KR100959344B1 - Putty composition for rail train - Google Patents
Putty composition for rail train Download PDFInfo
- Publication number
- KR100959344B1 KR100959344B1 KR1020080011025A KR20080011025A KR100959344B1 KR 100959344 B1 KR100959344 B1 KR 100959344B1 KR 1020080011025 A KR1020080011025 A KR 1020080011025A KR 20080011025 A KR20080011025 A KR 20080011025A KR 100959344 B1 KR100959344 B1 KR 100959344B1
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- putty
- curing agent
- composition
- present
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/34—Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
Abstract
본 발명은 철도차량에 적합한 퍼티(putty)에 관한 것으로, 종래의 에폭시계 퍼티와 동등한 기계적 물성을 보유하면서도 건조 시간이 현저하게 단축될 수 있고 비중이 낮은 철도차량용 퍼티 조성물을 제공하는 것을 목적으로 한다.The present invention relates to a putty suitable for a railway vehicle, and aims to provide a putty composition for a railway car which has a mechanical property equivalent to that of a conventional epoxy putty and can be significantly shortened in drying time and has a low specific gravity .
상기 목적을 달성하기 위한 본 발명에 따른 퍼티 조성물은, 주제와 경화제를 혼합하여 사용하는 2액형 퍼티 조성물로서, 상기 주제는 비스페놀-A: 25 ~ 35중량%, 지방족 글리시딜에테르: 5 ~ 15중량%, 탈크: 45 ~ 60중량%를 함유하고, 상기 경화제는 지방족 아민: 18 ~ 30중량%, TEPA(Tri-Ethyl-Propyl-Amine): 5 ~ 10중량%, DMP-30: 5 ~ 15중량%, 탈크: 40 ~ 56중량%를 함유하고, 나머지 불가피한 불순물로 이루어진 것을 특징으로 한다.In order to achieve the above object, the present invention provides a two-pack type putty composition comprising a mixture of a mixture of a main component and a curing agent, wherein the composition comprises 25 to 35% by weight of bisphenol-A, 5 to 15% by weight of aliphatic glycidyl ether, Wherein the curing agent comprises 18 to 30% by weight of aliphatic amine, 5 to 10% by weight of triethyl-propyl-amine, 5 to 15% by weight of DMP-30, By weight, and talc: 40 to 56% by weight, and the remaining unavoidable impurities.
퍼티 조성물 Putty composition
Description
본 발명은 철도차량에 적합한 퍼티(putty)에 관한 것으로, 더욱 상세하게는 우수한 기계적 물성과 함께 건조시간이 매우 짧아 철도차량의 도장시간을 현저하게 단축시킬 수 있고 비중이 낮아 철도차량의 경량화에 도움이 될 수 있는 퍼티 조성물에 관한 것이다.The present invention relates to a putty suitable for a railway vehicle, and more particularly, to a putty which is suitable for a railway vehicle, and which has excellent mechanical properties and a very short drying time, thus remarkably shortening the painting time of the railway vehicle, ≪ / RTI >
철도 차량은 가혹한 환경에서 장시간(내구연한이 30년 이상) 운행하는 운송설비이므로, 차량의 내구성, 안정성, 유지관리 및 미감의 측면에서 도장 품질이 매우 중요하다.Railway vehicles are transportation facilities that operate in harsh environments for a long period of time (more than 30 years), so paint quality is very important in terms of durability, stability, maintenance and aesthetics of vehicles.
한편, 철도 차량 제작 공정 중에서 차체 외판에 적용되는 도장 작업은 전처리(쇼트 블라스팅), 하도 도장, 퍼티 시공, 연마, 중도 도장, 연마, 상도 도장의 순서로 진행되는데, 각 공정에 있어서 도료의 건조 시간은 대략 20℃ 기준으로 20시간 정도 소요되는 것이 일반적이다.Meanwhile, in the process of manufacturing a railway vehicle, the coating work applied to the body panel is carried out in the order of pretreatment (shot blasting), undercoating, putty coating, polishing, intermediate painting, polishing and top painting. Generally takes about 20 hours at about 20 ° C.
이중 퍼티 시공은 총 4회에 걸쳐 실시해야만 차체 외판의 굴곡 부위를 보완할 수 있는데, 4회에 걸친 전체 퍼티 시공에는 총 80여 시간의 건조 시간이 소요되고 이는 전체 도장 작업 공정 건조 시간의 50%를 점하기 때문에, 제작 소요시 간(lead time) 측면에서 매우 중요한 공정이라고 할 수 있다.It is necessary to perform the double putty work four times in total to compensate the bending part of the outer shell of the body. In total putty work of 4 times, it takes about 80 hours of drying time, which is 50% It is an important process in terms of lead time.
한편, 현재 널리 사용되고 있는 철도차량용 퍼티는 크게 불포화 폴리에스터계 퍼티와 에폭시계 퍼티의 2종류로 분류가 된다.Meanwhile, currently widely used railway car putties are classified into two types, unsaturated polyester based putty and epoxy based putty.
이중 불포화 폴리에스터 퍼티는 건조시간이 20℃ 기준으로 2시간 정도로 건조가 매우 빠른 이점이 있으나 기계적 물성(내충격성, 내굴곡성 등)이 취약하여 차량 운행 과정에서 진동이나 외부의 충격 등에 의해 2 ~ 3년 경과 후 도막의 자연박리 현상이 발생하기 때문에, 30년의 도장 수명을 요구하는 철도차량용으로는 적합하지 않다.The polyunsaturated polyester putty has a very rapid drying time of about 2 hours at a drying time of 20 ° C, but the mechanical properties (impact resistance, flexural resistance, etc.) of the polyunsaturated polyester putty are poor. It is not suitable for a railway vehicle requiring a paint life of 30 years because a natural peeling phenomenon of the coating occurs after a lapse of a year.
상기 에폭시계 퍼티는 피도물의 열팽창에 따른 균열이나 박리 등의 문제는 적으나, 20℃ 기준으로 20 시간 정도의 건조 시간이 소요되기 때문에 전체 도장 공정 기간에서 차지하는 비중이 매우 커 생산성 저하의 주요 원인이 되고 있다.The epoxy putty has a few problems such as cracking or peeling due to thermal expansion of the substrate, but it takes a drying time of about 20 hours at 20 ° C, which is a major factor in the overall coating process, .
본 발명은 전술한 종래기술의 문제점을 해결하기 위해 창안된 것으로서, 종래의 에폭시계 퍼티와 동등한 기계적 물성을 보유하면서도 건조 시간이 현저하게 단축될 수 있는 철도차량용 퍼티 조성물을 제공하는 것을 해결하고자 하는 기술적 과제로 한다.Disclosure of Invention Technical Problem [8] Accordingly, the present invention has been made keeping in mind the above problems occurring in the prior art, and an object of the present invention is to provide a putty composition for a railway vehicle which can have a mechanical property equivalent to that of a conventional epoxy putty, We will do it.
상기 기술적 과제를 달성하기 위한 본 발명에 따른 퍼티 조성물은, 주제와 경화제를 혼합하여 사용하는 2액형 조성물로서, 상기 주제는 비스페놀-A: 25 ~ 35중량%, 지방족 글리시딜에테르: 5 ~ 15중량%, 탈크: 45 ~ 60중량%를 함유하고, 상기 경화제는 지방족 아민: 18 ~ 30중량%, TEPA(Tri-Ethyl-Propyl-Amine): 5 ~ 10중량%, DMP-30: 5 ~ 15중량%, 탈크: 40 ~ 56중량%를 함유하고, 나머지 불가피한 불순물로 이루어진 것을 특징으로 한다.In order to accomplish the above object, the present invention provides a two-component composition comprising a mixture of a base and a curing agent, wherein the base comprises 25 to 35% by weight of bisphenol-A, 5 to 15% by weight of aliphatic glycidyl ether, Wherein the curing agent comprises 18 to 30% by weight of aliphatic amine, 5 to 10% by weight of triethyl-propyl-amine, 5 to 15% by weight of DMP-30, By weight, and talc: 40 to 56% by weight, and the remaining unavoidable impurities.
또한, 상기 주제는 추가로, 제 1 항에 있어서, 상기 주제 및 경화제는 각각 안료를 1 ~ 10중량% 함유할 수 있다.In addition, the above subject matter may further include a base and a curing agent, wherein the base and the curing agent each contain 1 to 10% by weight of the pigment.
또한, 상기 안료에는 실리카 필러(silica filler): 1 ~ 5중량%(전체 조성물에 대한 비율임)와 다공질 필러: 0.5 ~ 5중량%(전체 조성물에 대한 비율임)를 포함할 수 있다.In addition, the pigment may include silica filler in an amount of 1 to 5% by weight (relative to the total composition) and 0.5 to 5% by weight of a porous filler (in terms of the total composition).
또한, 상기 주제 및 경화제는 각각 추가로 분산제: 0.5 ~ 2중량%, 유동성첨가제(rheology additive): 0.5 ~ 3중량% 및 레올로지제(rheology agnet): 0.01 ~ 1 중량%를 포함할 수 있다.The subject and the curing agent may further include 0.5 to 2 wt% of a dispersant, 0.5 to 3 wt% of a rheology additive, and 0.01 to 1 wt% of rheology agnet.
또한, 본 발명은 주제와 경화제를 혼합하여 사용하는 2액형 퍼티 조성물로서, 상기 주제는 비스페놀-A: 30중량%, 지방족 글리시딜에테르: 9중량%, 탈크: 53중량%, 분산제: 1중량%, 유동성첨가제(rheology additive): 1.2중량%, 실리카 필러(silica filler): 2.5중량%, 다공질 필러: 1.0중량%를 포함하고, 상기 경화제는 지방족 아민: 22.8중량%, TEPA(Tri-Ethyl-Propyl-Amine): 7.2중량%, DMP-30: 10중량%, 탈크: 51중량%, 실리카 필러(silica filler): 2.5중량%, 다공질 필러: 1.0중량%, 분산제: 1중량%, 유동성첨가제: 1.2중량%를 포함하는 것을 특징으로 한다.The present invention also provides a two-component putty composition comprising a mixture of a base and a curing agent, wherein the base contains 30 wt% of bisphenol-A, 9 wt% of aliphatic glycidyl ether, 53 wt% of talc, %, Rheology additive: 1.2 wt%, silica filler: 2.5 wt%, and porous filler: 1.0 wt%, the curing agent comprising aliphatic amine: 22.8 wt%, TEPA (Tri- Propyl-amine, 7.2 wt% DMP-30 10 wt%, talc 51 wt%, silica filler 2.5 wt%, porous filler 1.0 wt%, dispersant 1 wt% 1.2% by weight.
또한, 본 발명에 따른 퍼티 조성물은 여러 분야에 적용될 수 있으나, 특히 철도 차량용에 적합하다.Further, the putty composition according to the present invention can be applied to various fields, but is particularly suitable for railway vehicles.
다음으로, 각 성분을 상기와 같이 제한한 이유에 대해 구체적으로 설명한다.Next, the reason why each component is limited as described above will be described in detail.
상기 비스페놀-A는 주제 성분의 주성분 수지로서, 25중량% 미만으로 첨가되면 내충격성 및 굴곡성이 저하되며, 35중량% 초과하여 첨가되면 유동성이 심해서 흐름저항성이 저하되기 때문에, 상기 범위로 함유되는 것이 바람직하다.When bisphenol-A is the main component resin of the main component, if it is added in an amount of less than 25% by weight, the impact resistance and the bending property are deteriorated. If it is added in an amount exceeding 35% by weight, desirable.
상기 지방족 글리시딜에테르는 비스페놀-A와 블렌딩되면서, 당량이 높고 점도가 낮은 형태의 장쇄(long chain) 공중합 고분자를 형성하여, 퍼티의 경도, 부착성, 내굴곡성 및 연마성을 우수하게 하며, 퍼티에 유연성을 부여하고 퍼티의 기계적 물성치를 향상시키는 작용을 하며, 상기 범위 미만 또는 초과하여 함유되면 건조시간이 길어지거나 퍼티 물성치가 저하되므로, 상기 범위로 함유되는 것이 바람 직하다.The aliphatic glycidyl ether is blended with bisphenol-A to form a long chain copolymeric polymer having a high equivalent weight and a low viscosity, thereby improving the hardness, adhesiveness, flexural resistance and abrasion resistance of the putty, It imparts flexibility to the putty and improves the mechanical properties of the putty, and if it is contained in an amount less than or greater than the above range, the drying time becomes longer or the putty property decreases.
본 발명에서는 지방족 아민 18 ~ 30중량%와 트리에틸프로필아민(Tri-Ethyl-Propyl-Amine, 이하 "TEPA"): 5 ~ 10중량%를 혼합한 변성 지방족 아민을 사용하며, 지방족 아민은 아민가가 280 ~ 360이고, 점도는 25℃에서 2,000 ~ 4,000cps이며 C12 ~ C14의 것을 사용한다. 변성 지방족 아민은 고분자 체인을 길게 변성시켜 퍼티에 유연성을 부여하는 한편, 반응 속도를 빠르게 하여 퍼티의 건조시간을 단축시키는 작용을 한다. 지방족 아민과 TEPA의 함량이 상기 범위를 벗어나면 전술한 효과를 얻기 어려우므로, 상기 범위 내로 첨가하는 것이 바람직하다. In the present invention, a modified aliphatic amine mixed with 18 to 30 wt% of an aliphatic amine and 5 to 10 wt% of triethyl-propyl-amine (hereinafter referred to as "TEPA") is used, 280 to 360, and viscosity of 2,000 to 4,000 cps at 25 DEG C, and C12 to C14 are used. Modified aliphatic amines modify the polymer chains to give flexibility to the putty while speeding up the reaction rate and shortening the drying time of the putty. If the content of the aliphatic amine and the TEPA is out of the above range, it is difficult to obtain the effect described above.
상기 DMP-30(tris(dimethylaminomethyl)phenol)은 경화를 촉진(내지는 가속)하는 성분으로, 5중량% 미만으로 첨가되면 경화를 촉진하는 기능이 떨어지고, 15중량% 초과하여 첨가되면 내충격성 및 내굴곡성이 저하되기 때문에, 상기 범위로 함유되는 것이 바람직하다.When DMP-30 (tris (dimethylaminomethyl) phenol) is added as a component accelerating (or accelerating) curing, if it is added in an amount of less than 5% by weight, the function of accelerating curing is poor. It is preferably contained in the above range.
상기 탈크는 주제와 경화제에서 각각 45 ~ 60중량%와, 40 ~ 56중량%를 함유하는데, 상기 범위의 하한치 미만으로 첨가되면 연마성이 저하되며, 상기 범위의 상한치를 초과하여 첨가되면 내충격성 및 내굴곡성이 저하된다.The talc contains 45 to 60% by weight and 40 to 56% by weight in the case and the hardener, respectively. When the content is less than the lower limit of the above range, the abrasive property is deteriorated. When the content exceeds the upper limit of the above range, The bending resistance is lowered.
상기 실리카 필러는 특수 안료로서, 일반 체질 안료에 비해서 흡유량이 높아 퍼티의 점도 조절을 용이하게 하며, 건조시간 단축과 퍼티의 비중을 낮추는 작용을 한다. 실리카 필러를 1중량% 미만으로 첨가하면 상기 효과를 얻기 어렵고, 5중량%를 초과하여 첨가할 경우, 타 성분의 함량이 줄어들어 퍼티 전체의 물성이 떨어지므로, 1 ~ 5중량%의 범위로 첨가하는 것이 바람직하다.The silica filler is a special pigment, which has a higher oil absorption than ordinary extender pigments, facilitates control of the viscosity of the putty, and shortens the drying time and reduces the specific gravity of the putty. When the amount of the silica filler is less than 1% by weight, the above effects are difficult to obtain. When the amount of the silica filler is more than 5% by weight, the content of the other components is decreased to lower the physical properties of the whole putty. .
상기 다공질 필러도 특수 안료의 하나로서 주로 다공질 실리카가 사용되며, 일반 체질 안료에 비해서 흡유량이 높아 퍼티의 점도 조절을 용이하게 하며, 건조시간 단축과 퍼티의 비중을 낮추는 작용을 한다. 다공질 필러를 0.5중량% 미만으로 첨가하면 상기 효과를 얻기 어렵고, 5중량%를 초과하여 첨가할 경우, 타 성분의 함량이 줄어들어 퍼티 전체의 물성이 떨어지므로, 0.5 ~ 5중량%의 범위로 첨가하는 것이 바람직하다.The porous filler is also one of the special pigments, and mainly porous silica is used. The oil absorption is higher than that of general pigments, so that the viscosity of the putty can be easily controlled and the drying time is shortened and the specific gravity of the putty is lowered. When the content of the porous filler is less than 0.5% by weight, it is difficult to obtain the above effect. When the content of the porous filler is more than 5% by weight, the content of the other components is decreased to lower the physical properties of the whole putty. .
상기 분산제는 조성물 중의 고형분들을 고르게 분산시키는 기능을 하는 것으로서, 구체적으로 불포화폴리아마이드와 에스테르염 등이 사용되며, 0.5중량% 미만으로 첨가되면,분산 효과가 저하되고, 2중량% 초과하여 첨가되면 퍼티의 물성이 저하되기 때문에, 상기 범위로 첨가하는 것이 바람직하다.When the amount of the dispersant is less than 0.5% by weight, the dispersing effect is deteriorated. When the amount of the dispersant is more than 2% by weight, It is preferable to add it in the above range.
상기 유동성 첨가제(rheology additive)는 구체적으로 Fumed silica 등이 사용되며, 0.5중량% 미만으로 첨가되면 유동성이 높아져서 수직면에 퍼티를 시공시 흐름 현상이 발생되며, 3중량% 초과하여 첨가되면 점성이 높아져 작업성이 저하되기 때문에, 상기 범위로 첨가되는 것이 바람직하다.Fumed silica or the like is used as the rheology additive. When it is added in an amount of less than 0.5% by weight, flowability is increased and flow phenomenon occurs when the putty is applied to the vertical surface. When added more than 3% by weight, It is preferably added in the above range.
본 발명에 따른 퍼티 조성물은 종래의 에폭시계 퍼티에 비해 건조시간이 20시간에서 6시간 정도로 현저하게 단축될 뿐 아니라, 도막의 내박리성 등 기계적 물성이 우수하다.The putty composition according to the present invention is remarkably shortened in drying time from about 20 hours to about 6 hours as compared with the conventional epoxy putty and has excellent mechanical properties such as peeling resistance of the coating film.
또한 본 발명에 따른 퍼티 조성물은 100% 고형분으로 이루어져 있으므로 경화시 용제의 휘발에 따른 에너지 및 자원의 낭비를 막고 환경 오염도 유발하지 않 는다.Also, since the putty composition according to the present invention is composed of 100% solids, waste of energy and resources due to the volatilization of the solvent during curing is prevented and environmental pollution is not caused.
또한 본 발명에 따른 퍼티 조성물은 종래의 에폭시계 퍼티에 비해 비중이 낮아, 두께 1㎜로 도장할 경우 전체 도막 무게의 25중량%의 중량 감소 효과를 얻을 수 있어, 차량의 수직 하중 감소 및 차량 운행시 연료 절감 등의 효과를 기대할 수 있다.The putty composition according to the present invention has a specific gravity lower than that of the conventional epoxy putty, and when applied with a thickness of 1 mm, the weight reduction effect of 25 wt% of the total coat weight can be obtained, It is possible to expect the effect of reducing fuel consumption.
이하에서는 본 발명의 바람직한 실시예를 기초로 본 발명을 구체적으로 설명한다. 그러나 본 발명의 기술적 사상은 이에 한정되거나 제한되지 않고 당업자에 의해 변형되어 다양하게 실시될 수 있음은 물론이다.Hereinafter, the present invention will be described in detail based on preferred embodiments of the present invention. However, it should be understood that the technical spirit of the present invention is not limited thereto, and various modifications may be made by those skilled in the art.
본 발명의 실시예에 따른 퍼티 조성물은 하기 표 1과 같은 조성을 갖는다.The putty composition according to the embodiment of the present invention has the composition shown in Table 1 below.
(Fumed silica)Flowable additive
(Fumed silica)
(Bentonite Gel)Rheology
(Bentonite Gel)
(Fumed silica)Flowable additive
(Fumed silica)
(Bentonite Gel)Rheology
(Bentonite Gel)
이상과 같은 성분으로 각각 주제와 경화제를 공지의 퍼터용 교반기를 사용하여 배합하고 최종적으로 체질안료(extender pigment 4)를 투입한 후, 유동성 조정제(rheology agent)를 투입하여 점도를 85,000 ~ 105,000cps로 조정한 후, 교반 과정 중에서 혼입된 기포를 제거하는 탈포 공정을 실시하여 제조하였다.Each of the above components was mixed with a known hardener using a stirrer for putter, and finally extender pigment 4 was added thereto. Then, a rheology agent was added to adjust the viscosity to 85,000 to 105,000 cps Followed by a defoaming process for removing the bubbles entrained in the stirring process.
이와 같이 제조된 주제와 경화제를 혼합하여 도막을 형성한 후, 물성을 평가한 결과를 하기 표 2에 나타내었다. 측정방법은 한국 산업 규격(KS)을 인용하였으며, 한국 산업 규격(KS)에 측정 방법이 나와 있지 않는 경우에는 보편화되어 있는 측정 방법을 사용하였다.Table 2 shows the results of evaluating the physical properties of the coating film after mixing the thus prepared base with the curing agent. The measurement method cited the Korean Industrial Standard (KS) and the measurement method that is common is used when the measurement method is not described in the Korean Industrial Standard (KS).
상기 표 2에 나타나 있는 바와 같이, 본 발명의 실시예에 따른 퍼티의 경우, 비중이 1.25이므로 1㎜의 두께로 도장할 때, 기존의 에폭시 퍼티(비중이 1.6임)에 비해 약 25%의 중량이 감소한다. 이에 따라, 수직 하중이 감소하고 차량 운행시 연료가 절감될 수 있다.As shown in Table 2, in the case of the putty according to the embodiment of the present invention, since the specific gravity is 1.25, when the coating is applied to a thickness of 1 mm, the weight of the putty is about 25% of that of the conventional epoxy putty (specific gravity is 1.6) . As a result, the vertical load is reduced and the fuel can be saved when the vehicle is running.
또한, 고화 건조시간이 6시간 정도로 기존의 에폭시 퍼티의 건조시간인 20시간에 비해 현저하게 단축되므로, 본 발명에 따른 퍼티를 차량에 적용시 생산성이 크게 개선될 수 있다.In addition, since the solidification drying time is shortened to about 6 hours, compared with the drying time of the conventional epoxy putty of 20 hours, the productivity can be greatly improved when the putty according to the present invention is applied to a vehicle.
또한, 본 발명의 실시예에 따른 도막은 연성이 우수하여 1㎜ 도장 후, 180°벤딩시 도막의 박리가 나타나지 않았고, 내충격성에도 문제가 없다.Further, the coating film according to the embodiment of the present invention is excellent in ductility, so that peeling of the coating film does not occur at 180 ° bending after coating of 1 mm, and there is no problem in impact resistance.
또한, 외관 평가에 있어서도, 기존의 에폭시 퍼티와 대비할 때 차이가 없이 양호하였다.Also, in appearance evaluation, there was no difference when compared with existing epoxy putty.
Claims (6)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020080011025A KR100959344B1 (en) | 2008-02-04 | 2008-02-04 | Putty composition for rail train |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020080011025A KR100959344B1 (en) | 2008-02-04 | 2008-02-04 | Putty composition for rail train |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20090085232A KR20090085232A (en) | 2009-08-07 |
| KR100959344B1 true KR100959344B1 (en) | 2010-05-20 |
Family
ID=41205289
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020080011025A KR100959344B1 (en) | 2008-02-04 | 2008-02-04 | Putty composition for rail train |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR100959344B1 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101158469B1 (en) * | 2009-12-30 | 2012-06-19 | 이상신 | Method for preparation of non-toxic recyclable fire retardant putty with environmental friendly properties |
| KR101383193B1 (en) * | 2012-08-13 | 2014-04-09 | 건설화학공업주식회사 | Unsaturated polyester putty composition of two liquid type having a good grinding property |
| KR102259894B1 (en) * | 2019-04-01 | 2021-06-03 | 신정은 | Putty and method of construction using the same |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100594508B1 (en) * | 2006-03-25 | 2006-06-30 | (주)콘스코 | Reinforcing methods using as silane modified epoxy composition for underwater structure |
-
2008
- 2008-02-04 KR KR1020080011025A patent/KR100959344B1/en active IP Right Grant
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100594508B1 (en) * | 2006-03-25 | 2006-06-30 | (주)콘스코 | Reinforcing methods using as silane modified epoxy composition for underwater structure |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20090085232A (en) | 2009-08-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR100873048B1 (en) | Solvent free epoxy paint composition for flooring system and construction method using same | |
| CN101619201B (en) | Underwater epoxy adhesive and preparation method thereof | |
| CN111794548B (en) | Reinforced concrete crack-following coating system and anti-corrosion application thereof | |
| CN105295702A (en) | Elastic coating and preparation method thereof | |
| CN109439185B (en) | Multifunctional camouflage paint and preparation method thereof | |
| KR100959344B1 (en) | Putty composition for rail train | |
| KR101392471B1 (en) | Eco-functional compositions of primer paint having two component type and the method of producing the same | |
| CN107879668A (en) | A kind of cracking resistance epoxy resin mortar for expansion joint Rapid-Repair and preparation method thereof | |
| KR101046212B1 (en) | Solvent-free epoxy paint composition for floor finish and andconstruction method using thereof | |
| CN113512335A (en) | Water-based paint composition for cold chain container | |
| CN105778704A (en) | Flexible impasto solvent-free epoxy coal tar pitch paint and manufacture method thereof | |
| CN111205717A (en) | High-hardness silver flashing baking paint and preparation method thereof | |
| CN106634754A (en) | Building sealing glue and preparation method thereof | |
| KR0145117B1 (en) | Epoxy resin mortar | |
| KR101383193B1 (en) | Unsaturated polyester putty composition of two liquid type having a good grinding property | |
| CN109929446B (en) | Solvent-free epoxy coal tar pitch anticorrosive paint and manufacturing method thereof | |
| CN110577764B (en) | Solvent-free epoxy resin putty capable of being thickly coated on inner and outer decks of ships and inner walls of cabins | |
| CN106009523A (en) | Joint beautifying agent for ceramic tile joint treatment and decoration | |
| CN109486398A (en) | A kind of painting dressing automobiles paint and preparation method thereof | |
| CN112322144B (en) | High molecular resin water-proof anticorrosive paint and its preparation method | |
| EP2627456B1 (en) | Lightweight terrazzo surface composition | |
| KR20180007611A (en) | Coating Machine for Mark of Road | |
| KR101316649B1 (en) | Nanosized ceramic coating steel | |
| KR100965548B1 (en) | Polyol resin composition for nonsolvent polyurethane coating material, manufacturing method thereof, nonsolvent polyurethane coating material, and construction method using thereof | |
| CN113717568B (en) | Solvent-resistant mud yellow eye-filling ash and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| E902 | Notification of reason for refusal | ||
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant | ||
| FPAY | Annual fee payment |
Payment date: 20130415 Year of fee payment: 4 |
|
| FPAY | Annual fee payment |
Payment date: 20140416 Year of fee payment: 5 |
|
| FPAY | Annual fee payment |
Payment date: 20150429 Year of fee payment: 6 |
|
| FPAY | Annual fee payment |
Payment date: 20160428 Year of fee payment: 7 |
|
| FPAY | Annual fee payment |
Payment date: 20170427 Year of fee payment: 8 |
|
| FPAY | Annual fee payment |
Payment date: 20180425 Year of fee payment: 9 |
|
| FPAY | Annual fee payment |
Payment date: 20190425 Year of fee payment: 10 |