16 | 1976-09-21 | Ncr Corporation | Process for making a stable, relatively high concentration, solution of an organic color-reactive colorless dye in oil |
US5145573A (en) | 1990-01-22 | 1992-09-08 | Basf Aktiengesellschaft | Marked mineral oils and method of marking mineral oils with basic dyes |
Also Published As
Publication number | Publication date |
---|---|
KR20090126541A (ko) | 2009-12-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Suwanprasop et al. | Petroleum marker dyes synthesized from cardanol and aniline derivatives | |
EP0509818B1 (en) | Silent markers for petroleum, method of tagging, and method of detection | |
JP2003213278A (ja) | アントラキノンを用いた炭化水素のマーキング方法 | |
KR100996261B1 (ko) | 석유 제품용 크리스탈 바이올렛 락톤 식별제 조성물 및이를 이용한 석유 제품의 식별방법 | |
Liu et al. | Far‐Red‐Emitting TEG‐Substituted Squaraine Dye: Synthesis, Optical Properties, and Selective Detection of Cyanide in Aqueous Solution | |
Sutter et al. | Fluorescent pH‐Responsive Probes Based on Water‐Soluble Boron‐Dipyrromethene (BODIPY) Derivatives, Featuring Long‐Wavelength Emission | |
JP3854227B2 (ja) | 鉱油をマーキングする方法 | |
Liu et al. | A Highly Selective, Colorimetric, and Fluorometric Multisignaling Chemosensor for Hg2+ Based on Poly (p‐phenyleneethynylene) Containing Benzo [2, 1, 3] thiadiazole | |
Patil et al. | Substituent‐controlled selective and sensitive potential optical fluoride sensors based on salicylidene schiff base derivatives | |
Ros‐Lis et al. | Signalling Mechanisms in Anion‐Responsive Push‐Pull Chromophores: The Hydrogen‐Bonding, Deprotonation and Anion‐Exchange Chemistry of Functionalized Azo Dyes | |
CA2097792A1 (en) | Base extractable petroleum markers | |
Sultana et al. | Phthalimide‐Based Off‐On‐Off Fluorosensor for Cascade Detection of Cyanide Ions and Picric Acid | |
KR101029377B1 (ko) | 석유 제품용 플루오란 식별제 조성물 및 이를 이용한 석유제품의 식별방법 | |
KR100953358B1 (ko) | 금속 착염 발색제를 이용하여 발색되는 유류 식별용 마커, 상기 마커를 이용하는 유류 식별 방법 | |
US7956170B2 (en) | Aromatic-aliphatic azo derivatives particularly as markers for petroleum products, method for synthesizing them, use thereof and derived compositions | |
Rietsch et al. | Identification of the irreversible redox behavior of highly fluorescent benzothiadiazoles | |
Chairat et al. | An absorption spectroscopic investigation of the interaction of lac dyes with metal ions | |
US9090841B2 (en) | Tracers and method of marking hydrocarbon liquids | |
Hemdan et al. | Behavior of the electronic absorption spectrum of bromocresol purple toward neat solvents and binary aqueous solvents: revers solvatochromism, preferential solvation and multiparametric analysis | |
Patil et al. | Amide functionalized ionic liquid as facile fluorescent probe for detection of nitrophenolic compounds | |
Satpati et al. | Influence of confined water on the photophysics of dissolved solutes in reverse micelles | |
Balagurusamy et al. | Photometric and Colorimetric Cyanide Detection Sensor Using Amine Based Nitrobenzoxadiazole Derivatives | |
KR101224587B1 (ko) | 벤족사졸계 유류 식별제와 이를 포함하는 유류 식별용 조성물 | |
De Maria et al. | Kinetics of the ZE isomerization of monosubstituted azobenzenes in polar organic and aqueous micellar solvents | |
Anandhan et al. | 1H‐NMR, Photophysical, and pH Studies of 4‐(4, 5‐Diphenyl‐1H‐imidazol‐2‐yl) benzaldehyde through Experimental and DFT Theoretical Analysis |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
E902 | Notification of reason for refusal | ||
N231 | Notification of change of applicant | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
FPAY | Annual fee payment |
Payment date: 20131021 Year of fee payment: 4 |
|
FPAY | Annual fee payment |
Payment date: 20141110 Year of fee payment: 5 |
|
FPAY | Annual fee payment |
Payment date: 20151020 Year of fee payment: 6 |
|
FPAY | Annual fee payment |
Payment date: 20161111 Year of fee payment: 7 |
|
FPAY | Annual fee payment |
Payment date: 20171106 Year of fee payment: 8 |
|
FPAY | Annual fee payment |
Payment date: 20181030 Year of fee payment: 9 |
|
FPAY | Annual fee payment |
Payment date: 20191002 Year of fee payment: 10 |