KR100952490B1 - Citric ester based plasticizer composition for polyvinyl chloride - Google Patents

Abstract

The present invention relates to a novel citric acid ester plasticizer composition for polyvinyl chloride resin, and more particularly, to a polyvinyl chloride resin plasticizer composition comprising two or more compounds selected from citric acid ester compounds represented by the following general formula (1). The plasticizer composition according to the present invention may be used as a plasticizer of polyvinyl chloride resin, and thus may be processed into a polyvinyl chloride resin having excellent sheet heating loss, migration resistance, static heat resistance, transparency, adhesiveness, tensile strength and elongation. .

[Formula 1]

In Formula 1, R ₁ , R ₂ and R ₃ are the same as or different from each other and are a linear or pulverized alkyl group having 4 to 10 carbon atoms.

 Polyvinyl chloride resin, citric acid, ester, plasticizer

Description

Citric ester based plasticizer composition for polyvinyl chloride resin

The present invention relates to a novel multicomponent citric acid ester plasticizer composition, and in particular, it is used as a plasticizer for polyvinyl chloride resin, and has excellent sheet heating loss, migration resistance, static heat resistance, transparency, adhesion, tensile strength and elongation. A citric acid ester plasticizer composition that can be processed into a polyvinyl chloride resin having properties.

Polyvinyl chloride resin (PVC) is a general-purpose resin capable of imparting various processing properties by appropriately mixing various additives such as plasticizers, stabilizers, fillers, pigments, and the like. Using these various processing properties, polyvinyl chloride resin is widely used in various products as a material from film, hose, pipe, electric wire, artificial leather to wallpaper, gloves and toys.

In particular, the plasticizer is a compound consisting of a polar portion and a nonpolar portion, and is generally a compound of an aliphatic acid such as phthalic acid or trimellitic acid or an aliphatic acid such as adipic acid, and an alcohol such as 2-ethylhexanol, n-butanol or isononylol. It is prepared by esterification reaction. These plasticizers are added to the polyvinyl chloride resin to lower the melting temperature and melt viscosity to improve workability. In addition, flexibility, electrical insulation, sheet heating loss, migration resistance, static heat resistance, transparency, adhesion, tensile strength and It serves as an essential additive that imparts various properties and functions such as elongation.

Typical plasticizers used for processing polyvinyl chloride resins include phthalates and dioctyl adipates (DOA) such as dioctyl phthalate (DOP), dibutyl phthalate (DBP) and diisononyl phthalate (DINP). , Adipates such as diisononyl adipate (DINA), and adipates such as trimellitates, and the most widely used plasticizers are phthalate di 2-ethylhexyl phthalate ( DEHP), which serves as a standard plasticizer for evaluating the performance of other plasticizers.

However, with the improvement of living standards and the rapid development of the food industry, regulations on plasticizers as a direct contact with food are increasingly expanded. In particular, the phthalate plasticizers are defined as endocrine disruptors in Japan, the United States, etc. In 2004, the use of phthalate plasticizers was banned in children's products in Europe, and the Ministry of Environment of Korea phthalate plasticizers And there is a movement to designate as a restricted material, there is a lot of controversy regarding the safety and toxicity of phthalate plasticizers at home and abroad. Therefore, the development of environment-friendly non-phthalate plasticizers is urgently avoided and the controversy of stability of phthalate plasticizers is urgent.

Eco-friendly plasticizers include neopentylglycol ester (Korean Patent No. 0385731), trimethylolpropane ester (Korean Patent No. 2002-0057559), diethylene glycol ester (Korean Patent No. 2005-0026178), dipropylene Glycol esters (Korean Patent No. 2006-0097587), triethylene glycol esters (Korean Patent No. 2006-0108210), and the like have already been disclosed. However, the plasticizers are inferior in process properties compared to conventional plasticizers (such as di 2-ethylhexyl phthalate), which are currently commercialized, and have a disadvantage in that compatibility with polyvinyl chloride resin is insufficient in plastisol processing. In addition, triethanol methane ester is a plasticizer having excellent physical properties compared to trimethylolpropane ester and other plasticizers, and trimethylolpropane ester has been known to be inferior in physical properties, and the single-component ester is weak in order to act as a plasticizer. In many cases, it is difficult to expect excellent physical properties, and even a case of incompatibility with the polyvinyl chloride resin occurs at all (US Pat. No. 3,939,201).

The present invention aims to provide an environment-friendly nonphthalate plasticizer composition as a plasticizer composition for polyvinyl chloride resin.

In addition, an object of the present invention is to provide a polyvinyl chloride resin including the plasticizer composition and excellent in physical properties such as sheet heating loss, migration resistance, static heat resistance, transparency, adhesion, tensile strength and elongation.

The present invention can solve the above problems by providing a plasticizer composition for polyvinyl chloride resin comprising two or more compounds selected from citric acid ester compounds represented by the following formula (1).

In Formula 1, R ₁ , R _2, and R ₃ are the same as or different from each other, and are a linear or pulverized alkyl group having 4 to 10 carbon atoms.

In addition, the present invention provides a polyvinyl chloride resin comprising the citric acid ester plasticizer composition.

The plasticizer composition for polyvinyl chloride resin containing the citric acid ester according to the present invention can be processed into a polyvinyl chloride resin excellent in sheet heating loss, migration resistance, static heat resistance, transparency, adhesion, tensile strength and elongation, etc. Has an effect.

In addition, the polyvinyl chloride resin according to the present invention can be very usefully applied to processed products containing the polyvinyl chloride resin.

The present invention has a technical feature in the plasticizer composition for polyvinyl chloride resin comprising at least two compounds selected from citric acid ester compounds represented by the formula (1).

In particular, the present invention relates to a) 2- (acetyloxy) -propane-tri- (2-ethylhexyl) ester, b) 2- (acetyloxy) -propane-tri-butylester, c) 2- (acetyloxy) Propane-2-butyl-1,3-bis (2-ethylhexyl) ester, d) 2- (acetyloxy) -propane-1,2-dibutyl-3- (2-ethylhexyl) ester, e) 2- (acetyloxy) -propane-1,3-dibutyl-2- (2-ethylhexyl) ester, and f) 2- (acetyloxy) -propane-1-butyl-2,3-bis (2- Two or more compounds selected from ethylhexyl) esters. That is, the six different esters are citric acid ester compounds represented by Chemical Formula 1.

As citric acid ester plasticizer composition, Korean Patent Publication No. 2004-0102064 discloses a plasticizer for biodegradable aliphatic polyester resin and a biodegradable resin composition. The object of the present invention is to improve the biodegradability of the resin, and it is described that the plasticizer of Chemical Formula 1 may be used as a plasticizer necessarily added to a biodegradable polyester resin. In addition, in the disclosed invention, only 20 to 30 parts by weight of the plasticizer is limited to 100 parts by weight of the biodegradable polyester resin, which is insufficient in water resistance when a large amount of the plasticizer is added to the surface of the molded article. This is because it is easy to bleed out, which causes a problem of lowering the biodegradability of the excellent biodegradable polyester resin.

However, in the present invention, in order to impart excellent sheet heating loss, migration resistance, static heat resistance, transparency, adhesiveness, tensile strength and elongation properties to the conventional polyvinyl chloride resin, two or more alcohols must be synthesized to the general formula (1). It is a technical feature to provide the plasticizer composition for polyvinyl chloride resins containing the citric acid-type ester compound shown. In particular, the plasticizer composition according to the present invention may be contained in 40 to 80 parts by weight with respect to 100 parts by weight of the polyvinyl chloride resin, it is preferable to include a plasticizer composition of the above range content so that the plasticization properties are sufficiently exhibited.

Accordingly, the known technology is completely different from the present invention because the purpose, use, configuration and content range of the plasticizer composition required are completely different from the present invention.

Hereinafter, the present invention will be described in more detail.

In Formula 1, R ₁ , R ₂ and R ₃ are the same as or different from each other, a straight chain or crushed alkyl group having 4 to 10 carbon atoms, the plasticizer composition of the present invention is citric acid, acetic anhydride and 4 to 4 carbon atoms It is prepared by synthesizing two or more alcohols selected from ten alcohols. At this time, when using only a single component of the alcohol in the alcohol to prepare a single component of the ester, in the case of such a single component of the plasticizer to play a role as a plasticizer there are many parts that can not obtain excellent physical properties, even Also occurs when there is no compatibility with the polyvinyl chloride resin (US Pat. No. 3,939,201).

Therefore, the plasticizer composition of the formula (1) using two or more alcohols necessarily is a novel plasticizer composition used for polyvinyl chloride resin.

Particularly, each of R ₁ , R ₂ and R ₃ is an alkyl group selected from 4 to 10 carbon atoms, and the alcohol used in the present invention may be any one selected from among 4 to 10 carbon atoms. If it is too large, the elongation and oil absorption force is lowered, the hardness is high. Therefore, in the present invention, n-butanol, pentanol, hexanol, heptanol, n-octanol, 2-octanol, 6-methyl-2-heptanol, 4-methyl-3-heptanol, 2,4,4 Two or more alcohols selected from -trimethylpentanol, 2-propylpentanol and 2-ethylhexanol can be used more preferably. More preferably, n-butanol and 2-ethylhexanol may be used, which is competitive in cost and excellent in properties such as heating loss, elongation, migration resistance, transparency, etc. when applied as a plasticizer. Thus, R ₁ , R ₂ , and R ₃ are each n-butyl, pentyl, hexyl, heptyl, n-octyl, 2-octyl, 6-methyl-2-heptyl, 4-methyl-3-heptyl, 2,4 , 4-trimethylpentyl, 2-propylpentyl and 2-ethylhexyl.

In addition, in the plasticizer composition comprising the citric acid ester compound according to the present invention, when using a single-component alcohol, for example, when only n-butanol is used, it is excellent in compatibility with polyvinyl chloride resin There is a problem that the planet, tensile strength and elongation are reduced, and when only 2-ethylhexanol is used, the hardness of the polyvinyl chloride resin is high, and the compatibility is poor. Therefore, there is necessarily a technical feature in producing a plasticizer composition using two or more kinds of alcohols. In particular, the two or more kinds of alcohols may be preferably used as mixed alcohols of n-butanol / 2-ethylhexanol.

On the other hand, the plasticizer composition containing the multicomponent citric acid ester compound also exhibits different physical properties depending on the type of alcohol and carboxylic acid used. For example, a plasticizer composition comprising a multicomponent citric acid ester compound prepared by synthesizing ethanol and isodecanol as a raw material has a problem in that it has excellent migration resistance but is poor in oil absorption and plasticity, and has high hardness.

As described above, the single component citric acid ester plasticizer composition as well as the multicomponent citric acid ester plasticizer composition are compatible with polyvinyl chloride resin, sheet heating loss, migration resistance, static heat resistance, transparency, adhesiveness, tensile strength and elongation. Since it is difficult to supplement all the physical properties of the back, it is very important to selectively synthesize the acid and alcohol of the appropriate composition. Accordingly, the ester mixture of the present invention prepares a multicomponent citric acid ester plasticizer composition with a suitable composition as described above using, as a raw material, two or more kinds of alcohols described above in an appropriate acid and alcohol, that is, citric acid and acetic anhydride.

In addition, the plasticizer composition of the present invention comprises the above six different citric acid ester compounds, their content is a) 2- (acetyloxy) -propane-tri- (2-ethylhexyl) ester 1 to 30 % By weight, b) 5--25% by weight of 2- (acetyloxy) -propane-tri-butylester, c) 2- (acetyloxy) -propane-2-butyl-1,3-bis (2-ethylhexyl) 5-30% by weight of ester, d) 2- (acetyloxy) -propane-1,2-dibutyl-3- (2-ethylhexyl) ester 5-30% by weight, e) 2- (acetyloxy) -propane 3-30 wt% of -1,3-dibutyl-2- (2-ethylhexyl) ester, and f) 2- (acetyloxy) -propane-1-butyl-2,3-bis (2-ethylhexyl) It may be included in 10 to 40% by weight ester.

The plasticizer composition comprising the citric acid-based ester compound of the present invention can be prepared using a method generally carried out in the art, the method is not particularly limited, but may be prepared by the following method. Specifically, the plasticizer composition is based on 1 mol of citric acid, 1 to 1.5 mol ratio of acetic anhydride, 3 to 6 mol ratio of two or more alcohols selected from alcohols of 4 to 10 carbon atoms, 0.001 to 0.10 mol ratio of catalyst and 0.1 to 2.0 mol ratio of entraining materials. After mixing, it may be prepared by reacting for 2 to 8 hours at 100 ~ 200 ℃.

In particular, more preferably, 0.9 to 2.5 molar ratio of n-butanol, 0.9 to 2.5 molar ratio of 2-ethylhexanol, 0.7 to 1.4 molar ratio of cyclohexane, which is an entrained material, and 0.001 to 0.01 molar ratio of dimethyl sulfate, which are catalysts, are mixed with 1 mole of citric acid. Can be prepared. At this time, when the reaction temperature is less than 100 ℃ or the reaction time is less than 2 hours, there is a lot of unreacted, a problem of yield reduction occurs, and when the reaction temperature exceeds 200 ℃ or the reaction time exceeds 8 hours citric acid Since decomposition of the plasticizer causes a problem of deterioration due to discoloration of the plasticizer, it is preferable to react at the above temperature and time conditions.

The reactant is neutralized with sodium carbonate (Na ₂ CO ₃ ), washed with neutralized reactant, depressurized and dehydrated to decolorize the reactant to remove water, and then a conventional adsorbent such as diatomaceous earth is added and filtered. The plasticizer composition containing the final citric acid ester compound can be obtained through.

The present invention also provides a polyvinyl chloride (PVC) resin comprising the plasticizer composition according to the present invention. The plasticizer composition according to the present invention may be contained in an amount of 40 to 80 parts by weight based on 100 parts by weight of polyvinyl chloride resin, and when the content of the plasticizer composition is less than 40 parts by weight, the content of the plasticizer may be low, indicating sufficient plasticizing power. The problem may occur, and if it exceeds 80 parts by weight, it may be a problem that the amount of transition of the plasticizer to the polyvinyl chloride resin surface may increase, so it is preferable to include the plasticizer composition in the above range. PVC resin using the plasticizer containing the citric acid ester compound of the present invention is excellent in sheet heating loss, transition resistance, static heat resistance, transparency, adhesiveness, tensile strength and elongation is suitable for application to processed products such as food packaging wraps .

The present invention will be described in more detail with reference to Examples, but the present invention is not limited by the following Examples.

Example 1

Preparation of Citric Acid Ester Plasticizer Compositions

288.2 g (1.5 moles) of citric acid, 191.78 g (2.58 moles) of n-butanol, 336.97 g (2.58 moles) of 2-ethylhexanol, 105 g of cyclohexane as a splash material and 1.44 g of catalyst dimethylsulfate were mixed with a stirrer and a thermometer, After the reaction was performed at 140 ° C. for 4 hours using a flask equipped with a generator for removing water, unreacted acid and cyclohexane were removed under reduced pressure. 176.1 g of acetic anhydride (1.73 mol) and 1.44 g of dimethyl sulfate as a catalyst are added dropwise, and further reacted at 105 ° C. for about 3 hours. Next, after neutralizing with 10.26 g of sodium carbonate (Na ₂ CO ₃ ), after washing with water, dehydrating and decolorizing, diatomaceous earth was added to an adsorbent and filtered to obtain a citric acid-based plasticizer composition of the present invention.

The composition of the produced citric acid ester plasticizer was gas chromatography (GC) analysis, and a) 2- (acetyloxy) -propane-tri- (2-ethylhexyl) ester 9.4 wt%, b) 2- ( 11.3 wt% acetyloxy) -propane-tri-butyl ester, c) 12.5 wt% of 2- (acetyloxy) -propane-2-butyl-1,3-bis (2-ethylhexyl) ester, d) 2- ( Acetyloxy) -propane-1,2-dibutyl-3- (2-ethylhexyl) ester 25.6 wt%, e) 2- (acetyloxy) -propane-1,3-dibutyl-2- (2-ethyl Hexyl) ester 16.5% by weight, and f) 2- (acetyloxy) -propane-1-butyl-2,3-bis (2-ethylhexyl) ester 24.7% by weight, the results are shown in Figure 1 As shown.

Preparation of Polyvinyl Chloride Resin

In order to measure the physical properties of the citric acid-based plasticizer obtained in the step as a plasticizer, a specimen was prepared by referring to ASTM D638. 60 parts by weight of the plasticizer of the present invention and 3 parts by weight of a calcium-zinc stabilizer (LTX-630, Korea Daehyup) were mixed with 100 parts by weight of polyvinyl chloride resin (LS-100, LG Chemical) using a Haake Mixer. Press work was performed by using a hot press at 180 ℃ for 3 minutes preheating, heating for 3 minutes, and then made a polyvinyl chloride sheet of 3 mm thickness, to prepare a plurality of dumbbell-type specimens of type C type, and measured physical properties The results are shown in Table 1 and Table 2.

Example  2

Example 1 was carried out in the same manner as in Example 1 except that 288.2 g (1.5 mol) of citric acid, 277.3 g (3.73 mol) of n-butanol, and 186.8 g (1.43 mol) of 2-ethylhexanol were used. A citric acid plasticizer composition was obtained, and a polyvinyl chloride sheet was prepared to measure physical properties, and the results are shown in Tables 1 and 2.

The composition of the prepared citric acid ester plasticizer was gas chromatography (GC) analysis, and a) 2- (acetyloxy) -propane-tri- (2-ethylhexyl) ester 21.3 wt%, b) 2- ( Acetyloxy) -propane-tri-butyl ester 6.2% by weight, c) 2- (acetyloxy) -propane-2-butyl-1,3-bis (2-ethylhexyl) ester 28.4% by weight, d) 2- ( 6.4% by weight of acetyloxy) -propane-1,2-dibutyl-3- (2-ethylhexyl) ester, e) 2- (acetyloxy) -propane-1,3-dibutyl-2- (2-ethyl Hexyl) ester 4.5% by weight, and f) 2- (acetyloxy) -propane-1-butyl-2,3-bis (2-ethylhexyl) ester was found to be 33.2% by weight.

Example 3

Citric acid was carried out in the same manner as in Example 1, except that 288.2 g (1.5 mol) of citric acid, 487.2 g (3.73 mol) of 2-ethylhexanol, and 106.3 g (1.43 mol) of n-butanol were used in Example 1 The plasticizer composition was obtained, and a polyvinyl chloride sheet was prepared to measure physical properties, and the results are shown in Tables 1 and 2.

The composition of the citric acid-based plasticizer prepared was gas chromatography (GC) analysis, and a) 3.4 wt% of 2- (acetyloxy) -propane-tri- (2-ethylhexyl) ester, b) 2- ( Acetyloxy) -propane-tri-butyl ester 24.7 wt%, c) 2- (acetyloxy) -propane-2-butyl-1,3-bis (2-ethylhexyl) ester 9.5 wt%, d) 2- ( Acetyloxy) -propane-1,2-dibutyl-3- (2-ethylhexyl) ester 26.4 wt%, e) 2- (acetyloxy) -propane-1,3-dibutyl-2- (2-ethyl Hexyl) ester 24.8 wt%, and f) 2- (acetyloxy) -propane-1-butyl-2,3-bis (2-ethylhexyl) ester 11.2 wt%.

Example 4

Citric acid-based plasticizer was carried out in the same manner as in Example 1 except for using 288.2 g (1.5 mol) of citric acid, 372.2 g (2.58 mol) of isononyl alcohol, and 191.2 g (2.58 mol) of n-butanol. The composition was obtained, and a polyvinyl chloride sheet was prepared to measure physical properties, and the results are shown in Tables 1 and 2.

The composition of the citric acid-based plasticizer prepared by gas chromatography (GC) analysis showed that a) 2- (acetyloxy) -propane-tri-isononyl ester 10.2% by weight, b) 2- (acetyloxy)- Propane-tri-butyl ester 12.6 wt%, c) 2- (acetyloxy) -propane-2-butyl-1,3-diisononyl ester 11.5 wt%, d) 2- (acetyloxy) -propane-1, 27.3 weight percent 2-dibutyl-3-isononyl ester, e) 13.8 weight percent 2- (acetyloxy) -propane-1,3-dibutyl-2-isononyl ester, and f) 2- (acetyloxy) It was confirmed that it was 24.6% by weight of propane-1-butyl-2,3-diisononyl ester.

Example 5

Citric acid system was carried out in the same manner as in Example 1 except that 288.2 g (1.5 mol) of citric acid, 336.0 g (2.58 mol) of n-octanol, and 106.3 g (2.58 mol) of n-butanol were used in Example 1 A plasticizer composition was obtained, and a polyvinyl chloride sheet was prepared to measure physical properties, and the results are shown in Tables 1 and 2.

The composition of the citric acid-based plasticizer prepared by gas chromatography (GC) analysis showed that a) 2- (acetyloxy) -propane-tri-octyl ester 11.3 wt%, b) 2- (acetyloxy) -propane 14.2 wt% tri-butyl ester, c) 10.6 wt% 2- (acetyloxy) -propane-2-butyl-1,3-dioctyl ester, d) 2- (acetyloxy) -propane-1,2- 23.5 wt% dibutyl-3-octyl ester, e) 18.3 wt% 2- (acetyloxy) -propane-1,3-dibutyl-2-octyl ester, and f) 2- (acetyloxy) -propane-1 It was confirmed that it was 22.1 weight% of -butyl-2,3-dioctyl ester.

Comparative example  One

A citric acid-based plasticizer composition was obtained in the same manner as in Example 1 except that 288.2 g (1.5 mol) of citric acid and 383.6 g (5.18 mol) of n-butanol were used in Example 1, and a polyvinyl chloride sheet was prepared. The physical properties were measured and the results are shown in Table 1 and Table 2.

The composition of the produced citric acid ester plasticizer was confirmed by gas chromatography (GC, gas chromatography) analysis, 100% by weight of 2- (acetyloxy) -propane-tri-butyl ester.

Comparative example  2

A citric acid-based plasticizer composition was obtained in the same manner as in Example 1 except that 288.2 g (1.5 mol) of citric acid and 674.0 g (5.18 mol) of 2-ethylhexanol were used in Example 1, and a polyvinyl chloride sheet was obtained. Was prepared to measure the physical properties and the results are shown in Table 1 and Table 2.

The composition of the produced citric acid ester plasticizer was confirmed by gas chromatography (GC, gas chromatography) analysis, 100% by weight of 2- (acetyloxy) -propane-tri- (2-ethylhexyl) ester.

Comparative example  3

Using polyvinyl chloride compound (DOA), an adipate-based plasticizer used in food packaging wraps, polyvinyl chloride compounds were prepared according to the method of Example 1 and measured for physical properties. Shown in

Comparative example  4

Using LGFlex EBN (LG Chemical, Korean Patent No. 10-0385731), a plasticizer currently used in food packaging, polyvinyl chloride compounds were prepared according to the method of Example 1 and the physical properties were measured and the results are shown. 1 and Table 2.

Comparative example  5

Using Citrocizer A (Aekyung Emulsification), a citric acid plasticizer currently used in food packaging, polyvinyl chloride compounds were prepared according to the method of Example 1, and the physical properties thereof were shown in Table 1 and Table 2. .

Comparative example  6

In general, polyvinyl chloride compounds were prepared according to the method of Example 1 using DEHP (dioctyl phthalate, Dongyang Steel Chemical), the most widely used phthalate plasticizer, and the physical properties thereof were measured. Indicated.

Comparative example  7

Using a commercially available plasticizer LGFlex BET (LG Chemical, Korean Patent No. 10-0426229), according to the method of Example 1 to prepare a polyvinyl chloride compound and to measure the physical properties of the results Table 1 and Table 2 Shown in

Test Example 1: Processing Characteristics

Processability in preparing the polyvinyl chloride resin compound was determined using the torque value. The compound was manufactured using a Haake mixer, and the maximum torque value at the initial measurement and the torque value at the stabilized state after 10 minutes were measured at 160 ° C. and 40 rpm, and are shown in Table 1 below. At this time, the larger the maximum torque value means that the oil absorption is worse, the larger the equilibrium torque value means that the plasticity force is lowered.

Torque value (Nm) Equilibrium torque value (Nm) Example 1 8.09 4.39 Example 2 8.53 3.64 Example 3 7.46 3.76 Example 4 8.36 3.94 Example 5 8.34 3.53 Comparative Example 1 10.56 4.62 Comparative Example 2 5.75 4.42 Comparative Example 3 6.95 3.47 Comparative Example 4 8.88 3.82 Comparative Example 5 9.38 4.09 Comparative Example 6 6.15 3.86 Comparative Example 7 8.94 4.35

Test Example 2: Sheet Physical Properties

The polyvinyl chloride specimens prepared above are shown in Table 2 by specifying physical properties in the following manner.

1) Hardness : Shore A hardness, hardness test (C type) After the needle was completely lowered, the hardness value appeared after 3 seconds. After testing five places for each sheet specimen, the average value was shown.

2) Sheet heating loss : After maintaining the polyvinyl chloride sheet (5 cm × 5 cm) in an oven at 130 ℃ for 3 hours, stored in a constant temperature and humidity room for 4 hours or more and the weight change was measured according to the following equation (1) will be.

% Heat Loss = {(Initial Weight-Weight after Heating) / Initial Weight} × 100

3) Transition resistance : Polyvinyl chloride sheet (3 cm × 3 cm) was inserted between polystyrene (PS) plates in an oven at 80 ° C, and left for 48 hours under a 5 kg load. Then, the weight change is measured and calculated according to Equation 2 below.

Permeability (%) = {(Initial Weight-Weight after Heating) / Initial Weight} × 100

4) Static heat resistance : Put polyvinyl chloride sheet (2 cm × 2 cm) in the oven at 195 ℃, take out after 5 minutes, and measure the discoloration degree (ΔE, color difference) of L, a, b value using a colormeter It is calculated according to the following equation (3).

Static heat resistance (ΔE) = [(L _o -L) ² + (a _o -a) ² + (b _o -b) ² ] ^1/2

5) Transparency : The transmittance was measured using a Haze meter.

6) Adhesiveness: The degree of adhesiveness was directly compared by direct contact with hands. When the adhesiveness was very excellent, it was evaluated as 5, normal 3, and poor 1.

7) Tensile strength and elongation : After cutting the specimen into type C type according to ASTM D 638 method, using UTM (universal testing machine), pull the crosshead speed at the speed of 500 mm / min, and then cut the specimen. The strength and elongation at is calculated according to Equation 3 below.

Tensile strength = load value at break (kg _f ) / {thickness (cm) × width (cm)}

Elongation = {length at break / initial length} × 100

division Hardness (shore A) Sheet heating loss (%) Tolerance (%) Static heat resistance (△ E) Transparency (%) Sticky Tensile Strength (Kg _f / cm ² ) Elongation (%) Example 1 74 0.80 3.89 1.57 89.7 4 167.9 403 Example 2 73 1.04 4.64 1.62 88.9 5 164.6 394 Example 3 74 0.75 2.85 1.59 88.4 4 170.1 412 Example 4 73 0.79 2.65 2.65 88.7 4 174.5 385 Example 5 73 0.87 3.94 1.62 89.4 5 176.4 416 Comparative Example 1 76 4.39 5.19 7.24 87.2 3 164.2 379 Comparative Example 2 77 2.42 4.86 4.52 87.2 3 146.3 383 Comparative Example 3 75 2.13 9.48 5.99 88.0 2 139.4 375 Comparative Example 4 73 1.91 12.31 6.24 87.6 4 139.3 382 Comparative Example 5 76 4.48 5.27 7.50 86.9 3 162.4 372 Comparative Example 6 74 2.15 4.73 2.86 87.7 3 158.4 387 Comparative Example 7 74 2.08 9.86 5.89 87.4 4 148.7 368

As shown in Table 1, in Examples 1 to 5 prepared by adding the citric acid-based plasticizer according to the present invention to the polyvinyl chloride resin, plasticizers (comparative examples 1 to 2, 4 to 3) that were used in the conventional food packaging wraps Compared with 5 and 7), it was confirmed that the oil absorption or plasticity showing the processing characteristics of the plasticizer is excellent. However, in the case of the plasticizers of Comparative Examples 3 (DOA) and 6 (DEHP), which are adipate- and phthalate-based plasticizers, compared to citric acid-based plasticizers according to the present invention, although the oil absorption and plasticity are somewhat superior, endocrine system disorders There are drawbacks to environmental regulations, including substances.

In addition, as shown in Table 2, in the case of Examples 1 to 5 prepared by adding the citric acid-based plasticizer according to the present invention to the polyvinyl chloride resin (Comparative Examples 1 to 7) Compared with these, it was confirmed that the properties of heat loss, migration resistance, static heat resistance, transparency, adhesion, tensile strength and elongation are very excellent.

In particular, it was confirmed that the physical properties such as adhesion, tensile strength, elongation required for the physical properties of the packaging wraps are very excellent. In addition, in the case of including the plasticizers of Comparative Example 1 and Comparative Example 2 prepared using only one type of alcohol, it was found that the hardness is higher and the plasticity is lower than that of the Examples of the present invention.

Therefore, when the citric acid-based plasticizer according to the present invention is added to a polyvinyl chloride resin, it has excellent physical properties compared to conventional plasticizers without including endocrine-based obstacles such as adipate-based or phthalate-based plasticizers. I could confirm that there is.

1 shows gas chromatography data of citric acid-based plasticizer prepared according to Example 1. FIG.

Claims (7)

delete delete delete a) 1 to 30% by weight of 2- (acetyloxy) -propane-tri- (2-ethylhexyl) ester, b) 5-25 wt% of 2- (acetyloxy) -propane-tri-butyl ester, c) 5-30% by weight of 2- (acetyloxy) -propane-2-butyl-1,3-bis (2-ethylhexyl) ester, d) 5-30% by weight of 2- (acetyloxy) -propane-1,2-dibutyl-3- (2-ethylhexyl) ester, e) 3 to 30% by weight of 2- (acetyloxy) -propane-1,3-dibutyl-2- (2-ethylhexyl) ester, and f) 10 to 40% by weight of 2- (acetyloxy) -propane-1-butyl-2,3-bis (2-ethylhexyl) ester Plasticizer composition for polyvinyl chloride resin, characterized in that comprises a. delete 100 parts by weight of polyvinyl chloride (PVC) resin, and Polyvinyl chloride (PVC) resin comprising 40 to 80 parts by weight of the plasticizer composition of claim 4. delete

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