KR100981516B1 - Fabrication Methode of Metal Bipolar Plate for Direct Methanol Fuel Cell - Google Patents

Abstract

The present invention relates to a method for producing a metal separator for direct methanol fuel cell having high corrosion resistance and low interfacial contact resistance. The method for producing a metal separator for direct methanol fuel cell according to the present invention is weight%, C: 0.02 or less, N: 0.02 or less, Si: 0.4 or less, Mn: 0.2 or less, P: 0.04 or less, S: 0.02 or less, Cr: 15 to 34%, Mo: 0.1 to 5%, Cu: 0.1 to 2%, Ni: 0.8% or less, Ti: 0.5 or less, Nb: 0.5 or less V: 0 to 1%, W: 0 to 4% Preparing a ferritic stainless steel containing a composition in which La is 0 to 1%, Zr is 0 to 1%, and B is 0 to 0.1%. Washing the separator in an aqueous sulfuric acid solution, and passivating the washed separator in a mixed solution of nitric acid and hydrofluoric acid.

Direct Methanol Fuel Cell, Ferritic Stainless Steel, Separator, Single Cell

Description

Fabrication Method of Metal Bipolar Plate for Direct Methanol Fuel Cell}

The present invention relates to a method for producing a metal separator, and more particularly, to a method for manufacturing a metal separator for a direct methanol fuel cell (DMFC) having high corrosion resistance and low interfacial contact resistance.

Recently, according to the functionalization and miniaturization of portable electronic devices such as notebooks, video recorders, digital phones, PDAs, and the like, new power sources that can be used for a long time with higher output than conventional batteries are actively being developed.

In the fuel cell power generation technology that converts chemical energy of fuel directly into electrical energy by using electrochemical reaction, direct methanol fuel cell (DMFC) does not need fuel conversion process (or reforming process) and operates at room temperature. It is mainly developed as a portable fuel cell. However, in order to use for this purpose, there is still a need for technology development of weight, volume and power and durability.

A direct methanol fuel cell is formed in a stack form by stacking or electrically connecting these MEAs as a separator based on a membrane electrode assembly (MEA) composed of a polymer electrolyte membrane and an electrode. do.

As a separator material for a direct methanol fuel cell, a technology development is currently being conducted, focusing on a composite separator and a metal separator material made of carbon and polymer. Carbon (or graphite) -based separators have the disadvantages of high gas or liquid permeability, poor mechanical strength and formability, and high processing costs, whereas stainless steel separators have excellent gas tightness, high thermal / electrical conductivity, Since it is possible to thin the film, it is possible to reduce the weight and the excellent impact resistance, and it is possible to form the flow path quickly and easily by using the thin plate forming process, thereby lowering the price of the separator. Due to these advantages, the demand for the adoption of metal separators is gradually increasing, and for the commercialization of fuel cells, the development of metal separators must be accompanied.

In order to commercialize portable fuel cells (W ~ 200W) using separators, we developed high corrosion resistant and inexpensive sheet metal materials that can overcome the limitations of conventional graphite separators. Weight). Given that the price and weight share of the separator in the fuel cell stack are 50-60% and 70-80%, respectively, the low cost stainless steel unique alloy with stiffness, flexibility, and thickness can meet the price target of the fuel cell. The development of materials and the mass production of components for the manufacture of large fuel cell stacks must be essential to the fuel cell production process.

In addition, in order to satisfy the power density and startability of the fuel cell, it is necessary to improve thermal conductivity and electrical conductivity by using a metal separator plate, to reduce weight and volume, and to secure corrosion resistance to increase durability.

An object of the present invention is to provide a method for producing a metal separator plate for direct methanol fuel cell having excellent corrosion resistance and low interfacial contact resistance by modifying the surface of the stainless steel separator plate.

In order to solve the above technical problem, the manufacturing method of the metal separator for direct methanol fuel cell of the present invention is a weight%, C: 0.02 or less, N: 0.02 or less, Si: 0.4 or less, Mn: 0.2 or less, P: 0.04 or less , S: 0.02 or less, Cr: 15 to 34%, Mo: 0.1 to 5%, Cu: 0.1 to 2%, Ni: 0.8% or less, Ti: 0.5 or less, Nb: 0.5 or less V: 0 to 1 Preparing a ferritic stainless steel containing a composition in which%, W: 0 to 4%, La: 0 to 1%, Zr: 0 to 1%, and B: 0 to 0.1% Forming a separating plate, washing the separating plate in an aqueous sulfuric acid solution, and passivating the separating plate in a mixed solution of nitric acid and hydrofluoric acid.

Preferably, the step of cleaning includes the step of removing the oxide film from the surface by maintaining the separator in a 0.05 ~ 20% by weight aqueous solution of sulfuric acid at a temperature of 50 ~ 75 ℃ 30 seconds to 5 minutes.

The passivating step includes maintaining the separator for 30 seconds to 10 minutes at a temperature of 40 to 60 ° C. in a mixed solution of 10 to 20 wt% nitric acid and 1 to 10 wt% hydrofluoric acid.

Forming the separator includes a stamping or hydroforming process.

According to the present invention, it is possible to provide a metal separation plate having excellent mechanical strength while simultaneously securing high corrosion resistance and high conductivity (or low contact resistance) by surface modification. In addition, while maintaining the same output density (W / ㎠) of the direct methanol fuel cell using a conventional graphite separator, it is possible to lower the separator material price, including thinner and thinner the separator. In addition, there is an effect of ensuring the long-term stability of the stack performance, including the weight and miniaturization of the direct methanol fuel cell.

Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings so that those skilled in the art may easily implement the present invention. The present invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein.

1 is an exploded perspective view of a direct methanol fuel cell having a metal separator manufactured by a method of manufacturing a metal separator for a direct methanol fuel cell according to an embodiment of the present invention.

As shown in FIG. 1, the fuel cell includes a solid polymer electrolyte 112, catalysts 114 and 116, gaskets 118a and 118b, a metal separator plate 120, and an end plate 130. The liquid fuel 140, such as an aqueous methanol solution, is supplied to the anode in the fuel cell through an opening and a flow path formed in the end plate 130 and the metal separator 120 of the fuel cell, and includes an oxidant such as air containing oxygen ( 150 is supplied to the cathode in the fuel cell through another opening and another flow path formed in the end plate 130 and the metal separator plate 120 of the fuel cell. The anode by-product, the unreacted fuel 140a and the cathode by-product (eg, water) generated in the electrochemical reaction in the fuel cell are discharged from the fuel cell.

The catalysts 114 and 116 form an anode electrode and a cathode electrode on both sides of the electrolyte 112, and form a membrane electrode assembly 110 together with the electrolyte 112. Platinum ruthenium black may be used as a material of the catalyst (or anode) forming the anode electrode, and platinum black (Pt black) may be used as the material of the catalyst (or cathode) forming the cathode electrode. .

The gaskets 118a and 118b are disposed between the electrolyte 112 and the metal separator 120 to prevent leakage of fuel and air supplied to the anode electrode and the cathode electrode through the flow path of the metal separator 120, respectively. Seal tightly. Gaskets 118a and 118b may be formed of Teflon or rubber gaskets.

The pair of end plates 130 are formed to apply a predetermined pressure to the laminate of the membrane electrode assembly, the gaskets 118a and 118b and the metal separating plate 120 in a direction facing each other in the stacking direction, and by means of fastening means. Can be combined with each other.

The separator plate 120 is formed of stainless steel. Since stainless steel is excellent in ductility and thin plate manufacturing is possible, it is useful to form a metal separator plate with a flow path by an inexpensive manufacturing method such as press molding and hydroforming. In addition, stainless steel is excellent in properties such as impact resistance, gas impermeability, and corrosion resistance.

In particular, the separator 120 of the present embodiment is a ferritic stainless steel having a specific composition, and has a high corrosion resistance and low contact resistance as a separator for direct methanol that directly supplies a liquid fuel to the anode, such as an aqueous methanol solution, through surface modification notarization. Has characteristics. Therefore, the direct methanol fuel cell using the separator plate 120 of the present embodiment may exhibit excellent performance.

More specifically, the manufacturing method of the stainless steel used as the separator plate 120 of the present embodiment is as follows. The stainless steel of the present embodiment is, by weight, C: 0.02 or less, N: 0.02 or less, Si: 0.4 or less, Mn: 0.2 or less, P: 0.04 or less, S: 0.02 or less, Cr: 15 to 34%, Mo: 0.1 5%, Cu: 0.1-2%, Ni: 0.8% or less, Ti: 0.5 or less, Nb: 0.5 or less V: 0-1%, W: 0-4%, La: 0-1%, Zr: 0 ~ 1%, B: 0 ~ 0.1% Single or mixed composition to produce cast steel by continuous casting, or cast steel by steel casting, hot rolling, annealing, pickling, cold rolling The annealing and pickling may be repeated to produce a cold rolled annealing plate having a thickness of 0.05 mm to 2 mm.

Table 1 shows the composition of the manufactured stainless steel.

Hereinafter, the reason for limiting each component content will be described in detail. In addition, all% described below is weight%.

C and N form Cr carbonitride in stainless steel, and as a result, the corrosion resistance of the Cr-deficient layer is lowered, so the lower the content of the two elements is preferable. In the present invention, the composition ratio is limited to C: 0.02% or less and N: 0.02% or less.

Since Si suppresses the element, toughness, and moldability which are effective for deoxidation, in the present invention, the composition ratio of Si is limited to within 0.4%.

Mn is an element that increases deoxidation, but the inclusion MnS reduces corrosion resistance. In the present invention, the composition ratio of Mn is limited to within 0.2%.

Since P not only reduces corrosion resistance but also toughness, in this embodiment, the composition ratio of P is limited to within 0.04%.

S forms MnS, which becomes a starting point of corrosion and reduces corrosion resistance. In this embodiment, the composition ratio of S is limited to within 0.02% in consideration of this.

Cr increases the corrosion resistance in the acidic atmosphere in which the fuel cell is operated, but reduces the toughness, and therefore, in the present embodiment, the composition ratio of Cr is limited to 25% to 32%.

Mo increases the corrosion resistance in the acidic atmosphere in which the fuel cell is operated, but reduces the toughness, and therefore, in the present embodiment, the composition ratio of Mo is limited to the range of 0% to 5%.

Cu increases the corrosion resistance in an acidic atmosphere in which the fuel cell operates, but the performance of the fuel cell may be degraded due to the elution of Cu when excessively added. In this embodiment, the composition ratio of Cu is limited to 0.1% to 2% in consideration of this.

Ni serves to reduce some contact resistance, but when excessively added, Ni dissolution and moldability may be reduced. In this embodiment, in consideration of this, the composition ratio of Ni is limited to 0.8% or less.

Ti and Nb deteriorate the element and toughness effective for forming C and N in carbon as carbonitrides. In this embodiment, each composition ratio is limited to 0.5% or less in consideration of this.

In addition to this, one or two or more kinds of V, W, La, Zr and B may be added, and their composition ratios are as follows.

V increases the corrosion resistance in the acidic atmosphere in which the fuel cell operates, but when excessively added, ions are eluted and the performance of the cell may be degraded. In this embodiment, the composition ratio of V is limited to 1% or less in consideration of this.

W has the effect of increasing the corrosion resistance and lowering the interfacial contact resistance in the acidic atmosphere in which the fuel cell operates, but deteriorates the toughness upon excessive addition. In this embodiment, the composition ratio of W is limited to 4% or less in consideration of this.

La may induce fine dispersion of sulfide-based inclusions in steel and densification of the passivation film, but problems such as nozzle clogging occur when over-added. In this embodiment, the composition ratio of La is limited to 1% or less in consideration of this.

Zr increases the corrosion resistance in an acidic atmosphere in which the fuel cell is operated, but causes surface defects when excessively added. Therefore, in the present embodiment, the composition ratio of Zr is limited to 1% or less.

B forms a nitride in the steel and improves its corrosion resistance but causes surface defects upon excessive addition, so the composition ratio of B is limited to 0.1% in this embodiment.

According to the above structure, the cold rolled annealing plate of a specific composition is prepared as the stainless steel for metal separating plates of a present Example.

The prepared cold rolled annealing plate is processed by a press molding, a hydroforming process, and the like, whereby an anode flow path, a cathode flow path, a cooling channel, manifolds and the like can be formed on the cold rolled annealing plate. Through the above-described process, a metal separator plate before surface modification is prepared.

Thereafter, a step of a degreasing process of controlling the surface roughness of the separator to 0.01-5 μm using a shot blast, a wire brush, or the like is performed. After the degreasing step, the separator is immersed in 0.05-20% by weight of sulfuric acid solution at a temperature of 50-75 ° C for 30 seconds to 5 minutes to remove the oxide film from the surface. The step of washing in the process of washing with a large amount of water, and passivating the surface of the separator plate by dipping for 30 seconds to 10 minutes at a temperature of 40 to 60 ℃ in a mixed solution of 10 to 20% by weight nitric acid and 1 to 10% by weight hydrofluoric acid After performing the steps of the washing process to finally wash the chemicals on the separator plate.

The surface modification process of this embodiment mentioned above is demonstrated in more detail below.

2 is a graph of the potential of the stainless steel separator according to one embodiment of the present invention measured at 70 ° C. in a 15 wt% sulfuric acid solution using a saturated calomel electrode as a reference electrode.

On the surface of the prepared cold rolled annealing plate (stainless steel), generally a thin protective oxide is formed. Such an oxide is an iron-chromium oxide, and has a high iron content, which is not suitable as the metal separation plate of the present embodiment and should be removed.

As illustrated in FIG. 2, when the stainless steel is immersed in the sulfuric acid aqueous solution, the oxide formed on the surface of the stainless steel begins to be removed, and as a result, the potential gradually decreases. After a certain time, when the oxide formed on the surface of the immersed stainless steel is removed, the potential is no longer lowered and becomes saturated.

Therefore, when the stainless steel is immersed in the sulfuric acid aqueous solution until the saturation at a lower potential than the initial immersion, the oxide formed on the surface of the stainless steel can be removed.

In the present embodiment, the stainless steel is washed in an aqueous sulfuric acid solution of 5% to 20% at 50 ° C to 75 ° C and weight percent, and the treatment time is 20 seconds to 5 minutes.

If the sulfuric acid aqueous solution temperature and concentration is too low, it is not easy to remove the oxide film on the surface of the stainless steel, on the contrary, too high may cause damage to the stainless steel (or base material), the temperature was limited to 50 ℃ to 75 ℃, The concentration is limited to 5% to 20% by weight.

Figure 3 is a graph showing the result of measuring the potential of the stainless steel separator according to an embodiment of the saturated calomel electrode as a conventional electrode in a mixed solution of 70 ℃, 15% by weight nitric acid and 5% by weight of hydrofluoric acid .

When stainless steel is immersed in an oxidizing solution such as a mixed solution of nitric acid and hydrofluoric acid, a passivation film is formed on the surface thereof. As the passivation film is formed on the surface as described above, the potential of the stainless steel becomes high.

Therefore, when the stainless steel is immersed in the mixed solution of nitric acid and hydrofluoric acid until the point of saturation at a higher potential than the initial immersion, a passivation film is formed on the surface of the stainless steel.

As shown in FIG. 3, the passivation coating is more rapidly when washed with sulfuric acid when comparing with (A) and without washing with sulfuric acid (B) before immersing in a mixed solution of nitric acid and hydrofluoric acid. Formed, the interfacial contact resistance after the final surface modification has a lower value. These results indicate that sulfuric acid cleaning is effective in forming passivation film with low contact resistance.

In this embodiment, the passivation treatment for 30 seconds to 10 minutes effectively forms a passivation film on the surface of the stainless steel. This treatment time varies depending on the surface roughness, and the greater the surface roughness, the greater the contact area between the mixed solution and the surface. The greater the surface roughness, the shorter the time required for each process.

In addition, the lower the passivation treatment temperature, the more time is required for the passivation treatment. On the contrary, if the passivation treatment temperature is too high, surface damage may be caused rather than harmful to contact resistance and corrosion resistance. To a temperature of from 60 ° C.

In addition, in the concentration of nitric acid, passivation is difficult at less than 10% by weight, and on the contrary, if it is too high, there is no effect of reducing contact resistance, so in this embodiment, the concentration of nitric acid is limited to 10% by weight to 20% by weight.

In the concentration of hydrofluoric acid, the passivation film may become unstable at less than 1% by weight. In contrast, in the present embodiment, the concentration of the hydrofluoric acid is 1% by weight because it may cause surface damage upon excessive addition. To 10% by weight.

In one embodiment of the present invention was measured the interfacial contact resistance before and after chemical surface modification at a contact pressure of 140N / ㎠, the results are listed in Table 2.

As can be seen in Table 2, the Cr and Mo content is low, and stainless steel added with Cu and W has a lower initial interface contact resistance.

In addition, the steel subjected to the chemical surface modification treatment according to the present embodiment has an interfacial contact resistance of 3mPa 2 ~ 6mPa 2 at a contact pressure of 140N / ㎠. In the interfacial contact resistance measured after the polarization test under the fuel cell simulation conditions, excellent characteristics of 4mΩ㎠ to 8.52mΩ㎠ were obtained. The current density after the polarization test also has a low value of 0.5 ㎂ / ㎠ or less, and after measuring the Fe, Cr and Ni elution ions in the corrosion solution after the polarization test, 0.050 mg / L, which does not cause the performance degradation of the fuel cell. Only the following Fe eluted ions were detected.

After chemical surface modification, the passivation film thickness has a thickness of 2 nm to 5 nm, and the concentration distribution of the Cr oxide layer is Fe oxide layer after chemical surface modification, that is, sulfuric acid cleaning and mixed solution passivation at the outermost surface layer within 1 nm region. The concentration is higher than the concentration distribution of. In addition, Cr (OH) 3 exists as a main phase in a surface layer part. That is, it can be confirmed that after passivation of the chemical surface, a passivation film having good environmental conditions for direct methanol fuel cell was formed on the surface of stainless steel.

In addition to the separator of the present embodiment, the MEA production and the evaluation of the unit cell were performed as follows. The catalyst was mixed with a Nafion solution, distilled water, and an alcohol solvent (eg, 1-propanol, 2-propanol) to prepare an electrode slurry required for unit cell fabrication. The prepared catalyst slurry was uniformly mechanically coated on a porous gas diffusion layer (eg, carbon paper or carbon cloth) by a bar-coating method. The catalyst coating gas diffusion layer thus prepared was dried in a dryer at 70 ° C. for 6 hours. Gas diffusion layers of the cathode and anode were treated with Teflon (PTFE) solution to impart water repellency. The catalyst loading of the coated catalyst layer was adjusted to be in the range of 2 to 5 mgPt (or Pt-Ru) / cm 2 for the air electrode and the fuel electrode, respectively. The thickness of the catalyst layer prepared by the bar-coating was adjusted uniformly to be in the range of 20-50 μm.

A membrane electrode assembly (MEA) to be used as a unit cell was fabricated by a hot pressing method by providing a catalyst layer and a gas diffusion layer on both sides of a polymer membrane (eg, Nafion 115). At this time, the pressing pressure was adjusted in the range of 27-100 kg / cm 2 and the pressing temperature and time were adjusted in the range of 60-150 ° C. and 30-120 seconds, respectively. As such, according to the above-described processes, the metal separator plate 120 of the present embodiment is prepared.

4 is a schematic block diagram of a system for evaluating the performance of a single cell stack with a stainless separator of the present invention.

As shown in FIG. 4, the performance evaluation system includes a unit cell unit 100a, a fuel / air supply unit 200, and a data collection and measurement system control unit 300.

The unit cell unit 100a includes a stack (or unit cell stack) made of unit cells. The unit cell unit 100a is formed of one membrane electrode assembly, a gasket, and a pair of metal separation plates. The unit cell unit 100a of this embodiment is substantially the same as the direct methanol fuel cell shown in FIG. 1 except that it includes a pair of metal separator plates and a single membrane electrode assembly interposed therebetween.

In this embodiment, the active area of the electrode used for the unit cell was 9 cm 2 (3 cm × 3 cm). As a fuel used for performance measurement, a 1 molar concentration of aqueous methanol solution was used. One mole of methanol was supplied at 4 kW / min to the anode of the unit cell, and air was supplied at a flow rate of 300 kW / min to the cathode. The flow paths of the fuel electrode and the air electrode were respectively processed into a sulfentine structure.

The fuel / air supply unit 200 supplies fuel and air to the unit cell unit 100a. The fuel / air supply unit 200 may include a fuel tank, a fuel pump, and an air pump.

The data collection and measurement system controller 300 measures the voltage, current, and temperature of the unit battery unit 100a. The data collection and measurement system controller 300 may control the temperature of the unit cell unit 100 and control the flow rate of fuel and / or air supplied from the fuel / air supply unit 200 to the unit cell unit 100. Can be. The data collection and measurement system control unit 300 may include a controller, a sensor, and the like.

In addition, the performance evaluation system may include a heat exchanger for adjusting the unit cell unit 100, a mass flow controller (MFC) for controlling the flow rate of fuel and / or air.

Figure 5 is a graph showing the results of measuring the output voltage and output density for 2,006 hours while maintaining a current density of about 150 mA / cm 2 at 60 ° C single cell stack with a stainless separator plate of the present invention.

As shown in Fig. 5, the unit cell was supplied with methanol and air in a molar concentration of 1 mol to the anode and the cathode, respectively, while maintaining the temperature at 60 deg. The initial voltage when the measurement was started at a constant current density of 150 mA / cm 2 was 0.411 V. After about 2006 hours, the voltage decreased slightly to 0.382 V. In this case, the voltage drop rate was calculated as 0.014V / 1,000 hours and the voltage drop rate was 3.406% / 1,000 hours.

6 shows the results of measuring the voltage, current density, and output density at the time when 159 hours and 2006 hours have elapsed after starting the long-term performance evaluation of the unit cell stack including the stainless steel separator of the present invention at 60 ° C. The graph shown.

As shown in Fig. 6, the peak powers measured at the start time of the long-term performance measurement, at the time of 159 hours after the start time and at the time of 2,006 hours, were 88.7 kV / cm 2 (0.34V) and 99.3 kV /, respectively. Cm 2 (0.3V), and 88.7 mA / cm 2 (0.3 V), respectively, at 0.4 V cell voltage of 75.6 mA / cm 2, 82.7 dB / cm 2, and 75.1 dB / cm 2. That is, the power density drop for 2,006 hours was 0.5 kW / cm 2 and the power density drop rate was 0.249 kW / cm 2 per 1,000 hours.

7 is a graph showing the results of measuring the cell resistance (cell resistance) of the unit cell stack for 2,006 hours while maintaining a current density of 150 ㎃ / ㎠ at 60 ℃ in a single cell stack with a stainless separator plate of the present invention .

As shown in FIG. 7, the initial cell resistance at which the measurement was started by maintaining a constant current density of 150 mA / cm 2 was 40.5 to 41 mPa, and then decreased to about 35 to 36 mPa after 240 hours and 2,006 hours had elapsed. Afterwards, the resistance value remained constant at 35-36mΩ with little change. From these results, the contact resistance of the unit cell MEA was slightly lowered during the initial 240 hours, but after 240 hours, the contact of the MEA was stabilized and maintained to be almost constant. In addition, since the cell resistance does not change even after a long time of 2,006 hours, the contact resistance and corrosion resistance of the metal separator of the present embodiment are considered to be excellent.

It should be noted that the above embodiments have set limited conditions in order to express the technical idea of the present invention and that they are not intended to be limiting in the application of the present invention. In addition, those skilled in the art will understand that various embodiments are possible within the scope of the technical idea of the present invention.

1 is an exploded perspective view of a direct methanol fuel cell having a metal separator manufactured by a method for manufacturing a metal separator for a direct methanol fuel cell according to an embodiment of the present invention.

Figure 2 is a graph showing the result of measuring the potential of the stainless steel separator according to an embodiment of the saturated calomel electrode as a reference electrode in 70 ℃, 15% by weight aqueous sulfuric acid solution.

Figure 3 is a graph showing the result of measuring the potential of the stainless steel separator according to an embodiment of the saturated calomel electrode as a conventional electrode in a mixed solution of 70 ℃, 15% by weight nitric acid and 5% by weight of hydrofluoric acid.

4 is a block diagram of a system for evaluating the performance of a single cell stack with a stainless separator plate of the present invention.

Figure 5 is a graph showing the results of measuring the output voltage and output density for 2,006 hours while maintaining a current density of about 150 mA / cm 2 at 60 ° C single cell stack with a stainless separator plate of the present invention.

Figure 6 shows the results of measuring the voltage, current density, and output density at the time when 159 hours and 2,006 hours have elapsed after the start of long-term performance evaluation of the unit cell stack with a stainless separator plate of the present invention at 60 ℃ graph.

7 is a graph showing the results of measuring the cell resistance of the unit cell stack for 2,006 hours while maintaining a current density of 150 mA / cm 2 at 60 ° C. in the unit cell stack including the stainless steel separator of the present invention.

Explanation of symbols on the main parts of the drawings

100: direct methanol fuel cell

100a: single cell stack

200: fuel / air supply unit

300: data acquisition and measurement system control unit

Claims (4)

By weight%, C: 0.02 or less, N: 0.02 or less, Si: 0.4 or less, Mn: 0.2 or less, P: 0.04 or less, S: 0.02 or less, Cr: 15 to 34%, Mo: 0.1 to 5%, Cu: 0.1 to 2%, Ni: 0.8% or less, Ti: 0.5 or less, Nb: 0.5 or less, V: 0 to 1%, W: 0 to 4%, La: 0 to 1%, Zr: 0 to 1% , B: preparing a ferritic stainless steel containing a composition in which 0 to 0.1% of a single or mixed addition; Molding the stainless steel into a separator; Washing the separator in an aqueous sulfuric acid solution; And A method of manufacturing a metal separator for direct methanol fuel cell comprising the step of passivating the separator in a mixed solution of nitric acid and hydrofluoric acid. The method of claim 1, The cleaning step is a metal separator for direct methanol fuel cell comprising the step of removing the oxide film from the surface by maintaining the separator in a 0.05 ~ 20% by weight sulfuric acid solution at a temperature of 50 ~ 75 ℃ 30 seconds to 5 minutes. Method of preparation. The method according to claim 1 or 2, The passivating step is a direct methanol fuel comprising maintaining the separation plate at a temperature of 40 to 60 ° C. for 30 seconds to 10 minutes in a mixed solution of 10 to 20 wt% nitric acid and 1 to 10 wt% hydrofluoric acid. The manufacturing method of the metal separator plate for batteries. The method of claim 3, Forming the separator is a method of manufacturing a metal separator for direct methanol fuel cell comprising a stamping or hydroforming process.

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