KR100901430B1 - The natural resin composite containing charcoal and method of manufacturing the same - Google Patents

Abstract

A method for manufacturing a natural resin composition is provided to ensure deodorization, negative ion and far-infrared radiation, anti-fungi function, indoor humidity control, effect of intercepting electromagnetic waves and water veins, atopy prevention effect and anti-aging effect. A method for manufacturing a natural resin composition containing charcoal comprises the steps of: heating linseed oil 10-30 parts by weight, tung oil 10-30 parts by weight and rosin 10-30 parts by weight under a nitrogen atmosphere to prepare natural resin; adding D-limonene 5-10 parts by weight and at least one selected form the group consisting of zirconium and diepentene as a first additive to the natural resin in order to prepare the diluted natural resin; and after adding charcoal to the diluted natural resin and mixing them at 1000-1200 rpm for 1-3 hours, mixing hollow filler 30-90 parts by weight, Kelzyme 30-40 parts by weight, porous mineral 30-40 parts by weight, ground calcium carbonate, 30-40 parts by weight and elvan 30-40 parts by weight for 30 minutes - 2 hours and adding water 35-50 parts by weight and at least one 20-35 parts by weight selected form the group consisting of xanthane gum sodium carbonate as a second additive.

Description

The natural resin composite containing charcoal and method of manufacturing the same}

The present invention relates to a method for producing a natural resin composition containing charcoal and a composition therefrom, and more particularly, it is possible to provide a charcoal paint harmless to the human body using natural resins and charcoal, seaweed (Kelzyme), deodorization, anion Method of producing natural resin composition containing charcoal, which can create a pleasant indoor environment, provide atopy prevention effect and anti-aging effect, because it has the effect of preventing divergence, far-infrared radiation, antifungal, indoor humidity control, water vein and electromagnetic wave And a composition by the composition thereby.

In modern society, due to economic development, conventional building paints have been used irrespective of the harmfulness of their components, as long as their function can be fulfilled. In recent years, the seriousness of environmental problems has emerged, and the movement to limit construction paints has been activated. In the conventional building paints, when polluting the environment, a lot of harmful substances are released.

In addition, these days, sick house syndrome has become a serious social problem, people suffering from sick house syndrome has symptoms such as itching, dizziness, headache, skin problems, and varies depending on the individual.

The exact cause of the sick house syndrome is difficult to determine, but volatile substances in the building are considered to be the main causes, such as formaldehyde (HCHO) and volatile organic compounds (VOC's).

These harmful substances are generated from new wallpaper or floor coverings and are known to last for about six months to two years.

It is known that toxic chlorine gas is also released in such buildings, and formaldehyde is also released, which is widely used in preservatives, adhesives, and plywood, and is known as a carcinogen that adversely affects the nervous system and organs.

On the other hand, negative ions are known to be beneficial to the human body, and products that generate negative ions have been researched and developed in order to utilize them in improving the environment. However, many products that focus on negative ions have limited roles as environmental materials and also negatively generate negative ions. Most of the generators inevitably generate free radicals due to the principle of negative ion generation, and free radicals are recognized as health inhibitors that cause immunodeficiency and leukemia. Also, electromagnetic waves generated by generators are neo-pollutants and appear as serious health obstacles. There is a situation.

There is an urgent need for the development of building materials to solve these problems.

In addition, as the standard of living improves as income increases, the consumer's desire for high-quality residential space increases, and an attempt to make a healthier and more comfortable residential space by applying health materials beneficial to the human body to building materials is in progress.

Therefore, the first technical problem to be solved by the present invention is to provide a charcoal paint harmless to the human body using natural resins and charcoal, algae (Kelzyme) and deodorization, anion divergence, far infrared divergence, antifungal properties, indoor humidity control, water vein And because it has the effect of blocking the electromagnetic waves to provide a method for producing a natural resin composition containing charcoal that can create a comfortable indoor environment and impart atopy prevention effect and anti-aging effect.

In addition, the second technical problem to be solved by the present invention is to provide a charcoal paint harmless to the human body using natural resins and charcoal, algae (Kelzyme), deodorization, anion emission, far infrared emission, anti-fungal properties, indoor humidity control, Since it has an effect of blocking water vein and electromagnetic waves, it is to provide a natural resin composition containing charcoal which can create a pleasant indoor environment and impart atopy prevention effect and anti-aging effect.

The present invention to achieve the first technical problem described above,

10 to 30 parts by weight of linseed oil, 10 to 30 parts by weight of tung oil and 10 to 30 parts by weight of rosin in a nitrogen (N2) atmosphere to prepare a natural resin (step S1) And, by adding 5 to 10 parts by weight of the plant (D-Limonene) and the first additive to the natural resin to prepare a diluted natural resin (S2 step) and to the charcoal to the diluted natural resin 1 to 3 Stir at 1000 to 1200 rpm for 30 hours, hollow pillars 30 to 90 parts by weight, seaweed (Kelzyme) 30 to 40 parts by weight, porous minerals 30 to 40 parts by weight, bicarbonate 30 to 40 parts by weight and elvan 30 to 40 parts by weight Injecting the mixture for 30 minutes to 2 hours, and adding 35 to 50 parts by weight of water and 20 to 35 parts by weight of the second additive is uniformly mixed for 20 minutes to 1 hour (S3 step), characterized in that Of natural resin composition containing charcoal To provide a crude method.

According to one embodiment of the present invention, the heating temperature in step S1 may be 210 to 260 ℃.

According to another embodiment of the present invention, the heating time in step S1 may be 10 to 20 hours.

According to another embodiment of the present invention, the hollow filler is a polyacrylonitrile coated with calcium carbonate and titanium dioxide, the size of which may be 10 to 40㎛.

According to another embodiment of the present invention, the porous mineral may be a diatomaceous earth mainly composed of porous silicon dioxide.

According to another embodiment of the present invention, the nitrogen may be supplied at an amount and rate of 0.01 to 0.04 ft ³ / min / gal.

According to another embodiment of the present invention, the size of the elvan can be 5 to 20㎛

According to another embodiment of the present invention, the charcoal may be at least one selected from the group consisting of bamboo charcoal, oak charcoal and red pine charcoal.

According to another embodiment of the present invention, the char may have an average particle size of 20 to 40 μm.

The present invention to achieve the above-described second technical problem,

It provides a natural aqueous coating composition prepared by the above-described manufacturing method.

It is possible to provide a charcoal paint harmless to the human body by using natural resins and charcoal, algae (Kelzyme) by the method and the composition of the natural resin composition containing the charcoal according to the present invention, deodorization, anion emission, far-infrared emission, It has the effect of anti-mildew, indoor humidity control, blocking water vein and electromagnetic waves, creating a pleasant indoor environment, giving atopy prevention effect and anti-aging effect.

Hereinafter, the present invention will be described in more detail.

The method for producing a natural resin composition containing charcoal and the composition according to the present invention is capable of providing charcoal paints harmless to the human body using natural resins and charcoal and seaweed (Kelzyme), deodorization, anion emission, far infrared emission, anti As it has the effect of controlling mold, indoor humidity control, water vein and electromagnetic wave, it has the characteristics of creating a pleasant indoor environment, giving atopy prevention effect and anti-aging effect.

First, looking at step S1, 10 to 30 parts by weight of linseed oil, 10 to 30 parts by weight of tung oil and 10 to 30 parts by weight of rosin in a nitrogen (N ₂ ) atmosphere by heating in a natural Preparing a resin (step S1) and adding 5 to 10 parts by weight of plants (D-Limonene) and the first additive to the natural resin to prepare a diluted natural resin.

The linseed oil is the most widely used paint and is a dry oil obtained from the seeds of flax and is produced in Southeast Asia and various regions. The lining acid tends to yellow when the light is light due to the high dryness and the content of many unsaturated groups. have. Its main component is 22% oleic acid (C ₁₈ H ₃₄ O ₂ ), linoleic acid (C ₁₈ H ₃₂ O ₂ ) 16%, linolenic acid (C ₁₈ H ₃₀ O ₂ ) 52%.

If 10 to 30 parts by weight of such flaxseeds are used, if less than 10 parts by weight, the flexibility is insufficient and can be gelled in the middle of the reaction, on the contrary, if it exceeds 30 parts by weight, the performance of the coating after the actual construction may be degraded have.

In addition, the oil is extracted from camellia and is mainly produced in China and Japan, and has a conjugated double bond as a dry oil, characterized by fast drying and high viscosity. Due to the fast reaction speed, special attention is required in the polymerization process, and it is hard and has good water resistance and alkali resistance. The main ingredients are oleic acid 8%, eleostearic acid 80%, palmitic acid 8%.

10 to 30 parts by weight of such oil may be used. If less than 10 parts by weight, drying may proceed slowly after construction, and if it exceeds 30 parts by weight, the resin may gel during the reaction.

The rosin is wound on pine to collect the sap to distill the sap of the coating film is strong and increases the wear resistance, adhesive strength and excellent corrosion resistance, antiseptic, insect repellent effect. The main ingredients are 80% rosin, 15% volatile terepine oil and 5% moisture.

If 10 to 30 parts by weight of the rosin is used, if less than 10 parts by weight, a decrease in adhesive strength may occur after construction, on the contrary, if it exceeds 30 parts by weight, the resin may gel during the reaction.

In addition, the step of preparing the natural resin is carried out in a nitrogen atmosphere, the reason is to increase the reaction efficiency, such as reaction rate, color. Nitrogen at this time is supplied in an amount and rate of 0.01 to 0.04 ft ³ / min / gal. If less than 0.01, the reaction efficiency can be reduced, on the contrary, if exceeding 0.04, the supply of more than necessary may cause waste of energy resources.

The linseed oil, kerosene and rosin in the nitrogen atmosphere is heated, the temperature may be 210 to 260 ℃. If it is less than 210 ° C., the automatic oxidation and Diels Alder reactivity may be insufficient. On the contrary, if it exceeds 260 ° C., the color may be carbonized and blackened and may gel during the reaction.

In addition, the heating time here is 10 to 20 hours, if less than 10 hours, the reaction efficiency can be reduced, on the contrary, if it exceeds 20 hours can be gelated during the reaction due to overreaction.

Next, looking at step S2, by adding 5 to 10 parts by weight of the plant (D-Limonene) and the first additive to the natural resin to prepare a diluted natural resin.

The limonene (D-Limonene) is extracted from the lemon plant is used as a natural fragrance and diluent, and the fragrance is helpful to increase the amount of adrenaline in the human body.

After the reaction of step S1 is terminated, cooling is started, and when the temperature is about 140 ° C. or less, the natural resin is diluted by adding 5 to 10 parts by weight of the plant and the first additive. Here, if the plant is less than 5 parts by weight, storage stability may be reduced and defects may occur during storage. On the contrary, if the amount of plants exceeds 10 parts by weight, the characteristics of the coating after construction may deteriorate.

In addition, the first additive may be at least one selected from the group consisting of zirconium and dipentene.

The first additive is used in 5 to 10 parts by weight, if less than 5 parts by weight, the storage stability may be reduced and high viscosity, and if it exceeds 10 parts by weight, it may be irritating to the human body.

Finally, in the step S3, the charcoal is added to the diluted natural resin at 1000 to 1200 rpm for 1 to 3 hours, and the hollow pillars 30 to 90 parts by weight, seaweed (Kelzyme) 30 to 40 parts by weight, porous 30 to 40 parts by weight of minerals, 30 to 40 parts by weight of heavy coal, and 30 to 40 parts by weight of ganbanite were added, mixed for 30 minutes to 2 hours, and 35 to 50 parts by weight of water and 20 to 35 parts by weight of the second additive were further added. Mixing uniformly for 20 minutes to 1 hour (step S3).

Here, the charcoal is added to the diluted natural resin at 1000 to 1200 rpm for 1 to 3 hours. If less than 1000 rpm, the dispersion effect is low, so that the process efficiency may be lowered. Bubbles may occur, and if less than 1 hour of stirring may not exhibit the dispersing effect properly, if exceeding 3 hours may cause unnecessary manufacturing costs such as excessive energy release.

In addition, the charcoal is at least one selected from the group consisting of bamboo charcoal, oak charcoal and red pine charcoal, the average particle size is 20 to 40㎛. If the average particle size is less than 20 μm, it may gel during storage and conversely, if it exceeds 40 μm, a precipitate may be produced during storage.

In addition, the hollow pillar is a polyacrylonitrile (poly acrylonitrile) is coated with calcium carbonate and titanium dioxide, the size of 10 to 40 ㎛ used, if the hollow pillar is less than 10 ㎛, high viscosity Due to this, productivity may be reduced, and on the contrary, when it exceeds 40 μm, the surface may be roughened.

In addition, the hollow pillar may be used 30 to 90 parts by weight, if less than 30 parts by weight, the effect of condensation and heat insulation can be lowered, on the contrary, if it exceeds 90 parts by weight may be insufficient storage stability.

In addition, the algae is a powder obtained by crushing fossils of algae, called kerfs in the sea, containing calcium, minerals, microorganisms, and active enzymes. When mixed with soil, the algae increase the production quality of plant and grain harvest and are absorbed by the human body. If you have healthy skin, increase immunity, anti-aging, osteoporosis preventive effect. In addition, the components of the seaweeds, calcium oxide (CaO), calcium carbonate (CaCO3), oxo (I), zinc (Zn), chromium (trivalent Cr), magnesium (Mg), iron (Fe), sodium (Na), potassium (K), manganese (Mn), silica (Si), selenium (Se), phosphorus (P) and other seaweed microorganisms.

30 to 40 parts by weight of the seaweed is used, if less than 30 parts by weight, the effect of physiological activation energy dissipation can be reduced, on the contrary, if more than 40 parts by weight, the other components are relatively less adversely affect the overall effect Can be crazy

In addition, the size of the porous mineral is 30 to 50㎛, if less than 30㎛ may cause a lack of fluidity of the entire composition due to the high viscosity, on the contrary, if the thickness exceeds 50㎛, the surface of the porous mineral is porous Diatomaceous earth containing silicon dioxide as a main component can be used, and the amount used is 30 to 40 parts by weight. If less than 30 parts by weight, the effect of heat insulation, deodorization and humidity control is insufficient, on the contrary, if it exceeds 40 parts by weight, other components may be relatively insufficient.

On the other hand, the bicarbonate is produced by using limestone as a raw material is usually used as a sieving pigment. The amount used here is 30 to 40 parts by weight, if less than 30 parts by weight of the coating film may be insufficient strength and poor workability, on the contrary, if it exceeds 40 parts by weight, the amount of other components is relatively reduced.

In addition, the ganbanite is a porous pigment containing a large amount of minerals such as ferric oxide, calcium, manganese, magnesium, etc., which are mainly composed of silicic anhydride and aluminum oxide, and are adsorbing, promoting development, neutralizing toxicity, preventing cancer, and deodorizing. It has far-infrared emission effect. Such elvan has a size of 5 to 20 μm, and if it is less than 5 μm, the high viscosity may result in insufficient fluidity of the entire composition, and if it exceeds 20 μm, the surface may become rough. In addition, the ganbanite uses 30 to 40 parts by weight, if less than 30 parts by weight, lack of fluidity due to high viscosity may be a problem, on the contrary, if it exceeds 40 parts by weight, the surface may be rough.

In addition, the hollow pillar, the seaweed (Kelzyme), porous minerals, bicarbonate and ganbanite is added to mix for 30 minutes to 2 hours, if less than 30 minutes may cause a problem of low dispersibility, if 2 Over time, bubbles may occur due to overdispersion.

Finally, 35 to 50 parts by weight of water and 20 to 35 parts by weight of the second additive are further added to uniformly mix for 20 minutes to 1 hour.

Wherein the water is used 35 to 50 parts by weight, if less than 35 parts by weight is high viscosity and adversely affect the workability, on the contrary if more than 50 parts by weight may cause a low viscosity problem.

On the other hand, the second additive may be at least one selected from the group consisting of Xanthane Cum and sodium carbonate.

If the second additive is less than 20 parts by weight, the emulsification capacity may be reduced. On the contrary, if the second additive is more than 35 parts by weight, the water resistance or adhesive strength of the coating film after construction may be reduced.

In this case, the water and the second additive are uniformly mixed for 20 minutes to 1 hour, but if it is less than 20 minutes, the storage stability or emulsification performance may be insufficient, and if it exceeds 1 hour, excessive mixing may cause bubbles. have.

On the other hand, 10 to 30 parts by weight of linseed oil, 10 to 30 parts by weight of tung oil and 10 to 30 parts by weight of rosin in a nitrogen (N2) atmosphere to prepare a natural resin (S1) Step) and adding 5 to 10 parts by weight of plants (D-Limonene) and the first additive to the natural resin to prepare a diluted natural resin (step S2) and the charcoal to the diluted natural resin 1 to 1 to Stir at 1000 to 1200 rpm for 3 hours, 30 to 90 parts by weight of hollow pillars, 30 to 40 parts by weight of seaweed (Kelzyme), 30 to 40 parts by weight of porous minerals, 30 to 40 parts by weight of bicarbonate and 30 to 40 parts by weight of ganbanite Charcoal is prepared through the addition of 30 minutes to 2 hours and mixing 35 to 50 parts by weight of water and 20 to 35 parts by weight of the second additive to uniformly mix for 20 minutes to 1 hour (step S3). Natural resin composition containing Using charcoal and seaweed (Kelzyme), it is possible to provide charcoal paint that is harmless to the human body, and it has a deodorizing effect, anion emission, far-infrared emission, anti-fungal properties, indoor humidity control, blocking vein and electromagnetic waves, creating a pleasant indoor environment. It can give atopic prevention effect and anti-aging effect.

Example 1

* First, 20 parts by weight of linseed oil, 20 parts by weight of tung oil and 20 parts by weight of rosin are supplied at a rate and rate of 0.03 ft ³ / min / gal of nitrogen (N ₂ ) at 230 ° C. It was heated for 15 hours to prepare a natural resin. Subsequently, after cooling to 140 ° C., 10 parts by weight of limonene (D-Limonene) was added to plants, and 8 parts by weight of zirconium and dipentene were added as first additives to dilute the natural resin. Next, red pine charcoal was added to the diluted natural resin and stirred at 1100 rpm for 2 hours, followed by 55 parts by weight of hollow pillars, 35 parts by weight of seaweed (Kelzyme), 40 parts by weight of porous minerals, 35 parts by weight of bicarbonate and elvan 40 parts by weight were added to the mixture for 1 hour, and then 40 parts by weight of water and 30 parts by weight of xanthan gum and sodium carbonate were added as a second additive, and the mixture was uniformly mixed for 50 minutes to contain a natural resin containing charcoal according to the present invention. The composition was prepared.

Experimental Example 1

The natural resin composition containing charcoal prepared according to Example 1 was tested according to the experimental methods and specifications shown in Table 1 below and the results were shown.

   Item     Experiment method    Test result    Remarks  Exterior    Black paint  KSM 5000  Polish  60 ° mirror polisher    10 or less / matt  KSM 5000-3311 Volume solids (%)     40-50  KSM 5000-03 State (KU)  Krebs-stomer Viscometer 25 ℃     80-100  KSM 5000-2122  Specific gravity (25 ℃)  100cc specific gravity cup     1.2 ± 0.2  KSM 5000-2131 Drying time (25 ℃) Touch   Within 40 minutes  KSM 5000-2511 Solidification   More than 4 hours very   More than 24 hours  Deodorization rate (%)  After 120 minutes    93% or more  KICM-FIR-1085 Water resistance  Distilled water 7 days immersion, swelling, peeling     Good  KSM 5000-1121 Alkali resistance  Saturated Ca (OH) 2 solution, 7 days deposition,     Good  KSM 5000-1121 Wash resistance  Washability Test 1000 Times     Good  KSM 5000-3351 Workability  Paint brush     Good  KSM 5000-2412  Airless Paint     Good Anion emission amount   (ION / CC)  Forest area: 800 ~ 1300 ION Downtown: 50 ~ 100 ION     More than 1000  KFIA-FI-1042 Antifungal  Pluraria Fullyulence (Horse) Aspergillus Niger (hypha) Penicillium Citrium (hypha)   4-week incubation: 10 (none)  KSM 5000-3431 KSM 6020 Far infrared radiation rate  Emissivity of 5 ~ 20㎛ wavelength     92% or more (no decrease)  FT-IR, Black Body Total Volatile Organics  Compound (TVOC)  Less than 0.4mg / ㎡h     none  Main test method Formaldehyde  (HCHO)  Less than 0.12mg / ㎡h     none  Main test method Condition in container  Rivering, Skinning, Pigmentation    clear  KSM 5000-2011 Repaintable  Lifting, Softening, Smoothness     Good  KSM 5000-2421

Referring to <Table 1>, the natural resin composition containing charcoal according to the present invention is capable of providing charcoal paints harmless to the human body using natural resins and charcoal and algae (Kelzyme) and deodorizing, anion dissipation, far-infrared radiation , Anti-mildew, indoor humidity control, water vein and the effect of blocking the electromagnetic wave, so it can be confirmed that to create a pleasant indoor environment and to give atopic prevention effect and anti-aging effect.

Claims (10)

10 to 30 parts by weight of linseed oil, 10 to 30 parts by weight of tung oil and 10 to 30 parts by weight of rosin in a nitrogen (N2) atmosphere to prepare a natural resin (step S1) ; Preparing a diluted natural resin by adding at least one selected from the group consisting of 5 to 10 parts by weight of plants (D-Limonene) and zirconium and dipentene as the first additive (S2); And Charcoal is added to the diluted natural resin at 1000 to 1200 rpm for 1 to 3 hours, 30 to 90 parts by weight of hollow pillars, 30 to 40 parts by weight of seaweed (Kelzyme), 30 to 40 parts by weight of porous minerals, and heavy coal 30 to 40 parts by weight and 30 to 40 parts by weight of elvan rock are added and mixed for 30 minutes to 2 hours, and at least one selected from the group consisting of Xanthane Cum and sodium carbonate as 35 to 50 parts by weight of water and the second additive. Adding 20 to 35 parts by weight to further uniformly mixed for 20 minutes to 1 hour (step S3); The method of producing a natural resin composition containing a charcoal comprising a. The method of claim 1, The heating temperature in the step S1 is a method for producing a natural resin composition containing charcoal, characterized in that 210 to 260 ℃. The method of claim 1, The heating time in the step S1 is a method for producing a natural resin composition containing charcoal, characterized in that 10 to 20 hours. The method of claim 1, The hollow filler is a polyacrylonitrile (poly acrylonitrile) is coated with calcium carbonate and titanium dioxide, the method of producing a natural resin composition containing charcoal, characterized in that the size of 10 to 40㎛ . The method of claim 1, The porous mineral is a method for producing a natural resin composition containing charcoal, characterized in that the diatomaceous earth containing the main component of porous silicon dioxide. The method of claim 5, wherein The porous mineral is a method of producing a natural resin composition containing charcoal, characterized in that the size of 30 to 50㎛. The method of claim 1, The elvan is a method of producing a soft resin composition containing charcoal, characterized in that the size of 5 to 20㎛. The method of claim 1, The charcoal is a method of producing a natural resin composition containing a charcoal, characterized in that at least one selected from the group consisting of bamboo charcoal, oak charcoal and red pine charcoal. The method of claim 1, The charcoal is a method of producing a natural resin composition containing a charcoal, characterized in that the average particle size of 20 to 40㎛. 10. A natural resin composition containing charcoal prepared by the method of any one of claims 1 to 6 and 8 to 9.