KR100886617B1 - Manufacturing method of antibiotic deodorant and machine using thereof - Google Patents

Abstract

The present invention relates to a method for producing antimicrobial deodorant combining wood vinegar and minerals, and more particularly, to producing crude wood vinegar by hardwood and conifers such as oak, pine, pine, cypress, bamboo, etc. The present invention relates to a method for preparing antimicrobial deodorant by mixing, reacting and combining crude wood vinegar in a state containing soluble tar and suspended tar, such as ocher, zeolite and activated clay, which are highly functional minerals. To this end, the present invention is a method for producing a stable and homogeneous high concentration crude wood vinegar using a carbonized carbonization system in a much simpler process than the deodorant manufacturing method using the conventional wood vinegar, and a highly functional inorganic material that has undergone purification, aging, and reaction By combining and reacting the crude wood vinegar, characterized in that the method for producing an antibacterial deodorant combination of wood vinegar and inorganic matters with excellent deodorizing efficiency.

Antibacterial deodorant combining wood vinegar and inorganic matter, crude wood vinegar, aging, reaction, combination, dry carbonization system, particulate matter, absorption, neutralization

Description

Manufacturing method of antimicrobial deodorant combining wood vinegar and mineral and apparatus used therein {Manufacturing method of antibiotic deodorant and machine using Julia}

The present invention relates to an antimicrobial deodorant using crude wood vinegar and inorganic matters and a method for producing the same, and more specifically, to a method for producing crude wood vinegar, and more specifically, carbonized carbonaceous plants such as oak, pine, pine, cypress, bamboo, etc. Method of producing an antibacterial deodorant by producing crude wood vinegar (liquid freshly cooled by charcoal smoke, hereinafter 'woodwood vinegar'), by combining and reacting the crude wood vinegar and a mineral rich in a high functional substance and using the same It is about a device.

In general, the deodorizing method is to remove the odorous substances by a method such as absorption, neutralization, adsorption, oxidation, decomposition, masking.

The wet absorption method is a method of deodorizing a malodorous component by contacting with an aqueous solution of an acidic or alkaline chemical using the solubility of a gas in a liquid. Direct spraying is difficult, the removal rate of organic solvents is low, and secondary environmental pollutants are generated due to the increase of maintenance costs and the generation of waste water.

Adsorption deodorization method is a method to deodorize the odor component by adsorption by using a blower such as activated carbon by a blower. The scope of application is limited, it is difficult to apply to a large amount of emission sources, it is inadequate for the treatment of moisture and high temperature exhaust gas, and the maintenance cost such as the regeneration and exchange of adsorbent is high.

Catalytic oxidation is a method of deodorizing odorous substances using a catalyst as a medium. The treatment efficiency is high, but the scope of application is limited due to excessive facility costs and maintenance costs.

Combustion method is a method of burning odorous substances by direct combustion at high temperature and is suitable for small throughput and high concentration, and high facility cost and maintenance cost.

Microbial deodorization method is a method of deodorizing odor component by biochemical reaction, it is difficult to maintain microbial activity condition and it is expensive for facility, but it is suitable for big exhaust gas treatment.

The ozone deodorization method is a method of oxidizing and removing odorous substances by contact with ozone, and the ozone generator installation cost and operation cost are high.

Masking method, also known as aroma, is a method of concealing odorous substances with other fragrances and is the most widely used, and the method of use is simple and diverse. However, since it is not the removal of odor components, it must be sprayed continuously, and there are problems such as secondary odor removal, not fundamental odor removal.

Recently, a technology of eco-friendly deodorant mixed by extracting deodorant components of natural plants and vegetation by various methods has been developed.

As an example, as shown in FIG. 1, hardwoods, conifers, and vegetation, such as oak, are carbonized in a heating furnace to obtain crude wood vinegar, and aged for about 6 months to separate them into a water layer, a wood vinegar layer, a tar layer, and the wood vinegar solution of the wood vinegar layer. It is a method of separating and using as a deodorant through filtration, stirring, evaporation, and distillation, or by mixing with other essential oils and other deodorants of vegetation.

This method is an eco-friendly product that has good effects such as absorption, neutralization, oxidation, and decomposition of deodorant when it comes into contact with odorous substances, and has a long ripening period of about 6 months. This is complicated and the production cost is higher than necessary.

In addition, as described above, the conventional wood vinegar was necessary for the long-term aging process of crude wood vinegar, which is a process for separating the tar component in the crude wood vinegar, and to reduce the unique smell of the crude wood vinegar, conventionally removed such odor and tar Since there is no technique used, the wood vinegar was aged and left to separate and used. However, since tar is removed in spite of having excellent deodorizing effect during aging and politics, the present invention has been studied to provide an antibacterial deodorant having a better function by using crude wood vinegar without tar.

The present invention, in order to solve the problems of the prior art as described above, the use of environmentally friendly deodorant and easy to use, high processing efficiency, economical, eco-friendly and wide range of use of environmentally friendly antibacterial deodorant including the removal of odor Its purpose is to provide a method and a method of use.

The conventional manufacturing method is to remove the tar component having excellent deodorizing ability by aging and leaving the crude wood vinegar for about 6 months, and filtering, stirring, evaporating, and distilling only the mature wood vinegar, so that the wood vinegar deodorant has been greatly reduced. I manufacture it,

As a technical problem to be achieved by the present invention, without decomposing the crude wood vinegar produced in a carbonized carbonization furnace (see FIG. 3) without aging, filtration, stirring, evaporation, and distillation, the excellent deodorization of soluble tar and floating tar in crude wood vinegar By using a function, and in combination with the crude wood vinegar with a high functional inorganic material having excellent deodorization, adsorption, and purification components, the production process of the deodorant is simplified (refer to FIG. 2), greatly reducing the production cost, The present invention was completed by being able to manufacture an excellent anti-bacterial deodorant with improved deodorant effect.

The antimicrobial deodorant is directly mixed with the substance causing odor or diluted with water, or the antimicrobial deodorant is mixed with water in the odor generating source, mixed, stirred, sprayed, and sprayed in an aqueous state to be absorbed and adsorbed. By neutralization, fermentation, etc., it is easy and effective to remove odorous substances and to suppress and eliminate the occurrence of moldy decaying odor.

The object of the present invention is the food treatment plant, compost fermentation plant, organic fertilizer plant, livestock manure treatment plant, manure, sewage treatment plant, slaughterhouse and slaughterhouse, livestock farm, waste dumping place, agricultural and fishery market, food manufacturing plant, waste treatment plant, incineration plant, pulp and paper leather Antibacterial and deodorant which combines wood and liquor which is very economical and environmental and improves the quality of life in removing and treating odorous substances and bacterial odorous substances generated in industrial sites, hospitals, restaurants, nightlife, etc. It is used to provide industrial field and real life.

The present invention relates to an antimicrobial deodorant combining a crude wood salt and an inorganic substance and a method for preparing the same, and more particularly, a crude wood salt containing a dissolved tar and a floating tar (cold liquid freshly cooled by charcoal smoke, hereinafter referred to as 'wooden wood salt'). It relates to an antimicrobial deodorant and a method for producing the same, characterized in that it comprises any one or more functional inorganic materials selected from ocher, zeolite, activated clay.

The present invention produces crude wood vinegar from hardwoods and conifers such as oak, pine, pine, cypress, bamboo, juniper, cypress, ginkgo by dry carbonization method, solubilized tar and suspended tar containing soluble tar and suspended tar The present invention relates to a method for preparing an antimicrobial deodorant mixed with high functional minerals such as ocher, zeolite, activated clay, and the like, and the use thereof.

To this end, the present invention can produce a stable and homogeneous high concentration of crude wood vinegar using a carbonized carbonization system (see Fig. 3), conventionally aged and settled crude wood vinegar for about 6 months, water layer, wood vinegar layer, tar layer Compared to the method of preparing a deodorant through filtration, stirring, evaporation, and distillation of the wood vinegar solution of the wood vinegar layer (see FIG. 1), crude wood vinegar is used without undergoing aging and settling process. There is a characteristic that can be produced by the process antibacterial deodorant. In addition, by combining and reacting the high functional inorganic material and the crude wood vinegar, which has undergone the purification and aging, and the reaction process, it is characterized by a method of preparing an antibacterial deodorant combining the wood vinegar and the inorganic material with excellent deodorizing efficiency.

That is, there is no conventional odor removal technology of the strong odor crude wood vinegar compared to using only wood vinegar by aging it, the present invention was found that the tar mixed in wood vinegar has an excellent odor removal function, without separating such tar In order to use it completely, as a material to remove the smell of crude wood vinegar and to make its function more excellent, it has developed a technology for mixing high functional inorganic materials such as ocher, zeolite, activated clay, and the like.

The antimicrobial deodorant prepared as described above is directly absorbed, mixed, agitated or sprayed and sprayed with an odorous substance including organic substances, inorganic substances and particulate matter, or diluted with water to stir or sprayed and sprayed to an odorous substance. The reaction of adsorption, neutralization, fermentation, etc. is simple and easy to effectively suppress and remove odorous substances.

In addition, the odor emission material is aspirated to remove the odor substance by contacting and reacting the absorption tower with an antibacterial deodorant of the present invention as a solution.

The present invention is an eco-friendly deodorant which has much better performance than conventional deodorants and conventional herbicide deodorants by combining and reacting the high functional properties of inorganic soluble tars and floating tars with strong antibacterial properties such as organic acids. The preparation method of the present invention is presented.

In addition, it features excellent price competitiveness, easy to apply, and easy to use.

Hereinafter, the components of the present invention will be described in more detail.

The present invention is a high functional inorganic material to remove the smell of the crude wood vinegar and improve its function, any one or more selected from ocher, zeolite, activated clay after purification and aging, combined with crude wood vinegar after the reaction process, By reacting to prepare an antibacterial deodorant combination of wood vinegar and inorganic substances with excellent deodorizing efficiency.

In the present invention, the high functional inorganic material means that one selected from ocher, zeolite, and activated clay can be used alone or mixed, and the functional inorganic material is mixed with water and stirred for 1 to 20 days. After aging, particles having an average particle diameter of 0.01 to 0.05 mm may be separately added or added as a mixed solution mixed with water. The functional inorganic material, which is a mixed solution in the particulate state or in a mixed state with water, is preferably added in an amount of 1 to 20% by weight of the total antimicrobial deodorant composition. When used in the above range has an excellent antibacterial deodorizing effect in the economic range.

In the present invention, the ocher has been known as an excellent antimicrobial, deodorizing function, and after the aged ocher is aged by stirring for 1 to 20 days in water, the average particle diameter of 0.01 ~ 0.05mm size (300 ~ 400 mesh) particles Only use it separately. Using in the above range can maintain the crude wood vinegar in solution, and can be removed by adsorption and reaction of harmful substances in the crude wood vinegar.

At this time, when the aging process is activated, it is preferable to go through the aging process because the microorganisms are activated to make a good environment for reaction. At this time, the mixing ratio of ocher and water is preferable because it is advantageous to the maturation conditions to use water of 1 to 10 times the weight of the ocher.

In addition, the zeolite is known as a porous material, it is known as a very excellent antibacterial, anti-odor material. The aging process of the zeolite is the same as the above ocher, so further description thereof will be omitted.

In addition, the activated clay is known as a material having an excellent adsorption capacity, and the adsorption power for the suspended tar having a large particle in the floating tar is very excellent. The maturing process of activated clay is also the same as the loess, so further description thereof will be omitted.

Next, a method for producing an antibacterial deodorant will be described in detail.

a) producing carbonized gas by burning, carbonizing, and distilling the wood chips into chips in a dry carbonization furnace;

b) preparing the carbonized gas prepared by using a condensation system as crude wood vinegar containing dissolved tar and suspended tar;

c) mixing at least one functional inorganic material selected from ocher, zeolite and activated clay with water and stirring to mature for 1 to 20 days;

d) mixing and reacting the crude wood vinegar and the functional inorganic material;

It includes.

In the step a), the carbonized carbonization furnace includes a combustion zone of 400 to 600 ° C., a carbonization zone of 250 to 400 ° C., and a drying zone of 150 to 250 ° C., and the carbonized gas combusted from the bottom by the low oxygen carbonization method is a carbonization zone. It is discharged to the upper part through the carbonation zone. The carbonized gas thus discharged is condensed by the condensation system of step b) to prepare crude wood vinegar including dissolved tar and suspended tar. At this time, the condensation method has a high condensation efficiency using a multi-stage condensation method.

Next, an apparatus for manufacturing crude wood vinegar according to the present invention will be described with reference to FIG. 3.

A dry distillation type carbonization tank (10) through which wood chips are crushed and carbonized gas which has undergone combustion, carbonization and dry distillation is discharged upwardly;

A first collecting tank 20 collecting the discharged carbon gas;

A multi-stage condensation tank (30) for condensing the collected carbonized gas in a multi-stage to crude wood vinegar;

A first reservoir (40) for storing the crude wood vinegar condensed from the condensation tank;

A second collecting tank 50 for collecting carbonized gas not condensed from the condensing tank;

A centrifugation tank (60) for converting tar in the carbonized gas collected by the second collection tank (50) into a crude wood vinegar by centrifugation;

A blower 70 for discharging the carbonized gas from which tar is separated by the centrifugation tank 60;

A second storage tank (80) for storing the crude wood vinegar converted from the centrifugation tank (60);

Crude wood vinegar storage tank (100) for storing the crude wood vinegar transferred by the transfer pump 90 from the first reservoir (40) and the second reservoir (80);

It includes.

Hereinafter, described in detail by the accompanying drawings as follows.

Figure 2 is a method for producing a wood vinegar antibacterial deodorant made from hardwoods and conifers such as oak, pine, pine, cypress, bamboo, juniper, etc., showing the overall manufacturing process and Figure 3 is a dry matter for producing crude wood vinegar It is a block diagram which shows a type | mold carbonization furnace.

To explain the method, hardwoods and conifers such as oak, pine, pine, cypress, bamboo and juniper are made into chips of about 30 mm x 50 mm, and the damper 14 at the upper part of the carbonized carbonization of FIG. 3 is opened. The chip is put in a certain amount and closed by the automatic device. The injected chip is burned at 400 ° C. to 600 ° C. in the lower combustion zone 11 in the carbonization furnace 10, and carbonized at a temperature of 250 ° C. to 400 ° C. at the central carbonization zone 12, and at the upper end. The carbonization zone 13 is formed at 150 ° C to 250 ° C, and carbonization continues. The carbonization condition at this time is a low oxygen carbonization method to supply only a very small amount of air to continue the carbonization, the carbonized carbide (charcoal) is discharged through the lower hopper 15, the carbonized gas (dry gas) is about 80 ~ 150 ℃ 1 is discharged into the collection tank 20 and the condensation tank (30).

The condensed carbonized gas (dry gas) is condensed by the cooling water supplied from the cooling tower 33 and discharged into the crude wood liquor state, collected in the first storage tank 40, and then stored by the feed pump 90 by the water level device. Stored in tank 100.

In order to improve the efficiency of condensation recovery, the condensation tank 30 is condensed into multiple stages 31 and 32, and the centrifugal separation tank 60 is used to collect tar and uncondensed gas having a large particle size contained in the carbonized gas discharged after condensation. ) And the carbonized gas is discharged through the pipe in the state containing the carbon component by the exhaust fan 70 is reused as thermal energy.

The preparation method of crude wood vinegar extracted from the carbonized carbonization furnace 10 of the above method has a much higher concentration of organic acid, which is an essential requirement of the odor deodorant, and a higher concentration of soluble tar than the conventional charcoal kiln.

Therefore, to maintain the stability and homogeneity of the product performance, and to produce a raw material excellent in the content of organic components and methanol phenols is proposed the above manufacturing method of a continuous carbonization process.

In addition, in order to further improve the deodorizing performance and antibacterial performance, the size of the particles is 0.01mm after aging the yellow soil with strong deodorizing effect and antibacterial property among minerals which are high functional materials and having strong adsorption power as clay mineral for 1 ~ 20 days. After the reaction of ocher solution separated by about 0.05 mm 1 ~ 20% by weight based on the total volume with 80 ~ 99% by weight crude wood vinegar, or by mixing the zeolite, activated clay with water and aged, Single or two or more kinds are reacted by combining 1-20 wt% with 80-99 wt% of crude wood vinegar based on the total volume. At this time, the floating tar component having a large particle size is precipitated.

Characterized by the manufacturing method aimed at producing high functional antibacterial deodorant with strong antibacterial properties, the natural odor of wood vinegar itself is removed by zeolite's excellent deodorization, adsorption, catalytic function and deodorizing function such as activated clay and purification function. do.

The use and use of the antimicrobial deodorant in combination with the wood vinegar and the inorganic substance of the present invention is diluted with the antibacterial deodorant and odor emission material after diluting 5 to 40 times by weight of water with respect to the weight of the antibacterial deodorant directly or Remove odor from odor emission source by mixing, diluting and stirring, and then use in other process to reduce odor emission, or by spraying and spraying directly to odorous substances polluted and generated in air from odor emission material , Odor, neutralization, fermentation, etc., and odorous substances generated from the discharge source are aspirated through the hood and duct to enter the absorption tower to contact and react with the solution of the antibacterial deodorant in the tower. Types of absorption tower include packed column type, spray tower scrubber, venturi type, and cyclone jet type. It includes its attached facilities.

The optimum use condition of the antibacterial deodorant is mixed with water of 5 to 40 times the weight of the antibacterial deodorant, prepared as a solution, and then mixed, diluted, using the antimicrobial deodorant 0.1 to 20% by volume based on the total volume of the odor emission material, The highest efficiency when used with stirring.

Optimal use conditions for direct spraying, spraying, and contacting odorous substances discharged to the air are 0.1 to 5% by volume based on the total volume of odor emission after diluting with a solution by mixing with 5 to 40 parts by weight of water based on the weight of the antibacterial deodorant. When spraying, spraying, or contacting 20% by volume of discharged pollutants with discharged sources, the efficiency is the highest. use.

In addition, the optimal use conditions for removing the malodorous substances by contacting them with the solution of the antimicrobial deodorant in the absorption tower and removing them are a solution diluted by mixing with water of 5 to 30 times with respect to the weight of the antimicrobial deodorant. Continue to use it. At this time, the optimum pH range of the circulating solution is the solution at pH 5 to pH 6, and the removal efficiency is highest when contacted at an air column speed of 0.5 m / sec to 1.5 m / sec or a residence time of 2 to 10 seconds.

The production conditions of high quality antibacterial deodorant are important because the choice of carbonization furnace with high organic acid components made by ionization at high temperature is important, and the production method of homogeneous crude wood vinegar which is produced continuously under the same temperature and dry conditions It is an essential requirement for improvement. In addition, it proposes the composition of antimicrobial deodorant which has strong antibacterial ability and excellent deodorant performance by combining and possessing strong deodorizing property of crude wood vinegar and unique characteristic of high functional mineral which is eco-friendly and very useful for our flora and fauna.

As described above, the present invention, by contacting the odorous tar and floating tar and organic acids with strong deodorizing properties inherent to crude wood directly to odorous substances, much higher performance than the conventional deodorant and conventional wood vinegar deodorant, excellent deodorizing effect It is manufactured by combining and reacting high functional properties of inorganic materials such as ocher, zeolite, and activated clay, which have strong antibacterial properties, so that it can produce deodorant with superior antibacterial properties, and has a wide range of application and use range for livestock manure, livestock farms, food processing plants, food Businesses that emit organic odors such as factories and ammonia, and infectious odors of fungal bacteria, remove basement molds polluted with air quality, remove odors such as food, alcohol, and sweat from entertainment venues, and soak in restaurants. It is widely applied to the removal of odors and treatment of businesses that emit bacterial odors such as hospitals. Long life cycle

The manufacturing process of deodorant is greatly reduced to increase productivity and efficiency, and the cost of production is greatly reduced, thereby increasing price competitiveness. Therefore, it is possible to provide high efficiency and inexpensive products to users.

Simple convenience of directly mixing and stirring odor emission materials such as collected food, compost, organic fertilizer, livestock manure, manure, sewage sludge, slaughter, wastewater sludge, etc. It is easy to use because it can remove the odor emission material because it is used as a method of removing the odor substance and the present invention in the existing absorption tower, etc.

The antibacterial deodorant of the present invention is an environmentally friendly material that is harmless to the human body, and promotes the growth of pigs, cows, and chickens by removing the air purification and bacterial substances as an environmental improving agent of copper and plants, and changes the ammonia odor into an amino acid group. There is no secondary environmental pollution, and it is expected to contribute to the industrial site and real life as an excellent eco-friendly antibacterial and deodorant that combines the effect of soil improver with the growth promoting activity of microorganism together with ocher and zeolite.

Hereinafter, the present invention will be described by way of example for the detailed description of the present invention, but the present invention is not limited to the following examples.

EXAMPLE

Preparation of crude wood vinegar

The oak and cypress trees were mixed in a 1: 1 weight ratio and crushed by a crusher to prepare chips of 30 mm × 50 mm size, which were charged to the dampers of the carbonized carbonization furnace of FIG. 3. At this time, the temperature of the carbonization zone was 300 ° C and the carbonized zone was maintained at 200 ° C. Steam was discharged to 140 ° C. at the upper end of the distillation type carbonization furnace, first cooled in the first collection tank, and then cooled in a condensation tank to condense crude wood vinegar. At this time, tar components not separated at low temperature were separated by centrifugation tank. An antibacterial deodorant was prepared using the crude wood vinegar thus prepared.

Functional minerals  Produce

10 kg of ocher was mixed with 40 kg of water and left for 10 days while stirring at a speed of 25 rpm. The ocher solution was filtered through a sieve of 300 mesh to remove coarse particles.

After mixing 10 kg of zeolite and 40 kg of water, the mixture was left for 10 days while stirring at a speed of 25 rpm. The zeolite solution was filtered through a sieve of 300 mesh to remove coarse particles.

After mixing 10 kg of activated clay and 30 kg of water, the mixture was left for 10 days while stirring at a speed of 25 rpm. A 300 mesh sieve was used to filter the activated clay solution through a sieve to remove coarse particles.

The ocher solution: zeolite solution: activated clay solution was mixed in a 1: 1: 1 weight ratio to prepare a functional inorganic solution.

Preparation of Antibacterial Deodorant

For 80 kg of the crude wood vinegar prepared above, 20 kg of the functional inorganic solution was mixed, and then stirred at room temperature for 10 days, followed by sieving to remove floating tar with large particles.

As a result, the odor of crude wood vinegar was reduced, and an antibacterial deodorant having a viscosity of 20 cps was prepared.

Experimental Example

Deodorizing effect was measured by various methods using the antibacterial deodorant prepared in the above Examples.

Experimental Example 1

A odor source (ammonia water, Na ₂ S) is injected into a 50 × 50 × 50 cm acrylic container so that the odor concentration inside the device is 50 ppm of methylmerethane, 60 ppm of hydrogen sulfide, 60 ppm of ammonia, and 60 ppm of trimethylamine (Model 801). , Gas Tec Co, Japan). In each device, 20 ml of the antibacterial deodorant solution was sprayed through an injector. (The following experiment was performed by comparing 7.0 kg (7 times) and 15 kg (15 times) of water per 1.0 kg of the antibacterial deodorant.) After 5 minutes, 30 minutes, 1 hour, 2 hours, 3 hours after each concentration was measured by the KS M 0062 (detector tube gas measuring instrument) method. At this time, the room temperature was 25 ℃, relative humidity was 65%.

The results are shown in Table 1 below.

[Table 1] (Unit: ppm)

Experimental Example 2

Odor substances generated during the processing of food processing establishments, ammonia, hydrogen sulfide, amines, methyl mercaptan was measured and analyzed.

When the antimicrobial deodorant was introduced into the food hopper, the solution was directly added to the input hopper as a 10-fold diluted solution, and then added at 1.0% by volume with respect to the amount of food, followed by stirring for 30 minutes. (30 tons))-Grinding (crushing fiber and foreign substances in food)-Dehydration-Storage (storage of crushed food)-Drying (evaporating and drying water in food, temperature: 600 ℃, rotary dryer-100 tons / day) Food was processed in steps. In the leachate, the storage tank, and the grinding process, sensory methods were used, and samples were taken from the dryer outlet outlet. The measuring method was the same as that of Experimental example 1. In the sensory method, 20 panelists smelled the sample and checked the degree of strong odor on a 5-point scale. (1 degree or less: almost no smell, 2 degrees: slight odor 3 degrees: odor, 4 degrees: severe odor, 5 degrees: bad odor, shortness of breath)

The results are shown in Tables 2 and 3 below.

TABLE 2

Table 3 Sensory Measurement

Experimental Example 3

The compost fermentation plant (room temperature: 27 ℃) produces organic compost through fermentation and ripening process at the compost fermentation plant after transporting compostable materials into the compost and mixing each material. Neutralization, adsorption, and reaction were carried out by contacting the odorous substance with a high-pressure sprayer and spraying the odorous substance. Reacted and treated. At this time, the mixture was diluted by mixing in an antibacterial deodorant: water = 1:20 weight ratio, and sprayed on the upper part of 0.1 vol% relative to the compost amount.

Sampling was measured before and after administering the antibacterial deodorant to the odor concentration flowing into the bio-filter (odor) in the tower by sucking the odor generated in the compost through a fan through the hood. The measuring method was the same as that of Experimental example 1.

Sensory methods were measured in the mixing warehouse and fermentation site, and odor was measured at the site boundary as a whole. In the sensory method, 20 panelists smelled the sample before spraying and spraying and after 10 minutes to check the strong odor on a 5-point scale. (1 degree or less: almost no smell, 2 degrees: slight odor 3 degrees: odor, 4 degrees: severe odor, 5 degrees: bad odor, shortness of breath)

TABLE 4

TABLE 5

1 is a schematic view showing a manufacturing process of a conventional deodorant

Figure 2 is a schematic diagram showing a manufacturing process of the antibacterial deodorant of the present invention

3 is a schematic view showing a carbonized carbonization furnace

<Description of the symbols for the main parts of the drawings>

10: distillation type carbonization tank 20: first collection tank

30: multistage condensation tank 40: first reservoir

50: second collection tank 60: centrifugation tank

70: exhaust fan 80: second reservoir

90: transfer pump 100: storage tank

11: burning stand 12: carbonization stand

13: dry mass vs. 14: upper damper

15: Hopper 31: first condensation tank

32: second condensation tank 33: cooling tower

Claims (12)

Produced by the carbonized carbonization method, the antibacterial deodorant characterized in that it comprises crude wood vinegar containing dissolved tar and suspended tar without undergoing aging and policing process, and ocher which has undergone aging while mixing with water and stirring. The method of claim 1, The ocher is mixed with water and aged while stirring, and then the particles having an average particle diameter of 0.01 ~ 0.05mm is added separately or added as a mixed solution in a mixed state with water. The method of claim 2, The mixing ratio of the ocher and water is an antimicrobial deodorant, characterized in that the mixture of ocher: water 1: 1 to 10 by weight. The method of claim 2, The antimicrobial deodorant is an antibacterial deodorant, characterized in that it comprises crude wood vinegar 80 ~ 99% by weight and 1 ~ 20% by weight ocher. The antimicrobial deodorant of any one of claims 1 to 4 is directly mixed and stirred with the odor emission material, or the antimicrobial deodorant is diluted with water and sprayed and sprayed onto the odor emission material in an aqueous solution. Antibacterial deodorization method. The method of claim 5, When diluting with the water, antimicrobial deodorizing method characterized in that to dilute by mixing water of 5 to 40 times the weight of the antibacterial deodorant. An antimicrobial deodorizing method characterized in that the odor emission material is aspirated into a hood or a duct to contact and react the antimicrobial deodorant of any one of claims 1 to 4 in an absorption tower including a scrubber type. a) Chips crushed wood include a combustion zone of 400 ~ 600 ℃, carbonized zone of 250 ~ 400 ℃, carbonized zone of 150 ~ 250 ℃, carbonized gas burned from the bottom by low oxygen carbonization method Discharged to the upper part by the stand Producing carbonized gas through combustion, carbonization and dry distillation in a carbonized carbonization furnace; b) preparing the carbonized gas prepared by using a condensation system as crude wood vinegar containing dissolved tar and suspended tar; c) mixing at least one functional inorganic material selected from ocher, zeolite and activated clay with water and stirring to mature for 1 to 20 days; d) mixing and reacting the crude wood vinegar and the functional inorganic material; Method for producing an antibacterial deodorant comprising a. delete The method of claim 8, The functional inorganic material is an antimicrobial deodorant manufacturing method, characterized in that using an average particle diameter of 0.01 ~ 0.05mm. The method of claim 8, The wood is an oak, pine, pine, cypress, bamboo, juniper, cypress, ginkgo, any one or more selected from the method of producing an antibacterial deodorant. A dry distillation type carbonization tank (10) through which wood chips are crushed and carbonized gas which has undergone combustion, carbonization and dry distillation is discharged upwardly; A first collecting tank 20 collecting the discharged carbon gas; A multi-stage condensation tank (30) for condensing the collected carbonized gas in a multi-stage to crude wood vinegar; A first reservoir (40) for storing the crude wood vinegar condensed from the condensation tank; A second collecting tank 50 for collecting carbonized gas not condensed from the condensing tank; A centrifugation tank (60) for converting tar in the carbonized gas collected by the second collection tank (50) into a crude wood vinegar by centrifugation; A blower 70 for discharging the carbonized gas from which tar is separated by the centrifugation tank 60; A second storage tank (80) for storing the crude wood vinegar converted from the centrifugation tank (60); Crude wood vinegar storage tank (100) for storing the crude wood vinegar transferred by the transfer pump 90 from the first reservoir (40) and the second reservoir (80); Carbonated distilled wood solution preparation apparatus comprising a.

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